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Argus FMB Fertilizer Production Chart illuminating the markets Fertilizer Market Reporting Consulting Events

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Argus FMB Fertilizer Production Chart

illuminating the markets

FertilizerMarket Reporting

ConsultingEvents

t = metric tonne * These products are liquids to which other soluble nutrients and/or chemical treatments (like insecticides) may be added.Note: Finished dry bulk or liquid products may be combined to create NPK fertilizer blends. Micronutrients may be added at various stages of production.

Ammonia (NH3)33mmBtu + H+ N

Argus FMB Fertilizer Production Chart

argusmedia.com/FertilizerTrademark notice:ARGUS, ARGUS MEDIA, the ARGUS logo, DEWITT, FMB, FUNDALYTICS, METAL-PAGES, JIM JORDAN & ASSOCIATES, JJ&A, ARGUS publication titles and ARGUS index names are trademarks of Argus Media Limited.

Oxygen(O2)

Nitrogen (N) from air

Hydrogen (H)from hydrocarbon

source

CO2 removed from ammonia

synthesis

Nitric Acid (HNO3).028t nh3

Ammonium Nitrate (NH3O3)

0.21 t NH3 + 0.78t HNO3

Urea (CH4N2O)0.76t CO2+0.58t NH3

UAN32*(NH3O3)

0.36t CH4N20 +0.45 t

Nitrophosphate NP and NPK production when K

added

DAP/MAP 0.47t H3PO4 + 0.22t NH30.54t H2PO4 + 0.15t NH3

Phosphate rock (mined)

Typical sulfur content/barrel of oil

<0.7pc Light sweet (0.4pc WTI, Brent)>0.7pc Medium sour (1.4pc Urals)>2pc Heavy sour (3.3pc Maya)

Average S content of US refined crude in 2013 was 1.44pc/barrel

EvaporateWater

Phos Acid (H3PO4) wet process

3.3t 70pc rock + 2.8t H2SO4or 3.5t rock + 1t S

Ammonium Polyphosphate*10-34-0 = 0.49t SPA+0.12t NH3+0.39t H2O11-37-0 = 0.54t SPA+0.13t NH3+0.33tH2O

Superphosphoric Acid

Base metal smelting/Sulfur Dioxide

Sulfuric Acid (H2SO4)

0.33 t S

Gypsum particulate

Oil refining/Natural gas processingSulfur

Hydrochloric acidbyproduct of SOP production

SOP (K2SO4)Mannhiem process

0.85t KCl + 0.6t H2SO4

Ammonium Sulfate (NH4)2SO4

Caprolactam production 1t capro yields 1.5-4t amsul byproduct (new technology has less byproduct)

Salt lake deposits

MOP (KCl:NaCl)

Leaching with sulfate brine

Calcium

Feedgrade Phosphate

Potassium compound ores via

mining or brines

Byproduct steam, power

Major product covered by Argus FMB

N P S

KHydrocarbon energy comparison

1 ft³ nat gas = 1.025 mmBtu1 st coal = 19.49 mmBtu1 barrel oil = 5.8 mmBtu1MWh electricity = 3.412 mmBtu

TSP

SSP

Purified acid and derivatives

SPA

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Argus FMB Fertilizer Production Chart

Argus FMB

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