ANTEC

May 16-20, 2 0 0 4At Chicago's IXIavy PierChicago, Illinois

CONFERENCE PROCEEDINV o l u m e I I - M a t e r i a l

Practical Joint Designs for Laser Welding of Thermoplastics 1236T. Kirkland, Dukane Intelligent Assembly SolutionsComparison of Weld Morphology of Poly car onate and Polypropylene for a Range of Welding Methods 1241A. Benatar, C. Krishnan, D. Toussant, The Ohio State UniversityResistive Implant Welding of Thermoplastic Composite 1246A. Savitski, EWIInduction Welding Takes New Aim for Reinforced Thermoplastics in High Strength and Load Bearing

Applications 1251V.A. Kagan, Technical AdviserR.J. Nichols, Ashland Specialty ChemicalRapid Microwave Welding of Two Polymethylmethacrylate (PMMA) Substrate ., 1256A.A. Yussuf, I. Sbarski, J.P. Hayes, N. Tran, M. Solomon, Swinburne University of TechnologyIndustrial Applications for Laser Welding of Plastics 1261M. Cherdron, Bielomatik

SIG016 - PROCESS MONITORING & CONTROL

M33—Innovative Monitoring Techniques for Polymer Extrusion

In-line Monitoring of Polymer Melting Process in a Counter-Rotating Twin-Screw Extruder byUltrasound Technique 1266

D. Wang, K. Min, The University of AkronIn-Process Temperature Measurement in Extrusion Using Continuous Wave Ultrasound 1271C.L. Thomas, K. Trivedi, D. Cuff, University of UtahIn-Process Viscosity Monitoring for Extrusion Control 1274M. McAfee, S. Thompson, G.M. McNally, Queen's University BelfastCorrelation Between Degree of Exfoliation, Dielectric Properties, and Light Transmission of Nylon 11/

Clay Nanocomposites Probed by an Online Dielectric Slit Die 1279Y.H. Lee, A.J. Bur, S.C. Roth, National Institute of Standards and TechnologyReal-Time Dielectric Measurements and Microstructure of Polymer/Clay Nanocomposites 1284A.J. Bur, Y.H. Lee, S.C. Roth, National Institute of Standards and Technology

T16—Innovative Measuring Techniques for Process Monitoring

Optimization of Transfer Lines in Plastic Industry 1290M. Nourelfath, F. Erchiqui, A. Zeblah, Universite du Quebec en Abitibi-TemiscamingueNon-Destructive On-line Monitoring of Nylon Cast Process 1295V. Japala, R. Chadwick, Cast Nylon SolutionsUltrasonic Monitoring of Quiescent Crystallization of Polypropylene under Pressure 1300F. Liegey, Ecole des MinesJ. Tatibouet, A. Derdouri, NRC CanadaInjection Moulding Process Assessment by Energy Monitoring 1305A. Dawson, H.S.Rajamani, P. Coates, University of BradfordR. Collis, L. Owen, D. Owen, Mitsui-Fanuc UKUltrasonic Monitoring of Gas Assisted Injection Moulding (GAIM) 1310E.C. Brown, L. Mulvaney- Johnson, P.D. Coates, University of BradfordFluorescent Probes for Monitoring Microstrcture of Polymer/Clay Nanocomposites 1315A.J. Bur, S.C. Roth, P.R. Start, National Institute of Standards and TechnologyP.H. Maupin, DOE

VOLUME II - MATERIALSCOMPOSITES - 39

M9—Nanocomposites I

Effect of Nano-Size Clay Particles on the Flexural Properties of Syntactic Foams 1320N. Gupta, G. Li, H.D. Jerro, E. Woldesenbet, S.S. Pang, Louisiana State UniveristyMeasurement of Sintering Characteristics of Clay-Reinforced Polyamide 6 Nanocomposite 1325J. Kim, T.S. Creasy, Texas ASM University

ANTEC 2004 / xxi

The Characteristics of PA-6/Clay and PA-66/Clay Nanocomposites 1330M. Mehrabzadeh, M. Kamal, McGill UniversityEffects of Stress on the Exfoliation of Polystyrene Nanocomposites 1336M.K. Dolgovskij, C.W. Macosko, F. Lortie, University of MinnesotaMix Models for Analysis and Optimization of Natural Rubber/Carbon Black Batches 1341J. Campanelli, T. Rose, J. Varner, Goodyear Tire and Rubber Co.Mechanical Property of Surface Modified Silica Nanoparticle Filled Poly (Ethylene 2,6-Naphthalate) 1357S.H. Kim, S.H. Ann, Hanyang UniversityC.K. Yoon, Mobil Chemical Company

M10—Composites Properties and Testing

Characterization of Delamination Resistance of Fibre Reinforced Polymers (FRP) under TransverseLoading using a Newly Developed Beam Test 1364

E. Gallagher, T. Kuboki, P.Y. Jar, J.J., Cheng, University of AlbertaPrediction of Residual Strength of Laminated Composites Subjected to Low Velocity Impact 1369Y. Zhao, C. Hess, E. Hill, Embry-Riddle Aeronautical Univ.C.S. Wang, Southern UniversityDelamination Resistance of Fibre-Reinforced Polymers (FRP) under Transverse Loading - Effect of

Contact Indentation on the Beam Test 1374S. Yuen, C. Fan, T. Kuboki, P.Y. Jar, T.W. Forest, J.J. Cheng, University of AlbertaCharacterization of the Fatigue Behavior of RTM-Laminates by Isocyclic Stress-Strain Diagrams 1379E. Ladstatter, Polymer Competence Center LeobenG. Pinter, University of LeobenW. Billinger, Fischer Advanced Composite Components AGR.W. Lang, University of Leoben and Polymer Competence Center LeobenStudy of the Mechanisms of Fracture and Mechanical Properities of an Engineering Knitted Fabric

Reinforced Composite 1384C.R. Rios-Soberanis, Centro de Investigacion Cientifica de YucatanS.L. Ogin, C. Lekakou, Surrey UniversityK.H. Leong, Cooperative Research Centre for Advanced Composites StructuresPrediction of Mechanical Properties of SMC parts 1390H. Hamada, A. Nakai, Kyoto Institute of TechnologyM. Kawamura, Matsushita Electric Works, Ltd.

M29—Composite Applications & Tooling

Reinforced Thermoplastic Composites for Floor Structure of Mass Transit Applications 1396U.K. Vaidya, F. Samalot, University of Alabama at BirminghamK. Gleich, Southern Research InstituteBiocomposite Sheet Molding Compound Housing Panels and Their Properties 1400G. Mehta, L.T. Drzal, A.K. Mohanty, M. Misra, K. Thayer, Michigan State UniversityCompression Moldable Laminate Composite Bipolar Plates for Fuel Cells 1405J. Huang, D.G. Baird, Virginia TechMultifunctional Polymer-Matrix Structural Composites 1410D.D. L. Chung, University at Buffalo, SUNYHighly Conductive Cavities Combine Variable Mold Temperature to Create More Efficient Molding 1415P.R. Lewis, P. R. Lewis ConsultingJ.H. Cunningham, J. H. Cunningham & Assoc.Thermoforming-Stamping of Continuous Fiber Thermoplastic Composites: New Tooling Equipment 1425J. Denault, G. Lebrun, P. Gagnon, National Research Council of CanadaDevelopment of Rubber Pressure Moulding Technique to Fabricate Fiber Reinforced Plastic

Components using Polyester Resin and Natural Rubber 1430K.K. Kar, Indian Institute of Technology, Kanpur, and Massachusetts Institute of TechnologyJ.U. Otaigbe, The University of Southern MississippiS. Sharma, Indian Institute of TechnologyP. Kumar, Design Programme, Indian Institute of Technology

xxii /ANTEC 2004

T13—Nanocomposites II

Carbon Nanotubes and Nanocapsules Composites with High Electromagnetic Shielding 1436W.S. Jou, National Kaohsiung University of Applied Sciences and University of WisconsinH.Z. Cheng, I-Shou UniversityC. Hsu, C. Chang, National Kaohsiung University of Applied SciencesGraphite Platelet/Nylon Nanocomposites 1441H. Fukushima, L.T. Drzal, Michigan State UniversityS.H. Lee, LG ChemicalElectrospinning: Preparation of Aligned and Oriented Polyacrylonitrile Nanofibers 1446S.F. Fennessey, R.J. Farris, University of Massachusetts, AmherstInfluence of Nanoparticles on the Shrinkage Control of Low Profile Unsaturated Polyester Composites 1451L. Xu, L.J. Lee, The Ohio State UniversityControl of Strain Hardening in Rubbery State PLA Through the Addition of Montmorillonite

