127
Wright State University Wright State University CORE Scholar CORE Scholar Browse all Theses and Dissertations Theses and Dissertations 2014 Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel Cell Hybrid Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel Cell Hybrid Gas Turbine Power System for Aerospace Application Gas Turbine Power System for Aerospace Application Ryan R. Sinnamon Wright State University Follow this and additional works at: https://corescholar.libraries.wright.edu/etd_all Part of the Mechanical Engineering Commons Repository Citation Repository Citation Sinnamon, Ryan R., "Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel Cell Hybrid Gas Turbine Power System for Aerospace Application" (2014). Browse all Theses and Dissertations. 1198. https://corescholar.libraries.wright.edu/etd_all/1198 This Thesis is brought to you for free and open access by the Theses and Dissertations at CORE Scholar. It has been accepted for inclusion in Browse all Theses and Dissertations by an authorized administrator of CORE Scholar. For more information, please contact [email protected].

Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

  • Upload
    others

  • View
    5

  • Download
    0

Embed Size (px)

Citation preview

Page 1: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

Wright State University Wright State University

CORE Scholar CORE Scholar

Browse all Theses and Dissertations Theses and Dissertations

2014

Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel Cell Hybrid Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel Cell Hybrid

Gas Turbine Power System for Aerospace Application Gas Turbine Power System for Aerospace Application

Ryan R. Sinnamon Wright State University

Follow this and additional works at: https://corescholar.libraries.wright.edu/etd_all

Part of the Mechanical Engineering Commons

Repository Citation Repository Citation Sinnamon, Ryan R., "Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel Cell Hybrid Gas Turbine Power System for Aerospace Application" (2014). Browse all Theses and Dissertations. 1198. https://corescholar.libraries.wright.edu/etd_all/1198

This Thesis is brought to you for free and open access by the Theses and Dissertations at CORE Scholar. It has been accepted for inclusion in Browse all Theses and Dissertations by an authorized administrator of CORE Scholar. For more information, please contact [email protected].

Page 2: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

ANALYSIS OF A FUEL CELL COMBUSTOR IN A SOLID OXIDE FUEL CELL

HYBRID GAS TURBINE POWER SYSTEM FOR AEROSPACE APPLICATION

A thesis submitted in partial fulfillment

of the requirements for the degree of

Master of Science in Engineering

By

RYAN RUSSELL SINNAMON

B.S., Wright State University, 2012

2014

Wright State University

Page 3: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

WRIGHT STATE UNIVERSITY

GRADUATE SCHOOL

April 30, 2014

I HEREBY RECOMMEND THAT THE THESIS PREPARED UNDER MY

SUPERVISION BY Ryan Russell Sinnamon ENTITLED Analysis of a Fuel Cell

Combustor in a Solid Oxide Fuel Cell Hybrid Gas Turbine Power System for Aerospace

Application BE ACCEPTED IN PARTIAL FULFILLMENT OF THE

REQUIREMENTS FOR THE DEGREE OF Master of Science in Engineering.

Committee on

Final Examination

Scott Thomas, Ph.D.

Hong Huang, Ph.D.

Robert E.W. Fyffe, Ph.D.

Vice President for Research and

Dean of the Graduate School

Rory A. Roberts, Ph.D.

Thesis Director

George Huang, Ph.D.

Chair

Department of Mechanical and

Materials Engineering

College of Engineering and

Computer Science

Page 4: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

iii

ABSTRACT

Sinnamon, Ryan Russell. M.S.Egr., Wright State University, 2014.

Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel Cell Hybrid Power System for

Aerospace Application.

Over the last few years, fuel cell technology has significantly advanced and has

become a mode of clean power generation for many engineering applications. Currently

the dominant application for fuel cell technology is with stationary power generation.

Very little has been published for applications on mobile platforms, such as unmanned

aerial vehicles. With unmanned aerial vehicles being used more frequently for national

defense and reconnaissance, there is a need for a more efficiency, longer endurance

power system that can support the increased electrical loads onboard. It has already been

proven by others that fuel cell gas turbine hybrid systems can achieve higher system

efficiencies at maximum power. The integration of a solid oxide fuel cell combustor with

a gas turbine engine has the potential to significantly increase system efficiency at off-

design conditions and have a higher energy density compared to traditional heat based

systems. This results in abilities to support larger onboard electrical loads and longer

mission durations. The majority of unmanned air vehicle mission time is spent during

loiter, at part load operation. Increasing part load efficiency significantly increases

mission duration and decreases operational costs. These hybrid systems can potentially

have lower power degradation at higher altitudes compared to traditional heat based

propulsion systems. The purpose of this research was to analyze the performance of a

solid oxide fuel cell combustor hybrid gas turbine power system at design and off-design

operating conditions at various altitudes. A system level MATLAB/Simulink model has

Page 5: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

iv

been created to analyze the performance of such a system. The hybrid propulsion system

was modeled as an anode-supported solid oxide fuel cell integrated with a commercially-

available gas turbine engine used for remote control aircraft. The design point operation

of the system was for maximum power at sea-level. A steady-state part load performance

analysis was conducted for various loads ranging from 10 ≤ L ≤ 100 percent design load

at varying altitudes ranging from 0 ≤ Y ≤ 20,000 feet. This analysis was conducted for

four different fuel types: humidified hydrogen, propane, methane, and JP-8 jet fuel. The

analysis showed that maximum system efficiency was achieved at loads of 40 ≤ L ≤ 60

percent design load at each altitude and fuel type. The system utilizing methane fuel,

internally-steam reformed within the fuel cell, proved to have the highest system

efficiency of 46.8 percent (LHV) at a part load of L = 60 percent and an altitude of Y =

20,000 feet.

Page 6: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

v

TABLE OF CONTENTS

Page

INTRODUCTION .............................................................................................................. 1

BACKGROUND ................................................................................................................ 7

Solid Oxide Fuel Cells .................................................................................................. 10

MATHEMATICAL MODEL ........................................................................................... 11

Solid Oxide Fuel Cell Model ........................................................................................ 12

SOFC Electrochemistry ................................................................................................ 12

SOFC Polarization Losses ............................................................................................ 15

Activation Polarization ............................................................................................. 15

Ohmic Polarization ................................................................................................... 17

Concentration Polarization........................................................................................ 18

Energy Analysis ............................................................................................................ 20

Combustor Model ......................................................................................................... 22

Gas Turbine Model ....................................................................................................... 22

SOFC Combustor / GT Model ...................................................................................... 24

RESULTS AND DISCUSSION ....................................................................................... 26

Steady-State Part Load Performance Analysis ............................................................. 27

Impact to UAV Performance ........................................................................................ 40

CONCLUSIONS .............................................................................................................. 42

Page 7: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

vi

APPENDIX A: MATLAB/SIMULINK MODEL FILES ................................................ 45

APPENDIX B: EFFECTIVE DIFFUSIVITY: LEONARD-JONES POTENTIALS ...... 51

APPENDIX C: SOFC/GT FUEL CHEMISTRY ............................................................. 53

APPENDIX F: SUMMARY OF SOFC/GT MODEL DATA .......................................... 55

REFERENCES ............................................................................................................... 107

Page 8: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

vii

LIST OF FIGURES

Page

Figure 1: Anode Supported SOFC Schematic. ................................................................. 10

Figure 2: Traditional Gas Turbine Engine Schematic. ..................................................... 24

Figure 3: SOFC/GT Schematic. ........................................................................................ 25

Figure 4: System Efficiency versus Part Load: (a) Sea-Level; (b) 4,000 ft. ..................... 31

Figure 5: System Efficiency versus Part Load: (a) 8,000 ft; (b) 12,000 ft. ...................... 32

Figure 6: System Efficiency versus Part Load: (a) 16,000 ft; (b) 20,000 ft. .................... 33

Figure 7: Fuel Utilization versus Part Load – CH4 (SR). ................................................. 35

Figure 8: Compressor Mass Flow versus Part Load – CH4 (SR). .................................... 36

Figure 9: Solid Oxide Fuel Cell Voltage versus Part Load – CH4 (SR). ......................... 36

Figure 10: System Efficiency versus Part Load: Methane Steam Reformation. .............. 37

Figure 11: System Efficiency versus Part Load: JP-8 Steam Reformation. ..................... 38

Figure 12: System Efficiency versus Part Load: Humidified Hydrogen. ......................... 38

Figure 13: System Efficiency versus Part Load: Methane Partial Oxidation. .................. 39

Figure 14: System Efficiency versus Part Load: Propane Partial Oxidation. ................... 39

Figure 15: System Efficiency versus Part Load: JP-8 Partial Oxidation. ......................... 40

Figure 16: CH4 (SR) – System Load versus Part Load. ................................................... 56

Figure 17: CH4 (SR) – Fuel Utilization versus Part Load. ............................................... 57

Figure 18: CH4 (SR) – Turbine Inlet Temperature versus Part Load............................... 58

Figure 19: CH4 (SR) – Gas Turbine Shaft Speed versus Part Load. ................................ 59

Figure 20: CH4 (SR) – Compressor Mass Flow Rate versus Part Load. .......................... 60

Figure 21: CH4 (SR) – Solid Oxide Fuel Cell Voltage versus Part Load. ....................... 61

Figure 22: CH4 (SR) – Solid Oxide Fuel Cell Power versus Part Load. .......................... 62

Page 9: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

viii

Figure 23: CH4 (SR) – Gas Turbine Power versus Part Load. ......................................... 63

Figure 24: JP8 (SR) – System Load versus Part Load. ..................................................... 64

Figure 25: JP8 (SR) – Fuel Utilization versus Part Load.................................................. 65

Figure 26: JP8 (SR) – Turbine Inlet Temperature versus Part Load. ............................... 66

Figure 27: JP8 (SR) – Gas Turbine Shaft Speed versus Part Load. .................................. 67

Figure 28: JP8 (SR) – Compressor Mass Flow Rate versus Part Load. ........................... 68

Figure 29: JP8 (SR) – Solid Oxide Fuel Cell Voltage versus Part Load. ......................... 69

Figure 30: JP8 (SR) – Solid Oxide Fuel Cell Power versus Part Load............................. 70

Figure 31: JP8 (SR) – Gas Turbine Power versus Part Load. ........................................... 71

Figure 32: H2 – System Load versus Part Load. .............................................................. 72

Figure 33: H2 – Fuel Utilization versus Part Load. .......................................................... 73

Figure 34: H2 – Turbine Inlet Temperature versus Part Load. ......................................... 74

Figure 35: H2 – Gas Turbine Speed versus Part Load. ..................................................... 75

Figure 36: H2 – Compressor Mass Flow Rate versus Part Load. ..................................... 76

Figure 37: H2 – Solid Oxide Fuel Cell Voltage versus Part Load.................................... 77

Figure 38: H2 – Solid Oxide Fuel Cell Power versus Part Load. ..................................... 78

Figure 39: H2 – Gas Turbine Power versus Part Load. .................................................... 79

Figure 40: CH4 (POX) – System Load versus Part Load. ................................................ 80

Figure 41: CH4 (POX) – Fuel Utilization versus Part Load. ............................................ 81

Figure 42: CH4 (POX) – Turbine Inlet Temperature versus Part Load. .......................... 82

Figure 43: CH4 (POX) – Gas Turbine Shaft Speed versus Part Load. ............................. 83

Figure 44: CH4 (POX) – Compressor Mass Flow Rate versus Part Load........................ 84

Figure 45: CH4 (POX) – Solid Oxide Fuel Cell Voltage versus Part Load. .................... 85

Page 10: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

ix

Figure 46: CH4 (POX) – Solid Oxide Fuel Cell Power versus Part Load. ....................... 86

Figure 47: CH4 (POX) – Gas Turbine Power versus Part Load. ...................................... 87

Figure 48: C3H8 (POX) – System Load versus Part Load. .............................................. 88

Figure 49: C3H8 (POX) – Fuel Utilization versus Part Load. .......................................... 89

Figure 50: C3H8 (POX) – Turbine Inlet Temperature versus Part Load. ........................ 90

Figure 51: C3H8 (POX) – Gas Turbine Shaft Speed versus Part Load. ........................... 91

Figure 52: C3H8 (POX) – Compressor Mass Flow Rate versus Part Load. .................... 92

Figure 53: C3H8 (POX) – Solid Oxide Fuel Cell Voltage versus Part Load. .................. 93

Figure 54: C3H8 (POX) – Solid Oxide Fuel Cell Power versus Part Load. ..................... 94

Figure 55: C3H8 (POX) – Gas Turbine Power versus Part Load. .................................... 95

Figure 56: JP8 (POX) – System Load versus Part Load. .................................................. 96

Figure 57: JP8 (POX) – Fuel Utilization versus Part Load. ............................................. 97

Figure 58: JP8 (POX) – Turbine Inlet Temperature versus Part Load. ............................ 98

Figure 59: JP8 (POX) – Gas Turbine Shaft Speed versus Part Load................................ 99

Figure 60: JP8 (POX) – Compressor Mass Flow Rate versus Part Load. ...................... 100

Figure 61: JP8 (POX) – Solid Oxide Fuel Cell Voltage versus Part Load. .................... 101

Figure 62: JP8 (POX) – Solid Oxide Fuel Cell Power versus Part Load. ...................... 102

Figure 63: JP8 (POX) – Gas Turbine Power versus Part Load....................................... 103

Page 11: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

x

LIST OF TABLES

Page

Table 1: Fuel Cell Characteristics ....................................................................................... 9

Table 2: SOFC Activation Polarization Model Input Parameters .................................... 17

Table 3: SOFC Ohmic Polarization Model Input Parameters .......................................... 18

Table 4: SOFC Concentration Polarization Model Input Parameters. .............................. 19

Table 5: Specific Heat Coefficients for Various Gases. ................................................... 21

Table 6: Gas Turbine Model Input Parameters. ................................................................ 24

Table 7: Fuel Processing - Hydrogen Yield. ..................................................................... 28

Table 8: Maximum System Sizes – Sea-Level at Full Load ............................................. 28

Table 9: Part Load Performance Efficiency Model Data.................................................. 30

Table 10: Propulsion System Comparison. ....................................................................... 41

Table 11: CH4 (SR) – System Load. ................................................................................ 56

Table 12: CH4 (SR) – Fuel Utilization. ............................................................................ 57

Table 13: CH4 (SR) – Turbine Inlet Temperature. ........................................................... 58

Table 14: CH4 (SR) – Gas Turbine Shaft Speed. ............................................................. 59

Table 15: CH4 (SR) – Compressor Mass Flow Rate. ....................................................... 60

Table 16: CH4 (SR) – Solid Oxide Fuel Cell Voltage...................................................... 61

Table 17: CH4 (SR) – Solid Oxide Fuel Cell Power. ....................................................... 62

Table 18: CH4 (SR) – Gas Turbine Power. ...................................................................... 63

Table 19: JP8 (SR) – System Load. .................................................................................. 64

Table 20: JP8 (SR) – Fuel Utilization. .............................................................................. 65

Table 21: JP8 (SR) – Turbine Inlet Temperature. ............................................................. 66

Page 12: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

xi

Table 22: JP8 (SR) – Gas Turbine Shaft Speed. ............................................................... 67

Table 23: JP8 (SR) – Compressor Mass Flow Rate. ......................................................... 68

Table 24: JP8 (SR) – Solid Oxide Fuel Cell Voltage. ...................................................... 69

Table 25: JP8 (SR) – Solid Oxide Fuel Cell Power. ......................................................... 70

Table 26: JP8 (SR) – Gas Turbine Power. ........................................................................ 71

Table 27: H2 – System Load. ........................................................................................... 72

Table 28: H2 – Fuel Utilization. ....................................................................................... 73

Table 29: H2 – Turbine Inlet Temperature. ...................................................................... 74

Table 30: H2 – Gas Turbine Shaft Speed. ........................................................................ 75

Table 31: H2 – Compressor Mass Flow Rate. .................................................................. 76

Table 32: H2 – Solid Oxide Fuel Cell Voltage. ................................................................ 77

Table 33: H2 – Solid Oxide Fuel Cell Power. .................................................................. 78

Table 34: H2 – Gas Turbine Power. ................................................................................. 79

Table 35: CH4 (POX) – System Load. ............................................................................. 80

Table 36: CH4 (POX) – Fuel Utilization. ......................................................................... 81

Table 37: CH4 (POX) – Turbine Inlet Temperature. ........................................................ 82

Table 38: CH4 (POX) – Gas Turbine Shaft Speed. .......................................................... 83

Table 39: CH4 (POX) – Compressor Mass Flow Rate. .................................................... 84

Table 40: CH4 (POX) – Solid Oxide Fuel Cell Voltage. ................................................. 85

Table 41: CH4 (POX) – Solid Oxide Fuel Cell Power. .................................................... 86

Table 42: CH4 (POX) – Gas Turbine Power. ................................................................... 87

Table 43: C3H8 (POX) – System Load. ........................................................................... 88

Table 44: C3H8 (POX) – Fuel Utilization. ....................................................................... 89

Page 13: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

xii

Table 45: C3H8 (POX) – Turbine Inlet Temperature. ...................................................... 90

Table 46: C3H8 (POX) – Gas Turbine Shaft Speed. ........................................................ 91

Table 47: C3H8 (POX) – Compressor Mass Flow Rate. .................................................. 92

Table 48: C3H8 (POX) – Solid Oxide Fuel Cell Voltage. ............................................... 93

Table 49: C3H8 (POX) – Solid Oxide Fuel Cell Power. .................................................. 94

Table 50: C3H8 (POX) – Gas Turbine Power. ................................................................. 95

Table 51: JP8 (POX) – System Load. ............................................................................... 96

Table 52: JP8 (POX) - Fuel Utilization. ........................................................................... 97

Table 53: JP8 (POX) – Turbine Inlet Temperature. ......................................................... 98

Table 54: JP8 (POX) – Gas Turbine Shaft Speed. ............................................................ 99

Table 55: JP8 (POX) – Compressor Mass Flow Rate..................................................... 100

Table 56: JP8 (POX) – Solid Oxide Fuel Cell Voltage. ................................................. 101

Table 57: JP8 (POX) – Solid Oxide Fuel Cell Power. .................................................... 102

Table 58: JP8 (POX) – Gas Turbine Power. ................................................................... 103

