Anhydrous Hydrochloric Acid : Production And Transportation

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  • 8/19/2019 Anhydrous Hydrochloric Acid : Production And Transportation

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    ANHYDROUS HYDROCHLORIC ACID:PRODUCTION AND TRANSPORTATION

    PREPARED BY : PRUTHVISH MEHTA

      GUIDED BY : PROF. K.S. AGRAWAL

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    INTRODUCTION

    • Hydrogen chloride (IUPAC NAME), chemical compound, HCl, a colorless,gas with an unpleasant, acrid odor

    • Hydrogen chloride is a diatomic molecule, consisting o! a hydrogen atochlorine atom Cl connected "y a co#alent single "ond

    • It is #ery solu"le in water and readily solu"le in alcohol and ether

    • It !umes in moist air

    $ecause o! its acidic nature, hydrogen chloride is corrosi#e, particularlypresence o! moisture

    • It is not %amma"le, and the li&uid is a poor conductor o! electricity

    http://www.encyclopedia.com/topic/Hydrogen_chloride.aspx

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    USES

    • Manu!acture o! ru""er

    • Pharmaceuticals

    • Inorganic and organic chemicals as well as in gasoline re'ning

    • Metals processing

    • ool reclaiming

    • u""er hydrochloric 'lms that a strong, water resistant and pac*aging mate

    • Manu!acturing insert "earing "lan*s

    • In electronics industry, a high purity grade o! hydrogen chloride is used as ansemiconductor materials

    Handbook o !o"#$%&&%d 'a&%&( Co"#$%&&%d Ga& A&&o!)a*)on( S#$)n'%$ S!)%n!% + B,&)n%&& M%d)a( -/0,n/1222( 315

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    PROPERTIES

    PYSICAL PROPERTIES CHEMICAL PROPERTIES

    • Molecular weight + -.-/ g0mol• 1atent heat o! !usion (/,2/

    melting point) + 3.43 *50*

    • Melting point + 6//./4 7C• 1atent heat o! #apori8ation

    "oiling point) + ..449 *50*g

    • $oiling point (/2/ "ar) + 643 7C • Critical temperature + 2:9

    •1i&uid density (/2/ "ar at "oilingpoint) + //:;:4 *g0m

    • Critical pressure + 43- "a

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    PRODUCTION

    • LABORATORY METHODS+

    D)$%!* &8n*6%&)&+Com"ination o! hydrogen and chlorine in presence o! U= light

    Cl;(g) > H;(g) ? ; HCl(g)

    • O$'an)! &8n*6%&)&:

    $yproduct during !ormation o! chlorinated and %uorinated organic ceg @e%on, reon and other CCs

    6H > Cl; ? 6Cl > HCl

    6Cl > H ? 6 > HCl

    6**#&:77%n.=)k)#%d)a.o$'7=)k)7H8d$o'%n>!69o$)d%

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    HCL GENERATOR

    6**#&:77===.%$o=)d.o$'7a$!6)?%7$6od),"7!6%")&*$876!9'a&.a$'[email protected]*"9

    Muriatic acid is dripped in a %sul!uric acid

    • Behydration ta*es place a"sor"

    li"erating HC1 gas• HCl gas is the "u""led in sulph

    stirred in IPA6Iso Propyl Alcohol

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    METHODS OF SHIPMENT

    Under the appropriate regulation, anhydrous hydrogen chloride is aushipment as !ollows+

    Handbook o !o"#$%&&%d 'a&%&( Co"#$%&&%d Ga& A&&o!)a*)on( S#$)n'%$ S!)%n!% + B,&)n%&& M%d)a( -/0,n/1222(315

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    CONTAINERS AND CYLINDERS

    Handbook o !o"#$%&&%d 'a&%&( Co"#$%&&%d Ga& A&&o!)a*)on( S#$)n'%$ S!)%n!% + B,&)n%&& M%d)a( -/0,n/1222( #a'%

    • Containers are manu!actured to Bepa @ransportation (B@) regulations, which material o! construction, method o! manu!act

    and with what products they are permitted towell as other details

    • A cylinder is a hollow tu"e with a closed concaand @he opposite end is tapered to a small opthat is threaded to accommodate the installat

    #al#e• Cylinders that meet the !ollowing @C0B@ are

    authori8ed !or hydrogen chloride ser#ice + A/AA/422, AD/422, AAD/422 and E/422

    • B@6A;2/3 and B@6@ cylinders are o!ten uanhydrous hydrogen chloride ser#ices

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    CARGO TANKS AND TUBE TRAILORS

    • Constructed o! , the tan*s con!orm toB@ speci'cation MC6/ or MC64 andmust "e insulated

    Handbook o !o"#$%&&%d 'a&%&( Co"#$%&&%d Ga& A&&o!)a*)on( S#$)n'%$ S!)%n!% + B,&)n%&& M%d)a( -/0,n/122

    • Handling large &uantities tu"e trailors are

    used•  A typical tu"e trailer contains ;/,222

    pounds o! hydrogen chloride

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    VALVES AND CONNECTIONS

    6**#:77===.a)$#$od,!*&.!o"7!o"#an87S,&*a)nab)9)*87%n?)$on"%n*/6%a9*6/and&a%*877"%d)a7F)9%&7PDF7!o"#an87&a%*8'$a"/3.#d

    •  @he standard connection !or hydrogen chloride is the C

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    SAFETY AND HAARDS

    • A threshold limit #alue (@1=) ceiling limit o! 3 ppm or 9 mg0m !or hydrogenadopted "y the U ccupational a!ety and Health Administration and the Amo!

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     @HANG U