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    Barringer & Associates, Inc. 2007 1

    Corrosion Problems QuantifiedWith Gumbel Lower Distribution

    Paul Barringer, P.E.Barringer & Associates, Inc.P.O. Box 3985Humble, TX 77347-3985

    Phone: 281-852-6810

    FAX: 281-852-3749

    Email: [email protected]: http://www.barringer1.com

    Abstract: Several case studies show how to separate general corrosion from accelerated

    corrosion and how to predict end of useful life of products.

    Barringer & Associates, Inc. 2007 2

    Gumbel Upper or Gumbel Lower?

    The Gumbel upper distribution is used when

    you have BIG numbers. Its best know for

    flood data (you only record the deepest

    [largest] stream gage reading for a single year).

    The Gumbel lower distribution is used when

    you have LITTLE numbers. Its used whereyouve only recorded the thinnest [smallest]

    wall in a single corrosion area.The Gumbel Smallest Extreme Value is considered a model for a system having n elements in a series and

    where the failure distributions of components are reasonably uniform and similar (See British Standard BS 5760).

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    Barringer & Associates, Inc. 2007 3

    Whats The Math Difference?The Gumbel largest ex treme value CDF is: The Gumbel smallest extreme value CDF is:F t( ) e

    e

    t ( )

    F t( ) 1 e e

    t

    Rear anging the equations to read Rear anging the equations to read

    F t( ) e e

    t ( )

    1

    ee

    t ( )

    Or 1

    F t( )e

    e

    t ( )

    1 F t( ) e e

    t

    1

    ee

    t

    Or 1

    1 F t( ) e

    e

    t

    Taking t he l og of bot h s ides you ge t: Taking t he log of bot h s ides you ge t:

    ln 1

    F t( )

    e

    t ( )

    ln

    1

    1 F t( )

    e

    t

    Again, taking the log of both sides you get: Again, taking the log of both sides you get:

    ln ln 1

    F t( )

    t ( )

    t

    + ln ln

    1

    1 F t( )

    t

    t

    Y = mX + b Y = mX + b

    t ln ln 1

    F t( )

    t l n l n 1

    1 F t( )

    +

    For Monte Carlo modeling: For Monte Carlo modeling:

    t ln ln a_random_no( )( ) t ln ln 1 a_random_no( )( )+

    Both are alsoknown as the

    double

    exponential

    The Weibull distribution straight line equation

    l n l n 1

    1 F t( )

    ln t( ) l n( )

    is a scale factor is a shape factorSmall steeplines for G- & G+

    distributions

    Observations:

    Same Y-axis

    Weibull haslog X-axis

    Gumbel hasuniform

    X-axis

    Barringer & Associates, Inc. 2007 4

    Problem 1: Heat Exchanger Thin Tubes?

    We have a shell & tube heat exchanger

    Process fluids are inside the tubes and the

    tubes are loosing wall thickness with use

    Outside the tubes are cooling water

    Periodic inspections have recorded theminimum wall thickness in each tubeselected randomly. We have only one wall

    thickness for each tube inspected.

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    Barringer & Associates, Inc. 2007 5

    Whats The Issue? How To Resolve? Heat exchanger is 17 years old460 tubes

    At turnaround, eddy current wall thickness

    inspection occurredWere worried!

    Did an IRIS inspection on 10% of tubesNowwere more worriedwhat does the data say?

    Retube NOW at 17 years with T/A delays?Retube next turnaround in 3 years at 20 years?

    Retube at 2nd turnaround in 6 years at 23 years)?Time Issues

    Barringer & Associates, Inc. 2007 6

    What Are Cost Consequences?

