Basic of PVC Resin Process

TPC VinaPlastic & Chemical Corp., Ltd.

VINATPC

IntroductionBasic of PVC Resin Process

What is PVC ?

• PVC is one kind of thermoplastic resin produced by polymerization of Vinyl Chloride monomer (VCM).Formular: (-CH2-CHCl-)n

TPC VinaPlastic & Chemical Corp., Ltd.VINA

TPC

PVC POLYMERIZATION MECHANISM

1. INITIATION : Under positive temp., Initiators will be discomposed into some forms of free radical.

RO- C-O- O- C- OR 2 RO-C-O. 2RO. + 2CO2

O O O

RO. + CH2 = CHCl RO- CHCl – CH2 .

Free radical

Active radical

VINATPC


TPC

2. CHAIN DEVELOPMENT: RO- CHCl – CH2

. + CH2 = CHCl -Q RO- CHCl – CH2 - CHCl – CH2.

RO- CHCl – CH2 - CHCl – CH2. + CH2 = CHCl + ........

(- CHCl – CH2 -)n-1- CHCl – CH2.

3. CHAIN END: 2-(- CHCl – CH2 -)n-1- CHCl – CH2

. (- CHCl – CH2

-)2n

2-(- CHCl – CH2 -)n-1- CHCl – CH2. (- CHCl –

CH2 -)n + (- CHCl – CH2

-)n-1- CHCl = CH2

Others


TPC

PVC APPLICATION

PVC resin is used extensively in water supply and drainage pipe, electric wire and cable, building materials, wrapping and packaging film for fresh product and other fields, supporting our daily life on a basic level


TPC

APPLICATION OF TPC Vina PRODUCT

GRADE K VALUE APPLICATION

SG580 56 - 59

65 - 67SG660

SG710 70 - 72

RIGID PROFILES, SEMI-RIGID & RIGID FILM & SHEET, BOTTLE, FITTING,...


TPC TPC VinaPlastic & Chemical Corp., Ltd.VINA

TPC

RIGID PIPE, FLEXIBLE HOSES, FILM & SHEET, WIRES & CABLES, PROFILES,...

WIRES & CABLES, ARTIFICIAL LEATHER,..


TPC

SUPERIOR FEATURES OF PVC Rigid PVC Flexible PVC

• Resistant to corrosion, chemicals, oil, and weathering• Easy to process• Lightweight (1/5 of iron or 1/10 of lead)• Flame-resistant and self-extinguishing• Excellent electric insulation• Easy coloring and printing with vivid tones for many colors• Choice of transparent, semi-transparent, or opaque products according to application

• Excellent transparent and lustrous properties• Superior elasticity and tear resistance• Soft and flexible• Barrier to oxygen• Resistant to weathering


TPC

GENERAL FULL FLOW CHART OF

VCM & PVC PRODUCTION

(CH2-CHCl)n

Natural gas

Crude oil NaphthaEthylene

DichlorideEthylene

Vinyl chloride monomer

PVC resin

Salt(NaCl)

Chlorine(Cl2)

CH2=CH2 CH2Cl-CH2Cl CH2=CHCl

Electrolysis

NAPHTHA SEPARATION

Crude oil

Synthetic rubber

Detergent materials

PlasticsSynthetic textile materials

Solvents

Others

Crude oil is refined for separating Naphtha (naphtha is the oil with the mixing of Hydrocarbon C10), up to the boiling temperature,

and many products of petrochemicals.

OIL REFINERY

Gas

Gasoline

Naphtha

Jet fuel

Kerosene

Diesel oil

Heavy oil

VINATPC

- Ethylene (C2H4) : 28-38 %

- Propylene (C3H6) : 13-18 %

- Butadiene (C4H6) : 4-5 %

- Butane/ Butylene : 4-5 %

- Aromatic : 7-4 %

NAPHTHA CRACKING(750-8700C and pressure)

DISTILLATION COLUMN

ETHYLENE

ETHYLENE PRODUCTION

Naphtha is led into the cracker to yield the mixing products of Hydrocarbon with high percentage of Ethylene (C2H4). Then, this mixture is distilled for separating Ethylene (C2H4).

VINATPC

CHLORINE PRODUCTION

PURIFICATION ELECTROLYSIS

FREEZERDRYER

Salt solution

Hydro (H2)

CHLORINE (Cl2)

NaOH

The pure Salt solution is led into the electrolysis for producing Chlorine, Chlorine is frozen and dried for VCM production

VINATPC

CHLORINE PRODUCTION

Strong Strong Caustic Caustic SodaSoda

H2O

Na+

Cl2

Cl-

Cl-

H2OH-

H2O

Na+

Chlorine Chlorine GasGas

HydrogeHydrogen Gasn Gas

Depleted Depleted BrineBrine

Anolyte

Metal Anode

Saturated BrineSaturated Brine WaterWater

Catholyte

Metal Cathode

Cation Exchange Membrene

(Chlo-Alkaline Plant)(Chlo-Alkaline Plant)VINA

TPC

VINYL CHLORIDE

COMBINED CHLORINATION ANDOXYCHLORINATION

PURIFICATION

VINYL CHLORIDEPURIFICATION

DICHLOROETHANEPYROLYSIS

Ethylene

Chlorine

Oxygen

Recycle HCl

Water

HCl stream

VCM PRODUCTIONVINA

TPC

VCM PRODUCTION

EDC Purification (Distillation and Extraction units)