Table 59: CH4 (IR) – Part Load System Efficiency. ...................................................... 104

Table 60: JP8 (SR) – Part Load System Efficency. ........................................................ 104

Table 61: H2 – Part Load System Efficiecy. .................................................................. 105

Table 62: CH4 (POX) – Part Load System Efficiency. .................................................. 105

Table 63: C3H8 (POX) – Part Load System Efficiency. ................................................ 106

Table 64: JP8 (POX) – Part Load System Efficiency. .................................................... 106

Page 14: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

xiii

NOMENCLATURE

Fuel cell active area,

Interconnect area specific resistance, Ω-

Chemical activity of diatomic Hydrogen, dimensionless

Chemical activity of water vapor, dimensionless

Chemical activity of diatomic Oxygen, dimensionless

Gas mixture concentration,

Pre-exponential factor for anode exchange current density, A/

Pre-exponential factor for cathode exchange current density, A/

Electrolyte temperature dependence term 1/K

Resistance pre-exponential factor, dimensionless

Gas mixture specific heat, kJ/kmol-K

Anode effective diffusivity,

Cathode effective diffusivity,

Average anode grain size, μm

Average cathode grain size, μm

Binary gas diffusivity,

E Voltage, V

Energy, W

Anode activation energy, J/mole

Cathode activation energy, J/mole

Nernst Cell Potential, V

Cell potential at standard conditions, V

F Faraday’s Constant, 96485 C/mole

Gibbs free energy of formation, kJ/mole

Page 15: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

xiv

Enthalpy, kJ

Convective heat transfer coefficient, W/

Enthalpy of formulation at standard reference state, kJ/mol

Sensible enthalpy at standard reference state, kJ/mol

Sensible enthalpy at STP condition, kJ/mol

Current, A

Current density, A/

Anode limiting current density, A/

Cathode limiting current density, A/

Anode electrode exchange current density, A/

Cathode electrode exchange current density, A/

Specific heat ratio, dimensionless

Coefficient of the anode exchange current density, A/m²

Coefficient of the cathode exchange current density, A/m²

SOFC/GT load, percent

Molecular weight, g/mol

Mass flow rate, kg/s

Species flow rate, kmole/s

Number of electrons transferred anode side, dimensionless

Number of electrons transferred cathode side, dimensionless

Power, kW

Power density, W/

Total mixture pressure, atm

Partial pressure of diatomic Hydrogen, atm

Partial pressure of water vapor, atm

Partial pressure of diatomic Oxygen, atm

Standard reference pressure, atm

Pressure ratio, dimensionless

Heat, W

Ratio of anode grain contact neck length to grain size, dimensionless

Page 16: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

xv

Ratio of cathode grain contact neck length to grain size, dimensionless

Average anode pore radius, micron

Average cathode pore radius, micron

Universal gas constant, J/mole-K

Reaction rates for each gas species, kmol/s

Temperature, K

Volume,

Work, kW

Gas species mole fraction, kmol

Altitude, ft

Number of electrons transferred for each molecule of fuel

Symmetry coefficient, dimensionless

Electrolyte thickness, μm

Anode electrode porosity, dimensionless

Cathode electrode porosity, dimensionless

Anode activation polarization, V

Cathode activation polarization, V

Compressor design efficiency, dimensionless

Anode concentration polarization, V

Cathode concentration polarization, V

Electrolyte ohmic polarization, V

Interconnect ohmic polarization, V

Turbine design efficiency, dimensionless

Fuel Utilization

Anode electrode tortuosity, dimensionless

σ Leonard-Jones collision diameter, angstrom

Ω Diffusion collision integral, dimensionless

Page 17: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

xvi

Page 18: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

xvii

ACKNOWLEDGEMENTS

I have learned so much through this journey of pursuing an advanced degree in

mechanical engineering. Through this process, I have enhanced my engineering,

mathematical, and communication skillsets, thus growing as an engineer. I have

encountered many people during this time whom have contributed a great deal to my

education.

I would first like to thank my thesis advisor, Dr. Rory Roberts, for the opportunity

to conduct this research and pursue an advanced degree in engineering. Without all of his

time and financial support contributed, this would not have been possible. Whenever I

would run into an issue with my model and be completely stuck, he would provide

enough guidance to set me off in the right direction. Not only did he provide guidance

with my research, but he also provided guidance with any questions I had about course

selection.

I would also like to thank my committee member Dr. Scott Thomas. His office

door was also open for additional help. If I needed to have someone there to just listen

while I talked through a problem, engineering or personal, he was available. I would like

to thank my other committee member Dr. Hong Huang for taking time out of her busy

schedule to review this thesis and attend my defense presentation.

Last but not least I would like to thank my wonderful family and friends. Without

their unconditional support, this would have been a much harder journey. During the long

nights and stressful times, they were always there for me. I couldn’t have asked for better

support during my studies.

Page 19: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

1

INTRODUCTION

As unmanned aerial vehicles (UAVs) become more advanced and continue to

push the envelope, the need for a high efficiency, long endurance propulsion system that

is capable of supporting large onboard electrical loads increases. The integration of a gas

turbine (GT) with a solid oxide fuel cell (SOFC) has already proven to be an efficient and

useful means of stationary power generation. Traditional solid oxide fuel cell hybrid gas

turbine (SOFC/GT) power systems are composed of components that are not ideal for an

airborne platform, such as heavy heat exchangers, motor driven blowers, and separate

combustion regions. The integration of a SOFC combustor hybrid GT system eliminates

the need for such heavy equipment by combining the SOFC and combustor regions,

along with strategic plumbing in which chemical recuperation is achievable. With the

integration of a fuel cell module to a GT engine, these hybrid systems can have lower

power degradation characteristics at high altitude conditions compared to traditional heat

based power systems. Traditional heat based power systems have large performance

degradations at higher altitudes. This power degradation is coupled with the lower

available air supply from the compressor. For example, the Capstone C30 micro turbine

drops to 45 percent of the maximum power at 20,000 feet, which is a 55 percent

degradation in power (Capstone 2006). The majority of the available published research

talks about stationary SOFC/GT system performance and modeling, while select few

discuss applications for airborne platforms. Although this is true, stationary and mobile

SOFC/GT’s share the same unique component, the SOFC. The physics and chemistry

behind the operation of the SOFC remains the same between both applications, therefore

Page 20: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

2

much can be learned and applied to airborne platforms by studying stationary systems.

Several publications were reviewed that pertain to this area of research and were used to

provide guidance.

Chinda and Brault (2012) of the College of Industrial Technology at King

Mongkut’s University of Technology, North Bangkok, have created a SOFC/GT power

system numerical model for an auxiliary power unit. Their auxiliary power unit was

designed to deliver 440 kW of net electrical power for a long-range, 300 passenger

aircraft. Their SOFC/GT hybrid model achieved system efficiencies of 45.1 percent,

compared to a similar model with cycle efficiency of 42.0 percent. The high efficiency

system was achieved by conducting an analysis to determine the optimal configuration of

the SOFC, compressor, combustor, heat exchanger, and GT. The configuration that

Chinda’s and Brault’s used was the following: air gets compressed via a compressor, the

air is then heated by exhaust gases from the gas turbine exit via a heat exchanger, then

both air (oxidant) and hydrogen (fuel) is supplied to the SOFC. The SOFC produces

electricity along with high pressure and high temperature exhaust. The unspent SOFC

fuel and high temperature and pressure SOFC cathode exhaust is then combusted in a

combustor. This created heat is then used to preheat the fuel going into the SOFC and is

sent to the turbine to expand and generate even more electrical power. This set up allows

for the SOFC to be self-sustaining in terms of temperature balance across the cell stack.

Utilizing the waste heat from the SOFC in the gas turbine increases the cycle efficiency.

This study showed that with certain flow rates and heat transfer coefficients, extreme

temperatures could be reached, hurting the performance of both the compressor and gas

Page 21: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

3

turbine. Using this study, the authors were able to optimize their fuel and oxidant flow

rates to achieve an optimum cycle efficiency of 45.1 percent.

Freeh, Pratt, and Brouwer (2004) developed SOFC and fuel processing models

that were incorporated into the Numerical Propulsion Systems Simulation (NPSS)

software package. The NPSS is a National Aeronautics and Space Administration

(NASA) computing architecture that is used to aid in numerical propulsion system

modeling. A generic SOFC/GT system, not optimized for any parameters, was modeled

within the NPSS software package to evaluate combined model capability. The system

modeled consisted of an SOFC, compressor, turbine, steam reformer, and multiple heat

exchangers. A kerosene type jet fuel Jet-A, modeled as , was used as the main fuel

source for the simulation. The SOFC/GT system hybrid was designed to run at 200 kW of

net electrical power. Of the 200 kW produced, the SOFC made up 186 kW of the total

electrical output. In their model, the SOFC was operated at a cell voltage of E = 0.571

volts, a current density of j = 500 mA/ resulting in a power density of p = 285

mW/ , fuel utilization of μ = 75.0 percent, a stack temperature of 900°C, and a stack

pressure of 4.5 bar. The open circuit and Nernst voltages were reported as = 0.947 V

and = 0.878 V respectively. A compressor adiabatic efficiency of 75 percent and

turbine adiabatic efficiency of 85 percent were used. The turbine inlet temperature was

held to 650°C, while the compressor exit temperature was 243°C. The compressor

pressure ratio used was = 4.94. Having used higher heating value (HHV) for the

incoming fuel energy flow, the thermal efficiency of the modeled system was

approximately 40.6 percent.

Page 22: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

4

Chan, S., H. Ho, and Y. Tian (2003) modeled a large scale internal reforming

solid oxide fuel cell and gas turbine power system (IRSOFC-GT) for application in the

residential power supply as a stand alone power station. The system under study

consisted of a combustor, SOFC stack of 40,000 cells, gas turbine, free-rotating power

turbine, two compressors, two recouperators, and a heat-recovery steam generator. This

system was modeled to predict plant performance under full and part load operating

conditions. The fuel cells were operated at a voltage of E = 0.619 volts, a current density

of j = 250.7 mA/ , and a fuel utilization of μ = 85 percent. The net power output of the

plant was = 1700 kW with a net thermal efficiency of 80.5 percent, lower heating value

(LHV). This study showed that plant efficiency was maximum at full load operation. At

part load operation, operating at 56.8 percent of full load, the electrical efficiency

degraded by 22.6 percent. Chan, S., H. Ho, and Y. Tian (2003) concluded that in a large

scale SOFC/GT power plant, it is cost-effective to operate by direct combustion of the

incoming fuel, thus imporving gas turbine performance under part load operation.

Aguiar, P., C.S. Adjiman, and N.P. Brandon (2004) developed a one-dimensional

dynamic anode supported planar solid oxide fuel cell stack model. The model used mass

and energy balances along with electrochemical principles to relate anode and cathode

compositions to SOFC voltage, current density, and power density. The perforamce was

analyazed for co-flow and counter flow operation at several temperatures, T = 1073,

1023, and 973 k (800, 750, and 700 °C ) and for various fuel utilizations, μ = 0, 50, 75,

and 80 percent. The maximum power density for the planar SOFC occurred with a fully

reformed fuel mixture at 1073 k. The fuel was fully reformed internally within the first 20

percent of the length of the cell. The power and current density was p = 0.86 W/ and

Page 23: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

5

j = 2.1 A/ , respectfully, with an operating voltage of E = 0.42 V. A secondary fuel

was analyzed, 10 percent pre-reformed methane at μ = 75 percent fuel utilization. With

this fuel mixture, the SOFC operated at E = 0.66 volts and a power density of p = 0.33

W/ at 75 percent fuel utilization.

Kimijima, Komatsu, and Szmyd (2010) numerically modeled a 220 kW solid

oxide fuel cell gas turbine hybrid system at sea-level. Their system was based off of work

previously conducted by Song, Sohn, Kim, Ro, and Suzuki (2005) that created a quasi-

two dimensional model of a tubular SOFC/GT hybrid system. This system consisted of a

compressor, turbine, SOFC module, two recuperators, a desulfurizer and an electric

generator. The exhaust gas from the SOFC was sent to the turbine to generate mechanical

power. The thermal energy from the turbine exhaust was recovered in a recuperator and

used to pre-heat the incoming fuel and air. The incoming fuel is desulfurized prior to

entering the SOFC. Of the 220 kW total power output, the gas turbine contributed 45 kW.

The compressor and turbine efficiencies were 78 and 82 percent respectively. The turbine

inlet temperature was held to 840°C with a pressure ratio of 2.9. Both recuperators

temperature effectiveness were 89 percent. The SOFC module had an active cell area of

A = 94.5 and a current density of j = 3200 A/ . The SOFC module was modeled

as a pre-reformer, internal reformer, and a cell stack. The only fuel analyzed was

methane, which recirculated from the anode exhaust to be the steam supply for the

reformer. A part load analysis was conducted in terms of power output percentage. This

system showed to have a 60 percent (LHV) power generation efficiency at the design-

point conditions.

Page 24: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

6

Dicks (1998) and Clark, Dicks, Pointon, Smith, and Swann (1997) conducted

research on catalysts and fuel reforming processes for fuel cells. Direct steam reforming

(SR) and catalytic partial oxidation (POX) are two attractive methods for producing

hydrogen from hydrocarbon fuels such as natural gas. Reforming fuels by catalytic partial

oxidation is typically less efficient compared to steam reformation. The main reason for

this is because in the partial oxidation reaction, a significant portion of the hydrogen fuel

is oxidized to provide heat necessary for the reaction to occur. To achieve direct steam

reformation, a fuel cell anode material that is chemically-stable must be chosen. The

anode of choice is a Nickel-Yttria-Stabilized Zirconia cermet (Ni-YSZ). This cermet,

when fabricated by means of chemical vapour deposition (CVD) methods, have shown to

be stable for 30,000 hours of operation. One of the most problematic issues with the Ni-

YSZ cermet is that at high operating temperatures, the steam reformation kinetics occur

rapidly, causing much of the fuel to be reformed a short distance from the cell entrance.

This can cause a large thermal gradient across the cell if not properly managed, leading to

mechanical failure.

The main purpose of the present research was to analyze the part load

performance of a solid oxide fuel cell combustor hybrid gas turbine propulsion system at

design and off-design operating conditions for application on unmanned aerial vehicles.

A system level numerical model was created within the MATLAB/Simulink environment

that is capable of capturing both the dynamic and steady-state performance of an anode-

supported SOFC combustor integrated with a commercially-available gas turbine engine

used for remote control aircraft. The design point operation of the hybrid system was for

maximum power at sea level. A steady-state part load performance analysis was

Page 25: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

7

conducted for various loads ranging from 10 ≤ L ≤ 100 percent and at varying altitudes

ranging from 0 ≤ Y ≤ 20,000 feet. The load was normalized by the maximum power load

occurring at sea level. This analysis was conducted for different fuel mixtures:

humidified hydrogen, propane, methane, and JP-8 jet propellant. Three different fuel

processing methods were modeled also: a catalytic partial oxidation of propane, methane,

and JP-8 jet propellant, direct reformation of methane internal to the fuel cell, and steam

reformation of the jet propellant. For this analysis, lower heating value (LHV) was used

for fuel energy input and efficiency calculations. For the present steady-state analysis, the

system thermal efficiency was plotted against the normalized load for each altitude and

fuel type. A complete data set including fuel utilization, electrical power (SOFC and GT),

compressor mass flow rate, and turbine shaft speed plotted against the normalized load

for each altitude and fuel type is shown in Appendix F.

BACKGROUND

Fuel cells are an energy conversion device that directly converts the chemical

energy stored in a fuel into electricity through electrochemical reactions that take place at

the electrode – electrolyte interface. This direct conversion of energy is what makes fuel

cells more efficient than traditional combustion engines. Fuel cells have many advantages

over traditional combustion engines. Fuel cells have high efficiencies, fast reaction rates,

silent operation, no moving mechanical parts, continuous power production as long as

fuel and oxidant is supplied, and can be thermally self-sustaining (utilization of high

temperature exhaust gases). Some disadvantages to fuel cells are: expensive processing

cost due to exotic materials for high temperature application and material degradation.

Page 26: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

8

There are three main components to a fuel cell: anode, cathode, and electrolyte. The

anode is the electrode where the hydrogen reduction reaction takes place. This is where

the hydrogen fuel loses two electrons, producing positively charged hydrogen ions and

two electrons. These two electrons travel to the cathode via an external circuit, where

they are harnessed to do electrical work. The cathode is the electrode where the oxygen

reduction reaction takes place. This is where oxygen from the air supply gains the two

electrons. The electrolyte is a material that is an ionic conductor and electronic insulator,

thus allowing the hydrogen (in the case of hydrogen ion conducting electrolytes) ions to

diffuse through to the cathode side, while blocking electron transfer. The two

electrochemical half-reactions for hydrogen – oxygen fuel cells with hydrogen

conducting electrolytes, such as the PAFC and PEMFC, are shown below (O'Hare, et al.

2009):

+

Thus, the total reaction for hydrogen – oxygen fuel cells is shown below:

Fuel cells are classified by the type of material the electrolyte is made of. There

are five main types of fuel cells: Phosphoric acid fuel cells (PAFC), polymer electrolyte

fuel cells (PEMFC), alkaline fuel cells (AFC), molten carbonate fuel cells (MCFC), and

solid oxide fuel cells (SOFC), each having their own advantages and disadvantages.

Table 1 below shows the different conducting ions and operating temperatures for the

five fuel cells mentioned above.

Page 27: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

9

Table 1: Fuel Cell Characteristics

Fuel Cell Conducting Ion Operation Temperature

PAFC 180 – 210 °C

PEMFC RT – 80°C

AFC 60 – 250°C

MCFC 500 – 650°C

SOFC 600 – 1000°C

When dealing with fuel cells, the key to work potential of a fuel cell lies with Gibbs free

energy. In a chemical reaction, only a certain amount of chemical energy can be

converted to do useful work. From thermodynamics, the Gibbs free energy gives the

maximum amount of energy that is available for useful work. In an electrochemical

process, the available work comes from the movement of electrons as current. The

standard potential or open circuit voltage (OCV) for the above total reaction is given by

(Larminie and Dicks 2003):

Fuel cells have three main irreversibility’s, or polarizations, that cause voltage losses.

