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Assured Flame Retardant Polyesters from

Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

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Page 1: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

AssuredFlameRetardantPolyestersfrom

Page 2: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

IntroductiontoRecron®FS

• NeedforSmarterTextiles

• IntroducingRecron®FS

• TrademarkService

• GlobalNetwork

• PathForward

Page 3: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

FireistheTopDestroyer

• Accountsfor>50%ofalldamagesandloss

• Hasclaimed>1.8bn Eurosinfinanciallossinlast5years

• Causesincludeappliancemalfunction,carelessbehaviour,

exposuretounidentifiedheatsource,openflameetc.

• Hencefirespreadanddamagecanbepreventedunlikeother

factorssuchasnaturalcalamities,planecrashesetc.

• Textilesformthemainflamepropagator;soweneedtoadd

flameretardantfunctionality tothem

Needforflame-retardanttextiles

Page 4: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

WhatisRecron®FS?

• Newbrandofflame-retardantpolyesterforglobal

homestextiles,upholsteryandinteriorsmarkets

• Backedbystrongchemistry

• RecentlylaunchedatMoOD 2017atBrussels,

Belgium

• 360*degreesupportintermsoftrademarkservice,

technicalsupportandmarketingsupport

• Extensivepromotionsintradefairs,magazines,

conferencesetc.

Best combinationofassuredfiresafetyandvalue-for-money

Page 5: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

HowisRecron®FSDifferent?

• Strongbrandbackedbythelargestintegratedpolyester

producerintheworld

• Superioringredientchemistry

• TrademarkservicetohelpassurevaluechainofFR

performance

• Dedicatedteamofmarketingpersonsandtechnical

specialistsacrosskeyFRmarketsglobally

• Strongdigitalstrategytoconnectkeyinfluencers(such

ashotels,contractors)withvaluechain(weavers)

• Exploringtie-upwithlabsgloballytofasttrackFRtesting

New-agefireprotection

Page 6: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

Recron®FS:TrademarkService

Page 7: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

OtherSupport

• Consistent,assuredqualitysupply

• Promotioninexposandtradeforums

• Passingonsalesleads

• Technicalsupportandguidancefromhighly

competenttechservicesteam

• Visibilityinmarketingcommunications

Value-addedservicesforbetterreturns

Page 8: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

PathForward:Collaboration• AggressivestrategytogrowinglobalFRmarkets

• Havetiedupwith15+channelpartnersacrossthe

world;addingmoreinEU,Turkey

• Incollaborationwithtrainedpeopleacross

Germany,Austria,Belgium,Turkey,Spain,Italywho

havebeenearmarkedtopromoteRecron®FS

• Willbeapproachingtheotherpartsofthevalue

chainandshowcasecollections

• Collaboratewithchannelpartnerstocreatemutual

value

Aggressivegrowthplans

Page 9: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

ThankYou!

Page 10: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

TechnicalPresentation

• FlameRetardantEffectofRecron®FS

• SuperiorityoverTopicalFinish

• CertificationsPassed

• ProductRange

Page 11: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

WhyRecron®FS?

• Bestamongtheclasswithpcontentof7500

ppmvspcontentof~6300ppminother

popularFRyarnsavailable

• LOI>35ispossiblesubjecttoallDuecareis

followed

• Bestwrt Tensilepropertiesintheclass,

estimatedimprovedstrengthby10%

• Bestwhitenesscomparedtocompetition

• WideProductrange:POY/Textured/Fancy/

Spun/ATY/Chenilleetc

Page 12: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

FlameRetardant Effect of Recron FS

• Fastflamepropagationisduetoradicalsin

theflame.

• Adequateamountofphosphorous

compoundcatchestheradicalsandthus

interruptthechainreactionandextinguish

theflame.

• Thisstopstheflameandthefabricmelts

awayfromtheignitionsource

Page 13: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

Topically Treated Fabrics

• Flameretardancycanalsobeachievedby

treatingfabricswithflameretardantchemicals.

• Chemicalsusedgenerally:Antimonyoxide,

chlorine-,bromine- otherphosphorous

containingorganicchemical,appliedonthefabric

surface

• Theflameretardantchemicalsaresubjectto

wearandtear.

• Nonuniformcoatingreducestheflame

retardancyofthefabric.