EDEDCC

EDEDCC

VCM Purification(Distillation and Extraction units)

VCMVCM

Purified VCM to PVC PlantsPurified VCM to PVC Plants

Oxy Chlorination (Fluidized Bed Reactor)

C2H4+2HCl+1/2 O2 C2H4Cl2+H2O

Direct Chlorination (Fixed Bed Reactor)

C2H4+Cl2 C2H4Cl2

Ethylene

Chlorine

Oxygen

Ethylene dichloride (EDC) Section

EDC Cracking

C2H4Cl2 C2H3Cl+HCl

Recycle HCl

Import EDC

Purified EDCPurified EDC

Process Description Process Description

VINATPC

MONOMER RECOVERY AND WASTE WATER TREATMENT

VCM MONOMER

SUSPENDING AGENTS

DE-MIN WATER

POLYMERIZATION

VCM RECOVERY

DE-WATERING

DRYING

PACKING

MONOMERRECOVERY

WASTE WATERTREATMENT

RAW MATERIALS HANDLING MAIN PROCESS

MONOMERPURIFICATION

SCREEN

INITIATOR

ADDITIVES

PVC SUSPENSION PROCESS FLOW CHARTVINA

TPC


TPC

Materials used in TPC Vina process

Phenolic resinRCS1

T-C9H19-C(O)OO-C(CH3)2-C6H5Cumyl peroxyneodecanoate

C-2910

[C4H9-CH(C2H5)-CH2-OC(O)O]2Di-2-ethylhexyl peroxyneodecanoate

C-199

C(CH3)3(OH)C6H2(CH2)2COOC18H

37

Octadecyl 3 propionateAD-58

HOC6H4-C3H6-C6H4OH2,2-Diphenyl propaneAD-37

C6H7O2(OH)x(OCH3)y(OC3H7)z

(x + y + z = 3)

Metylhydroxyl propyl cenlulose

AG-56

Polyvinyl alcoholAG-25[CH2CH-OC(O)CH3]x[CH2CH-OH]y

Polyvinyl alcoholAG-14

CH2=CH-CLVinyl chlorideVCM3

H2ODemin. waterPW2

FormulaChemical nameMaterialNo


TPC

Materials used in TPC Vina process

HCLHydrochloric Acid HA21

C9H19-C(O)OO-C(CH3)3Ter-butyl peroxyneodecanoate

C-2611

KOHPotassium hydroxideCH-2520

NaOHPellet Sodium hydroxideCH-619

NaOHFlake Sodium hydroxideCH-618

C6H5C(CH3)=CH2α - Methyl styreneINH-317

(CH3)3CC6H3(OH)2P-Tert-butyl catecholINH-116

CH3-OHMethanolCH-1215

HO-CH2-CH2-OHEthylene glycolCH-914

HO-CH2-CH2-SH2-Mercapto EthanolCH-2013

[T-C4H9-CH2CH(CH3)CH2-C(O)O]2

Di-3.5.5-trimethylhexanoylperoxide

C-3012

FormulaChemical nameMaterialNo

OH

C(CH3)3

C(CH3)3

(CH2)-COOC18H37 AD5-Octadexyl 3-(3,5 di-ter butyl-4-hydroxyphenyl)

OH

CH3

CH3

C OH AD3-2,2-Di phenyl propane

CH3

CH3

CH3C

OH

OH

P-tert -butyl catechol

C=CH2

CH3

Alpha metyl styren-INH3

(C4H9-CH-CH2-O-C-O)2

C2H5O CH-19: di-2 etylhexyl-peroxidicarbonate

C9H19-C-O-O-C(CH3)3

O

CH-26E: ter-butyl-peroxineodecanoate

CH3

CH3

Ct-C9H19-C-O-O-O

CH29: Cummylperoxineodecanoate

(CH3-C-CH2-CH-CH2-C-0-)2

CH3

CH3

CH3 OCH-30E: di-3,5,5 -trimetyl hexanoyl peroxide

Chemicals formular structure of RM used in PVC resin production

MAIN PROPERTIES OF SOME MATERIALS

Material n Hydrolysis (%) Clouding point (oC)

AG-1 700 71 33.8

AG-2 2000 80 53.5

Material Molecular W (g/mol)

T1/2 at 1 hr. (oC)

Assay (%)

Active Oxygene

(%)

SADT (oC)

C-19 346.5 64 75 3.46 5

C-29 306.4 56 75 3.92 10

C-26 244.4 64 50 3.27 25

C-30 314.5 77 50 2.54 30


TPC

Materials Used For Reactor Of Each GradeNo Material SG580 SG660 SG710 REMARK

1 RCS x x x Anti fouling agent

2 PW x x x

3 VCM x x x

4 AG-1 x x x

5 AG-2 x x x

6 AG-5 x

7 AD-3 x x x

8 AD-5 x x x Use in Reactor & Recovery Tank

9 CH-20 x

10 C-19 x x

11 C-29 x x

12 C-26 x

13 C-30 x

COMBINATION SYSTEM OF INITIATORS

C-19C-29

C-19 + C29

Reaction time (hr.)

