AMO ENVIRONMENTAL DECISIONS AUXIER & ASSOCIATES, …0001 amo environmental decisions auxier & associates, inc. west lake landfill stormwater st and ard level iv report of analysis

0001

AMO ENVIRONMENTAL DECISIONS

AUXIER & ASSOCIATES, INC.

West Lake Landfill Stormwater

ST AND ARD LEVEL IV REPORT OF ANALYSIS

WORK ORDER #18-03110-OR

May 11, 2018

EBERLINE ANALYTICAL/OAK RIDGE LABORATORY

OAK RIDGE, TN

0002

TABLE OF CONTENTS

SECTION DESCRIPTION PAGE

I Chain of Custody & pH Check 0004

II Sample Acknowledgement 0013

III Case Narrative 0016

IV Analytical Results Summary 0020

V Analytical Standards 0023

VI Quality Control Sample Results Summary 0059

VII Laboratory Technician's Notes 0072

VIII Analytical Data (Isotopic Uranium) 0102

IX Analytical Data (Total Uranium) 0141

X Analytical Data (Isotopic Thorium) 0192

XI Analytical Data (Radium-226) 0231

XII Analytical Data (Radium-228) 0265

XIII Barium-133 Analytical Tracer Data 0281

XIV Analytical Data (Gross Alpha/Beta) 0310

Last Page 0329

0003

STANDARD OPERATING PROCEDURE f~LINE

Sample Receiving

LABORATORY DATA SUPPORT CHECKLIST

MP-001-3

Eberline Services Work Order # ___ 1_8_-_0_3_1 _1 _Q ____ _

The checklist items listed below are to be initialed by appropriate staff upon completion/verification.

Date for Partial Initials Date Initials Checklist Items

Sample Log-In

Data Compilation

First Technical Data Review

MP-001, Rev. 19 Effective: 2111118

Page 14 of 15

Second Technical Data Review

Data Entry/Electronic Deliverable

Case Narrative

Electronic Deliverable Proof

Samples Analyzed within Holding Time es? No?

Technical/Clerical Corrections, Signatures Needed, Problems, Etc Date/Initials

Date package approved by:

Laboratory Manager Date

Copy No. ___ _ Radiochemistry Services

0004

SECTION I

CHAIN OF CUSTODY &pH CHECK

0005

Chain of ustody Record ~ ~ ,: No 001 ~~ EB ER.LINE

- --------- Oak Ridgll, TN 31830 s e: RV! c 11: s (865) 481-0083 Pt,o410 • (85.5) 483-4621 Fl!X

~

Project Name: West Lake Stormwater Project Number:

Send Report To: Paul Rosasco Sampler (i?rint Name):~ PageJ_ ot_L Address: EMSI Sampler (Print Name):~'kt @ .,.,,,,,.,,~,,._

Shipment Method: Fed Ex

Airbill Number: ~? Ol '1,f J M Phone: Laboratory Receiving:

Fax:

'j ,.. • , ~ ample I Sample ample Number ol l Lab ::;ample l r-,eld Sample iD I Date Time Matrix . Containers (to oo completed by lab)

ru - , ... 00! ~ 1eo2r ~id -2

l

by:

::::::::> L per; Received by: (Signature)

~d~ elinquished by: Received by: {Signature)

Dale: Time:

la 2, ,s i ":ko Date: Time:

Sample Custodian Remarks (Completed By Laboratory):

QA/QC Level I Turnaround I Sample Receip!

Total # Containers Received?

/2~-Relinquished by: (Signature) ~ec~~gnat~

s-,9.J-,r (ri3d Date: 1me:

Level n Routine )( COC Seals Present? ;_j

level ll 0 24 Hour 0 COC Seals Intact? Leve! m 0 1 Week 0 Received Containers intact? Other • Other ___

Temperature?

0006

EBERLINE ~3E.PVIC.:Et_,

Oak Ridge Laboratory

Internal Chain of Custody

Comments

Location (circle one)

Received by ~ Rough Prep Prep Separations

Relinquished by Sample Storage Rough Prep

Received by Sample Storage Rough Prep

Relinquished by Sample Storage Rough Prep Prep ~

Received by Sample Storage Rough Prep Prep Separations

Relinquished by Sample Storage Rough Prep Prep Separations

Received by Rough Prep Prep Separations








Work Order#

Lab Deadline

Analysis

Sample Matrix

Sample Fraction

04

Count Room

Count Room

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18-03110 4/12/2018

UUISO - Level 4 Water

HP 210 / 270 Storage Detector Activity Location

38 DDl.4

: i

l

l

l

l

Ini ials Date

~7PO _J -, /Jfl 7ff/~-V~J1Y

Kr/ 3/?oAB (Tfs-b

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Printed: 3/23/2018 4:37 PM

0007

EBERLINE



Comments
















Work Order# 18-03110 Lab Deadline 4/12/2018

Analysis KPA_LIQ - Level 4

Sample Matrix Water

Sample I HP 210 / 270 Storage Fraction Detector Activity Location

04 38 DDl.4

:

i I

Initi.als Date

Count Ro'1{_v ( i11,, r , , l( ~ 'f(['LU/- () ?,Jv/ Count Ro~(' (;' f 1 t-iDdu 4 /J~ 1 v Count Room 7 Count Room

Count Room

Count Room

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Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room I

Printed: 3/23/2018 4:37 PM

0008

EBERLINE r::;Er<VIC'.E._~J



Comments



Relinquished by Sample Storage Rough Prep

Received by Sample Storage Rough Prep Prep

Relinquished by Sample Storage Rough Prep Prep ~ Received by Sample Storage Rough Prep Prep Separations


/'

Received by Sa~l~l Rough Prep Prep Separations

',s.,--/








Work Order#

Lab Deadline

Analysis

Sample Matrix

Sample Fraction

04

Count Room

Count Room

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Count Room

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Count Room

Count Room

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Count Room

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i

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I

18-03110 4/12/2018

ThlSO - Level 4 Water

HP 210 / 270 Storage Detector Activity Location

38 DDl.4

o+i;-o ?. '3() ri l \r

Printed: 3123/2018 4:37 PM

0009

EBERLINE ~3Er~VIC'.EG



Comments



Relinquished by Sample Storage Rough Prep Separations

Received by Sample Storage Rough Prep Prep S~ns

Relinquished by Sample Storage Rough Prep Prep ~~ Received by Sample Storage Rough Prep Prep Separations


~------Received by Sample Storage Rough Prep Prep Separations








Work Order#

Lab Deadline

Analysis

Sample Matrix

Sample Fraction

04

Count Room ,-::;--

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

' /

18-03110 4/12/2018

Ra226 - Level 4 Water

HP 210 / 270 Storage

Detector Activity Location

38 DDl.4

'

.Initials Date

'{j) 4:/i,, irs ii p 4/3/!8 os-s--e

Printed 3/23/2018 4 37 PM

0010

EBERLINE



Comments



Relinquished by Sample Storage Separations

Received by Sample Storage Stp~ns

Relinquished by Sample Storage s~~s



Received by Sample Storage Rough Prep Prep <ieP.<!@liQns

Relinquished by Sample Storage Rough Prep Prep Sefl(l@!lbns



Received by s Rough Prep Prep Separations




Work Order#

Lab Deadline

Analysis

Sample Matrix

Sample Fraction

04

Count Room

Count Room

Count Room

Count Room

cE9 ~ Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

18-03110 4/12/2018

Ra228 - Level 4 Water

HP 210 / 270 Storage

Detector Activity : Location

38 DDl.4

;

Initials Date

\W --1k(1;v I~~(

l~P L//3//8 (15"5()

;Pq c,/1/~z: t:;,,-1:::::,.: v

·JO ( l ,) Cl .C\, /\'J P. 35"

\Co Y l cl ( r'6 llZH-\Lf.> ~lq ~ V~'i'.J

Printed; 312312018 4 37 PM

0011

, ~EBER~~,~:.~

- Oak Ridge Laboratory


Comments






Received by ~e

Rough Prep Prep Separations










Work Order#

Lab Deadline

Analysis

Sample Matrix

Sample Fraction

04

Count Room;;a

Count Room

~ e Count Room

Count Room

Count Room

Count Room

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18-03110 4/12/2018

GaGbT ThSr-Level4 Water

; HP 210 / 270 • Storage

Detector Activity Location

38 DDl.4

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.

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loitials , I Date

--v<!c~lS~~:J& ✓1 t 1MC-t 21l14/Lle

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Printed: 3/23/2018 4:37 PM

0012

Printed: 3/23/2018 11:40 AM

,: Sample Receiving Report EBER~~~c~ (Volumes, pH, & CPM)

FR ClientID # Btls Comments Matrix

01 LCS 0 WA

02 BLANK 0 WA

03 DUP 0 WA

04 OU-1-008 ; 2 WA V Container Number oHOria

1 <2 2 <2

Re~(#~ Date.$-;).3-fr

Page 1 of 1

Internal Work Order -"-~-··-·· -·~·•-~-.----·-··- -~-·--- ·-----.--·---

18-03110

Storage DDl.4

DDl.4

DDl.4

DDl.4 oH Final

<2 <2

Received By

]BAILEY

Rec Vol Ttl CPM Max

7.52 38 Volume Ill CPM

3.7600 38 3.7600 36

MP-001, Rev 5

Effective: 11/22/02

0013

SECTION II

SAMPLE ACKNOWLEDGEMENT

0014

Client Name

AMO Environmental Decisions

Project Name

WESTLAKE

Internal ID Client ID

01 LCS

02 BLANK

03 DUP

04 OU-1-008

~ EBERLINE SERVICES

Sample Log In Report

Contract/PO Project Type

WESTLAKE Environmental

Client WO Sample Disp

WESTLAKE STORMWATER w

Sample Date Matrix Storage

03/23/18 WA DDl.4

03/23/18 WA DDl.4

03/23/18 WA DDl.4

03/19/18 18:02 WA DDl.4

Totals Per Analysis (non QA samples)

Oak Ridge Laboratory 601 Scarboro Rd. Oak Ridge, TN 37830

Voice: (865) 481-0683 Fax: (865) 483-4621

Date Received

03/23/2018 Lab Deadline

04/12/2018 f- ::J <D co 0 ~I I .0 ' N N (f) ('.) < N N

"' CL "' "' -" ('.) CL 0:: 0:: f- :::J

X X X X X X I I

X X X X X XI I

X X X X X XI I

X X X X X XI I I I

1 1 1 1 1 1 0 0

Invoice J West Lake Landfill OU-1 Resp

AMO Environmental DecIsIons

PO Box 410

Danboro, PA 18916

Voice 215-230-8282

Fax 215-230-8283

Contact Marsha Joseph

Voice 865-675-3669

Fax 865-675-3677

Required Turnaround Days .. ~. - •fl:!'l!l"•l7if,C:

28 18-03110 Internal Deadline ,- ..

04/19/2018 04/20/2018

I I I I I I I I I I I I I I I I~

I I I I I I I I I I I I I I I I I 6



I I I I I I I I I I I I I I I I I ' I I I I I I I I I I I I I I I I I

0 -0 -0 -0 -0 -0 -0

0 -0 -0 -0 -0 -0 -0 -0 -0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

Report Data Paul Rosasco, P E

Eng Management Support, Inc

7220 W. Jefferson Ave, Suite 406

Lakewood, CO 80235

Voice 303-940-3426

Fax

Printed· 3/23/2018 4·37 PM

0015

EBERLIN STANDARD OPERATING PROCEDURE MP-001, Rev. 19

Effective: 2111/18 Page 13 of 15 Sample Receiving

SAMPLE RECEIPT CHECKLIST MP-001-2

WORKORDER#_....._1__..8.._-____;,,,Q-'-3_1_1_Q_

SAMPLE MATRIX/MATRICES:

WERE SAMPLES:

Received in good condition?

If aqueous, properly preserved

WERE CHAIN OF CUSTODY SEALS:

Present on outside of package?

Unbroken on outside of package?

Present on samples?

Unbroken on samples?

Was chain of custody present upon sample receipt?

(CIRCLE ONE OR BOTH)

C6UEO~ NON-AQUEOUS

(CIRCLE EITHER YES, NO, OR N/A)

N

N N/A

0 N

@ N

If) N

m N

(iJ N -IF THE RESPONSE TO ANY OF THE ABOVE IS NO, A DISCREPANT SAMPLE RECEIPT REPORT

(DSR) HAS BEEN ISSUED.

REMARKS: ____________________________ _

SI~ DATE: 3~:i.J-J ~

Copy No. ___ _ Radiochemistry Services

0016

SECTION III

CASE NARRATIVE

0017

• EBERLINE

"j EBS-OR-43704

May 11, 2018

Paul Rosasco

SERVICES

Engineering Management Support, Inc. 7220 W. Jefferson Ave., Suite 406 Lakewood, CO 80235

SAMPLE RECEIPT

CASE NARRATIVE Work Order# 18-03110-0R

EBERLINE ANALYTICAL CORf'ORATION

601 SCt\f~BOFW f~0/1D

OAK RIDGE. TEf\lNESSEf: 78;)()

PHONE (861>) L,81 0683 FAX (865) 483·-4621

This work order contains one water sample received 03/23/2018. Sample was analyzed for Isotopic Uranium, Total Uranium by KPA, Isotopic Thorium, Radium-226/228 and Gross Alpha/Beta.

CLIENT ID

OU-1-008

ANALYTICAL METHODS

LAB ID

18-03 110-04

Isotopic Uranium was analyzed using EPA Method 908.0 Modified. Total Uranium was analyzed using Method ASTM D5174 Modified. Isotopic Thorium was analyzed using EPA Method 907.0 Modified. Radium-226 was analyzed using EPA Method 903.0 Modified. Radium-228 was analyzed using EPA Method 904.0. Gross Alpha/Beta was performed using EPA Method 900.0 Modified.

ANALYTICAL RESULTS

Combined Standard Uncertainty is reported at 1-sigma value.

Minimum Detectable Activity (MDA) values for data represented in this report are sample-specific. MDA measurements are determined based on factors and conditions including instrument settings, aliquot size and matrix type.

ISOTOPIC URANIUM

Sample was prepared by removing a representative aliquot followed by mixed acid digestions as appropriate. Uranium was selectively extracted by ion exchange. Uranium was eluted, micro-precipitated and mounted on micro-porous filter media. Sample activities were then determined by alpha spectroscopy using energy specific regions of interest for Uranium-234, Uranium-235 and Uranium-238. Chemical recovery was determined by the use of a Uranium-232 tracer. Activity of the Uranium-232 tracer was determined by alpha spectroscopy using an energy specific region of interest.

Sample demonstrated acceptable results for all Uranium analyses. Chemical recovery was acceptable for all samples. The Uranium-234, Uranium-235 and Uranium-238 method blank demonstrated acceptable results. Results for the Uranium-234, Uranium-235 and Uranium-238 duplicate demonstrated an

Page I of 3

0018

ANALYTICAL RESULTS CONTINUED

ISOTOPIC URANIUM CONTINUED

acceptable relative percent difference and normalized difference. Results for the Uranium-234 and

Uranium-238 laboratory control sample demonstrated an acceptable percent recovery.

TOT AL URANIUM

A volumetric aliquot of the sample was removed and wet ashed until clear. Sample was muffled and

diluted to a known volume. An aliquot was removed from this dilution. This aliquot was oxidized,

complexed with Chem-Check, Ura-Plex and subsequently analyzed using a kinetic phosphorescent

analyzer.

Sample demonstrated acceptable results for all Total Uranium analyses. Chemical recovery was

acceptable for all samples. The Total Uranium method blank demonstrated an acceptable result. Results

for the Total Uranium duplicate demonstrated an acceptable relative percent difference and normalized

difference. Results for the Total Uranium low and high calibration range laboratory control sample

demonstrated an acceptable percent recovery.

ISOTOPIC THORIUM

Sample was prepared by removing a representative aliquot followed by mixed acid digestions as

appropriate. Thorium was selectively extracted by ion exchange. Thorium was eluted, micro-precipitated

and mounted on micro-porous filter media. Sample activities were then determined by alpha spectroscopy

using energy specific regions of interest for Thorium-228, Thorium-230 and Thorium-232. Chemical

recovery was determined by the use of a Thorium-229 tracer. Activity of the Thorium-229 tracer was

determined by alpha spectroscopy using an energy specific region of interest.

Sample demonstrated acceptable results for all Thorium analyses. Chemical recovery was acceptable for

all samples. The Thorium-228, Thorium-230 and Thorium-232 method blank demonstrated acceptable

results. Results for the Thorium-228, Thorium-230 and Thorium-232 duplicate demonstrated a high

relative percent difference; however, normalized difference is within acceptable limits for the analytical

technique. Results for the Thorium-228, Thorium-230 and Thorium-232 laboratory control sample

demonstrated an acceptable percent recovery.

RADIUM-226

Sample was prepared by removing a representative aliquot followed by mixed acid digestions as

appropriate. This was followed by precipitations of Radium/Barium Sulfate. Precipitates were dissolved

in alkaline EDT A. Radium was selectively precipitated and then mounted on micro-porous filter media.

Sample was counted by alpha spectroscopy using an energy specific region of interest for Radium-226.

Inherent self-absorption from elemental Barium was corrected for in the final result. Chemical recovery

was calculated by the use of a Barium-133 tracer, which was determined by HPGe gamma spectroscopy.

Sample demonstrated acceptable results for all Radium-226 analyses. Chemical recovery was acceptable

for all samples. The Radium-226 method blank demonstrated an acceptable result. Results for the

Radium-226 duplicate demonstrated an acceptable relative percent difference and normalized difference.