    Failure $ is dependent on outside temperatures:

    Summer failure = $750,000 lost margins & retube

    Fall failure = $500,000 lost margins & retube

    Winter failure = $100,000 lost margins & retube

    Spring failure = $250,000 lost margins & retube

    Another key issue is environmental impact

    along with the cost issues if failure occurs

    Murphy says: Big Money Issues Will Prevail

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    Barringer & Associates, Inc. 2007 7

    Why Did They Inspect? Rule of thumb for this facility-

    Inspect tubes if wall thickness has been

    reduced by 1/3, i.e. from 0.083 to 0.055

    Consider retubing heat exchangers when tubewall thickness has been reduced to of

    original wall thickness, i.e. when wall thickness

    has been reduced from 0.083 to 0.0415

    This exchanger has environmental concerns

    Barringer & Associates, Inc. 2007 8

    Eddy Current vs IRIS Inspection

    Eddy current inspection is the usual quick

    and inexpensive inspection of each tube

    minimum wall is reported for each tube

    IRIS inspection is a more detailed and more

    expensive inspection with a rotating head

    ultrasonic toolminimum wall is reportedfor each tube and tube IDs must be veryclean for an accurate IRIS inspection.

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    Barringer & Associates, Inc. 2007 9

    What Did IRIS Inspection Find? The minimum wall thickness report shows:

    Minimum allowed wall thickness is 0.036for structural integrity.

    Wall*qty0.050*1 0.063*90.055*1 0.064*90.056*2 0.065*40.058*2 0.066*50.059*1 0.067*20.061*6 0.069*4

    Wall thickness

    measured

    in inches

    Rule of thumb triggers

    inspection at 0.050

    Barringer & Associates, Inc. 2007 10

    Stacks Of DataUse SherwinsInspection Option

    Wall Thickness Discovered At Inspection

    (low)ProbabilityOf

    Occurrence(

    high)

    Discovery

    Age/Thickness

    Failur

    eages

    Use top

    of stack for

    regression

    We have stacks of data from the heat exchanger inspection because

    the IRIS data have been rounded to three significant digits.

    Benign failure

    occurred here?

    Benign failure

    discovered here

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    Barringer & Associates, Inc. 2007 11

    Competing Models:

    Weibull? or Gumbel Distributions?

    Weibull Distribution

    with rank regression

    & inspection option

    Data stacks from

    course measurements

    use inspection optionfor regression

    R= Coefficient of regression

    ccc= critical correlation coefficient

    Small risk of wall thickness

    less than min allowed

    Barringer & Associates, Inc. 2007 12

    Competing Models:Weibull or Gumbel Distributions?

    Gumbel- Distribution

    with rank regression

    R2= (Coefficient of regression)2

    (ccc)2= (critical correlation coefficient)2Higher risk of wall thickness less than

    min allowed more conservative

    Bigger than for

    Weibull distribution

    use Gumble-

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    Barringer & Associates, Inc. 2007 13

    PDF Curves

    Note the Gumbel- distribution says to

    expect more occurrences with thinner wallsx

    ~2*x

    Barringer & Associates, Inc. 2007 14

    PDF Details

    0.04 0.060

    50

    100

    1

    e

    t

    e

    t ( )

    t t0( )

    1

    e

    t t0

    t

    Gumbel Lower PDF

    Weibull PDF

    0.04 0.050

    2

    4

    1

    e

    t

    e

    t

    t t0( )

    1

    e

    t t0

    t

    (0.050459, 3.933565)

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    Barringer & Associates, Inc. 2007 15

    The SMALLEST value is recorded for each

    tube thickness which motivates use of the

    Gumbel smallest distribution. Just as for

    flood data (the largest yearly value) motivates

    the use of the Gumbel largest distribution.

    The Gumbel smallest distribution is a better

    curve fit and shows greater % potentialfailure than Weibull, thus more conservative.

    Why Gumbel Lower Distribution?

    Barringer & Associates, Inc. 2007 16

    1

    5

    2

    10

    20

    30

    40

    5060

    7080

    9095

    99

    .03 .04 .05 .06 .07 .08 .09 .1 .11

    Heat Exchanger IRIS Inspection Data

    Tube Wall Thickness (inches)

    0.06427 0.00316 0.989 46/0

    Xi Del r^2 n/s

    G-/rr/insp1

    Year 17

    OccurrencesCDF%

    Area is 1% high

    by 0.01 wide

    note the

    magnification!

    Area is 1% high

    by 0.01 wide

    =0.06427

    Structuralminimumis0.036

    Parameters:

    Location

    Slope/Shape

    Considerretubeiflessthan0.0

    415

    Inspectiflessthan0.0

    55

    Small steep line slopeLarge flat line slope.