Nanoparticles 1456J.H. Mulligan, M. Cakmak, The University of AkronOptimizing Nanoceramic Content in Composite Feedstocks for Thermal Spray 1461A. Saenz, T. Twardowski, Philadelphia UniversityR. Knight, Drexel University

T14—Biocomposites I

The Effect of Injection Speed on the Weld Line Properties of Jute Fiber/Poly (Butylene) SuccinateBiodegradable Composites 1468

U.S. Ishiaku, Y.W. Leong, O.A. Khondker, A. Nakai, H. Hamada, Kyoto Institute of TechnologyStructural Beams and Panels from Natural Fibers through Hybrid and Hierarchical Cellular Designs 1473R. Burgueno, M.J. Quagliata, A.K. Mohanty, M. Misra, G. Mehta, L. Drzal, Michigan State UniversityRecycled Newspaper and Chicken Feathers as Reinforcement Fiber in Bio-Composite Materials 1478M.A. Dweib, R.P. Wool, Center for Composite Materials, University of Delaware, NewarkT.A. Bullions, A.C. Loos, Center for High Performance Manufacturing, Virginia Tech, BlacksburgGreen Composites from Biofibers and Poly(3-hydroxybutyrate) 1483A.K. Mohanty, L.T. Drzal, P. Mulukutla, S.M. Desai, M. Misra, Michigan State UniversityThermal and Mechanical Properties of Functional Monomer Modified Soy Protein Plastic by Reactive

Extrusion Technology 1488W. Liu, M. Misra, A.K. Mohanty, L.T. Drzal, Michigan State UniversityMechanical Properties of Hybrid Polyester Composites 1493I. Catic, M. Sercer, M. Rujnic-Sokele, University of Zagreb

T28—Nanocomposites III

Process Induced Orientation of Nanolayers in Polyolefin Nanocomposites 1498S. Kumar, K. Jayaraman, Michigan State UniversityKinetic Stability of the Well-Exfoliated State in Polypropylene-Clay Nanocomposites Made by Solid-

State Shear Pulverization 1503K.G. Kasimatis, J.M. Torkelson, Northwestern UniversityThermo-Kinetic Compounding of Polypropylene and Clay 1508T.G. Gopakumar, D.J.Y.S. Page, Royal Military CollegeProperties and Morphology of TPO-based Nanocomposites 1513H.S. Lee, D.R. Paul, University of TexasP.D. Fasulo, W.R. Rodgers, General Motors Research and Development CenterTensile Properties and Fracture Toughness of PP-Based Nanocomposites 1518M.N. Bureau, M.T.Ton-That, F. Perrin-Sarazin, National Research Council CanadaDevelopment of Polyolefin Nanocomposites: Relationship Between Formulation, Processing, Structure

and Performance 1523M.T. Ton-That, F. Perrin-Sarazin, M. Bureau, K. Cole, J. Denault, National Research CouncilPolymer-Clay Nanocomposites Prepared in Supercritical Carbon Dioxide 1528M. Garcia-Leiner, A.J. Lesser, University of Massachusetts at AmherstMechanical and Electrical Properties of Exfoliated Graphite-Platelet Polypropylene Nanocomposites 1533K. Kalaitzidou, H. Fukushima, L.T. Drzal, Michigan State University

ANTEC 2004 /xxiii

In-Situ Wide-Angle X-ray Scattering (WAXS) Analysis of Electrically ActivatedPolypropylene(PP)/Clay Nanocomposites 1538

D. H. Kim, K.S. Cho, K.H. Ann, S.J. Lee, Seoul National UniversityJ.H. Lim, Y.K. Kwon, Inha University

W14—Thermoset Composites and Special Fibers

Vibration-Assisted Liquid Composite Molding 1544R. Gibson, E. Ayorinde, Mechanical Engineering, Wayne State UniversityRapid Surface Treatment of Reinforcing Fibers Using Ultraviolet Light Processing 1548M. Rich, L.T. Drzal, P. Askeland Michigan State UniversityWater Diffusion Based Non-Destructive Evaluation (NDE) of PMR-H-50/M60J 4HS Weave Carbon

Fabric Composite Materials under Stress-Thermal Cycling 1553J. Ju, R.J. Morgan, Texas A&M UniversityNanocomposite Polyetherimide with High Thermo Oxidative Stability 1558J. Lou, V. Harinath, J. Sankar, K. Roberts, L. Uitenham, North Carolina Agricultural & Technical State

University

W27—Thermoplastic Composites

Internet Controlled Thermoplastic Impregnation of Glass Fibers Yarns with Pultrusion 1564P. Das, O. Ozturk, J. Molenaur, R.B. Pipes, University of AkronOptimization of Thermoplastic Impregnation of Glass Fiber Yarns with Pultrusion 1569O. Ozturk, P. Das, M. Stadler, R.B. Pipes, University of AkronLow Cost Processing of Carbon Fabric Reinforced Nylon Composites 1573S. Pillay, H. Ning, G.M. Janowski, U.K. Vaidya, University of Alabama at BirminghamK. Gleich, Southern Research InstituteLong Fiber Reinforced Post-Consumer Carpet 1578J.D. Muzzy, Y. Wang, P. Patel, K. Jin, S. Samanta, L. Bryson, B. Shaw, Georgia Institute of TechnologyC. Hagberg, NFM Welding Engineers, Inc.Low-Cost Composite Materials from Post-Consumer Plastics and Waste Paper 1583A.R. James, I. Sbarski, S.H. Masood, Swinburne University of TechnologyE. Kosior, Visy IndustriesFilament Winding Processing Conditions to Produce Thermoplastic Composites from Towpregs 1588J.P.L.G. Nunes, F. Van Hattum, University ofMinhoJ.F.M. Silva, Instituto de Engenharia do PortoA.T. Marques, Instituto de Engenharia Mecanica e Gestao IndustrialProcessing and Mechanical Properties of Continuous Fiber Reinforced Thermoplastics 1593H. Hamada, A. Nakai, T. Narita, Kyoto Institute of TechnologyE. Fukui, I. Komiya, FUKUI Fishing Net Co.

W28—Biocomposites II

Measurement System Analysis for Viscosity Measurement of Highly Filled Biofiber Composites 1598S. Godavarti, Aspen MaterialsInjection Molded Biocomposites from Natural Fibers and Modified Polyamide 1603M. Misra, A.K. Mohanty, L.T. Drzal, Michigan State UniversityP. Tummala, Michigan State University and QTR, IncProcessing/Structure/Property Relationships for Artificial Wood Made from Stretched PP/Wood-Fiber

Composites 1608Y.S. Kim, G. Guo, K.H. Wang, C.B. Park, University of TorontoF.W. Maine, PSA Composites Inc.Effect of Processing Conditions on the Physico-Mechanical Properties of Cellulose Fiber Reinforced

Poly (Lactic Acid) 1614M.S. Huda, A.K. Mohanty, L.T. Drzal, M. Misra, Michigan State UniversityE. Schut, CreaFill Fibers CorpBiobased Composites Manufactured through a Reactive Extrusion of Maleated Wood Particles 1619K. Carlborn, L.M. Matuana, Michigan State UniversityMaleated Wood Fiber-High Density Polyethylene Composites: Coupling Agent Performance 1624Z. Lu, Q. Wu, I. Negulescu, Louisiana State University

xxiv /ANTEC 2004

The Effect of Surface Active Agent Solution on the Mechanical Properties of Wood-PolymerComposites 1632

P. Douglas, W.R. Murphy, G. McNally, Polymer Processing Research CentreMechanical Properties of Carbonized Bamboo Fiber Reinforced Biodegradable Polymer Composite 1636H. Matsui, Suehiro Industrial Co. LTD.K. Kitagawa, T. Semba, Kyoto Municipal Institute for Industrial ResearchH. Okumura, U.S. Ishiaku, H. Hamada, Kyoto Institute of TechnologyThe Study of Using Vetiver Grass as a Filler in Polypropylene Composites 1641Y. Ruksakulpiwat, W. Thomthong, W. Sutaphan, N. Suppakarn, Suranaree University of Technology

ELECTRICAL AND ELECTRONIC - 24

M5—Novel Materials and Material Modifications

Development of Thermoplastic Electrolytes and their Ionic Conductivity 1648T. Puatrakul, S. Jeung, K. Min, University of AkronElectrical Properties of Carbon Nanofiber-Modified Thermotropic Liquid Crystalline Polymers 1652S. Lee, A.A. Ogale, Clemson UniversityM.S. Kim, Myongji UniversityApplication of Iradiation Cross-Linking for the Improvement of the Short-Time Thermo-Mechanical