These are activation polarizations, ohmic polarizations, and concentration polarizations.

Activation polarizations are losses due to electrochemical reaction kinetics that occur at

the electrode – electrolyte interfaces. Ohmic polarizations are losses due to ionic and

electronic charge transport. Concentration polarizations are losses due mass transport, the

supplying and removal of products and reactants. The combination of the OCV and the

polarizations give an actual cell potential under operating conditions.

Page 28: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

10

Solid Oxide Fuel Cells

The two most common geometries of SOFC’s are planar and tubular types. The

planar geometry uses a flat sandwich type stack up of the electrodes and electrolyte. To

maintain fuel and oxidant seperation, this geometry requires additional flow structures to

be constructed for the fuel and oxident streams. The tubular geometry provides added

mechanical stability due to the rigid cylindrical geometry compared to a planar SOFC.

This added mechanical stablility makes the tubular SOFC a better selection for

applicaiton in airborne platforms. Tubular SOFC’s with a capped end further increase the

cell’s mechanical stablility while also reducing the probability of leaks due to the reduced

number of connection points. Fuel cells are typically anode or cathode supported. For the

present research, an anode-supported SOFC was modeled. With an anode-supported fuel

cell, the anode material provides the main support for the cell. The electrolyte and

cathode layers are then applied on top of the anode material, creating the electrode –

electrolyte stack up. Figure 1 below shows a schematic and electrode – electrolyte stack

up for an anode supported SOFC.

Figure 1: Anode Supported SOFC Schematic.

The present SOFC model was modeled after an anode-supported fuel cell with

Yttria-Stabilized Zirconia (YSZ) as the electrolyte, a Nickel – Yttria-Stabilized Zirconia

Page 29: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

11

(Ni-YSZ) anode, and a Lanthanum Strontium Manganite – Yttria-Stabalized Zirconia

cathode (LSM-YSZ). Both Ni-YSZ and LSM-YSZ are ceramic mixed ionic-electronic

conductors (MIEC’s). These MIEC’s help increase electrochemical reactivity at both

electrode-electrolyte interfaces, thus leading to increased performance. Oxygen ions

transfer through the YSZ electrolyte by a vacancy hopping process. The introduction of

Yttria to a Zirconia lattice creates oxygen vacancies throughout the lattice. These oxygen

vacancies are created to maintain charge neutrality of the electrolyte. (Caputo, Chao and

Huang 2007) and (Kilo, et al. 2003) have performed detailed work in this area and have

shown that the ionic conductivity of the YSZ electrolyte is maximum when the dopant

concentration is 8 to 10 mole percent . Beyond 10 mole percent , the electrolyte

conductivity decreases. For the present study, a YSZ electrolyte with 10 mole percent

was modeled. To promote sufficient transfer of the oxygen ions through the YSZ

electrolyte, the SOFC must be operated at a high temperature (600-1000°C). This

required high operating temperature makes this type of fuel cell ideal for application in a

gas turbine, after the combustion region.

MATHEMATICAL MODEL

A system level mathematical model of the SOFC combustor / GT system was

created within the MATLAB/Simulink environment. Simulink is a software package that

enables users to simulate and analyze dynamic and steady-state systems. The Simulink

modeling environment uses a block and flow type construction, with a full library of

mathematical blocks. The model created consists of both the SOFC/GT and a system

controller. The present model has the capability to operate with various fuel types and

Page 30: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

12

fuel processing methods. The model is also capable of simulating operation at full or part

load at altitudes ranging from 0 ≤ Y ≤ 20,000 feet. To make interfacing with the system

user friendly, all the model parameters and variables are stored in one centralized

Microsoft Excel workbook. These parameters are read into the model by a separate script

file. Once these parameters are read in, the model is ready to be run. The model is run by

a simulation file that opens the SOFC/GT model and applies all the model parameters.

Once these are loaded, the simulation file then loops through all the part loads and

altitudes, exporting data specified by the user. These files are discussed in detail in

Appendix A.

Solid Oxide Fuel Cell Model

The mathematical modeling of the solid oxide fuel cell has been broken into

subsystems. There are subsystems for the cell electrochemistry, anode, and cathode.

Each of the anode and cathode subsystems has been treated as a control volume. In the

present model, the conservation of species, moles, and energy has been accounted for in

each of these subsystems. The conservation of momentum was not accounted for due to

the added complexities to the model.

SOFC Electrochemistry

In solid oxide fuel cell electrochemistry there is one main electrochemical

reaction that takes place within the cell:

Page 31: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

13

This total reaction can be broken up into two half-reactions, one taking place at the

anode-electrolyte interface and the other taking place at the cathode-electrolyte interface.

These two half reactions are as follows:

At the anode-electrolyte interface, the diatomic hydrogen fuel reacts with the negatively

charged oxygen ions that have diffused through the electrolyte from the cathode side. The

reaction of the diatomic hydrogen and oxygen ion produces water and two electrons. Due

to the high operating temperature of the SOFC, the water produced is in the form of

steam. At the cathode-electrolyte interface, diatomic oxygen reacts with two electrons

(having conducted from anode to cathode via an external circuit) to produce negatively

charged oxygen ions. These oxygen ions then diffuse through the ionic conducting YSZ

electrolyte. The work done by a fuel cell is in the form of an electric current.

A fuel cell’s electrochemical cell voltage is a function of chemical activity,

species concentration, gas pressure, and temperature. The Nernst potential (Nernst

equation) is the backbone of fuel cell thermodynamics. This equation relates temperature,

gas pressure, and species concentration to the electrochemical cell voltage or open circuit

voltage (OCV) and for the above reaction is given by (O'Hare, et al. 2009):

ln(

+

Page 32: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

14

For an ideal gas assumption, the chemical activity for diatomic hydrogen, diatomic

oxygen, and the water vapor is given by (Koehler, Jarrell and Bond 2001):

This assumption reduces the above Nernst potential equation to the following given by

(Yang, et al. 2013):

ln(

+

To expand the capability of the model and allow for fuel flexibility, a seven

species reaction vector is utilized. This reaction vector accounts for the consumption and

production of each species:

The reaction rates are related to the current demand of the fuel cell by Faraday’s Law:

Faraday’s law states that the amount of substance consumed or produced at the electrode

interface is directly proportional to the amount of electricity that passes through the cell.

Thus, the more current drawn from the cell, the more reactants consumed and products

produced. Using this relationship and the electrochemical half-reactions for the SOFC,

reaction vectors can be written for both the anode and cathode:

Page 33: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

15

SOFC Polarization Losses

Under real operating conditions, a fuel cell operates at a voltage less than that

described by the Nernst equation. This is due to polarizations that inhibit the fuel cell

reaction kinetics, electrical and ionic charge transport, and the convective and diffusive

mass transport. As the current demand from the fuel cell increases, the operational

voltage of the cell decreases due to these polarizations. The operational fuel cell voltage

is calculated by subtracting each of the polarizations from the Nernst potential:

Activation Polarization

In electrochemistry, cell potential is used to drive the electrochemical reactions

and their finite rates. Fuel cell reaction kinetics discusses how the mechanisms behind the

electrochemical reactions behave. In order to convert incoming reactants into products

and produce a voltage, a thermodynamically favorable forward reaction must occur. An

energy barrier must be overcome to produce a forward reaction. The reaction rate, or rate

at which reactants are converted into products, is determined by the probability of a

reactant species overcoming the energy barrier (activation energy). This activation barrier

Page 34: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

16

can be reduced by sacrificing some of the available cell potential. This activation

polarization can be solved for by using a modified version of the Butler-Volmer equation:

(

* +

(

*

In this equation, the operational current density is defined as:

There are many different published equations for anode and cathode exchange current

density, relating activation energy and detailed material properties of each electrode. The

anode and cathode exchange current density is calculated as follows:

(

*

(

*

The coefficient of the anode and cathode exchange current density takes into

account electrode specific properties such as porosity and grain size and is given by:

(

) [

( ) ]

(

) [

( ) ]

The model input parameters for the activation polarization sub-system are shown below

in Table 2.

Page 35: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

17

Table 2: SOFC Activation Polarization Model Input Parameters

Input Parameter Anode Cathode

Activation energy, (j/mol) 1.20E+05 1.50E+05

Number of electrons transferred, 2 4

Pre-exponential factor, (A/ 6.479E+03 2.265E+06

Porosity, (dimensionless) 0.40 0.40

Tortuosity, (dimensionless) 2.8 N/A

Average pore radius, (μm) 3 3

Average grain size, 1.5 1.5

Ratio of grain contact neck length to grain size 0.7 0.7

Ohmic Polarization

The ohmic losses in a fuel cell consist of resistance of the ion flow through the

electrolyte and resistance of electron flow through the electrodes. Accumulation and

depletion of electrons on both of the electrodes creates a voltage gradient. This voltage

gradient is what drives the transfer of electrons from electrode to electrode. The same

phenomena occur with the oxygen ions within the electrolyte. The voltage deficit is the

voltage required to overcome the resistances with both the electrodes and electrolyte. The

relationship for this voltage can be determined by using a form of Ohm’s law:

(°C)

The above equation is the voltage loss for the cell interconnects. When multiple cells are

connected together, whether in series or parallel, interconnects are made between each

cell to maintain a complete electrical circuit, thus allowing current to flow from one

current collector to the next. The electronic and ionic ohmic losses are given by (Antloga,

et al. 2005):

Page 36: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

18

The total ohmic losses within a fuel cell then become:

The model input parameters for the ohmic polarization sub-systems are shown below in

Table 3

Table 3: SOFC Ohmic Polarization Model Input Parameters

Input Parameter Value

Interconnect area-specific resistance, (Ω/ 0.05

Electrolyte temperature dependence term, (1/K) -3708.5

Resistance pre-exponential factor, 1.6549

Electrolyte Thickness, ( μm)

20

Concentration Polarization

Concentration polarization deals with the losses due to mass transport

phenomena. The two main types of mass transport within a fuel cell are due to diffusive

transport in the electrodes and convective transport in the fuel / oxidant flow channels.

The convective forces within the flow channels are due to the pressure gradients caused

by the pumps and compressors needed to supply fuel and oxidant to the cell. The

diffusive forces within the electrodes are due to species consumption and depletion at the

electrode-electrolyte interface. This results in a concentration gradient, thus driving the

chemical species through the electrodes. The governing equation for the concentration

polarization is given by (O'Hare, et al. 2009):

(

) (

* +

(

) (

*

This equation accounts for both the anode and cathode concentration terms. When

reactant concentrations at the electrode-electrolyte interface drop to zero, this presents a

Page 37: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

19

limiting case for the mass transport phenomena. Therefore, the fuel cell cannot handle a

current higher than that of the limiting current density, shown below:

The effective diffusivities for the anode and cathode reaction sites are calculated using

thermophysics principles, Leonard-jones potentials to describe the interaction between

gas species. A detailed explanation of this calculation is discussed in Appendix B. Due

to the porous nature of the fuel cell materials, during diffusion, gas molecules are

restricted. There are many published equations for this diffusion correction, but for high

temperature operation a more accurate model has been determined (Cussler 1995):

The model input parameters for the concentration polarization subsystem are shown

below in Table 4.

Table 4: SOFC Concentration Polarization Model Input Parameters.

Input Parameter Anode Cathode

Symmetry coefficient, 0.5 0.5

Gas mixture concentration, 10,000 10,000

Pre-exponential factor, (A/ 6.479E+03 2.265E+06

Porosity, (dimensionless) 0.40 0.40

Tortuosity, (dimensionless) 2.8 N/A

Page 38: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

20

Energy Analysis

A mass and energy analysis has been employed on each of the control volume

subsystems. Momentum conservation was not taken into account for this research due to

the complexities added. The conservation of mass was employed to account for each of

the gas species within the cell:

One assumption made for the mass conservation was that the chemical reactions for each

species occur in a quasi-static nature. Similar to the seven species reaction vector, a seven

species mole fraction vector was created to allow for mass conservation of multiple gas

species:

Mathematically, the total species conservation within the fuel cell becomes:

The conservation of energy was employed to account for all the energy entering

and exiting both the anode and cathode gas streams:

From fundamental thermodynamic energy laws, for a control volume, the energy

equation becomes:

Accounting for the enthalpy flows for both gas streams, the energy equation takes on

another form:

Page 39: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

21

[ ]

The gas species specific heat was calculated using a third-order polynomial curve fit

given by (Cengal and Boles 2011):

( )

The specific heat coefficients for different gases are shown below in Table 5.

Table 5: Specific Heat Coefficients for Various Gases.

Gas Formula

Methane 19.89

18

5.024 1.269 -11.01

Carbon Monoxide 18.16

0.1675 0.5372 -2.222

Carbon Dioxide 22.26 5.981 -3.501 -7.469

Hydrogen 29.11 -0.1916 0.4003 -0.8704

Water Vapor 32.24 0.1923 1.055 -3.595

Nitrogen 28.9 -0.1571 0.8081 -2.873

Oxygen 25.48 1.52 -0.7155 1.312

The enthalpy of the gas streams were calculated by integrating the third-order polynomial

equation for the specific heat of each gas, with respect to temperature:

∫ ( )

The heat transfer accounted for in the present model consists for the convective heat

transfer of the gas streams, the heat generated due to ohmic heating, and heat form the

water gas shift. Heat due to radiative heating was not taken into account for in this model

because a single cell was analyzed. To simulate a SOFC stack, the incoming and

outgoing flow rates of the fuel and oxidant were manipulated to simulate a user-specified

stack size. The heat produced due to ohmic heating was calculated as follows:

Page 40: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

22

Combustor Model

The combustor modeled is used to combust the unspent fuel from the anode-off

gas stream. The combustion chamber was treated as a single gas phase reactor and

assumed achieve complete combustion adiabatically. For the combustion subsystem, a

conservation of mass and energy was employed, very similar to that in the above sections

of this paper. The governing energy conservation equation used for this process, as

defined by fundamental thermodynamic principles is given by:

The combustor was modeled as a dynamic energy conversion equation. Assuming a

steady-state combustion process, the heat output was calculated by:

∑ ∑

The assumption of adiabatic combustion forces the enthalpy flow of the reactants to equal

the enthalpy flow of the products:

∑ ∑

This is an iterative process, upon which the adiabatic flame temperature can be

calculated.

Gas Turbine Model

The gas turbine modeled for these simulations are based off parameters from a

single-shaft, commercially-available remote control aircraft jet engine, the Jet Cat P-80

manufactured by Jet Cat USA. This engine is capable of producing 22 pounds of thrust at

a maximum shaft speed of 125,000 revolutions per minute (USA 2014). The gas turbine

model consists of a low pressure compressor, low pressure shaft, and low pressure

Page 41: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

23

turbine. The model loads in engine maps containing normalized parameters such as

pressure and shaft speed. The compressor and turbine outlet temperatures were calculated

using isentropic compression and expansion relationships given by (Cengal and Boles

2011):

(

(

(

)*+

( (

(

)

),

The specific heat ratio for an ideal gas was given by (Cengal and Boles 2011):

The compressor and turbine work was calculated from the enthalpy differential between

the inlet and exit states:

( )

( )

The low pressure shaft was modeled to calculate rotational speed by accounting for the

compressor load, turbine load, and engine input load. The shaft model assumes operation

is such that there is no friction. Table 6 below lists compressor and turbine properties

used in this study.

Page 42: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

24

Table 6: Gas Turbine Model Input Parameters.

Input Parameter Value

Design pressure ratio, 3.7

Design mass flow rate, (kg/s) 0.09

Design speed, (rev/min) 125,000

Compressor efficiency, 0.7

Turbine efficiency, 0.7

SOFC Combustor / GT Model

The unique integration of the SOFC combustor and the GT engine is really what

makes this system different from other published SOFC/GT hybrids. A traditional gas

turbine engine schematic is shown below in Figure 2.

Figure 2: Traditional Gas Turbine Engine Schematic.

In this system fuel and high pressure oxidant are combusted in a combustion chamber to

produce high temperature exhaust gas. This high temperature exhaust gas is then sent to

expand within the turbine, thus creating thrust or turning and electrical generator. The

problem with this system is the inefficient conversion of chemical energy within the fuel

to useful energy. For UAV systems, this useful energy is typically in the form of

electrical work or mechanical (propulsive) work. The traditional system wastes energy

Page 43: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

25

during the conversion process from chemical energy to thermal / heat energy. Each

energy conversion process involves a degradation of the quality of the energy, starting

out as high quality chemical energy and ending up as lower quality thermal energy.

The SOFC combustor / GT modeled takes advantage of the wasted energy

described above. A fuel cell stack can be integrated into the system to produce additional

electrical energy at a very low expense, while still maintaining a high quality exhaust gas

stream to be sent to the turbine engine. The only drawback to the system is the added

weight of the fuel cell stack. The SOFC/GT system modeled is shown below in Figure 3.

Figure 3: SOFC/GT Schematic.

In this hybrid system, the compressor and turbine operate like they would in a

traditional system but in addition; air and fuel are sent to the SOFC, producing additional

electricity capable of powering onboard electronics or sustaining other electrical loads

needed during flight. The unique feature about this system is the plumbing of the SOFC

combustor to the GT engine. Figure 3 shows all major components and plumbing

between the GT and SOFC combustor. The system has been broken into seven different

states to give an in depth look at operational characteristics. States 1 – 2 represents the

Page 44: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

26

compression of atmospheric air. The fuel is supplied at state 6 at the anode inlet. The

compressed air and unspent fuel from states 2 and 7 mixes together and combusts in the

combustion chamber, resulting in non-oxygen depleted high temperature combustion

products. The high temperature combustion products are then sent to the cathode side of

the SOFC. The cathode stream temperature increases as it travels down the cell due to

heat generation within the cell. The high temperature exhaust is then expanded in the

turbine between states 4 and 5. Power is produced between states 6 and 7 from a direct

conversion of fuel energy to electrical energy through electrochemical reactions and

between States 4 and 5 from the expansion of hot SOFC exhaust through the GT. This

configuration has many benefits such as the utilization of waste heat of the cathode-off

steam and pressurized stack operation. The pressurized operation of the fuel cell stack

helps increase performance by allowing the electrochemical reaction kinetics to occur at a

faster rate.