Rea

ctio

n ra

te Maximum heat removal capacity of Reactor

1. Utilize the heat removal capacity of the system

2. Shorten reaction time

VINATPC


TPC

Function of Material in TPC Vina processNo Material Function Original

stateUsed state

1 RCS Reactor coating to wall fouling removal

Solution 5.5%

Solution 5.5%

2 PW Make reaction environment Liquid Liquid

3 VCM Main ingredient of PVC Liquid Liquid

4 AG-1 Primary Suspension agent Solid 7% solution

5 AG-2 Suspension agent Solid 5.5% solution

6 AG-5 Suspension agent Solid 2% solution

7 AD-3 Chain break Solid 10.2% solution

8 AD-5 Heat stable and de-foam Emul. 50% Emul. 50%

9 C-19 Initiator Sol. 75% Sol. 75%

10 C-29 Initiator Sol. 75% Sol. 75%


TPC

No Material Function Original state

Used state

11 C-26 Initiator Emul. 50% Emul. 50%

12 C-30 Initiator Emul. 50% Emul. 50%

13 CH-20 Chain transfer agent Liquid Solution 13%

14 CH-9 Reduce freezing point of RW Liquid Solution 20%

15 CH-12 Methanol solvent Liquid 163 kg CH-12 + 20 kg INH-116 INH-1 Inhibiting self-reaction Solid

17 INH-3 Inhibiting reaction Liquid Liquid

18 CH-6 NaOH (make base environment)

Solid 2m3 PW + 250kg AD-3 +175kg CH-

6

19 CH-6 Dehydrate for RVCM Solid Solid

20 CH-25 Dehydrate & remove inhibitor Solid Solid

21 HA Neutralizing waste water Sol. 32% Sol. 32%

Function of Material in TPC Vina process


TPC

MECHANISM OF CHAIN TRANSFER IN SG580 PRODUCTION RO- CHCl – CH2

. + CH2 = CHCl -Q RO- CHCl – CH2 - CHCl – CH2.

RO- CHCl – CH2 - CHCl – CH2. + CH2 = CHCl + ........

(- CHCl – CH2 -)n-1- CHCl – CH2.

CHAIN TRANSFER: (- CHCl – CH2 -)n-1- CHCl – CH2

. + HO-CH2-CH2-SH

-(- CHCl – CH2 -)n-1- CHCl – CH3 +

CH3-CH-S.

CH3-CH-S. + CH2=CH-Cl CH3-CH-S-CH2-CH

.Cl

QUALITY SPECIFICATION

ITEM UNIT SG580 SG660 SG710

K-Value

Bulk Density

Volatile Matter

Sieve Analysis

- Retained on 250 micron

- Retained on 75 micron

g/ml

%

%

%

56 - 59 65 - 67 70 - 72

0.48 - 0.55 0.46 - 0.520.50 - 0.60

0.3 Max 0.3 Max 0.3 Max

2.0 Max 2.0 Max 2.0 Max

90.0 Min 90.0 Min 90.0 Min

VINATPC

Air

Distillation 25 trayD=0.75, H=8.6

Dehydrator (use 1/3)D=1.5, H=4.3 mKOH 38x35x18mm

Dehydrator (use 2/3)D=0.65, H=4.3 mNaOH 38x35x18mm

PW

Dryer

SiloB

SiloA

Slurrytank A

Strippingcolumn

Steam(LS)

VCM recovery by NASH compressor

Recoverytank

AG

OSBLVCM

Crude VCM tank

PolymerizerAD

Packing

VCM

Slurrytank B

LS

Decanter

VCM recovery by 800 section

ATM

Screen

PROCESS FLOW DIAGRAM

Cat.

KOH & NaOH supplier

Quadrimex-France

Tel: +33(0)490787085

Fax: +33(0)490787081

[email protected]

