ARSOIS^O - Records Collections · a a Sampl e No. Dilutio n Facto r % Molsttir o •3-I i'J y5 Ntf toi (/i (/ii ^) Locatio n COMPOUN D 2 o ^ ^ — o •i 1 1 O Z ± 4 Uiomophony

UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION III

CENTRAL REGIONAL LABORATORY839 BESTGATE ROAD

ANNAPOLIS, MARYLAND 21401(301) 266-9180

DATE : February 10, 1989

SUBJECT: Organic Data Validation for the Eastern Diversified Metals SiteCase 10699

FROM : Theresa A.Region III Acting ESAT DPO (3ES23)

TO : Suzanne BillingsRegional Project Manager (3HW12)

Thru: Pat Krantz "\iyChief, QA Section (3ES23)

Attached is the organic data review for the Eastern DiversifiedMetals Site (Case 10699) completed by the Region IIIEnvironmental Services Assistance Team (ESAT) contractor underthe direction of Region III ESD.

If you have questions.regarding this review, please call me.

Attachment

cc: Mark diFeliciantonio, COM (w/attachments)Elaine Spiewak (3HW10) (w/o attachments)

TID File: 03881210 Task #1438

-_i-;_=K-%~ .

ARSOISÔ

2568A RIVA ROADSUITE 300ANNAPOLIS, MD 21401PHONE: 301 -266-9887

MANAGERS Ns X DESIGNERS/CONSULTANTS

DATE: February 6, 1989

SUBJECT: Organic Data Validation for Case 10699Site: Eastern Diversified Metals

PROM: Sudabeh Rowshan-Kolar Albert T. EllisOrganic Data Reviewer Senior Organic Data Reviewer

TO: • Terry SimpsonActing ESAT Deputy Project Officer

THROUGH: Charles MatkovichcÊSAT Team Manager

Overview

Case 10699 consisted of five (5) soil samples and two (2) watersamples for volatile, semi-volatile, and pesticide/PCB analyses.Included in this case were one (1) equipment blank and one (1)trip blank. The trip blank was analyzed for volatile organicsonly. One sample was analyzed for pesticide/PCB compounds only.The samples were analyzed as a Contract Laboratory Program (CLP)Routine Analytical Service (RAS) .

\

Summary

All samples were successfully analyzed for all target compoundswith the exception of 2-butanone and 3-nitroaniline. Allinstrument and method sensitivities were according to theContract Laboratory Program (CLP) Routine Analytical Services(RAS) protocol.

Ma-jor Problem

o The response factors (RFs) for 2-butanone, and 3-nitroanilinewere less than 0.05 in the initial and/or continuingcalibrations. The quantitation limits for these compoundswere t|fiiified "R" for unreliable in the affected samples.

VI, VII and Table I in Appendix F) .

Minor Problems

o Several compounds failed precision criteria for continuingcalibrations. Positive results are qualified "J" anddetection limits are qualified "UJ" for the affected samples.(See Table I in Appendix F) . . « D o n i r • •An ou J 64 I

o The semi-volatile surrogates of samples CY753DL, "CY753MSDL,CY753MSDDL were outside the QC limits, due to dilution.

Page 2 of 3

The extractions of the semi-volatile fraction in samplesCY754 and CY760 were performed three (3) days in excess ofholding time. The extractions of the pesticide fraction insamples CY753 and CY767 were performed four (4) days inexcess of holding time. The quantitation limits for thesesamples were qualified "UL", and positive results arequalified "L".

The percent recovery of dibutylchlorendate was outside the QClimits in samples CY767, CY753MS, CY753MSD and CY753.This is due to the interference from samples matrix presentin these medium level soils. The surrogate recovery was alsooutside the QC limits for PBLKM.

Medium level sem-volatile extractions of samples CY753 andCY767 were performed. The data summary forms show dilutionfactors of 60 for these samples due to the medium levelextraction. These two samples were run at two differentdilutions, both dilutions were used in the data summary form.

Medium level pesticide extraction of samples CY753 and CY767were performed. The data summary form shows dilution factorsof 300 for CY753 and 150 for CY767, due to the medium levelextraction and dilution.

The dilution factor for the pesticide analysis of sampleCY767 was corrected during the data review. (See the SupportDocuments of Appendix F).

NOTES

The maximum concentrations of all compounds found in thetrip or method blanks are listed below. All samples withconcentrations of common laboratory contaminants less thanten times (<lOx) the blank level and uncommon laboratorycontaminants less than five times (<5x) the blank level havebeen qualified "B" on the data summary. (See also AppendixF). ^

_-*s?i? £*Z-

Concentration fug/Kg)

meQiylene chloride* 1 Jacetone* 2 J2-butanone* 3 J . . .* - common laboratory contaminants

The reported tentatively identified compounds (TIC) ofAppendix D have been reviewed and corrected during data

valiaation- flR30!6l42

Page 3 of 3

All data for Case 10699 were reviewed in accordance with theFunctional Guidelines for Evaluating Organic Analyses withModifications for Use Within Region III. The text of thisreport addresses only those problems affecting usability.

Attachments

1) Appendix A - Glossary of Data Qualifier Codes2) Appendix B - Data Summary. These include:

(a)' All positive results for target compounds withqualifier flags where applicable;

(b) All unusable detection limits (qualified "R").3) Appendix C - Results as Reported by the Laboratory for

all Target Compounds.4) Appendix D - Reviewed and Corrected Tentatively

Identified Compounds5) Appendix E - DPO Report for Contractual Compliance6) Appendix F - Support Documentation

RR3Q 16U3

Appendix A

Glossary of Data Qualifiers

_ -

AH30I6H

GlC£SA?.i CF DATA QUALIFIER CODES (ORGANIC) '

CODZS P.ZL--.TZD 'T'Q T'E'>i'?'~~~C.aTrc-N(csnfider.ee concerning presence cr absence of compounds) :

U = Net detected. The associated number indicatesapproximate '.sample concentration necessary to be

• • detected.

(NO CODE) = confirmed identification.

3 =" Net detected substantially above the level reported inlaboratory or field blanks.

?. = Unreliable rssult. Compound aay cr may net be presentin the sample. Supporting data necessary to confirarssult.

N = Tentative identification . Consider present. Specialr.sthcds r.av be needed to ccnfirn its ~resance cr absence

/-.— -» V^, •-^Ji'^ »^-%- V^-^Vs ^^.^—•^™ *

?! = Ic~Tcur.d tresent. Reported value cav be biased hich.Actual value is e:cpected to be lever.

L = Ccr.peund present. Reported value nay be biased lew.Actual value is expected to be higher.

UJ = Not detected, quantitation liait may be inaccurate crinprecise.

UL = No ;<| tected, quantitation limit is probably higher.

AR30l6li5

Appendix B

Data Summary Forms

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NARRATIVE

FOR CODE^fF

Appendix C

Results as Reported by the Laboratoryfor All Target Compounds

AR30I659

1A ' EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET

CY753Lab Name: LANCASTER LABS Contract: 68-W8-0055

Lab Code: LANCAS Case No.: 10699 SAS No.: SDG No.: CY753

Matrix: (soil/water) SOIL Lab Sample ID: A1323238L

Sample wt/vol: 5.0 (g/siL) G Lab File ID: A1323238L

Level: (low/med) LOW ' Date Received: 10/29/88

% Moisture: .not dec. 20 Date Analyzed: 11/01/88

Column: (pack/cap) PACK ' -Dilution Factor: 1.00

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/KG Q

74-87-3———————Chlorome thane_74-83-9———————Bromomethane__75-01-4———————Vinyl Chloride_75-00-3———————Chloroethane75-09-2————————Methylene Chloride67-64-1———————Acetone75-15-0———————Carbon Disulfide__75-35-4———————l,l-Dichloroethene_75-34-3———————1,1-Dichloroethane"540-59-0——————1,2-Dichloroethene (total)_67-66-3———————Chloroform107-06-2——————1,2-Dichloroethane_78-93-3———————2-3utanone71-55-6———————l,l,l-Trichloroethane_56-23-5———————Carbon Tetrachloride_^108-05-4——————Vinyl Acetate_75-27-4———————Bromodichloromethane__78-87-5———————1,2-Dichloropropane___10061-01-5—————cis-1, 3-Dichloropropene_79-01-6———————Trichloroethene124-48-1——————Dibromochloromethane_79-00-5———————1, l, 2-Trichloroethane_71-43-2———————Benzene10061-02-6-pp -trans-l/3-Dichloropropene_

108-10-1—- |i -4-Methyl-2-Pentanone591-78-6————"——2-Hexanone127-18-4——————Tetrachloroethene_________79-34-5———————1/1/2 / 2-Tetrachloroethane_108-88-3——————Toluene108-90-7——————Chlorobenzene_100-41-4——————Ethylbenzene_J100-42-5——————Styrene1330-20-7—————Xylene (total).

13131313740666666

1366

1366666666613136666666

UUUuBBUUUUUUUUUUUUUuuuuuu~uuu-uuuuuu

FORM I VOA ' AR30 1 6l&i)7 Rev.

: v - 21

j.o • SPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ' _______



: (soil/water) SOIL. Lab Sample ID: 1323238

Sample wt/vol: 1.0 (g/mL) G Lab File ID: >D1504

Level: (low/sied) MED Date Received: 10/29/88

% Moisture: not dec. 20 dec. Date Extracted: 11/03/88

Extraction: (Sepf/Cont/Sonc) SONG Date Analyzed: 11/05/88

GPC Cleanup: " (Y/N) N pH:7.0 Dilution Factor: 1.00000

CONCENTRATION UNITS:GAS NO. COMPOUND (ug/L or ug/Kg) UG/KG Q

108-95-2——————Phenol_______________111-44-4——————bis (2-Chloroethyl) ether95-57-8———————2-Chlorophenol541-73-1———————l,3-Dichlorobenzene_106-46-7———————l,4-Dichlorobenzene_100-51-6——————Benzyl alcohol____"95-50-1———————1,2-Dichlorobenzene95-48-7———————2-Methylphenol_108-60-1——————bis (2-Chloroisopropyl) ether106-44-5——————4-Methylphenol_621-64-7——————N-Nitroso-di-n-propylamine_67-72-1———————Hexachloroethane_____________98-95-3————————Nitrobenzene______________78-59-1———————Isophorone88-75-5————————2-Nitrophenol_____105-67-9——————2,4-Dimethylphenol_65-85-0———————Benzoic acid111-91-1——————bis (2-Chloroethoxy) methane120-83-2——————2/4-Dichlorophenol______"120-82-1——————1/2,4-Trichlorobenzene___91-20-3———————Naphthalene,106-47-8——————4-Chloroaniline87-68-3———s?TH59-50-7———. •~«-4-Chloro-3-methylphenol_91-57-6———#!Si*r-2-Methylnaphthalene_77-47-4———---•—Hexachlorocyclopentadiene__88-06-2———————2/4,6-Trichlorophenol_____:95-95-4———————2 / 4,5-Trichlorophenol_____91-58-7———————2-Chloronaphthalene_______88-74-4———————2-Nitroaniline___________131-11-3——————Dimethylphthalate_208-96-8——•———Acenaphthylene_606-20-2——————2,6-Dinitrotoluene

2400024000240002400024000240002400024000240002400024000240002400024000240002400013000024000240002400024000240002400024000240002400024000130000240001300002400024000

UUUuuuuuuuuuuuuuuuuuuuuuuuuuuuuu

61FORM I SV-1 1/87 Rev.

-A 203

1C • EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ________



Matrix: (soil/water) SOIL Lab Sample ID: 1323238

Sample vt/vol: i.o . (g/mL) G Lab File ID: >D1504

Level: (low/med) MED Date Received: 10/29/88



GPC Cleanup: (Y/N) N pH:7.0 Dilution Factor: 1.00000


99-09-2———————3-Nitroaniline_83-32-9———————Acenaphthene_51-28-5———————2,4-Dinitronhenol100-02-7——————4-Nitrophenol___"132-64-9——————Dibenzofuran121-14-2——————2,4-Dinitrotoluene84-66-2———————Diethylphthalate_7005-72-3—————4-Chlorophenyl-phenylether_86-73—7———————Fluorene100-01-6——————4-Nitroaniline__________534-52-1——————4, 6-Dinitro-2-riethylphenol_86-30-6———————N-Nitrosodiphenylamine (1)~101-55-3——————4-Bromophenyl-phenylether_118-74-1——————Kexachlorobenzene_______87-86-5———————Pentachlorophenol_______85-01-8———————Phenanthrene___________12 0-12-7——————Anthracene84-74-2———————Di-n-butylphthalate_206-44-0——————Fluoranthene_____~129-00-0——————Pyrene_85-68-7———————Butylbenzylphthalate91-94-1——- rj-Mr- 3/3'-Dichlorobenzidine_56-55-3—r lf lS—Benzo (a) anthracene_218-01-9— f-Chrysene117-81-7—-S.-sSS.-bis (2-Ethylhexyl) phthalate117-84-0——————Di-n-octylphthalate_____"205-99-2——————Benzo (b) f luoranthene_____207-08-9—•————Benzo (3c)'f luoranthene_____50-32-8———————Benzo (a) pyrene_193-39-5——————Indeno (1 / 2 / 3 -cd) pyrene_53-70-3———————Dibenz (a/h) anthracene191-24-2——————Benzo (g,h,i)perylene_____

130000240001300001300002400024000240002400024000130000130000240002400024000130000240002400024000240002400024000500002400024000

32000003600002400024000240002400024000

uuuuuuuuuuuuuuuuuuuuuuuuE

uuuuu

(1) - Cannot be separated from Diphenylamine

FORM I SV-2 1/87 Rev.

204

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

CY753DLLab Name: LANCASTER LABS Contract: 68-W8-0055


ix: (soil/water) SOIL Lab Sample ID: 1323238

Sample wt/vol: 1.0 (g/mL) G Lab File ID: >E3950




GPC Cleanup: " '(Y/N) N pH:7.0 Dilution Factor: 100.0000


108-95-2——————Phenol_______________111-44-4——————bis (2-Chloroethyl) ether95-57-8———————2-ChloroDhenol541-73-1——————1, 3-Dichlorobenzene_106-46-7——————l,4-Dichlorobenzene_100-51-6——————Benzyl alcohol_95-50-1———————1,2-Dichlorobenzene95-48-7———————2-Methylphenol_108-60-1——————bis (2-Chloroisopropyl) ether_106-44-5——————4-Methylphenol621-64-7——————N-Nitroso-di-n-propylamine_67-72-1———————Hexachloroethane______________98-95-3————————Nitrobenzene__________________78-59-1———————Isoohorone88-75-5———————2-Nitrophenol____105-67-9——————2,4-Dimethylphenol_65-85-0———————Benzoic acid111-91-1——————bis (2-Chloroethoxy) methane_________120-83-2——————2,4-Dichlorophenol120-82-1——————1,2,4-Trichlorobenzene91-20-3———————Naphthalene,106-47-8 —————— 4-Chloroaniline ___________87-68-3 —— --=?? — Hexachlorobutadiene _______59-50-7 —— >£*£*• — 4-Chlorp-3-znethylphenol91-57-6 — w?? — 2-Methylnaphthalene77-47-4——i~~---—Hexachlorocyclopentadiene_88-06-2———————2 / 4 , 6-Trichlorophenol95-95-4 ———————2,4,5-Trichlorophenol___91-58-7———————2-Chloronaphthalene_________88-74-4———'———2-Nitroaniline ___131-11-3——————Dimethylphthalate_208-96-8——————Acenaphthylene_606-20-2—————2,6-Dinitrotoluene_

2400000240000024000002400000240000024000002400000240000024000002400000240000024000002400000240000024000002400000130000002400000240000024000002400000240000024000002400000240000024000002400000130000002400000130000002400000240000024000ft<R 3 3? 6 6

Uuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuu


- 240

-«- . ->*A SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _______










99-09-2———————3-Nitroaniline_83-32-9———————Acenaphthene_51-28-5————————2 , 4-Dinitrophenol100-02-7——————4-Nitrophenol___~132-64-9———————Dibenzofuran121-14-2——————2,4-Dinitrotoluene84-66-2———————Diethylphthalate_7005-72-3—————4-Chlorophenyl-phenylether_86-73-7———————Fluorene100-01-6——————4-Nitroaniline________________534-52-1——————4,6-Dinitro-2-aethylphenol_86-30-6———————N-Nitrosodiphenylainine (1)_101-55-3——————4-Bromophenyl-phenylether_118-74-1——————Kexachlorobensene________87-86-5———————Pentachlorophenol___________85-01-8———————Phenanthrene___________________120-12-7——————Anthracene84-74-2———————Di-n-butylphthalate_206-44-0——————Fluoranthene______129-00-0 ——————Pyr ene_85-68-7———————Butylbenzylphthalate__91-94-1———————3,3'-Dichlorobenzidine_56-55-3—- - r-——Benzo (a) anthracene______218-01-9- r .r——Chrysene• . -*s—•*1i'*Bv.ii ™ ••—— bis(2-Ethylhexyl)phthalate117-8 4 - 0--: - —— Di-n-octy Iphthal ate205-99-2 —————— Benzo (b) f luoranthene _207-08-9 —————— Benzo (k) f luoranthene50-32-8 ——————— Benzo (a) pyrene_193 -3 9-5——————Indeno (1/2,3 -cd) pyrene_53-70-3———————Dibenz (a,h) anthracene___191-24-2——————Benzo (g,h,i)perylene_

130000002400000130000001300000024000002400000240000024000002400000130000001300000024000002400000240000013000000240000024000002400000240000024000002400000500000024000002400000440000027000024000002400000240000024000002400000240

UUUUUUUUUuuuuuuuuuuuuuuu

DJ DUUUuuJJ6 64

(1) - Cannot be separated from Diphenylamina


24

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET _________



atrix: (soil/water) SOIL Lab Sample ID: 1323238DF10

Sample wt/vol: 1.0 (g/mL) G Lab File ID: A88316 027.RES



Extraction: (Sepf/Cont/Sonc) SONG. Date Analyzed: 11/12/88

GPC Cleanup: " (Y/N) N pH:7.0 Dilution Factor: 10.0

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/KGV Q

1 T Q O f SZ

IT Q Q Q _ Q

76-44-8 ——309-00-2 —1024-57-3-

60-57-1 ——72-55-9 ——*7T> — OA..O— ._— .

33213-65-972-54-8 ——1031-07-8-

72-43-5 ———53494-70-55103-71-9-5103-74-2-8001-35-2-12674-11-211104-28-211141-16-553469-21-912672-29-6

———— alpha-BHC

————— delta-BHC———— gamma-BHC (Lindane)————— Heptachlor———— Aldrin————— Heptachlor epoxide————— Endosulfan I———— Dieldrin___ — 4 A/_nnp^ / *t LJLJ*-*

—— •—— Endrin .———— Endosulfan II

^ / T U LJ luf

---—— Endosulfan sulfate*x / *4 LJU J.

———— Methoxychlor———— Endrin Jcetone————— alpha-Chlordane———— cjamma-Chlordane———— Toxaphene———— Aroclor-1016— ——— Aroclor-1221-* i?«--Aroclor-12 3 2*-**~r- Aroclor-12 4 2is ssi-j — Aroclor-12 4 8

11097-69-1 ———— Aroclor-125411096-82-5———— Aroclor-12 60

1500.1500.7500.1500.7500.7500.2500.1500.3000.3000.3000.3000.3000.3000.520.

15000.3000.15000.15000.30000.140000.75000.140000'.93000.140000.30000.30000.

UUUYUUYUYUZUUUUuuuJU 'uuuuuxuxux.cuxuu

FORM I PEST AR30 j &8$? Rev-

> 625

: 1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET ________



Matrix: (soil/water) SOIL Lab Sample ID: A1323241LR

Sample wt/vol: 5.0 (g/mL) G Lab File ID: A1323241LR

Level: (low/aed) LOW : Date Received: 10/29/88

% Moisture: not dec. 21 Date Analyzed: 11/02/88

Column: (pack/cap) PACK Dilution Factor: 1.00


74-87-3———————Chloromethane_74-83-9————————Bromomethane75-01-4———————Vinyl Chloride____75-00-3———————Chloroethane_____75-09-2———————Methylene Chloride67-64-1———————Acetone_________~75-15-0———————Carbon Disulfide__75-35-4———————1,1-Dichloroethene75-34-3———————l,l-Dichloroethane~540-59-0——————1,2-Dichloroethene (total).67-66-3———————Chloroform107-06-2——————1,2-Dichloroethane__78-93-3————————2-3utanone__________71-55-6———————1,1,1-Trichloroethane.56-23-5———————Carbon Tetrachloride_^108-05-4——————Vinyl Acetate,75-27-4———————Bromodichloromethane78-87-5———————1,2-Dichloropropane______10061-01-5————cis-1,3-Dichloropropene_79-01-6———————Trichloroethene_____124-48-1——————Dibromochloromethane_79-00-5———————1,1,2-Trichloroethane.'71-43-2——*—MT:—Benzene

-02—6-^^-5—trans-l,3-Dichloropropene_____75-25-2——/ fts —Bromoform108-10-1—--'----4-Methyl-2»Pentanone_591-78-6——————2-Hexanone__________127-18-4——————Tetrachloroethene79-34-5———————1/1/2,2-Tetrachloroethane_108-88-3——————Toluene108-90-7——————Chlorobenzene100-41-4——————Ethylbenzene__]100-42-5—————Styrene1330-20-7—————Xylene (total).

1313131337666666

13661366666666613136676

UUUuBJJUuuuuuuuuuuuuuuuuuuuuuuuu

Ai3(W66(if.

