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Annual meeting of the Astrophysical Chemistry Group Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Society on progress in astrochemistry. Meeting to Meeting to discuss discuss connections connections between between interstellar interstellar and and terrestrial terrestrial plasma plasma chemistry. chemistry.

Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

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Page 1: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

Annual meeting of the Astrophysical Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Chemistry Group of the Royal Chemical

Society and Royal Astronomical Society on Society and Royal Astronomical Society on progress in astrochemistry.progress in astrochemistry.

Meeting Meeting to discussto discuss

connectionconnections between s between interstellar interstellar and and terrestrial terrestrial plasma plasma chemistry.chemistry.

Page 2: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

From Astrochemistry From Astrochemistry viewview

Meeting discussed key (recent) Meeting discussed key (recent) advances in astrochemistryadvances in astrochemistry

Page 3: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

From Astrochemistry From Astrochemistry viewview

The huge amount of data that new The huge amount of data that new observations has/will generate (e.g observations has/will generate (e.g Fuller Alma; Tielens, Roueff)Fuller Alma; Tielens, Roueff)

The challenge to interpret this data – The challenge to interpret this data – need for A&M dataneed for A&M data

The use/development of chemical The use/development of chemical models (eg Herbst, Walsh, Woods)models (eg Herbst, Walsh, Woods)

Page 4: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

From Astrochemistry From Astrochemistry viewview

We have seen continued challenge of We have seen continued challenge of exploring the surface (dust) chemistry exploring the surface (dust) chemistry (Herbst, Goumans) (Herbst, Goumans)

Eg to explain HEg to explain H22 formation (Roueff, formation (Roueff, Lemaire)Lemaire)

Larger compounds generated by ice Larger compounds generated by ice processingprocessing

(McCoustra, Ioppolo, Jheeta)(McCoustra, Ioppolo, Jheeta)

Page 5: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

From Astrochemistry From Astrochemistry viewview

Challenge of exploring the surface Challenge of exploring the surface (dust) chemistry EU/UK well set to (dust) chemistry EU/UK well set to tackle this challenge tackle this challenge

Page 6: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

Data overload ?Data overload ?

DatabasesDatabases Assembly, Assembly,

intercomparisointercomparison, n, error/sensitiviterror/sensitivity analysisy analysis

Page 7: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

COST is supported by the EU RTD Framework Programme

ESF provides the COST Office through an EC contract

VAMDC

• A database of Atomic and molecular data for applications including astronomy.

• Http://www.vamdc.org/

Page 8: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

COST is supported by the EU RTD Framework Programme

ESF provides the COST Office through an EC contract

VAMDC - Brussels - Nov 08

Page 9: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

COST is supported by the EU RTD Framework Programme

ESF provides the COST Office through an EC contract

KEY VAMDC OUTCOMES Develop or/and extend

standards for interoperability of AM resources

Implementation of 17 selected databases Compatibility with existing extraction tools

Create a safe environment where latest AM data can be easily published (even small sets)

Linking producers and users

KEY BENEFITS

Uniform access, i.e. saving time with format of data, tools development

Increase level of scientific analysis of ground/space missions or experiments good standardisation

implies Documentation allows cross-matching

of different sets of AM data

allows wide access to the latest published AM data

Page 10: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

This meeting aimed to bring (lab) This meeting aimed to bring (lab) plasma and astrochemistry plasma and astrochemistry

community togethercommunity together Question Question Are they compatible ? Are they compatible ?

Time scales (general issue for lab Time scales (general issue for lab surface chemistry)surface chemistry)

Densities (three body collisions Densities (three body collisions in lab plasma)in lab plasma)

Page 11: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

Electron attachmentElectron attachment

Anions seen in ISM - exciting Anions seen in ISM - exciting new area of astrochemistry new area of astrochemistry

e + Ae + A AA-- + h + hνν

In lab plasmas third body In lab plasmas third body stabilises Astabilises A- - rdensities too low in rdensities too low in ISM etcISM etc

Page 12: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

Electron attachmentElectron attachment

Plasmas provide a lot of date on Plasmas provide a lot of date on (dissociate) electron attachment (dissociate) electron attachment rate constants (cross sections) rate constants (cross sections)

e + ABe + AB AA-- + B + B

Page 13: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

Are experimental Are experimental conditions too extreme ?conditions too extreme ?