VINATPC

PVC Production Process Flow Diagram

Screen

PVC bag

Silo A

Silo B

Packing

VCM vessel

VCM Tank

A

VCM Tank

B

VCM Tank

C

VCM Daily Tank

• Water

• Suspending agent

• Additives

• Catalysts

A B

Reactor

Recovery Tank

Slurry Tank A

Slurry Tank B

Stripping Column

A

B

Decanter

Dryer

Sub materials

VCM Tank

D

VINATPC

CENTRAL CONTROL ROOM


TPC

TC1301ASP 58.30 oCPV 58.34 oCOP 33.1 %

PI1301A 8.83 KG/cm2

DW

AG1

AG2

AG5

GA1113A,B

DW

GA1111

FA1302A-1

GA1103A

GA1103B

GA1104

TO FA1303

DPW DPW

DPW

LS

TO FA1803

GA1306

M SGA1327GA1305

LS

T-cont start 56.3oC

10 ton DW GD start

M S

AF STEP & CHARGING

VINATPC

CHARGING PATTERN

5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100

PW

AD-5

AG-1

AG-2

AG-5

HPW

VCM

Catalyst

Heat Up

CH-20

Charging section

M S

LI1101

LI1102

LI1103

FA1102AAG-1

FA1102BAG-2

FA1103BAG-5

TC1101

FA1104BAD-5

FA1106ACH-20

FA1201PW

GA1101A

GA1101B

GA1102B

GA1103B

GA1113AB

M

M

FA1105VCM

GA1104

DC1301A HEAT UP GR01>GR205

CATCHARGING

CATCHARGING

TRENDGROUP035

TRENDGROUP035

TEMPCONT. ATEMP

CONT. A

TRENDGROUP036

TRENDGROUP036

CH-20 CHARGECH-20

CHARGE

TRENDGROUP037

TRENDGROUP037

AD3CHARGE

AD3CHARGE

TRENDGROUP038

TRENDGROUP038

TRENDGROUP039

TRENDGROUP039

TRENDGROUP040

TRENDGROUP040

TRENDGROUP041

TRENDGROUP041

TRENDGROUP042

TRENDGROUP042

FA1328A

FA1318ADW

GA1312A

GA1311A

GA1204A

GA1204B GA1305A

1322ALSLC

CW

CWR

CW

EI1301A 42.5 AMP

1325A1321A

FI1323A 1850 l/h FQ1323A 1398 L

FQ1324ASP 7699 LPV 0 L

CATFEEDCATFEED

CATWASHCATWASH

FC1324ASP 1593 l/hPV 0 l/hOP -5.0 %

TI1302A 58.0 oC

1323A

1324A

FA1303

(RVCM)

A INERTSP 10 MINPV 10 MIN

HW

TI1307A 34.4 oC

CWR

FC1316ASP 0 m3/hPV 0 m3/hOP -5.0 %PREAGI TM

SP 10 MINPV 0 MIN

FI1316A2 4.8 m3/h

FM1316A 0 m3/h

TI1306A 28.8 oC

TI1309A 31.6 oC

FI1315A 504.8 m3/h

94.7 %

TC1303ASP 70.0 oCPV 70.1 oCOP 25.0 %

A REAC TMSP 275 MINPV 0 MINA DEPRESSSP 135 MINPV 0 MIN

TI1308A 49.1 oC

DC1301A

TC1301ASP 58.30 oCPV 50.34 oCOP -5.0 %

PI1301A 7.83 KG

GA1113A

GA1113B

1109

1349 1399


l/h

GA1103A1310A

FQ1329ASP 134 LPV 133 L

l/h0.00

0.00

CH20

AD3

LI1108 1.065 M (11.588 m3)

LI1110 0.481 M (10.868 m3)

M S

0.0 %

BACK UPBACK UP

DC1301A POLY SECTION GR01>GR205

CATCHARGING

CATCHARGING

TRENDGROUP035

TRENDGROUP035

TEMPCONT. ATEMP

CONT. A

TRENDGROUP036

TRENDGROUP036

CH-20 CHARGECH-20

CHARGE

TRENDGROUP037

TRENDGROUP037

AD3CHARGE

AD3CHARGE

TRENDGROUP038

TRENDGROUP038

TRENDGROUP039

TRENDGROUP039

TRENDGROUP040

TRENDGROUP040

TRENDGROUP041

TRENDGROUP041

TRENDGROUP042

TRENDGROUP042

FA1328A

FA1318ADW

GA1312A

GA1311A

GA1204A

GA1204B GA1305A

1322ALSLC

CW

CWR

CW

EI1301A 42.5 AMP

1325A1321A

FI1323A 3371 l/h FQ1323A 10198 L

FQ1324ASP 7699 LPV 3702 L

CATFEEDCATFEED

CATWASHCATWASH

FC1324ASP 1593 l/hPV 1607 l/hOP 16.5 %

TI1302A 58.0 oC

1323A

1324A

FA1303

(RVCM)

A INERTSP 10 MINPV 10 MIN

HW

TI1307A 34.4 oC

CWR

FC1316ASP 472.8 m3/hPV 471.9 m3/hOP 61.2 %PREAGI TM

SP 10 MINPV 14 MIN

FI1316A2 4.8 m3/h

FM1316A 477 m3/h

TI1306A 28.8 oC

TI1309A 31.6 oC

FI1315A 254.8 m3/h

94.7 %

TC1303ASP 70.0 oCPV 29.1 oCOP -5.0 %

A REAC TMSP 275 MINPV 140 MINA DEPRESSSP 135 MINPV 0 MIN

TI1308A 49.1 oC

DC1301A

TC1301ASP 58.30 oCPV 58.34 oCOP 30.1 %

PI1301A 8.83 KG

GA1113A

GA1113B

1109

1349 1399


l/h

GA1103A1310A

FQ1329ASP 134 LPV 133 L

l/h0.00

0.00

CH20

AD3

LI1108 1.065 M (11.588 m3)

LI1110 0.481 M (10.868 m3)

M S

0.0 %

BACK UPBACK UP

REACTION PROFILE

Reaction time (hr.)

P,

T

x

End press.= 6.0 SG660

Reaction pressure

Reaction Temp.