Properties of 3D-MID's 1657Z. Brocka, G.W. Ehrenstein, Institute of Polymer TechnologyA Novel CNTs/Polymer/PE Composite with High Electromagnetic Shielding 1662H.Z. Cheng, P.T. Lin, C.C. Huang, E.C. Chen, I-Shou UniversityW.S. Jou, National Kaohsiung University of Applied SciencesA Injection Molded High Electromagnetic Shielding and Low Cost Carbon Fiber Composites 1668W.S. Jou, National Kaohsiung University of Applied Sciences and University of WisconsinH.Z. Cheng, I-Shou UniversityC. Weng and Y. Hsu, National Kaohsiung University of Applied Sciences

W6—Analysis of Microelectronic Packaging

'Distribution of a Minor Solid Constituent in a Transfer Molded Leadframe Microcircuit Package 1674Y. Huang, University of Maryland and University of Maryland at College ParkD. Bigio, M. Pecht, University of Maryland, College Park'Three-Dimensional CAE of Wire-Sweep in Microchip Encapsulation 1679W.H. Yang, D. Hsu, V. Yang, CoreTechR.Y. Chang, National Tsing-Hua UniversityF. Su, ChipMOSS.J. Huang, S. Juang, National Chen Kung University'Three-Dimensional Dynamic Simulation of Paddle Shift During Semiconductor-Chip Encapsulation 1684S. Han, F. Costa, S. Ray, MoldflowS. Willmorth, Micron Technology'Molding Analysis for Underfill of Flip-Chip Packages 1689W.R. Jong, S.C. Chen, C.C. Lai, T.H. Kuo, H.W. Liu, Chung Yuan Christian UniversityS. Ho, W.Y. Lo, Ta Hwa Institute of Technology'The Analysis on the Fatigue Life of Flip Chip Package Under Cyclic Thermo-Mechanical Loading 1694W.R. Jong, C.C. Chiu, H. Tsai, S.C. Chen, Chung Yuan Christian University'Structural Analysis of DC-DC Converters 1699W.R. Jong, S.H. Peng, T.H. Kuo, Chung Yuan Christian UniversityS. Hu, Delta Electronics, Inc.S. Ho, Ta Hwa Institute of Technology

Present in a joint session.

ANTEC 20041xxv

ENGINEERING PROPERTIES AND STRUCTURE - 26

M6—Synthesis and Fabrication of Nanocomposites

Insights into the Formation and Properties of Well-Exfoliated Nanocomposites 1704T.D. Fornes, D.R. Paul, University of TexasSynthesis and Properties of Polymer Blend Nanocomposites. Part II.: Thermoplastic Olefin (TPO) 1709K.Y. Lee, L.A. Goettler, University of AkronRheological Characterization of Polystyrene-Clay Nanocomposites as they Relate to the Degree of

Dispersion 1714J. Zhao, R. Fibiger, H. Pham, E. Garcia-Meitin, L. Liu, V. Juarez, D. King, The Dow Chemical Co.N. Roberman, University of MinnesotaEffect of Clay Surface Modification on the Polymer Nanocomposite Foam Structure 1723X. Han, C. Zeng, M.J. Wingert, L.J. Lee, K.W. Koelling, D.L. Tomasko, Ohio State UniversityProducing Polymer Nanocomposites with Exfoliated Pristine Clay 1728J. Wu, J. Liu, Hong Kong University of Science and TechnologyK. Wang, L. Chen, C. He, Institute of Materials Research and EngineeringGraphene Nanoplatelet Reinforced Polymer Coatings 1733S.C. Wong, E. Sutherland, F.M. Uhl, S. Yerramaddu, D.C. Webster, B.Z. Jang, North Dakota State

University

M7—Bio-Polymers

Melt Rheology of Polylactides 1740J. Dorgan, B. Braun, D. Knauss, J. Janzen, Colorado School of MinesNovel Controlled Drug Release Biodegradable Polymers Systems 1744F.Y.C. Boey, S. Venkatraman, J. Pan, L.P. Tan, Nanyang Technological UniversityMechanical Responses in Biomimetic Polymer Hydroxyapatite Nanocomposites 1759K.S. Katti, P. Turlapati, North Dakota State UniversityMultiscale Modeling Of Biological Nanocomposite Nacre 1764D.R. Katti, K.S. Katti, S.M. Pradhan, North Dakota State UniversityDegradation Studies of PLA Films Grafted with Hydrophilic Polymers 1769A.V. Janorkar, D.E. Hirt, Clemson UniversityThe Comparitive Role of Relaxation and Forced Retraction on the Structural Organization Processes

in Uniaxially Stretched PLA Films from Amorphous Precursors 1774J.H. Mulligan, M. Cakmak, The University of Akron

M13—Advances in Polymer Durability and Lifetime Prediction (Special Session in Honorof Prof. Alexander Chudnovsky)

'Strength, Toughness, Lifetime and Reliability of Plastics in Engineering Applications 3962A. Chudnovsky, University of Illinois at Chicago'interrelationships Between Fatigue and Creep Fracture in Poly(ethylene) and Poly(vinyl chloride) 3966E. Baer, A. Hiltner, J. Yu, T.E. Bernal-Lara, Case Western Reserve University'Yield and Fracture of Polymers and Nanocomposites in Multiaxial Stress 3971A.J. Lesser, University of Massachusetts'Applicability and Limitations of Fracture Mechanics Concepts for Lifetime Prediction of Polyethylene

Pipes 3976R.W. Lang, Z. Major, G. Pinter, University of LeobenW. Balika, Polymer Competence Center Leoben'Modelling Impact Fracture and RCP Resistance of Thermoplastics from Cohesive Properties 3977P. Leevers, Imperial College London'Residual Strain Characterisation using an Embedded FBG Sensors: Measurements and Simulations 3982J. Botsis, F. Colpo, L. Humbert, Swiss Federal Institute of Technology

Present in ajoint session.

xxvi/ ANTEC 2004

M22—Deformation, Fracture and Toughening of Nanocomposites

Deformation Processes of Single-Wall Carbon Nanotubes in Composites 1780R.J. Young, M. Lucas, UMIST and University of ManchesterOn the Tearing Toughness and Permeability Modelling of Polymer Nanocomposites 1785Y.W. Mai, C. Lu, University of SydneyR.K. Li, J. Wong, City University of Hong KongMicro-Deformation and Fracture Behavior of Epoxy Based Nanocomposites with Highly Exfoliated

Pristine Clay 1790J. Wu, Hong Kong University of Science and Technology and Institute of Materials Research and

EngineeringK. Wang, L. Chen, C. He, Institute of Materials Research and EngineeringA.F. Yee, University of Michigan and Institute of Materials Research and EngineeringTensile Property, Morphology and Micro-Deformation of Polypropylene/CaC03 Nanocomposites 1795Y. Zhang, CM. Chan, J. Wu, Hong Kong University of Science and TechnologyFracture Behavior of Core-Shell Rubber-Toughened a-Zirconium Phosphate-Based Epoxy

Nanocomposites 1800K.T. Gam, N. Bestaoui, A. Clearfield, H.J. Sue, Texas A&M UniversityM. Miyamoto, Kaneka CorporationN. Miyatake, Kaneka Texas CorporationRemote Strain-Sensor Coatings Based Upon Carbon Nanotube-Polymer Composites 1805R.J. Young, J. Halary, J. Stanford, P. Lovell, UMISTSome Studies on Montmorillonite (MMT) Filled Polypropylene Composite Systems 1810R.K.Y. Li, D. Shi, City University of Hong KongImportance of Concomitant Strengthening and Toughening in Nanoclay-Reinforced Polymers 1815S.C. Wong, North Dakota State UniversityL. Chen, C. He, Institute of Materials Research and Engineering, SingaporeX. Lu, Nanyang Technological UniversityMechanical Properties and Fracture Behavior of Epoxy Nanocomposites with Highly Exfoliated

Pristine Clay 1820K. Wang, L. Chen, C. He, M.L. Toh, Institute of Materials Research and EngineeringJ. Wu, Hong Kong University of Science and Technology and Institute of Materials Research and

Engineering

M23—Processing Effects on Polymer Properties

Comparison of the Effect of Pigments on the Mechanical and Thermal Properties on Two DifferentCatalysed Propylene-Ethylene Random Copolymers 1826