    Heres Where We Are At Year 17. Can We Make Year 20?

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    Barringer & Associates, Inc. 2007 17

    General Corrosion

    Wall Thickness

    Probabilityof

    Occurrence

    Start = datum

    General Deterioration

    Note Parallel Lines

    min

    t=3yrst=6t=9

    Low probability

    of thin wall below

    minimum!

    63.2%

    Dont exceed thisprobability of thin wall

    t=?This becomes acritical value!

    Barringer & Associates, Inc. 2007 18

    General Corrosion Trend Line

    Characteristic

    WallThickness,

    Time

    Critical Value, ,For Wall Thickness

    End of life!An easy decision.

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    Barringer & Associates, Inc. 2007 19

    Accelerated Corrosion

    Wall Thickness

    Probabilityof

    Occurrence

    start

    General Deterioration

    min

    Accelerated

    Deterioration

    Breaks The

    Min Wall

    Limits!

    !

    t=3t=6t=9

    Dont exceed this

    probability of thin wall

    You must know when toaccept the risk of failureand when to accept the

    risk of failure!

    $Risk = pof*$Consequence

    99.9%

    Barringer & Associates, Inc. 2007 20

    Accelerated Corrosion Trend Line

    Wall

    ThicknessAtA

    SpecifiedRisksay0.1%

    Time

    Minimum Wall Thickness At

    Acceptable Risk Level.

    End of life!Difficult decision.

    Wall loss from general corrosion

    Wall loss from accelerated corrosion

    Wall loss fromboth general + accelerated corrosion

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    Barringer & Associates, Inc. 2007 21

    .1

    .5

    .2

    1

    5

    2

    10

    20

    3040

    5060

    7080 90

    9599

    99.9

    .03 .04 .05 .06 .07 .08 .09 .1 .11

    Heat Exchanger IRIS Inspection Data

    Tube Wall Thickness (inches)

    0.09706 0.0020362

    0.06427 0.0031573 0.989 46/0

    = Xi = Del r^2 n/s

    G-/rr/insp1

    Year 17

    Year 0

    OccurrenceCDF%

    MinAllowedWall=0.036

    Year ??

    Assumes new tubewith tmin = 0.083

    and tmax = 0.101

    for ~6* = 99.8

    Typical Corrosion rate = (0.09706-0.06427)/17 = ~0.002/yr

    Note the flatter slope

    with larger meansmore wall thk. scatter!

    You Must Know Wall Thickness At Time Zero

    Barringer & Associates, Inc. 2007 22

    Wall Thickness @ 99.9%

    0.06496 @ 20 years

    0.101 @ 0 years

    0.07034 @ 17 years

    0.05956 @ 23 years

    Data needed for constructionof trendlines on next pagewith as new slopes.

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    Barringer & Associates, Inc. 2007 23

    .1

    .5

    .2

    1

    5

    2

    10

    20

    3040

    5060

    7080 90

    9599

    99.9

    .03 .04 .05 .06 .07 .08 .09 .1 .11

    Heat Exchanger Construction Lines

    Tube Wall Thickness (inches)

    G-/rr/insp1

    Year 17

    Year 0

    OccurrenceCDF%

    MinAllowedWall=0.036

    Year 20

    0.05237 0.083

    0.04246

    As New Slope

    Accelerated

    CorrosionEffects

    0.1010.070370.06496

    0.03531

    General Corrosion

    Year 20 Forecasted Line: = 0.05848, = 0.0033541 with 0.1228% occurrence at 0.036 wall.

    Year 23

    Barringer & Associates, Inc. 2007 24

    Wall Thickness at 0.1% Risk vs Time

    0.05237

    0.083

    0.04246

    17

    Y=0.083-0.0018017t

    Y=0.083-0.0023847t

    0.03531 @ 20 years

    0.02815 @ 23 years General + AccelerateCorrosion Rate

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    Barringer & Associates, Inc. 2007 25

    Retube Or Not Retube Now? At year 20 (next turnaround) the minimum

    wall thickness will decline to just under 0.036

    The risk for falling below 0.036 min wall is

    0.1228%

    $risk = (prob. of failure)*$Consequence, $risk exposure = 0.1228%*$750,000 = $921

    take the risk for running 3 more yearsDo not retube now. Run to TA at yr 20.