Depress. Point = Preact. – 0.5

x

Heat up cut =

Treact. – 5

T-Cont start =

Treact. – 2

Grade SG580 SG660 SG710

Reaction temp. (oC) 66.3 58.3 51.7

Reaction press. (kg/cm2) 10.87 8.83 7.38

End press. (kg/cm2) 8.0 6.0 6.0

Conversion 84% 87% 82%

POLYA BPO MANAGEMENT PANEL GR01>GR0052

POLY

POLYINIA

POLY-A

4.0POLY-B

11.0

AFCOATCHGCHKADWFEEDCATALYSTHEATUPAPOLYADISCCHKASELFDISCPUMPDISCPLYREC FILWASH

BTMWASHLINEWASH

VCMTOAIRPOLYEND

NASH1REHEATRAD5FD2

RECOV

3.0RECODAT1RECODAT2

NASH2 RECOEQUZ TRSCHECK RECTRANS TRSRINS TRSWASH

PHINT3 PHINT4

HEATUPABTMPUMP

POLYDATAPHINT1

AD5FEEDTCONA

CATALYSTWPLANA

AD3FEEDPHINT1

PREHEAT

PHINT2

AG1FEED

INERTA

PHINT3

AG2FEED

CH20FDA

PHINT4

AG5FEED VCMFEED

PRERECOVRAD5FEED

READY

CATCHK

READY

6.0AIRTOVCMRDYEND3

3

33

41

3

33

3

3

3

4

3

5

5

5

55

55 5 55 5

3

3

3

3

33

3

3

3

3

3

3

3

3

3

3

3

3

4

3

3

3

3

3

3

3

3

1

3

1

1

RECOVERY TANK GR01>GR403

CATCHARGING

CATCHARGING

TRENDGROUP035

TRENDGROUP035

TEMPCONT. ATEMP

CONT. A

TRENDGROUP036

TRENDGROUP036

CH-20 CHARGECH-20

CHARGE

TRENDGROUP037

TRENDGROUP037

AD3CHARGE

AD3CHARGE

TRENDGROUP038

TRENDGROUP038

TRENDGROUP039

TRENDGROUP039

TRENDGROUP040

TRENDGROUP040

TRENDGROUP041

TRENDGROUP041

TRENDGROUP042

TRENDGROUP042

PW

GA1316

GA1314

GA1103C

GA1302

LS

EI1303 0.1 AMP

1326A

LI1109 0.633 M

FQ1322SP 0.0 LPV 0.0 L

LC1305SP 4.000 MPV 12.703 MOP – 5.0 %

1383

1381

DISCHARGING

SLURRYNASH2 W TMSP 0 MINPV 10 MIN

FA1304

PC1305SP – 0.55 KGPV – 0.50 KGOP – 5.0 % TI1310 53.1 oC

M S

1359

1387

1385

1327A

1375 1393

PI1503 8.51 KG

1386

1382

PC1305 40.0 %

1326B1327B

LI1308 4.90 M

LI1309 10.22 M

GA1307

WASH COUNT05

1384DW

1379

HALFHALF FULLFULL

1378

1380

LA1315

1397

1394 1398

LI1501A 4.99 M13961395

EI1305 0.0 AMP

PW

PW

FA1310

FA1501A

FA1501B GRADE

MVP66MVP66

FA1501A GRADE

MVP66MVP66

FA1304 GRADE

FA1803

FA1303

EQ

PW

LEQ

PWD P W

A D 5

LS

JF1302

PC1802SP 0.020 kg/cm2

PV 0.164 kg/cm2

OP 105.0 %

PC1404SP 4.800 kg/cm2

PV 3.919 kg/cm2

OP 120.0 %

PC1403SP 5.000 kg/cm2

PV 3.919 kg/cm2

OP 120.0 %

LC1302SP 0.200 MPV 10.191 MOP 1122.2 % PI1303 0.85 KG

MVP66MVP66

RECOVERY SECTION GR01>GR402

EQ LINE EQ LINE

TREND GROUP046 TREND GROUP046

400 SECTION 400 SECTION


RECOVERY TANK RECOVERY TANK


INHI-1 INJECT INHI-1 INJECT

EQ LINE EQ LINE

M S

M S

M S


DC1301A

DC1301B

FA1304

8.65kg/cm2

6.39kg/cm2

-0.27 kg/cm2

1382

1392A

1311A

1392B

1311B

LA1315

TI1310 53.1oC

PC1305 45.0%

LC1803SP 0.500MPV 0.878MOP 105.0%

EA1803GA1803

LC1302SP 0.200MPV 0.180MOP 15.4%

LC1401SP 0.300MPV 0.357MOP 95.2%

LC1402SP 0.200MPV 0.197MOP 42.7%

GA1303 GA1401 GA1402FA1303 FA1401 FA1402

EI1401 -0.4A

EI1401 -0.0A

GB1401 GB1402LLL

LLL

L

TC1401SP 45.0oCPV 40.2oCOP 65.0%