Results for the Radium-226 laboratory control sample demonstrated an acceptable percent recovery.

Page 2 of 3

0019

'

ANALYTICAL RESULTS CONTINUED

RADIUM-228

Following alpha spectroscopy analysis of Radium-226, Barium/Radium Sulfate precipitates were

redissolved and allowed for sufficient ingrowth of the Actinium-228 daughter. After ingrowth, Actinium-

228 was selectively precipitated. Precipitates were filtered and beta emissions for Actinium-228 were then

counted on a gas proportional counter. Chemical recovery was determined by the use of a Barium-133

tracer, the activity of which was determined by HPGe gamma spectroscopy and an elemental Yttrium

caITier by gravimetric measurements. The product of these two recoveries was used to calculate chemical

yield.

Sample demonstrated acceptable results for all Radium-228 analyses. Chemical recovery was acceptable

for all samples. The Radium-228 method blank demonstrated an acceptable result. Results for the

Radium-228 duplicate demonstrated a high relative percent difference; however, normalized difference is

within acceptable limits for the analytical technique. Results for the Radium-228 laboratory control

sample demonstrated an acceptable percent recovery.

GROSS ALPHA & BET A

Sample was prepared by evaporation of a representative volumetric aliquot acidified with HN03•

Reduced sample was then transfeITed to a steel planchet for final evaporation to dryness and flaming.

Sample was then counted on a gas proportional counter. Results were coITected as required for inherent

self-absorption based on residual mass present.

Sample demonstrated acceptable results for all Gross Alpha and Beta analyses. The Gross Alpha and Beta

method blank demonstrated acceptable results. Results for the Gross Alpha duplicate demonstrated a high

relative percent difference; however, normalized difference is within acceptable limits for the analytical

technique. Results for the Gross Beta duplicate demonstrated an acceptable relative percent difference and

normalized difference. Results for the Gross Alpha and Beta laboratory control sample demonstrated an

acceptable percent recovery.

CERTIFICATION OF ACCURACY

I certify that this data report is in compliance with the terms and conditions of the Purchase Order, both

technically and for completeness, for other than the conditions detailed above. Release of the data

contained in this hard copy data package has been authorized by the cognizant project manager or his/her

__ de§_jgnee to be accurate as verifi by the following signature.

M.R. McDougall ------------Laboratory Manager

Date: 5/11/2018

Eberline /\nalytical wants and encourages your feedback regarding our performance providing radioanalytical services. Please

visit http://eberlineanalytical.com/ to provide us with feedback on our services.

Page 3 of 3

0020

SECTION IV

ANALYTICAL RESULTS SUMMARY

0021

Printed: 5/11/2018 2:16 PM Page 1 of 2

Report To: Work Order Details:

Eberline Analytical Paul Rosasco, P.E. SDG:: 18-03110 ,•o•m•••••••••-••••-• --~-- •--•••• .. ' ·- -· ·- ~-,,, .... ,, .. ,

--~-----~l1JJ.:~am1_9_~ment Support1_Jnc. Project:: WEST LAKE Stormwater

Final Report of Analysis 7220 W. Jefferson Ave, Suite 40,~ Analysis Category: : ENVIRONMENTAL ·------------Lakewood, CO 80235 Sample Matrix:

1 WA Lab Sample Client Sample Receipt Analysis Batch

Analyte Method Result cu Report

ID Type : ID Date Date Date ID CSU MDA i CV

Units

18-03110-01 LCS KNOWN 03/23/18 00:00 3/23/2018 1 3/27/2018 1

18-0311 0 I Gross Alpha EPA 900.0 Modified 2.68E+02 I 1.15E+01 I I pCi/I

18-03110-01 LCS I SPIKE 03/23/18 00:00 3/23/2018 . 3/27/2018 i 18-03110 Gross Alpha EPA 900.0 Modified 3.10E+02 ! 3.98E+00 3.41E+01 2.54E-01 3.14E-01 pCin

18-03110-02 MBL I BLANK 03/23/18 00:00 3/23/2018 ; 3/27/2018 ; 18-03110 Gross Alpha EPA 900.0 Modified 3.97E-02 1.35E-01 1.35E-01 3.01E-01 3.65E-01 pCin

18-03110-03 DUP . OU-1-008 03/19/18 18:02 3/23/2018 3/27/2018 : 18-03110 Gross Alpha EPA 900.0 Modified 2.80E+00 , 1.94E+00 1.97E+00 3.35E+00 6.04E-01 pCin

I 3/23/2018 I 3/27/2018 : 18-03110

---18-03110-04 DO OU-1-008 03/19/18 18:02 Gross Alpha EPA 900.0 Modified 4.25E+00 1.96E+00 2.02E+00 2.55E+00 4.82E-01 pCi/I

:

18-03110-01 LCS KNOWN 03/23/18 00:00 3/23/2018 : 3/27/2018 i 18-03110 Gross Beta EPA 900.0 Modified 2.77E+02 8.30E+00 i pCin -----

18-03110-01 LCS : SPIKE 03/23/18 00:00 3/23/2018 3/27/2018 [ 18-03110 Gross Beta EPA 900.0 Modified 2.82E+02 ! 3.15E+00 3.91E+01 6.12E-01 1.95E+00 pCi/I

18-0311 0-02 MBL BLANK 03/23/18 00:00 3/23/2018 , 3/27/2018 i 18-03110 Gross Beta EPA 900.0 Modified -2.37E-01 2.57E-01 2.59E-01 5.78E-01 i 1.81E+00 1

pCin "---

18-03110-03 DUP OU-1-008 03/19/18 18:02 3/23/2018 ; 3/27/2018 I 18-03110 , Gross Beta EPA 900.0 Modified 1.95E+01 2.46E+00 3.64E+00 3.43E+00 7.70E+00 ; pCin

18-03110-04 DO OU-1-008 03/19/18 18:02 3/23/2018 i 3/27/2018 I 18-03110 i Gross Beta EPA 900.0 Modified 1.69E+01 2.31E+00 3.29E+00 3.30E+00 7.31E+00 pCin

I : . i : --

18-03110-01 LCS KNOWN 03/23/18 00:00 3/23/2018 4/2/2018 18-03110 Radium-226 EPA 903.0 Modified 1.00E+01 4.61E-01 pCi/I

18-03110-01 LCS . SPIKE 03/23/18 00:00 3/23/2018 i 4/2/2018 18-03110 1 Radium-226 EPA 903.0 Modified 9.91E+00 1.37E+00 2.50E+00 4.41E-01 5.56E-02 i pCin

18-03110-02 MBL : BLANK 03/23/18 00:00 3/23/2018 I 4/2/2018 ! 18-03110 Radium-226 EPA 903.0 Modified 2.23E-01 : 2.41E-01 2.45E-01 3.62E-01 I 3.68E-02 pCi/I ---

18-03110-03 DUP I OU-1-008 03/19/18 18:02 3/23/2018 4/2/2018 I 18-03110 Radium-226 EPA 903.0 Modified I I 1.19E-01 I 1.54E-01 1.56E-01 2.44E-01 2.36E-02 pCi/I

18-03110-04 DO OU-1-008 03/19/1818:02 3/23/2018 I 4/2/2018 ; 18-03110 Radium-226 EPA 903.0 Modified 1.47E-01 I 1.29E-01 1.33E-01 1.55E-01 1.54E-02 pCin

I I

18-03110-01 LCS KNOWN 03/23/18 00:00 3/23/2018 . 4/9/2018 i 18-03110 Radium-228 EPA 904.0 8.96E+00 ; 4.57E-01 I pCin

I

18-03110-01 LCS i SPIKE 03/23/18 00:00 3/23/2018 I 4/9/2018 ! 18-03110 Radium-228 EPA 904.0 8.43E+00 7.20E-01 2.04E+00 8.65E-01 1.06E-01 pCin

18-03110-02 MBL j BLANK 03/23/18 00:00 3/23/2018 i 4/9/2018 i 18-03110 Radium-228 EPA 904.0 2.64E-01 i 3.20E-01 3.25E-01 6.54E-01 1.07E-01 ! pCin

18-03110-03 DUP I OU-1-008 03/19/18 18:02 3/23/2018 : 4/9/2018 18-03110 Radium-228 EPA 904.0 9.25E-01 3.72E-01 4.27E-01 6.88E-01 1.06E-01 I pCi/1 I

18-03110-04 DO I OU-1-008 03/19/18 18:02 3/23/2018 ! 4/9/2018 ! 18-03110 Radium-228 EPA904.0 1.49E-01 3.36E-01 3.38E-01 7.03E-01 1.05E-01 I

pCin i I ; : i

18-03110-01 LCS : KNOWN 03/23/18 00:00 3/23/2018 ' 3/30/2018 : 18-03110 1

Thorium-228 EPA 907.0 Modified 4.80E+00 i 1.73E-01 •

pCin

18-03110-01 LCS I SPIKE 03/23/18 00:00 3/23/2018 1 3/30/2018 I 18-03110 Thorium-228 EPA 907.0 Modified 5.81E+00 , 1.09E+00 1.22E+00 1.20E-01 1.66E-02 pCi/I :

18-03110-02 MBL . BLANK 03/23/18 00:00 3/23/2018 3/30/2018 18-03110 Thorium-228 EPA 907.0 Modified 5.29E-03 3.43E-02 3.43E-02 9.33E-02 1.30E-02 : pCin

18-03110-03 DUP OU-1-008 03/19/1818:02 3/23/2018 3/30/2018 18-03110 Thorium-228 EPA 907.0 Modified -3.87E-02 7.02E-02 7.03E-02 1

2.14E-01 4.16E-02 pCin

18-03110-04 DO OU-1-008 03/19/18 18:02 3/23/2018 , 3/30/2018 18-03110 Thorium-228 EPA 907.0 Modified 3.44E-03 1.14E-01 1.14E-01 2.74E-01 9.26E-02 i pCin i

i :

18-03110-01 LCS I KNOWN 03/23/18 00:00 3/23/2018 i 3/30/2018 18-03110 Thorium-230 EPA 907.0 Modified 5.37E+00 1.45E-01 pCin

18-03110-01 LCS SPIKE 03/23/18 00:00 3/23/2018 I 3/30/2018 18-03110 Thorium-230 EPA 907.0 Modified 6.64E+00 1.22E+00 1.47E+00 1.34E-01 1.25E-01 i pCin

18-03110-02 MBL i BLANK 03/23/18 00:00 3/23/2018 ; 3/30/2018 18-0311 0 , Thorium-230 EPA 907.0 Modified 1.07E-01 i 9.52E-02 9.61E-02 1.18E-01 1.06E-01 pCin

18-03110-03 DUP OU-1-008 03/19/18 18102 3/23/2018 3/30/2018 18-03110 Thorium-230 EPA 907 .0 Modified 1.60E-01 1.59E-01 1.61E-01 2.03E-01 1.90E-01 pCin

18-03110-04 DO OU-1-008 03/19/18 18:02 3/23/2018 i 3/30/2018 18-03110 Thorium-230 EPA 907.0 Modified I 2.83E-01 ' 1.99E-01 2.02E-01 1.85E-01 1.77E-01 pCin i

CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (1-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample; MBL=Blank; DUP=Duplicate; TRG=Normal Sample; DO=Duplicate Original; CV=Critical Value

( . EBERLINE

~ ANALYT!CAL

EBERLINE CAL CORPORATION 601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621

0022


Report To: Work Order Details:

Eberline Analytical .................... Paul Rosasco, P.E,:________ _ SDG:: 18-03110 ...... , .... ·•-·~ ·~~ ... ,,,_.,, •.. _~ •-'••·. --·-·-··-···-""- ·-··--·-

Eng. Management Support, Inc. _ -·· Project: j WEST LAKE Stormwater

Final Report of Analysis """"~•--·

7220 W. Jefferson Ave, Suite 406 . Analysis Category: ! ENVIRONMENTAL ------~-~-Lakewood, CO 80235 Sample Matrix: : WA

Lab Sample Client Sample Receipt Analysis Batch I Report I

Analyte Method ' Result cu CSU MDA CV ID Type ID Date Date : Date ID I Units

18-03110.01 LCS KNOWN 03/23/18 00:00 3/23/2018 • 3/30/2018 : 18-03110 Thorium-232 EPA 907.0 Modified ; 4.80E+00 1.73E-01 : pCi/1 ---18-03110-01 LCS SPIKE 03/23/18 00:00 3/23/2018 3/30/2018 • 18-03110 Thorium-232 EPA 907.0 Modified 5.80E+00 1.09E+00 1.21E+00 1.65E-01 4.54E-02 pCi/1

18-03110-02 MBL BLANK 03/23/18 00:00 3/23/2018 3/30/2018 ' 18-03110 Thorium-232 EPA 907.0 Modified -3.80E-03 6.11E-02 6.11E-02 1.50E-01 5.53E-02 pCi/I

18-0311 0-03 DUP OU-1-008 03/19/1818:02 3/23/2018 : 3/30/2018 : 18-03110 Thorium-232 EPA 907.0 Modified 1.58E-02 6.57E-02 6.57E-02 1.69E-01 1.97E-02 pCi/1

18-03110-04 DO OU-1-008 03/19/18 18:02 3/23/2018 : 3/30/2018 I 18-03110 Thorium-232 EPA 907.0 Modified -5.87E-03 6.64E-02 6.64E-02 2.04E-01 4.00E-02 pCi/1 -·-· - ---------

:

18-03110-01 LCS : KNOWN 03/23/18 00:00 3/23/2018 : 3/27/2018 : 18-03110 Total Uranium ASTM D5174 Modified 8.00E+00 1.60E-01 ug/I

18-03110-0H LCSH KNOWN-H 03/23/18 00:00 3/23/2018 I 3/27/2018 1 18-03110 Total Uranium ASTM D5174 Modified I 2.00E+02 4.00E+00 ug/I

18-03110.01 LCS SPIKE 03/23/18 00:00 3/23/2018 i 3/27/2018 , 18-03110 Total Uranium ASTM D5174 Modified 8.65E+00 1.88E-01 2.69E+00 1.01E+00 i 1.01E+00 ug/1 --

18-03110-0H LCSH SPIKE-H 03/23/18 00:00 3/23/2018 i 3/27/2018 1 18-03110 Total Uranium ASTM D5174 Modified 1.96E+02 3.99E+00 6.10E+01 1.01E+00 1.01E+00 ug/1

18-0311 0-02 MBL BLANK 03/23/18 00:00 3/23/2018 : 3/27/2018 i 18-03110 Total Uranium ASTM D5174 Modified 0.00E+00 1.01E+00 1.01E+00 1.01E+00 1.01E+00 ug/1 --

18-03110-03 DUP OU-1-008 03/19/18 18:02 3/23/2018 3/27/2018 : 18-03110 Total Uranium ASTM D5174 Modified j 4.12E+00 9.50E-02 1.28E+00 1.01E+00 1.01E+00 ug/1

18-03110-04 DO OU-1-008 03/19/18 18:02 3/23/2018 3/27/2018 • 18-03110 : Total Uranium ASTM D5174 Modified 4.23E+00 1 9.91E-02 1.32E+00 1.01E+00 1.01E+00 : ug/1

: 18-03110.01 LCS KNOWN 03/23/18 00:00 3/23/2018 i 3/30/2018 i 18-03110 Uranium-234 EPA 908.0 Modified 7.28E+00 l 2.62E-01 pCi/1

18-03110-01 LCS SPIKE 03/23/18 00:00 3/23/2018 ; 3/30/2018 1

18-03110 1 Uranium-234 EPA 908.0 Modified 6.06E+00 8.95E-01 9.95E-01 6.70E-02 7.31E-03 pCi/1

18-03110-02 MBL BLANK 03/23/18 00:00 3/23/2018 i 3/30/2018 : 18-03110 Uranium-234 EPA 908.0 Modified -9.93E-03 3.02E-02 3.03E-02 8.24E-02 1.26E-02 pCVI

18-03110-03 DUP OU-1-008 03/19/18 18:02 3/23/2018 · 3/30/2018 : 18-03110 Uranium-234 EPA 908.0 Modified i 1.17E+00 1 3.65E-01 3.74E-01 1.52E-01 2.62E-02 ' pCi/1

18-0311 Q.04 DO OU-1-008 03/19/18 18:02 3/23/2018 3/30/2018 ; 18-03110 Uranium-234 EPA 908.0 Modified 1.06E+00 3.62E-01 3.69E-01 1.48E-01 1.95E-02 pCi/1

; 18-03110-01 LCS i SPIKE 03/23/18 00:00 312312018 , 313012018 I 18-0311 o Uranium-235 EPA 908.0 Modified 4.67E-01 1.87E-01 1.90E-01 : 1.04E-01 1.55E-03 pCi/1

18-03110-02 MBL BLANK 03/23/18 00:00 3/23/2018 . 3/30/2018 I 18-03110 Uranium-235 EPA 908.0 Modified 5.76E-03 1 3.73E-02 3.73E-02 1.02E-01 1.15E-02 I pCi/1

18-03110-03 DUP I OU-1-008 03/19/1818:02 3/23/2018 3/30/2018 i 18-03110 Uranium-235 EPA 908.0 Modified 1.14E-01 I 1.24E-01 1.24E-01 1.50E-01 1.14E-02 pCi/I

18-03110-04 DO OU-1-008 03/19/1818:02 3/23/2018 : 3/30/2018 i 18-03110 Uranium-235 EPA 908.0 Modified 9.83E-02 i 1.19E-01 1.19E-01 I 1.45E-01 7.90E-03 pCi/1

I i : : :

18-0311().01 LCS . KNOWN 03/23/18 00:00 3/23/2018 i 3/30/2018 / 18-03110 Uranium-238 EPA 908.0 Modified 7.06E+00 2.54E-01 : pCi/1

18-03110-01 LCS : SPIKE 03/23/18 00:00 312312018 I 313012018 i 18-03110 Uranium-238 EPA 908.0 Modified 6.13E+00 9.03E-01 1.00E+00 6.67E-02 7.09E-03 pCi/1 ·-

18-03110-02 MBL : BLANK 03/23/18 00:00 3/23/2018 • 3/30/2018 , 18-03110 Uranium-238 EPA 908.0 Modified -2.91E-04 • 3.09E-02 3.09E-02 9.16E-02 1.73E-02 : pCi/1

18-03110-03 DUP I OU-1-008 03/19/1818:02 312312018 I 313012018 18-03110 Uranium-238 EPA 908.0 Modified 9.26E-01 3.18E-01 3.25E-01 1.21E-01 1.28E-02 pCi/1

18-03110-04 DO OU-1-008 03/19/18 18:02 3/23/2018 1 3/30/2018 i 18-03110 Uranium-238 EPA 908.0 Modified 1.04E+00 3.59E-01 3.67E-01 1.68E-01 4.68E-03 . pCi/1

CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (1-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample; MBL=Blank; DUP=Duplicate; TRG=Nonmal Sample; DO=Duplicate Original; CV=Critical Value

( . EBERLINE :@ ANALYTICAL

EBERLINE CAL CORPORATION

601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/ 483-4621

0023

SECTIONV

ANALYTICAL STANDARD

0024

. . ., ·,, ·.>;~

QA/QC REVIEWED CERTIFICATE OF CALIBRATION

Date t,q(lnitialsJ/£ ALPHA STANDARD SOLUTION

Radionuclide: U-238NAT

Half Life:

Customer:

P.O.No.:

TMA EBERLINE

OR2778

Catalog No.:

(4.468 ± 0.005) x lOA9 years

7338 Reference Date: January 1 1995 12:00 PST.

Source No.: 479-50 Contained Radioactivity: (Total U) 8.016 µ,Ci

Contained Radioactivity: (Total U) 297 kBq

Description of Solution a. Mass of solution:

b. Chemical form:

65.2896 gin a 50 ml flame sealed ampoule

Uranyl Nitrate in H2O

c. Carrier content: None

d. Density: Approximately 1.3202

Radioimpurities

Radioactive Daughters

Refer to attached technical data sheet

Refer to attached technical data sheet

Radionuclide Concentration

(Total U) 0.1228

Method of Calibration

Activity calculations are based upon known specific activity and mass.

