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An Introduction. Product Categories: - Fully Formulated Dielectric Telecommunication Refrigeration - Intermediates Alkylates, Sulfonates, Polybutene - Synthetic Basestocks Alkylates, PB, PAO - Additives Component and Packages. - PowerPoint PPT Presentation
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An Introduction
Product Categories:Product Categories:- Fully Formulated- Fully Formulated
DielectricDielectricTelecommunicationTelecommunicationRefrigerationRefrigeration
- Intermediates- IntermediatesAlkylates, Sulfonates, PolybuteneAlkylates, Sulfonates, Polybutene
- Synthetic Basestocks- Synthetic BasestocksAlkylates, PB, PAOAlkylates, PB, PAO
- Additives - Additives Component and PackagesComponent and Packages
Soltex has been formulating, qualifying and supplying alkylateSoltex has been formulating, qualifying and supplying alkylate
and polybutene based performance products to the power, and polybutene based performance products to the power, telecommunication, refrigeration, lubrication, plastics, adhesives, telecommunication, refrigeration, lubrication, plastics, adhesives, rubber and personal care industries for over 20 years.rubber and personal care industries for over 20 years.
Dielectric FluidsDielectric FluidsAlkylate / Polybutene blends insulation oils with optimum high oxidative and thermal stability.Alkylate / Polybutene blends insulation oils with optimum high oxidative and thermal stability.
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QUALIFIED AT THESE UTILITY/CABLE COMPANIES: Dominion Electric – Richmond, VAPotomac Electric – Washington, D. C.Boston Edison (N Star) – Boston, MANYPA – Newburg, NYCambridge Electric/Okonite – Cambridge, MAPS of Colorado – Denver, COBaltimore Gas & Electric – Baltimore, MDConsolidated Edison – New York, NYLos Angeles Power & Water – Los Angeles, CAWA Chester/Florida Power & Light – Miami, FLJacksonville Electric, - Jacksonville, FLNational Grid / Keyspan-Hicksville, NYExelon/Commonwealth Edison – Chicago, ILMAC Products – Kearney, NJUnderground Systems – Armonk, NYW.A. Chester/Northeast Utility- Bethel, CTW.A. Chester/Memphis P&L Memphis, TNPSE&G – Somerset, NJThe Okonite Company – Ramsey, NJPrysmian – Canada and USHydro One, EHV,Comstock – Toronto, ON
Telecommunication Oils and GelsTelecommunication Oils and Gels
Formulations of PB/Waxes and antioxidants which impart tack, oxidation stability and water Formulations of PB/Waxes and antioxidants which impart tack, oxidation stability and water repellency. repellency.
Synthetic Alkylate Refrigeration FluidsSynthetic Alkylate Refrigeration Fluids Excellent low temperature properties, low flocculant points indicating good solvency for a hydrocarbon in polar fluids, Excellent low temperature properties, low flocculant points indicating good solvency for a hydrocarbon in polar fluids,
low foaming, good lubrication, thermal stability, excellent elastomeric compatibilitylow foaming, good lubrication, thermal stability, excellent elastomeric compatibility..
OEM APPROVALSTecumseh ProductsBristol Compressors
YorkGreenville Products
MycomFES
Carrier/CarlyleCopeland
General ElectricTrane
Scroll TechnologiesWhirlpoolEmbraco
Intermediates ProductsIntermediates Products
-Alkylates -Alkylates
-Sulfonates -Sulfonates
-Polybutenes-Polybutenes
AlkylatesAlkylates
Alkylates have good low temperature properties, solubility, oxidative and thermal stability. Possible alternatives to more expensive esters or less oxidative Alkylates have good low temperature properties, solubility, oxidative and thermal stability. Possible alternatives to more expensive esters or less oxidative stable naphthenic. stable naphthenic.
Property Napthenic Ester Alkylate
Oxidative Stability * ** ***Pour Point *** *** ***Aniline Point * *** **Hydrolytic Stability ** ***
Current Alkylate Products Qualitative Comparison
Sulfonates Sulfonates – oleum and mixture of oleum and natural sulfonation – oleum and mixture of oleum and natural sulfonation yielding neutral and over based sulfonates of Sodium, Barium, yielding neutral and over based sulfonates of Sodium, Barium,
Calcium,MagnesiumCalcium,Magnesium
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SulfonatesSulfonates
Gelled Sulfonates Gelled Sulfonates – crystalline calcium – crystalline calcium
sulfonates in sulfonates in solvent, oil or water carriers.solvent, oil or water carriers.