I.F.M. Major, G.M. McNally, A.H. Clarke, Polymer Processing Research CentreH. Ross, Canyon EuropeDrawing of Nylon 66 Fibers in the Presence of Supercritical Carbon Dioxide 1831X. Hu, A.J. Lesser, University of Massachusette AmherstEffects of Carbon Nanofibers on Polystyrene Nanocomposites and Foams 1836J. Shen, L.J. Lee, The Ohio State UniversityShear-Induced Migration of Glass Beads During Injection Molding in Filled Polymer Compound and

its Effect on Mechanical Properties and Electrical Conductivity 1841CM. Hong, S.C. Jana, University of AkronComparative Structure Development in Injection Molding of Various Polyolefins 1846J. Suh, J.L. White, The University of AkronCompositional Heterogeneity of Ethylene-Acrylate Copolymers: Effect on Melt Rheology 1851R.T. Chou, Y. Brun, M.T. Pottiger, DuPont Co.On-line Birefringence Measurement in Film Blowing Process 1856H. Ito, K. Suzuki, T. Kikutani, Tokyo Institute of TechnologyH.J. Kang, Dankook UniversityT. Kanai, Idemitsu Petrochemical Co., Ltd.Influence of Blend Composition on Structure Development during Uniaxial Stretching of Melt Miscible

PVC/PCL 1860M.C Ramirez-Huerta, M. Cakmak, University of Akron

ANTEC 2004 / xxvii

Flow-Induced Crystallization and Birefringence in High-Speed Spun Pet Fibers 1865K.H. Kim, A.I. Isayev, K. Kwon, University of Akron

T6—Characterization of Nanocomposites

Computational Materials: Modeling and Simulation of Nanostructured Materials and Systems 1872T. Gates, J.A. Hinkley, NASA Langley Research CenterRheology, Processing and Electrical Properties of Multiwall Carbon Nanotube/Polypropylene

Nanocomposites 1877S.B. Kharchenko, K.B. Migler, J.F. Douglas, J. Obrzut, National Institute of Standards and TechnologyE.A. Grulke, University of KentuckyThe Development of Structure in a Melt Blended Polypropylene Organoclay Nanocomposite 1882M.D. Read, L. Liu, J.D. Harris, R.R. Samson, The Dow Chemical CompanyA Comparative Study of Low Filler Content Polypropylene Nano- and Micro-Composites 1887A. Vaxman, N. Tsalic, D. Benderly, R. Shalom, Carmel Olefins LtdM. Narkis, Technion - IITProperties of UV Curable Acrylate Nanocomposite Coatings 1892F.M. Uhl, S.P. Davuluri, S.C. Wong, D. Webster, North Dakota State UniversityStructure and Properties of Polyurethane/Clay Nanocomposites and Foams 1896X. Cao, L.J. Lee, The Ohio State UniversityT. Widya, C. Macosko, University of Minnesota

T7—Mechanical Properties of Polymers

Mechanical Properties of Bisphenol-A Polycarbonate via Controlled Crystallization and OrientationUsing Supercritical Carbon Dioxide 1902

X. Hu, A.J. Lesser, University of Massachusette AmherstMechanical Properties of Injection Molded Glass Fiber Reinforced PC/ABS with PC Oligomer 1907S. Takashima, S. Baba, H. Hamada, Kyoto Institute of TechnologyM. Mizoguchi, T. Kuriyama, Yamagata UniversityModeling of Viscoplastic Constitutive Equation for Inelastic Deformation of Polymer with Unloading 1912M. Mizuno, Akita Prefectural UniversityY. Sanomura, Tamagawa UniversityMechanical Properties of PC/ABS Ultra High-Speed Injection Moldings 1917S. Baba, S. Takashima, Y.W. Leong , H. Hamada, Kyoto Institute of TechnologyM. Mizoguchi, T. Kuriyama, Yamagata UniversityInfluence of Gamma Radiation Dose and Loading Rate on Fracture Toughness of Polycarbonate 1922N.S. Melo, J.C Miguez Suarez, IMELong-Term Creep Prediction Utilizing The Non-Linear Strain Energy Equivalence Theory 1927J.K. Lynch, T.J. Nosker, R.W. Renfree, Rutgers UniversityK. Van Ness, Washington and Lee University

T20—Polymer Surface Phenomenon and Scratch

Surface Damage of Polymers in Nanoscale 1934J. Wong, R. Li, City University of Hong KongH.J. Sue, Texas A&M UniveristyK. Y. Zeng, Institute of Materials Research and EngineeringY.W. Mai, University of SydneyDetermination of Scratch Behaviour of Molded Plastics 1938H. Kita, M. Makoto, National Institute of Technology and Evaluation (NITE)T. Kitamura, T. Kuriyama, Yamagata UniversitySurface Characterization of Rigid Rod Polymers 1943S.E. Morgan, C.K. Hong, S.D. Benson, University of Southern MississippiN. Malkovich, Mississippi Polymer Technologies, Inc.C.L. McCormick, Polymer ScienceG. Cannon, Chemistry and BiochemistryTransmission of Tribological Measurement Values from the Model-System to the Part-System 1948R. Kiinkel, G.W. Ehrenstein, Institute of Polymer Technology

xxviii /ANTEC 2004

Artificial Weathering Effects on the Scratch Resistance of Automotive Instrument Panel TPOs 1953B.M. Wichterman, D.A. Britz, R.A. Ryntz, Visteon CorporationSurface Properties of Amphipathic Films of Natural and Synthetic Polymers 1957C.K. Hong, S.D. Benson, G.C. Cannon, C.L. McCormick, S.E. Morgan, University of Southern MississippiPolyurethane-Clay Nanocomposites via Bulk-Polymerization Methods 1962A. Pattanayak, S.C. Jana, University Of AkronEvaluation of Scratch Resistance of Polymers 1967H.J. Sue, M.W. Wong, A. Moyse, G.T. Lim, Texas A&M UniversityF. Lee, W.J.Boo, Atlas Material Testing Technology LLC

T21—Fundamental Origins of Deformation and Fracture

Structural Formation of Amorphous Poly(ethylene terephthalate) During Uniaxial Deformation aboveGlass Temperature 1974

B.S. Hsiao, D. Kawakami, S. Ran, C. Burger, I. Sics, State University of New York/Stony BrookInvestigation of the Microscopic Origins of the Torque and Normal Force Responses of Glassy

Polymers 1979A. Flory, G.B. McKenna, Texas Tech UniversityUse of Thermography in Craze Growth and Plastic Zone Studies of Polycarbonate 1984R.P. Patki, P.J. Phillips, B. Yang, P.K. Liaw, University of TennesseeThe Craze Strength/Yield Strength Ratio 1989T. Pecorini, Eastman Chemical CompanyHysteresis Loss of Polymeric Materials: Finding of New Dimensionless Parameters 1994K.K. Kar, Indian Institute of Technology, Kanpur, and Massachusetts Institute of TechnologyA.K. Bhowmick, Indian Institute of Technology KharagpurJ.U. Otaigbe, The University of Southern MississippiCompaction and Dilatation Effects During the Plastic Deformation of Glassy Polymers 1999C. G'Sell, J.M. Jean-Romain, A. Dahoun, J.M. Hiver, Ecole des Mines de Nancy (France)Enhanced Toughness Properties in Nanostructured Glassy Polymers by all Acrylic Block Copolymers

Prepared by Controlled Radical Polymerization 2004P. Gerard, ATOFINAO. Guerret, GRL, ATOFINAEffect of Deformational Behavior of Cell Structure on Mechanical Properties of Polyurethane Foam

under Compressive Loading 2009A. Goto, Osaka Sangyo UniversityK. Yamaguchi, Industrial Technology Center ofWakayama PrefectureH. Hamada, Kyoto Institute of TechnologyIn-Situ Characterization of Cavitation During the Deformation of Semi-Crystalline Polymers 2013C. G'Sell, F. Addiego, A. Dahoun, J.M. Hiver, Ecole des Mines de Nancy

T29—Advances in Polymer Durability and Lifetime Prediction

'Designing Impact-Modified Polypropylene for Durability 3988CP. Bosnyak, H.T. Pham, Dow ChemicalW. Zhou, A. Chudnovsky, University of Illinois at Chicago'Effect of Process Zone on Tear Resistance of Polymeric Films 3991S. Wu, K. Sehanobish, The Dow Chemcial'Accelerated Test for Stress Corrosion Crack Initiation in PB Tubing 3996W. Zhou, University of Illinois at ChicagoX. Niu, RR Donnelley'Creep of Polyphthalamide (PPA) under Compression and Temperature 4002R. Li, Motorolajnc.'Assessment of Polycarbonate Toughness by Creep Test 4007W. Zhou, A. Chudnovsky, University of Illinois at ChicagoCP. Bosnyak, K. Sehanobish, Dow Chemical

Present in a joint session.