Uncertainty of Measurement

a. Systematic uncertainty in instrument calibration:

b. Random uncertainty in assay:

c. Random uncertainty in weighing(s):

d. Total uncertainty at the 99 % confidence level:

NIST Traceability

±3,0%

±0,0%

±2,0%

±3,6%

•

g/ml @20°c.

µCi/g.

This calibration is implicitly traceable to the National Institute of Standards and Technology.

Leak Test(s)

See reverse side for Leak Test(s) applied to this source.

Notes

1. Nuclear daw. were taken from "Table of Radioactive Isotopes•, edited by Virginia S. Shirley, 1986.

()..-8

2. IPL participates in an NIST measurement assurance program to e.tablish and maintain implicit traceability for a number of nuclides,

based on the blind assay (and later NIST certification) of Standard Reference Materials (As in NRC Regulatory Guidi: 4. I 5).

I .. · .... ~~.· .. · .. •.•t.·•··· ... ·.·/.·'·.··.• ... · .. \; .•....•...• ·•.·.··. '.l'J/. '·, ,_. ·. ··-.

. . .

ISOTOP.E

P R O [) ll C T .S

l,AB.ORATO!Ur:S

ISOTOPE PRODUCTS LABORATORIES

3017 N. SAN FERNANDO BLVD.

BURBANK, CALIFORNIA 91504

818 •843•7000 FAX 818 •843•6168

_,.._,,.

, ',,

lE(},lvAu...47 YCONfROL

~ t7et-fgv1~ 1931f-Date Signed

. ··, ',.•\''' ·,• .. '-'·.-·•" ! ,',' •,

0025

, ~--~-f;;;Rl,-1 N E I ~ ;,f:RVICf!S

QUALITY CONTROL PROGRAM MP-009

Rev.a; 11/01/03 Title: Radioactive Reference Standards Solutions & Records

EBERLINE SERVICES - OAK RIDGE LABORATORY RADIOACTIVE REFERENCE SOLUTIONS PRIMARY DILUTION RECERTIFICATION

MP009

CURRENT DATE 7/12/2017 0:00

SOLUTION REFERENCE #r-lP_L_4 __ 7 __ 9-,,.5-o--.. -. ----- SOLUTION # ·. · . · ' u,;.a . · .

Half Life, Years Half Life, Days

I ., 4.46aE+oel I .1.e32E+12I

Radionuclide ...• • ... ~;~U

Certified Activity 8:016~+00 µCi Certified Concentration · · , . µCi per gram

Ampoule /Solution Gross Empty Ampoule

Solution Net Total Activity in Ampoule

Referen~e Date._l __ ·.-'· 1 .... 11 __ 11_9_9_5 __ 0:_oo_,!

· .. _. · .•97:6400 Weight, Grams

· .. 32;5020 Weight, Grams 65.1380 Weight, Grams

8.0160 µCl

Chemical Com osition of Standard Solution

Dilution Instructions: Dilution Solvent Used

Dilute to a volume ofj 1000;00. · !milliliters

Certified Total Activity ofl 8.0160jµCi Which EQuals . 1.780E+07jdpm at the date listed above

. . This activity concentration is based on the original

· And after dilution the activity of this solution isl _ 1. 77955E+04jdpm/m•eference date listed above, All activities are corrected to the date and time of analysis by the laboratory data

processing software.

Expiration Date:! June 28, 2018

Date: 7/12/2017 0:00 -------Date: __ 7_/_2';_$.,._/1 ___ 1_

0026

Rev.a; 11101103 Title: Radioactive Reference Standardi; Solutions & Records

EBERLINE SERVICES-OAK RIDGE LABORATORY RADIOACTIVE REFERENCE STANDARD SOLUTIONS

SECONDARY DILUTION RECERTIFICATION

MP-009 Date 7/12/2017 0:00

Solution Reference # IPL479~5o · Solution # U-Sa

Princi al Radionuclide Half Life, Years

~;2:1?,238l): !· . 4A6SE+oa! Half Life, Da):'.S I . 1.632E+12I

Radionuclide of Interest . 2.34: 2a,s.: ~~u; Reference Date!: ·'. ,1/1/19950:0o)

Parent Solution Cone. 17798E+04 · dpmlml


Uranly Nitrate.in 11V!'.J-JN03 : :

Dilution Instructions: Dilution Solvent Used !1MHNQ; · .. ••·

SECONDARY VOLUMETRIC DILUTION

Vol. Parent Solution: . . .·· > :ltOOOO ml

Total Activity: 7.1182E+04 dpm Final Volume: · ·. · 1000;00 ml

NOTES:

Final Activity Concentration:! 7.1182E+01 jdpmfml

This activity concentration is based on the original reference date listed above. All activities are corrected to the date and time of analysis by the laboratory data processing software.

1-------------------------, Isotopic Distribution as: U-238 Atom % = 48.239 U-235 Atom % = 2.25 U-234 Atom% .a 49.501 All values +/- 3.6%

U-238 = 71.162 dpm/rnl X 0.46249 "'34.345 dpmlml U-235 = 71.162 dpmlml X 0.0225 = 1.602 dpmlml U-236 = 71.162 dpmlml X 0.49501 .a 35.236 dpmlml

Isotopic ratios from manufacturer's d~ta sheet

Vertfied&Appr~

Expiration Date:i June 28, 2018

0027

RECORD co~·y Tracer Solution for Environmental Analysis & Disequilibrium Studies

Description

Product Description & Measurement Certificate

Principal radionuclide: Daughter Nuclide:

uranium 232 (U-232) Th-228

Product code: UDPl 0050 Batch Number: 92/232/67

Measurement Reference date: 01 March2000

Accuracy

Radionuclidic

Purity

Isotopic Purity

Chemical Composition

Physical Data

Remarks

Approved Signatory

Radioactive concentration U-232 which is equivalent to

Volume of solution Total activity ofU-232

which is equivalent to

6.739E+o3 becquerels per gram of solution

l.821E-0l microcuries per gram of solution

5.035 millilitres 3.61E+o4 becquerels 9.76E-0l microcuries

Method of measurement (see reverse of this certificate)

Random uncertainty is: ± 0. 7% Systematic uncertainty: ± 0.5%

Overall uncertainty in the radioactive concentration quoted above: ± 1.7%

Overall uncertainty is defined on the reverse of this certificate.

Any radioactive impurities measured are listed below, expressed as percentages

of the activity of the principle radionuclide at the reference date.

Th-228 and daughter activity removed 2 Feb 2000

U-232 daughters activity will increase with time. By alpha 88% U-232, 12% daughters on 1/3/00

,.,.ne isotopic composition, exprP.ssed as atom per cent at the reference date .

1'-l'ot measured

Calculated weight ofU-232, 4.42E-08 grams, as 2M HN03 solution in a flame sealed glass vial.

This Tracer solution has been produced 'carrier free'.

Recommended halflifo of uranium 232: 6.980E+0l years

Principle energies of alpha emissions {MeV): 5.26331 .7%, 5.320 68.0%

Branching ratio for alpha emission: 100%

Calculated specific activity of uranium 232: 8. 167E+o5 Bq per microgram U•232.

For safety information and notes to ensure correct usage by all persons handling this radior1ctive Tracer

solution please read the instructions accompanying the package.

AEA Technology operates a quality management system which has been independently audited and

approved to ISO 9001.

Project Ref. AE23 l 5

Roger Wiltshi.re

Prepared and characteri:;;ed in the UK, for world wide distribution by Isotrak, AEA Technology, QSA.

Trkcert.wps 10/03/00 AEA Technrilogy is the trading name of AEA Technology pie

0028

Rev.8; 11/01/03


Title: Radioactive Reference Standards Solutions & Records

EBERLINE SERVICES - OAK RIDGE LABORATORY

RADIOACTIVE REFERENCE SOLUTIONS

PRIMARY DILUTION RECERT/FICA T/ON

MP009


SOLUTION REFERENCE # ,...A_E_A/_A_m_e_rs_h_a_m_9_2/-2-32_/_67--, SOLUTION # 1--------,U...,._..,.1-=-o----1

Princi al Radionuclide 232u

Radionuclide 232U

Half Life, Years

I· 7.200E+01 I

Certified Activity 9. 760E-01 µCi

Certified Concentration µCi per gram .__ ___ _.

Half Life, Days

I 2.630E+04l

Reference Date 1~ ___ 3/_1/_2_0_00_0:_0~0 I

Ampoule /Solution Gross~Weight, Grams

Empty Ampoule Weight, Grams

Solution Net Weight, Grams

Total Activity in Ampoule 0.9760 µCi

Chemical Composition of Standard Solution


Dilute to a volume of I 1000. 00 I milliliters

Certified Total Activity of! 0.9760lµCi Which Eauals 2.167E+06ldpm at the date listed above

And after.dilution the activity of this· solution isl 2.167E+03jdp'm/ml This activity concentration is based on the original

reference date listed above. All activities are

corrected to the date and time of analysis by the

laboratory data processing software.

Expiration Date: I October 4, 2018

10/7/2017 0:00

Date:

0029

( EBERLINE ~ , ~,I !"1-✓ I• l '•

Rev.8; 1110110·3

QUALITY CONTROL PROGRAM , MP-009


EBERLINE SERVICES - OAK RIDGE LABORATORY ·

RADIOACTIVE REFERENCE STANDARD SOLUTIONS SECONDARY DILUTION RECERTIFICATION

MP-009 Date 10/7/2017 0:00 1----------i

Solution Reference # AEA/Amersham 92/232/67 Solution # U-1 Oa

Principal Radionuclide 3 ,LJ

Half Life, Years Half Life, Days

I 7 .200E+01 I I 2.630E+04I

R_adionuclide of Interest' 232

U I Parent Solution Cone._ 2.167E+03 dpm/ml

Reference Date~l ___ 3_/1_/2_0_0_0_0_:o~ol




Vol. Parent Solution: Total Activity: Final Volume:

NOTES:

10.0000 ml 2.1670E+04 dpm

1000.00 ml

~--------------

Final Activity Concentration:! 2.1670E+01 I dpm/ml

This activity concentration is based on the original

reference date listed· above. All activities are ·


laboratory data processing software. ·

Expiration Date:! October 4, 2018

Verified & Approved By_=~---"'.=rT"'"'ll='===--~--~>-s----~.,_ ____ _,,, ______ _

QC Approval _..,__....,..:.{,W,,µ..<-J---.i-..:;;.._-"'-..J,-,,t-.-..::.i.,="'---

0030

C!Irrtifi.catr of J\uaJ~ziz

Standard Reference Material® 3164

Uranium Standard Solution

Lot No. 080521

This Standard Reference Material (SRM) is intended for use as a primary calibration standard for the quantitative

determination of uranium. One unit of SRM 3 l 64 consists of five 10 mL sealed borosilicate glass ampoules of an

acidified aqueous solution. The solution contains nitric acid at a volume fraction of approximately 10 %.

Certified Value of Uranium: 9.994 mg/g ± 0.016 mg/g

The certified value is based on ( 1) gravimetric preparation using high-purity uranium oxide (U30 8) and

(2) inductively coupled plasma optical emissi011 spectrometry (TCP-OES) using four primary standards

independently prepared from high-purity uranium metal.

The uncertainty in the certified value is calculated as

U = kuc

where k = 2.14 is the coverage factor for a 95 % confidence interval. The quantity u, is the combined standard

uncertainty calculated according to the ISO Guide [ l]. The value of u0 is intended to represent, at the level of one

standard deviation, the combined effect of uncertainty components associated with the gravimetric preparation, the

lCP-OES determination, and method bias [2].

Expiration of Certification: The certification of SRM 3164 Lot No. 080521 is valid, within the measurement

uncertainty specified, until 20 July 2020, provided the SRM is handled in accordance with instructions given in this

certificate (see "Instructions for Use"). This certification is nullified if the SRM is damaged, contaminated, or

otherwise modified.

Maintenance of Certification: NIST will monitor this SRM over the period of its certification. If substantive

technical changes occur that affect the certification before the expiration of certification, NIST will notify the

purchaser. Registration (see attached sheet-) will facilitate notification.

Coordination of the technical measur~ leading to the certification of SRM 3164 was provided by

M.R. Winchester of the NIST Analytical Chemistry Division.

This SRM was prepared by T.A. Butler of the NIST Analytical Chemistry Division. The TCP-OES analysis was

performed by T.A. Butler and M.R. Winchester of the NIST Analytical Chemistry Division. Primary standards for

ICP-OES calibration were prepared by T.A. Butler of the NIST Analytical Chemistry Division. ;-

Statistical consultation was provided by S.D. Leigh of the NIST Statistical Engineering Divisidn.

Support aspects involved in the issuance of this SRM were coordinated through the NIST Measurement Services

Division.

Gaithersburg, MD 20899 Certificate Issue Date: 25 August 2009

SRM 3164

Stephen A. Wi~, Chiei

Analytical Chemistry Ii)ivision

Robert L. Watters, Jr., Chief

Measurement Services Division

Page I of3

0031

( E 8 ~ R ~l,~,~ : QUALITY ~~~o~~OL PROGRAM

Rev 8; 11/01/03 Title: Radioactive Reference Standards Solutions & Records

EBERLINE SERVICES -OAK RIDGE LABORATORY

RADIOACTIVE REFERENCE STANDARD SOLUTIONS INITIAL DILUTION

MP-009 Date 11/10/20170:00

Solution Reference # NlST3J64 Lot# 080521 Solution # •.... u~12

Princi al Radionuclide Natural U .

Half Life, Years 1 4.46as+o91

Half Life, Days I ·1.632E+12!

Radionuclide of Interest N~tllri'.iU.J, .. ·, Reference Date! '----"··..a.ff_/2_5'--/2~0_09-'-:-o_:O=Oj

Parent Solution Cone. .. 9 .. 99E+00· · ·· mglg


Dilution Instructions:

Vol. Parent Solution: Total Mass;

Final Volume:

NOTES:

Dilution Solvent Used

PRIMARY VOLUMETRIC DILUTION

·. 1:00QO g 9.9940E+00 mg

1000:0Q ml Final Mass Concentration:

Rounded Concentration: 9.9940E+03 nglg 1.0000E+04 nglg

This concentration is based on the original reference

date listed above.

Expiration Date:I November 9, 2018

Date: November 11, 2017

Date: i1 lei7 I I

0032


Rev.8; 11 /01 /03 Title: Radioactive Reference Standards Solutions & Records


RADIOACTIVE REFERENCE STANDARD SOLUTIONS SECONDARY DILUTION (Recertification)

MP-009

Princi al Radionuclide NaturalU

Half Life, Years I · AA68E;+09.l

Half Life, Days I 1.632E+12I

Radionuclide of Interest N;).fura(JJ .. Reference Date! · 8/25/20090:00!

Parent Solution Cone. 1'.008+02 ng/ml

U-15-5


Dilution Instructions: Dilution Solvent Used l10%HNO~ ·.···


Vol. Parent Solution: · .1Q'.0000 ml

Total Mass: 1.0000E+03 ng

Final Volume: , J000,0.0 ml

NOTES:

/

Final Activity Concentration:! 1.0000E+OO!ng/ml


date listed above.

