M/s. Aarti Industries Limited (Unit-III), GIDC Estate, Jhagadia.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 11

ANNEXURE I

PROPOSED TERMS OF REFERENCE

As per standard ToR of organic manufacturing sector issued by MoEF&CC.

2

1

3

4

5

6

7

BA D F G H I JE

BA C D F G H I JE

8

2

1

3

4

5

6

7

8

C

A0

KEY PLAN:

NORTH

PLOT NO:- 758/1-2-3, G.I.D.C. INDUS. ESTATE, JHAGADIA. 393 110

NO.

DRAWN

REVISIONS

CHECKEDDESCRIPTION

DATE

S

W

E

SW

SE

NE

NW

N

GENERAL NOTES:

EXPANSION

PLOT NO. 756/7

AJANTA

PANOLI INTERMEDIATE

PLOT NO. 756/3A,B , 756/2A,B

AARTI INDUSTRIES LIMITED UNIT-1

PLOT NO. 778

PLOT NO. 756/4 A/B

PLOT NO. 756/5/A/B

PLOT NO. 779

PLOT NO. 756/6

GID

C R

OA

D

GID

C R

OA

D

ENDEKA CERAMIC

STAR

PANOLI INTERMEDIATE

GIDC ROAD

GIDC ROAD

Chemie Organics India

KLJ Organics Ltd.

GIDC ROAD

GID

C R

OA

D

KEY PLAN

PLOT NO. 758/1-2-3

GIDC ROAD

DCM

UPL

SURVEY NO. 126

UNIT-2

SURVEY NO 135

SURVEY NO 136

PLOT NO. 756/8 ,756/9

TOTAL PLOT AREA 42,735 Sqm.

GREEN BELT 5,570 Sqm.

Security Cabin

2

Sub Station

3

Security Cabin

4

Security Cabin

4

WAREHOUSE

9M WIDE ROAD

8M

W

ID

E R

OA

D

AREA FOR

COOLING TOWER

CENTRAL HYDRANT &

RAW WATER STORAGE

(ABOVE GROUND / UG)

Hydrogen Plant

1

13

PILOT PLANT

5

HYDROGENATION &

NITRATION TANK FARM

8

9

10

11

12

14

9M WIDE ROAD

Ca(OH)2 Plant

16

Multi story Building ( Division 3 Office

Sitting,Dining,Locker&

Change Room,Fire Tender &

Ambulance Parking,Central Safety

Office&OHC

PIP

E R

AC

K B

AY

PIP

E R

AC

K B

AY

PIPE RACK BAY

15

HE

IG

HT

: 21337

CH

LO

RIN

AT

OR

ID

2300

HE

IG

HT

: 15530

AC

ID

S

TR

IP

PE

R

ID

1000

HE

IG

HT

: 26942

BZ

C

OLU

MN

ID

1350

HE

IG

HT

: 26754

BZ

C

OLU

MN

ID

850

HE

IG

HT

: 20200

DC

B C

OLU

MN

ID

1900

HE

IG

HT

: 34710

MC

B C

OLU

MN

ID

1400

6C

01

04

6C

01

05

6C

01

03

6C

01

02

6C

01

01

6R

01

01

HE

IG

HT

: 21337

6R

0101

ID

2300

HE

IG

HT

: 21337

ID

2300

6R

0101

HE

IG

HT

: 21337

ID

2300

6R

0101

HE

IG

HT

: 21337

ID

2300

6R

0101

20M x12.0M

20M x12.0M

32.0x20.6M

24.0x10.0M

20.6x13.17M

20.6x18.0M

20.6x10.0M

20.6x12.8M

5.0x5.0M

30.36x26.4M

75.0x20.0M

40.0x35.0M

40.0x29.0M

5.0x5.0M

5.0x5.0M

18

30.0x29.0M

S.P.P.

RE

WIN

DE

R

B.S.R.

35.0 X 15.3

FINISHING

HOUSEPAPER MACHINE AREA

CT-1 CT-2

PIPE RACK BAYPIPE RACK BAY

TOLUENE CHLORINATION

Security

Cabin

75 TWO WHEELER PARKING

30.0 M W I D E R O A D

30

C

AR

P

AR

KIN

G

GATE

Residue

storage shed &

Chilled Water vam

20.5x10.5M

Toluene Chlorination

Tank Farm

14.0x13.5M

ETP Plant

6

TECHNOLOGY

BUILDING

17

19

20

27

12x8M

56.8x12.5

6ST0408B

Ø8000mm

CAP.500KL

6ST0407

Ø5700mm

CAP.200KL

6ST0410

Ø3400mm

CAP.40KL

6ST0413

Ø3100mm

CAP.30KL

9M

W

ID

E R

OA

D

9M

W

ID

E R

OA

D

TA

NK

ER

MO

VE

ME

NT

30.0X30.0M

22

Hydrogenation

Plant

Hydrogenation

Separation Plant

FLOURINATION PLANT

24.0 x 18.0mtr.

Production Plant

TCNB

2,5 DCNB

TCNB TANK FARM

2,5 DCNB FARM

M/s. Aarti Industries Limited (Unit-III), GIDC Estate, Jhagadia.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 13

ANNEXURE III

LIST OF DIRECTORS WITH ADDRESS

SR. NO.

NAME OF DIRECTOR

DESIGNATION ADDRESS TELEPHONE NO.

1.

Shri. Rajendra V Gogri

Chairman & Managing Director

1401, Antriksh, Murar Road, Mulund (West), Mumbai -400080

022-67976666

2.