• Thefinishchemicalsareleachedintowater

leadingtowaterpollution

Page 14: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

Recron®FS:SuperiorityoverFRFinish

• Unlikefabricsthatreceiveasurfacetreatmentatalaterstage,Recron® FSofferslong-termsecurity.

• Demonstratedbelowwithexampleofradish(wherecolorpropertyislimitedtooutersurface)and

beetroot(wherecolourpropertyispresenteverywhere)

FRFinishPropertiesonlyonsurface

Recron®FSPropertiesthroughoutandpermanent

FRProperty

Page 15: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

Recron®FS(Inherent)vsFRFinish(Topical)

FRTopicalFinish

Performance Constantthroughoutfabriclife

Degradesoverusageandtime

FRComponentAddition Chemicalmodification Physicalprocess

FRChemicalPresence Uniformconcentrationthroughoutthepolymer

Non-Uniformconcentrationonsurfaceoffabric

FRProperties ConsistencyofFREffect ChancesofInconsistentFREffect

CostoverFabricLifeCycle Low:One-timecost High:Recurrentcosts

Page 16: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

Limitlessdesignoptions

Page 17: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

InternationalCertifications

Page 18: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

ProductRange

Recron®FSProducts Source

POY

130D/48F,72F POY Direct160D/48F,72F POY Direct260D/48F POY Direct

260D/72F,144F POY Direct520D/144F POY Direct500D/96F POY Direct

Textured

75D/48For72FIM FalseTwistText Direct75D/48F,72FTexLIM FalseTwistText Direct155D/144FSDTexLIM FalseTwistText Direct155D/48F,72FGFT FalseTwistText Direct155D/72F,144FHIM FalseTwistText Direct330D/96FTexLIM FalseTwistText Direct330D/96FTexHIM FalseTwistText Direct90DCTS- Fancy IrregularHighTwist Direct180DCTS- Fancy IrregularHighTwist Direct

FullyDrawnYarn(2step)75D/48F DrawWinder PartnerMills150D/48F DrawWinder PartnerMills300D/96F DrawWinder PartnerMills

Recron®FSProducts SourceAirTexturedYarns Plain170D- 2000D Plain PartnerMills

330D- 2000D Slub PartnerMills

Chenille

3.5Nm Chenille PartnerMills4.5Nm Chenille PartnerMills5Nm Chenille PartnerMills6Nm Chenille PartnerMills

PSF 1.5D AllCutlength Direct3.0D AllCutlength Direct

SpunYarn

1/8s SpunYarn PartnerMills1/10s SpunYarn PartnerMills1/20s SpunYarn PartnerMills1/30s SpunYarn PartnerMills1/40s SpunYarn PartnerMills2/8s SpunYarn PartnerMills2/10s SpunYarn PartnerMills2/20s SpunYarn PartnerMills2/30s SpunYarn PartnerMills2/40s SpunYarn PartnerMills

Page 19: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

ThankYou!

Page 20: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

Recron®FSDueCare

• GeneralGuidelines

• Dyeing

• Scouring

• Finishing

• ProductRange

Page 21: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

Recron®FS– GeneralGuidelines

Recron®FSis• Modifiedpolyesterwithin-builtinherentFR(FlameRetardent)properties• Softerinnature withbetterdyeuptake• ItissuggestedtotakeprecautionsindifferentstagestoensureFRefficacyisintactinthefinishedproduct*

• Allauxiliariesusedindownstreamprocessesshouldbethoroughlychecked,validatedandmustbeeasilywashablefromfinishedproduct.Thisistrueeveniftheauxiliariesthemselvespossessflameretardant(FR)characteristics.

• Processtobetobetriedfirstinlab,checkedforproductFRefficacy&thentobeusedinbulkprocesses

• Recron®FShastechnologicallysuperiorefficacy;wesuggestnottomixwithFRproductsfromothersuppliers.