Expiration Date:f November 9, 2018!

Date: 11/11/2017 0:00

~--·~-·--~ -··~

QC Approval ......a....,,.,..-c-'d-'..,.___._,,,,,...~-~~r+-- Date: lj/, :3[17 r,

0033

l;;:.~.E;; .. ~k.lN_S;:;: ; !:-iERVICE!'..S .

Rev.8; 11 /01 /03



EBERLINE SERVICES- OAK RIDGE LABORATORY

RADIOACTIVE REFERENCE STANDARD SOLUTIONS SECONDARY DILUTION Initial Dilution

MP-009

Princi al Radionuclide NaturallJ ,

Half Life, Years .I' , Ai468E;+09!

Half Life, Days ! 1.6~2E+12I

Radionuclide of Interest Natu.raJ\tJ . Reference Date!<· 812$i2Q09 b:ooj

Parent Solution Cone. 1.:'00~+02 ng/ml

U-12-5




Vol. Parent Solution: . 50.0000 ml


Final Volume: ... 1,0QQ,00 ml

NOTES:

Fina.I Activity Concentration: I 5.0000E+OO!ng/ml


date listed above.

Expiration Date:jNovember 9, 20181

Date: 11/11/20170:00

Date: I i/L:.,? ft 7 I f

0034

~BERL,!NJ;;:: QUALITY CONTROL PROGRAM

' SP.:AVICl:.S MP-009

Rev.8; 11/01103 Title: Radioactive Reference Standards Solutions & Records



MP-009 Date 11/11/2017 0:00

Solution Reference·# J:iJl:ST3164'Lot# 0805Zt Solution# ':.Q.~}·2::~·";

Princi al Radionuclide

Natural u

Radionuclide of Interest · Natur!;ill lJ

Half Life, Years I · .· 4.468~+o9l

Parent Solution Cone. 1.Q0E+03 : ng/ml

U-12-6

Half Life, Days ! 1.632E+12!

Reference Date! · 8/25/20090:00!




Vol. Parent Solution: '10,P:QOO ml


Final Volume: JOOQ;QQ ml

NOTES:

Final Activity Concentration:! 1.0000E+01 Ing/ml


date listed above.

Expiration Date:I November 9, 201 Bl

Date: 11/11/2017 0:00

Date: 1d1~/17 r 7

.· .. 1

0035

Rev.8; 11/01/03 Title: Radioactive Reference Standards Solutions & Records



MP-009 Date. 11/11/20170:00

Solution Reference# NIS'T3'1,$4,Lot#080:52.1 Solution # l;;!d2~4;

Princi al Radionuclide Na.turaltJ

· Half Life, Years I 4A68E+09I

Half Life, Days I 1.632E+12l

Radionuclide of Interest Parent Solution Coric. i,,--,-,,.,....,,,,,....,_,......-1ng/ml

Reference Date I .. • · • . &/~5/~Q.09 Ci:QO'I

U-12


Dilution Instructions: Dilution Solvent Used l1Ci%HNQ3 '


Vol. Parent Solution:' ·, .. · ,5>0000 ml


Final Volume: ··.• ./1'QQO,OQ ml

NOTES:

Final Activity Concentration: l 5.0000E+01 Ing/ml


date listed above.

Expiration Date:! November 9, 2018 I

0036

Rev.8; 11/01/03




RADIOACTIVE REFERENCE STANDARD SOLUTIONS

SECONDARY DILUTION (Recertification)

MP-009. Date 11/11/2017 0:00

Solution Reference# :Nl$T31J54:Lot#0805:~:r Solution # · lP1V5.< -


Natural U

-Half Life, Years r 4.4aag+os.j

Half Life, Days I 1.632E+12)

Radionuclide of Interest N~tura_l W __ ---_: Reference Date I · 8125[2009 0:00,I

Parent Solution Cone. i:Ot:1E;t04' '; ng/ml

U-12




Vol. Parent Solution:•·----• --- ?tQ:OOOQ ml


Final Volume: 1 '-•• ;t000,00, ml

NOTES:

Final Activity Concentration: I 1.0000E+02jng/ml


date listed above.

Expiration Date:! November 9, 2018 !

Date: November 11, 2017

Date: 1,jrit '?

0037

Rev.8; 11/01/03



EBERLINE SERVICES~ OAK RIDGE LABORATORY

RADIOACTIVE REFERENCE STANDARD SOLUTIONS SECONDARY DILUTION (Recertification)

MP-009 Date 11/11/20170:00

Solution Reference# Nl$::t'$1E?4 t::.9f#Ql3Q52l ' Solution#; , :1P::\f~/p[ '


Natural U,,

Radionuclide of Interest . Natural U ,

Half Life, Years I. . 4A68E+09'!

Parent Solution Cone. 1:d0Sf04' • ng/ml

U-12

Half Life, Days

I 1.634E+12I

Reference Date!, 8725/2009 0:001


Dilution Instructions: Dilution Solvent Used ltQ%HN93


Vol. Parent Solution: 10d;b,OOO ml

Total Mass: 1-.0000E+06 ng

Final Volume: , 1'000;00 ml

NOTES:

(------

\ ·,-.. .... -....

Final Activity Concentration: I 1.0000E+03!ng/ml


date listed above.

Expiration Date:!November 9, 2018!

Date: 11/11/2017 0:00

Date: 1' /13U.,..,.) _....,,~....._,., ___ .,._, -

0038

CERTIFICATE OF CALIBRATION ALPHA STANDARD SOLUTION

Radionuclide: Th-232

Half Life: . (1.405 ± 0.006) x 10~ 10 years

Customer:

P.O.No.:

TMA EBERLINE

VH1632

1h-8

Catalog No.: 7232

435-104-2

Reference Date: November 1 1993 12:00 PST.

Source No.: Contained Radioactivity: (fh-232) 0.0933 µCi.

Contained Radioactivity: (Th-232) 3.45 kBq.


b. Chemical form:

c. Carrier content:

11.9712 g (in a 10 ml flame sealed ampoule)

Th(NO3)4 in water

None added

d. Density: Approx. 1.21 g/ml@20°C.

Radioimpurities None detected (other than daughters).

Radioactive Daughters Ra-228, Ac-228, Th-228, Ra-224, Rn-220, Po-216, Pb-212, Bi-212, Po-212, Tl-208

Radionuclide Concentration (Th-232) 0.00779


Activity calculations are based upon known specific activity and mass.





d. Total uncertainty at the 99% confidence level:

NIST Traceability

±3.0%

±0.0%

±2.0%

±3.6%


Leak Test(s)

See reverse side for Leak Test(s) applied to this source.

Notes

1. Nuclear data were taken from "'(able of Radioactive Isotopes", edited by Virginia S. Shirley, ·i986.

µCi/g,

2. IPL participates in an NIST measurement assurance program to establish and maintain implicit traceability for a number of nuclid~s,

based on the blind assay (and later NIST certification) of Standard Reference Materials (As in NRC Regulatory Guide 4.15).


1800 North Keystone Street

Burbank, California 91504

818 843 ~ 7000

QUALITY CONTROL

Date Signed

0039

;: EJ>E R \--,~!;;'c~ I QUALITY CONTROL PROGRAM

MP-009


EBERLINE SERVICES - OAK RIDGE LABORATORY RADIOACTIVE REFERENCE SOLUTIONS PRIMARY DILUTION RECERTIFICATION

MP009

CURRENT DATE 8/16/2017 0:00 ,,.........,--..,.....--------..... t--------SOLUTION REFERENCE # IPL435"-104;,2 · ' . SOLUTION # Th~ .

Radionuctide · · 232 & .. h ·

Half Life, Years

I · · ·.1AOSE+10I

Certified Activity . · <9.330E;cfJ2 µCi

Certified Concentration.___ ___ _.µCi per gram

Half Life, Days

j 5.132E+12j

Reference DateJ._.-. _ _;.1.1_/1_1_19..,..9_3_0_:o ..... ol

Ampoule /Solution Gross 18:8415 Weight, Grams

Empty Ampoule .. :.:.6.9296 Weight, Grams

Solution Net 11.9119 Weight, Grams



l"fh(N03)4 in H2O,

DIiution Instructions: Dilution Solvent Used . j1% NitricAcid

Dilute to a volume of! -1000.00 . !milliliters

Certified Total Activity of! 0.0933!µCi Which Eauals 2.071 E+05jdpm at the date listed above

And after dilution the activity of this solution isl 2.071E+02!dprn/ml This activity concentration is based on the original reference date listed above. All activities are corrected to the date and time of analysis by the laboratory data processing software.

Expiration Date:! August 11, 2018

VArifiArl P. AnnrnvArl Rv " ✓ ---,,,-;:--------+----

Rt1R1?n11 n·nn

Date:

0040

~ ~J::RLIN,_t;; I QUALITY COMPN-OTO~OL PROGRAM ~ Si:tRv1ce.:s

Rev.8; 1/10/03 Title: Radioactive Reference Standards· Solutions & Records

EBERLINE SERVICES~ OAK RIDGE LABORATORY RADIOACTIVE REFERENCE STANDARD SOLUTIONS


MP-009 Solution Reference# IPL435"104'--2

Prine! al Radionuclide ·· Z!ij&232Th

Radionuclide of Interest • ·. 228 &

232Th ·

Half Life, Years

I . t405E+10!

Parent Solution Cone. 2.07E+02 ·· dpm/ml


Date 8/16/2017 0:00 Solution # > · · Th~Bb

Half Life, Dar I 5.132E+12I

Reference Date .... I __ 1..a1 .... 11 __ 11 ..... 9_93_·• '""o:_oo ..... l

Dilution Instructions: Dilution Solvent Used l 1 % Nitric Acid


Vol. Parent Solution: · · · · · soo:0000 ml

Total Activity: 1.0355E+05 dpm

Final Volume: 1000,00 ml

NOTES:

Final Activity Concentration: I 1. 0355E+02! dpmlml


Expiration Date:I August 11, 2018

Date: 8/16/2017 0:00 ----,----Date: ____ e;+-'-'b (?"'+/ ...... 17_

I

0041

RTIFICATE OF ALIBRATI~et q\

LPHA ST AND ARD SOLUTION" \)\J' \ ~:~\\t\i

Radionuclide

Half Life:

Th-230 Customer:

P.O.No.:

~f&l\\l t~ ~v(); TMA EBERLM~ I\\\'' TI4944 \\I~

Catalog No.:

(7 .54 ± 0.03) x 10"4 years

7230 Reference Date: November 1 1991 12;00 PST.

Source No.: Contained Radioactivity: 1.036 µCi.


b. Chemical form:

c. Carrier content:

d. Density:

Radioimpurities

Radioactive Daughters

Radionuclide Concentration


5.0042 Th(NO3)4 in 0.lN HNO3

None added

1.0016

See attached technical data sheet

See attached technical data sheet

0.207

Weighed aliquots of the solution were assayed using a liquid scintillation counter.

Uncertainty of Measurement a. Systematic uncertainty in instrument calibration:



d. Total uncertainty at the 99% confidence level:

NIST Traceability

±2.0% ±0,5%

±0,2%

±2.7%

grams.

gram/ml @ 20°C.

µCi/gram.


Notes 1. Nuclear data were taken from "Table of Isotopes\ Seventh Edition, edited by Virginia S. Shirley.

2. IPL participates in an NIST measurement assurance program to establish and maintain implicit

traceability for a number of nuclides, based on the blind assay(and later NIST certification) of

Standard Reference Materials. (As in NRC Regulatory Guide 4.15)

ISOTOPE PRODUCTS LABORATORIES 1800 No. Keystone Street.,

Burbank, California 91S04 818 843 - 7000

0042

'.~® ....... , """.··:.E1S·e:RLINE , ._.·. ~· . ~·-,, 1-:v••:f· ,;


Rev.14; 10/10/2012


EBERLINE SERVICES -OAK RIDGE LABORATORY


PRIMARY DILUTION RECERTIFICA TfON

MP009


SOLUTION REFERENCE #,...IP_L_3_8_8_-1_1_6 ____ ...., SOLUTION #i-------,,T,,...h-..,.1-----t

Princi al Radionuclide 230Th

Half Life, Years

I 7.540E+04I

Radionuclide 230Thorium

Certified Activity 1.036E+00 µCi

Certified Concentration,__ ___ _.µCi per gram


Solution Net

Total Activity in Ampoule


Half Life, Days

I 2.754E+07I

Reference Date!~ __ 1_1/_1_/1_9_9_1 _0:_o_.ol

9.2660 Weight, Grams



1.0360 µCi

Dilution Instructions: Dilution Solvent Used !0.1N HN03

Dilute to a volume of! 1000. 00 I milliliters

Certified Total Activity of! 1.0360lµCi Which Eauals 2.300E+06jdpm at the date listed above


And after dilution the activity of this solution isl 2.300E+03ldprruml-ence date listed above. All activities .ire

corrected to the date and time of analysis by tl1e


Expiration Date:! January 10, 2019

Date: 2/10/2018 0:00

Date: '3 cg;· __ .......__ ...... ____ _

0043

Rev.14; 10/10/2012



EBERLINE SERVICES-OAK RIDGE LABORATORY



MP-009 Date 2/10/2018 0:00

Solution Reference# IPL 388-116 Solution #,,_ __ T_h--1-b __ _.

Half Life, Years

I 7.540E+04I

Half Life, Days

I 2.754E+07I

Radionuclide of Interest 0Thorium Reference Date! .... __ 1_1_/1_/1_9_9_1 _0_:0__.0 I Parent Solution Cone. 2.30E+03 dpm/ml


Dilution Instructions:

Vol. Parent Solution:

Total Activity:

Final Volume:

NOTES:

Dilution Solvent Used jo.1N HNO3


10.0000 ml

2.2999E+04 dpm 1000.00 ml

Final Activity Concentration: I 2.2999E+01 jdpm/ml





Expiration Date:I January 10, 2019

Date: 2/10/20180:00

Date: --'~I---+----

0044

-~ Isotope Products . Laboratories

An Eckert & Ziegler Company

24937 Avenue Tibbitts Valencia, California 91355

Tel 661•309·1010 Fax 661•257•8303

CERTIFICATE OF CALIBRATION ALPHA STANDARD SOLUTION

Radionuclide: Half-life: Catalog No.:

Th-229 7340 ± 160 years 7229

Customer: P.O.No.: Reference Date:

EBERLINE SERVICES 00009633 15-Jan-02 12:00 PST

Source No.: 867-54 Contained Radioactivity:

(Th-229 only) 1.013 µCi 37.48

Physical Description: A. Mass of solution:

B. Chemical form:

5.0147 gin 5 ml flame-sealed ampoule

Th(NO3)4 in 0.1M HN03

C. Carr[er content: 10µg Th/ml

D. Density: 1.0016 g/ml @ 20°C.

Radioimpurities:

None detected (daughters in equilibrium)

Radionuclide Concentration: 0.2020 µCi/g, 7.474 kBq/g

Method of Calibration:

This source was prepared from a weighed aliquot of solution whose activity in µCi/g was determined

using gamma ray spectrometry.

Peak energy used for integration: 193.5 keV

Branching ratio used: 0.0441 gammas per decay

Uncertainty of Measurement: A. Type A (random) uncertainty:

B. Type B (systematic) uncertainty:

C. Uncertainty in aliquot weighing:

D. Total uncertainty at the 99% confidence level:

Notes: - See reverse side for leak test(s) performed on this source.

± 0.7 % ± 3.0 % ± 0.0 % ± 3.1 %

7li-!8

kBq

- IPL participates in a NIST measurement assurance program to establish and maintain implicit traceability

for a number of nuclides, based on the blind assay (and later NIST certification) of Standard Reference

Materials (As in NRC Regulatory Guide 4.15).

- Nuclear data was taken from IAEA Technical Report Series No. 261.

- This solution has a working life of 5 years.

1-Tt½i-o2... Quality'control Date Signed IPL Ref. No.: 867-54

------------------ISO 9001 CERTIFIED ------------------

Medical Imaging Laboratory Industrial Gauging Laboratory

24937 Avenue Tibbitts Valencia, California 91355 1800 North Keystone Street Burbank, California 91504

0045

;: E;e E"" b~!:'o!'i I QUALITY CONTROL PROGRAM

MP-009

Rev.a; 1110/03 Title: Radioactive Reference Standards Solutions & Records

EBERLINE SERVICES - OAK RIDGE LABORATORY RADIOACTIVE REFERENCE SOLUTIONS PRIMARY D/LUnON RECERTIFICATION

MP 009


SOLUTION REFERENCE #,...IP_L_8_67--5-4...,_·::--_.·:--.. -.. -.,...----, SOLUTION #1-'°---.-.• T"""h-.,.1,_,8,-·. ---i

Half Life, Years 1 · . 7~340E+031

Half Life, Days

I 2.s81 E+oel

Radionuclide 1 • :~h Reference Date! · . 1/15/2002 o:ooj Certified Activity ·· t013E+00 µCi

Certified Concentration.__ ___ __.µCi per gram

Ampoule /Solution Gross Empty Ampoule .


·· 8.7752 Weight, Grams

. 3.75~1 Weight, Grams 5.0161 Weight, Grams 1.0130 µCi

Chemical Com osition_of Standard Solution

·h(N03)4 in0:1M·HNOi .• . .