RESULTS AND DISCUSSION

To ensure that the SOFC model was operating close to reality, a series of

experiments were conducted on a tubular SOFC. There experiments consisted of voltage-

current density tests for various temperatures and fuel utilizations. The SOFC model

performance correlated well with the experimental data from the voltage-current density

tests. This data is now shown here due to limitations necessary for protecting intellectual

property.

Page 45: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

27

Steady-State Part Load Performance Analysis

The SOFC/GT model was sized for maximum power operation at sea-level and

for this research, the SOFC stack was sized to the commercially-available gas turbine

parameters. A mathematical controller was modeled to maintain a turbine inlet

temperature of 1093 k and a fuel cell stack temperature gradient of 170°C, which was set

to maintain chemical stability within the cell. During scoping runs, the fuel utilization of

the SOFC cell was not allowed to change; this caused the cell temperature gradient to

exponentially increase at lower part loads. It was then determined that the fuel utilization

needed to be flexible to maintain the 170°C gradient through all operating conditions.

A steady-state part load performance analysis was conducted using the SOFC

Combustor / Hybrid GT model over an altitude range of 0 ≤ Y ≤ 20,000 feet and a part

load range of 10 ≤ L ≤ 100 percent. This analysis was conducted for four different fuel

types: humidified hydrogen, methane, propane, and JP-8 jet fuel. The humidified

hydrogen model operated on a fuel composition of 97 percent hydrogen 3 percent water

vapor. Methane fuel was modeled two ways: a catalytic partial oxidation (POX) of the

methane gas and direct reformation of the methane internal to the cell through steam

reformation (SR). The propane case was modeled using a catalytic partial oxidation of the

propane gas. The JP-8 (Jet Propellant 8) was modeled two ways: a catalytic partial

oxidation of the JP-8 in an air POX reactor and steam reformation using added heat from

the SOFC. In both fuel processing methods, the JP-8 was fully reformed, no

hydrocarbons present in the reformation products. The hydrogen yield for each of the fuel

Page 46: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

28

processing methods modeled is shown below in Table 7. A detailed chemical analysis of

the fuel processing methods is discussed in Appendix C.

Table 7: Fuel Processing - Hydrogen Yield.

Fuel Hydrogen Yield (

– Steam Reformation 80 %

– Partial Oxidation 75 %

JP-8 – Steam Reformation 75 %

JP-8 – Partial Oxidation 67.5 %

– Partial Oxidation 70 %

As mentioned above, each model was sized to operate at maximum power at sea-

level. Maximum power was determined by increasing the system load until the voltage

reached the minimum operating point of = 0.5 volts (user-defined) and both the turbine

inlet temperature and SOFC temperature gradient criteria were met. Once this occurred,

the maximum load and total system power was established. The total system power is the

sum of the SOFC and GT power outputs. If the criteria were not met, the load and fuel

cell stack size was varied and the process was repeated. The system power results for

each model are summarized below in

Table 8.

Table 8: Maximum System Sizes – Sea-Level at Full Load

Fuel Number

of Cells

SOFC Power

(kW)

GT Power

(KW)

Total Power

(kW)

– Steam Reformation 215 22.85 5.12 27.97

JP-8 – Steam Reformation 200 21.49 5.21 26.7

- Humidified 180 21.34 4.63 25.97

– Partial Oxidation 180 19.76 5.08 24.84

JP-8 – Partial Oxidation 180 19.39 5.45 24.84

– Partial Oxidation 180 19.49 5.25 24.74

Page 47: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

29

The part load performance analysis showed that the model with the highest

system efficiency, and highest sea-level efficiency, was the SOFC/GT systems operating

on the direct internal steam reformation of methane and JP-8. This can be explained by

the systems thermal heat sink capacity. The heat sink capacity of the systems modeled

were limited by the gas turbine, thus the fuel cell stacks were sized to fit the fixed thermal

sink capacity. The systems utilizing steam reformation of the fuel increases the overall

system thermal heat sink capacity due to the endothermic nature of the steam reformation

reaction. The methane and JP-8 steam reformation systems produced the highest

efficiencies because during the steam reformation, heat is absorbed within the fuel cell

due to the steam reformation reaction. The absorption of this heat reduces the overall

temperature of the SOFC, thus dropping the turbine inlet temperature from the 1093 k set

point. This allows the fuel cell stack size to be increased. The larger stack size

subsequently results in a larger net power output from the SOFC. The internal steam

reformation of the methane not only increases power output from the cell, it also helps

with the cell thermal management and chemical recuperation through reforming with

waste heat. The part load performance efficiency data from the model is summarized

below in Table 9.

Page 48: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

30

Table 9: Part Load Performance Efficiency Model Data.

The SOFC/GT system running on steam reformation of methane has a system efficiency

that is 3 percent higher than that of the steam reformed JP-8, 30.4 percent higher than that

of the humidified hydrogen system, 40.9 percent higher than that of the partial oxidation

of methane system, 56 percent higher than that of partial oxidation of JP-8 system, and

51.9 percent higher than that of the partial oxidation of propane system. System

efficiency versus part load for each fuel type has been plotted in Figure 4 through Figure

6.

Fuel

Total

Power

(kW)

Max.

Efficiency

(%)

Sea-Level

Efficiency

(%)

– Steam Reformation 27.97 46.8 33.85

JP-8 – Steam Reformation 26.7 45.4 33.13

- Humidified 25.97 35.88 26.46

– Partial Oxidation 24.84 33.2 24.71

JP-8 – Partial Oxidation 24.84 30.0 22.39

– Partial Oxidation 24.74

30.8 22.93

Page 49: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

31

(a)

(b)

Figure 4: System Efficiency versus Part Load: (a) Sea-Level; (b) 4,000 ft.

Page 50: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

32

(a)

(b)

Figure 5: System Efficiency versus Part Load: (a) 8,000 ft; (b) 12,000 ft.

Page 51: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

33

(a)

(b)

Figure 6: System Efficiency versus Part Load: (a) 16,000 ft; (b) 20,000 ft.

Page 52: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

34

Figure 4 through Figure 6 clearly show how much of an impact on system

efficiency utilizing the natural internal reformation of methane fuel has. This internal

reformation is capable of being conducted because of the high operating temperature of

the SOFC, therefore no exotic internal catalyst would be needed to perform the fuel

reformation, unlike in an air POX reactor. In each of the cases, the maximum efficiency

occurs around 40 to 50 percent load. System efficiency drops off below 40 percent and

above 50 percent load. Operating below 40 percent load, the SOFC/GT system efficiency

significantly decreases. This is because below 40 percent load, the turbine speed saturates

at its minimum speed of 55,000 revolutions per minute. This results in the systems

inability to decrease the air mass flow rate through the system via the GT, consequently

causing the SOFC temperature gradient to rise above the 170°C set gradient. In order to

maintain this temperature gradient, the fuel utilization of the fuel cell must drop, sending

more fuel to the combustor. This increases the cathode inlet stream temperature, thus re-

establishing the SOFC temperature gradient. This causes a drop in system efficiency

because the system is no longer using fuel to produce additional electricity from the fuel

cell, but rather just for combustion purposes to maintain temperature. At loads below 40

percent, the hybrid SOFC/GT system starts acting like a traditional GT system and all the

added benefits of the hybrid system go to waste. System efficiency is lower at loads

higher than 50 percent design load. At these loads, the system fuel utilization is constant

but due to the increasing load the GT is continuously speeding up, bringing in more

cooling flow until it is saturated at its upper limit of 125k RPM at 100 percent design

load. The increased load causes the SOFC to drop in voltage, resulting in a less efficient

state of operation. To maintain constant fuel utilization, the fuel flow rate is increased.

Page 53: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

35

This increases the fuel energy introduced to the system. The power produced by the

SOFC and GT due to this increased load is not significant compared to the additional fuel

energy brought into the system, thus resulting in lower calculated system efficiencies. To

show these relationships, the fuel utilization, compressor mass flow rates, and SOFC

voltage for the internally reformed methane is plotted versus part load in Figure 7 through

Figure 9 below.

Figure 7: Fuel Utilization versus Part Load – CH4 (SR).

Page 54: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

36

Figure 8: Compressor Mass Flow versus Part Load – CH4 (SR).

Figure 9: Solid Oxide Fuel Cell Voltage versus Part Load – CH4 (SR).

These trends were consistent for each fuel type. The system efficiency versus part

load operation for each of the individual fuel types has been plotted in Figure 10 through

Figure 15, from sea-level to a ceiling of 20,000 feet. As altitude increases, the maximum

Page 55: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

37

load available at each altitude decreases. This is due to a decrease in air density and thus

a lower mass flow rate for the same turbine speed. Due to the decrease in the amount of

cooling air coming into the system, the load must be decreased to maintain the cell

temperature gradient. For each system, the maximum load available decreases from 100

percent at sea-level, to approximately 78-80 percent at 20,000 feet.

Figure 10: System Efficiency versus Part Load: Methane Steam Reformation.

Page 56: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

38

Figure 11: System Efficiency versus Part Load: JP-8 Steam Reformation.

Figure 12: System Efficiency versus Part Load: Humidified Hydrogen.

Page 57: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

39

Figure 13: System Efficiency versus Part Load: Methane Partial Oxidation.

Figure 14: System Efficiency versus Part Load: Propane Partial Oxidation.

Page 58: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

40

Figure 15: System Efficiency versus Part Load: JP-8 Partial Oxidation.

Impact to UAV Performance

A numerical comparison between a current UAV with a traditional heat based

propulsion system and the system analyzed in this study was conducted. The Predator’s

Rotax 914 four cylinder turbo-prop was compared against the fuel cell combustor hybrid

gas turbine system operating on steam reformed JP-8. Parameters that were compared

were engine weight, engine power density, fuel capacity, system power, and potential

work. This comparison is shown below in Table 10. The fuel cell combustor hybrid gas

turbine system is a heavier system, approximately 122.7 kg compared to the Rotax 914 at

78 kg. However, the SOFC/GT system has a much higher average system efficiency of

46 percent compared to 20 percent from the Rotax 914. Using the same fuel energy and

system wet weights; the SOFC/GT system analyzed in this research has more than

doubled the potential work compared to the Predator’s Rotax 914 propulsion system. A

UAV using this fuel cell combustor gas turbine hybrid propulsion system could achieve

Page 59: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

41

much longer loiter durations during a mission compared to current UAV traditional heat

based propulsion systems.

Table 10: Propulsion System Comparison.

Propulsion System Comparison

Specifications Rotax 914 SOFC/GT

Fuel Energy [kW-hr/kg] 11.97 11.97

System Weight dry [kg] 512.0 556.7

System Weight wet [kg] 1,020.0 1,020.0

Engine Volume [L] 185.2 237.0

Engine Weight [kg] 78.0 122.7

Engine Power Density [kW/kg] 0.94 0.44

Engine Power Density [kW/L] 0.39 0.23

Fuel Capacity [kg] 508.0 463.3

System Power [kW] 73.0 54.0

Average System Efficiency 20% 46%

Potential Work [kW-hr] 1,216.4 2,551.3

Page 60: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

42

CONCLUSIONS

A solid oxide fuel cell combustor gas turbine hybrid power system model for

application in unmanned aerial vehicles was developed within the MATLAB/Simulink

mathematical modeling software package. A steady-state part load performance analysis

was conducted using the SOFC Combustor / Hybrid GT model over an altitude range of 0

≤ Y ≤ 20,000 feet and a part load range of 10 ≤ L ≤ 100 percent. This analysis was

conducted for four different fuel types: humidified hydrogen, methane, propane, and JP-8

jet fuel. The humidified hydrogen model operated on a fuel composition of 97 percent

hydrogen 3 percent water vapor. Methane fuel was modeled two ways: a catalytic partial

oxidation of the methane gas (POX) and direct reformation of the methane internal to the

cell through steam reformation (SR). The propane case was modeled using a catalytic

partial oxidation of the propane gas. The JP-8 (Jet Propellant 8) was modeled two ways: a

catalytic partial oxidation of the JP-8 in an air CPOX reactor and steam reformation using

added heat from the SOFC. A system controller was modeled to maintain a turbine inlet

temperature of 1093 k and keep the solid oxide fuel cell temperature gradient at 170°C,

thus maintaining chemical stability within the cell.

It was found that if the fuel utilization of the fuel cell was not allowed to vary

with load and altitude, at part loads approximately lower than 40 percent, the fuel cell

temperature gradient exponentially increased. This was caused by a dramatic decrease in

cooling air due to the gas turbine being at its minimum shaft speed. The fuel cell

temperature gradient was successfully maintained once the fuel utilization was flexible.

Each system was sized to operate at maximum power at sea-level. As altitude increased,

it was observed that the maximum load decreased. This is due to the decrease in air

Page 61: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

43

density and thus a lower mass flow rate for the same turbine speed. The maximum load

dropped from 100 percent at sea-level to approximately only 80 percent, of the maximum

sea-level load, at 20,000 feet, which is 20 percent degradation in power. Traditional heat

based power systems have larger power degradations at part load operation, such as the

Capstone C30 micro turbine having a 55 percent power degradation at 20,000 feet. The

maximum system efficiency for each fuel type occurred around part loads of 40 ≤ L ≤ 60

percent. The most efficient system was found to be the SOFC/GT model that operated on

internally steam reformed methane. This reformation process is only able to happen

naturally due to the high operating temperature of the SOFC (˃ 600°C). This reformation

process is so advantageous to an airborne system because it allows for a larger fuel cell

stack for the same gas turbine size. This increase in stack size not only increases the net

power produced by the system, but also the overall system efficiency. The steam

reformed methane showed to have an efficiency at sea level of 33.85 percent and a

maximum efficiency at an altitude to L = 20,000 feet of 46.8 percent, with a stack size of

215 cells and a net power output of 27.87 kW. The increased performance at part loads at

altitude is opposite that of a traditional gas turbine engine. The hybrid system modeled

does not show the same performance degradation as current UAV systems have at part

loads, operating on traditional Brayton and Otto cycles.

A comparison between current UAV propulsion technology, such as the Rotax

914, and the fuel cell combustor system in this study showed that the hybrid system has

approximately double the work potential than the Rotax 914 (SOFC/GT with 2,551 kW-

hr, Rotax 914 with 1,216 kW-hr). The present analysis shows that the part load

performance of a SOFC/GT hybrid system depends heavily on the characteristics of the

Page 62: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

44

fuel cell combustor. The thermal management of these hybrid systems is crucial to

system performance, both full load and part load. Failing to manage the thermodynamics

of these systems will lead to a cascading effect ultimately resulting in system failure.

Since the majority of a UAV’s mission is during loiter, being able to operate at a higher

efficiency at part load seen during loiter will significantly increase mission duration and

mission range. This model can be further expanded upon to perform a dynamic analysis

on other aspects of the solid oxide fuel cell combustor gas turbine hybrid operating cycle.

By continuing this work and building upon mathematical models like the present, it will

allow us to continue learning about the integration, operation, and management of these

hybrid systems.

Page 63: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

45

APPENDIX A: MATLAB/SIMULINK MODEL FILES

To make this mathematical model user-friendly, the number of files needed to run

simulations was minimized. All model parameters are stored in one Microsoft Excel file.

Each component to the model has its own Excel sheet full of parameters. A MATLAB

scrip file was written to read in every parameter from the Excel file using MATLAB’s

“xlsread” command. In doing this, if a user needed to make a parameter change and re-

run a simulation, all they would need to do would be update the Excel workbook and

save. This file organization relieves a lot of complexities that can be involved in

computer aided numerical modeling. To run the model, another script file was written. It

is in this file where the user is able to specify what data is to be saved from the

simulation. This file allows the simulation to be run without having to have the model file

physically open. All files needed for the simulation must be in the same folder. The

sequence to running a simulation is as follows:

1.) Apply parameters to the model:

a. Run “SOFC_GT_OpenModel” file

2.) Specify which model to run and what simulation data to record and execute:

a. Run “Run_Simulaiton” file.

To help with debugging purposes, multiple progress bars were added to show the user

exactly what part load and altitude the model was currently running. This is helpful when

there are issues with the model; the user knows exactly what case was being simulated,

thus cutting down on debugging time. These files are shown below.

Page 64: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

46

Page 65: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

47

Page 66: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

48

Page 67: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

49

Page 68: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

50

Page 69: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

51

APPENDIX B: EFFECTIVE DIFFUSIVITY: LEONARD-JONES POTENTIALS

The effective diffusivity has been calculated using the Chapman-Enskog Theory

which has been proven to be accurate to approximately eight percent. In kinetic gas

theory, diffusivity is dependent on both the properties of the particle doing the diffusing

and the particles that are being diffused. Typically i denotes the diffusing party and j

denotes the party being diffused. To calculate the binary gas diffusion coefficient, a

weighted average of all seven gas species has been taken. The interaction between the

particles has been accounted for using Leonard-Jones potential parameters such as

collision diameter and collision integrals.