ANTEC 20041xxix

'Application of Acoustic Emission Technique for the Quality Control of Epoxy Coatings on SteelSubstrate 4013

H. Wu, The University of Illinois at ChicagoH. Chen, H. Pham, N. Jivraj, M. Franca, The Dow Chemical Company'Micro-Deformation and Failure Mechanism in Polymeric Materials as Studied by In-Situ

Deformation Test in Transmission Electron Microscopy (TEM) 4018H. Tang, R. Cieslinski, N. Verghese, N. Jivraj, The Dow Chemical Company*A Critical Review on the FNCT Approach for the Ranking of Thermoplastics Pipe Grades 4023M. Haager, Polymer Competence Center LeobenG. Pinter, R.W. Lang, University of Leoben*A Fatigue Approach for Lifetime Prediction of PE-HD Pipe Grades 4028W. Balika, Polymer Competence Center LeobenG. Pinter, R.W. Lang, University of LeobenB.H. Choi, University of Illinois at Chicago

W7—Films and Packaging Polymers

Reduction of Stress-Whitening in Polypropylene Extrusion Blow Molded Bottles 2020T. Pressly, N. Jivraj, C. Bosnyak, G. Young, V. Tharp, The Dow Chemical CompanyA Novel Understanding on the Effects of Industrial Retorting in Ethylene-Vinyl Alcohol Copolymers

Used in Retortable Food Packaging Applications 2025J.M. Lagaron, A. Lopez-Rubio, R. Catala, R. Gavara, IATA-CSICE. Gimenez, University Jaume IT. Yamamoto, Y. Saito, NIPPON GOHSEINovel Polypropylene Material for BOPP Film 2030S. Kim, Sunoco ChemicalDevelopment of Evoh-Kaolinite Nanocomposites for High Barrier Packaging Applications 2035E. Gimenez, L. Cabedo, J.J. Saura, University Jaume IJ.M. Lagaron, R. Gavara, Institute of Agrochemistry and Food Technology (IATA-CSIC),Cutting and Tear Resistance of Polymeric Films 2040M.E. Light, A.J. Lesser, University of Massachusetts, AmherstComparison of Infrared Spectroscopy and X-Ray Pole Figures for Biaxial Orientation

Characterization of Different Polyethylene Films 2045A. Ajji, X. Zhang, S. Elkoun, Industrial Materials Institute, NRC

W8—Polymer Morphology and Crystallization

How Much Do We Really Understand About Crystallization in Polymers? 2052P.J. Phillips, X. Guan, University of TennesseeEvidence of Dual Phase for the Amorphous State of Polymers from Crystallization Kinetics 2057J.P. Ibar, Eknet Research and Stratek Plastics LtdMorphology, Crystallization Kinetics and Dynamic Mechanical Analysis of Phosphate Glass-

Polyamide 12 Hybrid Materials 2063K. Urman, J. Otaigbe, University of Southern MississippiCrystallinity, Orientation and Mechanical Property Development in Melt Spinning Poly(ethylene-co-

octene) Filaments 2067H. Shan, J.L. White, University of AkronThe Effect of Shear and Pressure on the Crystallization of Polymers 2072S. Westphal, Westphal Beachside Consultants,IncDiverse Morphologies and Dynamic Mechanical Behavior in Metallocene Polyethylene Copolymers 2076X. Guan, P.J. Phillips, University of Tennessee, Knoxville

W9—Special Interests in Polymer Science and Engineering

The Influence of Ionic Functionality on the Interfacial Tension in Polypropylene/Copolyester Blends 2082P.L. Hopson, R.B. Moore, University of Southern Mississippi

Present in a joint session.

xxx/ANTEC 2004

Polymer Blends as Proton-Exchange Membrane Materials for Fuel Cells 2087S. Swier, M.T. Shaw, R.A. Weiss, University of ConnecticutIn-Situ Ultrasonic Compatibilization of Dynamically Vulcanized PP/EPDM Blends 2092W. Feng, A.I. Isayev, University of AkronEffect of the Viscosity Ratio on the Particle Coalescence in PS/HDPE Blends under Extensional Flow 2097M.O. Vazquez, O.G. Bello, M. Arellano, F. Moscoso, R. Gonzalez-Nunez, Universidad de GuadalajaraPhotomechanical Oxidation of Anisotropic Polyethylene 2102J.R. White, T.A. Egerton, P.A. Christensen, CQ. Jin, University of Newcastle upon TyneModeling of Cell Structure in Polyurethane Foam 2107K. Yamashita, C. Nonomura, Toyobo Research Center Co.,LTD.A. Goto, Osaka Sangyo UniversityK. Yamaguchi, Industrial Technology Center ofWakayama Prefecture

W22—Films and Packaging Polymers

Biaxial Orientation of Multilayer LDPE/PET Films: Structure and Properties 2112A. Ajji, X. Zhang, Industrial Materials Institute, NRCHaze Improvement with Addition of HP-LDPE or HDPE; Part II - Mechanistic Understanding 2117H. Chen, J. Li, R.L. Sammler, CT. Lue, R. Kolb, T.H. Kwalk, Univation TechnologiesPredictions of MD Tear Strengths of Some Solution Octene LLDPE Film Resins 2122X.C. Wang, NOVA Chemicals CorporationLinear and Non-Linear Biaxial Stress-Optical Behavior in Pet Films as Observed by Real Time True

Stress-True Strain-Birefringence Technique 2127M. Hassan, M. Cakmak, The University of AkronThe Effect of Maleic Anhydride Coupling Agent on Melt Processed Semi-Crystalline Pet

Nanocomposite Films 2130CT. Thellen, C. Orroth, D. Froio, J. Lucciarini, J. Ratto, U.S. Army Soldier Systems Center, RDECOMA. Ranade, N. D'Souza, University of North TexasThe Influence of Molecular Weight on the Relaxation Behavior of Uniaxially Strethed Pen Films as

Investigated by Real Time Spectral Birefringence Technique 2135C.I. Martins, M. Cakmak, University of AkronHaze Improvement with Addition of HP-LDPE or HDPE: Part I - Blown Film Property Comparison 2140CT. Lue, T.H. Kwalk, D. Li, C.R. Davey, D.Y. Chiu, Univation TechnologiesThe Influence of Draw Conditions on the Morphology and Physical Performance of POE Film 2144C.C. Lin, Y.K. Hsiao, C.Y. Chuang, Plastics Industry Development CenterEnhancement of Adhesion Between High Density Polyethylene and Poly (Ethylene Terephthalate)

Films 2151H. Durgun, Anadolu UniversityG. Bayram, Middle East Technical University

W23—Polymer Morphology and Crystallization

Morphology Evolution in Polytetrafluoroethylene as a Function of Deformation and Melt Time andTemperature: Nano-Fibrils and Single- and Multi-Molecule Folded Chain Single Crystals 2158

P.H. Geil, J. Yang, R.A. Williams, K.L. Petersen, University of IllinoisT.C Long, P. Xu, W. L. Gore & Assocs., Inc.Influence of Co-Monomer Distribution Profile on the Crystallization Characteristics and Physical

Properties of High Density Polyethylene 2163R.K. Krishnaswamy, Q. Yang, Chevron Phillips Chemical CompanyThe Effect of Blend Composition on the Deformation Behavior of Pen/PEI Blend Using On-Line

Mechano-Optical Technique 2168K.D. Kanuga, M. Cakmak, University of AkronComparing Models for the Glass Transition Temperatures of Compatible Polymer Mixtures 2173F. Rodriguez, Cornell UniversityStructure-Property Relationships in Metallocene Based Ethylene-Octene Plastomers 2178M. Varma-Nair, ExxonMobilN.R. Dharmarajan, M.G. Williams, ExxonMobil Chemical CompanyBreak-through in High Performance Ionomers: Morphology and Properties 2186J.C. Chen, J.D. Londono, DuPont Co.