FORM I VOA 1/87 Rev

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET



ix: (soil/water) SOIL Lab Sample ID: 1323241


Level: (low/med) LOW Date Received: 10/29/88



GPC Cleanup: ' (Y/N) Y pH:4.5 Dilution Factor: 1.00000


108-95-2——————Phenol________________________111-44-4——————bis (2-Chloroethyl) ether95-57-8———————2-Chlorophenol541-73-1——————l,3-Dichlorobenzene_106-46-7——————1,4-Dichlorobenzene100-51-6——————Benzyl alcohol____~95-50-1———————1,2-Dichlorobenzene95-48-7———————2-Methylphenol_108-60-1——————bis (2-Chloroisopropyl) ether__106-44-5——————4-Methylphenol____________621-64-7——————N-Nitroso-di-n-propylamine_67-72-1———————Kexachloroethane______98-95-3———————Nitrobenzene_____________78-59-1———————IsoDhorone88-75-5———————2-Nitrophenol____105-67-9——————2,4-Dimethylphenol_65-85-0———————Benzoic acid111-91-1——————bis (2-Chloroethoxy) methane_____120-83-2——————2,4-Dichlorophenol120-82-1——————1/2/4-Trichlorobenzene91-20-3———————Naphthalene,106-47-8——————4-Chloroaniline_________87-68-3———--r-T^-Hexachlorobutadiene59-50-7 ——— -4-Chloro-3-methylphenol_9 1-57-6 ——— "? f-2 -Methylnaphthal ene_77-47-4————-—-Hexachlorocyclopentadiene_88-06-2———————2,4 / 6-Trichlorophenol95-95-4———————2 / 4,5-Trichlorophenol______91-58-7———————2-Chloronaphthalene__________88-74-4———————2-Nitroaniline______________131-11-3——————Dimethylphthalate_208-96-8——————Acenaphthylene_606-20-2——————2,6-Dinitrotoluene_

840840840840840840840840840840840840840840840840420084084084084084084084084084084042008404200840840840 U

UUuuuuuuuuuuuuuuuuuuuuuuuuuuuuuu

——mretrrw?FORM I SV-1 1/87 Rev.

249

1C . EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _________


Lab Code: LANCAS Case No.: 10699 SAS No.: ' SDG No.: CY753



Level: (low/iaed) LOW ' Date Received: 10/29/88



GPC Cleanup: (Y/N) Y pH:4.5 Dilution Factor: 1.00000

CONCENTRATION UNITS:CAS NO. • COMPOUND (ug/L or ug/Kg) UG/KG ' Q

99-09-2———————3-Nitroaniline_83-32-9———————Acenaphthene_51-28-5————————2 , 4-Dinitrophenol100-02-7———————4-Nitrophenol___~132-64-9———————Dibenzofuran121-14-2——————2,4-Dinitrotoluene84-66-2———————Diethylphthalate.7005-72-3—————4-Chlorophenyl-phenylether_86-73-7———————Fluorene100-01-6——————4-Nitroaniline__________________534-52-1——————4, 6-Dinitro-2-methylphenol_86-30-6———————N-Nitrosodiphenylamine (1)_101-55-3——————4-Bromophenyl-phenylether_118-74-1——————Hexachlorobenzene_______87-86-5———————Pentachlorophenol_______85-01-8———————Phenanthrene________________________120-12-7——————Anthracene84-74-2———————Di-n-butylphthalate_206-4 4-0——————Fluoranthene______~129-00-0——————Pyrene_85-68-7———————Butylbenzylphthalate91-94-1————'---3,3 '-Dichlorobenzidine_56-55-3——®£*4—Benzo (a) anthracene"218-01-9—117-81-7——:S**s*-b!s (2-Ethylhexyl) phthalate117-84-0——————Di-n-octylphthalate_______205-99-2——————Benzo (b) f luoranthene________207-08-9——————Benzo (k) f luoranthene__________50-32-8———————Benzo (a) pyrene193-39-5——————Indeno(1,2, 3-cd) pyrene_53-70-3———————Dibenz(a,hjanthracene___191-24-2——————Benzo (g,h/i)perylene_

42008404200420084084084084084042004200840840840.42008408408408408408401700840840840840840840840840840840-mo-

uUUUUUUUUUUUuuuU 'uuuuuuuuuuuuuuuub b cr(1) - Cannot be separated from Diphenylamine


25(

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET __________


«b Code: LANCAS Case No.: 10699 SAS No.: SDG No.: CY753

trix: (soil/water) SOIL Lab Sample ID: 1323241

Sample wt/vol: 30 (g/mL) G Lab File ID: A88323 026.RES






•i i o oe._o___ ___

76-44-8 ———————309-00-2 ——————1024-57-3 —————

60-57-1 ———————72-55-9 ———————TO — OH — Q— . — — ___-._

33213-65-9 ————72-54-8 ———————1031-07-8 —————50-29-3 ———————72-43-5 ———————53494-70-5 ————

5103-74-2 —————8001-35-2 —————^ +* t_ *~t A T -1 "^12674— 11— 2——— — —11104-28-2 ————11141-16-5- r-r53469-21-9- -p-12672-29-6-S-11097-69-1 —— • —

-alpha-BHC-beta-BHC-delta-BHC-gamsia-BHC (Lindane)-Heotachlor-Aldrin-Heptachlor epoxide-Endosulfan I-Dieldrin

i *t *JLJEt-Endrin-Endosulfan II—&. 4.'— nnn*± f *T LJLJLJ

-Endosulfan sulfate— A. &.'— niVP*r / *t LJU ±

-Methoxychl or-Endrin ketone-alpha-Chlordane-gamma-Chlordane-Toxaphene-Aroclor-1016-Aroclor-1221-Aroclor-1232-Aroclor-12 4 2-Aroclor-12 4 8-Aroclor-1254-Aroclor-12 60

20.51.51.51.20.20.10.10.20.20.20.20.20.20.20.100.20.100.100.200.200.200.200.200.200.200.200.

UXUYUYUYUXUXUUUuuuuuuuuuuuuxuxuxuxuxuu

FORM I PEST AR30i/66$ev.

65

1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET ________



Matrix: (soil/water) SOIL Lab Sample ID: A1323242LR

Sample wt/vol: 5.0 (g/mL) G Lab File ID: A1323242LR

Level: (low/med) LOW ' - Date Received: 10/29/88

% Moisture: not dec. 22 Date Analyz'ed: 11/02/88

Column: (pack/cap) PACK ' Dilution Factor: 1.00


74-87-3———————Chloromethane_74-83-9————————Bromomethane__75-01-4———————Vinyl Chloride,75-00-3————————Chloroethane75-09-2———————Methylene Chloride_________67-64-1———————Acetone___________________________75-15-0———————Carbon Disulfide________75-35-4———————1,1-Dichloroethene____________75-34-3———————1,1-Dichloroethane______540-59-0——————1,2-Dichloroethene (total).67-66-3———————Chloroform107-06-2——————l/2-Dichloroethane__78-93-3———————2-3utanone_________71-55-6———————l/l/l-Trichloroethane_56-23-5———————Carbon Tetrachloride_108-05-4——————Vinyl Acetate_75-27-4———————Bromodichloromethane_78-87-5———————l,2-Dichloropropane_10061-01-5————cis-l,3-Dichloropropene_79-01-6———————Trichloroethene______"124-48-1——————Dibromochloromethane_______79-00-5———————1,1,2-Trichloroethane_____71-4 3 -2 ———---rrBenzene10061-02-6—gr? -trans-1..3-Dichloropropene_____75-25-2108-10-1——--™4-Methyl-2-Pentanone_591-78-6——————2-Hexanone127-18-4——————Tetrachloroethene79-34-5——————l/l,2/2-Tetrachloroethane_108-88-3——————Toluene_______________"108-90-7——————Chlorobenzene_____________100-41-4——————Ethylbenzene_____________________100-42-5——————Styrene1330-20-7—————Xylene (total).

131313132S666666136613666666

, 666131366566

A* 3

uuuuBJJUuuuuuuuuuuuuuuuuuuuuuuJuuu67

FORM I VOA 1/87 Rev

IB ' EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ________


Code: LANCAS Case No.: 10699 SAS No.: SDG No.: CY753


Sample wt/vol: 30.0 (g/nL) G Lab File ID: >E3656

Level: (low/med) LOW . Date Received: 10/29/88



GPC Cleanup: (Y/N) Y pH:4,0 ' Dilution Factor: 1.00000


108-95-2——————Phenol_____________111-44-4——————bis (2-Chloroethyl) ether95-57-8———————2-ChloroDhenol541-73-1——————l,3-Dichlcrobenzene_106-46-7——————1,4-Dichlorobenzene"100-51-6———————Benzyl alcohol_95-50-1———————1,2-Dichlorobenzene95-48-7———————2-Methylphenol.108-60-1——————bis (2-Chloroisopropyl) ether106-44-5——————4-Methylphenol__________~621-64 -7——————N-Nitroso-di-n-propylamine_67-72-1———————Hexachloroethane_________98-95-3———————Nitrobenzene__________________78-59-1———————Isophorone_88-75-5———————2-Nitrophenol____105-67-9——————2, 4-Dimethylphenol_65-85-0———————Benzoic acid111-91-1——————bis (2-Chloroethoxy) methane120-83-2——————2,4-Dichlorophenol_________~_120-82-1——————112,4-Trichlorobenzene_____91-20-3 ———————Naphthalene,106-47-8——---->- 4-Chloroaniline87-68-3——•-*-** --Hexachlorobutadiene59-50-7———*f»«-4-C91-57-6———i-TJ.'. 2-Methylnaphthalene_77-47-4———————Hexachlorocyclopentadiene_88-06-2———————2 , 4,6-Trichlorophenol95-95-4———————2,4,5-Trichlorophenol___91-58-7———————2-Chloronaphthalene__________88-74-4———————2-Nitroaniline________131-11-3——————Dimethylphthalate__208-96-8—————•—Acenaphthylene________606-20-2——————2,6-Dinitrotoluene_

860860860860860860860860860860860860860860860860430086086086086086086086086086086043008604300860860860

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FORM I SV-1 AR30.IW-.Rev.

• - 277

1C EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET __________

Lab Name: LANCASTER LABS Contract: 68-W8-0055CY760








CONCENTRATION UNITS:CAS NO. ' COMPOUND (ug/L or ug/Kg) UG/KG Q

99-09-2———————3-Nitroaniline_83-32-9———————Acenaohthene51-28-5———————2,4-Dinitrophenol100-02-7——————4-Nitrophenol___"

J-64-9——————Dibenzofuran121-14-2——————2,4-Dinitrotoluene84-66-2———————Diethylphthalate7005-72-3—————4-Chlorophenyl-phenylether_86-73-7———————Fluorene100-01-6——————4-Nitroaniline__________534-52-1——————4, 6-Dinitro-2-methyIphenol.86-30-6———————N-Nitrosodiphenylamine (1) ~101-55-3——————4-Bromophenyl-phenylether__118-74-1——————Hexachlorobenzene_______87-86-5———————Pentachlorophenol________85-01-8———————Phenanthrene__________________120-12-7——————Anthracene __84-74-2———————Di-n-butylphthalate_2 0 6-4 4 - 0 ——————Fluoranthene_____~129-00-0——————Pyrene_85-68-7——~jr-—Butylbenzylphthalate_91-94-1——r Sg—3,3'-Dichlorobenzidine_56-55-3—H y gS—Benzo (a) anthracene218-01-9—;*-s-*&5—Chrysene_117-81-7——————bis (2-Ethylhexyl) phthalate_

-Di-n-octylphthalate__205-99-2——————Benzo (b) f luoranthene_

r-08-9——————Benzo (k) f luoranthene"50-32-8———————Benzo(a)pyrene__193-39-5——————Indeno (1,2,3-cd) pyrene_53-70-3———————Dibenz (a, h) anthracene191-24-2——————Benzo (g,h, i) perylene_


430086043004300860860860860860430043008608608604300860860860860860•3601700860860860860860860860860

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FORM I SV-2 1/87 Rev.278

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET _____________


!ab Code: LANCAS Case No.: 10699 SAS No.: SDG No.: CY753


Sample wt/vol: 30 (g/aL) G Lab File ID: A88323 022.RES






319-84-6———————alpha-BHC_________319-85-7———————beta-SHC__________319-86-8———————delta-3HC_________58-89-9———————camma-3HC (Lindane)76-44-8———————Heptachlor________\309-00-2——————Aldrin1024-57-3—————Heptachlor epoxide_959-98-8——————Endosulfan I_____"60-57-1———————Dieldrin________72-55-9—————————4 , 4 ' -DDE__________72-20-8———————Endrin33213-65-9—————Endosulfan II72-54-8————————4 ,4 '-ODD____"1031-07-8—————Endosulfan sulfate.50-29-3————————4,4'-DDT_72-43-5———————Methoxychlor53494-70-5————Endrin ketone__5103-71-9—————alpha-Chlordane_5103-74-2—————gamma-Chlordane"8001-35-2—————Toxaphene_12674-11-2- - —Aroclor-101611104-28-2—-*4:—Aroclor-122l"

-16-5 ™-Aroclor-12 3 253469-21-9-———Aroclor-1242"12672-29-6—————Aroclor-1248~11097-69-1—————Aroclor-1254"11096-82-5—————Aroclor-1260"

10,10,10,10,10.10.10.10.21,21.21.21.21.21.21.

100.21.

100.100,210.100,100,100,100,100,210,210.

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FORM I PEST ArVOO 1 6^7 Rev.

663

1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET __________



Matrix: (soil/water) WATER Lab Sample ID: A1323243W

Sample wt/vol: 5.0 (g/aL) ML Lab File ID: A1323243W


% Moisture: not dec. Date Analyzed: 11/02/88


CONCENTRATION UNITS:GAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

74-87-3———————Chloromethane__74-83-9———————Bromomethane_75-01-4——————Vinyl Chloride,75-00-3———————Chloroethane75-09-2———————Methylene Chloride67-64-1———————Acetone_________~75-15-0————————Carbon Disulfide_____75-35-4———————l,l-Dichloroethene_75-34-3———————1, l-Dichloroethane~540-59-0——————1, 2-Dichloroethene (total)67-66-3———————Chloroform107-06-2——————1,2-Dichloroethane___73-93-3———————2-3utanone__________71-55-6———————1,1,1-Trichloroe thane_56-23-5———————Carbon Tetrachloride_^108-05-4——————Vinyl Acetate_______75-27-4———————Bromodichloromethane_78-87-5———————1,2-Dichloropropane_10061-01-5————cis-1,3-Dichloropropene_79-01-6———————Trichloroethene______~124-48-1——————Dibromochloromethane_____79-00-5———————1,1,2-Trichloroethane__71-43-2———————Benzene

75-25-2—— -S» S3— Broaofona— trans-l,3-Dichloropropene_

108-10-1—**«ft* -4 -Methyl-2 -Pentanone_591-78-6——---•--2-Hexanone127-18-4——————Tetrachloroethene79-34 -5———————1,1,2,2 -Tetrachl or oethane_108-88-3——————Toluene108-90-7——————Chlorobenzene100-41-4 ——————Ethylbenzene_J100-42-5——————styrene_1330-20-7—————Xylene (total).

1010101051055555510551055555555510105555555

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FORM I VOA • AR30

58

IB • EPA SAMPLE NO.SZMIVOLATILE ORGANICS ANALYSIS DATA SHEET __________



Matrix: (soil/water) WATER Lab Sample ID: 1323243

Sample wt/vol: 1000 ( (g/aL) ML Lab File ID: >D1401


% Moisture: not dec. dec. Date Extracted: 11/01/88

Extraction: (Sepf/Cont/Sonc) SEPF Date Analyzed: 11/01/88


CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

108-95-2——————Phenol_______________111-44-4——————bis (2-Chloroethyl) ether95-57-8———————2-Chlorophenol541-73-1———————l,3-Dichlorobenzene_106-46-7———————1, 4-Dichlorobensene100-51-6——————Benzyl alcohol.95-50-1———————1,2-Dichlorobenzene95-48-7———————2-Methylphenol,108-60-1——————bis (2-Chloroisopropyl) ether_106-44-5——————4-Methylphenol______________621-64-7——————N-Nitroso-di-n-propylamine_67-72-1————————Hexachloroethane___________98-95-3————————Nitrobenzene______________78-59-1———————Isophorone88-75-5———————2-Nitrophenol____105-67-9——————2,4-Dimethylphenol_65-85-0———————Benzoic acid111-91-1——————bis (2-Chloroethoxy) methane_120-83-2——————2,4-Dichlorophenol______~120-82-1—————1/2,4-Trichlorobenzene______91-20-3 ——————Naphthalene106-47-8——---;--4-Chloroaniline___87-68-3——.-•-T-?—Hexachlorobutadiene59-50-7———l-f -4-Chloro-3-methylphenol91-57-6———•———2-Methylnaphthalene77-47-4———————Hexachlorocyclopentadiene_88-06-2———————2,4,6-Trichlorophenol___95-95-4———————2,4,5-Trichlorophenol91-58-7———————2-Chloronaphthalene_________88-74-4———————2-Nitroaniline_______________131-11-3—————Dimethylphthalate.208-96-8———•—-Acenaphthylene_606-20-2——————2,6-Dinitrotoluene_

10101010101010101010101010101010501010101010101010101050105010

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FORM I SV-1 . 1/87 Rev.

30





Sample wt/vol: 1000 ( (g/mL) ML Lab File ID: >D1401

Level: .(low/med) LOW . Date Received: 10/29/88

% Moisture: not dec. dec. . Date Extracted: 11/01/88

Extraction: (Sepf/Cont/Sonc) SEPF Date Analyzed: 11/01/88 .



99-09-2———————3-Nitroaniline_83-32-9———————Acenaphthene51-28-5———————2,4-Dinitrophenol100-02-7——————4-Nitrophenol___"132-64-9——————Dibenzofuran121-14-2——————2,4-Dinitrotoluene84-66-2———————Diethylphthalate,7005-72-3—————4-Chlorophenyl-phenylether_86-73-7————————Fluorene100-01-6——————4-Nitroaniline534-52-1——————4 , 6-Dinitro-2-methyIphenol_86-30-6———————N-Nitrosodiphenylamine (1)_101-55-3——————4-3romophenyl-phenylether_____118-74-1——————Hexachlorobenzene_______________87-86-5———————Pentachlorophenol_________85-01-8———————Phenanthrene________________120-12-7——————Anthracene84-7 4-2———————Di-n-butylphthal ate_206-44-0——————Fluoranthene_____~129-00-0——————Pyrene_85-68-7 ——————— Butylbenzylphthalate91-94-1 ——— ?-sR-3 , 3 '-Dichlorobenzidine_

"56-55-3— —— *%"£f -Benzo (a) anthracene218-01-9——~§~£-' _ _________________117-81-7—-~~-bis (2-Ethylhexyl) phthalate_117-84-0——————Di-n-octylphthalate_______.205-99-2—————•—Benzo (b) f luoranthene______•207-08-9——————Benzo (k) f luoranthene___________50-32-8———————Benzo (a) pyrene.193-39-5——————Indeno(1,2,3-cd) pyrene_53-70-3———————Dibenz (a,h) anthracene__191-24-2——————Benzo(g,h,i)perylene_

(JL) - Cannot be separated from Diphenylamine

501050501010101010505010101050101010101010•2010101010101010101010

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Ifa/bFORM I SV-2 1/87 Rev.

303

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET ______________



fRtrix: (soil/water) WATER Lab Sample ID: 1323243

Sample wt/vol: 1000 (g/aL) ML Lab File ID: A88305 022.RES

Level: (low/aed) LOW Date Received: 10/29/88:





•» i Q_Q/I_£;___•31 Q_Q=T_"7___

76-44-8 ———

1024-57-3 —

60-57-1 ———72-55-9 ———"7*7_*7n_S____

33213-65-9-"7 *5 C A D _

1031-07-8 —50-29-3 ———

53494-70-5-5103-71-9 —5103-74-2 —8001-35-2 —12674-11-2-11104-28-2-11141-16-5-53469-21-9-12672-29-6-11097-69-1-iine/;_0«5 _•_J..LUy t>— oZ — O

——— alpha-3HC———— beta-3HC •

———— gamma-3HC (Lindane)———— He_tachlor———— Aldrin———— Heptachlor epoxide———— Endosulfan I———— Dieldrin

~T / *± U LJ Lj

_____ Endrin——— Endosulfan II

^ , ~l LJLSkJ

——— Endosulfan sulfate, H 1/J X

———— Methoxychlor———— Endrin ketone———— alpha-Chlordane———— gamma-Chlordane———— Toxaphene———— Aroclor-1016——— Aroclor-12 21-;-**-Aroclor-1232--.-i-Arocior-1242--• -Aroclor-1248——— Aroclor-12 54——— Aroclor-12 60

.05

.05

.05

.05

.05

.05

.05

.05

.1

.1

.1

.1

.1

.1

.1

.5

.1

.5

.51..5.5;s.5.51.1. .......

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FORM I PEST AR30

1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET _____________




Sample wt/vol: 5.0 (g/mL) ML Lab File ID: A1323246W





74-87-3———————Chloromethane_74-83-9———————Bromoaethane__75-01-4———————Vinyl Chloride75-00-3———————Chloroethane75-09-2———————Methylene Chloride67-64-1———————Acetone_________"75-15-0———————Carbon Disulfide__75-35-4———————1,1-Dichloroethene75-34-3———————1,1-Dichloroethane"540-59-0——————1,2-Dichloroethene (total)_67-66-3———————Chloroform_________________________107-06-2——————1,2-Dichloroethane________78-93-3———————2-3utanone_________71-55-6———————l,l,l-Trichloroethane_56-23-5———————Carbon Tetrachloride___108-05-4——————Vinyl Acetate_______75-27-4———————Bromodichlorome thane_78-87-5———————l,2-Dichloropropane_10061-01-5————cis-l,3-Dichloropropene_79-01-6———————Trichloroethene__________~_124-48-1——————Dibromochl or ome thane______79-00-5———————1,1,2-Trichloroethane__71-43-2———-t^z-—Benzene10061-02-6* * '—trans-1,3-Dichloropropene__75-25-2——«»Hissi—Bromoform108-10-1——-----4-Methyl-2-Pentanone_591-78-6——————2-Hexanone127-18-4——————Tetrachloroethene79-34-5———————1,1,2,2-Tetrachloroethane_108-88-3——————Toluene108-90-7——————Chlorobenzene_100-41-4——————Ethylbenzene__100-42-5——————Styrene_1330-20-7—————Xylene (total).