    Time & Money Issues Converge

    Barringer & Associates, Inc. 2007 26

    Tube Exchanger Summary

    Avoided the recently discovered and recently

    expected turnaround delay for accelerated delivery of

    heat exchanger ($750,000 expenditure avoided)

    based on use of one day analysis of data.

    Pressing on toward the next turnaround three years

    into the future

    At year 20, install a new tube bundle. Whats the risk for continuing to year 23?

    0.91%*$750,000 = $6,825if risk adverse, reject.

    If risk acceptingmaybe, but very doubtful.

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    Barringer & Associates, Inc. 2007 27

    Problem 2: Column Corrosion A column is rapidly loosing wall thickness.

    Fluids/gasses within the column are violent.

    Frequent Inspectionsdata is all over the map!

    Loss of containment will impact personnel and

    environment issues withbig $s

    What should we do:

    --Run?if so, for how long?--Shut down?if so, how to persuade themanagement team?

    Barringer & Associates, Inc. 2007 28

    Developed Outer Surface Of Tower

    Height

    Circumference

    Inspection

    Grid

    Over Bad

    Spots

    Data collection

    on the grid

    will contain both

    good walls and

    bad walls!

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    Barringer & Associates, Inc. 2007 29

    Raw Data UT Inspections

    Thin worry!

    Thick

    ignore!Rapid

    Deterioration

    In WallThickness

    Remaining Wall Thickness (Mils/10)

    Barringer & Associates, Inc. 2007 30

    Truncated DataThin Data Only

    Remaining Wall Thickness (Mils/10)

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    Barringer & Associates, Inc. 2007 31

    End Points For Corrosion Curve

    49

    51

    32.3

    33.09

    31.09

    25.17

    25.56

    25.17

    Gen + Accel Cor.

    @ 99.9%Days Thickness

    0 51

    906 33.09

    966 32.3

    1105 27.561127 27.17

    UT Wall Thickness Construction Lines

    Gen + Accel Cor.

    @ 0.1%

    Days Thickness

    0 49

    906 25.56966 23.61

    1105 19.26

    1127 19.53

    General Corros.@ 0.1%

    Days Thickness

    0 49

    906 31.09

    966 25.17

    1105 25.56

    1127 25.17

    Barringer & Associates, Inc. 2007 32

    End Of Life Clearly Shown

    Y=49.065-0.02128*X General Corrosion

    949

    General + Accelerated Corrosion

    1176

    1178

    1460

    End Of Life

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    Barringer & Associates, Inc. 2007 33

    Summary ASME minimum wall was violated at 949 days

    API fitness for service will be violated at 1176 daysand we are 1127 days into service

    Plan an immediate orderly shutdown for replacement

    Outage + planned replacement =$10,000,000

    Emergency outage + emergency replacement =$20,000,000 because of safety hazards

    Risk is too high! 0.1%*$10,000,000 = $10,000 andclimbing toward $20,000,000. Take action now!

    Barringer & Associates, Inc. 2007 34

    Now, For Grins

    Consider the Gumbel larger distribution

    Houston flood

    Aircraft gust loads

    Space shuttle rocket motor O-ring burnsDiscussions about the

    Gumbel lower distribution

    always raise questions

    about the Gumbel upper

    distribution

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    Barringer & Associates, Inc. 2007 35

    It Rained A Little

    On June 9, 200123 Inches!

    Cars are

    submerged

    on US 59

    highway!

    Barringer & Associates, Inc. 2007 36

    .1.5.2

    15

    2

    1020

    3040

    5060

    70

    80

    90

    95

    99

    99.9

    0 10 20 30 40 50 60 70 80

    Peak Annual Stream Flows-Gage Height (feet)

    USGS 08074000 Buffalo Bayou at Houston, Texas

    Peak Gage Height (feet)

    17.2 5.99 0.978 67/0

    Xi Del r^2 n/s

    G+/rr

    June9,2001

    OccurrenceCDF(%)

    F

    orecastedOneHundred

    Y

    earFloodGageHeight

    44.76

    Depth for 100 yr flood

    comes from the return

    period, RP = 1/(1-p).