ANTEC 2004 / xxxi

Relationship between Mould Temperature and Properties of Injection-Moulded Pure and BetaNucleated Polypropylenes 2191

R. Cermak, M. Obadal, M. Polaskova, K. Stoklasa, Tomas Bata University in ZlinCharacterization of LLDPE/Monmorillonite Nanocomposite 2196S.H. Ryu, J.H. Bae, Kyung Hee UniversityY.W. Chang, Han Yang UniversityMechanical Behavior of Thermoplastic Olefins (TPOs) During Three-Point Bend Impact 2201L. Gonzalez, T.E. Godlewski, B. Wooten, P.A. Gustafson, Ford Motor Company

POLYMER ANALYSIS DIVISION

M26—Thermosets & Advanced Analysis

Controlled Epoxy Network Structure-Property Relationships: The Effect of Chain Termination 2208N.E. Verghese, M.J. Marks, H.Q. Pham, KJ. Hrovat, The Dow Chemical CompanyRelation Between Mobility and Diffusion Factors for Thermoset Cure 2212Y. Meng, S.L. Simon, Texas Tech UniversityEvaluation of Thermoset UV Curing Kinetics by Calorimetry, Rheology and FTIR Spectroscopy 2217V. Tan, M.W. Young, S. Patel, Polymer Processing InstituteM. Xanthos, New Jersey Institute of TechnologyMorphology-Properties Relationship of Siloxane-Modified Epoxy Resins 2222M. Zhang, G.C. Martin, Syracuse UniversityEffect of Cure Cycle on Residual Stress Development in Thermosetting Materials 2227M. Merzlyakov, G.B. McKenna, S.L. Simon, Texas Tech UniversityEffects of Ultrasonic Processing on the Thermal Behavior of Epoxy Polymers 2231R. West, V. Malhotra, Southern Illinois UniversityThe Effect of Absorbed Moisture on the Elevated Temperature Properties of Polyetherimide 2236M. Sepe, Dickten & Masch Mfg.Measurement and Prediction of Fibre Orientation within a Three-Dimensional Flow 2241F. Caton-Rose, P. Coates, B. Whiteside, University of BradfordP. Hine, A. Duckett, University of LeedsP. Jittman, C. Chapman, G. Smith, University of WarwickThe Effect of Atmospheric Pressure Glow Discharge (APGD) Treatment on Polyetherimide,

Polybutyleneterephthalate and Polyamides 2246A. Ruddy, G. McNally, W. Murphy, Polymer Processing Research Centre, Queen's University, BelfastG. Nersisyan, W. Graham, School of Pure and Applied Physics, Queen's University, Belfast

T11—Thermal Analysis and Rheology: Glasses, Rubbers, and Viscoelastic Materials

Effect of Freeze-Drying on the Glass Temperature of Cyclic Polystrenes 2252S.L. Simon, G.B. McKenna, Texas Tech UniversityP. Bernazzani, Lamar UniversityEvaluation of a Molecular-Based Yield Model for Glassy Networks 2258K.J. Calzia, A.J. Lesser, University Massachusetts AmherstM. Marks, N. Verghese, Dow ChemicalModeling the Yield Behavior of Glassy Networks using Molecular-Based Parameters 2263A.J. Lesser, K.J. Calzia, University Massachusetts AmherstThe Temperature Dependent Viscoelastic and Viscoplastic Behaviour of Nylon 12 2267N.A. McFerran, C. Armstrong, T. McNally, G. Menary, G. McNally, The Queens University of BelfastPerformance Comparison of a Custom Strain Gage Based Load Cell with a Rheometric Series Force

Rebalance Transducer 2272S.A. Hutcheson, X.F. Shi, G.B. McKenna, Texas Tech UniversityFinite Element Analysis of Hyperelastic Materials: Elastomeric Seal 2277K.K. Kar, Indian Institute of Technology, Kanpur, and Massachusetts Institute of TechnologyM. Rawat, Indian Institute of TechnologyJ.U. Otaigbe, The University of Southern Mississippi

xxxii/ANTEC 2004

T25—Founder Award Symposium in Honor of Professor M.T. Shaw

High Tg Polymer/Electroactive Organic Compound Blends for LED/PV Applications 2284X. Jiang, L. Robeson, W. Burgoyne, Jr., Corporate R&D, Air Products and Chemicals, Inc.Review of the Ultrasensitive Oxygen Consumption Method Used for Making More Reliable

Extrapolated Predictions of Polymer Lifetimes 2289K. Gillen, Organic Materials, Sandia National LaboratoriesM. Celina, R. Bernstein, Sandia National LaboratoriesReal-Time Synchrotron X-ray Techniques for Polymer Processing Research 2294B. Hsiao, Chemistry, State University of New York/Stony BrookRecent Developments in Melt Rheometry 2295J. Dealy, Chemical Engineering, McGill UniversityThe Use of Rheology to Characterize the Branching Structure in Sparsely Branched Metallocene

Catalyzed Polyethylenes 2296D. Baird, P. Doerpinghaus, Chemical Engineering, Virginia TechUnderstanding and Control of Sharkskin 2301K. Migler, Polymers Division, National Institute of Standards and TechnologyReal-time Monitoring of Mass-Change During the Structural Evolution of an Epoxy Glass Subsequent

to Relative Humidity Jumps Through the Glass Transition 2302L. Banda, Y. Zheng, G. McKenna, M. Alcoutlabi, Department of Chemical Engineering, Texas Tech

UniversityFabrication and Characterization of Structure Membranes for Proton Transport 2307M. Shaw, Polymer Program and Chemical Engineering, University of ConnecticutJ. Gasa, Polymer Program, IMS, University of Connecticut

T26—Polymer Nanostructures: Surface Interactions & Electrical Conductivity

Applications of Nanostructured Carbons in Polymer-Based Materials 2314D.D. L. Chung, University at Buffalo, SUNYThermal and Electrical Analysis of Vapor Grown Carbon Nanofiber/Polyoxymethylene

(VGCNF/POM) Composites 2319S. Yang, K. Lozano, R. Jones, L. Espinoza, A. Lomeli, Univ Texas Pan AmericanSmart Adhesion: Controlling Polymer Interfaces Through Patterning 2324A.J. Crosby, University of MassachusettsMechanical Properties of Epoxy-Multiwalled Carbon Nanotube Composites 2328Z. Yang, N.A. D'Souza, University of North TexasInvestigation of Reinforcement Mechanisms of Carbon Nanotube-Polymer Composites with Numerical

Simulation 2333L. Zhu, K.A. Narh, New Jersey Institute of TechnologyEffects of Free-Surface and Interfacial Effects and Plasticizer Content on the Distribution of Glass

Transition Temperatures in Nanoconfined Polymers 2338CJ. Ellison, J.M. Torkelson, Northwestern UniversityEffect of Montmorillonite Layered Silicate (MLS) on Crystallization Growth Rate in Semi-Crystalline

PET Nanocomposites 2343S. Pendse, A. Ranade, N. D'Souza, University of North TexasJ.A. Ratto, U.S. Army Soldier System CommandEpoxy + Montmorillonite Nanocomposite Processing Influences on Dispersion 2348P. Butzloff, N.A. D'Souza, University of North Texas

W24—High Resolution Polymer Microscopy and Surface Analysis

Micro-Thermomechanical Properties of Composite Polymer Surfaces as Probed by Scanning ProbeMicroscopy 2356

V. Tsukruk , Iowa State UniversityHigh Resolution Polymer Microscopy at GE's Global Research Center 2357J.A. Teetsov, L. Denault, A. Alizadeh, S. Ghanti, W. Cicha, E. Hall, General Electric Global Research

CenterConfocal Raman Imaging of Heterogeneous Polymeric Materials 2360CA. Michaels, D.B. Klinedinst, National Institute of Standards and TechnologyD.B. Chase, DuPont

ANTEC 2004 /xxxiii

Combining Mechanics and Chemistry to Generate Controlled Nano-Scale Topography in PolymerThin Films 2363

H.T. Evensen, Univeristy ofWisconsin-PlattevilleR.W. Carpick, F. Denes, S. Manolache, University of Wisconsin-MadisonS. Zhao, Gentel BiosurfacesNear Field Infrared Microscopy of Polymer Surfaces 2364S. Romanov, L. Stebounova, B. Akhremitchev, G. Walker, University of PittsburghThermomechanical Probing of Molecular Mobilities of Nanoconfined and Structurally Constrained

Polymer Films 2369R.M. Overney, T. Gray, J. Wei, S. Sills, University of WashingtonMapping Polymeric Properties using Combinatorial and High-Throughput Methods: Adhesion and

Mechanical Properties 2374CM. Stafford, A.M. Forster, A. Chiche, A. Karim, M.Y.M. Chiang, National Institute of Standards and

TechnologyThe Use of Inverse Gas Chromatography to Study Surface Thermal Oxidation of Polypropylene 2380A.A. Calhoun, P.D. Nicholson, E.N. Chiang, A.B. Barnes, Whitman College

W11—Permeation Testing of Polymer Materials

Characterization of the Transport Properties in Elastomeric Polymer Membranes By FT-IR-ATR 2386J. Sloan, Weapons & Materials Research Directorate, U.S. Army Research LabPermselectivity Measurements of Ion Beam Modified Barrier Membranes for Improved

Chemical/Biological Protective Clothing 2390W. Zukas, E. Wilusz, Individual Protection Directorate, U.S. Army Research, Development and Engineering