Shri. Rashesh C Gogri

ViceChairman Managing Director

601, Antriksh, Murar Road, Mulund (West), Mumbai -400080

022-67976666

3. Shri. Parimal H Desai

Whole -time Director A-1403, 14th floor, Runwal heights, LBS marg, Mulund (West), Mumbai-400080

022-67976666

4. Shri. Manoj M Chheda

Whole -time Director Dunhill Villa Co. Op. Hsg-Soc.Ltd, esant Road, Santracruz (West), Mumbai -400054

022-67976666

5. Shri. Kirit R Mehta Whole -time Director 10, Pushpendra Mansion, Phirojshah Mehta Road, Santracruz (West), Mumbai-400054

0260-2400366

6. Smt. Hetal Gogri Gala

Whole -time Director 558-B, Gopal Sadan, Block No.801, 8th floor, Jamshed Road, Matunga (East)Mumbai 400019

022-67976666

7. Shri. Renil R Gogri Whole -time Director 1401, Antriksh, Murar Road, Mulund (West), Mumbai -400080

022-67976666

M/s. Aarti Industries Limited (Unit-III), GIDC Estate, Jhagadia.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 14

ANNEXURE IV

LIST OF PRODUCTS AND THEIR PRODUCTION CAPACITY ALONG WITH RAWMATERIAL LIST OF PRODUCTS AND THEIR PRODUCTION CAPACITY

Sr. No. Name of Product CAS No. Total Quantity in MT/Month

End use

Organic products

1. 2,5 Di Chloro Nitro Benzene AND/OR 89-61-2

2500

Dyes Intermediate

2. 2,3,4 Tri Chloro Nitro Benzene AND/OR17700-09-3 Raw material for agro

and other chemicals

3. 2,4,5 Tri Chloro Nitro Benzene AND/OR 89-69-0 Pigment Intermediate

4. 3 5 DC4FNB (Nitration product) 3107-19-5

200 Raw material for agro and other chemicals

5. 2, 5 Dichloro Aniline 95-82-9

2000 Raw material for agro and other chemicals

6. Trifluorobromobenzene (TFBrB) 176317-02-5

100 Raw material for agro and other chemicals

7. Trifluoroaniline (TFA) 3862-73-5

100 Raw material for agro and other chemicals

8. FOE Hydroxy --

100 Raw material for agro and other chemicals

9. 4,4' Bis(3-aminophenoxy)-bipheny (4,4' BAPBP)

105112-76-3 100

Polymer Intermediate

10. Nitrolone 100-01-6 100 Pigment Intermediate

11. Carbendazim 10605-21-7 250 Agro Technical

12. 4-fluoronitrobenzene (PFNB) AND/OR 350-46-9

2000

Raw material for agro and other chemicals

13. ortho fluoronitrobenzene (OFNB) AND/OR

1493-27-2 Pharma/Agro Intermediate

14. 2,4 Difluoronitrobenzene(2, 4 DFNB) AND/OR

446-35-5 Raw material for agro and other chemicals

15. 3,4 Chlorofluoronitrobenzene(3, 4 CFNB) AND/OR

350-30-1 Pharma Intermediate

16. 2-Fluoro-3-chloronitrobenzene(2,3 FCNB) AND/OR

2106-49-2 Raw material for agro and other chemicals

17. 2,3,4 Trifluoronitrobenzene (2,3,4 TFNB) AND/OR

771-69-7 Raw material for agro and other chemicals

M/s. Aarti Industries Limited (Unit-III), GIDC Estate, Jhagadia.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 15

LIST OF RAW MATERIALS

Sr. No.

Name of Products Name of Raw materials Raw Material Consumption in MT/Month

CAS No.

1. 2,5 Di Chloro Nitro

Benzene

pDCB 1914.06 106-46-7 Conc. Nitric Acid 845.833 7697-37-2

Sulphuric Acid 708.333 7664-93-9 Total 3468.23 --

2.

2,3,4 Tri Chloro Nitro Benzene

1,2,3 TCB 2031.25 87-61-6 Conc. Nitic Acid 805.47 7697-37-2 Sulphuric Acid 7.81 7664-93-9 Soda Solution 58.59 --

Total 2903.13 -- 3.

2,4,5 Tri Chloro Nitro Benzene

1,2,4 TCB 2031.25 120-82-1 Conc. Nitic Acid 750.00 7697-37-2 Sulphuric Acid 175.00 7664-93-9 Soda Solution 58.59 --

Total 3014.84 -- 4.

3 5 DC4FNB (Nitration product)

2,3 Dichloronitrobenzene (2,3 DCNB)

222.97 611-06-3

KF 101.1 7789-23-3 Sulfolane 19.9 126-33-0 PEG 600 2.27 25322-68-3 Chlorine 40.53 7782-50-5

Sodium bicarbonate (10%) 20.07 144-55-8

18. Ortho Chloro Toluene/Para Chloro Toluene (OCT/PCT)

95-49-8/ 3327-51-3

4000 Multiple End Uses

Total 11450 Inorganic Products

19. Potassium Chloride (KCl)

7447-40-7 3111

Mineral supplement and as a Raw material

for other chemicals

20.

Calcium Hydroxide (Ca(OH)2)

1305-62-0

400

Used as a flocculent for wastewater

treatment and in paper industries.

21. Hydrogen 1333-74-0

3000Nm3/Hr. Used in chemical

reaction and process

Total(Solid Inorganic Products)

Total(Gaseous Inorganic Products) 3511 MT/Month 3000 Nm3/Hr.

