Atomic Modifications and Doping of Metal Oxides for Commercially

Significant Partial Oxidation

J. Gleaves and G. Yablonski

Heterogeneous Kineticsand Particle Chemistry Laboratory

http://crelonweb.wustl.edu

Heterogeneous Selective Oxidation Programs

Heterogeneous Kinetics and Particle Chemistry Laboratory (HKPCL)Chemical Reaction Engineering Laboratory (CREL)Chemical Engineering Dept., Washington University, St. Louis, MO

CH4 + 1/2O2 CO + 2H2 Fuels, ChemicalsSupported metal

CH2 CHCOOHCH3CH2CH3 + 2O2 + 2H2O

propane acrylic acid

Metal oxide

CH2 CHCNCH3CH2CH3 + 2O2 + NH3 + 4H2O

propane acrylonitrile

Metal oxide

+ 1/2 O2 + H2OMetal oxideC2H5 CH CH2

ethylbenzene styrene

+ 1/2 O2

propene propene oxide

Metal oxideCH2 CHCH3 H2C CHCH3

O

TAP-2 - Atomic Deposition System

Deposition chamber

Mass spectrometer

TAP Reactor chamber

Diffusion pump