Sulfonic AcidSulfonic Acid – oleum sulfonated linear alkylaromatic sulfonic – oleum sulfonated linear alkylaromatic sulfonic acidacid
Sulfonic Acid:Sulfonic Acid: oleum sulfonated, highly active oleum sulfonated, highly active
sulfonic acid with little free acidity sulfonic acid with little free acidity and almost no odor which yields and almost no odor which yields
products of very light color.products of very light color.
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S
O
O
OH
C12H25
C12 H25
SulfonatesSulfonates
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Metal Characteristic
Sodium Solvency, low ash and stain
Calcium Ash, general purpose, scavenger for combustion acids
Barium Ash, best corrosion inhibition, non-staining
Magnesium Ash, vanedium scavenger
Applications:Detergent in lubricant (neutralizing acidic products of combustion and degradation). Rust and corrosion inhibitionBoundary and extreme pressure lubrication in metal working Base for Calcium Sulfonate grease (overbased) Emulsifiers
Metal (%)
Inorganic Salt %
Oil % Avg. MW
TBN Vis @ 100 cSt
Sulfol 465 Emulsifiable oils or as bases, dispersants
Sodium (62)
0.6 34 465
Sulfol 500 Same as 465 Sodium (62)
0.6 34 500
Neutral Bar 50 First intent, non-staining rust protection with good demulsibility and detergency
Barium(6.6)
50 4.0 25 – 100
Neutral Cal 10 High activity, imparts good rust and corrosion properties
Calcium (60)
60 980 10 212
AmorCal 400 Excellent gelling, excess alkalinity Calcium (20)
980 400 75
AmorCal 800 High solubility, excess alkalinity, good detergency
Calcium (20)
980 400 110
AmorCal 400 FG Excellent gelling, excess alkalinity and food grade
Calcium (20)
980 400
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Soltex Gelled Calcium Sufonates
PRODUCT Description Application % Non Volatile
Viscosity cP Flash PtDensity
Salt Spray Test
ThixoCal 7600Dispersion of modified calcium in mineral.
Corrosion preventive compound with enhanced penetrating characteristics,.
58-65 50-90,000 105 9.0
ThixoCal 2000/A
Solvent free, gelled calcium sulfonate in an oil carrier.
Basestock, removable rust preventative Bearings, hinges,
wire rope cable lubes 96 85-135,000 340
8.9-9.9
ThixoCal 3000AGelled calcium sulfonate, wax, oil and others
in mineral spiritsBase for formulations, short term
outdoor or long-term indoor storage
58-62 40-65,000 1057.8-8.0
ThixoCal 5300/5400
High solids, moderately formulated corrosion preventive compound 68-73 10-25,000 105 1.0
Excess of 5000 hrs at 3
mils
ThixoCal 5752xFormulated with waxes, oils and other
ingredients in mineral spirits.General rust proofing
52-58 3-6000 1057.2-7.4
ThixoCal 8100High solids, low VOC, corrosion prevention Base for architectural and plant
equipment and structural steel coatings
68-74 5-13,000 1058.0-8.3
ThixoCal 820080% solids corrosion preventive base
compound with additivesBase, penetrant.
78-82 7-15,000 1058.0-8.23
ThixoCal 4400Morpholine-Free, water-based rust and
corrosion preventive coatingAutomotive anti-corrosion coating
OEM and aftermarket 45 3.5-9,0007.8-8.2
ThixoCal 4500Formulated corrosion prenentive water-borne
coating excess amineBase for water-borne anticorrosion
coatings 46-52 25-60,0008.1-8.3
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Sulfonate New Products Under Development:
1. Biodegradable Rail Curve Lubricant
2. Grease base (No.1 and 2 grease available)
3. Food Grade Overbased Calcium Sulfonate (available)
4. Magnesium Carboxylate
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Polybutylenes:Soltex Polybutene products are range from 350 to 2600 MW and from 12cSt at 40C to 4900cSt at 100C. We react, formulate and blend these – to make derivatives of PB and custom PB blends just right for the application.
Polybutenes increase viscosity, add tack, decompose cleanly, are synthetic, NSF, Kosher and Halal approved, and have good oxidative and thermal stability.
C
CH3
CH3
H2C C
CH3
CH2
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I - alpha-Vinylidene
C
CH3
CH3
CH
C
CH3
CH3
Polybutenes:
CH
CH3
C
CH3
C
CH3
CH3
C
CH3
C
CH3
CH
CH3
CH3
II beta-Vinylidene III - Tri-substituted IV - Tetra-substituted
No. Terminal Olefin StructureConventional
PIB%
HR PIB%
I-PIB%
Ialpha-Vinylidene (alpha-olefin)
4 - 5 75 - 90 50 – 65
II beta-Vinylidene absent or minor 10 - 25 35 – 50
IIITri-substituted 63 -67 absent or
minorabsent or
minor
IV Tetra-substituted 22 – 28 1 - 5 1 – 5
IV-A Tetra-substituted 5 - 10 1 – 2 1 – 2
C
CH3
C
CH3
CH
CH3
CH3
IV-A Tetra-substituted
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High Molecular Weight Polyisobutylenes:Extremely high molecular weight polymers which are solid at ambient conditions.They are used in food contact applications, greases, medical adhesives, asphalt Improver, electrical insulating material, adhesives sealants, special pigments.