Total(Organic+ Inorganic) 14961 MT/Month + 3000 Nm3/Hr.

M/s. Aarti Industries Limited (Unit-III), GIDC Estate, Jhagadia.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 16

Nitric acid (98%) 91.2 7697-37-2 Sulfuric acid (98%) 0.72 7664-93-9

Total 498.73 -- 5.

2, 5 Dichloro Aniline

Di Chloro Nitro Benzene 2399.19 611-06-3 Hydrogen 78.14 12385-13-6 Methanol 17.14 67-56-1 Catalyst 0.34 --

Total 2494.81 -- 6.

Trifluorobromobenzene (TFBrB)

3,5-Dichloro-4-fluoronitrobenzene (3,5

DC4FNB) 128.34 3107-19-5

KF 78.23 7789-23-3 Sulfolane 4.21 126-33-0 PEG 400 1.45 25322-68-3

MCB 3.70 108-90-7 Hydrogen gas 3.60 12385-13-6 Pt/C catalyst 0.70 --

Ammonia 25% 0.17 7664-41-7 Methanol 2.20 67-56-1

Bromine gas 50.12 7726-95-6 H2O2 23.92 7722-84-1

NaHSO3 0.95 7631-90-5 MDC 1.72 75-09-2

50% H3PO2 92.23 6303-21-5 NaNO2 76.04 7632-00-0 CuSO4 0.86 7758-99-8

Boric acid 0.86 10043-35-3 HCl 174.59 7647-01-0

Na2CO3 0.66 497-19-8 Total 644.56 --

7.

Trifluoroaniline (TFA)

3,5-Dichloro-4-fluoronitrobenzene (3,5

DC4FNB)

149.49 3107-19-5

KF 91.13 7789-23-3 Sulfolane 4.90 126-33-0 PEG 400 1.69 25322-68-3

MCB 4.31 108-90-7 Hydrogen gas 4.19 12385-13-6 Pt/C catalyst 0.81 --

Ammonia 25% 0.20 7664-41-7 Methanol 2.57 67-56-1

Total 259.29 -- 8.

FOE Hydroxy FIA(4-fluoro-N-(propan-2-

yl)aniline) 86.37

70441-63-3

M/s. Aarti Industries Limited (Unit-III), GIDC Estate, Jhagadia.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 17

Chloro acetyl chloride 74.51 79-04-9 NaOH 124.06 1310-73-2 HCl 65.6 7647-01-0

Toluene 4.5 108-88-3 Acetic acid 32.78 64-19-7

Acetone 2.4 67-64-1 TEBAC 2.39 56-37-1

Total 392.61 -- 9.

4,4' Bis(3-aminophenoxy)-bipheny (4,4' BAPBP)

Meta Dinitro Benzene (MDNB) 125.17

25154-54-5

4,4'-Biphenol 67.69 92-88-6 Potassium carbonate 55.10 584-08-7

DMF 26.85 68-12-2 Toluene 4.34 108-88-3

Pt/C catalyst 2.80 -- Methanol 27.97 67-56-1

Hydrogen gas 3.78 12385-13-6 Total 313.71 --

10.

Nitrolone

Orthophenylene diamine (OPDA)

92.77 95-54-5

Urea 54.65 57-13-6 ODCB 8.26 95-50-1

Nitric acid (98%) 64.67 7697-37-2 Ethylene dichloride (EDC) 55.48 107-06-2

Hydrogen gas 4.44 12385-13-6 Pt/C catalyst 0.31 --

Methanol 20.25 67-56-1 Total 300.83 --

11.

Carbendazim

Calcium Cyanamide 191.5 156-62-7 o-phenylenediamine 155.5 95-54-5

Methyl chloroformate 161.5 79-22-1 Total 508.5 --

12.

PFNB

Para Nitro Chloro Benzene(PNCB)

2550.50 100-00-5

KF 764.36 7789-23-3 Sulfolane 80.32 126-33-0 Catalyst 6.34 --

Total 3401.50 -- 13.

OFNB

Ortho Nitro Chloro Benzene (ONCB) 2251.61

88-73-3

KF 762.58 7789-23-3 Sulfolane 80.07 126-33-0 Catalyst 6.45 --

Total 3100.72 --

M/s. Aarti Industries Limited (Unit-III), GIDC Estate, Jhagadia.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 18

14.

2, 4 DFNB

2,4 DCNB 2536.86 611-06-3 KF 1141.78 7789-23-3

Sulfolane 106.56 126-33-0 Catalyst 11.34 --

Total 3796.54 -- 15.

3, 4 CFNB

3,4 DCNB 2432.00 611-06-3 KF 729.60 7789-23-3

Sulfolane 186.00 126-33-0 Catalyst 6.08 --

Total 3353.68 -- 16.

2, 3 FCNB

2,3 Dichloronitrobenzene (2,3 DCNB)

2360 611-06-3

KF 1070 7789-23-3 Sulfolane 209.12 126-33-0 PEG 600 23.6 25322-68-3

Total 3662.72 -- 17.

2, 3, 4 TFNB

2,4-Dichloro-4-fluoronitrobenzene (2,4

DC3FNB) 3000 3107-19-5

KF 2158 7789-23-3 Sulfolane 115.5 126-33-0 PEG 400 3372 25322-68-3

MCB 101.16 108-90-7 Total 8786.66 --

18.

OCT/PCT

Fresh Toluene 2937.57 108-88-3 Catalyst 8.87 -- Chlorine 2268.19 7782-50-5

Total 5214.63 -- 19.