CommandF. Karasz, Department of Polymer Science and Engineering, University of MassachusettsUltra-Low Permeation Test Method for Fuel System Applications 2395P. Delbarre, V. Adam, B. Bonazza, Materials Engineering, TI AutomotivePermeability Measurement of Polymers and Layered Silicate Nanocomposites 2405A. Ranade, N. D'Souza, Materials Science andEng., University of North TexasB. Gnade, Electrical Eng. and Chemistry, University of Texas at DallasJ. Ratto, U.S. Army Soldier Systems Center RDECOMLiquid Permeation of Elastomers with a Fully Flooded Cell Test Method 2410A. Rodriguez, Individual Protection Directorate, U.S. Army Research, Development and Engineering

CommandD. Rivin, Science and Technology Directorate, U.S. Army Research, Development and Engineering

CommandEffects of Nanoparticle Morphology on the Permeation and Physical Properties of Polymer

Nanocomposites 2415W. Zukas, Individual Protection Directorate, U.S. Army Research, Development and Engineering CommandD. Froio, J. Ratto, A. Rodriguez, M. Sennett, C. Thellen, E. Welsh, D. Ziegler, Science and Technology

Directorate, U.S. Army Research, Development and Engineering Command

W25—Biopolymers: Blends and Composites

The Effect of Montmorillonite Layered Silicates on the Properties of Ethylene Co-Vinyl Alcohol BlownFilm Nanocomposites 2422

D.L. Froio, D. Ziegler, C. Orroth, C. Thellen, J. Lucciarini, J.A. Ratto, US Army Soldier Systems CenterRDECOM

Effect of Fiber Source on Cellulose Reinforced Polymer Nanocomposites 2427W.J. Orts, S. Imam, J. Shey, G.M. Glenn, M. Inglesby, M. Guttman, A. Nguyen, USDA-ARS-WRRCJ.F. Revol, PAPRICANHarnessing Natural Polymers and Fibers for the Development of Biocomposites 2432G. Markevicius, V. Malhotra, Southern Illinois UniversityProcessing, Performance and Evaluation of Biopolymers and Composites 2437S.H. Imam, G.M. Glenn, J. Shey, W.J. Orts, D. Wood, T. Nguyen, K. Cornish, A. Clamczynski,

WRRC-PWA-ARS-USDA

xxxiv /ANTEC 2004

Novel Solvent-Free Method for Functionalization of Polyhydroxyalkanoates : Synthesis andCharacterizations 2442

M. Misra, S.M. Desai, A.K. Mohanty, L.T. Drzal, Michigan State UniversityEffect of Heat-Sealing Temperature on Mechanical Properties at Heat-Sealed Parts in Biodegradable

Plastic Film 2447Y. Hashimoto, Fuji-Impulse Co., Ltd.M. Mizoguchi, Yamagata UniversityT. Tetsuya, PerkinElmer Japan Co., Ltd.K. Kazuo, Kyoto Municipal Institute of Industrial ResearchY. Fujita, Sun-HosoH. Hamada, U. Ishiaku, Kyoto Institute of TechnologyMorphological and Functional Properties Acetyiated Starch Foams Extruded with Cellulose 2452J. Guan, M.A. Hanna, University of Nebraska-LincolnDevelopment of a Gelation Model for Methyl Cellulose Hydrogels 2479S.C. Joshi, Y.C. Lam, L. Lin, Nanyang Technological UniversityFiber Reinforced Extruded Starch Foam 2484G.M. Glenn, S.H. Imam, W.J. Orts, A. Klamczynski, USDA-ARS, WRRC

THERMOPLASTIC MATERIALS AND FOAMS - 29

M8—Advances in Nanopolymers and their Applications

Synthesis and Characterization of Nanopolymer: High Density Polyethylene 2490K.K. Kar, Indian Institute of Technology, Kanpur, and Massachusetts Institute of TechnologyP. Paik, Indian Institute of TechnologyJ.U. Otaigbe, The University of Southern MississippiCharacterization of Structure and Viscoelastic Properties of Polypropylene Nanopolymer 2495K.K. Kar, Indian Institute of Technology, Kanpur, and Massachusetts Institute of TechnologyP. Paik, Indian Institute of TechnologyJ.U. Otaigbe, The University of Southern MississippiSynthesis and Characterization of Nano Polystyrene: Effect of Temperature, Shear Rate and Solvents 2500K.K. Kar, Indian Institute of Technology, Kanpur, and Massachusetts Institute ofTechnologyR. Kumar, P. Paik, Indian Institute ofTechnology, KanpurJ.U. Otaigbe, The University of Southern MississippiScanning Electron Microscopy, Spectroscopy and Viscoelastic Studies of Nano Low Density

Polyethylene 2505K.K. Kar, Indian Institute ofTechnology, Kanpur, and Massachusetts Institute ofTechnologyA.S. Suresrao, P. Paik, Indian Institute ofTechnology, KanpurJ.U. Otaigbe, The University of Southern MississippiOptimum Content of Clay for Microcellular LDPE/Clay Nanocomposite Foams Blown with CO2 2510K.H. Wang, Y.H. Lee, C.B. Park, University of TorontoKinetics of Gas Sorption and Diffusion in Polymer-Clay Nanocomposites 2515A.R. Manninen, H.E. Naguib, University of OttawaV. Nawaby, M. Day, National Research Council Canada

M25—Thermoplastics Foams: Advances and Applications Part I

Moisture Resistant Nylon - Dimensional Stability 2522J.S. Chung, Frontier Performance Polymers Corp.T. Woo, C.W. Oakley, J.F. Osterndorf, TACOM-ARDEC, US ArmyV. Mehta, Polymer Dynamix LLCEffect of Additives on the Solubility and Diffusivity of CO2 in Polystyrene 2527C. Vachon, J. Tatibouet, National Research Council CanadaFundamental Understanding of the ABS-CO2 Interactions, its Retrograde Behavior and Development

of Nanocellular Structures 2532A.V. Nawaby, National Research Council of CanadaY.P. Handa, Pactiv Corporation

ANTEC 2004 / xxxy

An Investigation of Microcellular Injection Molding (MuCell) on the Structure-Property Relationshipsof Engineering Thermoplastics used in Exterior Automotive Applications 2537

S. Edwards, J. Kennedy, J. Nicholson, Schefenacker Vision Systems AustraliaN.R. Choudhury, M. Provatas, University of South AustraliaFundamental Study of CBA-Blown Bubble Growth and Collapse under Atmospheric Pressure 2542D. Xu, C.B. Park, R.G. Fenton, H. Jiang, University of TorontoR. Pop-Iliev, University of Ontario Institute ofTechnologyNucleation in Foams as Assessed by In-Line Ultrasonic Measurements 2552J. Tatibouet, R. Gendron, Industrial Materials Institute/National Research Council CanadaMethods of Expanding Polystyrene to Ultra Low-Density Foam 2557CP. Park, Bushitol CorporationTorsion Properties of Cylindrical Polymer Foams 2562D. Rodrigue, Y. Pelletier, R. Gosselin, Laval UniversityComparison of SS-Based and SL-Based Estimation of Gas Solubility 2566G. Li, J. Wang, C.B. Park, University of TorontoP. Moulinie, Bayer PolymersR. Simha, Case Western Reserve University

T9—Advances in Polymerization and Applications of Polymers Produced

Physical and Mechanical Properties of Composites Based on Syndiotactic Polistyrene 2578E. Kowalska, Z. Wielgosz, S. Galka, S. Pasynkiewicz, Industrial Chemistry Research InstituteW. Skupinski, Industrial Chemistry Research Institute and Warsaw University ofTechnologyIsothermal Crystallization Kinetics and Morphology of Polypropylene and Propylene/Ethylene (P/E)

Copolymers 2591C.H. Stephens, A.R. Kamdar, A. Hiltner, E. Baer, Case Western Reserve UniversityB.C. Poon, S. Chum, P. Ansems, K. Swogger, The Dow Chemical CompanyComparison of the Elastomeric Properties of Developmental Performance Elastomers (DPE's) and

Ethylene-Octene (E/O) Elastomers 2596P. Dias, A. Hiltner, E. Baer, Case Western Reserve UniversityP. Ansems, S. Chum, The Dow Chemical CompanyStructure-Property Relationships and Applications of Novel Flexible TPO Based on Blends of

Developmental Performance Elastomer and Polypropylene 2600W. Cheung, R. Wevers, C. Diehl, M. Prieto, P. Cham, Dow ChemicalNovel Propylene Based Fibers 2606S. Ethiopia, A. Chang, K. Stewart, R. Pepper, P.S. Chum, The Dow Chemical Company