1010101051055555510551055555555510105555-5

Aff30

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P678FORM I VOA 1/87 Rev.

1A ' EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET ______


ib Code: LANCAS Case No.: 10699 SAS No.: SDG No.: CY753

fatrix: (soil/water) SOIL Lab Sample ID: A1313247L

Sample wt/vol: 5.0 (g/aL) G Lab File ID: A1323247L





74-87-3———————Chloromethane______74-83-9———————Bromomethane_____75-01-4———————Vinyl Chloride_____75-00-3———————Chloroethane_____75-09-2———————Methylene Chloride67-64-1————————Acetone___________75-15-0————————Carbon Bisulfide75-35-4———————1,1-Dichloroethene______________75-34-3———————1,1-Dichloroethane________540-59-0——————1,2-Dichloroethene (total)_67-66-3———————Chloroform107-06-2——————1,2-Dichloroethane____78-93-3——;————2-3utanone__________71-55-6———————1,1,1-Trichloroethane__56-23-5———————Carbon Tetrachloride_____108-05-4——————Vinyl Acetate____________75-27-4———————Bromodichloromethane___78-87-5———————1,2-Dichloropropane______10061-01-5————cis-l,3-Dichloropropene_79-01-6———————Trichloroethene______~124-48-1——————Dibromochloromethane_____79-00-5———————1,1,2-Trichloroethane__71-43-2—————•—Benzene10061-02-6—:----trans-l,3-Dichloropropene_75-25-2—•———:r-Broaoform____________~108-10-1—--T.rS—4-Methy 1-2-Pent anone_591-78-6————--2-Hexanone________"127-18-4——————Tetrachloroethene79-34-5———————l,l,2,2-Tetrachloroethane_108-88-3———————Toluene108-90-7——————Chlorobenzene_100-41-4——————Ethylbenzene_100-42-5——————Styrene_1330-20-7—————Xylene (total).

11111111466666661166116666666

• 6611116 .6666

ARS30

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P679FORM I VOA 1/87 Rev.

•• . '72

IB • EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _________




Sample wt/vol: 1.0 (g/aL) G Lab File ID: >D1505i •

Level: (low/med) MZD • Date Received: 10/29/88


Extraction:- (Sepf/Cont/Sonc) SONG Date Analyzed: 11/05/88



108-95-2——————Phenol________________________111-44-4——————bis (2-Chloroethyl) ether95-57-8———————2-Chlorophenol541-73-1——————l,3-Dichlorobenzene_106-4 6-7——————1,4 -Dichlorcbenzene_100-51-6——————Benzyl alcohol_______95-50-1———————1,2-Dichlorobenzene95-48-7———————2-Methy Iphenol,108-60-1——————bis (2-Chloroisopropyl) ether__106-44-5——————4-Methylphenol_____________621-64-7——————N-Nitroso-di-n-propylamine_67-72-1———————Hexachloroethane________________98-95-3———————Nitrobenzene___________________78-59-1———————Isophorone88-75-5———————2-Nitrophenol____105-67-9——————2,4-Dimethylphenol_65-85-0———————Benzoic acid111-91-1——————bis (2-Chloroethoxy) methane120-83-2——————2,4-Dichlorophenol120-82-1——————1,2,4-Trichlorobenzene91-20-3———————Naphthalene^106-47-8——rr -4-Chloroaniline87-68-3———e*=*-Hexachlorobutadiene59-50-7————*f*>>-4-Chloro-3-aethy Iphenol91-57-6——————2-Methylnaphthalene77-47-4———————Hexachlorocyclopentadiene_88-06-2———————2,4,6-Trichlorophenol95-95-4———————2,4,5-Trichlorophenol___91-58-7———————2-Chloronaphthalene_______88-74-4———————2-Nitroaniline131-11-3——————Dimethylphthalate_208-96-8-——————Acenaphthylene_606-20-2——————2,6-Dinitrotoluene_

230002300023000230002300023000230002300023000230002300023000230002300023000 .230001100002300023000230002300023000230002300023000230002300011000023000110000230002300023000

Afi

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313

1C EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _________



Matrix: (soil/water) SOIL ' Lab Sample ID: 1323247

Sample wt/vol: 1.0 (g/aL) G Lab File ID: >D1505

Level: (low/med) MED . . Date Received: 10/29/88 ••


Extraction: (Sepf/Cont/Sonc) SONG Date Analyzed: 11/05/88 '



99-09-2———————3-Nitroaniline_83-32-9————————Acenaphthene_51-28-5———————2, 4-Dinitrophenol100-02-7——————4-Nitrophenol____132-64-9——————Dibenzofuran121-14-2——————2,4-Dinitrotoluene84-66-2———————Diethylphthalate_7005-72-3—————4-Chlorophenyl-phenylether_8 6-73-7———————Fluorene__________;____~100-01-6——————4-Nitroaniline534-52-1——————4, 6-Dinitro-2-methylphenol_8 6-3 0-6———————N-Nitrosodiphenylamine (1) ~101-55-3——————4-Bromophenyl-phenylether__118-74-1——————Hexachlorobenzene__________87-86-5———————Pentachlorophenol_______85-01-8———————Phenanthrene_________•120-12-7——————Anthracene84-74-2———————Di-n-butylph thai ate.206-44-0——————Fluoranthene_____"129-00-0——————Pyrene_85-68-7———————Butylbenzylphthalate91-94-1————-~3,3 '-Dichlorobenzidine,56-55-3————•—--Benzo (a) anthracene_____218-01-9——~~- Chrysene_117-81-7——————bis (2-Ethylhexyl) phthalate117-84-0——————Di-n-octylphthalate_____'_205-99-2——————Benzo (b) f luoranthene_____207-08-9——————Benzo (k) f luoranthene_______50-32-8———————Benzo(a)pyrene_193-39-5—————-Indeno(1,2,3-cd) pyrene_53-70-3———————Dibenz (a, h) anthracene___191-24-2——————Benzo (g,h,i)perylene__

110000230001100001100002300023000230002300023000110000110000230002300023000110000• 2300023000230002300023000230.00460002300023000

210000030000023000

: 23000230002323(23000

3(

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tr.(JL4) - Cannot be separated from Diphenylamine


314

IB EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ________

CY767DLLab Naae: LANCASTER LABS Contract: 63-W8-0055


Matrix: (soil/water) SOIL Lab Saaple ID: 1323247

Sample wt/vol: 1.0 (g/aL) G Lab File ID: >E3902 . . . . .

Level: (low/med) MED Date Received: 10/29/88' * . • * '

% Moisture: not dec. 13 . dec. " Date Extracted: 11/03/88




108-95-2——————Phenol___________________111-44-4——————bis (2-Chloroethyl) ether95-57-8————————2-Chlorophenol541-73-1——————l,3-Dichlorobenzene_106-46-7——————l,4-Dichlorobenzene_100-51-6——————Benzyl alcohol____~95-50-1-——————1,2-Dichlorobenzene95-48-7———————2-Methylphenol108-60-1——————bis (2-Chloroisopropyl) ether_106-44-5——————4-Methylphenol621-64-7——————N-Nitroso-.di-n-propylamine_67-72-1———————Hexachloroethane_______________98-95-3———————Nitrobenzene_____________________78-59-1———————Isophorone.88-75-5———————2-Nitrophenol______105-67-9——————2,4-Dimethylphenol_65-85-0———————Benzoic acid111-91-1——————bis (2-Chloroethoxy) methane_120-83-2——————2,4-Dichlorophenol120-82-1——————1,2,4-Trichlorobenzene91-20-3————-——Naphthalene^106-47-8——*—•£*— 4-Chloroaniline87-68-3—*---.iSi—Hexachlorobutadiene59-50-7——-.~-i-.-. 4 -chloro-3 -methylphenol91-57-6———————2-Methylnaphthalene77-47-4———————Hexachlorocyclopentadiene88-06-2———•————2,4,6-Trichlorophenol_____95-95-4———————2,4,5-Trichlorophenol______91-58-7———————2-Chloronaphthalene____________88-74-4———————2-Nitroaniline131-11-3——————Diaethylphthalate.208-96-8—————Acenaphthylene_606-20-2——————2,6-Dinitrotoluene

3400003400003400003400003400003400003400003400003400003400003400003400003400003400003400003400001700000340000340000340000340.00034000034000034000034000034000034000017000003400001700000340000

340000

UUuuuuuuuuuuuuuuuuuuuuuuuuuuuu


340

: 1C EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ________




Sample wt/vol: 1.0 (g/aL) G Lab File ID: >E3902

Level: (low/aed) MED • Date Received: 10/29/88 •





99-09-2———————3-Nitroaniline_83-32-9———————Acenaphthene,51-28-5———————2,4-Dinitrophenol100-02-7——————4-Nitrophenol___"132-64-9——————Dibenzofuran121-14-2——————2,4-Dinitrotoluene84-66-2———————Diethylphthalate7005-72-3—————4-Chlorophenyl-phenylether_86-73-7————————Fluorene100-01-6——————4-Nitroaniline______________534-52-1——————4,6-Dinitro-2-inethy Iphenol,86-30-6———————N-Nitrosodiphenylamine (1)~101-55-3——————4-3romophenyl-phenylether_118-74-1——————Hexachlorobenzene_______________87-86-5———————Pentachlorophenol__________85-01-8———————Phenanthrene____________________12 0-12-7——————Anthracene84-74-2———————Di-n-butylphthalate_206-44-0——————Fluoranthene______129-00-0——————Pyrene_85-68-7——•————Sutylbenzylphthalate91-94-1————£—3,3 '-Dichlorobenzidine,56-55-3—-—>*_--Benzo (a) anthracene___"218-01-9——--*•—Chrysene_117-81-7——————bis (2-Ethylhexyl) phthalate117-84-0——————Di-n-octylphthalate_____~205-99-2——————Benzo (b)f luoranthene________207-08-9——————Benzo (k) f luoranthene________50-32-8———————Benzo (a) pyrene_193-39-5——————Indeno (1,2,3-cd) pyrene_53-70-3———————Dibenz (a,h) anthracene_191-24-2——————Benzo (g,h,i)peryl ene_

1700000340000170000017000003400003400003400003400003400001700000170000034000034000034000017000003400003400003400003400003400003400006900003400003400003400000570000340000340000340000340000340000340000AR30N

uuuuuuuuuuuuuuuuuuuuuuuu

uuuuuu



341

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET __________

CY767Lab Naae: LANCASTER LABS Contract: 68-W8-0055



Sample wt/vol: 1.0 (g/aL) G Lab File ID: A88316 020.RES

Level: (low/aed) MED '. • Date Received: 10/29/88





319-84-6 ——— •"? 1 Q — Qt>— 7_ — __.

c:s— SQ_Q_— — __.76-44-8 ————— •

1024-57-3 —— •

60-57-1 ————— •72-55-9 ————— •72-20-8 ————— •33213-65-9 — •72-54-8 ————— •i n*?T _n~7 — o___.

53494-70-5 — •5103-71-9 —— •5103-74-2 —— •8001-35-2 —— •

—— alpha-3HCT-i *"i -i "OVf**3G cl I>rTw

—— delta-3HC—— gaaaa-3HC (Lindane)——— Heptachlor—— Aldrin—— Heptachlor epoxide—— Endosulfan I——— Dieldrin

f f LJ LJ l_

—— Endrin——— Endosulfan II——— 4, 4 '-ODD—— Endosulfan sulfate——— 4, 4 /-DOT—— Methoxychlor—— Endrin ketone—— alpha-Chlordane—— gaaaa-Chlordane—— Toxaphene

12674-11-2---.-— Aroclor-101611104-28-2-=-~s- — Aroclor-122111141-16-S--s* — Aroclor-123253469-21-9——- — Aroclor-1242T *5 <J"7*5 — OQ C.

1 1 OQ7 — fiQ — 1 __.1TnQ£_O*> gr

—— Aroclor-12 4 8—— Aroclor-1254—— Aroclor-12 60

690.690.690.690.690.690.690.690.130.1400.1400.1400.'1400.1400.1400.6900.1400.6900.6900.14000.6900.6900.6900.6900.6900.14000.4300.

UXuxuxuxuxuxuxuxJuxuxuxuxuxuxux .uxuxuxuxTJXuxuxuxuxuxJ

RevTFORM I PEST A R 3 0 i

67

ID " EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET _________




Sample wt/vol: 30 ' (g/aL) G Lab File ID: A88323 027.RES



Extraction: (Sepf/Cont/Sonc) SONG Date Analyzed: 11/18/88 "* *



319-84-6———————alpha-3HC319-85-7———————beta-3HC_J319-86-3———————delta-BHC53-39-9———————ganna-SHC (Lindane)76-44-8———————Heptachlor_______j309-00-2——————Aldrin1024-57-3—————Heptachlor epoxide959-98-8——————Endosulfan I_____60-57-1———————Dieldrin________72-55-9—————————4 , 4 '-DDE__________72-20-8————————Endrin33213-65-9—————Endosulfan II72-54-8————————4 , 4 '-ODD____"1031-07-8—————Endosulfan sulfate50-29-3————————4 , 4 '-DOT_________"72-43 -5———————Methoxychlor__53494-70-5————Endrin ketone____5103-71-9—————alpha-Chlordane_5103-74-2—————gamaa-Chlordane"8001-35-2—————Toxaphene_12674-11-2————Aroclor-101611104-28-2——-4-Aroclor-122l"11141-16-5——— -Aroclor-12 3 2~53469-21-9——---Aroclor-124 2~12672-29-6—————Aroclor-1248~11097-69-1—————Aroclor-1254"11096-82-5—————Aroclor-1260"

18,18,9,9,9,9,9,9.18.18.18,18.18.18.18.92.18,92.92,180,92.180,92,92.92.180.180.

UXuxuuuuuuuuuuuuuuuuuuuuxuuuuu

AR30I685FORM I PEST 1/87 Rev,

69

Appendix D

Reviewed and CorrectedTentatively Identified Coapounds

AR30I686

IE EPA SAMPLE NOVOLATILE ORGANICS ANALYSIS DATA SHEET ___________TENTATIVELY IDENTIFIED COMPOUNDS

CY753Lab Name: LANCASTER LABS Contract: 68-W8-0055•Lb Code: LANCAS Case No.: 10699 SAS No.: SDG No.: CY753

Matrix: (soil/water) SOIL Lab Sample ID: A1323238L

Saaple wt/vol: 5.0 (g/aL) G Lab File ID: A1323238L

Level: (low/med) LOW " Date Received: 10/29/88

* Moisture: not dec. 20 \ Date Analyzed: 11/01/88

Column: (pack/c p) PACK Dilution Factor: 1.00

CONCENTRATION UNITS:Nuaber TICs found: 0 (ug/L or ug/Kg) UG/KG

CAS NUMBER COMPOUND NAME RT EST. CONC. Q

AR30I687FORM I VOA-TIC 1/87 Rev.

V 22

IF EPA SAMPLE NOSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ____

TENTATIVELY IDENTIFIED COMPOUNDSCY753

Lab Naae: LANCASTER LABS Contract: 68-W8-0055



Sample wt/vol: 1.0 (g/aL) G ' Lab File ID: >D1504

Level: (low/med) MED . Date Received: 10/29/88




CONCENTRATION UNITS:Number TICs found: 16 (ug/L or ug/Kg) UG/KG .

CAS NUMBER

1.2.3.4.5.6.7.8.9.10.11.12.13.1 4JL*i .15.16.

' COMPOUND NAME

Unknown phthalic acid/esternte wn phthalic acid/ester_Unknown phthalic acid/esterUnknown phthalic acid/esterUnknown phthalic acid/esterUnknown phthalic acid/esterUnknown phthalic acid/esterUnknown phthalic acid/esterUnknown phthalic acid/esterUnknown phosphoric acid/esteUnknown phosphoric acid/esteUnknown poly-aromatic amineUnknown phthalic acid/esterUiJu.uwii ph malic1 duia/tfbU.iUnknown phthalic acid/esterUnknown phthalic acid/ester

RTs--g-rr ~—" ?- ~

33.24*» f m -35.8336.0136.0636.1636.5136.6836.7436.9137.3337.4339.37

41.1145.77

EST. GONG.

6400... ——— g-) Q-O ___

22000.40000.34000.8700.11000.6700.5900.26000.38000.6600.11000.

490000.180000.

Q=====J

JJJ dJ ijjj ,jjjjjj

1 1 1

' AR 3 Of 6.8.8FORM I SV-TIC 1/87 Rev.

..'- 205

IE EPA SAMPLE NOVOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS


'Lab Code: LANCAS Case No.: 10699 SAS No.: SDG No.: CY753

Matrix: (soil/water) SOIL Lab Saaple ID: A1323241LR• -.

Saaple wt/vol: 5.0 (g/aL) G Lab File ID: A1323241LR

Level: (low/med) LOW " Date Received: 10/29/88


Coluan: (pack/cap) PACK • Dilution Factor: 1.00

CONCENTRATION UNITS:Number TICs found: 0 (ug/L or ug/Kg) UG/KG

GAS NUMBER COMPOUND NAME RT EST. GONG. Q

AR30I689

FORM I VOA-TIC 1/87 Rev.

.33

IF EPA SAMPLE NO.SZMIVOLATILE ORGANICS ANALYSIS 2ATA SHEET ___________

TENTATIVELY IDENTIFIED CCZPOUNDS fj CY754

Lab Nane: LANCASTER LASS Contract: 63-W8-0055

Lab Code: LANCAS Case. No.: 10699 SAS No.: SDG No.: CY753

Matrix: (scil/water) SOIL Lab Sample ID: 1323241


Level: (Isw/aed) LOW • Date Received: 10/29/88



GPC Cleanup: (Y/N) Y pH:4.5 Dilution Factcr: 1.00000

CONCENTRATION UNITS:Number TICs found: 15 (~g/L or ug/Kg) UG/SG

GAS NUM3IR

1.2. -j3.A

5.6.7.8.9.10.11.12.13.14.15.16.

COMPOUND NAME

Unjciovm ——— • ——————————Unknown aliphatic hydrocarbo.Unknown ———— . ____________ —UnknownUnknown aliphatic hydrocarboUnknownunknownUnknown aliphatic hydrocarboUnknownUnknown — ———————————————Unknown aliphatic hydrocarboUnknownUnknownUnknown aliphatic hydrocarboUnknown

RT

11 4133.74

• —— 34.92 —35.2736.0136.7937.8938.8039.63

—— 4-1. 4742.6743.2546.5843.2657.85

ZST. CONC.

"Li n n. .450.

360.440.610.660.830.380.

2500.340.820.2300.570.

Q

—— tr-oArJ —J

TjJJ

1 TJJ

' JJJ

I/I-f

AR30I690

FORM I SV-TIC 1/87 Rev.

, - 251

IE EPA SAMPLE NOVOLATILE ORGANICS ANALYSIS DATA SHEET ________TENTATIVELY IDENTIFIED COMPOUNDS



Matrix: (soil/water) SOIL Lab Saaple ID: A1323242LR

Saaple wt/vol: 5.0 (g/aL) G Lab File ID: A1323242LR

Level: (low/med) LOW • Date Received: 10/29/88

* Moisture: not dec. 22 Date Analyzed: 11/02/88 .


CONCENTRATION UNITS:Nuaber TICs found: 0 (ug/L or ug/Kg) UG/KG

CAS NUMBER COMPOUND NAME•

RT EST. CONC. Q

FORM I VOA-TIC

\

IF EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET __________


Lab Name: LANCASTER LABS Contract: 68-W8-0055









CAS NUMBER

1.2.3.4.5.6.7.8.9.10.11.12.13.

COMPOUND NAME

rgnteicnrn Ir.ctrrno ———— —————Unknown carboxylic acidUnknown aliphatic hydrocarbo[Unknown — • ———— - ——————————UnknownUnknown aliphatic hydrocarbo•JEfnteicim ———————— - _____ ——Unknown aliphatic hydrocarboUnknown

Unknown aliphatic hydrocarboUnknown

RT

1 * A-A-».

29.5533.74

—— 3-4T-&2—37.8938.80

| ——— 4_hr4-6—42.6646.57

—— 4J? — 5-9 —48.2457.86

EST. CONC.

————— T-S-P"————— 3-_KJ«- ———

350.430.420.380.460.

T ->on ,.,1900.490.

————— 6700; — —2300.660.

Q=====— JBft-

TT3— 1 1 n_JJ i-J-r

JJ

——— ff ———

JJ

f

SI/I

L

AR30I692


27

\IE EPA SAMPLE NO

VOLATILE ORGANICS ANALYSIS DATA SHEET __________________TENTATIVELY IDENTIFIED COMPOUNDS





Level: (low/med) LOW '• Date Received: 10/29/88

* Moisture: not dec. Date Analyzed: 11/02/88

Coluan: (pack/cap) PACK - Dilution Factor: 1.00•

CONCENTRATION UNITS:Number TICs found: 0 (ug/L or ug/Kg) UG/L

GAS NUMBER COMPOUND NAME RT EST. CONC. Q

AR30I693FORM I VOA-TIC . 1/87 Rev.