Ca(OH)2

CaCl2 (35% solution) 1714.4 10043-52-4 NaOH 454 1310-73-2 Total 2168.4 --

20. Hydrogen Methanol 1147 67-56-1

ANNEXURE V

M/s. Aarti Industries Limited (Unit-III), GIDC Estate, Jhagadia.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 19

BRIEF PROCESS DESCRIPTION

1) 2, 5 DICHLORO NITRO BENZENE

Manufacturing Process:

Mixed acid containing concentrated nitric acid and concentrated sulphuric acid is reacted with 2,

5 Di Chloro benzene to produce 2, 5 Di Chloro nitro benzene. The reaction gets completed in

series of nitrators with cooling coils and jackets. Reaction is followed by dil. sulphuric acid

separation, washing by water and soda ash, drying to get a 2, 5 Di Chloro nitro benzene and

unreacted 2, 5 Di Chloro benzene. Unreacted 2, 5 Di Chloro Benzene is recovered by steam

distillation and recycled.

Chemical reaction:

Material balance:

MM/s.Jyoti Om

2) 2,3,4

m Chemical

TRI CHLO

M/s. Aart

Research C

ORO NITRO

ti Industries

Centre Pvt. L

O BENZEN

s Limited (

Ltd., Anklesh

NE

(Unit-III), G

hwar.

GIDC Estat

te, Jhagadia

a.

20

M/s. Aarti Industries Limited (Unit-III), GIDC Estate, Jhagadia.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 21

Manufacturing process:

1,2,3/1,2,4 Tri Chloro Benzene is subjected to nitration reaction using nitric acid along

with sulphuric acid as dehydrating agent to yield 2,3,4/2,4,5 TRI CHLORO NIRTO BENZENE

& CRUDE TCNB.

Chemical Reaction:

3) 2,4,5 TRI CHLORO NITRO BENZENE

Manufacturing process:

1,2,3/1,2,4 Tri Chloro Benzene is subjected to nitration reaction using nitric acid along with sulphuric acid as dehydrating agent to yield 2,3,4/2,4,5 TRI CHLORO NIRTO BENZENE & CRUDE TCNB. Chemical Reaction:

Material Balance of 2, 3, 4 TRI CHLORO NITRO BENZENE

MM/s.Jyoti Om

m Chemical

M/s. Aart

Research C

ti Industries

Centre Pvt. L

s Limited (

Ltd., Anklesh

(Unit-III), G

hwar.

GIDC Estat

te, Jhagadia

a.

22

MM/s.Jyoti Om

Material

m Chemical

l Balance of

M/s. Aart

Research C

f 2, 4, 5 TRI

ti Industries

Centre Pvt. L

I CHLORO

s Limited (

Ltd., Anklesh

O NITRO BE

(Unit-III), G

hwar.

ENZENE:

GIDC Estat

te, Jhagadia

a.

23

MM/s.Jyoti Om

4) 3 5 D

Manufac

Process fluorinatipreparatithe chlorDichloro

Chemica

m Chemical

DC4FNB (NI

cturing proc

involves fluion agent iion of 2,6 Drinating agen-4-fluoronitr

al Reaction:

M/s. Aart

Research C

ITRATION

cess:

uorination oin sulfolane

Dichlorofluornt producingrobenzene b

:

ti Industries

Centre Pvt. L

N PRODUC

of 2,3 diche solvent urobenze from as Nox as by nitration o

s Limited (

Ltd., Anklesh

T)

hloronitrobenusing phasem 2-fluoro-3by product. of 2,6 Dichlo

(Unit-III), G

hwar.

nzene usinge transfer c3-chloronitroThe process

orofluoroben

GIDC Estat

g potassium catalyst. Pobenzene uss involves mnzene in nitra

te, Jhagadia

fluoride aProcess invsing chlorin

manufacturingating mixtur

a.

24

s the volves e gas g 3, 5 re.

MM/s.Jyoti Om

Material

m Chemical

l Balance:

M/s. Aart

Research C

ti Industries

Centre Pvt. L

s Limited (

Ltd., Anklesh

(Unit-III), G

hwar.

GIDC Estat

NO2 G

te, Jhagadia

Gas

a.

25

MM/s.Jyoti Om

5) 2, 5 DManufac

Here 2, 5

of metal

The react

Crude pr

as liquid

Chemica

Cl

N+

O

-O

2,5 Di chlo

Chemical FoMolecula

Material

m Chemical

DI CHLORcturing Pro

5 dichloro ni

powder cata

tion is follow

roduct is then

or flakes de

al reaction:

C

oro nitro benzene

ormula: C6H3Cl2Nar Weight: 192.00

l balance:

M/s. Aart

Research C

O ANILINEcess:

itrobenzene

alyst to prod

wed by catal

n subjected t

pending on t

Cl H

Hy

ChemicaMolecuNO2

0

ti Industries

Centre Pvt. L

E

is reacted in

duce 2, 5 dic

lyst filtration

to flash disti

the market r

H

ydrogen

al Formula: 3H2

ular Weight: 6

s Limited (

Ltd., Anklesh

n an autoclav

hloro aniline

n, solvent re

illation to ge

requirement.

Cl

2,5

ChemMol

(Unit-III), G

hwar.

ve reactor w

e. The reacti

ecovery, and

et the pure p

5 Di chloro anilin

mical Formula: C6

lecular Weight: 1

GIDC Estat

with hydrogen

ion mixture

d layer separ

product. Prod

ChM

NH2

Cl

ne

6H5Cl2N162.01

te, Jhagadia

n gas in pres

contains sol

ration and dr

duct is either

H

O

H

Water

hemical Formula:Molecular Weigh

a.