Binary Diffusion Coefficient:

[ (

*

]

Leonard-Jones Collision Diameter:

Leonard-Jones Potential Parameters found from Viscosities (Klein, et al. 1974)

Substance σ( ) ε/k (K)

Methane 3.758 148.6

Carbon Monoxide 3.69 91.7

Carbon Dioxide 3.941 195.2

Hydrogen 2.827 59.7

Water 2.641 809.1

Nitrogen 3.798 71.4

Oxygen 3.467 106.7

Page 70: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

52

Collision Integral Tabulated Data from (Klein, et al. 1974)

kT/e Ω kT/e Ω kT/e Ω kT/e Ω

0 10 1.3 1.273 2.7 0.977 4.8 0.8492

0.3 2.662 1.35 1.253 2.8 0.9672 4.9 0.8456

0.35 2.476 1.4 1.233 2.9 0.9576 5 0.8422

0.4 2.318 1.45 1.215 3 0.949 6 0.8124

0.45 2.184 1.5 1.198 3.1 0.9406 7 0.7896

0.5 2.066 1.55 1.182 3.2 0.9328 8 0.7712

0.55 1.966 1.6 1.167 3.3 0.9256 9 0.7556

0.6 1.877 1.65 1.153 3.4 0.9186 10 0.7424

0.65 1.798 1.7 1.14 3.5 0.912 20 0.664

0.7 1.729 1.75 1.128 3.6 0.9058 30 0.6232

0.75 1.667 1.8 1.116 3.7 0.8998 40 0.596

0.8 1.612 1.85 1.105 3.8 0.8942 50 0.5756

0.85 1.562 1.9 1.094 3.9 0.8888 60 0.5596

0.9 1.517 1.95 1.084 4 0.8836 70 0.5464

0.95 1.476 2 1.075 4.1 0.8788 80 0.5253

1 1.439 2.1 1.057 4.2 0.874 90 0.5256

1.05 1.406 2.2 1.041 4.3 0.8694 100 0.513

1.1 1.375 2.3 1.026 4.4 0.8652 200 0.4644

1.15 1.346 2.4 1.012 4.5 0.861 400 0.436

1.2 1.32 2.5 0.9996 4.6 0.8568 - -

1.25 1.296 2.6 0.9878 4.7 0.853 - -

Page 71: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

53

APPENDIX C: SOFC/GT FUEL CHEMISTRY

Besides the humidified hydrogen case, the two main fuel processing methods

modeled in the present model were with steam reformation and catalytic partial oxidation

of the fuels. In a steam reformation reaction, a hydrocarbon fuel reacts with steam at high

temperatures to produce carbon-monoxide, carbon-dioxide, hydrogen, and water in the

vapor state. Steam reformation is an endothermic reaction (absorbs energy). Steam

reformation typically has the highest hydrogen yield because steam reforming does not

react any oxygen, therefore does not cause a dilution of the air by nitrogen. To further

increase the hydrogen yield of this process, the carbon-monoxide can be shifted to

hydrogen in a water-gas shift reaction. In this reaction, carbon-monoxide reacts with

water vapor to produce carbon-dioxide and hydrogen. Partial oxidation reforming reacts a

hydrocarbon fuel with oxygen in the air to partially combust (oxidize) the fuel. This

reformation process is usually done with a catalyst. The chemical formulas used for these

reactions are given by (O'Hare, et al. 2009):

Hydrogen Yield:

Steam Reformation:

↔ (

*

Catalytic Partial Oxidation:

Page 72: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

54

Water-Gas Shift:

Page 73: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

55

APPENDIX F: SUMMARY OF SOFC/GT MODEL DATA

The following pages present the steady-state data recorded from the SOFC/GT

model part-load simulations for each fuel type and altitude.

Page 74: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

56

Table 11: CH4 (SR) – System Load.

Part Load (A) – CH4 (IR)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 21.0 19.9 19.0 18.2 17.3 16.5 15.7 15.0 14.2 13.4 12.7 20 42.0 39.8 38.0 36.4 34.6 33.0 31.4 30.0 28.4 26.8 25.4 30 63.0 59.7 57.0 54.6 51.9 49.5 47.1 45.0 42.6 40.2 38.1 40 84.0 79.6 76.0 72.8 69.2 66.0 62.8 60.0 56.8 53.6 50.8 50 105.0 99.5 95.0 91.0 86.5 82.5 78.5 75.0 71.0 67.0 63.5 60 126.0 119.4 114.0 109.2 103.8 99.0 94.2 90.0 85.2 80.4 76.2 70 147.0 139.3 133.0 127.4 121.1 115.5 109.9 105.0 99.4 93.8 88.9 80 168.0 159.2 152.0 145.6 138.4 132.0 125.6 120.0 113.6 107.2 101.6 90 189.0 179.1 171.0 163.8 155.7 148.5 141.3 135.0 127.8 120.6 114.3

100 210.0 199.0 190.0 182.0 173.0 165.0 157.0 150.0 142.0 134.0 127.0

Figure 16: CH4 (SR) – System Load versus Part Load.

Page 75: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

57

Table 12: CH4 (SR) – Fuel Utilization.

Fuel Utilization ( – CH4 (IR)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.216 0.215 0.216 0.217 0.218 0.219 0.220 0.221 0.221 0.221 0.223 20 0.357 0.355 0.357 0.358 0.360 0.361 0.362 0.365 0.365 0.365 0.366 30 0.456 0.454 0.456 0.458 0.459 0.461 0.462 0.465 0.465 0.461 0.450 40 0.529 0.528 0.530 0.531 0.533 0.534 0.527 0.521 0.514 0.505 0.496 50 0.567 0.565 0.563 0.560 0.557 0.553 0.549 0.544 0.538 0.533 0.525 60 0.570 0.569 0.569 0.567 0.565 0.563 0.559 0.557 0.554 0.549 0.544 70 0.571 0.571 0.571 0.570 0.569 0.567 0.566 0.564 0.562 0.559 0.554 80 0.570 0.570 0.570 0.570 0.570 0.570 0.570 0.569 0.567 0.565 0.565 90 0.569 0.569 0.569 0.569 0.570 0.571 0.571 0.571 0.571 0.570 0.569

100 0.569 0.569 0.570 0.570 0.571 0.572 0.572 0.573 0.573 0.573 0.573

Figure 17: CH4 (SR) – Fuel Utilization versus Part Load.

Page 76: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

58

Table 13: CH4 (SR) – Turbine Inlet Temperature.

Turbine Inlet Temperature (K) – CH4 (IR)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 1085 1086 1087 1088 1089 1089 1090 1091 1091 1092 1092 20 1087 1087 1088 1089 1089 1090 1091 1091 1092 1092 1093 30 1088 1089 1090 1090 1091 1091 1092 1092 1093 1093 1093 40 1091 1091 1092 1092 1093 1093 1093 1093 1093 1093 1093 50 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 60 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 70 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 80 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 90 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093

100 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093

Figure 18: CH4 (SR) – Turbine Inlet Temperature versus Part Load.

Page 77: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

59

Table 14: CH4 (SR) – Gas Turbine Shaft Speed.

Shaft Speed (kRPM) – CH4 (IR)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 20 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 30 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 56.5 60.6 40 55.0 55.0 55.0 55.0 55.0 55.2 57.8 60.8 63.7 67.2 70.8 50 61.0 61.3 62.8 64.8 66.7 69.0 71.4 73.6 75.3 77.0 79.4 60 78.0 77.7 78.3 79.4 80.4 81.5 82.8 84.3 85.3 86.5 88.1 70 91.5 90.7 91.1 91.7 92.3 93.0 93.4 94.4 94.7 95.4 96.5 80 103.5 102.5 102.5 102.5 102.4 102.4 102.4 102.8 102.9 102.9 103.0 90 113.4 112.1 112.0 112.1 111.7 111.4 111.3 111.7 111.3 111.1 111.2

100 124.4 122.8 122.3 122.2 121.7 121.6 121.5 121.9 121.4 120.8 120.8

Figure 19: CH4 (SR) – Gas Turbine Shaft Speed versus Part Load.

Page 78: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

60

Table 15: CH4 (SR) – Compressor Mass Flow Rate.

Compressor Mass Flow Rate (kg/s) – CH4 (IR)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.042 0.040 0.037 0.035 0.033 0.031 0.029 0.027 0.025 0.024 0.022 20 0.042 0.040 0.037 0.035 0.033 0.031 0.029 0.027 0.025 0.024 0.022 30 0.043 0.040 0.038 0.035 0.033 0.031 0.029 0.027 0.026 0.024 0.024 40 0.043 0.040 0.038 0.036 0.033 0.032 0.031 0.030 0.029 0.028 0.027 50 0.047 0.044 0.042 0.041 0.039 0.037 0.036 0.035 0.033 0.032 0.031 60 0.057 0.053 0.051 0.049 0.046 0.044 0.042 0.041 0.039 0.037 0.035 70 0.068 0.064 0.060 0.058 0.054 0.052 0.049 0.047 0.045 0.042 0.041 80 0.081 0.076 0.071 0.068 0.064 0.060 0.057 0.054 0.051 0.048 0.046 90 0.095 0.088 0.083 0.079 0.074 0.070 0.066 0.062 0.058 0.055 0.052

100 0.110 0.102 0.096 0.091 0.085 0.080 0.075 0.071 0.066 0.062 0.058

Figure 20: CH4 (SR) – Compressor Mass Flow Rate versus Part Load.

Page 79: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

61

Table 16: CH4 (SR) – Solid Oxide Fuel Cell Voltage.

SOFC Voltage (V) – CH4 (IR)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.927 0.927 0.927 0.927 0.927 0.926 0.926 0.925 0.924 0.924 0.923 20 0.857 0.860 0.862 0.863 0.865 0.866 0.867 0.868 0.869 0.871 0.871 30 0.794 0.800 0.803 0.806 0.810 0.813 0.816 0.818 0.821 0.825 0.830 40 0.737 0.744 0.750 0.754 0.760 0.764 0.770 0.776 0.782 0.789 0.795 50 0.687 0.697 0.705 0.712 0.720 0.727 0.735 0.741 0.749 0.757 0.764 60 0.647 0.658 0.667 0.675 0.685 0.693 0.702 0.709 0.718 0.727 0.736 70 0.609 0.621 0.632 0.641 0.652 0.661 0.671 0.680 0.689 0.700 0.709 80 0.573 0.587 0.598 0.609 0.620 0.631 0.641 0.651 0.662 0.673 0.683 90 0.538 0.554 0.566 0.578 0.590 0.602 0.614 0.624 0.636 0.648 0.659

100 0.506 0.522 0.535 0.548 0.562 0.574 0.587 0.598 0.611 0.624 0.636

Figure 21: CH4 (SR) – Solid Oxide Fuel Cell Voltage versus Part Load.

Page 80: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

62

Table 17: CH4 (SR) – Solid Oxide Fuel Cell Power.

SOFC Power (kW) – CH4 (IR)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 4.18 3.97 3.79 3.63 3.45 3.29 3.12 2.98 2.82 2.66 2.52 20 7.74 7.36 7.04 6.75 6.43 6.14 5.86 5.60 5.31 5.02 4.76 30 10.76 10.27 9.85 9.47 9.04 8.65 8.26 7.91 7.52 7.13 6.80 40 13.31 12.74 12.25 11.81 11.30 10.84 10.40 10.01 9.55 9.10 8.69 50 15.52 14.91 14.40 13.93 13.39 12.90 12.40 11.95 11.44 10.90 10.43 60 17.53 16.90 16.35 15.86 15.28 14.76 14.22 13.73 13.16 12.57 12.05 70 19.24 18.61 18.06 17.56 16.97 16.43 15.86 15.34 14.73 14.11 13.55 80 20.68 20.08 19.55 19.05 18.46 17.90 17.32 16.79 16.17 15.52 14.92 90 21.87 21.32 20.82 20.34 19.76 19.21 18.64 18.11 17.47 16.81 16.20

100 22.83 22.33 21.87 21.43 20.89 20.37 19.81 19.29 18.66 17.99 17.37

Figure 22: CH4 (SR) – Solid Oxide Fuel Cell Power versus Part Load.

Page 81: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

63

Table 18: CH4 (SR) – Gas Turbine Power.

GT Power (kW) – CH4 (IR)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 1.68 1.66 1.63 1.60 1.56 1.52 1.48 1.44 1.40 1.35 1.30 20 1.79 1.77 1.73 1.70 1.65 1.61 1.56 1.52 1.47 1.42 1.37 30 1.91 1.87 1.83 1.79 1.74 1.70 1.65 1.60 1.54 1.52 1.56 40 2.03 1.98 1.93 1.89 1.84 1.79 1.80 1.82 1.82 1.84 1.87 50 2.31 2.27 2.25 2.25 2.23 2.23 2.22 2.23 2.23 2.21 2.22 60 2.91 2.85 2.81 2.80 2.76 2.74 2.72 2.71 2.68 2.64 2.63 70 3.54 3.46 3.42 3.40 3.34 3.31 3.26 3.24 3.18 3.13 3.10 80 4.17 4.09 4.05 4.02 3.95 3.90 3.83 3.79 3.72 3.64 3.56 90 4.73 4.67 4.64 4.62 4.55 4.48 4.41 4.36 4.26 4.16 4.08

100 5.13 5.13 5.12 5.12 5.06 5.01 4.95 4.89 4.79 4.67 4.58

Figure 23: CH4 (SR) – Gas Turbine Power versus Part Load.

Page 82: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

64

Table 19: JP8 (SR) – System Load.

Part Load (A) Calculations – JP8 (SR)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 21.2 20.2 19.3 18.5 17.6 16.8 16.0 15.2 14.4 13.6 12.9 20 42.4 40.4 38.6 37.0 35.2 33.6 32.0 30.4 28.8 27.2 25.8 30 63.6 60.6 57.9 55.5 52.8 50.4 48.0 45.6 43.2 40.8 38.7 40 84.8 80.8 77.2 74.0 70.4 67.2 64.0 60.8 57.6 54.4 51.6 50 106.0 101.0 96.5 92.5 88.0 84.0 80.0 76.0 72.0 68.0 64.5 60 127.2 121.2 115.8 111.0 105.6 100.8 96.0 91.2 86.4 81.6 77.4 70 148.4 141.4 135.1 129.5 123.2 117.6 112.0 106.4 100.8 95.2 90.3 80 169.6 161.6 154.4 148.0 140.8 134.4 128.0 121.6 115.2 108.8 103.2 90 190.8 181.8 173.7 166.5 158.4 151.2 144.0 136.8 129.6 122.4 116.1

100 212.0 202.0 193.0 185.0 176.0 168.0 160.0 152.0 144.0 136.0 129.0

Figure 24: JP8 (SR) – System Load versus Part Load.

Page 83: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

65

Table 20: JP8 (SR) – Fuel Utilization.

Fuel Utilization ( – JP8 (SR)

Loa

d

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+

3

16E+3 18E+3 20E+3

10 0.21 0.206 0.207 0.209 0.21 0.210

5

0.212 0.21

3

0.213 0.213 0.214 20 0.34

5

0.3440

5

0.345 0.347 0.34

9

0.350

5

0.352 0.35

3

0.353 0.353 0.355 30 0.44

3

0.4420

7

0.443 0.446 0.44

8

0.449 0.450

2

0.45

2

0.452 0.440

8

0.430

5

40 0.51

6

0.516 0.516

8

0.519 0.51

8

0.513 0.508 0.5 0.49 0.486 0.475 50 0.55 0.545 0.542 0.539 0.53

5

0.532 0.528 0.52

2

0.517

5

0.51 0.506 60 0.55

4

0.55 0.547 0.546

2

0.54

4

0.541 0.54 0.53

3

0.532 0.528 0.524 70 0.55

4

0.55 0.547 0.546

2

0.54

5

0.545 0.545 0.54

4

0.54 0.534

5

0.534

5

80 0.55

4

0.55 0.548 0.548 0.54

7

0.547 0.548 0.54

8

0.547 0.545 0.543 90 0.55

4

0.55 0.549 0.549

2

0.55 0.55 0.55 0.55 0.55 0.547 0.547 100 0.55

4

0.554 0.554 0.554 0.55

6

0.556 0.556 0.55

6

0.556 0.555 0.555

Figure 25: JP8 (SR) – Fuel Utilization versus Part Load.

Page 84: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

66

Table 21: JP8 (SR) – Turbine Inlet Temperature.

Turbine Inlet Temperature (K) – JP8 (SR)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 1085 1086 1087 1088 1089 1089 1090 1091 1091 1092 1092 20 1087 1087 1088 1089 1090 1090 1091 1091 1092 1092 1093 30 1089 1089 1090 1091 1091 1092 1092 1093 1093 1093 1093 40 1092 1092 1092 1093 1093 1093 1093 1093 1093 1093 1093 50 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 60 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 70 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 80 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 90 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093

100 1094 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093

Figure 26: JP8 (SR) – Turbine Inlet Temperature versus Part Load.

Page 85: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

67

Table 22: JP8 (SR) – Gas Turbine Shaft Speed.

Shaft Speed (kRPM) – JP8 (SR)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 20 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 30 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.3 58.9 63.3 40 55.0 55.0 55.0 55.0 56.1 58.3 60.6 63.9 67.8 70.2 73.3 50 63.0 64.6 66.6 68.7 71.1 73.0 74.5 76.4 77.9 80.1 81.8 60 79.7 80.4 81.7 82.7 83.7 85.0 85.9 87.7 88.2 89.4 90.7 70 93.4 93.9 95.0 95.5 96.1 96.2 96.6 97.0 97.7 98.5 98.7 80 104.8 104.9 105.3 105.4 105.5 105.5 105.4 105.3 105.3 105.5 106.1 90 114.8 114.9 115.1 115.2 114.9 114.8 114.8 114.6 114.2 114.6 114.7

100 125.0 125.0 125.0 125.0 125.0 125.0 125.0 125.0 124.6 124.8 125.0

Figure 27: JP8 (SR) – Gas Turbine Shaft Speed versus Part Load.

Page 86: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

68

Table 23: JP8 (SR) – Compressor Mass Flow Rate.

Compressor Mass Flow Rate (kg/s) – JP8 (SR)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.042 0.040 0.037 0.035 0.033 0.031 0.029 0.027 0.025 0.024 0.022 20 0.043 0.040 0.038 0.036 0.033 0.031 0.029 0.027 0.026 0.024 0.022 30 0.043 0.041 0.038 0.036 0.034 0.032 0.030 0.028 0.026 0.026 0.025 40 0.043 0.041 0.038 0.036 0.034 0.033 0.032 0.031 0.030 0.029 0.029 50 0.048 0.046 0.044 0.043 0.041 0.039 0.038 0.037 0.035 0.034 0.033 60 0.059 0.056 0.054 0.051 0.049 0.047 0.045 0.043 0.041 0.039 0.037 70 0.071 0.067 0.064 0.061 0.058 0.055 0.052 0.049 0.047 0.045 0.043 80 0.083 0.079 0.076 0.072 0.068 0.064 0.061 0.057 0.054 0.051 0.048 90 0.098 0.093 0.088 0.083 0.078 0.074 0.070 0.066 0.062 0.058 0.055

100 0.112 0.106 0.100 0.094 0.089 0.084 0.079 0.074 0.069 0.065 0.061

Figure 28: JP8 (SR) – Compressor Mass Flow Rate versus Part Load.

Page 87: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

69

Table 24: JP8 (SR) – Solid Oxide Fuel Cell Voltage.