59

IF EPA SAMPLE NOSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ________


Lab Name: LANCASTER LABS Contract: 68-WS-0055



Sample wt/vol: 1000" (g/aL) ML Lab File ID: >D1401 .

Level: (low/med) LOW \ • ' • . Date Received: '10/29/88

* Moisture: not dec. dec. . Date Extracted: 11/01/88

Extraction: (Sepf/Cont/Sonc) . SEPF - . Date Analyzed: 11/01/88


CONCENTRATION UNITS:Number Ties found: 2 (ug/L or ug/Kg) UG/L

GAS NUMBERsssa- — .Sa— sss sssss uss r ?*rs r. , s

I.2.

COMPOUND NAME

•Piitaiown-ttllc Lriu l^Jgogarbo••'ffnlcnowB —————————— ———— : ——

RT

—— 55 -6-—

EST. CONC.

——————— 4- ———

Q

—— 3B-

FORM I SV-TIC . 1/87 Rev.

304

IE EPA SAMPLE NOVOLATILE ORGANICS ANALYSIS DATA SHEET __________TENTATIVELY IDENTIFIED COMPOUNDS

CY766Lab Name: LANCASTER LABS . Contract: 68-W8-0055

Aab Code: LANCAS Case No.: 10699 SAS No.: SDG No.: CY753



Level: (low/med) LOW '. Date Received: 10/29/88



CONCENTRATION UNITS:Number TICs found: 0 . (ug/L or ug/Kg) UG/L


FORM I VOA-TIC /7 Rev.&$/$

66

IE x EPA SAMPLE NOVOLATILE ORGANICS ANALYSIS DATA SHEET ________TENTATIVELY IDENTIFIED COMPOUNDS


Lab Code: LANCAS Case No.: 10699 SAS No.: * 'SDG No.: CY753' f

Matrix: (soil/water) SOIL - Lab Sample ID: A1313247L

Sample wt/vol: . 5.0- (g/mL) G Lab File ID: A1323247L/


% Moisture: not dec. 13 " """ " Date- Analyzed: "11/02/88

Column: (pack/cap) PACK " " Dilution Factor: 1.00• °

' ' . CONCENTRATION UNITS:Number TICs found: 0 (ug/L or ug/Kg) UG/KG


FORM I VOA-TIC B7 ReA R 3 0 I 6

73

IF * EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ________




atrix: (soil/water) SOIL Lab Sample ID: 1323247

Saaple wt/vol: l.o (g/aL) G Lab File ID: >D1505

Level: „„ (low/med)...- MED '. Date Received: .10/29/88' • • * , ' " . ' . * ' " " - .- ' *

% Moisture:~not~dec. 13 dec. Date Extracted: 11/03/88

Extraction: " (Sepf/Cont/Sonc) SONG Date Analyzed: 11/05/88



CAS NUMBER

1. /2.3.4.

, *'1r 7-8.9.10.

COMPOUND NAME

Unknown poly-aromatic ketone•gnfcaovn-phthalie aeid/eatog—Unknown phthalic acid/esterUnknown phthalic acid/esterUnknown phthalic acid/esterUnknown phthalic acid/esterUnknown phthalic acid/esterUnknown phthalic acid/esterUnknown phthalic acid/esterUnknown phthalic acid/ester

RT

30.4834 9T35.8536.0236.0836.1836.5136.6941.1545.78

EST. CONC.

7000."7 0086000.160000.130000.49000.44000.34000.320000.93000.

Q

J_ JJJJJJJJJ

AR30T691FORM I SV-TIC 1/87 Rev,

31

DBO Mport

Appendix E

contractual Compliance

AR301698

page 1 of 2

ORGANIC DATA VALIDATION SUMMARY

Date Review Completed: 1/17/89 Contract Lab.: Lancaster LabsCase No.: 10699 Contract No.: 68-W8-0055Site Name: Eastern Diversified Metals Lab DPO: Charles SandsSample Nos.: CY753,CY754,CY760,CY765- Reviewer: S. Rowshan-Kolar

CY768 From: Region III/ESAT~— - Phone: (301) 266-9887

CONCENTRATIONMATRIXsoil/solidaqueousother

low52

med high MATRIX RELATED COMMENTS

70LATILESGC/MS tunina — BFBInitial CalibrationContinuing CalibrationSurrogate RecoveryMatrix SpikesReagent BlanksHoldincr Times

OKX

XX

X

FYI

XX

X

Action COMMENT

See notes 1 and 2See notes 1 and 2

See note 3

3EMI-VOLATILESGC/MS tunina — DFTPPInitial CalibrationContinuing CalibrationSurrogate RecoveryMatrix SpikesReagent BlanksHolding Times

OKX

XX

FYI

XXXX

Action COMMENT

See notes 1 and 2See notes 1 and 2See note 4See note 5

PESTICIDESInstrument PerformanceInitial CalibrationContinuing CalibrationSurrogate RecoveryMatrix SpikesReagent BlanksHolding Times;:

OKXXX

Xx

FYI

XX

Action COMMENT

1

See note 6See note 7

OVERALL CASECompound IdentificationData Completeness

OKXX

FYI Action

REVIEWERS COMMENTS;

1699DOCUMENTATION ATTACHED (see following pages)

Case 10699 Page 2 of 2

Organic Data Validation Summary

Note 1 - The response factors for 2-butanone and 3-nitroanilinewere less than 0.05 in the initial or continuing

.„.—,„,.,. ... calibration. (See Table I of Appendix F) .

Note 2~~-~ The %RSD and %D values for several compounds exceeded""••-•• precision criteria in the initial and continuing calibration.

(See Table I of Appendix F).

Note 3 - The maximum concentrations of the following compoundswere found in the laboratory method blanks:

Compound Concentration fug/Kg^

methylene chloride* I Jacetone* 2 J2-butanone* 3 J

* = Common Laboratory Contaminant

Note 4 - Semi-volatile analysis of samples CY753DL, CY753MSDL andCY753MSDDL had surrogate recoveries outside the QC limitsdue to dilution.

Note 5 - The semi-volatile MS/MSD analysis of sample CY753 hadone (1) out of eleven (11) RPDs outside the QC limits. Thesemi-volatile MS/MSD analysis of sample CY760 had two (2)out of twenty-two (22) recoveries outside the QC limits.

Note 6 - The percent recovery of dibutylchlorendate was outsidethe QC limits in samples CY767, CY753MS, CY753MSDand CY753. This was due to the interferent from samplematrix present in the medium level soils. The surrogaterecovery was also outside the QC limits for PBLKM.

Note 7 - The pesticide MS/MSD analysis of sample CY753 had one(1) out of six (6) RPDs and one (1) out of twelve (12)recoveries outside the QC limits.

AR30I700

Appendix F

Support Documentation

AR30I70!

Case 10699

Table ICompounds and Associated Samples Affected by Calibration

Uncertain!ty

Volatiles CY753 CY754 CY760 CY765 CY766 CY767

2-butanone R R R R R

Semi-Volatiles

4-chloroaniline I I I3-nitroaniline R R Rhexachlorocyclopentadiene I I2,4-dinitrophenol C* C*

I = %RSD exceeded 30% in the initial calibration, positive resultswere qualified "J" and quantitation limits arequalified "UJ".

C = %D exceeded 25% in the continuing calibration. Positive resultsare qualified "J" and quantitation limits are qualified "UJ".

R = RF less than 0.05 in initial or continuing calibration. Thequantitation limits are qualified "R".

* = The "UL" and "L" qualifiers which denote low bias supercede thequalifiers issued in this table.

AR30I702

6AVOLATILE ORGANICS INITIAL CALIBRATION DATA



instrument ID: 01930 Calibration Date(s): 11/01/88 11/01/88

Matrix: (soil/water) SOIL ' Level: (low/med) LOW Coluan: (pack/cap) PACK

Min RRF for S?CC(S) - 0.300.(0.250 for Bromofora) Max %RSD for CCC(*) = 30.0%

Lab File ID: RRF20 =A20NO1R RRF50 =A50N01RRRF100=A100NO1 RRF150=A150N01 RRF200=A200NO1R

COMPOUND

Chloromethane ••Brsraomethane

RRF20

f 1.0340.556

Vinyl Chloride * 0.659ChloroethaneMethvlene ChlorideAcetoneCarbon Disulfide

0.3561.2690.8932.492

1, 1-Dichloroethene * 1.0631,1-Dichloroethane # 2.2311,2-Dichloroethene (total) 1.223Chloroform * 2.732J. , 2-Dichloroethane^-Butanonej., 1, 1-TrichloroethaneCarbon TetrachlorideVinyl AcetateBromodichloromethane

2.1690.0760.4380.4310.7950.529

1,2-Dichloropropane * 0.332cis-1, 3-DichloropropeneTrichloroetheneDibromochloromethane1,1, 2-TrichloroethaneBenzeneTrans-1, 3-DichloropropeneBromoform :4-Methyl-2-Pentanone2-Hexanone :':.ST 'Tetrachloroethener htfs1 , 1 , 2 , 2 -Te t r a chl oio thane =

0.4970.4200.4740.3520.8000.4570.4030.8120.6920.467

I 0.791Toluene * 0.688Chlorobenzene # 0.980Ethylbenzene * 0.475StyreneXylene (total)

Toluene-d8Bromofluorobenzenefe 2-Dichloroethane-d4

0.8390.528

1.1530.8081.937

RRF50

1.0200.6100.7120.3341.1620.6432.5961.0212.1751.1532.6342.1960.0460.4380.4470.7930.5370.3130.4900.3980.4980.3250.7200.4430.4840.7340.5850.4570.7080.6320.9110.4470.8150.501

1.1400.8182.058

RRF100

0.8170.6010.6340.3861.1080.5902.6251.0332.1601.1722.6002.0650.0460.4440.4530.8190.5520.3270.5200.3950.4790.3140.7050.4530.4830.7330.5850.4270.7140.6410.9060.4610.8400.508

1.1540.8472.039

RRF150

0.7530.5830.6630.3691.0880.5382.6490.9932.1041.1432.5272.0410.0450.4600.4670.8410.5780.3290.5370.3930.4810.3070.6790.4590.5160.7320.5760.4090.7000.6270.8840.4540.8570.519

1.1700.8612.080

RRF200

0.8310.5760.6420.3491.0250.5182.5770.9432.02S1.1022.4331.9930.0410.4570.4740.8450.5770.3220.5330.3920.4770.2920.6360.4430.5570.7010.5510.3990.6640.6080.8760.4310.8110.487

1.1470.82&2.073

RRF

0.8910.5850.6720.3691.1300.6362.5881.0122.1501.1612.5352.0930.0510.4470.4540.8200.5550.3250.5150.4000.4820.3180.7080.4510.4890.7420.5980.4320.7150.6390.9110.4540.8320.509

L 1.153ttWtf2.037

RSD

14.3|3.6|4.0*4.58.1

23.82.34.3*4.3£4.0|4.4*4.127.92.33.72.84.12.3*4.12.92.07.18.51.711.6|5.69.16.86.5t4.7*4.513.6*2.33.1

1.0IS2-62.9

FORM VI VOA 1/87 Rev._

~ "w tJ— "<e- T — ' -

- J ~ "-O KO 4

6AVOLATILE ORGANICS INITIAL CALIBRATION DATA



Instrument ID: 01930 Calibration Date(s): 11/02/88 11/02/88

Matrix:(soil/water) WATER Level:(low/med) LOW Column:(pack/cap) PACK

Min RRF for S?CC(f) = 0.300 (0.250 for Bromoform) Max %RSD for CCC(*) » 30.0%

Lab File ID: RRF20 =A20NO2R RRF50 =A50NO2RRRF100=A100NO2 RRF150=A150NO2 RRF200=A200NO2

COMPOUND

Chloromethane iBroraomethane

RRF20

! 0.6310.811

Vinyl Chloride * 0.702ChloroethaneMethylene ChlorideAcetoneCarbon Disulfide

0.4040.5670.3001.673

1,1-Dichloroethene * 0.8781,1-Dichloroethane 3 1.7401,2-Dichloroethene (total) 1.036Chloroform * 2.3241 , 2-Dichloroethane2-3utanone1,1, 1-TrichloroethaneCarbon TetrachlorideVinyl AcetateBrcmodichloromethane

1.7120.0210.3780.3760.5780.450

1,2-Dichloropropane * 0.277cis-l,3-DichloropropeneTrichloroetheneDibromochloromethane1,1, 2-TrichloroethaneBenzeneTrans-1 , 3-Dichloropropene

0.4120.4060.4380.3280.6820.373

Bromoform f 0.3004 -Methy 1 -2 -Pent anone2-Hexanone /SUSTetrachloroethen i S?1,1,2,2 -TetrachiilSiithane =

0.4030.2320.4160.570

Toluene ' * 0.627Chlorobenzene 3 0.958Ethylbenzene * 0.461StyreneXylene (total)==========================:::

Toluene-dSBromofluorobenzene1 , 2-Dichloroethane-d4

0.8100.506

========1.1110.7731.559

RRF50=====0.7990.7310.6710.3720.9130.2661.6760.8551.7151.0132.2201.7210.0200.3700.379,0.5780.4410.2640.4020.3880.4410.2910.6300.3610.3400.3890.2730.4120.5180.5760.8830.4300.7690.472

1.1060.7671.669

RRF100

0.8320.7510.6320.3660.8900.2311.8950.8441.6650.9792.1181.6050.0190.3700.3840.5760.4540.2620.4130.3780.4510.2760.6030.3640.3550.3500.2420.3960.4830.5600.8630.4270.7870.486

1.1010.7831.648

RRF150

0.7970.7250.6730.3700.6620.2291.9100.8231.6340.9692.0791.5950.0190.3730.3910.5920.4590.2630.4180.3760.4380.2690.5940.3710.3780.3600.2520.3930.4730.5470.8420.4220.8100.494

1.1000.7831.711

RRF200

0.7980.6320.6490.3540.8350.2301.8450.7941.6110.9362.0371.5730.0190.3730.3930.6030.4670.2630.4240.3680.4350.2630.5750.3710.3970.3640.256.0.3850.4730.5370.8350.4150.7800.474

========1.1010.7921.733no'

< >,:- > FORM VI VOA •?""

RRF======0.7710.7500.6750.3730.7730.2511.8010.3391.6730.9872.1561 ._&4i«

Q-.T20.3850.5850.4540.2660.4140.3830.4'410.2850.6170.3680.3540.3730.2610.4000.5030.5690.8760.4310.7910.486

1.1040.7801.6640170 .

RSD

10.4.6.62.8*5.019.612.56.43.8*3.233.95.4*4 ^1j 1-M0.91.92.02.12.4*2.03.8

' 1.49.16.71.410.5.5.96.23.33.336.2*5.6|4.1*2.32.9

======0.4

I-MA •

i 1- 1/87 Re\

7AVOLATILE CONTINUING CALIBRATION CHECK


teb Code: LANCAS Case No.: 10699 SAS No.: SDG No.: CY753

Instrument ID: 01930 Calibration Date: 11/01/88 Time: 21:05

Lab File ID: A50NOV1 Init. Calib. Date(s): 11/01/83 11/01/88

Matrix: (soil/water) SOIL Level: (low/med) LOW Column: (pack/cap) PACK

Min RRF50 for S?CC(f) - 0.300 (0.250 for Bromoform) Max %D for CCC(*) - 25.0%

COMPOUND

Chloromethane :Brcinomethane

RRF

f 0.8910.535

Vinyl Chloride * 0.672Chl or oethaneMethylene ChlorideAcetoneCarbon Disulfide

0.3691.1300.6362.538

1, 1-Dichloroethene * 1.0121,1-Dichloroethane 3 2.1501,2-Dichloroethene (total) 1.161Chloroform * 2.5851 , 2-Dichloroethane2-3utanone1,1, 1-TrichloroethaneCarbon TetrachlorideVinyl AcetateBromodichloromethane

2.0930.0510.4470.4540.8200.555

1,2-Dichloropropane * 0.325cis-1 , 3-DichloropropeneTrichloroetheneDibromochloromethane1 / 1 / 2-TrichloroethaneBenzeneTrans-1 , 3-DichloropropeneBromoform •4-Methyl-2-Pentanone2-Hex3;Tj,pneTetr chioroethene1 , 1 rTetrachl or oethane • i

0.5150.4000.4820.3180.7080.451

f 0.4390.7420.5980.4320.715

Toluen- * 0.639Chlorobenzene 3 0.911Ethylbenzene * 0.454StyreneXylene (total)***= =——-•—-—-•-•-*»— g --— • —•.—--•-•—— «»—aBi-—«- . ---M,-- .!---.——».-.—

Toluene-d8Bromofluorobenzene1 , 2-Dichloroethane-d4

0.8320.509

========:

1.1530.8332.037

RRF50

0.8910.6590.6630.3621.1340.5402.2581.0742.3441.2592.8702.281CpTosT0.4440.4540.7590.5550.3330.5080.4330.4950.3480.7810.4750.4450.6540.4970.4860.7430.6980.9980.4970.8610.529

========1.1400.8211.987

%D

O.Oi-12.7

0.6*1.9-4.815.112.8-6.1*-9.0^-8.4-11.0*-9.0

> 23.50.70.07.40.0-4.0*1.4

-8.3-2.7-9.4-10.3-5.39.0311.916:9-12.5-3.9'f-9.2*-9.63-9.5*-3.5-3.9

1.11.*2.1

R30I705

FORM VII VOA 1/87 Rev.

126

6BSEMIVOLATILE ORGANICS INITIAL CALIBRATION DATA

Lab Name: LANCASTER LABS INC. Contract: 68-W8-0055


Instrument ID: 302861 Calibration Date(s): 11/01/88

Min RR? for SPCC(#) s 0.050 , Max %RSD for CCC(*) •* 30.0%

Lab File ID: RRF20 »>W1403 RRF50 =>W1405RRF30 =>W1401 RRF120=>W1404 RRF160=>W1402

COMPOUND

Phenol ' •bis (2-Chloroethyl) ether2-Chlorophenol1, 3-Dichlorobenzene

RRF20

' 1.7201.6621.4631.612

1,4-Dichlorobenzene * 1.584Benzyl alcohol1, 2-Dichlorobenzene2--.ethylphenolbis (2-chlorciscpropyl) ether4-Methylphenol

.7851.5501.2642.1481.323

N-Nitroso-di-n-propylamine 3 1. 219HexachloroethaneNitrobenzeneIsophorone

.682

.429

.8732-Nitrophenol * .2652 , 4-DimethylphenolBenzoic acidbis (2-Chloroethoxy) methane

.323

.4862,4-Dichlorophenol * .3011,2, 4-TrichlorobenzeneNaphthalene4 -Chloroanil ine

.3361.036.202

Hexachlorobutadiene * .1844-Chloro-3-methylphenol * .3522 -Methylnaphthal ene .643Hexachlorocyclopentadiene' 3 .1762,4,6-Trichloropj eaol * .4082,4,5 -Tr ichl Grogf! eiil2 — Chl oronaphtIialTSjifc>2-Nitroaniline *~r-':-~DimethylphthalateAcenaphthylene2 , 6-Dinitrotoluene3-Nitroaniline

1.214

1.5831.842.368

Acenaphthene * 1.2312,4-Dinitrophenol 34-Nitrophenol • •.

RRF50

1.6541.7101.4201.6261.646.824

1.5921.2702.2331.3271.220.744.447.870.224.307.179.490.287.344

1.009.181.196.328.596.249.373.417

1.182.417

1.5021.745.365.010

1.125.115.102

RRF80

1.9021.6951.4321.6391.695.734

1.6491.2602.3441.3461.241.768.531

1.037.232.393.252.535.312.394

1.063.178.208.355.625.367.414.461

1.386.505

1.5431.865.434.012

1.238.170.130

RRF120

1.8501.5911.3651.5321.594.835

1.5831.2572.2011.3181.209.699.455.878.216.371.249.488.295.341.988.109.190.345.590.332.426.444

1.237.423

1.4811.600-.371'.0101.180.167.121

RRF160

1.9221.5741.4521.5041.464.824

1.4431.1742.2021.2631.195.670.456.915.236.395.249.512.319.331.939.327.181.373.583.329.444.413

1.184.484

1.3321.249.335.020

1.093/J.ft9£r..94»

RRF

1.8101.6471.4261.6031.597.800

1.5641.2452.2261.3161.217.713.463.915.235.359.232.502.303.349

1.007'.199.192.351.607.290.413.434

1.241.457

1.4881.660.375(Tois)

1/173i 7 6/3,ib$

RSD=====

6.5*3.72.74.25.4*5.24.83.23.32.41.435 . U8-fl7.7|8.1*

11.015.34.24.2*7.34VL

X"3~9T§-"""•~S76*

4.6*4.2

26.6.6.4*5.36.89.56.415.29J2-

5.4 121.6314. 1

FORM VI SV-1 1/87 Rev.