26

sence

lvent.

rying.

r sold

: 2H2Oht: 36

MM/s.Jyoti Om

6) TRIF

Manufac

Process ifluoronitrproducedpresence with sodiTFBrB).

Chemica

Material

m Chemical

FLUOROBR

cturing proc

involves synrobenzene u

d 2,3,4 Triflof H2O2 to

ium nitrate a

al Reaction:

l Balance:

M/s. Aart

Research C

ROMOBEN

cess:

nthesis of 2, 3using potassiuuoroaniline form 2,3,4 T

and Hypopho

:

ti Industries

Centre Pvt. L

NZENE (TF

3, 4 Trifluorum fluoride.(2,3,4 TFA)Trifluoro-6-bosphorous ac

s Limited (

Ltd., Anklesh

FBrB)

ronitrobenzen. 2,3,4 Triflu). 2, 3, 4 TFAbromoaniliecid to form 3

(Unit-III), G

hwar.

ne by fluorinuoronitrobenA under goe

e (2,3,4 TFBr3,4,5 Trifluo

GIDC Estat

nation of 3,5nzene is hydres brominatiorA) . 2,3,4 T

orobromoben

te, Jhagadia

5 Dichloro-4rogenated toon in the

TFBrA reactsnzene (3,4,5

a.

27

4-o

s

MM/s.Jyoti Om

7) TRIFManufacProcess ifluoronitrproducedChemica

N+

O

-O

3,5 Dichloro-4-f

Chemical FormMolecular Weig

m Chemical

FLUOROANcturing procinvolves synrobenzene u

d 2,3,4 Triflal Reaction:

F

Cl

Cl

fluoronitrobenzene

mula: C6H2Cl2FNO2

ght: 209.99

M/s. Aart

Research C

NILINE (Tcess:

nthesis of 2, 3using potassiuuoroaniline :

ti Industries

Centre Pvt. L

FA)

3, 4 Trifluorum fluoride.(2,3,4 TFA)

s Limited (

Ltd., Anklesh

ronitrobenzen. 2,3,4 Triflu).

(Unit-III), G

hwar.

ne by fluorinuoronitroben

GIDC Estat

nation of 3,5nzene is hydr

te, Jhagadia

5 Dichloro-4rogenated to

a.

28

4-o

MM/s.Jyoti Om

Material

8) FOE

Manufac

Process icaustic.

Chemica

m Chemical

l Balance:

HYDROXY

cturing proc

involves con

al Reaction:

M/s. Aart

Research C

Y

cess:

ndensation of

:

ti Industries

Centre Pvt. L

f FI aniline w

s Limited (

Ltd., Anklesh

with chloro a

(Unit-III), G

hwar.

acetyl chlori

GIDC Estat

ide (CAC) in

te, Jhagadia

n presence o

a.

29

of

MM/s.Jyoti Om

Material

9) 4,4' B

Manufac

Pp

Phy

ChemicaSTAGE-

m Chemical

l Balance:

BIS(3-AMIN

cturing proc

rocess involotassium carrocess involydrogen gas

al Reaction:-I

M/s. Aart

Research C

NOPHENO

cess:

lves condensrbonate, in Dlves hydroges. Which giv

:

ti Industries

Centre Pvt. L

OXY)-BIPHE

sation of metDMF/Toluenenation of 4,4es 4,4' BAPB

s Limited (

Ltd., Anklesh

ENY (4,4' B

ta dinitro bene solvent. F4’ BNPBP oBP as a prod

(Unit-III), G

hwar.

BAPBP)

enzene (MDNFor preparatiover Pt/C catduct and wat

GIDC Estat

NB), 4,4 Bipion of 4,4’ Btalyst and mter.

te, Jhagadia

phenol and BNPBP

methannol usi

a.

30

ing

MM/s.Jyoti Om

STAGE-

Material

m Chemical

-II

l Balance

M/s. Aart

Research C

ti Industries

Centre Pvt. L

s Limited (

Ltd., Anklesh

(Unit-III), G

hwar.

GIDC Estat

te, Jhagadia

a.

31

MM/s.Jyoti Om

10) 5-AM

Manufac

Pso

Psu

Phy

ChemicaSTAGE-

STAGE-

STAGE-

m Chemical

MINOBENI

cturing proc

rocess invololvent. reparation oulfuric acid. rocess involydrogen gas

al Reaction:-I

-II

-III

M/s. Aart

Research C

IMIDAZOL

cess:

lves condens

of 5-nitroben

lves hydroges.

:

ti Industries

Centre Pvt. L

LONE (5AB

sation of orth

nzoimidazolo

enation of 5-

s Limited (

Ltd., Anklesh

I) (NITROL

ho phenylen

one by reacti

-nitrobenzoim

(Unit-III), G

hwar.

LONE)

e diamine (O

ing Benzoim

midazolone

GIDC Estat

OPDA) and u

midazoline w

over Pt/C ca

te, Jhagadia

urea in ODC

with nitric aci

atalyst using

a.

32

CB

id in

g

MM/s.Jyoti Om

Material

m Chemical

l Balance

M/s. Aart

Research C

ti Industries

Centre Pvt. L

s Limited (

Ltd., Anklesh

(Unit-III), G

hwar.

GIDC Estat

te, Jhagadia

a.