PI1303 -0.08 kg/cm2

PC1401SP 1.000kg/cm2

PV 1.299kg/cm2

OP 105.0%


PV 1.299kg/cm2

OP -5.0%

14031402

1401

1404

RVCM

PC1404SP 4.80kg/cm2

PV 4.58kg/cm2

OP 20.0%

PC1403SP 5.00kg/cm2

PV 4.58kg/cm2

OP 20.0%FA1403

SLURRY TRANSFER SECTION GR01>GR502

RECOVERYSECTION

RECOVERYSECTION

TRENDGROUP005

TRENDGROUP005

SLURRYFEEDSECSLURRYFEEDSEC

TRENDGROUP053

TRENDGROUP053

UNIT SUMMARY

UNIT SUMMARY

TRENDGROUP054

TRENDGROUP054

EQLINEEQ

LINE

TRENDGROUP055

TRENDGROUP055

TRENDGROUP056

TRENDGROUP056

GA1302

GA1502

1524

LS

SLURRY

FA1501A

LC1502SP 3.600 MPV 3.579 MOP 1147.0 %

WASHWASH

FC1502SP 111500 kg/hPV 111499 kg/hOP 55.0 %

TI1501A 54.5 oC

PW

DA CYCLESP 30 MINPV 27 MIN

PI1504– 0.329 KG

FA1501BDA1501

SLYANO

SLYANO

PC804SP -260.0 mmHgPV -261.5 mmHgOP 145.6 %

GA1501A

TI1502 36.8 oC

GB1801HALFHALF FULLFULL

1502

GA1501B

WASHWASH

FC1501SP 40.00 t/hPV 40.32 t/hOP 142.8 %

GRADEMVP66MVP66

PI1501A – 0.598 KG

LI1501A 1.11 M

LT1501A 24.3 m3

LEQ

1518A

1503

LI1308 14.35 M

FA1801

HALFHALF FULLFULL

1501

PI1501B 10.00 KG

LI1501B 1.02 M

LT1501B 22.6 m3

TC1501B SP 170.0 oC PV11 64.8 oC OP11– 5.0 %

TI1505 95.7 oC

TI1504 90.6 oC

TI1503 87.3 oC

TI1506 99.4 oC

CR

CW

PW

GRADE MVP66MVP66

EI1501A 21.20 AMP

EI1502 31.69 AMP

EI1501B 23.16 AMP

SLYBNO

SLYBNO

PI1503 7.91 KG

PWWASH CNT

0

PW1518B

LA1503

LA1506

1514

1515B

1516

1515A

1517TCV

1501B

LS

AIR

GB1505A

PW

FI1502 Nm3/h

1513

1432

107

FA1501B WASHSP 30 MINPV 0 MIN

DECANTER SECTION GR01>GR602

SLURRY FEEDSEC SLURRY FEEDSEC


RINSE WATERTNK RINSE WATERTNK


DRYER SECTION DRYER SECTION


EI1504A 185.7AMP

GF1501A

JF1501

1521A

PWGFFEED2

GFFEED1

FROM FA1501B

1520A

1507A

FC1506ASP 26.60t/hPV 26.69t/hOP 38.4%

TI1507 64.9oC

DI1506A 1.073g/cc

MC1506ASP 7.70t/hPV 7.72t/hOP 44.3%

DM1506A 28.9%

NN11 7.70 T/HNN13 5.80 T/H

MC1506A FEED2 SPMC1506A FEED2 SP

LC1305SP 4.000MPV 4.049MOP 24.3%

OIL UNITGA1504APA1507A

ZS1503A

FM1506 13.56t/h

WWDECA 29.85t/h

TI1311 60.7oC


PV 2.013kg/cm2

OP 38.4%

EI1504B 138.5AMP

GF1501B

JF1501

1521B

1520B

1507B

FC1506BSP 19.91t/hPV 19.96t/hOP 32.4%

DI1506B 1.074g/cc

MC1506BSP 5.80t/hPV 5.83t/hOP 49.8%

GA1504BPA1507B

ZS1503B

OIL UNIT

PW

PW PW

DM1506B 29.1%

TC1514SP 58.7oCPV 62.9oCOP 0.2%

FI1511323.8

TC1511SP 96.5oCPV 97.2oCOP 49.9%

TC1513SP 90.0oCPV 89.9oC OP 33.1%

m3/h

TI1515 63.9

TI1516 60.8

TI1517 57.8TI1518 41.8

oC

PDI1523 267.3mmH2O

PDI1521 490.7mmH2O

oC

oCoC

BM

PF

BED

TO FA1501B

Cake moisture: SG580: 18%

SG660: 22%; SG710: 25%

DRYER SECTION GR01>GR603

DRY TROUBLE

DRYER

GFFEED1GFFEED2SLURRYBDFEEDWASH

SILOAB

DATASAMPLING

DATASAMPLING

TRENDGROUP062

TRENDGROUP062

UNITSUMMARY

UNITSUMMARY

TRENDGROUP063

TRENDGROUP063

PFMOITURE

PFMOITURE

TRENDGROUP064

TRENDGROUP064

AIRCONDI.

AIRCONDI.