6CSZMIVOLATILE ORGANICS INITIAL CALIBRATION DATA


b Code: LANCAS Case No.: 10699 SAS No.: SDG No.: CY753


Min RRF for S?CC(3) - 0.050. Max %RSD for CCC(*) » 30.0%

Lab File ID: RRF20 =>W1403 RRF50 =>W1405RRF30 =>W1401 RRF120=>W1404 RRF160=>W1402

COMPOUND

Dibenzofuran2 , 4-DinitrotolueneDiethylphthalate4-Chlorophenyl-phenyletherFluorene4-Nitroaniline4 , 6-Dinitro-2-methylphenol

RRF20

1.654.482

1.673.583

1.211

N-Nitrosodiphenylamine (1) * .4464-3romophenyl-phenyletherKexachlorobenzene

.240

.324Pentachlorophenol *•ChenanthreneRnthraceneDi-n-butylphthalate

1.024.965

1.704Fluoranthene * .961PyreneButylbenzylphthalate3 , 3 ' -DichlorobenzidineBenzo (a) anthraceneChrysenebis ( 2-Ethylhexy 1 ) phthalate

2.2531.409.203

1.2861.1802.244

Di-n-octylphthalate * 6.908Benzo (b) f luorantheneBenzo (k) f luoranthene

2.4172.069

Benzo (a) pyrene . * 1.931Indeno ( 1 , 2 , 3-cd) pyreneDibenz (a,h) anthrate rilbBenzo (g, h, i) peryiepfe

Ni t robenz ene-d52-FluorobiphenylTerphenyl-dl4Phenol-d62-Fluorophenol2,4, 6-Tribromophenol

1.8031.4761.572

.5801.6341.7682.3301.771.311

RRF50

1.569.473

1.522.550

1.095.069.135.371.224.317.124.982.924

1.639.921

2.1411.359.157

1.3231.2072.1326.4692.5032.0681.9371.9041.5331.641

.5811.6051.7192.3391.845.313

RRF80

1.751.579

1.594.580

1.172.094.155.355.228.342.147

1.026.977

1.708.975

2.1241.365.140

1.3201.1502.0694.6771.6451.5821.3851.3671.1471.191

.5921.7111.7382.2901.827.263

RRF120

1.653.511

1.579.5431.114.045.154.257.218.303.149.971.889

1.612.931

1.9351.250.1481.2111.0821.8814.9771.8911.4511.4661.4531.2141.245

.5681.7601.6522.3131.780.340

RRF160

1.539.497

1.423.457.939.076.163.253.209.295.166.919.872

1.493.871

2.0731.377.1921.3441.1362.0276.5612.2991.9391.9351.9141.5341.614

.5851.6701.8622.2421.758.294

RRF

1.643.508

1.558.543

1.106.071.152.336.224.316.147.985.925

1.631.932

2.1061.352.168

1.2971.1512.0705.9182.1511.8221.7311.6881.3811.452

.5811.6761.7482.3031.796.304

%RSD

4.38.36.09.49.428.47.824.4'5.35.8

11.7*4.55.05.44.3*5.64.516.74.04.1

' 6.517.2*17.115.816.2*15.413.514.9

1.53.74.41.72.19.3

Cannot be separated from Diphenylamine H iY G U I y .ar-C' FORM VI SV-2 1/87 Rev.

*55

6BSEMIVOLATILE ORGANICS INITIAL CALIBRATION DATA




Min RRF for SPCC(f) = 0.050; Max %RSD for CCC(*) 30.0%

Lab File ID: RRF20 =>W1453 RRF50 =>W1455RRF30 =>W1454 RRF120 >W1452 RRF160=>W1451

COMPOUND=====£— =r=s—:=:=3=s=:=5====s=ss=:=ss=3

RRF20=====

Phenol * 1.693bis (2-Chloroethyl) ether2-Chlorophenol1,3-Dichlorobenzene

1.6251.3971.550

1,4-Dichlorcbenzene * 1.528Senzyl alcohol1 , 2-Dichlorobenzene2 -Methy Iphenolbis (2-chloroisopropyl) ether4 -Methy Iphenol

.7341.5611.2433.0471.237

N-Nitroso-di-n-propylamine 3 1.346HexachloroethaneNitrobenzeneIsophorone

.702

.442

.9152-Nitrophenol * .2562 , 4 -Dinethy Iphenol3enzoic acidbis ( 2 -Chloroethoxy) methane

.345

.4862,4-Dichlorophenol * .2921,2, 4-TrichlorobenzeneNaphthalene4-Chloroaniline

.357

.977

.225Hexachlorobutadiene * .2064-Chloro-3-methylphenol * .3622 -Me thy Inaphthal ene .643Hexachlorocyclop| Ediene 3 .1422 , 4 , 6-Trichlorop|ji||il -* .4032 / 4 , S-TrichloropfieipO.2-Chloronaphthalene2-NitroanilineDimethylphthalateAcenaphthylene2 , 6-Dinitrotoluene3 -Nitroaniline

1.172

1.5331.820.370

Acenaphthene * 1.2152,4-Dinitrophenol 34-Nitrophenol 3

RRF50====:==

1.5941.6431.3801.6221.602.'851

1.5631.1963.0991.2501.381.733.452.901.216.331.215.494.305.364.998.230.220.351.609.297.395.427

1.177.496

1.5271.741.373.028

1.124.137.105

RRF80ss==:==

1.8521.6171.3781.6431.609.889

1.6451.2243.1811.2761.392.751.514

1.046.227.392.249.501.317.409

1.027.109.248.375.644.402.424.461

1.353.504

1.5121.690.433.016

1.174.180.128

RRF120===s=ss=s

1.8371.6151.3911.6241.589.874

1.5761.2573.3931.2961.443.763.492.972.222.394.255.512.312.362.989.207.218.375.610.343.425.461

1.158.523

" 1.3901.423.348.016

1.116.194.123

RRF160======1.8341.5761.4391.4641.443.771

1.4461.1523.3041.2131.369.678.489.954.226.399.245.488.314.340.923.344.195.380.554.-348.445.419

1.143.535

1.3671.239.346.024

1.079.208.143fiR-

RRF=S==3S=S

1.7621.6151.3971.5801.555.834

1.5581.2153.2051.2541.386.725.478.957.229.372.241.496.308.366.983.223.218.368.612.306.418.442

1.201.514

1.4661.583.37JL052:1i.inr.180.125t n i T n

RSD===s

6.5*1.51.84.74.4*6.44.63.54.52.6

6.36.06.9*8.57,32.13.2*7.03 . j^

(37~ 5 >1&T2*3.2*=Ur -IGTTsjjp473*5.07.23.45.515.49.4

) (30731>4.7*17. L12. p

$ 1


376

6CSEMIVOLATILE ORGANICS INITIAL CALIBRATION DATA



Instrument ID: 02861 . . Calibration Date(s): 11/03/88

Min RRF for S?CC(f) = 0.050" Max %RSD for CCC(*) = 30.0%


COMPOUND========sas=s=======±s==:==s==:==

Dibenzofuran2 , 4-DinitrotolueneDiethylphthalate4-Chlcrophenyl-phenyletherFluorene4-Nitroaniline4 , 6-Dinitro-2-methylphenol

RRF20======

1.625.4601.619

.6081.183

N-Nitrosodiphenylamine (1) * .4304-3romcphenyl-phenylether .Hexachlorobenzene

• .239.351

ipentachlorophenol *IphenanthreneAnthraceneDi-n-butylphthalate

.982

.9131.605

Fluoranthene * .930PyreneSutylbenzylphthalate3 , 3 '-DichlorobenzidineBenzo (a) anthraceneChrysenebis ( 2-Ethylhexyl ) phthalate

1.9811.122

.2431.2951.2111.648


2.4312.040

Benzo (a) pyrene * 1.943Indeno (1,2, 3-cd) g i neDibenz (a,h) anthraceneBenz o ( g , h , i ) peryierte

Ni tr obenz ene-d52-FluorobiphenylTerphenyl-dl4Phenol~d62-Fluorophenol2,4, 6-Tribromophenol

1.7201.3691.476

.5751.6231.6692.2221.690

.384

RRF50======

1.605.478

1.541.582

1.110.093.148.391.235.357.145.965.900

1.473.983

1.7401.006

.1791.2761.1251.4414.4172.2342.0361-9401.9471.5841.642

.5901.6041.5692.2061.665

.419

RRF80=====

1.697.569

1.571.532

1.131.081.163.314.248.394.173.972.962

1.5191.0641.567

.909

.1701.2201.0931.2793.0151.6841.4051.4251.4901.2601.250

.5961.6781.3952.1501.650

.404

RRF120======

1.544.498

1.447.490

1.040.077.166.293.220.339.167.955.891

1.450.930

1.619.964.169

1.2461.0131.3103.6721.8291.4921.5031.4521.2141.229

• .6151.6781.5382.2921.744

.374

RRF160======

1.528.477

1.390.462.962.087.174.304.205.300.169.922.8261.391

.9341.6561.024

.2021.2421.0351.3104.5982.3532.0171.9301.9771.6291.616

.5941.6721.5852.1951.716

.336A R -

RRF=====

1.600.497

1.514.545

1.086.086.163.347.229.348.164.959.898

1.488.988

1.7131.005

.1931.2561.0961.3984.1932.1161.7981.7481.7171.4111.443

.5941.6511.5512.2131.693

.3830170'

RSD=====4.38.76.2

11.88.0

10.96.7

17.5*7.49.87.6*2.45.55.44.7*9.57.9

16.12.37.2

11.020.7*15.917,914.9*14.313.313.6

2.52.16.42.32.28.3L_

.) Cannot be separated from Diphenylamine


37.7

63SEMIVOLATILE ORGANICS INITIAL CALIBRATION DATA




Min RRF for SPCC(3) «• 0.05O . Max %RSD for CCC(*) » 30.0%


COMPOUND

Phenol •bis (2-Chloroethyl) ether2-Chlorophenol1, 3-Dichlorobenzene

RRF20

« 1.7251.6351.4231.574

1, 4-Dichlorobenzene * 1.591Benzyl alcohol1 , 2-Dichlorcbenzene2-Methylphenolbis (2-chloroisopropyl) ether4-Methylphenol

.8551.4991.3162.3961.290

N-Nitroso-di-n-propylamine 3 1.298HexachloroethaneNitrobenzeneIsophorone

.703

.409

.8992-Nitrophenol * .2542 , 4-DimethylphenolBenzoic acidbis ( 2 -Chloroethoxy) methane

.335


.3241.000.200

Hexachlorobutadiene * .1824 -Chloro-3-methy Iphenol * .3382 -Methy Inaphthal ene .612Hexachlorocyclop t;idiene 3 .1462,4,6-Trichlorop3bfe t(&l * .4062,4,5 -Tr ichl or oplSitfal2-Chloronaphthalerie2-N.itroanilineDimethylphthal ateAcenaphthy 1 ene2 , 6-Dinitrotoluene3 -Nitroaniline

1.206

1.5841.839.358

Acenaphthene * 1.2632,4-Dinitrophenol 34-Nitrophenol ,\

RRF50

1.3971.7751.4241.6641.635.917

1.6091.2532.4121.3241.302.745.457.903.204.327.204.511.291.333.984.258.189.331.616.257.378.416

1.208.480

1.4371.796.377.023

1.177.142.120

RRF80

1.9751.6331.4461.6901.665.984

1.6781.3242.5851.3901.434.739.524

1.074.221.396.258.537.309.384

1.026.130.216.378.638.371.410.468

1.363.508

1.6191.627.446.009

1.221.184.149

RRF120

1.9871.6901.4861.6501.655.990

1.6371.3652.5771.4261.417.782.463.926.209.364.254.498.291.336.983.186.183.354.585.315.405.440

1.178.483

1.4301.341'.352.013

1.116.133.130

RRF160

2.0331.6511.5221.5331.510.946

1.4921.2772.4971.1631.362.722.431.934.236.400.261.512.313.330.969.324.182.383.586.•308.456.402

1.166.461

1.3421.086.330.021

1.111.201*RfP*

RRF

1.9231.6771.4611.6221.611.938

1.5831.3092.4941.3201.362.748.467.947.225.364.244.507.297.341.992.220.190.357.607.279.411.432

1.224.483

1.4821.548.373(017)

1.178.179

10 t W

RSD

6.3'3.62.94.1

:

3.9*5.95.33.13.67.64. L5.W9.07.79.0*9.311.14.34.4*7.12 ,

C-3T.&_."TTT

)c

6.6*3 . 7j<ttS*"iTs*6.76.53.97.821.4II. 9-

("3~sr.~9•v

~5T6*14.

?10*

Z.-1 75 3 FORM VI SV-1 1/87 Rev.

?" ' 398



ab Code: LANCAS Case No.: 10699 SAS No.: SDG No.: CY753


Min RRF for SPCC(3) s 0.050. Max %RSD for CCC(*) » 30.0%

Lab File ID: RRF20 =>W1502 RRF50 =>W1501RRFSO =>W1503 RRF120=>W1504 RRF160=>W1505

COMPOUND

Dibenzofuran2 , 4-DinitrotolueneDiethylphthalate4-chlorophenyl-phenyletherFluorene4-Nitroaniline4 , 6-Dinitro-2-methylphenol

RRF20

1.618.4331.717.566

1.198

N-Nitrosodiphenylamine (1) * .4464-3romophenyl-phenyletherHexachlorobenzene

.225

.322Pentachlorophenol *

. Phenanthrenepj.nthraceneDi-n-butylphthalate

.965

.9451.657

Fluoranthene * .934PyreneSutylbenzylphthalate3,3' -DichlorobenzidineSenzo (a) anthraceneChrysenebis (2-Ethylhexyl) phthalate

2.3191.304.2451.2741.1921.832


2.2081.914

Benzo (a) pyrene * 1.916Indeno ( 1 , 2 , 3 -cd) pyreneDibenz (a , h) anthrwaineBen z o ( g , h , i ) peryiej e

^ =•-. ' tt''J3r -,.

Nitrobenzene-d52-FluorobiphenylTerphenyl-dl4Phenol-d62-Fluorophenol2,4, 6-Tribromophenol

1.8271.4841.599

.5461.6601.8172.3231.807.344

RRF50-~f-sa~!->—~-- _—

1.599.476

1.593.537

1.133.115.142.370.201.302.133.984.921

1.564.983

1.9351.253.151

1.3021.1711.7495.3252.3131.9781.9521.9491.5661.661

.5621.6651.6042.3841.856.307

RRF30

1.757.590

1.737.556

1.173.115.164.331.219.350.169.996.985

1.6561.0091.779l.OSO.138

1.1981.0661.4473.4661.7181.3631.4141.3281.1061.103

.5981.6431.4812.3551.757.364

RRF120

1.536.521

1.507.469

1.038.092.163.287.213.315.169.961.915

1.547.981

1.6831.026.155

1.1791.0111.3073.7661.8151.5241.4551.3821.1701.161

.5921.6171.4672.5091.923.358

RRF160

1.435.4911.431.442.931.101.173.267.199.232.179.898.8401.432.9161.7771.100.200

1.2841.0411.3494.8832.1281.8031.9421.7901.'4801.482

.5931.6491.6272.3361.834.360

RRF

1.599.502

1.597.514

1.094.105.160.340.211.314.162.961.921

1.571.964

1.8991.155.173

1.2471.0961.5374.4992.0361.7171.7361.6551.3611.401

.5781.6471.5992.3811.845.346

%RSD

7.211.68.210.810.010.88.221.0*5.48.012.4*3.95.85.94.0*13.210.224.94.47.415.518.4*12.615.315.9*17.015.318.2

3.91.28.33.13.56.3

|) Cannot be separated from Diphenylamine

FORM VI sv~2 fi R 3 0 1 7 Y 7 Rev39

: 63SZMIVOLATILE ORGANICS INITIAL CALIBRATION DATA




Min RR? for SPCC(3) = 0.050 Max %RSD for CCC(*) - 30.0%

Lab File ID: RRF20 =>V3603 RRF50 =>V3605RRF30 =*>V3604 RRF120=>V3602 RRF160=>V3601

COMPOUND

Phenol •bis (2-Chloroethyl) ether2 -Chlorophenol1,3-Dichlorobenzene

RRF20

f 1.6351.6331.4541.533

1,4-Dichlorobenzene * 1.609Senzyl alcohol1, 2-Dichlorobenzene2 -He thy Iphenolbis (2-chloroisopropyl) ether4-Methylphenol

.5531.5881.3314.2591.299

N-Nitroso-di-n-propylamine # 1.449HexachloroethaneNitrobenzeneIsophorone

.728

.333

.7532-Nitrophenol * .2112 , 4-DimethylphenolSenzoic acidbis (2-Chlcroethoxy) methane

.332


.3351.119.405

Hexachlorobutadiene * .1724-Chloro-3-methylphenol * .3252-Methylnaphthalene .708Hexachlorocyclopaniadiene* 3 .0982,4,6-Trichlorqp$iilil * .3262 , 4 , 5-Trichlorop ||pl2-Chloronaphthalene "2-NitroanilineDimethylphthalateAcenaphthy 1 ene2 , 6-Dinitrotoluene3 -Nitroanil ine

1.160

1.5532.043.320

Acenaphthene * 1.3552,4-Dinitrophenol 34-Nitrophenol if

RRF50

1.5581.5271.3641.4971.566.642

1.5251.3033.7541.3171.309.674.382.725.207.322.118.481.295.330

1.039.413.166.316.604.168.343.3851.117.434

1.5181.907.350.176

1.265.125.071

RRF80

1.4621.4151.2701.3891.445.606

1.3951.0903.5551.1411.207.625.353.696.195.299.134.447.275.306.943.391.158.310.579.185.319.351

1.050.4161.3911.765.328.2111.151.134.030

RRF120

1.3891.3941.2561.3051.356.662

1.3001.0643.4841.1101.232.589.334.666.189.279.181.420.263.290.798.381.151.301.528.229.315.377.992.425

1.3321.566.324'.3401.048.159.096

RRF160

1.4561.4721.2461.3201.339.668

1.3501.0484.0561.1491.405.658.354.712.187.305.171.439.254.283.855.374.143.306.523.213.294.358.942.439

1.2781.568.314.3221.021-14fi.102

RRF

1.5001.4981.3181.4191.463.626

1.4311.1773.8211.2031.320.655.362.712.198.308.151.461.276.309.951.393.158.312.588.179.320.368

1.052.428

1.4141.770.327.262

1.168"J SD-i

- .088-'

RSD

6.4*7.76.38.48.3*7.68.413.08.68.18.0J

8'16.zl4.8|5.5*6.819.98.46.7*7.513.84.17.3*3.0*12.828.6.5.6*

. 4.38.52.48.311.84.2

("SO-fS"j3rr2*I5?.9ri16. II

FORM VI SV-1 1/87 Rev.420





Min RRF for SPCC(3) = 0.050 Max %RSD for CCC(*) - 30.0%

Lab File ID: RRF20 =>V3603 RRF50 =>V3605RRF30 =>V3604 RRF120=>V3602 RRF160=>V3601

COMPOUND

Dibenzofuran2 , 4-DinitrotolueneDie-hylphthalate4 -Chlorophenyl-phenyletherFluorene4-Nitroaniline4 , 6-Dinitro-2-rnethylphenol

RRF20

1.728.411

1.639.655

1.336

N-Nitrosodiphenylamine (1) * .5514-3romophenyl-phenyletherHexachlorobenz ene

.212

.220Pentachlorophenol *Phenanthrene•AnthraceneHDi-n-butylphthalate

1.1781.1391.730

Fluoranthene * 1.008PyreneButylbenzylphthalate3 , 3 ' -DichlorobenzidineSenzo (a) anthraceneChrysenebis (2-Ethylhexyl) phthalate

2.5331.430.297

1.3131.2732.123


1.5401.476

Benzo (a) pyrene * 1.282Indeno ( 1 , 2 , 3-cd) pyreneDibenz (a,h) anthracjsijeBen z o ( g , h , i ) peryl ens

Nitrobenzene-d52-FluorobiphenylTerphenyl-dl4Phenol-d62 -Fluorophenol2,4, 6-Tribromophenol

1.177.967.992

.5091.7761.8872.2771.428.201

RRF50

1.642.459

1.579.628

1.330.202.138.521.206.226.078

1.0661.0521.6081.0571.8321.151.218

1.1871.1611.6833.7261.4991.4851.3221.3331.1341.112

.4961.6861.4402.1521.444.239

RRF80

1.513.423

1.457.571

1.199.194.137.494.196.215.073.989.974

1.452.956

1.9571.141.183

1.1491.1521.5943.7691.5081.3761.2671.2431.0531.045

.4761.5601.5671.9721.392.220

RRF120

1.415.422

1.371.533

1.087.285.141.470.175.193.099.883.875

1.034.831

1.7701.034.249

1.0481.1161.3223.6131.4771.3301.2161.2371.0601.061

.4671.5281.5721.8851.322.235

RRF160

1.347.412

1.344.487

1.034.239.145.470.179.197.091.906.905

1.324.883

1.6751.000.249.988

1.0731.2553.5751.4501.2701.2321.2601.-0801.081

.4811.4211.4011.9371.294.213

RRF

1.529.426

1.488.575

1.207.242.140.501.194.210.087

1.004.989

1.440.947

1.9641.151.239

1.1371.1551.5963.7951.4951.3871.2641.2501.0591.058

sss ssssszss s ss

.4861.5941.5732.0441.376.221

f\ !™S 1 "7 I

RSD

10.34.59.711.912.521.22.56.9*8.46.8

12.3*12.010.919.79.7*17.114.717.711.16.521.77.6*2.36.73.3*4.55.74.2

=====3.48.712.18.04.87.1

oA n o u i / » -Cannot be separated from Diphenylamine


421

63SEMIVOLATILE ORGANICS INITIAL CALIBRATION DATA




Min RRF for S?CC(3) =• 0.050 Max %RSD for CCC(*) - 30.0%

Lab File ID: RRF20RRF30 >V3904 RRF12<

COMPOUND

Phenol 'bis (2-Chloroethyl) ether2-Chlorophenol1 , 3-Dichlorobenzene1, 4-Dichlorobenzene '3enzyl alcohol1, 2-Dichlorobenzene2 -Methy Iphenolbis (2-chloroisopropyl) ether4-MethylphenolN-Nitroso-di-n-propylamine 'HexachloroethaneNitrobenzeneIsophorone2-Nitrophenol •2 , 4-DimethylphenolSenzoic acidbis (2-Chloroethoxy) methane2 , 4 -Dichlorophenol ••1,2,4-TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene '4 -Chloro-3-methy Iphenol '2 -Me thy Inaphthal eneHexachlorocyclopentadiene- •2,4,6-Trichloropilsiibl ...*2,4, 5-TrichloroEJiij|£l2-Chloronaphtha£efiir2-NitroanilineDimethylphthalateAcenaphthylene2 , 6-Dinitrotoluene3-NitroanilineAcenaphthene •2 , 4 -Dinitrophenol =4-Nitrophenol •