33

MM/s.Jyoti Om

11) CAR

Manufac

Pin

Chemica

Material

12) ORT

Manufac

Psu

Chemica

m Chemical

RBENDAZIM

cturing proc

rocess involn aqueous m

al Reaction:

l Balance

THO FLUOR

cturing proc

rocess involulfolane solv

al Reaction:

M/s. Aart

Research C

M

cess:

lves condensmedium.

:

RONITROB

cess:

lves fluorinavent.

:

ti Industries

Centre Pvt. L

sation of calc

BENZENE

ation of 4-chl

s Limited (

Ltd., Anklesh

cium cyanam

(PFNB)

loronitroben

(Unit-III), G

hwar.

mide, OPDA

nzene (PNCB

GIDC Estat

A and methyl

B) with pota

te, Jhagadia

l chloroform

ssium fluori

a.

34

mate

ide in

MM/s.Jyoti Om

Material

13) ORT

Manufac

Pin

Chemica

Material

m Chemical

l Balance

THO FLUOR

cturing proc

rocess involn sulfolane sal Reaction:

l Balance

M/s. Aart

Research C

RONITROB

cess:

lves fluorinaolvent.

:

ti Industries

Centre Pvt. L

BENZENE

ation of 2-chl

s Limited (

Ltd., Anklesh

(OFNB)

loronitroben

(Unit-III), G

hwar.

nzene (ONCB

GIDC Estat

B) with pota

te, Jhagadia

assium fluori

a.

35

ide

MM/s.Jyoti Om

14) 2,4 D

Manufac

Pfl

Chemica

Material

15) ORT

Manufac

Pin

Chemica

m Chemical

DIFLUORO

cturing proc

rocess involluoride in sual Reaction:

l Balance

THO 3 CHL

cturing proc

rocess involn sulfolane sal Reaction:

M/s. Aart

Research C

ONITROBEN

cess:

lves fluorinaulfolane solve:

LORO 4 FLU

cess:

lves fluorinaolvent.

:

ti Industries

Centre Pvt. L

NZENE

ation of 2,4 Dent.

UORO NIT

ation of 2-chl

s Limited (

Ltd., Anklesh

Dichloronitro

TROBENZE

loronitroben

(Unit-III), G

hwar.

obenzene (2

ENE (3,4 CF

nzene (ONCB

GIDC Estat

,4 DCNB) w

FNB)

B) with pota

te, Jhagadia

with potassiu

assium fluori

a.

36

um

ide

MM/s.Jyoti Om

Material

16) 2-FL

Manufac

Pfl

Chemica

Material

m Chemical

l Balance

LUORO-3-C

cturing proc

rocess involluorination aal Reaction:

l Balance

M/s. Aart

Research C

CHLORONI

cess:

lves fluorinaagent in sulfo:

ti Industries

Centre Pvt. L

ITROBENZ

ation of 2,3 Dolane solven

s Limited (

Ltd., Anklesh

ZENE (2,3 F

Dichloronitront using phas

(Unit-III), G

hwar.

FCNB)

obenzene usse transfer ca

GIDC Estat

ing potassiuatalyst.

te, Jhagadia

um fluoride a

a.

37

as the

MM/s.Jyoti Om

17) 2,3,4

Manufac

P4

Chemica

Material

18) PAR

Manufac

Here Par

of metal

The reac

Crude pr

as liquid

m Chemical

TRIFLUO

cturing proc

rocess invol-fluoronitrobal Reaction:

l Balance

RA CHLORO

cturing Pro

ra Chloro nit

powder cata

ction is follo

roduct is then

or flakes de

M/s. Aart

Research C

RONITRO

cess:

lves synthesibenzene usin:

O ANILINE

cess:

trobenzene i

alyst to prod

owed by cat

n subjected t

pending on t

ti Industries

Centre Pvt. L

BENZENE

is of 2,3,4 Trng potassium

E / ORTHO

is reacted in

duce Para ch

talyst filtrat

to flash disti

the market r

s Limited (

Ltd., Anklesh

(2,3,4 TFN

rifluoronitrom fluoride.

O CHLORO

an autoclav

hloro aniline

tion, solvent

illation to ge

requirement.

(Unit-III), G

hwar.

NB)

obenzene by

O ANILINE

ve reactor w

e. The reacti

t recovery, l

et the pure p

GIDC Estat

fluorination

ith hydrogen

ion mixture

layer separa

product. Prod

te, Jhagadia

n of 3,5 Dich

n gas in pres

contains sol

ation and dr

duct is either

KCl 

a.

38

hloro-

sence

lvent.

rying.

r sold

MM/s.Jyoti Om

For prod

process

respectiv

product.

Chemica

N+

O

-O

Para chlor

Chemical Molecular

Material

m Chemical

duction of P

is applied

vely instead

al Reaction:

C

ro nitro benzene

Formula: C6H4Clr Weight: 157.55

l balance:

M/s. Aart

Research C

Para Chloro

by taking

of Meta Ch

:

l

H

Hyd

Chemical Molecul

lNO2

ti Industries

Centre Pvt. L

aniline and

Para Chlor

loro nitro be

H

drogen

Formula: 3H2

lar Weight: 6

s Limited (

Ltd., Anklesh

d Ortho Chl

ro nitroben

enzene. Refe

Cl

ChMo

(Unit-III), G

hwar.

loro aniline,

nzene and O

ference mate

Para chloro anili

hemical Formula:olecular Weight:

GIDC Estat

, same abov

Ortho Chlo

erial balance

NH2

ine

C6H6ClN127.57

ChM

te, Jhagadia

ve manufact

ro Nitroben

e is given fo

H

O

H

Water

hemical FormulaMolecular Weigh

a.

