A fluorosurfactant and photoreducible CuII-tren click catalyst: Surfactant and catalytic properties at liquid/liquid interfaces

Quentin Jochyms,a,b Pierre Guillot,b Emmanuel Mignard*b and Jean-Marc Vincent*a

a Univ. Bordeaux – CNRS UMR 5255, 351 Crs de la Libération, 33405 Talence, France.

b CNRS, LOF, UMR 5258, F33699 Pessac, France.

1H and 13C NMR spectra of compounds 6 and 7.

Electronic Supplementary Material (ESI) for Dalton Transactions.This journal is © The Royal Society of Chemistry 2015

1H (200 MHz) and 13C (50 MHz) NMR spectra of compound 6 (D2O).

0.00.51.01.52.02.53.03.54.04.55.05.56.06.57.07.58.0f1 (ppm)

4.00

1.00

1.00

1.97

0.99

3.06

4

3.44

93.

531

3.55

93.

593

3.61

93.

746

3.75

43.

807

3.81

6

4.33

24.

483

4.52

24.

670

0102030405060708090100110120130140150160170180190200f1 (ppm)

56.6

25

60.7

53

69.6

2772

.964

75.7

7676

.071

78.4

34

100.

600

1H (200 MHz) and 13C (50 MHz) NMR spectra of compound 7 (D2O).