=>V39o:)->V390:

RRF20

' 1.7861.7641.4531.571

" 1.638.713

1.5531.4034.4601.417

* 1.511.711.420.788

f .203.349

.525* .281

.3231.121.418

* .156fc .326

.650! .047* .334

1.163

1.5382.071.306

' 1.3311f

5I

RRF50

1.7721.6641.4011.5271.555.733

1.5391.2634.2251.3981.431.686.424.770.203.330.114.505.289.310

1.068.404.155.328.604.117.331.3551.131.479

1.4131.890.319.298

1.246.106.081

RRFfRRF]

RRF80

1.7011.5521.3321.4421.440.738

1.4191.2114.090I. 2911.381.663.407.747.200.316.153.483.275.305

1.014.410.148.318.586.162.330.368

1.083.486

1.3811.821.320.349

1.169.114.084

50 =>V3SL60=>V3S

RRF120

1.7681.5271.2831.3811.390.766

1.3631.1514.0081.2181.366.640.406.755.199.317.199.478.270.291.941.400.149.307.554.207.325.376

1.035.494

1.3251.723.313'.3531.102.153.097

?05301

RRF160

1.7561.4981.2721.3631.360.754

1.3421.1634.0251.2121.394.633.397.747.194.314.206.467.264.281.923.405.138.306.537.204.-327.361

1.024.491

1.3251.638.313.357

1.087.159A#3

RRF

1.7571.6011.3481.4571.477.741

1.4441.2394.1621.3071.417.663.411.762.200.325.163.492.276.302

1.013.407.149.317.586.147.329.365

1.087.487

1.3971.839.314.339

1.187.133

) I W*

%RSD=====

1.9*6.95.86.27.9*2.76.98.24.57.44.13

*•2W2.31.8*4.525.74.73.5*5.43.21.75.0*3.3*7-S-J

<5ST61.1*2.45.51.36.38.31.83.28.6*20.23Uj|


44



ab Code: LANCAS Case No.: 10699 SAS No.: SDG No.: CY753


Min RR? for S?CC(3) = 0.050 Max %RSD for CCC(*) - 30.0%

Lab File ID: RRF20 >V3903 RRF50 =>V3905RRF30 =>V3904 RRF120=>V3902 RRF160=>V3901

COMPOUND

Dibenzofuran2 , 4-DinitrotolueneDiethylphthalate4-Chlorophenyl-phenyletherFluorene4-Nitroaniline4 , 6-Dinitrc-2-:nethy Iphenol

RRF20

1.740.391

1.583.614

1.344

N-Nitrosodiphenylamine (1) * .5624 -Sroncphenyl-phenyletherKexachlorobenzene

.202

.203Pentachlorophenol *kPhenanthrener AnthraceneDi-n-butylphthalate

1.1131.1051.670

Fluoranthene * 1.011Pyrene3utylbenzylphthalate3,3' -DichlorobenzidineBenzo (a) anthraceneChrysenebis (2-Ethylhexyl)phthalate

2.2401.303.346

1.3511.2481.850


1.5341.543

Benzo (a) pyrene * 1.315Indeno ( 1 , 2 , 3 -cd) pyreneDibenz (a,h) anthr&cs ieBenzo (g/h, i) peryieire

Nitrobenzene-d52-FluorobiphenylTerphenyl-dl4Phenol-d62-Fluorophenol2,4, 6-Tribroiaophenol

1.137.937.964

.5711.7921.6982.5441.650.191

RRF50

1.591.424

1.486.572

1.225.258.132.527.190.206.073

1.0431.0261.540.980

1.9321.146.269

1.2921.2371.5663.1531.4311.3941.2341.2981.0851.116

.5591.6291.4912.4021.612.205

RRF80—.I • n i II.- —

1.526.426

1.431.546

1.175.273.138.507.182.202.085

1.006.993

1.576.932

1.8841.118.270

1.2041.1971.5383.1291.4201.3581.2401.2891.0941.082

.5541.6021.5262.2611.556.213

RRF120

1.415.398

1.324.488

1.038.307.143.490.180.183.102.952.933

1.407.366

2.0421.145.331

1.2491.1781.5663.5361.5181.3101.2511.2281.0351.040

.5471.5731.6422.1631.493.203

RRF160=====1.398.410

1.332.492

1.039.325.147.492.172.188.097.936.943

1.312.861

1.8411.083.340

1.2421.1821.4783.1471.4501.3311.2831.3381:1451.135

.5291.5121.5012.1441.424.195

RRF

1.534.410

1.432.542

1.164.291.141.516.185.199.089

1.0111.0001.501.930

1.9831.160.311

1.2671.2081.6003.3451.4701.3871.2751.2581.059.1.067

.5521.6221.5722.3031.547.201

RSD

9.13.87.79.9

11.210.65.25.8*6.14.9

14.4*7.27.09.47.2*8.07.212.44.42.79.08.6*3.56.72.3*6.27.46.4

2.86.55.97.35.94.2

Cannot be separated from Diphenylamine —•• —-


7BS2MIVOLATILE CONTINUING CALIBRATION CHECK


Lab Code: LANCAS Case,No.: 10699 SAS No.: SDG No.: CY753


Lab File ID: >V3651 Init. Calib. Date(s): 11/07/88

Min RRF50 for S?CC(3) - 0.050 Max %D for CCC(*) « 25.0%

COMPOUND

Phenol •>bis (2-Chloroethyl) ether2-ChlorophenolI f 3-Dichlorobenzene

RRF

' 1.5001.4981.3131.419

1,4-Dichlorobenzene * 1.463Benzyl alcohol1 , 2-Dichlorobenzene2 -Methylphenolbis (2-chloroisopropyl) ether4 -Methylphenol

.6261.4311.1773.3211.203

N-Nitrosc-di-n-propylamine 3 1.320KexachloroethaneNitrobenzeneIsophorone

. 655

.362

.7122-Nitrophenol * .1982 , 4-DimethylphenolBenzoic acidbis (2-Chloroethoxy) methane

.308

.151

.4612 , 4-Dichlorophenol * .2761,2, 4-TrichlorobenzeneNaphthalene4-Chloroaniline

.309

.951

.393Hexachlorobutadiene * . 1584-Chloro-3-methylphenol * .3122 -Methy Inaphthal ene .588Hexachlorocyclopentadiene 3 .1792 , 4 , 6-Trichlorophenol * .3202 , 4-jy5>grichl6rophenol2 -CKiCgronaphthalene2-N_giiSanilineDimethylphthalateAcenaphthylene2 , 6-Dinitrotoluene3 -Nitroaniline

.3681.052.428

1.4141.770.327.262

Acenaphthene * 1.1682 , 4 -Dinitrophenol 3 .1424-Nitrophenol •. .088

RRF50

1.6341.6501.4001.5351.570.667

1.5221.2374.0861.2521.400.678.400.760.201.316.120.481.297.325

1.004.400.177.330.602.192.353.388

1.142.469

1.4811.868

• .342.199

1.245.095.077

%D

8.9*10.16.28.27.4*6.56.35.16.94.06.133.510.46.81.9*2.620.44.47.4*5.35.61.911.8*5.9*2.3|7.5|10.5*5.48.69.44.75.54.624.1JL-fr*§_$__$£12.4$

———— fl-D

S

ftff30!7l6

FORM VII SV-1 1/87 Rev

7CSEMIVOLATILE CONTINUING CALIBRATION CHECK




Lab File ID: >V3651 Init. Calib. Date(s): 11/07/88

Min RRF50 for S?CC(#) = 0.050 Max %D for CCC(*) » 25.0%

COMPOUND

Dibenzofuran2 , 4-DinitrotolueneDiethylphthalate4-Chlorophenyl-phenyletherFluorene4-Nitroaniline4 , 6-Dinitro-2-methylphenol

RRF

1.529.426

1.438.575

1.207.242.140

N-Nitrosodiphenylamine (1) * .5014 -Sromophenyl-phenyletherKexachlorobenzene .

.194

.210Pentachlorophenol * .087PhenanthreneAnthraceneDi-n-butylphthalate

1.004.989

1.440Fluoranthene * .947PyreneButylbenzylphthalate3,3' -DichlorobenzidineBenzo (a) anthraceneChrysenebis(2-Ethylhexyl)phthalate

1.964"1.151

.2391.1371.1551.596


1.4951.387

Benzo (a) pyrene * 1.264Indeno (1,2,3 -cd) pyreneDibenz (a , h) anthraceneBenzode^h, i)perylene

NitxSJN&izene-dS-2-FluorobiphenylTerphenyl-dl4Phenol-d62-Fluorophenol2,4, 6-Tribromophenol

1.2501.0591.058

.4861.5941.5732.0441.376

.221

RRF50

1.621.454

1.522.656

1.331.246.142.510.208.246.086

1.0561.0441.5951.0061.9991.132

.2171. 2141.1761.5763.4351.4661.3911.2651.2991.1121.116

.5081.6751.5862.2061.473

.272

%D

6.06.62.3

14.210.31.71.61.7*7.317.0

.4*5.15.6

10.86.3*1.81.69.36.81.81.39.5*1.9.3.1*

3.95.05.5

4.65.1.87.97.0

22.9

(1) Cannot be separated from DiphenylamineRR301717.

FORM VII SV-2 1/87 Rev,

SOIL PESTICIDE SURROGATE RECOVERY \

Lab Name: LANCASTER LABS • Contract: 68-W8-0055


Level: (low/med) MED •

0102030405

EPASAMPLE NO.

PBLKM1 "•" ——CY767CY753MSCY753MSDCY753

SI(DBG) 3

-*rT0 *0 *0 *0 *

OTHER

. .

.._ .. ,.

ADVISORYQC LIMITS

SI (DBG) « Dibutylchlorendate (20-150)

3 Column to be used to flag recovery values

* Values outside of QC limits

D Surrogates diluted out

page 1 of 1FORM II PEST-2 1/87

•%

AR30I7.18- - ' - - - - " 6 1

3FSOIL PESTICIDE: MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Lab Name: LANCASTER LABS Contract; 63-W8-0055

,Lab Code: LANCAS Case No.: 10699 SAS No.: SDG No.: CY753

Matrix Spike - EPA Sample No.: CY753 Level: (low/med) MED

COMPOUND

gamma-BHC (Lindane)HeptachlorAldrinDieldrinZndrin4,4' -DOT

SPIKEADDED(ug/Kg)

226.195.190.843.547.576.

SAMPLECONCENTRATION

(ug/Kg)0.0.0.0.0.

414.

MSCONCENTRATION

(ug/Kg)

119.198.150.741.315.936.

MS

REG 3

5310279875891

QCLIMITSREG.

46-12735-13034-13231-13442-13923-134

COMPOUND

gamma~3HC (Lindane)HeptachlorAldrinDieldrinEndrin4,4'-DDT

SPIKEADDED(ug/Kg)

226.195.190.848.547.576.

MSDCONCENTRATION

(ug/Kg)

195.139.117.923.493.1253.

MSD%

REG 3

86716210990146 *

%RPD 3

-4736 *24 .-22-43-46

QC LIRPD

503143384550

EMITSREC.

46-12735-13034-13231-13442-13923-134

.

3 Column to be use;di;to flag recovery and RPD values with an asterisk

* Values outside";W QC limits

RPD: 1 out of 6 outside limitsSpike Recovery: 1 out of 12 outside limits

COMMENTS!

RR30I719FORM III PEST-2 - - 8/87"Rev.

• 3D /SOIL SEMIVOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY L ~

Lab Name: LANCASTER LABS Contract: 6S-W8-0055


Matrix Spike - EPA Sample No.: CY760 Level: (low/med) LOW

COMPOUND

Phenol2-Chlorophenol-.1, 4-DichlorobenzeneN-Nitroso-di-n-prop. (1)1,2, 4-Trichlorobenzene4-Chloro-3-methylphenolAcenaphthene4 -Nitrophenol2 , 4-DinitrotoluenePentachlorophenolPyrene

SPIKE. ADDED(ug/Kg)

1700017000360036003600170008600170008600170008600

SAMPLECONCENTRATION

(ug/Kg)

00000000000

MSCONCENTRATION

(ug/Kg)s i "i" ,m ™ jsssm s im.s si~rrrrsf

1300012000630062006300130006200190007400230009700

MS%

REG 3•»sa »!Mayig'B5g

7671737279767211236

' 135 *113

QCLIMITSREG.=====26- 9025-10228-10441-12638-10726-10331-13711-11428- 8917-10935-142

COMPOUND

Phenol2-Chlorophenol1 , 4-DichlorobenzeneN-Nitroso-di-n-prop. (1)1,2, 4-Trichlorobenzene4 -Chloro-3 -methy IphenolAcenaphthene4 -Nitrophenol2 , 4-DinitrotoluenePentachlorophenolpyrene dm

SPIKEADDED(ug/Kg)

1700017000860086008600170008600170008600170008600

MSDCONCENTRATION

(ug/Kg)

1200011000560058006200120006100190007200240009700

MSD%

REG 3

7165656772717111284141 *113

%RPD 3

7912797102 *-4. 0

QC L]RPD

355027382333 .1950474736

EMITSREG.

26- 9025-10228-10441-12638-10726-10331-13711-11428- 8917-10935-142

(1) N-Nitroso-di-n-propylamine3 Column to be used to flag recovery and RPD values with an asterisk* Values outside of QC limits


COMMENTS:ftR3Ql720

FORM III SV-2 1/87 Rev.

2DSOIL SEMIVOLATILE SURROGATE RECOVERY j

Lab Name: LANCASTER LABS Contract: 6S-W8-0055


Level:(low/med) MED

01020304050607080910

EPASAMPLE NO.

SBLKM1SBLKM2CY753 •CY753MSCY753MSDCY753DLCY753MSDLCY753MSDDLCY767CY767DL

SI(NBZ) *

80755649350 D0 D0 D5136

S2(FBP) 3

78786254480 D0 D0 D5564

S3(TPH) I

11812110084810 D0 D0 D91115

S4(PHL)3

79765454390 D0 D0 D4745

S5(2FP)3

79745356380 D0 D0 D5035

S6(TBP) 3

85765870670 D0 D0 D5725

OTHER TOTOUT

0000000000

QC LIMITSSI (NBZ) = Nitrobenzene-d5 (23-120)S2 (F3P) = 2-Fluorobiphenyl (30-115)S3 (TPH) = Terphenyl-dl4 (18-137)S4 (PHL) = Phenol-d6 (24-113)S5 (2FP) = 2-Fluorophenol (25-121)S6 (TBP) = 2,4,6-Tribromophenol (19-122)

3 Column to be used to flag recovery values* Values outside of contract required QC limitsD Surrogates diluted out

, , , AR30I72Ipage 1 of 1 - - ...FORM II SV-2 1/87 Rev.

18 o

20SOIL SEfilUOLfiTILE SURROGATE RECOVERY

Lib Name'LANCASTER LfiES Contracts63-U8-0055

Lab Code'LANCAS Case No.sl0699 SAS No.*____. SDG No.*CY753

Leuel s ( lou/rned) MED

010203040506070809101112131415161718192021222324252627282930

EPflSAMPLE NO.

SSLP;MISBLKM2CY753CY753MS '-CY753MSDCY753DLCY753MSOLCY753MSOOLCY767CY767DL

SI(NBZ)#)—— ——80.75,56.49.35.0. D0. D0. D

51 .36.

S2(FBP)#n =. = = =: =

78.78.62.54.43.0. D0. 00. D

55.64.

S3 |(TPH)#

118.121.100.84.81 .0. D0. D0. D

91 .115.

_____

' 54(PHL)#

79.76.54.54.39.0. D0. D0. D

47.45.

S5(2FP)#|

79."74.58.56.38.0. 00. D0. D

50.35.

S6(TBP)#3S3S«85.76.58.70.67.0. D0. D0. D

57.25.

OTHER TOTOUT

0000000000

.js-r QC LIMITSSI (HB g- N.trobensene-dS (23-120)S2 (FBF^fe2-Fluorobiphcnyl (30-115)S3 (TPfr>^-?Terphenyl-dl4 (18-137)S4 (PHL) - Phenol-d6 (24-113)35 (2FP) * 2-Fluorophenol • (25-121)56 (TEP) = 2,4,6-Trifaromopihenol (19-122)

# Column to be used to flag recovery ualues* Values outside of contract required QC limitsD Surrogates diluted out «*»3QI722

page 1 of 1FORM II SV-2 1/87 Reu.

a0

2DSOIL SEniUOLftTILE SURROGATE RECOUERY

L.ib Hdmes LANCASTER LhES Cent r act: 63-U5-0055

Cade«LAHCAS . Case No.:10699 SAS No.x____. SDG No.*CY753

el : ( lou/rned) MED

01020304050607080910111215141516171S19202122232425262?2829

EPftSAMPLE NO.

SELKM1SBLKM2CY753CY753MS ;CY753MSDCY753DLCY75~3MSDLCY753MSDOLCY767 'CY767DL

SI(NBZ)S

80.75.56.49.35.

• 0. D0. D0. D

51 .56.

S2

73.78.62.54.48.

. 0. D0. D0. D

55.64.

S3(TPH)#««« =118.121.100.84.81 .0. D0. D0. Q

91 .1 15.

S4

79.76.54.54.39.0. D0. D0. D

47.45.

S5

79." 74.58.56.38.0. D0. D0. D

50.35.

S6(TSP)S

85.76;58.70.67.0. D0. D0. D

57.25.. •

OTHER

m

TOTOUT

0000000000

_._ ' QC LIMITSSI (NE|-)« Nitrcbensene-G'5 (23-120)52 (FEJl||i 2-F]uorobiphenyl (30-115)S3 (TP'flf P Terphenyl-dl4 (18-137)S4 (PHL) - Phenol-d6 (24-113)55 (2FP) - 2-Fluorophenol (25^121) '56 (TBP) - 2,4,6-Tr i br or.iop.-heno 1 (19-122)

& Column to be used to flag recovery value?-* Ualues outside of contract required QC limitsD Surrogates diluted out

AR301723paqe 1 of 1

FORM II SU-2 • 1/87 F'eu

185

3DSOIL SEMIVOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY



Matrix Spike - EPA Sample No.: CY753 Level:(low/med) MSD

COMPOUND

Phenol2-Chlorophenol".1 , 4-DichlorobenzeneN-Nitroso-di-n-prop. (1)1,2, 4-Trichlorobenzene4 -Chloro-3 -methylphenolAcenaphthene4 -Nitronhenol2 , 4-DinitrotoluenePentachlorophenolPyrene

. SPIKE•ADDED(ug/Kg)

250000250000120000120000120000250000120000250000120000250000120000

SAMPLECONCENTRATION

(ug/Kg)

00000000000

MSCONCENTRATION' (ug/Kg)

1800001900007300090000780001800009700019000093000210000 '160000

MS*REG |

72766175657281767884133

QCLIMITSREC.

26- 9025-10228-10441-12638-10726-10331-13711-11428- 8917-10935-142

COMPOUND

Phenol2-Chlorophenol1 , 4-DichlorobenzeneN-Nitroso-di-n-prop. (1)1,2,4 -Tr ichl or obenz ene4 -Chl or o-3 -methylphenolAcenaphthene4 -Nitrophenol2 , 4-DinitrotoluenePentachlorophenolPyrene . Ill

SPIKEADDED(ug/Kg)

250000250000120000120000120000250000120000250000120000. 250000120000

MSDCONCENTRATION

(ug/Kg)

1300001300005000061000620001700009000019000087000180000150000

MSD%

REC £

52524251526875767372125

%RPD %======323837 *3822680715.6

— wQC LIMITSRPD

355027382333 -1950474736

REC.======26- 9025-10228-10441-12638-10726-10331-13711-11428- 8917-10935-142

(1) N-

£ Column to be used to flag recovery and RPD values with an asterisk* Values outside of QC limits


COMMENTS: All matrix spike / matrix spike dupilcate comj&ifrwifi bl&feed oui

FORM III SV-2 1/87 Rev.

18C

ID '• EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET


j|ab Code: LANCAS Case No.: 10699 SAS No.: SDG No.: CY753


Sample wt/vol: 1.0 ' (g/aL) G Lab File ID: A88316 020.RES

Level: (low/aed) MZD • • Date Received: 10/29/88



GPC Cleanuo: (Y/N) N pH:6.9 Dilution FactorJrTO" .5

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/KG

•71 Q_G ~_"7__

53-89-9 ———76-44-3 ———3na_nn_"5— _1024-57-3-QCQ_QQ_O__

60-57-1 ——72-55-9 ——

33213-65-9"7 *} C y* O

1031-07-8-

72-43-5 ——53494-70-55103-71-9-5103-74-2-8001-35-2-12674-11-211104-28-2

12672-29-6

———— alsha-BKCT-i r*i i T3T-"f*-"G WCt wi_w

————— delta-3HC———— gamsa-BHC (Lindane)———— Heotachlor————— Aldrin————— Heptachlor epoxide———— Endosulfan I————— Dieldrin———4 4'-nn'Fi / i-si~t±*

———— Endrin———— Endosulfan II

** / *t *JLJL>

———— Endosulfan sulfate

———— Methoxychlor———— Endrin ketone———— alpha-Chlordane———— gamma-Chlordane———— Toxaphene———— Aroclor-1016rMiiM. — Aroclor-12 21t&.-jtiii, — Aroclor-12 3 2ssasfe— Aroclor-12 4 2—— •-' — Arocl or-12 4 8

11097-69-1 ———— Aroclor-125411096-82-5———— Aroclor-12 60

690.690.