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Lubricant Additive Components:
Polymeric Thickeners
Tackifiers
Emulsifiers / Intermediates
Detergents
Dispersants
Viscosity Index Improvers
Pour Point Depressants
Antiwear/EP Additive
Grease Additives
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Soltex Polymeric Thickener - BSR-900Viscosity Modifier
Description:Soltex BSR 900 is a polybutene based polymeric thickener viscosity modifier developed for use in a wide range of high viscosity industrial
lubricants.
Features and Benefits• Excellent thickening at low treat levels( 5 to 40 %)• High shear stability • Superior oxidation resistance compared to Napthenic • Lower cost than PAO and PAG• Excellent solubility and clarity • Good viscosity index boost
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Soltex OMG Tackifiers – E857, E858, E859 FG
Description:High molecular weight PIB based polymeric Tackifiers developed for use in a wide range of industrial lubricants: 2500 to 3000 cSt @ 100 C: industrial grade, light colored grade and food grades available.
Features and BenefitsImparts a tack or stringiness to a substance and is typically used to provide adherence in fluid lubricants and stringiness in greases. • Food grade and non-food grade available• light colored available for color sensitive applications
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Soltex Polybutene Derivatives Emulsifiers / Intermediates / Dispersants / Anti-foulantsSoltex PCA 9010, 9030,9050, 9060, 9070, 9080 and 9090
PIBSA – Polybutenyl Succinic Anhydride – emulsifier, raw material
PIBSI – Polybutenyl Succinimide - dispersant
Di-PIBSI – Di-Polybutenyl Succinimide – anti-foulant
Soltex has the technical expertise to custom formulate a polyisobutylene emulsifier, dispersant, anti-foulant or other functional product to customers needs.
H3C C
CH3
CH3
CH2
CH3
CH3
CH2
CH2
CH2
CH
H2C
O
O
O
x
PIBSA = polyisobutenyl succinic anhydridePCA 9050x = 18-20
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Soltex Detergents AmorCal 800, Fricshun, PCA 4001
Soltex has the technical expertise to custom formulate a polyisobutylene emulsifier, dispersant, anti-foulant or other functional product to customers needs.
Description:Numerous metal salts of organic acids and non-metal compounds with and without excess base used to neutralize the acids to form salts and protect metal.
Features and BenefitsReact with acids formed in lubricants to form inert salts.Numerous metals (sodium, sulfur and barium available)Over based availableAshless, biodegradable and nontoxic available – allowing a boost in TBN without an increase in sulfur.
Viscosity Index ImproversSoltex S-Flow V1201 and S-Flow V6200
Description:
Alkyl methacrylate co-polymers in a highly refined mineral oil. Benefits:
Excellent shear stability and viscosity modification. Numerous grades available allow formulator to taylor to your specific applications.
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Pour Point DepressantsSoltex S-Flow P702, P750, P801, P821
Description:Alkyl methacrylate co-polymers that exhibit highly
effective control of paraffinic wax crystal formation in both industrial and automotive lubricants. A variety of product grades allow you to taylor to your specific application requirements: from low Napthenic content to heavier base oils and broad applicability.
Benefits:Offer lubricant formulator flexibility to choose a broad
application PPD and thus minimize inventory, or tailor to specific applications. They will not impact color of high quality base oils.
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Antiwear / EP Additive - Soltex PCA 3001 Functional Bismuth Soap
Non Toxic Extreme Pressure / Anti-wear AdditiveSoltex PCA 3001 is a very thermally stable EP/AW additive which works in conjunction with all types of sulfur to provide outstanding antiwear for gear oils, engine oils, hydraulic oils, and other industrial and automotive fluids. It will dramatically increase 4-ball weld loads and Timken OK weld points. Typical treat rates of 3.3% in combination with 0.4 elemental sulfur will produce a 4-ball weld load of 620kg in a ISO 220 base oil lithium complex, Lithium, or calcium complex grease.