Plasma surface reactions – plasmas Plasma surface reactions – plasmas are reactors with walls (Welzel, are reactors with walls (Welzel, Marinov)Marinov)

Benefit – Gabriel can see spectra that Benefit – Gabriel can see spectra that ‘mimic’ astrophysical observations.‘mimic’ astrophysical observations. Eg Eg vibrationally excited H2vibrationally excited H2

But then plasma scientists need to But then plasma scientists need to explain limits to astronomers explain limits to astronomers

Page 14: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

Plasma reactors -- good Plasma reactors -- good for spectroscopyfor spectroscopy

Linartz, Schlemmer, Galue, Linartz, Schlemmer, Galue, Indeed fundamental to making species Indeed fundamental to making species

(radical ions) to measure spectra (eg (radical ions) to measure spectra (eg anions)anions)

Hot plasmas – hot water – HHot plasmas – hot water – H33++

PAHs, clusters need plasmas > atmospheric PAHs, clusters need plasmas > atmospheric pressure dominated by clusterspressure dominated by clusters

Dust formation (Kovacevic, Goedheer) Dust formation (Kovacevic, Goedheer)

eg Ceg C22 H H22 plasmas plasmas

Page 15: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

Plasmas are used as Plasmas are used as planetary atmosphere planetary atmosphere

mimicsmimics Titan – plasmas Titan – plasmas

used to identify used to identify anionsanions

Mars chemistry Mars chemistry – ozone/water – ozone/water interactionsinteractions

Astrobiology – Astrobiology – (Urey Miller)(Urey Miller)

Page 16: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

But are we separated by But are we separated by language?language?

Evidence for two Evidence for two communities having communities having common interests but common interests but the overlap is poorthe overlap is poor

Terminology (and units) Terminology (and units) often differentoften different

So majority of both So majority of both communities remain in communities remain in ‘wings’ ‘wings’

Page 17: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

How to improve How to improve communication?communication?

Need more meetings – tutorials ?Need more meetings – tutorials ? What are astrochemistry What are astrochemistry

questions ?questions ? How do plasmas work ?How do plasmas work ?

What can one community do to What can one community do to help other ?help other ?

What can one help other ?What can one help other ?

Page 18: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

Meetings not enoughMeetings not enough

Exchange people and Exchange people and ideas ideas

Visits ! Visits !

Page 19: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

COST is supported by the EU RTD Framework Programme

ESF provides the COST Office through an EC contract

The Chemical Cosmos: Understanding Chemistry in Astronomical Environments

CM0805Start date: 17/04/2009End date: 16/04/2013

Nigel J Mason Chair The Open University / UK [email protected]

Beverley Bishop Administrator The Open University [email protected]

Page 20: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

COST is supported by the EU RTD Framework Programme

ESF provides the COST Office through an EC contract

• 22 countries:• Austria• Belgium• Czech Republic• Denmark • Finland• France• Germany• Hungary • Iceland• Ireland• Italy • Latvia• Netherlands• Poland• Portugal• Serbia• Slovakia• Spain• Slovania• Sweden • United Kingdom

22 COST countries

Chemical Cosmos-Partners

Page 21: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

COST is supported by the EU RTD Framework Programme

ESF provides the COST Office through an EC contract

Scientific context and objectives

• The main objective of this Action is to study chemical processes relevant to the physical conditions encountered in the interstellar medium, and on the surface and in the atmospheres of planetary bodies.

• The Action aims to provide new insights into the dynamics of the chemical reactions leading to molecular synthesis under such conditions and reveal how these are influenced by the ambient temperature and pressure.

• Special attention will also be given to the study of the novel surface chemistry prevalent on interstellar medium dust grains and planetary surfaces.

• The Action also aims to combine such laboratory data with complementary chemical models to allow a fuller interpretation of observational data.

Page 22: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

COST is supported by the EU RTD Framework Programme

ESF provides the COST Office through an EC contract

Organised in 3 Working groups

• Working group 1; Radical- and Ion-induced reactions in the interstellar medium (Gas phase chemistry) Wolf Geppert Stockholm

• Working group 2;. Heterogeneous and ice chemistry (Surface chemistry) Maria Palumbo Catania

• Working group 3;. Chemistry of planetary atmospheres (Models and observations ) exoplanets Christian Muller Brussels

Page 23: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

COST is supported by the EU RTD Framework Programme

ESF provides the COST Office through an EC contract

COST Astrochemistry meeting2011

• Malta October 12-14, 2011 in Valletta

Page 24: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

COST is supported by the EU RTD Framework Programme

ESF provides the COST Office through an EC contract

Short Term Scientific missions

Short visits between member countries (not member labs/groups)

Typically up to 1 month average funds up to 2000 euros

Simple application process (on line) and simple report (1 page A4)

Page 25: Annual meeting of the Astrophysical Chemistry Group of the Royal Chemical Society and Royal Astronomical Society on progress in astrochemistry. Meeting

COST is supported by the EU RTD Framework Programme

ESF provides the COST Office through an EC contract

So use STSMs for these links

• Eg willing to set fund for this year for 4/5 such visits to follow up this meeting

• OVER TO YOU !!

[email protected]

[email protected]