39

turing

nzene

or one

a: 2H2Oht: 36

MM/s.Jyoti Om

19) HYDManufac

Methano

superhea

the action

monoxid

residual c

The crack

PSA to re

Reaction

CH3OH

32

Material

m Chemical

DROGEN cturing Pro

l and demin

ated, reaches

n of the cata

de simultaneo

carbon mono

ked gas duri

emove the im

n

H+H2O

18

l balance:

M/s. Aart

Research C

cess:

eralized wat

a certain tem

alyst, takes p

ously and fo

oxide with a

ing the reacti

mpurities an

CO2+

44

ti Industries

Centre Pvt. L

ter mixture a

mperature an

lace the reac

rms finally t

a small quant

ion, after pu

nd then the qu

+3H2

6

s Limited (

Ltd., Anklesh

as per certain

nd pressure.

ctions of cata

the mixed ga

tity, etc.

urification an

ualified gas

(Unit-III), G

hwar.

n ratio, after

The mixed a

alyzed crack

ases of hydro

nd separation

is delivered

GIDC Estat

pressurized

and superhe

king and shif

ogen, carbon

n, is fed to th

.

te, Jhagadia

, evaporated

ated gas, un

fting of carb

n dioxide an

he section of

a.

40

d and

der

on

nd the

f

MM/s.Jyoti Om

20) CAL

Manufac

React calchloride

Chemica

CaCl2 +

110.9 +

Material

m Chemical

LCIUM HYD

cturing proc

lcium chlorisolution.

al Reaction:

+ 2NaOH

+ 39.9

l Balance

M/s. Aart

Research C

DROXIDE

cess:

de solution w

:

→ Ca(OH

= 74.0

ti Industries

Centre Pvt. L

with sodium

H)2 + 2NaC

+ 58.4

s Limited (

Ltd., Anklesh

m hydroxide t

Cl

(Unit-III), G

hwar.

to get calciu

GIDC Estat

um hydroxide

te, Jhagadia

e and sodium

a.

41

m

M/s. Aarti Industries Limited (Unit-III), GIDC Estate, Jhagadia.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 42

ANNEXURE VI

DETAILS OF WATER CONSUMPTION

Sr. No.

Purpose Total fresh water consumption (KL/day)

Recycled Water (KL/day)

Total Water Consumption (KL/day)

A Domestic 30 0 30 B Industrial

1)Process 230 0 230 2) Washing 10 0 10 3) Cooling 585 0 585 4) Gardening 0 30 30

Total (B) 825 30 855 Total (A+B) 855 30 885

DETAILS OF WASTE WATER GENERATION

Sr. No.

Purpose Total wastewater generation in KL/day

A Domestic 30 B Industrial

1)Process 388 2) Washing 10 3) Cooling 50

Total (B) 448 Total (A+B) 478

M/s. Aarti Industries Limited (Unit-III), GIDC Estate, Jhagadia.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 43

WORST CASE SCENARIO FOR WATER CONSUMPTION, WASTEWATER GENERATION AND HAZARDOUS WASTE

Sr. No.

Product Quantity (MT/M)

Water Consumption(KLD)

Wastewater generation (KLD)

Solid waste (MT/M)

Residue (MT/M)

1. DCNB 2500

12.17 20.83 0.000 0.00 2. 2,3,4,TCNB 8.05 21.48 0.000 0.00 3. 2,4,5, TCNB 4.32 21.48 0.000 0.00 4. 3,5

DC4FNB 200 3.91 6.87 0.000 8.16

5. DCA 2000 0.00 15.53 0.000 22.17 6. TFBrB 100 4.14 5.54 0.000 5.86 7. TFA 100 0.00 0.85 0.000 8.10 8. FOE

Hydroxy 100 7.33 13.00 0.000 8.00

9. Hydrogen 194.4 25.23 10. BAPAP 100 0.00 1.22 0.000 0.00 11. Nitrolone 100 41.53 42.97 0.000 0.00 12. Carbendazim 250 29.17 34.25 106 0.00 13. PFNB 2000 0.00 0.00 0.000 211.88 14. OFNB 0.00 0.00 0.000 203.13 15. 24DFNB 0.00 0.00 0.000 223.44 16. 34CFNB 0.00 0.00 0.000 92.68 17. 23FCNB 0.00 0.00 0.000 182.00 18. 234TFNB 0.00 0.00 0.000 224.00 19. OCT/PCT 4000 90.52 0.00 0.000 39.90 20. Ca(OH)2 400 16.39 53.20 0.000 0.00 11450 230 195 106 316

M/s. Aarti Industries Limited (Unit-III), GIDC Estate, Jhagadia.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 44

WATER BALANCE DIAGRAM (in KLD)

GIDC Drainage

Filter Press

Domestic 30

Cooling 585

Total Water Consumption from GIDC 885

(Fresh (855 KLD) + Reuse (30 KLD))

ETP 448

Gardening 30(R)

STP 30

Process 230

Washing 10

Blow Down50

Washing 10

M/s. Aarti Industries Limited (Unit-III), GIDC Estate, Jhagadia.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 45

ANNEXURE VII

EFFLUENT TREATMENT PLANT PROCESS DESCRIPTION: The dilute effluent from process plant and washing is taken to oil & grease trap for separation, oil and grease is skimmed off from the top. Effluent is then pumped to pH correction tank where pH is neutralized between 7.00 to 8.00 and compressed air is used for agitation. Then it is transferred to equalization tank where effluent from blow down (Cooling tower) is added and it is passed through filter press, where sludge is sent to decanter for sludge dewatering then it is taken to equalization tank after that effluent is pumped to primary settling tank where suspended solids are settled and the sludge is taken into membrane filter to separate the solid. Dried sludge is stored in a sludge storage tank. Clear water from settling tank is taken into aeration tank In this tank, extended type aeration system is adopted. Biological treatment is given to the effluent. Overflow is taken into secondary settling tank for excess sludge settling, biomass is recirculated in aeration tank if required or sent to membrane filter press. Overflow from secondary settling tank is passed through activated carbon filter + Sand filter and then taken into collection tank from where it is sent to GIDC Pipeline.