TRENDGROUP065

TRENDGROUP065

HWSECTION

HWSECTION

TRENDGROUP066

TRENDGROUP066

SCREENPNEUMASCREENPNEUMA

TRENDGROUP068

TRENDGROUP068

TRENDGROUP069

TRENDGROUP069

TRENDGROUP085

TRENDGROUP085

%RHEI150626.57AMP

TC1514SP 58.7 oCPV 62.9 oCOP 0.2 %

GA1503

LAMP OP TMSP 60 MINPV 40 MIN

mmH2O

PI1901

8.90KG

EI1507113.3 AMP

PI16010.912 KG

FA1502

JF1501

JF1503

JF1502

TI1515

63.9

TI1516

60.8

TI1517

57.8

TI1518

41.8(oC)

GB1502

GB1501

JF1505

LS

TI1512

91.1 oCFI1511323.8 m3/h

PDI1523267.3 mmH2O

PDI1525 – 27.5 mmH2O

GB1503

FA

`

FC1502

FC1501

JF1504

PI151699ATM

TI151962.3

MC1506ASP 7.70 t/hPV 7.85 t/hOP 43.8 % MC1506BSP 5.80 t/hPV 5.88 t/hOP 49.2 %

PC1511SP – 90.0 mmH2OPV 1– 89.0 mmH2OOP 65 %

TC1702SP 75.0 oCPV 74.7 oCOP 80.1 %

FC1512SP 310.0 Nm3/minPV 309.7 Nm3/minOP 76.2 %

FC1513SP 52.0 Nm3/minPV 52.1 Nm3/minOP 79.2 %

TC1511SP 96.5 oCPV 97.2 oCOP 49.9 %

AI1511

85.0

TI1500 30.3 oC

AC1502SP 0.200 %PV 0.218 %OP 139.1 %

AC1501SP 1.000 %PV 1.020 %OP 164.3 % TC1513

SP 90.0 oCPV 89.9 oCOP 33.1 %

FC1518SP 250.0 kg/hPV 110.0 kg/hOP 1130.0 %

HC1511

50.0SI1511

48.9

LI1501

A 6.0 M

B 5.1 M

`

1536

HC1701 – 5.0 %

EI1505126.3 AMP

BED FIN TMSP 30 MINPV 1 0 MIN

PDI1521490.7

mmH2O

HC1512

0.0

%%%

oC

HC1502

70.0%

XA1511

XA1512FD150

2

FF1501

DRYNOMVP66

GRADE

1533

FI1514BM

265.0Nm3/min

FI151444.63 Nm3/min

1532

SCREEN PNEUMA GR01>GR607

BED FIN TMSP 60 MINPV 40 MIN

OFFSPEC TMSP 60 MINPV 40 MIN

DRYERSECTION

TRENDGROUP067

SILOCHANGE

TRENDGROUP069

AIRCONDI.