SOFC Voltage (V) – JP8 (SR)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.921 0.922 0.921 0.921 0.921 0.920 0.920 0.919 0.919 0.919 0.918 20 0.853 0.855 0.857 0.858 0.860 0.861 0.863 0.864 0.865 0.866 0.867 30 0.791 0.796 0.799 0.802 0.806 0.809 0.812 0.814 0.818 0.823 0.828 40 0.734 0.741 0.746 0.750 0.756 0.762 0.768 0.774 0.781 0.787 0.794 50 0.686 0.695 0.703 0.710 0.718 0.725 0.733 0.740 0.748 0.756 0.762 60 0.646 0.656 0.666 0.674 0.683 0.691 0.699 0.709 0.717 0.726 0.734 70 0.608 0.620 0.631 0.640 0.651 0.660 0.669 0.678 0.689 0.699 0.707 80 0.572 0.586 0.597 0.607 0.619 0.629 0.640 0.650 0.661 0.672 0.682 90 0.538 0.553 0.565 0.576 0.589 0.600 0.612 0.623 0.635 0.648 0.658

100 0.507 0.521 0.534 0.546 0.559 0.572 0.584 0.597 0.610 0.623 0.635

Figure 29: JP8 (SR) – Solid Oxide Fuel Cell Voltage versus Part Load.

Page 88: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

70

Table 25: JP8 (SR) – Solid Oxide Fuel Cell Power.

SOFC Power (kW) – JP8 (SR)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 3.90 3.72 3.56 3.41 3.24 3.09 2.94 2.79 2.65 2.50 2.37 20 7.23 6.91 6.62 6.35 6.05 5.79 5.52 5.25 4.98 4.71 4.47 30 10.06 9.64 9.26 8.90 8.51 8.15 7.79 7.43 7.06 6.72 6.41 40 12.45 11.97 11.52 11.11 10.65 10.24 9.83 9.42 9.00 8.57 8.19 50 14.54 14.04 13.57 13.14 12.64 12.18 11.72 11.25 10.77 10.28 9.83 60 16.43 15.91 15.42 14.95 14.42 13.94 13.43 12.93 12.39 11.85 11.36 70 18.05 17.54 17.05 16.58 16.03 15.51 14.98 14.43 13.88 13.31 12.77 80 19.41 18.92 18.44 17.98 17.43 16.92 16.37 15.81 15.23 14.62 14.07 90 20.53 20.09 19.64 19.19 18.65 18.15 17.62 17.05 16.46 15.86 15.28

100 21.49 21.05 20.62 20.21 19.69 19.21 18.70 18.15 17.56 16.95 16.37

Figure 30: JP8 (SR) – Solid Oxide Fuel Cell Power versus Part Load.

Page 89: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

71

Table 26: JP8 (SR) – Gas Turbine Power.

GT Power (kW) – JP8 (SR)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 1.69 1.68 1.65 1.62 1.58 1.54 1.50 1.45 1.41 1.36 1.32 20 1.81 1.79 1.75 1.72 1.67 1.63 1.58 1.53 1.49 1.44 1.38 30 1.93 1.90 1.86 1.82 1.76 1.72 1.67 1.62 1.57 1.60 1.63 40 2.05 2.01 1.96 1.92 1.89 1.89 1.89 1.91 1.94 1.93 1.97 50 2.39 2.38 2.38 2.38 2.37 2.36 2.36 2.36 2.35 2.35 2.34 60 3.00 2.98 2.97 2.96 2.93 2.91 2.88 2.88 2.83 2.79 2.77 70 3.65 3.64 3.63 3.61 3.56 3.51 3.46 3.40 3.36 3.33 3.26 80 4.27 4.27 4.25 4.23 4.18 4.13 4.05 3.98 3.90 3.82 3.76 90 4.82 4.83 4.82 4.81 4.74 4.70 4.63 4.56 4.46 4.39 4.30

100 5.21 5.23 5.23 5.25 5.19 5.16 5.11 5.04 4.95 4.85 4.75

Figure 31: JP8 (SR) – Gas Turbine Power versus Part Load.

Page 90: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

72

Table 27: H2 – System Load.

Part Load (A) Calculations – H2

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 23.0 22.0 21.0 20.1 19.2 18.3 17.4 16.6 15.8 14.9 14.1 20 46.0 44.0 42.0 40.2 38.4 36.6 34.8 33.2 31.6 29.8 28.2 30 69.0 66.0 63.0 60.3 57.6 54.9 52.2 49.8 47.4 44.7 42.3 40 92.0 88.0 84.0 80.4 76.8 73.2 69.6 66.4 63.2 59.6 56.4 50 115.0 110.0 105.0 100.5 96.0 91.5 87.0 83.0 79.0 74.5 70.5 60 138.0 132.0 126.0 120.6 115.2 109.8 104.4 99.6 94.8 89.4 84.6 70 161.0 154.0 147.0 140.7 134.4 128.1 121.8 116.2 110.6 104.3 98.7 80 184.0 176.0 168.0 160.8 153.6 146.4 139.2 132.8 126.4 119.2 112.8 90 207.0 198.0 189.0 180.9 172.8 164.7 156.6 149.4 142.2 134.1 126.9

100 230.0 220.0 210.0 201.0 192.0 183.0 174.0 166.0 158.0 149.0 141.0

Figure 32: H2 – System Load versus Part Load.

Page 91: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

73

Table 28: H2 – Fuel Utilization.

Fuel Utilization ( – H2

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.196 0.196 0.197 0.198 0.199 0.200 0.201 0.202 0.203 0.203 0.204 20 0.328 0.328 0.330 0.331 0.334 0.335 0.336 0.338 0.339 0.339 0.334 30 0.423 0.424 0.425 0.427 0.430 0.431 0.432 0.426 0.418 0.409 0.400 40 0.490 0.489 0.485 0.481 0.476 0.471 0.466 0.460 0.454 0.447 0.440 50 0.500 0.496 0.496 0.493 0.491 0.487 0.483 0.479 0.474 0.469 0.463 60 0.502 0.501 0.501 0.499 0.497 0.495 0.492 0.489 0.486 0.483 0.480 70 0.502 0.502 0.502 0.502 0.502 0.500 0.498 0.496 0.494 0.492 0.490 80 0.503 0.503 0.503 0.503 0.503 0.503 0.503 0.503 0.500 0.498 0.496 90 0.506 0.506 0.506 0.506 0.506 0.506 0.506 0.507 0.507 0.506 0.506

100 0.529 0.528 0.529 0.530 0.531 0.531 0.531 0.532 0.533 0.532 0.532

Figure 33: H2 – Fuel Utilization versus Part Load.

Page 92: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

74

Table 29: H2 – Turbine Inlet Temperature.

Turbine Inlet Temperature (K) – H2

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 1085 1086 1087 1088 1089 1089 1090 1091 1091 1092 1092 20 1087 1088 1089 1089 1090 1091 1091 1092 1092 1093 1093 30 1090 1090 1091 1091 1092 1092 1093 1093 1093 1093 1093 40 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 50 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 60 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 70 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 80 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 90 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093

100 1098 1098 1098 1097 1098 1097 1097 1097 1097 1096 1096

Figure 34: H2 – Turbine Inlet Temperature versus Part Load.

Page 93: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

75

Table 30: H2 – Gas Turbine Shaft Speed.

Shaft Speed (kRPM) – H2

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 20 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 57.1 30 55.0 55.0 55.0 55.0 55.0 55.0 55.0 57.7 61.1 64.7 68.8 40 56.3 57.2 59.1 61.1 64.1 66.5 69.1 72.1 74.3 76.3 78.7 50 74.6 75.9 76.6 77.8 79.3 80.7 82.2 84.0 85.8 87.1 89.0 60 89.6 90.0 90.4 91.3 92.5 93.3 94.1 95.1 96.3 96.8 97.4 70 102.8 102.6 102.7 102.7 103.1 103.4 103.7 104.3 104.8 105.0 105.5 80 113.2 112.9 112.9 112.9 113.4 113.3 113.2 113.4 114.1 114.3 114.7 90 124.3 123.8 123.8 124.1 125.0 124.9 124.8 124.9 125.0 125.0 125.0

100 125.0 125.0 125.0 125.0 125.0 125.0 125.0 125.0 125.0 125.0 125.0

Figure 35: H2 – Gas Turbine Speed versus Part Load.

Page 94: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

76

Table 31: H2 – Compressor Mass Flow Rate.

Compressor Mass Flow Rate (kg/s) – H2

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.041 0.038 0.036 0.034 0.032 0.030 0.028 0.026 0.025 0.023 0.021 20 0.041 0.039 0.036 0.034 0.032 0.030 0.028 0.026 0.025 0.023 0.022 30 0.041 0.039 0.036 0.034 0.032 0.030 0.028 0.027 0.027 0.026 0.025 40 0.042 0.040 0.038 0.037 0.036 0.035 0.033 0.032 0.031 0.030 0.029 50 0.052 0.050 0.047 0.045 0.043 0.042 0.040 0.038 0.037 0.035 0.034 60 0.063 0.060 0.057 0.055 0.052 0.050 0.047 0.045 0.043 0.041 0.039 70 0.076 0.072 0.068 0.065 0.062 0.059 0.056 0.053 0.051 0.048 0.045 80 0.091 0.086 0.081 0.077 0.073 0.068 0.064 0.061 0.058 0.055 0.052 90 0.106 0.100 0.094 0.089 0.084 0.079 0.075 0.070 0.066 0.062 0.058

100 0.107 0.101 0.095 0.090 0.084 0.079 0.075 0.070 0.066 0.062 0.058

Figure 36: H2 – Compressor Mass Flow Rate versus Part Load.

Page 95: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

77

Table 32: H2 – Solid Oxide Fuel Cell Voltage.

SOFC Voltage (V) – H2

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.958 0.958 0.958 0.958 0.958 0.957 0.957 0.956 0.956 0.956 0.955 20 0.876 0.879 0.881 0.883 0.884 0.886 0.887 0.888 0.889 0.891 0.894 30 0.808 0.812 0.817 0.820 0.823 0.827 0.830 0.835 0.840 0.846 0.851 40 0.748 0.755 0.762 0.768 0.775 0.781 0.788 0.794 0.801 0.808 0.814 50 0.702 0.711 0.719 0.727 0.735 0.743 0.751 0.758 0.766 0.774 0.782 60 0.661 0.670 0.680 0.689 0.698 0.707 0.717 0.725 0.734 0.743 0.752 70 0.622 0.632 0.643 0.653 0.663 0.674 0.684 0.694 0.703 0.714 0.724 80 0.584 0.596 0.608 0.619 0.630 0.642 0.653 0.663 0.674 0.687 0.698 90 0.549 0.562 0.575 0.587 0.599 0.612 0.624 0.635 0.647 0.660 0.672

100 0.516 0.529 0.542 0.554 0.567 0.579 0.592 0.604 0.616 0.629 0.642

Figure 37: H2 – Solid Oxide Fuel Cell Voltage versus Part Load.

Page 96: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

78

Table 33: H2 – Solid Oxide Fuel Cell Power.

SOFC Power (kW) – H2

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 3.97 3.79 3.62 3.47 3.31 3.15 3.00 2.86 2.72 2.56 2.42 20 7.26 6.96 6.66 6.39 6.11 5.83 5.56 5.31 5.06 4.78 4.54 30 10.03 9.65 9.26 8.90 8.53 8.17 7.80 7.48 7.16 6.80 6.48 40 12.39 11.95 11.52 11.12 10.71 10.29 9.87 9.49 9.11 8.67 8.27 50 14.54 14.08 13.60 13.15 12.70 12.23 11.76 11.33 10.89 10.38 9.93 60 16.41 15.93 15.42 14.96 14.48 13.98 13.47 13.00 12.52 11.96 11.45 70 18.01 17.53 17.02 16.54 16.04 15.53 15.00 14.51 14.00 13.41 12.86 80 19.35 18.89 18.39 17.93 17.43 16.91 16.37 15.86 15.34 14.73 14.16 90 20.45 20.02 19.56 19.11 18.64 18.13 17.59 17.08 16.55 15.93 15.34

100 21.34 20.94 20.49 20.05 19.58 19.08 18.55 18.04 17.51 16.88 16.29

Figure 38: H2 – Solid Oxide Fuel Cell Power versus Part Load.

Page 97: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

79

Table 34: H2 – Gas Turbine Power.

GT Power (kW) – H2

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 1.58 1.56 1.54 1.51 1.47 1.44 1.40 1.37 1.33 1.28 1.24 20 1.66 1.64 1.61 1.58 1.54 1.51 1.47 1.42 1.38 1.33 1.33 30 1.75 1.73 1.69 1.66 1.61 1.57 1.53 1.54 1.57 1.59 1.62 40 1.88 1.87 1.87 1.88 1.90 1.90 1.91 1.93 1.95 1.95 1.96 50 2.40 2.41 2.39 2.39 2.39 2.39 2.38 2.39 2.40 2.38 2.38 60 2.99 2.98 2.96 2.96 2.95 2.93 2.91 2.91 2.89 2.85 2.82 70 3.57 3.57 3.55 3.53 3.50 3.48 3.45 3.44 3.41 3.34 3.29 80 4.06 4.08 4.07 4.07 4.05 4.02 3.97 3.93 3.92 3.85 3.79 90 4.37 4.44 4.46 4.49 4.49 4.47 4.44 4.40 4.36 4.28 4.19

100 4.63 4.68 4.69 4.70 4.68 4.65 4.61 4.56 4.49 4.40 4.31

Figure 39: H2 – Gas Turbine Power versus Part Load.

Page 98: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

80

Table 35: CH4 (POX) – System Load.

Part Load (A) Calculations – CH4 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 21.3 20.4 19.4 18.6 17.7 16.9 16.1 15.3 14.5 13.7 12.9 20 42.6 40.8 38.8 37.2 35.4 33.8 32.2 30.6 29.0 27.4 25.8 30 63.9 61.2 58.2 55.8 53.1 50.7 48.3 45.9 43.5 41.1 38.7 40 85.2 81.6 77.6 74.4 70.8 67.6 64.4 61.2 58.0 54.8 51.6 50 106.5 102.0 97.0 93.0 88.5 84.5 80.5 76.5 72.5 68.5 64.5 60 127.8 122.4 116.4 111.6 106.2 101.4 96.6 91.8 87.0 82.2 77.4 70 149.1 142.8 135.8 130.2 123.9 118.3 112.7 107.1 101.5 95.9 90.3 80 170.4 163.2 155.2 148.8 141.6 135.2 128.8 122.4 116.0 109.6 103.2 90 191.7 183.6 174.6 167.4 159.3 152.1 144.9 137.7 130.5 123.3 116.1

100 213.0 204.0 194.0 186.0 177.0 169.0 161.0 153.0 145.0 137.0 129.0

Figure 40: CH4 (POX) – System Load versus Part Load.

Page 99: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

81

Table 36: CH4 (POX) – Fuel Utilization.

Fuel Utilization ( – CH4 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.191 0.192 0.192 0.193 0.194 0.195 0.196 0.197 0.197 0.198 0.197 20 0.322 0.323 0.324 0.325 0.327 0.328 0.330 0.331 0.331 0.332 0.331 30 0.418 0.419 0.419 0.421 0.423 0.425 0.426 0.427 0.421 0.412 0.402 40 0.490 0.491 0.492 0.490 0.485 0.480 0.474 0.468 0.457 0.451 0.445 50 0.514 0.511 0.508 0.505 0.502 0.497 0.494 0.489 0.484 0.478 0.471 60 0.518 0.517 0.515 0.513 0.511 0.508 0.505 0.500 0.497 0.495 0.488 70 0.519 0.519 0.519 0.518 0.517 0.516 0.513 0.510 0.508 0.505 0.501 80 0.520 0.520 0.520 0.520 0.520 0.520 0.519 0.516 0.515 0.512 0.509 90 0.522 0.522 0.522 0.522 0.522 0.522 0.522 0.522 0.520 0.518 0.516

100 0.529 0.529 0.529 0.529 0.530 0.530 0.530 0.530 0.529 0.529 0.528

Figure 41: CH4 (POX) – Fuel Utilization versus Part Load.

Page 100: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

82

Table 37: CH4 (POX) – Turbine Inlet Temperature.

Turbine Inlet Temperature (K) – CH4 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 1085 1086 1087 1088 1088 1089 1090 1090 1091 1092 1092 20 1087 1087 1088 1089 1090 1090 1091 1091 1092 1092 1093 30 1089 1090 1090 1091 1091 1092 1092 1093 1093 1093 1093 40 1092 1092 1093 1093 1093 1093 1093 1093 1093 1093 1093 50 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 60 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 70 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 80 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 90 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093

100 1094 1094 1094 1094 1094 1094 1094 1094 1094 1094 1094

Figure 42: CH4 (POX) – Turbine Inlet Temperature versus Part Load.

Page 101: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

83

Table 38: CH4 (POX) – Gas Turbine Shaft Speed.

Shaft Speed (kRPM) – CH4 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 20 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.1 30 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 57.3 60.7 64.6 40 55.0 55.0 55.0 56.3 58.5 60.8 63.7 66.7 70.9 72.8 74.7 50 66.6 68.4 69.9 72.2 73.9 75.7 77.1 78.9 80.6 82.4 84.1 60 82.7 83.3 84.0 85.2 86.3 87.5 88.7 90.2 91.1 91.7 92.9 70 96.2 96.2 96.1 96.9 97.1 97.8 98.7 99.3 99.5 100.0 100.4 80 106.8 106.6 106.3 106.4 106.4 106.5 106.9 107.4 107.5 108.0 108.3 90 116.7 116.5 116.1 116.2 116.1 116.1 116.1 116.1 116.3 116.4 116.6

100 125.0 125.0 125.0 125.0 125.0 125.0 125.0 125.0 125.0 125.0 125.0

Figure 43: CH4 (POX) – Gas Turbine Shaft Speed versus Part Load.

Page 102: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

84

Table 39: CH4 (POX) – Compressor Mass Flow Rate.