Dilute to a volume of! • 1000~00. !milliliters

Certified Total Activity ofl 1.0130lµCi Which Equals 2.249E+06jdpm at the date listed above

I


And after dilution the activity of this solution is I 2.249E+03j dpm/ml reference date listed above. All activities are corrected to the date and time of analysis by the laboratory dat.a processing software,

Expiration Date: I August 11, 2018

n~tA· R/1Rt?n11 n·nn

0046


EBERLINE SERVICES-OAK RIDGE LABORATORY RADIOACTIVE REFERENCE STANDARD SOLUTIONS

SECONDARY DILUTION RECERTJFICA TION

MP-009 Solution Reference # IPL 867c-54

Princi al Radionuclide · · 229rh ·

Radionuclide of Interest · 229Th .·

Half Life, Years

l i.340E+os!

Parent Solution Cone. ·· 2.25E+03 • dpm/ml


TH(NO3)4 in 0.1 M H NQ3 · ..

Date 8/16/2017 0:00 Solution# Th-18a ...

Half Life, Days

I 2.aa1 E+osj

Reference Date! 1/15/2002 o:oo!

Dilution Instructions: Dilution Solvent Used I0~1M HNO~


NOTES:


10'.0000 ml 2:2490E+04 dpm

1000;00 ml Final Activity Concentration: I 2.2490E+01 ldpm/ml


Expiration Date: I August 11, 2018

0047

J}ational Jf nstftutt of $tanbatb!i & m;ecbnologp

<t'erttf tcate,· Standard Reference Material 425 lC Barium-133 Radioactivity _Standard

This Standard Reference Material (SRM) consists of radioactive barium-133. c~loride,. non-radioactive barium

chloride, and hydrochloric acid dissolved in 5 rnL of distilled water. The solution is contained in a flame

sealed NIST borosilicate-glass ampoule. The SRM is intended for the calibration of ionization chambers and

solid-state gamma-ray_spectrometry systems.

Radiological Hazard

The SRM ampoule contains barium-133 with a total activity of approximately 2.5 MBq. Barium-133 decays

by electron capture and during tlle decay process X-rays and gamma:rays with energies from 4 to 400 ke V are

emitted. Most of these photons escape from the SRM ampoule and can represent a radiation hazard.

Approximate unshielded dose rates at several distances (as of the reference time) are given in note [a]*.

Appropriate shielding and/or distance should be used to minimize personnel exposure. ,The SRM should be

used only by persons qualified to· han?le radioactive material. , ·

Chemical Hazard

The SRM ampoule contains .hydrochloric acid (HCl) with a concentration of 1 mole per liter .of water. The

solution is corrosive and represents a health hazard if it comes in contact with eyes or skin:, If the ampoule

is to be opened to transfer the solution, the recommended procedure is given on page 2. The ampoule should

be opened only by person,s qualified to h.andle both radioactive material and strong acid solution.

Storage and Handling

The SRM should be stored and used at a temperature between 5 and 65 °C. The solution in an unopened

ampoule should remain stable and homogeneous until at least June 2004.

The ampoule (or any subsequent container) should always be clearly marked as containing radioactive

material. If the ampoule is transported it should be packed, marked, labeled, and shipped in accordance with

the applicable national, international, and carrier regulations. The solution in the ampoule is a dangerous

good (hazardous material) both because of the radioactivity and because of the strong acid.

Preparation

This Standard Reference Material was prepared in the Physics Laboratory, Ionizing Radiation Division,

Radioactivity Group, J.M.R. Hutchinson, Group Leader. The overall technical direction and physical

measurements leading to certification were provided by L.L. Lucas of the Radioactivity Group and D.B. Golas,

Nuclear Energy Institute Research Associate.

The support aspects involved in the preparation, certification, and issuance of this SRM were coordinated

through the Standar~ Reference Materials Program by N.M. Trahey.

Gaithersburg, Maryland 20899

October 1994

SRM 4251C, p~ge 1 of 6

Thomas E. Gills, Chief

Standard Reference Materials Program

*Notes and references are on pages 5 and 6.

0048

~EB_ERLI_N_E I ~ SERVICES

QUALITY CONTROL PROGRAM QCP-009




PRIMARY DILUTION RE CERT/FICA TION

QCP 009-1

CURRENT DATEI 4/29/2017 0:00

SOLUTION REFERENCE #..,.N.,.,.IS"""T""'s.,,..,R""'M,..,.4_2,...5,--1 C-,----...., SOLUTION #l.,_ _ __,,,.B_a_..,,.6---il

Principal Radionuclide 1~Barium I

Radionuclide 133Barium

Half Life, Years

I 1.048E+o1 I

Certified Actlvlty.,.._,...,,.....,...._,,...,-1µCi

Certified Concentration 1.318E+01 µCi per gram

Half Life, Days

I 3.828E+03!

Reference Date .... l ___ 9/_1_/1_9_9_3_0_:o ...... oj

Ampoule /Solution Gross

Empty Ampoule Solution Net

Total Activity in Ampoule


.. 4.2582 Weight, Grams


66.5577 µCl


I '""BaCl2 in 1 M HCI

Dilution Instructions: Dilution Solvent Used 11M HCI

Dilute to a volume of! 1000.00 jmillillters

Certified Total Activity of! 66.5577jµCi Which Eauals I 1.478E+08ldpm at the date listed above

And after dilution the activity of this solution is! 1.478E+OS)dpm/ml This activity concentration is based on the original

reference date listed above. All activities are corrected

to the date and time of analysis by the laboratory data


Expiration Date:! April 27, 2018 I

" ----------- I Verified & Approved By I"--- -- ~~

-----d""~ n--.....--::---=7~---1~\---ac Approval, :,.,~j ~ -~ "i, \.

\. l

Date: 4/29/17 -------Date: s/;i./n ---1,""'--+,------

0049

Rev.B; 11/10/03

QUALITY CONTROL PROGRAM QCP-009

Title: Radioactive Reference Standards Solutlcms & Records




QCP-009-1-A

Solution Reference # NIST SRM4251 C · Date 4/29/17

Solution # ... _.----s-a_..S_a_·_· __

Prinoi al Radionuclide 133sa

Half Life, Years

I · 1.048E+01 ! Half Life, Days

j 3.828E+03j

Reference Datel ... ___ 9_/1_/1_9_93_0:_oo ..... l


Dilution Instructions: Dilution Solvent Used l1MHCI ·


Vol. Parent Solution: .• .>,,25i0000 ml

Total Activity: 3.6950E+06 dpm

Final Volume: . 1000.00 ml

NOTES:

Final Activity Concentration: I 3. 6950E+03l dpm/ml





e, Gr '"' 1(\-Expiration Date: .. I _A_p_r.,.il 2-7-,-2-01"'"2,_'. _I

;

Date: 4/29/17

Date: #0/1') I

0050

CERTIFICATE OF CALIBRATI lijA/OC REVIEWED ALPHA STANDARD SOLUTIO om d" g

t.=-=t.=t=.:t..::~::::::.J

Radionuclide:

Half Life:

Customer:

P'.O.No.:

TMA EBERLINE

VH1888

Catalog No.:

Ra-226

1600 ± 7 years

7226

453-26

Reference Date: February 1 1994 12:00 PST.

Source No.: Contained Radioactivity: (Ra-226) 1.001 µ.Ci.

Contained Radioactivity: (Ra-226) 37.0 kBq.


b. Chemical form:

c. Carrier content:

5.1864 g (in a 5 ml Flame Sealed Ampoule)

Ra(NO3)2 in 1 N HNO3

None added

d. Density: 1..0318 g/ml @20°C.

Radioimpurities None detected(other than daughters)·

Radioactive Daughters Rn-222, Po-218, At-218, Pb-214, Bi-214, Po-214, Tl-210, Pb-210, Bi-210, Po-210 and Tl-206.

Radionuclide Concentration (Ra-226) 0.1929


Weighed aliquots of the solution were assayed using gamma spectrometry:

Energy peak(s) integrated under: 186 keV.

Branching ratio(s) used: 0.0351 gamma rays per decay.




c. Random uncertainty in weigbing(s):

d. Total uncertainty at the 99 % confidence level:

NIST Traceability

±3.4%

±3.1%

±0.2%

±4,6%

µ.Ci/g.


Leak Test(s)

See reverse side for Leak Test(s) applied to this source,

Notes

1. Nuclear data were taken from "Table of Radioactive Isotopes", edited by Virginia S. Shirley, 1986.

2. IPL participates in an NIST measurement assurance program to establish and maintain implicit traceability for a number of nuclides,

b&sed on the blfo.d assay (arid later NIST certification) ofStimdiird Reference Miiterfals(As iii NRC Reguliitory Guide 4.15).


1800 North Keystone Street

Burbank, California 91504

818 843 -7000

QUALITY CONTROL

0,. 3, l99't Date Signed

0051

~ E a ER !a; ~!::lo!';; I

'

QUALITY CONTROL PROGRAM MP009

Rev.8; 11/01/03 Title: Radioactive Reference Standards Solutlons & Records

EBERLINE SERVICES• OAK RIDGE LABORATORY


PRIMARY DILUTION RECERTIFICATION MP009

CURRENT DATE! 9/20/2017 0:001

SOLUTION REFERENCE# IPL453c.26 I SOLUTION #I . : Ra;.s.· · I

Principal Radionuclide Half Life, Years Half Life, Da~s

226Radiuiri I I· .. 1.600E+03! I s.844E+osl

Radionuclide ~Radium· Reference Date! • 21111994 o:ool Certified Activity 1:001E+oo µCi

Certified Concentration , , µCi per gram

Ampoule /Solution Gross~Welgh~ Grams Empty Ampoule ·. . · · ·. Weight, Grams

Solution Net Weight, Grams



l.<.«>Rfl(NO~hi.n 1MHNQ3·•. ·,'' . . I . ,,.

Dilution Instructions: Dilution Solvent Used ,~M HN03. · I Dilute to a volume ofl · 1000;00 · I milliliters

Certified Total Activity of! : 1.0010lµCi Which Ecauals I 2.222E+06!dpm at the date listed above


And after dilution the activity of this solution isl 2.222E+03ldpm/ml reference date listed above. All activities are corrected



Expiration Date: I Seetember 20, 2018 I

~~ \

Verified & Approved By Date: 9/20/2017

~q\~ _? I \ \_

QC Approval \. ~~ ~ Date: 9/20/2017

- ~ J --

0052

Rev.a; 11/01103 Title: Radioactive Reference Standards Solutions & Records


RADIOACTIVE REFERENCE STANDARD SOLUTIONS SECONDARY DILUTION RECERTIFICA TJON

MP009

Solution Reference # IPL-453,.26


··· 226.Radium

Radionuclide of Interest ·. . ~ 6Radium .

Half Life, Years

I · 1;600E+03!

Parent Solution Cone. 2.22E+03 · dpmlml


.. Ra(N9s)2 in 1M HNOs ....

Date 9/20/2017 0:00

Solution # . Ra-5b .

Half Life, Daxs I s.844E+os!

Reference Date ... ! __ 21_1_11_9_94_. ·:·_o:_oo_,!

Dilution Instructions: Dilution Solvent Used j1MHNQj


NOTES:


20;0000 ml 4.4440E+04 dpm

1000.00 ml Final Activity Concentration: I 4.4440E+01 jdpmlml





Expiration Date:._l __ 2_0_-s_e_p-_1_a _ _.

Date:

Date:

9/20/2017 0:00

9/20/2017 0:00

0053

ANALYTICS

CERTIFICATE OF CALIBRATION Standard Radionuclide Source

62680-416

Ra-228 5 mL Liquid in Flame Sealed Vial

1380 Seaboard Industrial Blvd. Atlanta, Georgia 30318 · U.S.A.

Phone (404) 352-8677 Fax (404) 352-2837

This standard radionuclide source was prepared

gravimetrically from a calibrated master solution. The

master solution was calibrated using a germanium gamma

spectrometer system.

Radionuclide purity and calibration were checked using a

germanium gamma spectrometer system. The nuclear decay rate

and assay date for this source are given below.

ANALYTICS maintains traceability to the National Institute

of Standards and Technology through Measurements Assurance

Programs as described in USNRC Reg. Guide 4.15, Revision 1.

ISOTOPE:

ACTIVITY (dps):

HALF-LIFE:

CALIBRATION DATE:

TOTAL UNCERTAINTY*:

SYSTEMATIC:

RANDOM:

*99% Confidence Level

Ra-228

2.585 E3

5.75 years

November 7, 2001 12:00 EST

4.0%

3.0%

1.0%

Impurities: y-impurities (other than decay products) <0.1%

5.07198 grams 0.lM HCl solution with 50 µg/g Ba carrier.

PO NUMBER 9508, Item 1 (Part #4339A)

SOURCE PREPARED BY, M~~4i~ QA APPROVED:

0054

E BERLIN_J;: SE:~VICE$

Rev.a; 1/10/03

I QUALITY CONTROL PROGRAM MP--009


EBERLINE SERVICES - OAK RIDGE LABORATORY RADIOACTIVE REFERENCE SOLUTIONS

RECERTIFICATION MP009


SOLUTION REFERENCE # ... A-ri-a!--·. -ics-, ,-6-268...,,-0-.:4--1-6..,..'",---. SOLUTION #.,.._.._....,R __ a ___ ;.;1-,1-· ---1

Princi al Radionuclide . 226Ra •

Half Life, Years

I s.1soE+ciol Half Life, Days

I 2.1 OOE+03!

Radionuclide . · _ 228Ra _ · Certified Activity 6. 986E-02 µCi

Reference Date._j __ 1_1/7_· _I2_0 ___ 0_1 _0_:0__,0j

Certified Concentration..__ ___ _,µCi per gram



: 9A9.82 Weight, Grams 4:4895 Weight, Grams 5.-0087 Weight, Grams 0.0699 µCi



Dilute to a volume ofl · - 1000;00 !milliliters

I0.5MHCI'

Certified Total Activity ofl 0.0699lµCi Which Equals 1.551 E+05jdpm at the date listed above

I

And after dilution the activity of this solution is! 1.551 E+02!dpm/ml This activity concentration Is based on the original reference date listed above. All activities are corrected



Expiration Date:( February 20, 2018

Date: 2/28/17

0055

QA/QC REVIEWED ANALYTICS

Date Initials w(

CERTIFICATE OF CALIBRATION Standard Radionuclide Source

52094-416

Am-241 10 mL Liquid in Flame Sealed Vial

1380 Seaboard Industrial Blvd. Atlanta, Georgia 30318 · U.S.A.

Phone (404) 352-8677 Fax (404) 352-2837

This standard radionuclide source was prepared gravimetrically

from a calibrated master liquid radionuclide solution source.

The master source was calibrated by liquid scintillation

counting.

ANALYTICS maintains traceability to the National Institute of

Standards and Technology through Measurements Assurance Programs

as described in USNRC Reg. Guide 4.15, Revision 1.

ISOTOPE:

ACTIVITY (dps):

HALF-LIFE:

CALIBRATION DATE:

TOTAL ERROR:

Am-241

1.975 E+05

432.2 years

March 19, 1996 12:00 EST

3.0%

SYSTEMATIC ERROR: 2.37%

RANDOM ERROR: 0.63%

10.01177 grams of solution lM HCl.

PO NUMBER OR3830, Item 1

SOURCE PREPARED BY: Beverly,

QA APPROVED: M-~

0056

, e:;a ~J~J . .,.JN g I QUALITY c~~1~0L PROGRAM ~ SE.RV1ce.s


EBERLINE SERVICES-OAK RIDGE LABORATORY

RADIOACTIVE REFERENCE STANDARD SOLUTIONS SECONDARY DILUTION (RE-CERT/FICA TION)

Date 7/29/2017 0:00

Solution Reference # Anal cs 52094-416 Solution # A/B-7 al ha

Radionuclide of Interest 241Am

Half Life, Years

I 4.322E+02!

Parent Solution Cone. 1.19E+04 dpm/ml


j241AmCl3 in 1 M HCL

Half Life, Days l 1.579E+05 [

Reference Date .... I __ 3_/_19_/_19_9_6_0_:oo_.l



NOTES:


60.0000 ml 7.1100E+05 dpm

1000.00 ml Final Activity Concentration: I . 7.1100E+02jdpmlml





Expiration Date:I July 29, 2018

0057

Jlattonal 1htstttute of ~tanbarb~ & m;ccbnologp

ctertif tcate Standard Reference Material 4234A

Strontium-90 Radioactivity Standard

1bis Standard Reference Material (SRM) consists of radioactive strontium-90 chloride, non-radioactive

strontium chloride, non-radioactive yttrium chloride, and hydrochloric acid dissolved in 5 mL of distilled water.

The solution is contained in a flame-sealed NIST borosilicate-glass ampoule. The SRM ·is intended for the

calibration of beta-particle counting instruments and for the monitoring of rll;diochemical procedures.

Radiological Hazard

The SRM ampoule contains strontium-90 with a total activity of approximately 13 MBq. Strontium-90 decays

by beta-particle emission to yttrium-90, which also decays by beta-particle emission. None of the beta particles

escape froni the SRM ampoule. The beta particles emitted from strontium-90 and yttrium-90 produce

bremsstrahlung photons with energies up to 2 MeV. Most of these photons escape from the SRM ampoule

and can represent a radiation hazard. Approximate unshielded dose rates at several distances (as of the

reference time) are given in note [ a J*. Appropriate shielding and/or distance should be used to minimize

personnel exposure. The SRM should be used only by persons qualified to handle radioactive material.

Chemical Hazard

The SRM ampoule contains hydrochloric acid (HCl) with a concentration of 1 mole per liter of water. The

solution is corrosive and represents a health hazard if it comes in contact with eyes or skin. If the ampoule

is to be opened to transfer the solution, the recommended procedure is given on page 2. The ampoule should

be opened only by persons qualified to handle both radioactive material and strong acid solution.