ETP

Process water +

Washing Water

Oil and Grease

trap

pH correction tank

Equalization tank

Filter Press

Primary settling tank

Solid Collection

Aeration Tank

Secondary settling

Filter Press

Filter Press

Collection tank

Carbon and Sand Filter

GIDC Pipeline

Blow down

(Cooling tower)

M/s. Aarti Industries Limited (Unit-III), GIDC Estate, Jhagadia.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 46

WASTE WATER CHARACTERISTICS OF DIFFERENT STREAMS:

Sr. No.

Parameters Units

Effluent generation

Blow down (Cooling tower)

Washing water from floor & reactor washing

Process stream after HCl Neutralization

Capacity in KLD 50 10 388

1. PH -- 7-8 3-4 3-4

2. TSS mg/l 200-250 150-200 200-250

3. TDS mg/l 2500-3000 500-600 13000-18000

4. Ammonical Nitrogen

mg/l 0-10 20-25 25-30

5. C.O.D. mg/l 250-300 1000-1100 5000-7000

WASTE WATER CHARACTERISTICS OF COMPOSITE STREAMS BEFORE TREATMENT:

Sr. No.

Parameters Units

Effluent generation Composite Stream

Capacity in KLD 448

1. PH -- 6-7

2. TSS mg/l 170-220

3. TDS mg/l 8700-10500

4. Ammonical Nitrogen

mg/l 20-25

5. C.O.D. mg/l 2500-4500

M/s. Aarti Industries Limited (Unit-III), GIDC Estate, Jhagadia.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 47

ANNEXURE VIII

DETAILS OF ELECTRICITY AND FUEL CONSUMPTION

Sr. No.

Name Requirement Source

Total 1. Diesel 660 Litre/Hr. Local Market 2. Steam 30 MT/Hr. Aarti Industries

Limited, Jhagadia 3. Energy - Electricity 3500 kVA DGVCL

DETAILS OF FLUE GAS EMISSIONS

Sr. No.

Stack Attached To Stack Height in Meter

Fuel APCM Type of Emission

Permissible Limit

1. D.G. Set (Standby) (2 Nos) Capacity= 1500 KVA (Each)

11 Diesel -- PM SO2

NOX

150mg/ Nm3 100 ppm 50ppm

DETAILS OF PROCESS EMISSION

Sr. No.

Stack attached to Stack Height in Meter

APCM Parameter Permissible Limit

1. Scrubber connected to reactors.

11 Water scrubber followed by Alkali Scrubber

NOX HCl Cl2

25 Mg/Nm3 20 Mg/Nm3

09 Mg/Nm3 2. Scrubber connected to

tanks 11 Water Scrubber HF

HBr 4 mg/Nm3 20 mg/Nm3

3. Scrubber connected to tanks

11 Water Scrubber NH3 175 mg/Nm3

4. PSA Adsorber 26 Water scrubber -- --

M/s. Aarti Industries Limited (Unit-III), GIDC Estate, Jhagadia.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 48

ANNEXURE IX

DETAILS OF HAZARDOUS WASTE GENERATION & DISPOSAL

Sr.No.

Name of Waste Category Total Quantity Mode of disposal

1. ETP Waste 35.3 120

MT/Month Collection, Storage, Transportation,

disposal to TSDF.

2. Distillation

Residue 36.1

320 MT/Month

Collection, Storage, transportation, disposal at incineration/ Co-processing

3. Discarded

containers/bags 33.1

Whatsoever generated

Collection, Storage, Decontamination, Disposal by sold to authorize

recyclers.

4. Used oil 5.1 500

Lit/Month

Collection, Storage, Transportation, Disposal by selling to registered re-

processors.

5. Insulation Waste -- Whatsoever generated

Collection, Storage, Transportation disposal by at TSDF Site.

6. Spent Carbon 28.3 5

MT/month Collection, Storage, transportation, sent for incineration/ Co-processing

7. Solid Waste from

Process 35.3 110 MT/Month

Collection, Storage, Transportation, disposal to TSDF.

8. Off Specification

Product 36.1

Whatsoever generated

Collection, Storage, transportation, disposal at CHWIF

By-Product

9. Sodium chloride (NaCl)

-- 840

MT/Month

Sold as per rule-9 of Hazardous and other waste, 2016.

10. Sodium Acetate -- 75

MT/Month

11. Sodium Bromide (NaBr)

-- 3 MT/Month

12. Phosphoric Acid (H3PO4)

-- 125 MT/Month

13. Hydrochloric Acid (HCl)

-- 3990 MT/Month

Sold as per rule-9 of Hazardous and other waste, 2016 or will be neutralized and sent to GIDC drainage

Total (By-product)

5033 MT/Month