Compressor Mass Flow Rate (kg/s) – CH4 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.042 0.040 0.037 0.035 0.033 0.031 0.029 0.027 0.025 0.024 0.022 20 0.043 0.040 0.038 0.036 0.033 0.031 0.029 0.027 0.026 0.024 0.022 30 0.043 0.040 0.038 0.036 0.034 0.031 0.030 0.028 0.027 0.026 0.025 40 0.043 0.041 0.038 0.037 0.035 0.034 0.033 0.032 0.031 0.030 0.029 50 0.050 0.048 0.046 0.044 0.042 0.041 0.039 0.038 0.036 0.035 0.034 60 0.061 0.058 0.055 0.053 0.050 0.048 0.046 0.044 0.042 0.040 0.038 70 0.073 0.069 0.065 0.062 0.059 0.056 0.054 0.051 0.049 0.046 0.044 80 0.086 0.082 0.077 0.073 0.069 0.065 0.062 0.059 0.056 0.053 0.050 90 0.100 0.095 0.089 0.084 0.080 0.075 0.071 0.067 0.063 0.060 0.056

100 0.112 0.106 0.100 0.094 0.089 0.084 0.079 0.074 0.070 0.065 0.061

Figure 44: CH4 (POX) – Compressor Mass Flow Rate versus Part Load.

Page 103: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

85

Table 40: CH4 (POX) – Solid Oxide Fuel Cell Voltage.

SOFC Voltage (V) – CH4 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.923 0.923 0.923 0.922 0.922 0.922 0.921 0.921 0.920 0.920 0.919 20 0.855 0.857 0.859 0.861 0.862 0.864 0.865 0.866 0.867 0.869 0.870 30 0.794 0.798 0.802 0.805 0.809 0.812 0.814 0.817 0.822 0.827 0.832 40 0.738 0.744 0.750 0.755 0.761 0.767 0.773 0.779 0.786 0.793 0.799 50 0.693 0.701 0.709 0.716 0.724 0.731 0.738 0.746 0.753 0.761 0.769 60 0.653 0.662 0.672 0.680 0.689 0.697 0.706 0.715 0.723 0.731 0.741 70 0.616 0.626 0.637 0.646 0.656 0.665 0.675 0.685 0.694 0.704 0.714 80 0.581 0.592 0.604 0.614 0.625 0.635 0.646 0.656 0.667 0.678 0.689 90 0.547 0.559 0.572 0.583 0.596 0.607 0.618 0.629 0.641 0.653 0.666

100 0.516 0.528 0.542 0.554 0.567 0.579 0.591 0.603 0.616 0.629 0.642

Figure 45: CH4 (POX) – Solid Oxide Fuel Cell Voltage versus Part Load.

Page 104: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

86

Table 41: CH4 (POX) – Solid Oxide Fuel Cell Power.

SOFC Power (kW) – CH4 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 3.54 3.39 3.22 3.09 2.94 2.80 2.67 2.54 2.40 2.27 2.14 20 6.56 6.29 6.00 5.76 5.50 5.25 5.01 4.77 4.53 4.28 4.04 30 9.14 8.79 8.41 8.09 7.73 7.41 7.08 6.75 6.43 6.12 5.80 40 11.32 10.92 10.47 10.11 9.70 9.33 8.96 8.58 8.21 7.82 7.42 50 13.28 12.86 12.38 11.99 11.53 11.12 10.70 10.27 9.83 9.38 8.92 60 15.03 14.59 14.08 13.66 13.17 12.73 12.27 11.81 11.33 10.82 10.32 70 16.54 16.09 15.57 15.14 14.63 14.17 13.69 13.20 12.69 12.16 11.61 80 17.82 17.38 16.87 16.44 15.93 15.46 14.97 14.46 13.93 13.38 12.81 90 18.89 18.48 17.99 17.57 17.08 16.61 16.12 15.60 15.06 14.50 13.91

100 19.77 19.39 18.93 18.54 18.06 17.60 17.12 16.61 16.07 15.50 14.90

Figure 46: CH4 (POX) – Solid Oxide Fuel Cell Power versus Part Load.

Page 105: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

87

Table 42: CH4 (POX) – Gas Turbine Power.

GT Power (kW) – CH4 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 1.70 1.67 1.64 1.61 1.57 1.53 1.49 1.45 1.41 1.36 1.31 20 1.80 1.77 1.74 1.70 1.66 1.62 1.57 1.52 1.48 1.42 1.38 30 1.91 1.88 1.83 1.80 1.74 1.70 1.65 1.60 1.60 1.62 1.65 40 2.02 1.98 1.93 1.92 1.92 1.93 1.94 1.96 2.00 1.99 1.99 50 2.44 2.44 2.43 2.43 2.42 2.43 2.42 2.42 2.41 2.40 2.39 60 3.05 3.04 3.01 3.00 2.98 2.97 2.95 2.95 2.91 2.86 2.84 70 3.69 3.67 3.61 3.60 3.56 3.52 3.50 3.47 3.42 3.36 3.31 80 4.28 4.27 4.22 4.20 4.14 4.10 4.06 4.02 3.94 3.88 3.81 90 4.77 4.78 4.75 4.75 4.70 4.66 4.61 4.54 4.47 4.39 4.30

100 5.09 5.13 5.12 5.14 5.10 5.07 5.02 4.96 4.89 4.78 4.67

Figure 47: CH4 (POX) – Gas Turbine Power versus Part Load.

Page 106: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

88

Table 43: C3H8 (POX) – System Load.

Part Load (A) Calculations – C3H8 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 21.0 20.2 19.3 18.4 17.5 16.7 15.9 15.1 14.4 13.6 12.8 20 42.0 40.4 38.6 36.8 35.0 33.4 31.8 30.2 28.8 27.2 25.6 30 63.0 60.6 57.9 55.2 52.5 50.1 47.7 45.3 43.2 40.8 38.4 40 84.0 80.8 77.2 73.6 70.0 66.8 63.6 60.4 57.6 54.4 51.2 50 105.0 101.0 96.5 92.0 87.5 83.5 79.5 75.5 72.0 68.0 64.0 60 126.0 121.2 115.8 110.4 105.0 100.2 95.4 90.6 86.4 81.6 76.8 70 147.0 141.4 135.1 128.8 122.5 116.9 111.3 105.7 100.8 95.2 89.6 80 168.0 161.6 154.4 147.2 140.0 133.6 127.2 120.8 115.2 108.8 102.4 90 189.0 181.8 173.7 165.6 157.5 150.3 143.1 135.9 129.6 122.4 115.2

100 210.0 202.0 193.0 184.0 175.0 167.0 159.0 151.0 144.0 136.0 128.0

Figure 48: C3H8 (POX) – System Load versus Part Load.

Page 107: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

89

Table 44: C3H8 (POX) – Fuel Utilization.

Fuel Utilization ( – C3H8 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.190 0.192 0.193 0.193 0.194 0.195 0.196 0.197 0.198 0.198 0.198 20 0.321 0.323 0.325 0.325 0.327 0.328 0.329 0.330 0.332 0.332 0.332 30 0.417 0.419 0.421 0.422 0.423 0.425 0.426 0.427 0.426 0.415 0.405 40 0.490 0.492 0.494 0.494 0.490 0.482 0.480 0.470 0.465 0.456 0.451 50 0.514 0.515 0.513 0.509 0.505 0.502 0.498 0.493 0.487 0.482 0.475 60 0.522 0.522 0.519 0.517 0.516 0.513 0.510 0.504 0.502 0.499 0.493 70 0.526 0.524 0.524 0.522 0.521 0.519 0.517 0.515 0.513 0.509 0.505 80 0.527 0.527 0.525 0.525 0.524 0.524 0.522 0.520 0.518 0.516 0.514 90 0.527 0.527 0.527 0.527 0.527 0.527 0.526 0.525 0.524 0.523 0.522

100 0.530 0.532 0.532 0.532 0.532 0.532 0.532 0.532 0.532 0.532 0.531

Figure 49: C3H8 (POX) – Fuel Utilization versus Part Load.

Page 108: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

90

Table 45: C3H8 (POX) – Turbine Inlet Temperature.

Turbine Inlet Temperature (K) – C3H8 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 1085 1086 1087 1088 1088 1089 1090 1090 1091 1092 1092 20 1087 1087 1088 1089 1089 1090 1091 1091 1092 1093 1093 30 1089 1090 1090 1091 1091 1092 1092 1093 1093 1093 1093 40 1092 1092 1093 1093 1093 1093 1093 1093 1093 1093 1093 50 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 60 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 70 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 80 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 90 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093

100 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093

Figure 50: C3H8 (POX) – Turbine Inlet Temperature versus Part Load.

Page 109: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

91

Table 46: C3H8 (POX) – Gas Turbine Shaft Speed.

Shaft Speed (kRPM) – C3H8 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 20 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 30 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 56.3 60.1 63.8 40 55.0 55.0 55.0 55.3 57.2 60.1 61.9 65.8 68.9 71.9 73.4 50 66.1 67.2 68.9 70.9 73.2 74.5 76.0 77.7 80.1 81.6 83.4 60 81.3 82.1 83.5 84.2 84.9 86.2 87.4 89.0 90.3 91.0 92.2 70 94.1 95.2 95.5 95.9 96.3 96.9 97.7 98.1 98.8 99.4 99.8 80 105.1 105.3 105.7 105.4 105.6 105.6 105.9 106.3 107.1 107.3 107.4 90 115.1 115.3 115.3 115.0 114.9 114.8 114.9 115.0 115.6 115.5 115.1

100 125.0 125.0 125.0 125.0 125.0 125.0 125.0 125.0 125.0 125.0 125.0

Figure 51: C3H8 (POX) – Gas Turbine Shaft Speed versus Part Load.

Page 110: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

92

Table 47: C3H8 (POX) – Compressor Mass Flow Rate.

Compressor Mass Flow Rate (kg/s) – C3H8 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.043 0.040 0.038 0.036 0.033 0.031 0.029 0.027 0.026 0.024 0.022 20 0.043 0.041 0.038 0.036 0.034 0.032 0.030 0.028 0.026 0.024 0.023 30 0.043 0.041 0.039 0.036 0.034 0.032 0.030 0.028 0.027 0.026 0.026 40 0.044 0.041 0.039 0.037 0.035 0.034 0.033 0.032 0.031 0.030 0.029 50 0.051 0.048 0.046 0.044 0.043 0.041 0.039 0.038 0.037 0.035 0.034 60 0.061 0.058 0.056 0.053 0.050 0.048 0.046 0.044 0.042 0.040 0.039 70 0.072 0.069 0.066 0.062 0.059 0.056 0.054 0.051 0.049 0.046 0.044 80 0.085 0.081 0.077 0.073 0.069 0.065 0.062 0.059 0.056 0.053 0.050 90 0.099 0.094 0.089 0.084 0.079 0.075 0.071 0.067 0.064 0.060 0.056

100 0.113 0.107 0.101 0.095 0.090 0.085 0.080 0.075 0.071 0.066 0.062

Figure 52: C3H8 (POX) – Compressor Mass Flow Rate versus Part Load.

Page 111: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

93

Table 48: C3H8 (POX) – Solid Oxide Fuel Cell Voltage.

SOFC Voltage (V) – C3H8 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.915 0.915 0.915 0.915 0.915 0.914 0.914 0.913 0.912 0.912 0.912 20 0.850 0.851 0.853 0.855 0.857 0.858 0.859 0.860 0.861 0.862 0.864 30 0.790 0.793 0.797 0.801 0.804 0.807 0.810 0.813 0.816 0.821 0.826 40 0.735 0.740 0.745 0.750 0.756 0.763 0.768 0.775 0.780 0.787 0.793 50 0.690 0.696 0.704 0.712 0.720 0.727 0.734 0.741 0.748 0.755 0.763 60 0.650 0.658 0.667 0.676 0.685 0.693 0.702 0.711 0.718 0.726 0.736 70 0.613 0.622 0.632 0.642 0.653 0.662 0.671 0.681 0.689 0.699 0.709 80 0.578 0.588 0.599 0.610 0.622 0.632 0.642 0.653 0.663 0.674 0.685 90 0.545 0.556 0.568 0.580 0.592 0.603 0.615 0.626 0.637 0.649 0.661

100 0.514 0.525 0.538 0.551 0.564 0.576 0.588 0.601 0.612 0.624 0.638

Figure 53: C3H8 (POX) – Solid Oxide Fuel Cell Voltage versus Part Load.

Page 112: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

94

Table 49: C3H8 (POX) – Solid Oxide Fuel Cell Power.

SOFC Power (kW) – C3H8 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 3.46 3.33 3.18 3.03 2.88 2.75 2.61 2.48 2.37 2.23 2.10 20 6.43 6.19 5.93 5.66 5.40 5.16 4.92 4.68 4.46 4.22 3.98 30 8.96 8.65 8.30 7.95 7.60 7.28 6.95 6.63 6.34 6.03 5.71 40 11.12 10.76 10.35 9.94 9.53 9.17 8.79 8.42 8.09 7.70 7.30 50 13.05 12.66 12.22 11.79 11.34 10.92 10.50 10.07 9.69 9.25 8.79 60 14.75 14.35 13.90 13.43 12.95 12.50 12.05 11.59 11.16 10.67 10.17 70 16.22 15.83 15.37 14.89 14.39 13.93 13.45 12.95 12.51 11.98 11.44 80 17.48 17.09 16.65 16.17 15.67 15.19 14.71 14.20 13.74 13.19 12.62 90 18.55 18.19 17.75 17.29 16.79 16.32 15.84 15.32 14.85 14.29 13.70

100 19.43 19.08 18.68 18.24 17.77 17.32 16.84 16.33 15.85 15.29 14.69

Figure 54: C3H8 (POX) – Solid Oxide Fuel Cell Power versus Part Load.

Page 113: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

95

Table 50: C3H8 (POX) – Gas Turbine Power.

GT Power (kW) – C3H8 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 1.73 1.71 1.68 1.65 1.60 1.56 1.52 1.48 1.43 1.38 1.34 20 1.84 1.82 1.78 1.74 1.69 1.65 1.61 1.56 1.51 1.46 1.40 30 1.96 1.93 1.88 1.84 1.79 1.74 1.69 1.64 1.61 1.65 1.67 40 2.08 2.04 1.99 1.95 1.94 1.97 1.95 1.99 2.00 2.02 2.00 50 2.50 2.49 2.48 2.47 2.46 2.45 2.45 2.44 2.46 2.44 2.43 60 3.10 3.09 3.08 3.06 3.01 3.00 2.98 2.98 2.96 2.91 2.88 70 3.73 3.74 3.70 3.67 3.62 3.59 3.56 3.51 3.48 3.43 3.37 80 4.34 4.35 4.33 4.28 4.23 4.18 4.13 4.08 4.04 3.97 3.87 90 4.89 4.91 4.89 4.85 4.79 4.75 4.70 4.63 4.58 4.48 4.36

100 5.25 5.30 5.31 5.29 5.25 5.22 5.17 5.09 5.03 4.92 4.80

Figure 55: C3H8 (POX) – Gas Turbine Power versus Part Load.

Page 114: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

96

Table 51: JP8 (POX) – System Load.

Part Load (A) Calculations – JP8 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 21.2 20.2 19.3 18.5 17.6 16.8 16.0 15.2 14.4 13.6 12.9 20 42.4 40.4 38.6 37.0 35.2 33.6 32.0 30.4 28.8 27.2 25.8 30 63.6 60.6 57.9 55.5 52.8 50.4 48.0 45.6 43.2 40.8 38.7 40 84.8 80.8 77.2 74.0 70.4 67.2 64.0 60.8 57.6 54.4 51.6 50 106.0 101.0 96.5 92.5 88.0 84.0 80.0 76.0 72.0 68.0 64.5 60 127.2 121.2 115.8 111.0 105.6 100.8 96.0 91.2 86.4 81.6 77.4 70 148.4 141.4 135.1 129.5 123.2 117.6 112.0 106.4 100.8 95.2 90.3 80 169.6 161.6 154.4 148.0 140.8 134.4 128.0 121.6 115.2 108.8 103.2 90 190.8 181.8 173.7 166.5 158.4 151.2 144.0 136.8 129.6 122.4 116.1

100 212.0 202.0 193.0 185.0 176.0 168.0 160.0 152.0 144.0 136.0 129.0

Figure 56: JP8 (POX) – System Load versus Part Load.

Page 115: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

97

Table 52: JP8 (POX) - Fuel Utilization.

Fuel Utilization ( – JP8 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.193 0.193 0.194 0.195 0.196 0.197 0.198 0.198 0.199 0.199 0.2 20 0.325 0.325 0.326 0.328 0.33 0.331 0.332 0.333 0.333 0.334 0.335 30 0.421 0.421 0.423 0.425 0.427 0.428 0.429 0.431 0.428 0.415 0.41 40 0.495 0.494 0.496 0.496 0.492 0.485 0.483 0.475 0.468 0.461 0.452 50 0.521 0.516 0.516 0.514 0.509 0.505 0.482 0.5 0.492 0.486 0.48 60 0.524 0.523 0.523 0.522 0.52 0.514 0.499 0.507 0.507 0.502 0.494 70 0.526 0.525 0.525 0.525 0.525 0.524 0.522 0.52 0.516 0.513 0.511 80 0.529 0.527 0.527 0.527 0.527 0.527 0.527 0.526 0.524 0.52 0.517 90 0.53 0.53 0.53 0.53 0.53 0.529 0.529 0.528 0.528 0.528 0.526

100 0.536 0.535 0.535 0.536 0.536 0.536 0.536 0.536 0.536 0.536 0.536

Figure 57: JP8 (POX) – Fuel Utilization versus Part Load.

Page 116: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

98

Table 53: JP8 (POX) – Turbine Inlet Temperature.

Turbine Inlet Temperature (K) – JP8 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 1085 1086 1087 1087 1088 1089 1090 1090 1091 1092 1092 20 1087 1087 1088 1089 1089 1090 1091 1091 1092 1092 1093 30 1089 1089 1090 1091 1091 1092 1092 1093 1093 1093 1093 40 1092 1092 1093 1093 1093 1093 1093 1093 1093 1093 1093 50 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 60 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 70 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 80 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 90 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093

100 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093 1093

Figure 58: JP8 (POX) – Turbine Inlet Temperature versus Part Load.

Page 117: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

99

Table 54: JP8 (POX) – Gas Turbine Shaft Speed.