Features and BenefitsExcellent Extreme Pressure PropertiesLow Volatility yielding long life at high-temperatures.Non-Toxic Environmentally preferred
Table 1: Typical CharacteristicsProperty Test Method Units Value
Specific Gravity @ 20 ºC (77ºF)
ASTM D 287 G/ml 0.956
Kinematic Viscosity@ 40 ºC(104ºF)
ASTM D 445 CSt 163
Flash Point COC ºC 198
Weight Loss, 204 ºC, 22 hours ASTM D972 Wt. % 6.3
Pour Point ASTM D 97 ºC(ºF) -15(5)
Soltex Additive Packages:
Viscosity Modifier
Rust and OxidationInhibitors
PerformanceBoosters:Extra TBN
Extreme Pressure
Antioxidant
Friction Modifiers
Detergent Dispersants
PCMO, DEOTractor Hydraulic
Economy grade tractor hydraulic fluid
Safely used in most sump-type agricultural equipment including John Deere, Case and New Holland, Massey Ferguson and Ford
Provides gear wear protection, maintains hydraulic system performance and prevents oxidation to prolong fluid life.
Treat rate is 4.0 wt% in Group I,II base oil.
Tractor Hydraulic Additive Package
Multifunctional lube oil additive package used to formulate high quality mono-grade
and multi-grade gasoline and diesel engine oils with properties similar to a wide range of API classifications.
Contains detergents, dispersants, antioxidants, friction modifiers, rust and oxidation inhibitors
Non-detergent VI improvers required to meet multi-grade viscosity classifications
Performance boosters required to meet high TBN (>10) specifications
Passenger Car Motor Oil Additive Package
Diesel Engine Oil Additive Package
High performance diesel engine oil additive package for high speed turbocharged
engines operating on fuel containing up to 0.5% S
Contains Ashless dispersant, ZDDP, metallic detergents.
Non-detergent VM with SSI of 20 – 40 recommended for multigrade oils
PCA 2877 PCA2886
Viscosity @ 100C 90 65
TBN 115 78
Calcium wt% 3.8 2.0
Nitrogen wt % 0.55 1.10
Phosphorus wt% 1.87 0.87
Zinc Wt % 2.10 1.0
Molybdenum ppm 425
Soltex Passenger Car Motor Oil Additives – PCA 2877 and PCA 2886
High performance diesel engine oil additive package for high speed turbocharged engines operating on fuel containing up to 0.5 % Sulfur. Contains Ashless dispersant, ZDDP, metallic detergents. Field tested over 5 years with no complaints. Non-detergent VM with SSI of 20-40 recommended for multi grade oils.
Performance Level Wt %
CH-4 / SJ Premium 15.04
CH-4/SJ Fighting 13.07
CG-4, CF, CF2,CF4,CE/SJ 11.28
CF-2, CF 9
Specific Gravity @ 15.6C 0.971
Viscosity, cSt @ 100C 30
TBN, mg KOH/g 66
Calcium, Wt % 1.8
Nitrogen, Wt % 0.72
Phosphorus, Wt% 0.91
Zinc, Wt % 0.98
Molybdenum, ppm 700
Soltex Diesel Engine Oil AdditivePCA 2861
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Soltex Custom Additive Packages:
Blends of quality dispersants, detergents, antioxidants, AW/EP additivesand other ingredients can be custom blended to your specification.
- create many different lubricants from these bases - consolidate your purchases, - decrease your blending time - save money.
You specify the nitrogen, zinc, calcium, sulfur, phosphorus, total base number…
Soltex Services:
Technical Expertise: Ed Baxter: -Over 30 years experience in R&D including, R&D Director, Laboratory Director and Pilot Plant Manager -Experienced in Intellectual Property (IP) management; over 25 patents filed in last three years. -Broad product development experience in the areas of polymers (polyisobutylene, polyolefins, polyurethanes, polyethers),
hydrocarbon products, hydrocarbon resins, fuel and lube additives, lube basestocks, caulks, sealants, adhesives (PSA and hot melt), crop protection chemicals, bulk pharmaceuticals and cosmetic formulations.
-Synthetic organic experience in alkylations, etherifications, benzoylations, halogenation, alkylene oxide polymerizations (EO,PO,BO), olefin oligomerizations and polymerizations, hydroformylations, catalysis, aminations, maleations, hydrodimerizations (butadiene), dehydrations, hydrogenations, mannich base reactions, and, high pressure reaction chemistry.Experienced in instrumental methods of analysis including Gel Permeation Chromatography (GPC), High Performance Liquid Chromatography (HPLC), UV/Vis, FTIR, H1 NMR, C13 NMR, packed and capillary column GC and GC/MS.
Soltex has a full-service, independent, analytical laboratory specializing in petroleum and petrochemical applications. We offer a complete battery of standard ASTM test methods, from acid number to wax content, plus hard to find specialty procedures.
Laboratory Services:
Soltex Services:
- Bulk handling / trans - loading- packaging drums and totes- warehousing- heating of tank trucks / iso-containers