690.690.690.690.690.130.1400.1400.1400.'1400.1400.1400.6900.1400.6900.6900.14000.6900.6900. .6900*.6900.6900.14000.4300.

UXuxuxuxuxuxuxuxJuxuxuxuxuxuxTJX •uxuxuxUXUXuxuxTJXJ

FORM I PEST

8EPESTICIDE EVALUATION STANDARDS SUMMARY

Evaluation of Retention Time Shift for Dibutylchlorendate


Lab Code: IANCAS Case No.: 10699 SAS No.: SDG No.: CY753

Instrument ID: HP5890 12B GC Column ID: OV-101 CON

Dates of Analyses: 11/11/83 to 11/14/88

1234567391011121314151617181920212223242526272829303132333435363738

EPASAMPLE NO.

EVALAEVALBEVAL'CINDAINDBTOXAPHAR1660AR1221AR1232AR1242AR1248AR1254P3LKM1CY767ZZZZZCY753MSZZZZZEVALBCY753MSDZZZZZCY753ZZZZZZZZZZINDAZZZZZZZZZZZZZZZZZZZZEVALBZZZZZ *,

W? _/fl£«y£Ek£*£*£* fijrvij— Ti— „

zzzzfSSljZZZZZINDBZZZZZZZZZZZZZZZ

LAB SAMPLEID

= _ -=; =j==:-:.=.-iTrz===

EVALAEVALBEVALC178A-88-2DF1178B-88-2DF1TOXAPHENE ( 1 .1016/1260(.21221(0. 326NG1232(0. 314NG1242(0. 303NG1248(0. 277NG1254(0. 303NG3LK(ll/08/881323247HEXANE1323239DF10HEXANEEVALB1323240DF10HEXANE1323238DF10HEXANEHEXANE178A-88-2DF11323239DF1001323240DF1001323238DF100HEXANEEVALBBLK( 11/7/8 8)BLK( 11/7/8 8)132495813249591324957178B-88-2DF1132495613249601324961

DATEANALYZED

11/11/8811/11/8811/11/8811/11/8811/11/8311/11/8811/11/8311/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/3811/12/8311/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/88 -11/12/8811/12/8811/12/88

TIMEANALYZED

20:0820:4521:2221:5922:3623:1423:5100:2801:0501:4202:2002:5703:3404:1104:4805:2606:0306:4007:1707:5408:3209:0909:4610:2311:0111:3812:1512:5213:3014:0714:44 '15:2115:5916:3617:1317:5018:2719:05

%D

0.00.19.04.11.04.04.23.23.38.54.50.31

0.00

.08

0.00.11

.08

.08

.15

.08

0.00.04.11

• .08.19.27.19.04.04

0.00.23

*

*

*

*

*

•***

* Values outside of QC limits (2.0% for packed coltmms- , -, 0-0.3% for capillary columns) HnoUj /26

page 'l of 2FORM VIII PEST-2 1/87 REV.

7;

8EPESTICIDE EVALUATION STANDARDS SUMMARY

Evaluation of Retention Time Shift for Dibutylchlorandate



Cnstrument ID:.HP5390 12A GC Column ID: 2401/2250

Dates of Analyses: 11/11/83 to 11/14/88

t

1234567391011121314151617181920212223242526272329303132333435363738

EPASAMPLE NO.

EVALAEVALBEVAicINDAINDBTOXAPHAR1660AR1221AR1232AR1242AR124SAR1254P3LKM1CY767ZZZZZCY753MSZZZZZEVALBCY753MSDZZZZZCY753ZZZZZZZZZZINDAZZZZZZZZZZZZZZZZZZZZEVALBZZZZZZZZZZlSSS:zzzzsi fg:Z Z Z Zsw S""-ZZZZZ ~"INDBZZZZZZZZZZZZZZZ

LAB SAMPLEID

EVALAEVALBEVALC178A-83-2DF1178B-S3-2DF1TOXAPHENE(1.1016/1260(.21221(0. 326NG1232(0. 314NG1242(0. 303NG1248(0. 277NG1254(0. 303NGBLK(ll/08/881323247HEXANE1323239DF10HEXANEEVALB1323240DF10HEXANE1323238DF10HEXANEHEXANE178A-88-2DF11323239DF1001323240DF1001323238DF100HEXANEEVALBBLK( 11/7/8 8)BLK(ll/7/88)132495813249591324957178B-88-2DF1132495613249601324961

DATEANALYZED

11/11/8811/11/8811/11/8811/11/8811/11/8311/11/3311/11/3811/12/8811/12/8811/12/8811/12/8311/12/8311/12/8311/12/8311/12/8311/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/8811/12/88 .11/12/8811/12/8811/12/88

TIMEANALYZED

20:0820:4521:2221:5922:3623:1423:5100:2801:0501:4202:2002:5703:3404:1104:4805:2606:0306:4007:1707:5408:3209:0909:4610:2311:0111:3812 : 1512:5213:3014:0714:44"15:2115:5916:3617:1317:5018:2719:05

%D

0.00.04.04.04.40.04.24.32.32.52.48.24.08

.16

.23

.16

0.00

.12

.04

.24

0.00.08

0.00.08.08.04.04.91.48.24.28

*

*

*

*

*

•***

* Values outside of QC limits (2.0% for'packed columns,0.3% for capillary columns)

ge '1 of 2 ftR30i727FORM VIII PEST-2 "" " " 1/87 REV.

. 724

1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET ___________

Lab Name: LANCASTER LABS Contract: 68-W8-0055VBLK01


Matrix: (soil/water) SOIL Lab Sample ID: ABLKNO1

Sample wt/vol: 5.0 (g/mL) G Lab File ID: ABLKNO1





74-87-3————————Chlorcmethane_74-83-9 ———————Brcmomethane__75-01-4———————Vinyl Chloride,75-00-3 ———————Chloroethane75-09-2———————Methylene Chloride,67-64-1————————Acetone____________75-15-0———————Carbon Disulfide__75-35-4———————l,l-Dichloroethene_75-34-3———————1,1-Dichloroethane"540-59-0———————1,2-Dichloroethene (total)_67-66-3————————Chloroform107-06-2——————1,2-Dichloroethane____78-93-3————————2-3utanone______________71-55-6———————1,1,1-Trichloroethane__56-23-5———————Carbon Tetrachloride__108-05-4——————Vinyl Acetate________75-27-4———————Bromodichloromethane_____78-87-5———————1,2-Dichloropropane___10061-01-5————cis-l,3-Dichloropropene_79-01-6———————Trichloroethene124-48-1——————Dibromochloromethane_79-00-5———————l,l,2-Trichloroethane_71-43-2—————:—Benzene_____

75-25-2——*~s-£=s—Bromoformtrans-1,3-Dichloropropene__

108-10-1—* gp?-4 -Methyl-2 -Pentanone_591-78-6————---2-Hexanone127-18-4——————Tetrachloroethene______79-34-5———————1,1,2,2-Tetr a chloroethane_108-88-3——————Toluene108-90-7——————Chlorobenzene_100-41-4 ——————Ethylbenzene_100-42-5——————Styrene_____1330-20-7————:—Xylene (total).

101010101255555535510555555

' 5' 5-51010555555

UUUuJJuuuuuuJuuuU 'uuuuuuuuuuuuuuuuB172 8

FORM I VOA 1/87 Rev.

. . 141


VBLK01Lab Name: LANCASTER LABS Contract: 68-W8-0055


Matrix: (soil/water) SOIL Lab Sample ID: ABLKN01

Sample wt/vol: 5.0 (g/mL) G Lab File ID: ABLKNO1

Level: "(low/med) LOW ' Date Received:" 10/29/88


Column: (pack/cap1) PACK Dilution Factor: 1.00



*

AR30I729FORM I VOA-TIC " "1/87 Rev.

142

1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET



Matrix: (soil/water) SOIL Lab Sample ID: A3LKNOV1

Sample wt/vol: 5.0 (g/mL) G Lab File ID: ABLKNOV1


% Moisture: not dec. Date Analyzed: 11/01/88 •



74-37-3———————Chloromethane_74-83-9————————Bromomethane__75-01-4————————Vinyl Chloride,75-00-3————————Chloroethane75-09-2———————Methylene Chloride,67-64-1———————Acetone__________________75-15-0———————Carbon Disulfide__________75-35-4———————1,1-Dichloroethene_________75-34-3———————1,1-Dichloroethane________540-59-0——————1,2-Dichloroethene (total)_67-66-3———————Chloroform107-06-2——————l,2-Dichloroethane_73-93-3———————2-Butanone71-55-6———————1,1, l-Trichloroethane_56-23-5———————Carbon Tetrachloride_J108-05-4——————Vinyl Acetate75-27-4———————Bromodichloromethane_78-87-5———————l,2-Dichloropropane_10061-01-5————cis-l,3-Dichloropropene_79-01-6———————Trichloroethene124-48-1——————Dibromochloromethane_____79-00-5———————l,l,2-Trichloroethane_71-43-2———ssSgg— Benzene10061-02-6< t;S|f-trans-l, 3-Dichloropropene75-25-2 ——108-10-1——--Sii-4 -Methyl-2 -Pentanone_591-78-6——————2-Hexanone127-18-4——————Tetrachloroethene79-34-5———————1,1,2,2-Tetrachloroethane_108-88-3——————Toluene108-90-7——————Chlorobenzene_100-41-4——————Ethylbenzene_J100-42-5——————styrene_1330-20-7——————Xylene (total).

10 U10 U10 U10 U1 J10 U5 U5 U5 U5 U5 U5 U10 U5 U5 U10 U5 U5 U5 U5 U5 U

. 5 U5 U5 U '5 U10 U10 U5 U '5 U5 U5 U

iR:fti7$0B - U


153


Lab Naae: LANCASTER LABS Contract: 68-W8-0055VBLK02


Matrix: (soil/water) SOIL Lab Sample ID: ABLKNOV1

Sample wt/vol: 5.0 (g/mL) G Lab File ID: ABLKNOV1

Level: (low/med) LOW_ • _ Date Received: 10/29/88

% Moisture: not dec. Date Analyzed: ll/Oi/88



GAS NUMBER COMPOUND NAME RT EST. GONG. Q

FORM I VOA-TIC AR3Q j 7 3/J87 Rev

1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET _______



Matrix: (soil/water) WATER Lab Sample ID: ABLKN02

Sample wt/vol: 5.0 (g/mL) ML Lab File ID: ABLKNO2




CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L ' Q

74-37-3 ———————Chloromethane_74-83-9———————Bromomethane__75-01-4———————Vinyl Chloride75-00-3———————Chloroethane75-09-2————————Methyl ene Chloride_______67-64-1————————Acetone_____________________75-15-0————————Carbon Disulfide_____________75-35-4———————1,1-Dichloroethene______75-34-3———————1,1-Dichloroethane___________540-59-0——————1,2-Dichloroethene (total).67-66-3———————Chloroform107-06-2——————1,2-Dichloroethane____78-93-3———————2-3utanone_____________71-55-6———————1, l, l-Trichloroethane_56-23-5———————Carbon Tetrachloride__108-05-4——————Vinyl Acetate________75-27-4———————Bromodichloromethane_____78-87-5———————1,2-Dichloropropane___10061-01-5————cis-l,3-Dichloropropene_79-01-6———————Trichloroethene124-48-1——————Dibromochloromethane_79-00-5——T Sgr*" l/l/-2-Trichloroethane_71-43-2——'r &Sr- Benzene

75-25-2———--- --Bromoformtrans-1,3-Dichloropropene_

108-10-1——————4-Methyl-2-Pentanone_591-78-6——————2-Hexanone127-18-4——————Tetrachloroethene79-34-5———————1,1,2,2-Tetrachloroethane_108-88-3——————Toluene108-90-7——————Chlorobenzene100-41-4———————Ethylbenzene_J100-42-5——————Styrene_1330-20-7——————Xylene (total).

10101010510555555105510555555555101055555

ARSO

uuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuW32


* - \

IE EPA SAMPLE NOVOLATILE ORGANICS ANALYSIS DATA SHEET ______________TENTATIVELY IDENTIFIED COMPOUNDS

.Lab Name: LANCASTER LABS Contract: 68-W8-0055VBLK03


Matrix: (soil/water) WATER Lab Sample ID: ABLKNO2

Sample wt/voiU __5*° •(9/mIjL_Ml1 Lab File ID: ABLKNO2Level: , (low/aed) - LOW - Date Received: 10/29/88

% Moisture: not dec. -•—••• - Date Analyzed: 11/02/88

Column: (pack/ cap) PACK Dilution Factor: 1.00


CAS NUMBER COMPOUND NAME RT EST. GONG. Q

AR30I733FORM I VOA-TIC 1/87 Rev.

1.6.1

sIB EPA SAMPLE NO.

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _____________

Lab Name: LANCASTER LABS Contract: 68-W8-0055SBLKM2


Matrix: (soil/water) SOIL Lab Sample ID: MEDBLK2



% Moisture: not dec. 0. dec. Date. Extracted: 11/03/88




108-95-2——————Phenol_______________111-44-4——————bis (2-Chloroethyl) ether95-57-3————————2-ChloroDhenol541-73-1——————l,3-Dichlorobenzene_106-4 6-7———————1, 4-Dichlorobenzene_100-51-6———————3enzyl alcohol_____95-50-1———————1,2-Dichlorobenzene95-48-7———————2-Methy Iphenol108-60-1——————bis (2-Chloroisopropyl) ether_106-44-5——————4-Methy Iphenol621-64-7——————N-Nitroso-di-n-propylamine_67-72-1———————Hexachloroethane_______________98-95-3———————Nitrobenzene_____________78-59-1———————Isophorone88-75-5———————2-Nitrophenol____105-67-9——————2,4-Dimethylphenol_65-85-0———————Benzoic acid111-91-1——————bis (2-Chloroethoxy) methane_120-83-2——————2,4-Dichlorophenol120-82-1——————l,2,4-Trichlorobenzene_91-2 0-3 -——-33T—Naphthalene________~106-47-8—— 4-Chloroaniline__________87-68-3——3»BfesE?—Hexachlorobutadiene59-50-7—— s .-4 -Chloro-3 -methy Iphenol91-57-6———————2-Methylnaphthalene_77-47-4———————Hexachlorocyclopentadiene_88-06-2———————2,4,6-Trichlorophenol95-95-4———————2,4,5-Trichlorophenol___91-58-7———————2-Chloronaphthalene_______83-74-4———————2-Nitroaniline131-11-3 ——————Dimethylphthalate_208-96-8——————Acenaphthylene_606-20-2——————2, 6-Dinitrotoluene

200002000020000200002000020000200002000020000200002000020000200002000020000200001000002000020000200002000020000'2000020000200002000020000100000200001000002000200020000

UUUUUUUUUuuuuuuuuuuuuuuuuuuuuu

7vu


565






Level: (low/aed) MED Date Received: 10/29/88

% Moisture: not dec. 0. dec. Date Extracted: 11/03/88

Extraction: (Sepf/Cont/Sonc) SONC Date Analyzed: 11/10/88



99-09-2———————3-Nitroaniline_83-32-9———————Acenaphthene,51-28-5———————2, 4-Dinitrophenol100-02-7 —————— 4-Nitrophenol____132-64-9———————Dibenzofuran121-14-2 ——————— 2 , 4-Dinitrotoluene84-66-2————————Diethylphthalate_~7005-72-3—————4-Chlorophenyl-phenylether_86-73-7———————Fluorene100-01-6——————4-Nitroaniline_________534-52-1——————4, 6-Dinitro-2-methylphenol_86-30-6———————N-Nitrosodiphenylamine (1)]101-55-3——————4-3romophenyl-phenylether_]118-74-1——————Hexachlorobenzene_______87-86-5———————Pentachlorophenol_______85-01-8———————Phenanthrene____________120-12-7——————Anthracene__84-74-2————————Di-n-butylphthalate_206-44-0——————Fluoranthene_____~129-00-0——————Pyrene,85-68-7——-Sg£—Butvlbenzvlphthalate91-94-1——i sfe—3,3 '-Dichlorobenzidine_56-S5.-3—— —Benzo (a) anthracene218-01-9——•--i- —Chrysene_117-81-7——————bis (2-Ethylhexyl) phthalate117-84-0——————Di-n-octylphthalate_____"205-99-2——————Benzo (b) f luoranthene________207-08-9——————Benzo (k) f luoranthene________50-32-8———————Benzo(a)pyrene_193-39-5——————Indeno (1, 2, 3-cd) pyrene_53-70-3———————Dibenz(a,h)anthracene___191-24-2——————Benzo (g,h,i)perylene___

100000200001000001000002000020000200002000020000100000100000200002000020000100000200002000020000200002000020.0004000020000200002000020000200002000020000200002000020000

Uuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuu

(1) - Cannot be separated from Diphenylamine Aft 3u t 735


566

IF EPA SAMPLE NOSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _________

TENTATIVELY IDENTIFIED COMPOUNDS




Sample wt/vol: 1.0 (g/mL) G Lab File ID: >E3800 .

Level: .(low/med) MED ' i •' Date Received: 10/29/88

% Moisture: not dec. 0. dec. Date Extracted:'11/03/88





AR30I736.• • . - - • - - - . —


13 ' EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ___________

S3LKL3Lab Name: LANCASTER LABS Contract: 68-W8-0055

4feb Code: LANCAS Case No.: 10699 SAS No.: SDG No.: CY753

Matrix: (soil/water) SOIL Lab Sample ID: LOWBLK3

Sample wt/vol: 30.0 (g/mL) G • Lab File ID: >E3654






9

108-95-2———————Phenol________________111-44-4———————bis (2-Chloroethyl) ether95-57-3———————2-ChloroDhenol__541-73-1——————l,3-Dichlorobenzene_106-46-7——————1, 4-Dichlorobenzene_100-51-6——————Benzyl alcohol____"95-50-1———————1,2-Dichlorobenzene95-48-7———————2-Methylphenol108-60-1——————bis (2-Chloroisooropyl) ether106-44-5——————4 -Methylphenol__________~621-64-7——————N-Nitroso-di-n-propylamine__67-72-1————————Hexachloroethane__________98-95-3————————Nitrobenzene______________78-59-1———————Isophorone_88-75-5———————2-Nitrophenol______________105-67-9——————2,4-Dimethylphenol_______65-85-0———————Benzoic acid________________________111-91-1——————bis (2-Chloroethoxy) methane_____120-83-2——————2,4-Dichlorophenol120-82-1——————1,2/4-Trichlorobenzene91-20-3————-—Naphthalene,106-47-8—îsigg—4-Chloroaniline_______87-68-3——"-Js rSi—Hexachlorobutadiene59-50-7——-rsg —4-Chloro-3-methylphenol91-57-6—————-—2-Methylnaphthalene_77-47-4———————Hexachlorocyclopentadiene_88-06-2———————2,4,6-Trichlorophenol95-95-4———————2,4,5-Trichlorophenol91-58-7———————2-Chloronaphthalene______________88-74-4———————2-Nitroaniline__________131-11-3——————Dimethylphthalate

-96-8——————Acenaphthylene_606-20-2——————2 / 6-Dinitrotoluene_

670670670670670670670670670670670670670670670670330067067067067057067067067067067033006703300670670

Uuuuuuuuuuuuuuuuuuuuuuuuuuuuuuu

P7iiFORM I SV-1 1/87 Rev.

55

1C ' EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ____________

SBLKL3Lab Name: LANCASTER LABS Contract: 68-W8-0055



Sample wt/vol: 30.0 ' (g/mL) G Lab File ID: >E3654





CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or Ug/Kg) UG/KG Q

99-09-2———————3-Nitroaniline_8 3 -32-9 ———————Acenauhthene51-28-5————————2 , 4-Dinitrophenol100-02-7——————4-Nitrophenol___~132-64-9——————Dibenzofuran121-14-2——————2,4-Dinitrotoluene84-66-2———————Diethylphthalate7005-72-3—————4-Chlorophenyl-phenylether86-73-7———————Fluorene_______________100-01-6——————4-Nitroaniline__________534-52-1——————4, 6-Dinitro-2-methylphenol_86-30-6————————N-Nitrosodiphenylamine (1) ~101-55-3——————4-3romophenyl-phenylether__118-74-1——————Hexachlorobenzene_______87-86-5———————Pentachlorophenol________85-01-8———————Phenanthrene_______________________120-12-7——————Anthracene84-74-2———————Di-n-butylphthalate_2 06-44-0——————Fluoranthene_____~129-00-0——————Pyrene_85-68-7 ——————— Butylbenzylphthalate91-94-1 —— * --3 , 3 '-Dichlorobenzidine56-55-3 —— HH--Benzo (a) anthracene •218-01-9— p— Chrysene117-81-7—————bis (2-Ethylhexyl) phthalate117-84-0——————Di-n-octylphthalate_____"205-99-2——————Benzo (b) f luoranthene______207-08-9——————Benzo (k) f luoranthene______50-32-8———————Benzo (a) pyrene__________________193-39-5——————Indeno (l, 2,3-cd) pyrene_____53-70-3———————Dibenz (a,h) anthracene____191-24-2——————Benzo (g,h,i)perylene________

3300670

3300330067067067067067033003300670670670

3300670670670670670670

1300-670670670670670670670670

uuuuuuuuuuuuuuuuuuuuuuuuuuuuuu



551

IF 's EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDSSBLKL3




Sample wt/vol: 30.0 ' (g/mL) G Lab File ID: >E3654

Level: (low/med) LOW • .. ... ... Date Received: 10/29/88




CONCENTRATION UNITS:Number Tics found: 4 (ug/L or ug/Kg) UG/KG

CAS NUMBER

1.2.3.4.