Storage and Handling

The SRM should be stored and used at a temperature between 5 and 65 °C. The solution in an unopened

ampoule should remain stable and homogeneous until at least March 2005.

The ampoule (or any subsequent container) should always be clearly marked as containing radioactive

material. If the ampoule is transported it should be packed, marked, labeled, and shipped in accordance with

the applicable national, international, and carrier regulations. The solution in the ampoule is a dangerous

good (hazardous material) both because of the radioactivity and because of the strong acid.

Preparation

This Standard Reference Material was prepared in the Physics Laboratory, Ionizing Radiation Division,

Radioactivity Group, J.M.R. Hutchinson, Group Leader. The overall technical direction and physical

measurements leading to certification were provided by L.L. Lucas of the Radioactivity Group and D.B. Golas,

Nuclear Energy Institute Research Associate.

The support aspects involved in the preparation, certification, and issuance of this SRM were coordinated

through the Standard Reference Materials Program by N.M. Trahey.

Gaithersburg, Maryland 20899

May 1995 (Text only revised November 1997)

SRM 4234A, page 1 of 6

Thomas E. Gills, Chief

Standard Reference Materials Program

*Notes and references are on pages 5 and 6.

0058


EBERLINE SERVICES • OAK RIDGE LABORATORY

RADIOACTIVE REFERENCE STANDARD SOLUTIONS SECONDARY DJLUTION (RE•CERTIFICA TION)

QCP-009-1-A Date 7/29/2017 0:00

Solution Reference # NIST 4234A Solution # • A/B--7 beta

Princi al Radionuclide 00strontium

Half Life, Years

I : 2:878E+01 ! Half Life, Days

I 1.051E+04)

Radionuclide of Interest' . . .90Sr ' I Parent Solution Cone .. · f;52E+06 : dpmlml

Reference Date!: •· · '3h3h995·o:ool

The beta activity of solution reflects the original 90Strontium concentration and an equal concentration of OOVttrium.


l~sre~ .inJ ·M HCI ' . < I

Dilution Instructions: Dilution Solvent Used ltM HN03.

SECONDARY VOLUMETRIC DILUTJON

Vol. Parent Solution: 0'.5000 ml Total Activity: 7.5764E+05 dpm Final Volume: . . .. . · 1000.00 ml

NOTES:

Final Activity Concentration: I 7.5764E+02jdpm/ml


Expiration Date:I July 29, 2018

Date: ___ 0_7 __ /2_9_/1_7 __

Date: __ ,;-_f 1_(!_] __

0059

SECTION VI

QUALITY CONTROL SAMPLE RESULTS SUMMARY

0060

Eberline Analytical

Analysis Control Chart

w ... 18-03110

Analyte

U-234

U-238

Analyte

Analyte

U-234

U-238

U-235

Version

Nonnalized Difference

Analysis

UUISO

LCS Measured

83.21%

86.91%

MS Actual %Rec

I CSU

Measured

16.41%

16.37%

Expected MS Result

Duplicate Results

Nonnalized RPD Original

Difference Result

0.43 10.27 1.06E+00

0.45 11.42 1.04E+00

0.18 15.18 9.83E-02

Run Activity Units Aliquot Units

1 pCi

Laboratory Control Sample

LCS Expected

100.00%

100.00%

Expected MS Uncert

Original CSU

3.69E-01

3.67E-01

1.19E-01

Uncert. Known Expected

3.60% 7.28E+00

3.60% 7.06E+00

Matrix Spike

Actual MS Result

Duplicate Result

1.17E+00

9.26E-01

1.14E-01

Actual MS CSU

Duplicate CSU

3.74E-01

3.25E-01

1.24E-01

I

Known Error

2.62E-01

2.54E-01

Sample Result

LCS Relative Bias

0.83

0.87

Result

6.06E+00

6.13E+00

Sample CSU

LCS%R I

OK

OK

OK

Printed: 4/2/2018 8:22 AM

Page 1 of 2

Client Name


CSU

9.95E-01

1.00E+00

Sample Aliquot

Standard

ID

U-8a

U-8a

Standard ID

Standard

ACT(dpm)

3.20E+01

3.10E+01

Standard ACT{dpm)

QC Summary

I MS%R I MSND I

Standard

Error

3.60E+00

3.60E+00

Standard Error%

RepRPD

OK

OK

NA

I

Standard

Added (Q)

5.0SE-01

5.0SE-01

Standard Added(g)

Rep ND

OK

OK

OK

0061

Eberline Analytical Analysis Control Chart

WO • 18-03110

130.00

120.00

110.00

100.00

90.00

BO.OD

Analysis

UUISO

LCS % Recovery

I _________ I

Run Activity Units Aliguot Units

1 pCi

40.00

35.00

30.00

25.00

20.00

15.00

10.00 I

Printed: 4/2/2018 8:22 AM Page 2 of 2

Client Name


Replicate Sample RPO

! 70.00 +---------~-----------------~--------~

l U-234 U-238 5.00

- Lower Error ~~ ~%

- Upper Error 103.22 106.88 0.00 +-------------~--------------,-------

I U-235 U-234 U-238

• %R 83.21 86.91 - LowerError 11.98 13.43 I 23.87

- -LCL 75 75 - Upper Error 8.55 9.41 I 6.49

--Mean 100 100 • RPO 10.27 11.42 I 15.18

- -UCL 125 I 125 --CL 35 35 i 35

Normalized Difference

3.50

No Matrix Spike

3.00

2.50

2.00

1.50

1.00

0.50

0.00 LCS ND REP ND MSND

-U-234 0.00 0.43 0.00

=u-238 0.00 0.45 0.00

~UCL I 0.00

3

0.00

3

0.00

3

Version

0062

Eberline Services Analysis Control Chart

WO

18-03110

Analyte

TOTALU

TOTAL U (LCS-H)

Analyte

Analysis

KPA_LIQ

Nonnatized Difference

LCS Measured

108.14%

98.04%

MS Actual %Rec

I CSU

Measured

31.13%

31.12%

Expected MS Result

I I

Run Activity_ Units Aliguot Units

1 ug

Laboratory Control Sample !

LCS

I Expected

100.00% I

100.00% I

Expected MS Uncert

Uncert. Known

Expected

2.00% 8.00E+00

2.00% 2.00E+02

Matrix Spike

Actual MS Result

Actual MS CSU

Known j Result Error

i

1.60E-01 I 8.65E+00 f

! 4.00E+00 \ 1.96E+02

Sample Result

Sample CSU

-···-·-i--------

Replicate Sample

Analyte Normalized I RPO

Original I Original Replicate Replicate LCS Relative I LCS%R

Difference Result I CSU Result CSU Bias ,

I

TOTAL U 0.11 I 2.47 I 4.23E+00 1.32E+00 ! 4.12E+00 I 1.28E+00 I 1.08 OK

Version

I


Client Name


CSU

2.69E+00

6.10E+01

Sample Aliquot

Standard ID

LCS-L

LSC-H

Standard ID

Standard ACT(dpm)

8.00E+00

2.00E+02

Standard Cone

QC Summary

MS%R MSND

Standard Error

1.60E-01

4.00E+00

Standard Error%

Rep RPO

NA

Standard Added (g)

1.00E+00

1.00E+00

Standard Added (g)

Rep ND

OK

0063

Eberline Services Analysis Control Chart

WO

18-03110

130.00

120,00

110.00

100.00

90.00

80.00

Analysis Run Activity Units

KPA_LIQ 1 ug

LCS % Recovery

70.00 +-------------------~---------+--------~ TOTAL U TOTAL U (LCS-H)

- Lower Error 75.01 64.92

- Upper Error 141.28 131.16

• o/oR 108.14 98.04 -- -LCL 75 75

---Mean 100 100 • - -UCL 125 125


3.50

3.00 ----2.50

2.00

1.50

1.00

0.50

0.00 LCS ND REP ND MSND

0.00 0.11 0.00

0.00 0.00 0.00

•UCL 3 3 3

Version

Aliguot Units

40.00

35.00

30.00

25.00

2000

15.00

10.00

5.00

0 00

Lower Error

u er Error

RPD

CL

Printed: 4/12/20181:12 PM Page 2 of 2

Client Name


Replicate Sample RPD

• TOTAL U

2.85

2.08

2.47

35

No Matrix Spike

0064


• 0

18-03110

Analyte

TH-228

TH-230

TH-232

Analyte

Analyte

TH-228

TH-230

TH-232

Version

Analysis

ThlSO

LCS CSU Measured Measured

121.11% 21.04%

123.56% 22.13%

120.87% 20.80%

Normalized MS Actual Expected Difference %Rec MS Result

Duplicate Results

Normalized RPD

Original

Difference Result

0.61 239.02 3.44E-03

0.93 55.41 2.83E-01

0.45 437.75 -5.87E-03

Run Activity Units Aliquot Units

1 pCi I


LCS Uncert. Known

Known Result

Expected Expected Error

100.00% 3.60% 4.S0E+00 1.73E-01 5.81E+00

100.00% 2.70% 5.37E+00 1.45E-01 6.64E+00

100.00% 3.60% 4.S0E+00 1.73E-01 5.S0E+00

Matrix Spike

Expected Actual Actual Sample Sample

MSUncert MS Result MS CSU Result CSU

I Original Duplicate Duplicate LCS Relative I

LCS%R CSU Result CSU Bias

1.14E-01 -3.87E-02 7.03E-02 1.21 OK

2.02E-01 1.S0E-01 1.61E-01 1.24 OK

6.64E-02 1.58E-02 6.57E-02 1.21 OK


Client Name


CSU Standard Standard

I Standard Standard

ID ACT(dpm) Error Added (g)

1.22E+00 Th-Sb 1.04E+02 3.60E+00 1.03E-01

1.47E+00 Th-1b 2.35E+01 2.70E+00 5.07E-01

1.21E+00 Th-Sb 1.04E+02 3.60E+00 1.03E-01

Sample

I Standard Standard

I Standard Standard

Aliquot ID ACT(dpm) Error% Added(g)

QC Summary

I I MS¾R I MSND I RepRPD I Rep ND

NA OK

NA OK

NA OK

0065


• 18-03110

130.00

120.00

110.00

100.00

90.00

80.00

Analysis Run

ThlSO 1

LCS % Recovery

~------] UCL

l

1000 ------------ - LCL

TH-230 TH-232 TH-228

- Lower Error 96.47 98.73 96.47

- Upper Error, 145.76 148.39 145.28

• %R 121.11 123.56 120.87

--LCL 75 75 75

--Mean 100 100 100

- -UCL 125 I 125 125


3.50

3.00

2.50

2.00

1.50

1.00

0.50

0.00 I LCSND

-TH-228. 0.00 0.61

MSND

0.00

=TH-2301 0.00 0.93 0.00

- UCL I 3 3 3

Version

Activity Units

pCi

40.00

35.00

30.00

25.00

20.00

15.00

10.00

5.00

Ali_guot Units

Printed: 3/30/2018 11 :55 AM Page 2 of 2

Client Name



------1-------

0.00 +------~-------------------------------~ TH-228 TH-230 TH-232

- LowerError -387.38 78.07 3366.24

- UpperError 865.42 32.75 -2490.73

• RPO 239.02 55.41 437.75

- -CL 35 35 i 35

No Matrix Spike

0066

Eberline Analytical


18-03110

Analyte

RA-226

Analyte

Analyte

RA-226

Version


Analysis

Ra226

LCS Measured

98.94%

MS Actual ¾Rec

CSU Measured

25.25%

Expected MS Result

Duplicate Results


0.27

RPD

21.16

Original Result

1.47E-01

Printed: 4/3/2018 7:07 AM

Page 1 of2

Run Activity Units Ali_g_uot Units Client Name

1 pCi


LCS Expected

100.00%

Expected MS Unce,t

Original CSU

1.33E-01

Uncert. Expected

4.60%

Known

1.00E+01

Known Error

4.61E-01

Matrix Spike

Actual MS Result

Duplicate Result

1.19E-01

Actual MS CSU

Sample Result

Duplicate I LCS Relative

CSU Bias

1.56E-01 0.99


Result CSU

9.91E+00 I 2.50E+00

Sample CSU

Sample Aliquot

Standard ID

Ra-5b

Standard ID

Standard I Standard

ACT (dpm) Error

4.40E+01 I 4.60E+00

Standard ACT(dpm)

Standard Error%

QC Summary

LCS¾R MS¾R MSND RepRPD

OK NA

Standard Added (g)

5.06E-01

Standard Added(g)

Rep ND

OK

0067


WO

18-03110

130.00

120.00

110.00

100.00

90.00

80.00

Analysis

Ra226

LCS % Recovery

70.00 RA-226

- Lower Error 69.09

- Upper Error 128.80

• %R 98.94

- -LCL 75

--Mean 100

--UCL 125


Run

1

3.50 --------------------------------

3.00 +------------~-------------------

2.50 +--------------------------------

2.00 +--------------------------------

1.50 +--------------------------------

1.00 +--------------------------------

0.50 +--------------------------------

O.OO I LCS ND REP ND MS ND

-RA-226I 0.00 0.27 0.00

- UCL 3 3 3

Version

Activity Units

pCi

40.00

35.00

30.00

25.00

20.00

15.00

10.00

5.00

Ali_g_uot Units


Client Name



o.oo RA-226

- LowerError 32.66

- UpperError 9.67

• RPD 21.16

- -CL 35

No Matrix Spike

0068

Eberline Analytical


WO • 18-03110

Analyte

RA-228

Analyte

Analyte

RA-228

Version


Analysis

Ra228

LCS Measured

94.01%

MS Actual %Rec

CSU Measured

24.20%

Expected MS Result

Duplicate Results


2.80

RPD

144.60

Original Result

1.49E-01

Printed: 4/9/2018 1 :57 PM Page 1 of 2

Run Activity_ Units Ali_guot Units Client Name

1 pCi


LCS Expected

100.00%

Expected MS Uncert

Original CSU

3.38E-01

Uncert. Expected

5.10%

Known

8.96E+00

Known Error

4.57E-01

Matrix Spike

Actual MS Result

Duplicate Result

9.25E-01

Actual MS CSU

Sample Result

Duplicate I L CS Relative

CSU Bias

4.27E-01 0.94


Result CSU

8.43E+00 I 2.04E+00

Sample CSU

Sample Aliquot

Standard ID

Ra-12

Standard ID

Standard I Standard

ACT (dpm) Error

5.62E+01 I 5.10E+00

Srandard ACT(dpm)

Srandard Error%

QC Summary

LCS%R MS%R MSND RepRPD

OK NA

Standard Added (g)

3.54E-01

Srandard Added(g)

Rep ND

OK

0069


WO •

18-03110

130.00

- Lower Error

- Upper Error

• %R

- -LCL

--Mean

- -UCL

3.50

3.00

2.50

2.00

1.50

1.00

0.50

0.00 LCS ND

-RA-228 0.00

- UCL 3

Version

Analysis

Ra228

LCS % Recovery

.