TRENDGROUP084

DATA SETAIR

PI16010.912 kg/cm2

EI1601119.3 AMP

TO SILO A B

TI160130.2 oC

LS

FC1621SP 0.0 PV 0.0OP -5.0

kg/hkg/h%

LS

PVC

IA

AIR 1537A

1537B

1606 1607

1603 1604 1605

16021601

1610

FD1503XA1512

XA1511

LA1511

FLEXIBLEBAG

16231622 1621

1608 1609

1538

IA IA

IA

JF1601B

JF1601A

JF1601C

FC1516SP 0.0 PV 0.0OP -5.0

kg/hkg/h%

HC1601A65.0 %

TS1602

TS1603

GB1601

HV

LOCK

PA

STAR

FD1502PA SP 60 MINPV 40 MIN

PNEUMA FINSP 60 MINPV 40 MIN

HC150270.0 %

TI150030.3 oC

AI151185.3 %RH

FI1515107.3 Nm3/h

HV1531

FACTOR0.000CALC0.0

FD1502

` ``

LA1511

CW

SCREEN PNEUMA

FD1602EA1601

FE1501

SILO CHANGE GR01>GR608

DRYERSECTIONDRYER

SECTION

TRENDGROUP084

TRENDGROUP084

SCREENPNEUMASCREENPNEUMA

UNITSUMMARY

UNITSUMMARY

TS1602

FE9601A

GRADE

MVP66

9602A

FQ9601A 170.9 T

USEA

LA9603A

LA9601A

LA9602A

XC9601A

SILOA NO

GRADE

MVP66

9602B

FQ9601B 135.4 T

USEB

LA9603B

LA9601B

LA9602B

XC9601B

SILOB NO

` ``

135.4

1606

1601

1607

1602

JF1601A JF1601B JF1601CPI16010.912 kg/cm2

EI1601119.3

AMP

TI160130.2 oC

HC1601A

70.0 %

GB1601

SILOCHNG

TS1603

FD1502

SCREEN

FD1503

OFF SPEC

SCREEN

JFA JFB

H13N0812 H13N0813

ONEWAY

BATCH

SILO PURGESP 15 SECPV 1 0 SECSILO BATCHSP 300 MINPV 110 MIN

PNEUMA FINSP 11120 MINPV 10 MIN

9601

FE9601B

PACKING MACHINE


TPC

GB1302

FA1105

GA1205

PW

FA1803

FA1803

DW

GA1204A

GA1204B

FA1305

FA1309

GB1301

GA1306

GA1305

EA1303

1361

1362

1302

1315

13911392

13631333

1331

1320

1318

1321

1312

1303

1316

1314POLYMERIZER A / V SECTION

FA1703

Y

LS

DPW

GA1305

VG

1392 131113911315

1401

13221320

1318

1316

GA1204A

GA1204B

1321

POLYMERIZER V / A SECTION

FA1401 FA1402GA1401 GA1402

GB1401 GB1402

PC1401SP 1.000KGPV 1.050KG

LC1401SP 0.300MPV 0.357M

LC1402SP 0.200MPV 0.167M

PC1402SP 0.500KGPV 1.050KG

LC1302SP 0.200MPV 0.180M

EA1401 EA1402

INH-3 Section

1341A-11343A-1

1342A-1

1341A-21343A-2

1342A-2

FA1302A-1INH-3

FA1302A-2INH-3

NITROGEN40l x 6 x 23

Bar

NITROGEN40l x 150 Bar

NITROGEN40l x 6 x 23

Bar

DC1301A

TC1301ASP 58.30 oCPV 58.34 oCOP 30.1 %

PI1301A PV 8.83 KG

INH-3 Auto Charge condition:1. Power failure2. Reaction Flag ON (From Cat.

Feed to final press.)3. Pressure reach set value:

SG580: P = 12.0 barSG660: P = 10.0 barSG710: P = 9.0 bar92.5

kg

92.5kg

400 SECTION GR01>GR411

RAW MATMENU

RAW MATMENU

TRENDGROUP008

TRENDGROUP008

DWCHARGING

DWCHARGING

RINSEVALVE CK

RINSEVALVE CK

HWSECTION

HWSECTION

IW

FA1804 AD1411

FA1403

DA1401A

B C

DA1403 EA1407

EA1409A

FA1406

FA1409

FA1408FA1804

FA1405

GA1403A

GA1403BGA1405B

GA1405A

GA1406

1425

1426A 1426B 1426C1427 1410

1406

1411

IW

LS

CW

RW

FA1105

OSBL

VG

VG

EA1404

FI1408 1462 kg/h

TI1402 16.1 oC

PC1404SP 4.80 KGPV 4.10 KGOP 120.0 %

PC1403SP 5.00 KGPV 4.10 KGOP 120.0 %

LI1409 0.486 M

LI1410 0.156 M

LI1403 1.285 M

TI1404 29.8 oC

TI1408 38.8 oC

TI1409 43.8 oC

TI1412 29.2 oC

TI1413 31.53 oC

TI1410 36.2 oC

PI1405 – 0.39 KG

FC1404SP 1900 kg/hPV 1905 kg/hOP 1172.7 %

LMC1403SP 111.300 MPV 111.285 MOP 176.0 %

PC1409SP 1.00 KGPV 0.97 KGOP 0.0 % FC1409SP 0.000 m3/hPV 0.000 m3/hOP – 6.9 %

PC1406SP 5.00 KGPV 5.01 KGOP 163.7 %

FC1407SP 1500 kg/hPV 1503 kg/hOP 1135.6 %

PC1407SP 5.00 KGPV 5.01 KGOP 148.1 % LC1407

SP 0.500 MPV 0.501 MOP 50.0 %

FC1406SP 400.7 kg/hPV 399.9 kg/hOP 1132.7 %

LC1408SP 0.250 MPV 0.249 MOP 43.5 %

RESIDUERUN FL

DRAINPURGERUN FL

CUSHION TANK PANEL GR01>GR612

INH-1INJECTINH-1INJECT

TRENDGROUP071

TRENDGROUP071

EQLINEEQ

LINE

TRENDGROUP072

TRENDGROUP072

FA1403CRUDEVCM

FA1403CRUDEVCM

DA1801W/W

DA1801W/W

FA

FA

FA1501A

FA1304HALFHALF FULLFULL

DA1501 DA1801

FA1803

FA1801

FA1802

FA1804

RESIDUERECOVERYRESIDUE

RECOVERY

1524

LS

CW

1PC1804SP – 260.0 mmHgPV – 259.1 mmHgOP 153.3 %

1802

1801

1803

1PC1801SP – 0.700 KGPV – 0.590 KGOP 1 – 6.9 %

PC1802SP 0.020 KGPV 0.185 KGOP 1105.0 %

PC1403SP 5.00 KGPV 4.10 KGOP 120.0 %

TC1801 SP 45.0 oC PV 44.8 oC OP 135.3 %

LC1802SP 0.300 MPV 0.300 MOP 72.5 %

DA1801 LC1803SP 0.500 MPV 0.811 MOP 1105.0 %

LC1801SP 0.200 MPV 0.200 MOP 37.1 %

FI1801 16.70 m3/h

LI1804 0.608 M

PI1803 0.61 KG

AI1801 18.89 pH

AI1802 0.008 %

GA1801

GA1802EA1802 FA1803

1379

GB1801

GB1802

FA1804

CR

PROCESS FLOW BLOCK DIAGRAM


TPC

(AG, Cat, PW, AD)

POLYMERIZATION

VCM RECOVERY

DE-WATER

DRYING

SCREENING

BLOWING TO SILO

PACKING

PVC

OVERSIZE

VCM PURIFICATION

VCM

PVC RESIN

JETTY


TPC

VCM TANK YARDTPC VinaPlastic & Chemical Corp., Ltd.VINA

TPC

PRODUCTION AREA


TPC

WASTE WATER TREATMENT


TPC

THANK YOU!


TPC

Documents

Basic of PVC Resin Process