COMPOUND NAME

UnknownUnknown ketoneUnknownUnknown

RT

8.7011.4234.9247.67

EST. GONG.

1400.450.330.

14000.

Q

JAJJJ

AR301739


55

IB EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

Lab Name: LANCASTER LABS Contract: 68-W8-0055SBLKL2




Level: (low/aed) LOW ' Date Received: 10/29/88





108-95-2 ——— •111-44-4 ——— •95-57-3 ———— -541-73-1 ——— •106-46-7 ——— -100-51-6 ——— -95-50-1 ————— -95-48-7 ————— -108-60-1 ——— -106-44-5 ——— •<C O 1 __-r>f _"7 _

67-72-1 ————— •

78-59-1 ———— -88-75-5 ———— •105-67-9 ——— -65-85-0 ———— -111-91-1 ——— -120-83-2 ——— •120-82-1 ——— •91-20-3 —— Tgs106-47-8 — &$87-68-3 —— a=_g59-50-7 ——— —91-57-6 ———— •77-47-4 ———— •88-06-2 ———— -95-95-4 ———— -91-58-7 ————— •88-74-4 ————— -131-11-3 ———— •*)nQ_QC_O

606-20-2 ——— -

—— Phenol—— bis (2-Chloroethyl) ether ____—— 2-Chlorophenol—— 1,3-Dichlorobenzene—— 1 , 4-Dichlorobenzene—— Senzyl alcohol——— 1,2-Dichlorobenzene——— 2-Methylphenol——— bis (2-Chloroisopropyl) ether_——— 4-Methylphenol—— N-Nitroso-di-n-propylamine _—— Hexachloroethane—— Nitrobenzene—— Isophorone—— 2-Nitrophenol—— 2 , 4-Dimethylphenol—— Benzoic acid—— bis (2-Chloroethoxy) methane _—— 2 , 4-Dichlorophenol—— 1.. 2 / 4-TrichlorobenzeneHI — Naphthalenes=< — 4-ChloroanilineS£ — Hexachl orobutadi ene-- — 4-Chloro-3-methylphenol—— 2-Methylnaphthalene—— Hexachlorocyclopentadiene _ __—— 2 , 4 / 6-Trichlorophenol—— 2 , 4 , 5-Trichlorophenol—— 2-Chloronaphthalene—— 2-Nitroaniline—— Dimethylphthalate—— Acenaphthylene—— 2 . 6-Dinitrotoluene

6706706706706706706706706706706706706706706706703300670670670670'67067067067067067033006703300AfiftOI670670

UUuuuuuuuuuuuuuu •uuuuuu

. uuuuuuu

$0u


1C EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _______________


!,ab Code: LANCAS Case No.: 10699 SAS No.: SDG No.: CY753




% Moisture: not dec. 0. dec. . Date Extracted: 11/03/88




f

99-09-2———————3-Nitroaniline_83-32-9———————Acenaphthene_51-23-5———————2 / 4-Dinitrophenol100-02-7——————4-Nitrophenol___]132-64-9——————Dibenzofuran121-14-2———————2 , 4-Dinitrotoluene84-66-2————————Diethylphthalate_7005-72-3——————4-Chlorophenyl-phenylether86-73-7———————Fluorene100-01-6——————4-Nitroaniline_________534-52-1——————4, 6-Dinitro-2-methylphenol_86-30-6———————N-Nitrosodiphenylamine (1)~101-55-3——————4-3romophenyl-phenylether__'118-74-1——————Hexachlorobenzene_______87-86-5———————Pentachlorophenol_______85-01-8———————Phenanthrene____________________120-12-7——————Anthracene84-74-2———————Di-n-butylphthalate_206-44-0——————Fluoranthene______129-00-0——T.--S.—Pyrene_85-68-7- — -r sh-Butylbenzylphthalate91-94-1 —— -fi3|--3 , 3 '-Dichlorobenzidine_56-55-3 —— '- Pl — Benzo (a) anthracene218-01-9 — • ———— Chrysene_117-81-7——————bis(2-Ethylhexyl)phthalate117-84-0——————Di-n-octylphthalate______________205-99-2——————Benzo (b) f luoranthene________207-08-9——————Benzo (k) f luoranthene_______50-32-8———————Benzo (a) pyrene_193-39-5——————Indeno(1, 2 , 3-cd) pyrene_53-70-3———————Dibenz (a,h) anthracene_191-24-2——————Benzo (g,h,i)perylene__

3300670

33003300670670670670670330033006706706703300670670670670670.6701300670670670670670670670670

6-70

UUuuuuuuuuuuuuuuuuuuuuuuuuuuuuu



IF EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ______








Extraction: (Sep'f/Cont/Sonc) SONG Date Analyzed: 11/08/88



CAS NUMBER

1.2.3.4.5.

COMPOUND NAME

UnknownUnknown ketoneUnknownUnknownUnknown

RT

8.7211.4224.5237.5841.51

EST. GONG.

1000.470.320.480.360.

Q

JAJJJ flj 1


53

13 EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET __________



Matrix: (soil/water) SOIL Lab Sample ID: MZDBLK1






CONCENTRATION UNIT'S:CAS NO. COMPOUND (ug/L or ug/Kg) UG/KG Q

f

108-95-2——————Phenol_______________111-44-4——————bis (2-Chloroethyl) ether_95-57-3———————2-Chlorouhenol___________541-73-1——————l,3-Dichlorobenzene_106-46-7——————l,4-Dichlorobenzene_100-51-6——————Benzyl alcohol_____95-50-1———————l,2-Dichlorobenzene_95-48-7————————2-Methylphenol_108-60-1——————bis (2-Chloroisopropyl) ether106-44-5——————4-Methylphenol_ "621-64-7——————N-Nitroso-di-n-propylamine_67-72-1———————Hexachloroethane________93-95-3———————Nitrobenzene____________78-59-1———————Isophorone88-75-5———————2-Nitrophenol____105-67-9——————2,4-Dimethylphenol.65-85-0———————Benzoic acid____________111-91-1——————bis (2-Chloroethoxy) methane_120-83 -2——————2,4-Dichlorophenol120-82-1——————l,2,4-Trichlorobenzene_91-20-3——-Slip:—Naphthalene,106-47-8——4-Chloroaniline_87-68-3——*?«|j|t—Hexachlorobutadiene_59-50-7————--—4-Chloro-3-methylphenol91-57-6———————2-Methylnaphthalene_77-47-4———————Hexachlorocyclopentadiene88-06-2———————2,4,6-Trichlorophenol_____95-95-4———————2,4,5-Trichlorophenol_____91-58-7———————2-Chloronaphthalene_______88-74-4———————2-Nitroaniline_______________131-11-3——————Dimethylphthai ate_____________208-96-8 ——————Acenaphthylene____________606-20-2——————2, 6-Dinitrotoluene________

200002000020000200002000020000200002000020000200002000020000200002000020000200001000002000020000200002QOOO20000200.00200002000020000200001000002000010000020/2 00" 6*0""20000

Uuuuuuuuuuuuuuuuuuuuuuuuuuuuuu

u


___________52

1C EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ____________


Lab Code: LANCAS Case No.: 10699 SAS No.: . SDG No.: CY753



Level: (low/aed) MED . Date Received: 10/29/88

% Moisture: not dec. 0. dec. . Date Extracted: 11/03/88

Extraction: (Sepf/Cont/Sonc) SONC Date Analyzed: 11/03/88



99-09-2———————3-Nitroaniline_83-32-9———————Acenachthene51-28-5———————2,4-Dinitrophenol100-02-7——————4-Nitrophenol___~132-64-9——————Dibenzofuran121-14-2——————2,4-Dinitrotoluene84-66-2———————Diethylphthalate_7005-72-3—————4-Chlorophenyl-phenylether_86-73-7———————Fluorene100-01-6——————4-Nitroaniline______________534-52-1——————4, 6-Dinitro-2-methylphenol86-30-6———————N-Nitrosodiphenylamine (1)"101-55-3——————4-Bromophenyl-phenylether__118-74-1——————Hexachlorobenzene_____________87-86-5———————Pentachlorophenol_______85-01-8———————Phenanthrene____________________120-12-7——————Anthracene84-7 4-2 ———————Di-n-buty Iphthal at e_206-44-0——————Fluoranthene_____~129-00-0——-———Pyrene_85-68-7 —— "ssgi&ft — Butylbenzylphthalate91-94-1— •" jgh-3 , 3 '-Dichlorobenzidine_56-55-3 —— • S&Sp- Benzo (a) anthracene2 18-01-9 ——— — -~Chrysene_117-81-7——————bis (2-Ethylhexyl) phthalate117-84-0——————Di-n-octylphthalate_____"205-99-2——————Benzo (b) f luoranthene______207-08-9——————Benzo (k) f luoranthene_____50-32-8———————Benzo (a) pyrene_193-39-5——————Indeno (1/2,3-cd )pyrene_53-70-3———————Dibenz(a,h) anthracene___191-24-2——————Benzo(g,h,i)perylene__

10000020000100000100000200002000020000200002000010000010000020000200002000010000020000200002000020000200002000040000'2000020000200002000020000200002000020000

UUUUUUUUUUUUUuuuuuuuuuuuuuuuuu t



527

IF EPA SAMPLE NOSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _____________

TENTATIVELY IDENTIFIED COMPOUNDSSBLKM1




Sample wt/vol: 1.0 (g/mL) G . Lab File ID: >D1450

Level: (low/aed) MED :- Date Received: 10/29/88

% Moisture: not dec. 0. .dec. . Date Extracted: 11/03/88





.-

t' AR30J7.i.5


52

13 EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _________

Lab Name: LANCASTER LABS Contract: 68-W8-0055SBLKW1


Matrix: (soil/water) WATER Lab Sample ID: M.B.I

Sample wt/vol: 1000( (g/mL) ML Lab File ID: >D1400



Extraction: (Sepf/Cont/Sonc) SEPF ' Date Analyzed: 11/01/88

G?c Cleanup: (Y/N) N pH:6.7 Dilution Factor: 1.00000


108-95-2———————Phenol_______________111-44-4——————bis (2-Chloroethyl) ether95-57-3———————2-Chlorophenol541-73-1——————l,3-Dichlorobenzene_106-46-7——————1,4-Dichlorobenzene100-51-6——————Benzyl alcohol_____95-50-1———————1,2-Dichlorobenzene95-48-7———————2-Methylphenol_108-60-1——————bis (2-Chloroisopropyl) ether_106-44-5———————4-Methylphenol621-64-7——————N-Nitroso-di-n-propylamine_67-72-1————————Hexachloroethane__________98-95-3———————Nitrobenzene___________________78-59-1———————Isophorone88-75-5———————2-Nitrophenol____105-67-9——————2 / 4-Dimethylphenol_65-85-0———————Benzoic acid111-91-1——————bis (2-Chloroethoxy) methane_120-83-2——————2 / 4-Dichlorophenol120-82-1——'_z££-—1/2,4-Trichlorobenzene91-20-3——f^*S—Naphthalene106-47-8--*i —4-Chloroaniline87-68-3——~zss%i—Hexachlorobutadiene59-50-7———————4-Chloro-3-methylphenol91-57-6———————2-Methylnaphthalene_77-47-4———————Hexachlorocyclopentadiene_88-06-2———————2,4,6-Trichlorophenol___"95-95-4———————2,4,5-Trichlorophenol___91-58-7———————2-Chloronaphthalene_____88-74-4———————2-Nitroaniline131-11-3——————Dimethylphthalate_208-96-8——————Acenaphthylene_606-20-2——————2,6-Dinitrotoluene

1010101010101010101010101010101050101010101010101010105010

1010

uuuuuuuuuuuuuuuuuuuuuuuuuuuuuft 6uu t


5

1C EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _________


*ab Code: LANCAS Case No.: 10699 SAS No.: SDG No.: CY753

Matrix: (soil/water) WATER • Lab Sample ID: M.B.I

Sample wt/vol: 1000( (g/mL) ML Lab File ID: >D1400






99-09-2 ———83-32-9 ——p f *> o ff

100-02-7 —132-64-9 —121-14-2 —84-66-2 ——7005-72-3-86-73-7 ——100-01-6 —I— ' A tT " •*

S6_30-6 ——101-55-3 —118-74-1 —87-86-5 —— •85-01-8 —— •120-12-7 — •84-74-2 —— •206-44-0 — •129-00-0 — •85-68-7 —— •91-94-1 —— •56-55-3 ———

117-81-7 — -117-84-0 — •205-99-2 — •207-08-9 — •K n ^ *^ f*

193-39-5 — •53-70-3 —— •191-24-2 — •

————— 3-Nitroaniline<T-W<w* it* LJil l»HCi4 W>

———— 2 , 4-Dinitrophenol———— 4-Nitrophenol———— Dibenzofuran———— 2 , 4-Dinitrotoluene———— Diethylphthalate———— 4-Chlorophenyl-phenylether _———— Fluorene———— 4-Nitroaniline———— 4 , 6-Dinitro-2-methylphenol _————— N-Nitrosodiphenylamine (1) _———— 4-3romophenyl-phenylether __———— Hexachlorobenz ene———— Pentachlorophenol———— Phenanthrene———— Anthracene———— Di-n-butylphthalate———— Fluoranthene———— Pyrene•s K — Butylbenzylphthalate•sSEfs — 3 , 3 '-Dichlorobenzidine• P l— Benzo (a) anthracene—— -" — Chrysene———— bis (2-Ethylhexyl) phthalate _———— Di-n-octylphthalate———— Benzo (b) f luoranthene———— Benzo (k) f luoranthene———— Benzo (a) pyrene———— Indeno (1,2 , 3-cd) pyrene———— Dibenz (a,h) anthracene———— Benzo (a , h , i) pervlene

5010505010101010105050101010501010101010

• 10.2010101010101010

. A££O10

uuuuuuuuuuuuuuuuuuuuuuuuuuuuuu



IF EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _____________




Matrix: (soil/water) WATER Lab Sample ID: M.B.I

Sample wt/vol: 1000 (g/mL) ML Lab File ID: >D1400

Level: (low/med) LOW '. Date Received: 10/29/88





CAS NUMBER

1.2.

COMPOUND NAME

Unknown alicyclic hydrocarboUnknown

RT

30.6239.63

EST. CONC.

26.6.

Q

JJ

AR30I7U8FORM I SV-TIC . 1/87 Rev.

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET ______________

Lab Name: LANCASTER LABS Contract: 63-W8-0055PBLKL2

'Lab Code: LANCAS Case No.: 10699 SAS No.: SDG No.: CY753

Matrix: (soil/water) SOIL Lab Sample ID: BLK(ll/03/88

Sample wt/vol: 30 (g/mL) G Lab File ID: A88323 028.RES

Level: (low/med) LOW • Date Received: 10/29/88





319-34-6———————alpha-3HC_________319-35-7———————beta-3HC__________319-36-3———————delta-BHC_________58-39-9———————ganma-3HC (Lindane)76-44-3———————Heptachlor_______.309-00-2——————Aldrin __1024-57-3—————Heptachlor epoxide959-98-8——————Endosulfan I_____"60-57-1———————Dieldrin__________72-55-9————————4 , 4 ' -DDE_________72-20-8———————Endrin33213-65-9—————Endosulfan II72-54-8————————4 , 4 '-ODD_____"1031-07-8—————Endosulfan sulfate50-29-3————————4,4'-DDT72-43-5———————Methoxychlor53494-70-5————Endrin ketone5103-71-9—————alpha-Chlordane_5103-74-2—————gamma-Chlordane"8001-35-2 —--——Toxaphene______12674-ll-23*H—Aroclor-1016__11104-28-2 -—Aroclor-1221Hl4l-l6-S*ft -—Aroclor-1232"53469-21-9—'-"——Aroclor-1242~12672-29-6—————Aroclor-1248~11097-69-1————Aroclor-1254"11096-82-5————Aroclor-1260"

8,8,8,8.3.8,8,8.16.16.16.16.16.16.16.SO.16.80.80.

160.80,80,80.80,80.160.160.

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FORM I PEST 1/87 Rev.

12.

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET _____________

Lab Name: LANCASTER LABS Contract: 68-W8-0055PBLKL1


Matrix: (soil/water) SOIL Lab Sample ID: BLK(11/01/83

Sample wt/vol: 30 (g/inL) G Lab File ID: A88323 025.RES


% Moisture: not dec. 0 dec. -Date Extracted: 11/01/88




319-84-6———————alpha-SHC319-85-7———————beta-3HC__.319-86-3———————delta-3HC58-89-9————————ga:nina-3HC (Lindane)76-44-3————————Heptachlor309-00-2———————Aldrin1024-57-3—————Heptachlor epoxide959-98-8——————Endosulfan I______60-57-1———————Dieldrin________72-55-9————————4 , 4 ' -DDE__________72-20-3———————Endrin__________33213-65-9—————Endosulfan II_____72-54-8————————4 , 4 '-ODD1031-07-8—————Endosulfan sulfate50-29-3————————4/4'-DOT_________~72-43-5———————Methoxychlor_____53494-70-5————Endrin ketone__5103-71-9—————alpha-Chlordane_5103-74-2—————gamma-Chlordane"8 001-3 5-2 ---=?-—Toxaphene_

-11-_B |S—Aroclor-101611104-28-2 1—Aroclor-122l"11141-16-5-----—Aroclor-123253469-21-9—————Aroclor-1242~12672-29-6—————Aroclor-1248~11097-69-1—————Aroclor-1254"11096-82-5—————Aroclor-12 60~

8.8.8.8.8.8.8.8.16.16.16.16.16.16.16.80.16.80.SO.160.80.80.80.80.80.160.160.

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flR30!75QFORM I PEST 1/87 Rev\

12

: ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET

Lab Name: LANCASTER LABS Contract: 68-W8-0055PBLKM1


Matrix: (soil/water) SOIL Lab Sample ID: BLK(ll/08/88

Sample wt/vol: 1.0 (g/mL) G Lab File ID: A88316 019.RES

Level: (low/med) MED • Date Received: 10/29/88





319-84-6———————alpha-BHC______________319-85-7———————beta-BHC__________319-86-3———————delta-3HC_________53-39-9————-———ganma-3HC (Lindane)_76-44-3———————Heptachlor_________309-00-2——————Aldrin ______1024-57-3—————Heptachlor epoxide959-98-8——————Endosulfan I____I60-57-1——————Dieldrin________72-55-9—————————4 , 4 ' -DDE__________72-20-3———————Endrin33213-65-9—————Endosulfan II72-54-8—————————4 , 4 ' -ODD_____1031-07-8——————Endosulfan sulfate50-29-3————————4 ,4 ' -DOT_________~72-43-5———————Methoxychlor_____53494-70-5————Endrin ketone__5103-71-9—————alpha-Chlordane_5103-74-2—————gamma-Chlordane~8001-35-2—————Toxaphene_12674-11-2-yfig— Aroclor-1016.11104-28-2 g|||—Aroclor-12 211114 l-16-5r?*£*§—Aroclor-12 3 2~53469-21-9——-—Aroclor-1242"12672-29-6—————Aroclor-1248~11097-69-1—————Aroclor-1254"11096-82-5—————Aroclor-1260"

120.120.120.120.120.120.120.120.240.240.240.240.240.240.240.1200.240.1200.1200.2400.1200.1200.1200.1200.1200.2400.2400.

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AR30I75I.— "- •> -. . - Jf

FORM I PEST 1/87 Rev.

121

ID , EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET ______________ A

_ab Name: LANCASTER LABS Contract: 68-W8-0055PBLKW1

_ab Code: LANCAS Case No.: 10699 SAS No.: SDG No.: CY753

latrix: (soil/water) WATER Lab Sample ID: BLK(10/31/88

Sample wt/vol: 1000 ' (g/mL) ML Lab File ID: A88305 019.RES

Level: (low/med) LOW Date Received: 10/29/88 IScSS

% Moisture: not dec. dec. Date Extracted: 10/31/88 jjtS jf

Extraction: (Sepf/Cont/Sonc) SEPF Date Analyzed: 11/01/88 £Err

GPC Cleanup: (Y/N) N pH:7.1 Dilution Factor: 1.0 ^/ >

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q >:

319-84-6 —————

CO O Q Q

76-44-3 ——————309-00-2 —————1024-57-3 ————Q KQ_Q Q —O ______

60-57-1 ——————•7*5_5>6;_Q— _ — _ ___•7 •?_')n_8 _______33213-65-9 —— -72-54-8 ——————

"T jl *> ff? '72—43—5 ————— —53494-70-5 ———

5103-74-2 —— —8001-35-2 —— -r12674-11-2-***11104-28-2~Si11141-16-5*™53469-21-9 ———T O £*7 O_") Q_C____

11097-69-1 ———Tlftfti? O*l B?

— alpha-3HC— beta-3HC— delta-BHC— cramma-3HC (Lindane)— HeDtachlor

f**± 4J_ ±1

— Heptachlor epoxide— Endosulfan I— Dieldrin— 4, 4 '-DDE— Endrin— Endosulfan II--4, 4 '-ODD— Endosulfan sulfate—4, 4 '-DOT— Methoxychlor— Endrin ketone— alpha-Chlordane• — qamma-Chlordane•r -Toxaphene•*-Aroclor-1016i -Ar oclor-1221-Aroclor-12 3 2

• — Aroclor-1242• — Aroclor-1248• — Aroclor-12 54• — Aroclor-12 60

.05

.05

.05

.05

.05

.05

.05

.05

.1

.1

.1

.1

.1

.1

.1

.5

.1

.5

.51.

. .5.5:5 -.5

. .51.1.

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FORM I PEST5?

• 1/8

120