RA-228

64.71

123.31

94.01

75

100

125


REP ND

2.80

3

Run Activity Units

1 pCi

"IU.UU

35.00

30.00

25.00

20.00

15.00

10.00

5.00

0.00

- Lower Error

i - Upper Error

• RPD

--CL

MSND

0.00

3

Aliguot Units


Client Name



RA-228

196.08

93.13

144.60

35

No Matrix Spike

0070


WO • 18-03110

Analyte

GROSS ALPHA_ TH

GROSS BETA_SR

Analyte

Analyte

GROSS ALPHA_TH

GROSS BETA_SR

Version

I

Analysis

GaGbT_ThSr


LCS I Measured

115.57%

101.91%

MS Actual %Rec

CSU Measured

11.00%

13.86%

Expected MS Result

Duplicate Results

Normalized RPD

Original

Dffference Result

1.01 41.05 4.25E+00

Run Activity Units Ali_g_uot Units

1 pCi


LCS Expected

100.00%

100.00%

Expected MS Uncert

Original CSU

2.02E+00

Uncert. Known Expected

4.30% 2.68E+02

3.00% 2.77E+02

Matrix Spike

Actual MS Result

Duplicate Result

2.S0E+00

Actual MS CSU

Duplicate CSU

1.97E+00

I

Known Error

1.15E+01

8.30E+00

Sample Result

LCS Relative I Bias

1.16 I

Result

3.10E+02

2.82E+02

Sample CSU

LCS¾R

OK

1.00 13.79 I 1.69E+01 I 3.29E+00 I 1.95E+01 3.64E+00 I 1.02 I OK

I

I

I


Client Name


CSU

3.41E+01

3.91E+01

Sample Aliquot

Standard ID

A/B-07

A/B-07

Standard ID

Standard ACT(dpm)

5.94E+02

6.12E+02

Standard ACT(dpm)

QC Summary

I MS¾R I MSND

I I

I I

I

I

Standard Error

4.30E+00

3.00E+00

Standard Error¾

RepRPD

NA

OK

I

I

I

Standard Added(g)

1.00E+00

1.00E+00

Standard Addecl(g)

Rep ND

OK

OK

0071


• 0

18-03110

130.00

120.00

110.00

100.00

90.00

80.00

70.00 I - Lower Error

- Upper Error

• o/oR

- -LCL

--Mean

--UCL

3.50

3.00

2.50

2.00

1.50

1.00

0.50

000

- GROSS ALPHA TH = GROSS BETA SR

= - UCL

Version

Analysis Run

GaGbT ThSr 1

LCS % Recovery

1--------- I [ __ 1

GROSS ALPHA TH GROSS BETA_SR

100.28 85.05

130.87 118.77

115.57 101.91

~ ~

100 100

125 125


LCSND MSND

0.00 1.01 0.00

0.00 1.00 0.00

0.00 0.00 0.00

3 3 3

Activity Units Aliquot Units

pCi

40.00

35.00

30.00

25.00

20.00

15.00

10.00

5.00


Client Name



}------------

i

o.oo +1-----G-R_O_S_S_A_L_P_H_A_-T_H ___________ G_R_O_S_S_B_E_TA ___ S_R-----~

- LowerError 52.64 15.11

- UpperError 29.45 12.48

• RPO 41.05 13.79

--CL ~ ~

No Matrix Spike

0072

SECTION VII

LABO RA TORY TECHNICIAN'S NOTES & RUN LOGS

0073

ISOUNOTES

0074

Printed: 3/28/2018 9:19 AM

a,~EBERLINE ~ SERVICES

Work Order Analysis Notes

# Date Dept User

1 03/28/18 09: 19 PREP JHARVEY


601 Scarboro Rd. Oak Ridqe, TN 37830 Voice: 865,481.0683 www.eberlineservices.com

Page 1 of 1

Notes

AUQUOTED AND ADDED $PIKES AND TRACERS- DRll:D SAMPLES DOWN AND SUBMITTED

SAMPLES TO SEPARATIONS

0075


( Oak Ridge Laboratory Internal Work Order 18-03110 601 Scarboro Rd. --.. ---·•-Oo~,. _______ .,,

EBER~~~!=; Oak Ridge, TN 37830 Analysis Code UUISO Voice: 865.481.0683

Work Order Analysis Notes .. ••-'-'••·•-., ... www.eberlineservices.com Run Number 1

# I Date Dept I User Notes '

1 03/28/18 09: 19 PREP JHARVEY ALIQUOTED AND ADDED SPIKES AND TRACERS- DRIED SAMPLES DOWN AND SUBMITTED

SAMPLES TO SEPARATIONS ,·-···-- ···-----··----

2 03/29/18 15: 17 CHEM JDEMELAS Added concentrated HCI to sample beakers and heated to dryness; Added 20 ml 8N HCL to samples and

transferred to new, labeled C-Tubes, rinsing with 8N HCI to bring volume to ~35 ml; Preconditioned resin

columns with 35 ml 8N HCI; Centrifuged samples and loaded onto columns; Rinsed C-Tubes with 20 ml 8N

HCI, centrifuged as needed and loaded onto columns; Rinsed columns with 35 ml 8N HCI - 0.1 N NH41, 35 ml

of 6.5N HCI- 0.04N HF, and 10 ml of 6.5N HCI; Eluted Uranium with 50 ml of 0.5N HCI into clean, labeled 100

ml beakers; Dried-down samples on hotplate; Dissolved samples in ~10 ml of concentrated HCI; Transferred to

new, labeled C-Tubes with DI H2O. Set samples aside for later precipitation and filtering.

0076

Printed: 3/30/2018 4:51 AM

(EBER~~~~ Work Order Analysis Notes

# Date Dept User

1 03/28/18 09: 19 PREP JHARVEY

2 03/29/18 15: 17 CHEM JDEMEL.AS

3 03/30/18 04:51 CHEM TSMITH


601 Scarboro Rd. Oak Ridge, TN 37830 Voice: 865.481,0683 www.eberlineservices.com

Internal Work Order

Analysis Code

Run Number

Notes

Page 1 of 1

18-03110

UUISO 1

ALIQUOTED AND ADDED SPIKES AND TRACERS- DRIED SAMPLES DOWN AND SUBMITTED


Added concentrated HCI to sample beakers and heated to dryness; Added 20 ml 8N HCL to samples and

transferred to new, labeled C-Tubes, rinsing with 8N HCI to bring volume to ~35 ml; Preconditioned resin

columns with 35 ml 8N HCI; Centrifuged samples and loaded onto columns; Rinsed C-Tubes with 20 ml 8N

HCI, centrifuged as needed and loaded onto columns; Rinsed columns with 35 ml 8N HCI - 0.1 N NH4I, 35 ml

of 6.5N HCI - 0.04N HF, and 10 ml of 6.5N HCI; Eluted Uranium with 50 ml of 0.5N HCI into clean, labeled 100

ml beakers; Dried-down samples on hotplate; Dissolved samples in ~1 O ml of concentrated HCI; Transferred tc

new, labeled C-Tubes with DI H2O. Set samples aside for later precipitation and filtering.

Followed steps 12.1.7 to 12.4.5 in AP-005. ( Precipitated and filtered samples for Uranium}

0077

Eberline Analytical


Q EBERLINE .® ·············································-·················siRv1-c·is

Reagents Used in an Analysis

Reagent Reagent

ID Name

017230P Anion Exchange Resin -·~•~·--·- -·-·····-·--··---·····--~-

019826S HCI - HF -- . --·--·····-· ----·~·-

019775D02 Hydrochloric Acid

019827S Hydrochloric Acid -~-...... __.., •><••--·-····

019842S Hydrochloric Acid

Reagent


Internal Work Order

18-03110 Analysis Code Run

UUISO 1

Analyst Date

Concentration ID Recorded

Reagent Grade JDEMELAS 3/29/2018

6.5N - 0.04N JDEMELAS 3/29/2018

0.5N JDEMELAS 3/29/2018

6.5N JDEMELAS 3/29/2018 ·=···----·-·-·--

SN JDEMELAS 3/29/2018 ···-·-••,.-····--·~·-·~· ···-•-•>•--·

019861S HCI - NH41 SN - 0.1M JDEMELAS 3/29/2018 -·--···--·-··-·-----.,~··· . ----·--------·~···· ··-·--·-~

019831P Hydrochloric Acid Reagent Grade JDEMELAS 3/29/2018 ~•w•-~•--••'"--•-

-••m•-•----

019803S Carbon substrate Solution TSMITH 3/30/2018

019525P Hydrofluoric Acid Reagent Grade TSMITH 3/30/2018

···-·- ·-·--· _______ ,. __ ~·····-• --•--•••••••••--••••-•~•••••M•-•••-~•••-' •

019640S Neodymium Carrier 1 mg/ml TSMITH 3/30/2018

··-··. ---·--·~•>••·-------

019599P Reagent Alcohol Reagent Grade TSMITH 3/30/2018 __ " ___ .,, _____________

019433P Titanous Chloride Reagent Grade TSMITH 3/30/2018

0078

;

A-\ehc"- ·-. _S

- . --- 67 -·----...__ 001:\-e,... $c~111-t-:>le.,, tr l'Ji'e'.i'lt lor1)._ fi,Me,. Co1J;1fJ;\i,1t~ Arw,1~ ·"f:Lc~

, -1,)h; 1 t1o·~, ei \ \'\ l t--t) u (_f::,:{I._ ' l l'-'S-<"' ~o-, ~v,:v-r~ \Ll2 --~------ C

~Gtc\£i -I L~~~~1~UM,A ~'i\ 'i.-\:L\J ;lf'\v!S)..:__ ~ .

',,, ·,,

UG""I'- /JO - . -Ii-- -- \,,~, +_[;j-(3/t; 101--lci\ l\29 J,-\\.,-0\)....,;; I

~ti) -.. ·. •.

-------------. <;:;,_l,26 ·~ UI.J::::, {l ,~~])'\) ------- t J 6d1(ci A __ {JI 4) Yuzi.i·z_ - ••• >

---------- 2/JQfJ_f/;_ UtrJP- 1-SZlf (.,.,h -SV/0(6'1 KP' -7/'3o[l8 lBP3ll& /+( \-4) U(D\K, t')Zi' uu V,P ·-

·,·,

--- 7.J,1 S-6 fill I fl -")/30/lB / 80lli O A LL1i2 rsi& 'lht;61v1( ~'l !lU xP

. ·-

/V\O ·.,,

·-

3 l:3dlf'l ___ l~ C?:, l l_u_11__C::) -~ y ) tA.>Y'f\;0 l'3tS'1- (.J-1~1)·-_;. \(1-;, ·- ·._, ...

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--~·--··-·-

0079

TOTUNOTES

0080

#

1

Printed: 4/12/2018 1 :09 PM

~ E E:I E:: R L.,,J ....._. E:: ~ SERVICES

Work Order Analysis Notes

Date Dept User

04/12/18 13:09 PREP JPACHELLA


601 Scarboro Rd. Oak Ridge, TN 37830 Voice: 865.481.0683 www.eberlineservices.com

Internal Work Order

, ............................. ,. ............................... + Analysis Code

Run Number

Notes

Page 1 of 1

18-03110

Samples were aliquoted and wet ashed until clear. Samples were diluted. Dilution was aliquoted and mixed

with Uraplex. Samples were analyzed by KPA. Samples demonstrated intensities within the calibration range.

q f/ r;.~/r _,. .. / ye:cA-L-L(_,('_,

0081

Eberline Analytical Oak Ridge Laboratory

EBERLINE sic::RvtcEs


Reagent ID

Reagent Name

018695P Hydrogen Peroxide ,,,,,,,,-,,,,,,,,,,,, ____ ,,,,,, ,_,,,

019318D01 Nitric Acid ,,,,,,,,,,,,,,,,,,,

019436P Nitric Acid

019079P Uraplex


Internal Work Order

18-03110 Analysis Code

KPA_LIQ

0.3

0.8N

Reagent Concentration

Reagent Grade

Reagent Grade

Analyst ID

JPACHELLA

,,,,,,,,,,,,,,,,,_, __ ,,,_,_,,,_,,,,,,/,,,,,,,,,,,,,,,,,,,,,,,

0082

ISO TH NOTES

0083


-~ . . Oak Ridge Laboratory Internal Work Order 18-03110 ~EBERLINE 601 Scarboro Rd. V-N--•--,-~~•·----- --•--••-•-•••-•••M•-•-•-•-- ss~-

.. SEHYICES Oak Ridae, TN 37830 Analysis Code ThlSO Voice: 865.481.0683

Work Order Analysis Notes ... --··- . ···-· ··-----·-··--···-··-·· ---·--·-,-~

www.eberlineservices.com Run Number 1

# Date Dept User Notes

1 03/28/18 09: 19 PREP JHARVEY ALIQUOTED AND ADDED SPIKES AND TRACERS- DRIED SAMPLES DOWN AND SUBMITTED


0084

Printed: 3/29/2018 3:18 PM

(l:'.BERh~~c~ Work Order Analysis Notes

II Date Dept User

1 03/28/18 09: 19 PREP JHARVEY

2 03/29/18 15:18 CHEM JDEMELAS


601 Scarboro Rd. Oak Ridge, TN 37830 Voice: 865.481.0683 www.eberlineservices.com

Internal Work Order

Analysis Code

Run Number

Notes

Page 1 of 1

18-03110

ThlSO 1

ALIQUOTED AND ADDED SPIKES AND TRACERS- DRIED SAMPLES DOWN AND SUBMITTED


Added concentrated HNO3 to sample beakers and heated to dryness; Added 20 ml 8N HNO3 to samples and

transferred to new, labeled C-Tubes, adding 8N HNO3 to bring volume to ~35 ml; Preconditioned resin

columns with 50 ml 8N HNO3; Centrifuged samples as needed, and passed through columns; Rinsed C-Tubes

with 20 ml 8N HNO3; Centrifuged rinsates and loaded onto columns; Rinsed columns with 40 ml 8N HNO3;

Eluted Thorium with 50 ml of 8N HCI into clean, labeled 100-ml beakers; Dried-down samples on hotplate;

Dissolved samples in ~10 ml of concentrated HCI; Transferred to new, labeled C-Tubes with deiononized

water, bringing volume to ~15ml. Set sam12les aside for later 12reci12itation and filterina.

0085

Printed: 3/30/2018 4:53 AM

,: E B E R ~ ~!;':10

!;';; Work Order Analysis Notes

# Date Dept User

1 03/28/18 09: 19 PREP JHARVEY

2 03/29/18 15:18 CHEM JDEMEl..AS

3 03/30/18 04:53 CHEM TSMITH


601 Scarboro Rd. Oak Ridge, TN 37830 Voice: 865,481.0683 www.eberlineservices.com

Page 1 of 1

Internal Work Order 18-03110 t--••-----~--------------•-~"•w-

Analysis Code Th I SO Run Number 1

Notes

ALIQUOTED AND ADDED SPiKES AND TRACERS- DRIED SAMPLES DOWN AND SUBMITTED


Added concentrated HNO3 to sample beakers and heated to dryness; Added 20 ml 8N HNO3 to samples and

transferred to new, labeled C-Tubes, adding 8N HNO3 to bring volume to ~35 ml; Preconditioned resin

columns with 50 ml 8N HNO3; Centrifuged samples as needed, and passed through columns; Rinsed C-Tubes

with 20 ml 8N HNO3; Centrifuged rinsates and loaded onto columns; Rinsed columns with 40 ml 8N HNO3;

Eluted Thorium with 50 ml of 8N HCI into clean, labeled 100-ml beakers; Dried-down samples on hotplate;

Dissolved samples in ~10 ml of concentrated HCI; Transferred to new, labeled C-Tubes with deiononized

water, bringi!!_g volume to ~15ml. Set samples aside for later precipitation and filtering.

Followed steps 12.2.5 to 12.4.5 in AP-005. ( Precipitated and filtered samples for Thorium)

0086



Reagent Reagent

ID Name

017230P Anion Exchange Resin


Internal Work Order


ThISO


Reagent Grade

Analyst ID

JDEMELAS

Run

1 Date

Recorded

3/29/2018 -···-···············-----····· --~·-·"'--·--·---·····--·~-.. ~~---- ·---·"

019842S Hydrochloric Acid SN JDEMELAS 3/29/2018

019831P Hydrochloric Acid Reagent Grade JDEMELAS 3/29/2018 -<--<-~••--"'-=M= ···················-···-···-

019859S Hydrochloric Acid 8N JDEMELAS 3/29/2018 -..... •·-----,--~---.. ---·~·-·-·

019673P Nitric Acid Reagent Grade JDEMELAS 3/29/2018

019860S Nitric Acid SN JDEMELAS 3/29/2018

019803S Carbon substrate Solution TSMITH 3/30/2018

019578S Cerrium Carrier 0.lmg/ml TSMITH 3/30/2018 -~~---·-----.-·-·~·~

019525P Hydrofluoric Acid Reagent Grade TSMITH 3/30/2018

019599P Reagent Alcohol Reagent Grade TSMITH 3/30/2018 •- ~ --•••-•u-.-w --•--H•ll--••-

0087

0088

RA-226 NOTES

0089

Printed: 3/28/2018 9:27 AM

~ E;:BERh~!;:Jc~ · Work Order Analysis Notes

# Date Dept User

1 03/28/18 09:27 PREP JHARVEY .


601 Scarboro Rd. Oal< Ridae, TN 37830 Voice: 865.481.0683 www.eberlineservices.com

Page 1 of 1

Internal Work Order 18-03110 Analysis Code Ra226

---·-------------------·----Run Number 1

Notes

ALIOUOTED AND ADDED SPIKES AND TRACERS- PH'D SAMPLES- PRECIPITATED WITH BA AND PB

CARRIERS AND AMMONIUM SULFATE- DECANTED SAMPLES AND CENTRIFUGED- SUBMITTED

RADIUM PRECIP TO SEPARATIONS

0090


,: Oalc Ridge Laboratory Internal Work Order 18-03110 601 Scarboro Rd. ,. ____ ,. __

~• -----• •-w~--•--H• •••- ••-----•- ---EBER~~~c~ Oak Ridge, TN 37830 Analysis Code Ra226

Work Order Analysis Notes Voice: 865.481.0683 ·-.

www.eberlineservices.com Run Number 1

# Date Dept User Notes

1 03/28/18 09:27 PREP JHARVEY ALIQUOTED AND ADDED SPIKES AND TRACERS- PH'D SAMPLES- PRECIPITATED WITH BA AND PB



2 04/02/18 15:07 CHEM EBAILEY ADDED EDTA TO SAMPLES AND LET SIT. ADDED AMMONIUM SULFATE AND ACETIC ACID TO

SAMPLES. FILTERED ONTO TARED FILTER PAPERS, LET DRY UNDER HEAT LAMP, REWEIGHED,

ANn "'' 11:a.,TT<=l"I Tn r-rn 1NT.

0091


. . -~ $'"¼ - I:;: ae:: .. R .. k-J .....,. e:: ~

SERVICES

Reagents Used in an Analysis -~~-~,,~-

Reagent Reagent ID Name

019782P Ammonium Hydroxide

019713D03 Ammonium Sulfate

019792D01 Barium Carrier -

019464D01 Lead Carrier

019673P Nitric Acid

019210P Acetic Acid -·

019065D02 Ammonium Sulfate

019226S EDTA

Reagent

Printed: 4/2/2018 3: 54 PM Page 1 of 1

Internal Work Order

18-03110 Analysis Code Run

Ra226 1 Analyst Date


Reagent Grade JHARVEY 3/28/2018

200 mg/ml JHARVEY 3/28/2018



Reagent Grade JHARVEY 3/28/2018

Reagent Grade EBAILEY 4/2/2018

200 mg/ml EBAILEY 4/2/2018

0.25M EBAILEY 4/2/2018

0092

s .. · •Cb·i.•·•·(';c > ...•.. ; \ ..