Shaft Speed (kRPM) – JP8 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 20 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 30 55.0 55.0 55.0 55.0 55.0 55.0 55.0 55.0 56.1 60.4 63.4 40 55.0 55.0 55.0 55.6 57.5 60.2 62.1 65.4 68.5 71.2 74.0 50 65.6 67.3 68.5 70.5 73.1 74.6 80.2 77.1 79.3 81.1 83.3 60 82.1 82.3 82.9 83.9 84.9 86.8 90.5 89.3 89.6 90.8 92.8 70 95.4 95.3 95.6 96.1 96.4 96.7 97.6 98.0 98.6 99.0 99.6 80 105.9 105.7 105.7 105.8 105.8 105.8 105.8 106.0 106.2 106.9 107.7 90 115.8 115.1 115.1 115.2 115.1 115.3 115.3 115.4 115.1 114.8 115.4

100 125.0 125.0 125.0 125.0 125.0 125.0 125.0 125.0 125.0 125.0 125.0

Figure 59: JP8 (POX) – Gas Turbine Shaft Speed versus Part Load.

Page 118: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

100

Table 55: JP8 (POX) – Compressor Mass Flow Rate.

Compressor Mass Flow Rate (kg/s) – JP8 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.043 0.041 0.038 0.036 0.034 0.032 0.030 0.028 0.026 0.024 0.023 20 0.043 0.041 0.039 0.036 0.034 0.032 0.030 0.028 0.026 0.025 0.023 30 0.044 0.041 0.039 0.037 0.034 0.032 0.030 0.028 0.027 0.027 0.026 40 0.044 0.042 0.039 0.037 0.036 0.035 0.033 0.033 0.031 0.030 0.030 50 0.051 0.049 0.047 0.045 0.043 0.041 0.042 0.038 0.037 0.035 0.034 60 0.062 0.059 0.056 0.053 0.051 0.049 0.049 0.045 0.043 0.041 0.039 70 0.074 0.070 0.067 0.063 0.060 0.057 0.054 0.052 0.049 0.047 0.044 80 0.087 0.082 0.078 0.074 0.070 0.066 0.063 0.059 0.056 0.053 0.051 90 0.101 0.095 0.090 0.085 0.080 0.076 0.072 0.068 0.064 0.060 0.057

100 0.114 0.108 0.102 0.096 0.091 0.086 0.081 0.076 0.071 0.067 0.063

Figure 60: JP8 (POX) – Compressor Mass Flow Rate versus Part Load.

Page 119: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

101

Table 56: JP8 (POX) – Solid Oxide Fuel Cell Voltage.

SOFC Voltage (V) – JP8 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.911 0.911 0.911 0.911 0.911 0.910 0.910 0.909 0.909 0.908 0.908 20 0.846 0.848 0.850 0.851 0.853 0.854 0.856 0.857 0.858 0.859 0.860 30 0.786 0.791 0.794 0.797 0.800 0.803 0.806 0.809 0.813 0.818 0.822 40 0.730 0.737 0.742 0.747 0.753 0.759 0.764 0.771 0.777 0.784 0.789 50 0.685 0.694 0.701 0.708 0.716 0.723 0.734 0.737 0.745 0.753 0.759 60 0.646 0.656 0.664 0.672 0.681 0.690 0.701 0.707 0.715 0.724 0.732 70 0.609 0.620 0.630 0.638 0.648 0.658 0.667 0.677 0.687 0.696 0.705 80 0.573 0.586 0.597 0.606 0.618 0.628 0.638 0.648 0.659 0.671 0.681 90 0.540 0.553 0.565 0.576 0.588 0.599 0.611 0.622 0.634 0.645 0.656

100 0.508 0.522 0.535 0.546 0.560 0.572 0.584 0.596 0.609 0.622 0.633

Figure 61: JP8 (POX) – Solid Oxide Fuel Cell Voltage versus Part Load.

Page 120: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

102

Table 57: JP8 (POX) – Solid Oxide Fuel Cell Power.

SOFC Power (kW) – JP8 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 3.48 3.31 3.17 3.03 2.88 2.75 2.62 2.49 2.36 2.22 2.11 20 6.45 6.17 5.91 5.67 5.40 5.17 4.93 4.69 4.45 4.21 3.99 30 9.00 8.62 8.28 7.96 7.61 7.29 6.97 6.64 6.32 6.01 5.73 40 11.15 10.72 10.31 9.95 9.54 9.18 8.81 8.44 8.06 7.67 7.33 50 13.07 12.62 12.18 11.78 11.34 10.93 10.57 10.08 9.65 9.21 8.82 60 14.79 14.30 13.84 13.42 12.94 12.52 12.11 11.60 11.12 10.63 10.20 70 16.26 15.78 15.31 14.88 14.38 13.92 13.45 12.96 12.46 11.93 11.46 80 17.50 17.04 16.58 16.16 15.65 15.19 14.70 14.19 13.67 13.13 12.64 90 18.54 18.10 17.67 17.26 16.77 16.32 15.83 15.32 14.79 14.22 13.71

100 19.39 18.98 18.59 18.20 17.73 17.29 16.82 16.31 15.78 15.22 14.69

Figure 62: JP8 (POX) – Solid Oxide Fuel Cell Power versus Part Load.

Page 121: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

103

Table 58: JP8 (POX) – Gas Turbine Power.

GT Power (kW) – JP8 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 1.77 1.74 1.71 1.68 1.63 1.59 1.55 1.51 1.46 1.41 1.36 20 1.89 1.86 1.82 1.78 1.73 1.69 1.64 1.59 1.54 1.48 1.43 30 2.01 1.97 1.93 1.89 1.83 1.78 1.73 1.68 1.65 1.69 1.70 40 2.14 2.10 2.05 2.01 2.00 2.02 2.00 2.03 2.04 2.04 2.07 50 2.57 2.57 2.53 2.53 2.53 2.53 2.69 2.48 2.49 2.48 2.48 60 3.23 3.19 3.15 3.13 3.10 3.11 3.22 3.07 3.00 2.97 2.99 70 3.91 3.86 3.82 3.79 3.73 3.69 3.65 3.60 3.56 3.50 3.44 80 4.53 4.50 4.47 4.44 4.37 4.31 4.25 4.18 4.11 4.05 4.00 90 5.09 5.06 5.04 5.02 4.96 4.92 4.85 4.78 4.68 4.57 4.50

100 5.46 5.47 5.48 5.47 5.43 5.39 5.33 5.25 5.16 5.04 4.94

Figure 63: JP8 (POX) – Gas Turbine Power versus Part Load.

Page 122: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

104

Table 59: CH4 (IR) – Part Load System Efficiency.

Part Load System Efficiency – CH4 (IR)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.270 0.271 0.275 0.278 0.281 0.285 0.288 0.291 0.294 0.296 0.299 20 0.362 0.364 0.368 0.371 0.376 0.379 0.382 0.386 0.389 0.392 0.395 30 0.410 0.413 0.418 0.422 0.426 0.431 0.434 0.439 0.442 0.443 0.441 40 0.432 0.437 0.442 0.447 0.452 0.457 0.458 0.459 0.460 0.460 0.461 50 0.430 0.436 0.441 0.445 0.450 0.453 0.457 0.460 0.463 0.466 0.468 60 0.413 0.421 0.428 0.433 0.439 0.445 0.449 0.455 0.460 0.464 0.469 70 0.395 0.404 0.412 0.419 0.427 0.433 0.440 0.446 0.453 0.459 0.464 80 0.377 0.387 0.396 0.404 0.413 0.421 0.429 0.436 0.444 0.451 0.459 90 0.358 0.369 0.379 0.388 0.398 0.407 0.416 0.425 0.434 0.443 0.451

100 0.339 0.351 0.362 0.372 0.383 0.393 0.403 0.413 0.423 0.433 0.443

Table 60: JP8 (SR) – Part Load System Efficency.

Part Load System Efficiency – JP8 (SR)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.263 0.262 0.265 0.270 0.273 0.276 0.279 0.283 0.285 0.287 0.290 20 0.349 0.352 0.355 0.359 0.364 0.367 0.371 0.374 0.377 0.379 0.383 30 0.397 0.400 0.404 0.409 0.414 0.417 0.421 0.426 0.429 0.426 0.425 40 0.419 0.424 0.429 0.434 0.438 0.440 0.442 0.442 0.442 0.445 0.444 50 0.417 0.421 0.425 0.429 0.433 0.437 0.441 0.444 0.447 0.450 0.453 60 0.402 0.407 0.412 0.418 0.424 0.429 0.435 0.439 0.445 0.450 0.454 70 0.385 0.391 0.397 0.404 0.412 0.419 0.426 0.433 0.439 0.444 0.451 80 0.367 0.375 0.382 0.390 0.399 0.407 0.415 0.423 0.431 0.439 0.446 90 0.349 0.358 0.367 0.376 0.386 0.395 0.403 0.412 0.422 0.429 0.438

100 0.331 0.342 0.352 0.362 0.373 0.383 0.393 0.403 0.413 0.422 0.432

Page 123: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

105

Table 61: H2 – Part Load System Efficiecy.

Part Load System Efficiency – H2

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.209 0.212 0.214 0.217 0.220 0.223 0.225 0.228 0.230 0.232 0.235 20 0.282 0.284 0.288 0.291 0.295 0.297 0.300 0.303 0.306 0.308 0.308 30 0.320 0.324 0.328 0.331 0.336 0.339 0.342 0.342 0.341 0.340 0.340 40 0.337 0.340 0.343 0.344 0.346 0.348 0.350 0.351 0.352 0.353 0.354 50 0.327 0.330 0.335 0.338 0.342 0.345 0.348 0.351 0.353 0.356 0.358 60 0.313 0.318 0.324 0.329 0.333 0.338 0.342 0.346 0.350 0.355 0.359 70 0.298 0.305 0.311 0.317 0.324 0.329 0.335 0.340 0.345 0.350 0.356 80 0.284 0.291 0.298 0.305 0.312 0.319 0.326 0.332 0.338 0.344 0.350 90 0.269 0.277 0.285 0.293 0.300 0.308 0.316 0.323 0.330 0.338 0.345

100 0.265 0.273 0.281 0.289 0.297 0.305 0.313 0.321 0.329 0.337 0.345

Table 62: CH4 (POX) – Part Load System Efficiency.

Part Load System Efficiency – CH4 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.187 0.190 0.192 0.195 0.198 0.200 0.203 0.205 0.207 0.209 0.211 20 0.253 0.256 0.258 0.261 0.264 0.267 0.270 0.273 0.274 0.277 0.278 30 0.289 0.292 0.295 0.299 0.302 0.306 0.308 0.311 0.311 0.311 0.310 40 0.307 0.311 0.315 0.317 0.319 0.320 0.321 0.323 0.322 0.323 0.325 50 0.304 0.307 0.311 0.314 0.317 0.319 0.322 0.325 0.327 0.329 0.331 60 0.293 0.298 0.303 0.307 0.311 0.315 0.319 0.322 0.326 0.330 0.332 70 0.282 0.288 0.294 0.299 0.304 0.309 0.313 0.318 0.323 0.327 0.331 80 0.270 0.276 0.283 0.289 0.295 0.301 0.307 0.312 0.318 0.323 0.328 90 0.258 0.265 0.272 0.279 0.286 0.292 0.299 0.306 0.312 0.318 0.324

100 0.247 0.255 0.263 0.270 0.278 0.285 0.292 0.299 0.306 0.314 0.321

Page 124: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

106

Table 63: C3H8 (POX) – Part Load System Efficiency.

Part Load System Efficiency – C3H8 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.173 0.176 0.179 0.181 0.183 0.185 0.188 0.190 0.192 0.194 0.195 20 0.233 0.236 0.239 0.241 0.244 0.246 0.248 0.251 0.253 0.255 0.257 30 0.266 0.269 0.273 0.276 0.278 0.282 0.284 0.287 0.289 0.287 0.286 40 0.283 0.287 0.291 0.294 0.296 0.296 0.298 0.298 0.300 0.300 0.302 50 0.280 0.284 0.288 0.290 0.293 0.296 0.299 0.301 0.302 0.305 0.307 60 0.272 0.276 0.280 0.284 0.289 0.292 0.296 0.298 0.302 0.306 0.308 70 0.263 0.267 0.272 0.277 0.282 0.286 0.291 0.295 0.299 0.303 0.307 80 0.252 0.257 0.263 0.268 0.274 0.280 0.285 0.290 0.294 0.299 0.305 90 0.241 0.246 0.253 0.259 0.266 0.272 0.278 0.284 0.289 0.295 0.301

100 0.229 0.236 0.243 0.250 0.258 0.264 0.271 0.278 0.284 0.291 0.298

Table 64: JP8 (POX) – Part Load System Efficiency.

Part Load System Efficiency – JP8 (POX)

Load

(%)

Altitude (ft) 0E+0 2E+3 4E+3 6E+3 8E+3 10E+3 12E+3 14E+3 16E+3 18E+3 20E+3

10 0.170 0.172 0.175 0.177 0.179 0.182 0.184 0.185 0.188 0.189 0.192 20 0.228 0.230 0.233 0.235 0.238 0.241 0.243 0.245 0.247 0.249 0.251 30 0.260 0.262 0.266 0.269 0.272 0.275 0.277 0.280 0.281 0.279 0.280 40 0.276 0.279 0.283 0.286 0.288 0.288 0.291 0.291 0.292 0.293 0.294 50 0.274 0.276 0.280 0.283 0.286 0.288 0.285 0.295 0.296 0.298 0.300 60 0.265 0.269 0.274 0.278 0.282 0.284 0.284 0.291 0.295 0.298 0.300 70 0.255 0.260 0.265 0.270 0.275 0.280 0.284 0.288 0.292 0.296 0.301 80 0.245 0.250 0.256 0.261 0.267 0.273 0.278 0.283 0.288 0.293 0.297 90 0.234 0.241 0.247 0.253 0.259 0.265 0.271 0.277 0.283 0.289 0.294

100 0.224 0.231 0.238 0.244 0.251 0.258 0.264 0.271 0.278 0.285 0.291

Page 125: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

107

REFERENCES

Aguiar, P., C.S. Adjiman, and N.P. Brandon. "Anode-supported intermediate temperature

direct internal reforming solid oxide fuel cell. I: model-based steady-state

performance." Journal of Power Sources 238, 2004: 120-136.

Antloga, Mirko, Richard Goettler, Kurt Kneidel, and Liang Xue. "Single Cell Testing and

Performance Analysis of Planar Solid Oxide Fuel Cells." International

Conference of Advanced Ceramics and Composites, 2005: 75-82.

Capstone. "Technical Reference: Capstone Model C30 Performance." 410004 Rev. D.

Chatsworth, CA: Capstone, April 2006.

Caputo, James, Chieng-Chieh Chao, and Zubin Huang. "Oxygen Ion Diffusion in Yttria-

Stabilized Zirconia." ME346: Introduction to Molecular Simulations, 2007: 1-17.

Cengal, Yunus, and Micheal Boles. Thermodynamics An Engineering Approach 7th

Edition. New York, New York: McGraw Hill , 2011.

Chan, S., H. Ho, and Y. Tian. "Multi-Level Modeling of SOFC-Gas Turbine Hybrid

System." International Journal of Hydrogen Energy 28, 2003: 889-900.

Chinda, P.,Brault, P. "The hybrid solid oxide fuel cell (SOFC) and gas turbine (GT)

systems steady state modeling." International Journal of Hydrogen Energy,

37(11), 2012: 9237-9248. doi: 10.1016/j.ijhydene.2012.03.005.

Clark, S.H., A.L. Dicks, K. Pointon, T.A. Smith, and A. Swann. "Catalytic aspects of the

steam reforming of hydrocarbons in internal reforming fuel cells." Catalysis

Today, Volume 38, Number 4, 1997: 411-423.

Cussler, E.L. Diffusion: Mass Transfer in Fluid Systems. Cambridge : Cambridge

University Press, 1995.

Page 126: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

108

Dicks, A.L. "Advances in catalysts for internal reforming in high temperature fuel cells."

Journal of Power Sources, 1998: 111-122.

Freeh, Joshua, Joseph Pratt W., and Jacob Brouwer. "Development of a Solid-Oxide Fuel

Cell / Gas Turbine Hybrid System Model for Aerospace Applications."

NASA/TM-2004-213054, n.d.

Kilo, Martin, Christos Argirusis, Gunter Borchardt, and Robert A. Jackson. "Oxygen

diffusion in yttria stabilised zirconia-experimental results and molecular dynamics

calculations." The Owner Societies, 2003: 2219-2224.

Klein, Max, H. J. M. Hanley, Francis J. Smith, and Paul Holland. Tables of Collision

Integrals and Second Virial Coefficients for the (m,6,8) Intermolecular Potential

Function. Boulder: National Standar Reference Data System, 1974.

Koehler, T.M., D.B. Jarrell, and L.J. Bond. "High Temperature Ceramic Fuel Cell

Measurement and Diagnostics for Application to Solid Oxide Fuel Cell Systems."

Pacific Northwest National Laboratory, 2001.

Komatsu, Y., S. Kimijima, and J.S. Szmyd. "Performance analysis for the part-load

operation of a solid oxide fuel cell-micro gas turbine hybrid system." Energy, 35,

2010: 982-988.

Larminie, James, and Andrew Dicks. Fuel Cell Systems Explained. West Sussex,

England: Wiley, 2003.

O'Hare, Ryan, Suk-Won Cha, Whitney Colella, and Fritz Prinz. Fuel Cell Fundamentals

2nd Edition. Hoboken, New Jersey: Wiley, 2009.

Singhal, S.C. "Advances in solid oxide fuel cell technology." Solid State Ionics 135 ,

2000: 305-313.

Page 127: Analysis of a Fuel Cell Combustor in a Solid Oxide Fuel

109

Song, T.W., J.H. Sohn, T.S. Kim, S.T. Ro, and K. Suzuki. "Performance analysis of a

tubular solid oxide fuel cell/micro gas turbine hybrid system based on a quasi-two

dimensional model. ." Journal of Power Sources, 2005: 142:30-42.

USA, Jet Cat. Jet Cat USA. March 23, 2014. www.jetcatusa.com (accessed March 23,

2014).

Yang, Shuangqiao, Tao Chen, Ying Wang, Zhenbo Peng, and Wei Guo Wang.

"Electrochemical Analysis of an Anode-Supported SOFC." Journal of

Electrochemical Science, 2013: 2330-2344.