    When RP = 100 years,

    then p = 99%

    The flood was bad but not the worst

    recorded near downtown Houston!

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    Barringer & Associates, Inc. 2007 37

    0

    1

    2

    3

    4

    5

    10 50

    Assumed Houston Flood Cost In June 2001

    Gage Height (feet)

    20 30 40

    AssumedFloodCostUS

    ($Billion)

    June9,2001

    100yearflood

    willbea2X

    $problem

    Flood Cost Estimates In June 2002

    Barringer & Associates, Inc. 2007 38

    Aircraft Positive Gust Loads

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    Barringer & Associates, Inc. 2007 39

    Space Shuttle Burned O-Rings

    Calculated Joint Temperature, oF45o 50o 55o 60o 65o 70o 75o 80o

    Numberof

    Incidents

    3

    2

    1

    0

    Field Joint

    STS 51-C

    41B

    61C

    41C

    61A

    41D

    STS-2

    Field Joint

    Calculated Joint Temperature, oF45o 50o 55o 60o 65o 70o 75o 80o

    Numberof

    Incidents

    3

    2

    1

    0

    STS 51-C

    41B

    61C

    41C

    61A

    41D

    STS-2

    Flightswith noincidents

    Source: Engineering Ethics, Gail D. Baura,

    Elsevier, ISBN 13:978-0-088531-2, 2006, Page 73.

    Data from the Rogers Commission 1986

    Data53*3

    57*158*1

    63*1

    70*2

    75*2

    Data

    53*3

    57*158*1

    63*1-66*1

    -67*3

    -68*1

    -69*1

    70*2-70*2

    -72*1

    -73*175*2

    -76*2

    -78*1

    -79*1-80*1

    -81*1

    FailuresOnly

    Failures

    And

    Successes

    Barringer & Associates, Inc. 2007 40

    Good Practice AdviceWatch Out!

    Gumbel upper & lower distributions allow the use

    of negative numbers on the X-axis

    When using suspensions (as a sign) make sure

    you turn on display of the suspensions (under

    magnifying glass) so you can view they are in the

    correct locations AND (under the Method icon)

    make sure to turn the negative sign to indicatesuspension!

    Else, youll get misleading results.

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    Barringer & Associates, Inc. 2007 41

    Which Plot?

    Poor curve fit

    Suspended data

    shown on plot as >

    Barringer & Associates, Inc. 2007 42

    Gumble Upper Slightly Better-ButNot Every Data Fits A Plot!

    ?

    Better but not good curve fit

    Failures were resolved by rocket joint/O-ring redesign

    Failures demonstrated to exist

    If you fail to turn on - is a suspensionyou will conclude this is a good fit!!

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    Barringer & Associates, Inc. 2007 43

    Gumbel Upper Summary Works well when you have the largest

    recorded data such as flood data, fatiguedata, etc.

    Watch for traps with suspensions when usedwithout good practices can result in badconclusions.

    If Weibull, Lognormal, etc. dont work thendont expect automatic success with all data

    by use of the Gumbel upper distribution.

    Barringer & Associates, Inc. 2007 44

    Want More Details? Got to http://www.barringer1.com/problem.htm Look at WinSMITH Weibull software (which also includes Gumbel large

    and small distributions)

    See biographies at http://www.barringer1.comof Dr. Weibull and Dr.Abernethy who is the worlds leading expert in Weibull analysis

    Dr. Weibull got many of his ideas on extreme values while working atBofors Steel in Swedenyou can see Bofors antiaircraft guns at theMuseum of the Pacific in Fredricksburg, TX.

    See Gumbel, E. J., Statistics of Extremes, Columbia University Press, NewYork, 1958

    See Statistical Theory of Extreme Values And Some PracticalApplications, A Series of Lectures, PB 175818, 12 Feb 1954 by Emil J.Gumbel, National Bureau of Standards, U.S. Dept of Commerce, NTIS

    See A New Method Of Analyzing Extreme-Value Data, NACATN 3053, Jan 1954, U.S. Dept of Commerce, NTIS, byJulius Lieblein National Bureau of Standards