*Allinformationsharedinthisdocumentareindicativeandtheseneedtobeadoptedbasedupontheactualhardware

Page 22: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

Recron®FSPOY&DTY

Recommendationfortexturing1. Lowerprimaryheatertemperatureby5– 10*Crecommended2. T2tensionwouldbehighercomparedtoregular3. Conningoilusedmustbeeasilywashableduringhotwash,mineraloils

arenotrecommended

RecommendationforTwisting1. LowerWindingtensionisadvisedforRecron®FS2. Useproperoilwhichiseasilywashable,maximum<1%onyarnforeasy

removalinafterprocesses3. Heatsettingtemperaturearound90oC.4. HighershrinkageinfeedyarnsneedssofterpackagesforDyeing

Page 23: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

Recron®FS:Dyeing

• Dyeingprocedureisgenerallysimilartoregularpolyester• Usestandarddispersedyestufffordyeing• Scouringprocessisimportanttoremoveexternalmaterial,needsextraattention.• SuggestmaxDyeingtemp125± 3°C(topreventhydrolyticdamages)• SiliconebasedDefoamers/Softenersetc.mustbeavoided• ReductionclearingespeciallyforMedium&DarkcolorsbyusingHydro/Sodaash• Additives,auxiliariesandlubricantsmustbecompletelyremovable• TentativeFRYarnpackagedensitycanbe0.35+/-0.04• CycletimeofIn-out3min&out-in5minisrecommended

Caution- NOTtouseCausticorOxalicacid- FinalProductmustbefreeofSiliconoranylubricant- CarriersMUSTnotbeused

Page 24: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

Recron®FSScouring

• Above information is based upon the effectiveness of Textile Auxiliaries (by Archoma). Similar productsfrom other suppliers may also be used.

• Depending upon the Textile construction and available machinery, technological adjustments may benecessary

Chemicals1 2 3 4

Scouring Hotwash Rinsing&Neutralisation ColdRinsing

ImerolXNI 1-2gpl

Dispersingagent 0.5-1.0gplSandozinMRN/HostapalMRNorequivalentnon-ionicdetergent 0.5-1gpl

SodaAsh 1gpl

AceticAcid(60%) 0.5gpl

Temperature 90oC 80oC 60oC/Ambient AmbientTime 20min 10min 15min 5min

Page 25: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

Dyeing:Diagram

• Tempgradientfrom50oCtill90oCis1.5oC/min• Tempgradientfrom90oCtill125oCis1oC/min• PostDyeing,hotblast(hightemp.drain)wouldbepreferredforFibre/Yarnonly

Page 26: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

Dyeing:TypicalRecipe

• Dispersedyestuffs••••

1- 2g/l0.5 g/l1- 2g/l

LeominORLevegalDLPSodiumAcetate

levellingagenttobehigherforlowerdepth.asdispersingagentaspHBuffertoadjustpHto4.51– 2g/lAceticacid

1. startdyeingat 50°C2. heat to90°C at 1.5°C/min3. heat from90 – 125°C at 1 °C/min4. dyefor 30 to45minutes5. DohightempdraintoavoidoligomerdepositiononFibre/yarn

Page 27: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

ReductionClearing

Treat for 20minutesat 80°C with:

• 4g/l• 3g/l• 0.5g/l• 0.3g/l

Sodaash(notwithcausticsoda)SodiumhydrosulphiteSandozinMRNLevegalDLP

1. Rinsetwiceat 80°C2. Neutralize for15minutes at 60°C withaceticacid toachievepH

of6-73. Rinseat 50°C

üDuringRC,pHtobemaintainedaround10.5üAfterrinsing,itissuggestedtoboilasmallsampleinDMwatertoconfirmallAlkalifromfabricareremoved.

Page 28: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

AfterTreatment:Finishing

• Toreducefrictiononthefiber/yarn,itisnecessarytoapplylubricantsafterthedyeingwhichdonotaffectFRefficacy

• Lubricantsandadditivesappliedmustbeeasilyremovable.

Treatfor20minutesat40°Cwith:• 2g/l LeominKP• 1g/l LeominOR

• Similarchemicalsfromotherbrandedvendorscanalsobeusedtogetthedesiredresults.

• Siliconbasedproductsmustbeavoidedatallstagesofwetprocessing.

Page 29: Assured Flame Retardant Polyesters from...Imerol XNI 1-2 gpl Dispersing agent 0.5-1.0 gpl Sandozin MRN / Hostapal MRN or equivalent non-ionic detergent 0.5-1 gpl Soda Ash 1 gpl Acetic

ThankYou!