T22—Advances in Thermoplastic Foams and Applications Part II

Prediction of Density Variation in Thick Microcellular Sheets 2610K.V. Nadella, F. Mehta, V. Kumar, W. Li, University of WashingtonDesign of a Foaming Simulation System with a High Pressure Drop Rate 2615Q. Guo, J. Wang, C. Park, University of TorontoM. Oshima, Kyoto UniversityEffects of Nano-Particles on Density Reduction and Cell Morphology of Extruded mPE/Wood-

Fiber/Nano Composites 2620G. Guo, K.H. Wang, C.B. Park, Y.S. Kim, G. Li, University of TorontoIncrease of Open-Cell Content by Introducing a Secondary Blowing Agent 2626P.C Lee, C.B. Park, J. Wang, University of TorontoH.E. Naguib, University of OttawaSolid-State Polyimide Foaming from Powder Precursors: Effect of Particle Morphology on the

Diffusive Phenomena 2631C.I. Cano, R.B. Pipes, The University of AkronPorous Polystyrene Foam Produced at Supercritical Conditions 2636CM. Wong, W.C. Liang, Union Chemical Laboratories!Industrial Technology Research InstituteCH. Ying, M.L. Hung, Energy & Resources Laboratories/Industrial Technology Research Institute

xxxvi/ANTEC 2004

Microporous Films from Polymer Blends and Composites - Processing/ Structure/PropertyRelationships 2641

M. Xanthos, J. Wu, NJInstitute ofTechnologyEffects of CO2 Content on the Expansion Behaviors of PS Foams 2646X. Xu, Brite Manufacturing Inc.D. Xu, C.B. Park, University of TorontoAnalysis of Solubility and Spinodal Decomposition for Thermoplastic Foams 2653C.Y. Huang, L. Zhu, New Jersey Institute ofTechnologyS.T. Lee, J. Jun, Sealed Air Corporation

W10—Advances in Thermoplastic Foams and Applications: Part III

Entrained Gas Process for Injection Molding 2660J. Xu, Engel Machinery Inc.Microcellular Wood Fiber Reinforced Polypropylene Composites: A Comparative Study Between

Injection Molding and Extrusion Processes 26650. Faruk, A.K. Bledzki, Institute for Materials ScienceValidation of Shrinkage Predications for Injection Molded Parts 2670S. Prasad, S. Sharma, M. Jariwala, CM.F.Barry, University of Massachusetts LowellEffect of and Temperature on Cell Numbers of Amorphous Foamed Plastics 2674K. Muratani, M. Shimbo, Y. Miyano, Kanazawa Institute ofTechnologyMechanical and Fracture Behavior of Rigid-Rod Self Reinforced Polymers 2679N. Malkovich, R. Chavers, MPTK. Battjes, R.A. Bubeck, Michigan Molecular InstituteMechanical Properties of Interfaceless Composites 2683O.A. Khondker, T. Fukui, X. Yang, A. Nakai, H. Hamada, Kyoto Institute ofTechnology

SIG010 - ALLOYS AND BLENDS

W15—Morphology Development and Characterization of Various Polymeric Blend Systems andthe Effect of Compatibilization and Compounding on Specific Polymer Systems

Compatibility and Mechanical Property in Polymer Blends of a-MSAN/SMI 2688J.Lee, J. Cha, S.-H. Chea, S.-L. Kim, LG chemEffects of Incorporating Recycled HDPE to Virgin HDPE and LDPE to Produce Tubular Film 2694J.B. Sanchez, R. Grimaud, E. Galvis, R. Perera, Universidad Simon BolivarMixing and Compatibilization of Polymer Blends by Solid-State Shear Pulverization: Effects of

Microscopic Composition, Processing Aids, and Pulverization Parameters 2699A.H. Lebovitz, J.M. Torkelson, Northwestern UniversityA Model to Predict the Development of Particle Morphology in Seeded Emulsion Polymerizations 2704S. Mendoza-Fernandez, CF. Jasso-Gastinel, L.J. Gonzalez-Ortiz, Universidad de GuadalajaraPower Ultrasonic Irradiation Effects on the Mechanical Properties of Polymer B lends 2709J.G. Ryu, S.H. Kong, J.W. Lee, Sogang UniversityH. Kim, Dankook UniversityNylon 66 - Maleated EPDM Polyblends 2714R.D. Deanin, S. Mathur, University of Massachusetts Lowell

W32—Polymer Blends - Investigation and Characterization of Performance Enhancementsby Various Novel and Practical Approaches

Short Fiber Glass Reinforcement of Ductile Resins 2718R.R. Gallucci, General Electric PlasticsA Study of Processing and Characterization of Short Glass Fiber Reinforced ABS/PA6 Blends 2723G. Ozkoc, G. Bayram, E. Bayramli, Middle East Technical UniversityCompounding Order and Mechanical Properties in PP/PE/Talc Compound 2728T. Okumura, Technology Research Institute of Osaka PrefectureH. Hamada, Kyoto Institute ofTechnologyEffect of Blending Sequence on the Modulus, Toughness, and Structure of PC/PBT/talc Ternary

Composites 2733W. DePolo, D.G. Baird, Virginia Polytechnic Institute

ANTEC 2004 /xxxvii

Influence of Type of Filler on Natural Rubber Properties 2738M. Hernandez, M. Ichazo, J. Gonzalez, Universidad Simon BolivarC. Albano, Universidad Central de VenezuelaProperties of Injection Moldable Blends of {Latex/Wood Flour recipes} and Polypropylene 2743S. Morneau, SPRLJ.P. Ibar, Stratek Plastics LtdModification of Nylon 6,6 and Metallocene Linear Low-Density Polyethylenes Blends Using Ethylene

Methacrylic Acidlonomers 2748F. Gribben, G.M. McNally, R.W. Murphy, T. McNally, Queens University BelfastThe Performance of Poly vinyl Chloride / Thermoplastic Polyurethane Blends 2753D.C McConnell, G.M. McNally, W.R. Murphy, Queens, Belfast

PLASTIC PIPING PRODUCTS

W17—Plastic Piping

Steel Wire Reinforced Plastic Composite Pipe 2760L.J. Broutman, D.B. Edwards, B.D. Agarwal, Bodycote Broutman, Inc.The Effects of High Stress and Material Constraint on the Fracture Appearance of a Polyethylene

Liner Pipe 2764D.B. Edwards, Bodycote BroutmanR. Miller, Poly tubes (West), Inc.Modelling Mechanisms of Brittle Oxidative Degradation to Ensure Plastic Pipe Material Performance 2769K.E. Oliphant, P. Vibien, J.D. Kim, S. Chung, M. Toro, Jana LaboratoriesPOLYTRA© Full Traceability in PE Valve Manufacturing 2774R.W. Conley, Kerotest Manufacturing Corp.Structural Design of Stormwater Chambers 2779P.A. Sharff, J.L. Beaver, T.J. McGrath, Simpson Gumpertz & Heger Inc.

VOLUME III - SPECIAL AREASSPE DIVISIONS

INT1—Interactive Session One - Engineering Properties & Structure Division and Alloys & BlendsSIG Joint with Engineering Properties & Structure Division

Melt Residence Time Distributions in Smart Blenders and Continuous Chaotic Mixers 2788A. Joshi, D.A. Zumbrunnen, Clemson UniversityModeling of Mixers for Polymer Processing 2793U. Sundararaj, Y. Bai, K. Nandakumar, University of AlbertaThe Effects of Nanoclay on Morphology Development in Immiscible Polymer Systems by Chaotic

Mixing 2798D. Dharaiya, S. Jana, The University of AkronControllable Morphology Development by Chaotic Advectionof PP-LDPE Blends in a Smart Blender

Prototype 2803A.V. Dhoble, D.A. Zumbrunnen, Clemson UniversitySynthesis of Polyamide-Polyesters base Random-Block Terpolymers in a Twin Screw Extruder via

Reactive Extrusion : Process and Properties 2809I. Kim, J.L. White, Polymer EngineeringSynthesis of Thermoplastic Polyurethanes by Chaotic Mixing 2814C. Jung, S.C. Jana, The University of AkronAnalysis of the Effects of Flow Reorientation in Chaotic Mixing Flows on Coalescence in Blends of

Polypropylene and Polystyrene 2819J.E. Perilla, S.C. Jana, The University of AkronInvesigations of Linear and Non-Linear Stress Optical Regimes during Uniaxial and Simultaneous

Biaxial Stretching of Poly Lactic Acid Films by Real Time True Stress-Strain-BirefringenceTechnique 2824

X. Ou, M. Cakmak, University of AkronTensile Testing of Microtomed Sections from Molded Parts 2829R.M. Thurston, J.D. Clay, Battelle Memorial Institute

xxxviii/ANTEC 2004