A--\~h°' 3 . ...:::, 67 ----

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-

ll w'I"- ll\5-.~--- cll/4o, ~v~?.J-r'J \LI)

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_ID~ V~u- ~ 1\ \j,G-.,.\L \\,rt,~ AJo f / (J~ - ~~ULL · . -:_--_:t

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\. l SJ,::, .. l\._,,,, __ ~ ~--- 7)--\ # ----- _]}30/25_ U3ciitci J+ (31f:i'> UfQR.. a ;zl( 0 h ~-cfll!( 6'1

·l'""', lt[l. KP --

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1fsoho UCD\R l>Z~ 1,);1 S--0 !1111 ~1 _lLU V,P -

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:;/30/t8 l863J19A 61 i2 AMo t)Zl .. , 'l f1 ~M [ ~1 uu XP --

e~tl_ li,~_2Lln.il.~)--"-t ) ,w_y_'{\J:J l>G'1- ~t'6:D~ lCP -

l LL,{

~,.\ ?)-ki,~C1kcA-II . I lc/3 -

§1_\L~ l-0...Jv:.,1 lli.50_ l!;,,'i\J hr." d-

Y/L/18 ·rx; \ i ¥ RJ l i;1// 1 _c1.:b os-1° I C1tvu>1 f\lr.:,._ Y\P -

!Jiwa_ Jt6o3/z&A-( 1-'-i) U(D/( ci'll..-:f- -fJl 13"0""1, '.1 tP -. uu

11 I ·z_ A 8 t fb··3rzli A-(1 -L\J ~ll~ ,~1\i 11. ef+Zo -;-, XP --

zh s1',,,,1, ·11 1-11

-'1L?J18. \66-SI zq A-(!;J) \ 0 '),.? 17v --

- 5~y /VJi-fll . 2J,, ~-0111.;~,J KP"

jji/J 8 I '3o ~ lsz A (1 -'-0 (<c,,,.__ ,.

- us io3& i --Z-h S"'t?t-n /,1 t:,,P

l//t,.,/( 6 lt'X'fSl~A u 1 'D tifof:.. \D)~~ 'Z✓h St:'1ii11~11 JGP --

uu lf /;Zll6 1f2Q~~&AL1 -rs) 5015 f\h,r+h t zs--1 t(cr.._ KP

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~{L fb?__ b.l-~3-~~!t>-~\.-~

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5'.;,SJ~ .. 1-\-~~ _\uc+ ;2,\,.~t) -J.

~l1,, n \1>tJ'3 \ \0~L,-1':) fJ.ryv\,\) ~h,,;:so ....I- 2t»"¼ .• \l!J ---

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0093

RA-228 NOTES

0094

Printed: 3/28/2018 9:28 AM

,: E BER!;;:,ls~c~

Worlc Order Analysis Notes

# Date Dept User

1 03/28/18 09:28 PREP JHARVEY


601 Scarboro Rd. Oak Ridqe, TN 37830 Voice: 865,481.0683 www.eberlineservices.com

Internal Work Order

Analysis Code

Run Number

Notes

Page 1 of 1

18-03110 Ra228

1

ALIQUOTED AND ADDED SPIKES AND TRACERS- PH'D SAMPLES- PRECIPITATED WITH BA AND PB



0095

Printed: 4/9/2018 11 :27 AM

(EBER~~~c!=,; Work Order Analysis Notes

# Date Dept User

1 03/28/18 09:28 PREP JHARVEY

1,.,.--~---· --2 04/09/18 11 :27 CHEM EBAILEY

Oalc Ridge Laboratory

601 Scarboro Rd. Cale Ridge, TN 37830 Voice: 865.481.0683 www.eberlineservices.com

Internal Work Order

Analysis Code

Run Number

Notes

Page 1 of 1

18-03110

Ra228 1

ALIQUOTED AND ADDED SPIKES AND TRACERS- PH'D SAMPLES- PRECIPITATED WITH BA AND PB



ADDED FILTER PAPERS FROM COUNT ROOM TO LABELED C-TUBES, FILLED WITH EDTA SOLUTI-OtT

AND LET SIT OVERNIGHT. REMOVED FILTER FROM EDT A-ADDED 2MLS YTTRIUM 9MG/ML CARRIER

ADDED 18N NAOH TO SAMPLES AND RECORDED T1. HOT BATHED FOR 15 MIN, CENTRIFUGED AND

DISCARDED SUPERNANT. ADDED 6N HNO3, DI WATER, AND 10N NAOH. HOT BATHED FOR 15 MIN,

CENTRIFUGED AND DISCARDED SUPERNANT. ADDED 1 N HNO3, DI WATER, AND AMMONIUM

OXALATE. FILTERED ONTO TARED FILTER PAPERS. LET DRY UNDER HEAT LAMP, REWEIGHED AND

SUBMITTED TO COUNT.

0096


Q EBERLINE _@ ....... ············· ........ SERv1cEs


Reagent ID

................................................ , .......... - ........ , ... _. __ _ Reagent

Name



Ra228


Analyst ID

Run

1 Date

Recorded

019782P Ammonium Hydroxide Reagent Grade JHARVEY 3/28/2018 · ............ ..................... ......................... ---1 .......................... - ....... _____ 1------............................ f

019713D03 Ammonium Sulfate 200 mg/ml JHARVEY 3/28/2018 .......................... _, ......... - ............. -+--~-----·-···~-------~----·----------·-----~--.... -, ................................................. ..

019792D01 Barium Carrier 1 mg/ml JHARVEY 3/28/2018

019464D01 Lead Carrier 166 mg/ml JHARVEY 3/28/2018 ................ + .......................................... _________________________ .... _+-_

019673P Nitric Acid Reagent Grade JHARVEY 3/28/2018 _____ ____, ....

018122D04 Ammonium Oxalate 5% EBAILEY 4/9/2018 ---

019226S EDTA 0.25M EBAILEY 4/9/2018 -- -·- ·------·•-"-" _____ _,

018971D06 Nitric Acid lN EBAILEY 4/9/2018 .........................

019673D02 Nitric Acid 6N EBAILEY 4/9/2018 .... ,.,_ ........................................ .

018699D10 Sodium Hydroxide lOM EBAILEY 4/9/2018 .... , ........................... , ..

018699D07 Sodium Hydroxide 18M EBAILEY 4/9/2018

0097

--·-···-- ·----- -----·--l-·----------1-------~- ____ ____,_ __ ... ··,.

····-··--·-·-·-,----------'f-------~-------j-------t-----------f---------+-----c,,i.: .. ;

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··,,··•,

. ·-·-·--··•--t-------t-----------l------ ___ ___,__ ___ ·--·-···· --~····--·--··-------1··-··-------,,, ...... ,,

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·-···-- ----·-·---------,\---·-------·-·------•---~--------I

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·----··--·- ·-· _.,-•-·--····-··--···•)~---._ .. ___ -----+------ .---·-· -··---·---·····---····--····-··---··•---··-··-·· ---·---·- ·-·· ----··-----· ··-· ·--···-. --

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-- ----·····--····---.,,r-----_ ___ --------1-____ ________, ____ __.__ __ ----I---____ ....... -- ----·-··-·-,.-·-···-----·-·· --

--·----1---------+----·--··-·--·--·---------t-• -·- .. --···-·····-····--·-·-··- -- -·-······-----·--- , .. --

0098

ALPHA/BET A NOTES

0099

Printed: 3/27/2018 3:00 AM

~Ea E Rh~r:I!;;; Work Order Analysis Notes

# Date Dept User

1 03/27/18 03:00 PREP MHIGHTOWER


601 Scarboro Rd. Internal Work Order

Analysis Code

Page 1 of 1

18-03110

GaGbT ThSr Oak Ridge, TN 37830 Voice: 865.481.0683 www.eberlineservices.com

······-------+--------=------11 Run Nurnber 1

Notes

Ran TDS/TSS to determine aliquot. Aliquoted samples, dried, nitrated, transferred to tared planchets, dried,

flamed, re-weighed, and submitted to count room

0100


. . -~ Q EBERLINE _"'@ ......................... ···························· ......... SERvicEs


Reagent Reagent

ID Name ----~----·==-•--"=·--~

019074D01 Nitric Acid , .........

3N


Internal Work Order

18-03110 --·~·-

Analysis Code Run ·------

GaGbT _ThSr 1 ~~-·

Reagent Analyst Date


MHIGHTOWER 3/27/2018

0101

~G>8 P -=-----1--_c=.__--+-~~---i~"-l---------J--/-

c -:r, z y /( <

I---os V\,

~~-~~-~~6q~---+---'-~~~~-~~p__

,"---+~~-1-K p 'Cb

~~--=-4 ~~~~----1:~--l--~n&_------i-~~_J_t':r;g

, \lb

____ __c;c'-~--r---------',-----!-----+-------------!i:---------4------

0102

SECTION VIII

ANALYTICAL DAT A (ISOTOPIC URANIUM)

0103

Eberline Analytical


Analysis Sheet

Work Order

Analysis Code ~ UUISO 1

Date Received 3/23/2018

Lab Deadline 4/12/2018

Client I AMO Environmental Decisions

Project WESTLAKE

Report Level 4

Activity Units pCi

Aliquot Units

Matrix WA

Method EPA 908.0 Modified

Instrument Type Alpha Spectroscopy

Radiometric Tracer U-232

Radiometric Sol# U-10a

Tracer Act (dpm/g) 18.21

Carrier

Carrier Cone (mg/ml)

18-03110 UUISO Run 1

Printed: 313012018 4:58 AM

Page 1 of 3

I i i

Internal Sample [ Client Login i Sample Sample

Fraction Desc I ID CPM / Date Aliquot

~. 01 Les ~cs I 03123I1s 00:00 ~1.ooooE+oo

02 MBL BLANK · 03/23/18 00:00 1 1.0000E+00 I

I i

I

03 I DUP OU-1-008 38 I 03/19/18 18:02 : 5.0000E-01

- ! I

04 I DO OU-1-008 38 I 03/19/18 18:02 5.0000E-01 .

1

I 1

I I l~--------~

I i !

i I

I

1

!

I I

J--------"----f-------······ ... . +- I ' ··_ ·--__ _____,

* SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. A Indicates estimated SAF value.

** Actual mass exceeded the calibration curve range. Results should be qualified as appropriate.

0104

Eberline Analytical


Analysis Sheet

Internal Sample I Tracer

Fraction Desc I

Aliquot (g)

01 LCS 0.6058

02 MBL 0.6057

03 DUP 0.5941

04 DO 0.6001

I I

I

I I

I I

I Tracer Total I

Radiometric

ACT(dpm) Tracer (pCi) I

11.0 ~-·---

11.0 --~--

10.8

10.9


I R d. tr· : G C . ; a ,ome 1c rav arr,er

I % Rec i Added (ml) Grav Filter

Tare (g)

I 0.00 1

i !

I 0.00/ I

o.ooi I !

0.001 !

i !

! I I !

i i

I I I I

i I

I I

I

! Grav Filter Final (g)

I

• SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. ~ Indicates estimated SAF value.

•• Actual mass exceeded the calibration curve range. Results should be qualified as appropriate.

I Grav Filter Grav I Net (g) %Rec i

I I

I !

i i I I I i

!

I i

I

I I

I

j

I

I !

I I

Printed: 313012018 4:58 AM Page 2 of 3

Mean I SAF I SAF

I ! %Rec 1* 2· i

I ~ ..

-·-··-~

I

0105


Analysis Sheet

Internal [ Sample

Fraction I Desc

01 LCS

02 MBL

03 DUP

04 DO

Rough Prep Rough Prep

Date By

-

-

:

i

I

i I I

l

Prep I Date !

03/28/18 08:39

03/28/18 08:39

03/28/18 08:39

03/28/18 08:39

'

I


Prep By

JHARVEY

JHARVEY

JHARVEY

JHARVEY

I Sep to

I Date/Time

• SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. " Indicates estimated SAF value.


Sep tO I I

By I I

I

I

\

i

I

! -

;

Printed: 3/3012018 4:58 AM Page 3 of 3

Sep t1 Sep t1

Date/Time By

i

I I

0106


~ Lab Nuclide

Fraction

01 U-234

C: :::s ct:

.g 0 0 .!!!

i C: "'(

C: -!!! u

""'"

0 u, -::> ::>

1/) C: 0 "in ·c:; Q)

C cu -C: Q)

E C: 0 I,..

·s; C: w 0 :!:: ~

02 U-234

03 U-234

04 U-234

Sample Desc

LCS

MBL

DUP

DO

Preliminary Data Report & Analytical Calculations

Work Order: 18-0311 0-UUISO-1

Client Activity Results Error Estimate MDA

Identification Units

LCS pCi/1 6.06E+00 8.95E-01 6.70E-02

BLANK pCi/1 -9.93E-03 3.02E-02 8.24E-02

OU-1-008 pCi/1 1.17E+00 3.65E-01 1.52E-01

OU-1-008 pCi/1 1.06E+00 3.62E-01 1.48E-01

LCS I LCS

Known I ¾R

7.28E+00 83.21


LCS RPD MDA Blank

Flag Flag Flag Flag

OK OK

OK OK

OK OK

OK

0107

Eberline Analytical


( Lab Nuclide Fraction

01 U-234

§ a::

{: 8 .!!? ~

1a C: c:(

jl 0

~

0 u, -::, ::,

1/) C: 0 iii u (I)

C

Jg C: (I)

E C: 0 I..

·s;: C: w 0 ~ <

02 U-234

03 U-234

04 U-234

Sample Desc

LCS

MBL

DUP

DO


Work Order: 18-03110-UUISO-1

Sample I Sample Radiometric Grav Mean

Date I Aliquot %Rec %Rec %Rec

03/23/18 00:00 1.00E+00 114.68 0.00 0.00

03/23/18 00:00 1.00E+00 106.37 0.00 0.00

03/19/18 18:02 5.00E-01 110.03 0.00 0.00

03/19/18 18:02 5.00E-01 102.43 0.00 0.00

SAF SeptO

Date/Time


I Sept1

I Date/Time

0108

Eberline Analytical


( Lab Nuclide

Fraction

01 U-234

i:: ::, Q:

Cl)

"0 0 0 .!/? ~ cij i::

c:i:

II

~

0 en -::, ::,

II) C: 0

.!!? u Q)

C

.s C: Q)

E C: 0 ... ·s; C: w 0 :E <(

02 U-234

03 U-234

04 U-234

I Sample Desc

LCS

MBL

DUP

DO



Counting Halflife Detect Carrier Count

Counts

DatefTime (days) Time

03/30/18 13:25 A_Spec Alpha_057 170 4.33 E+02

03/30/18 13:25 A_Spec Alpha_058 170 -6.80 E-01

03/30/18 13:56 A_Spec Alpha_043 170 4.62 E+01

03/30/18 13:56 A_Spec Alpha_044 170 3.75 E+01

I Bkg CPM

2.00 E-03

4.00 E-03

5.00 E-03

3.00 E-03


Eff

16.5

17.1

19

18.4

0109

Eberline Analytical


<( Lab Nuclide Fraction

01 U-238

§ 0::

{: 0 0 .!/.! ~ iii c:: "(

~I

T""

0 u, -:::, :::,

1/) s::: .2 .!!! CJ Q)

C

Jg s::: Q)

E s::: 0 ... ·s;

s::: w 0 ::l!: <(

02 U-238

03 U-238

04 U-238

Sample Desc

LCS

MBL

DUP

DO



Client Activity Results Error Estimate MDA Identification Units

LCS pCi/I 6.13E+00 9.03E-01 6.67E-02

BLANK pCi/I -2.91E-04 3.09E-02 9.16E-02

OU-1-008 pCi/I 9.26E-01 3.18E-01 1.21E-01

OU-1-008 pCi/I 1.04E+00 3.59E-01 1.68E-01

LCS LCS

I Known %R

7.06E+00 86.91


LCS RPO MDA Blank

Flag Flag Flag Flag

OK OK

OK OK

OK OK

OK

0110


~ Lab I Nuclide

Fraction

01 U-238

s:::: ::, a:::

(I)

~ 0 u .!!! ~ "iii s:::: <t

11 u

~

0 u, -:::, :::,

U) C: 0

:!!? 0 Cl)

C

s C: Cl)

E C: 0 ... ·s: C: w 0 :E <(

02 U-238

03 U-238

04 U-238

Sample Oesc

LCS

MBL

DUP

DO



Sample Sample Radiometric

I Grav Mean

Date Aliquot %Rec %Rec %Rec

03/23/18 00:00 1.00E+00 114.68 0.00 0.00

03/23/18 00:00 1.00E+00 106.37 0.00 0.00

03/19/18 18:02 5.00E-01 110.03 0.00 0.00

03/19/18 18:02 5.00E-01 102.43 0.00 0.00

SAF I

SeptO OatefTime


I Sept1

OatefTime

0111


~ Lab Nuclide

Fraction

01 U-238

C: :, ll:

.g 0 (.)

.!!! ~ 'iij C: ,q;

~

~

T-

0 UJ -::, ::,

u, C 0

.!!? c., Q)

C

~ C Q)

E C 0 ... > C w 0 :!: <(

02 U-238

03 U-238

04 U-238

I I Sample

Desc

LCS

MBL

DUP

DO



Counting Halflife Detect Carrier Count

Counts

Date/Time (days) Time

03/30/18 13:25 A_Spec Alpha_057 170 4.40 E+02

03/30/18 13:25 A_Spec Alpha_058 170 -2.00 E-02

03/30/18 13:56 A_Spec Alpha_043 170 3.67 E+01

03/30/18 13:56 A_Spec Alpha_044 170 3.70 E+01

I Bkg CPM

2.00 E-03

6.00 E-03

2.00 E-03

0.00 E+00


Eff

16.5

17.1

19

18.4

0112


~ Lab Nuclide

Fraction

01 U-235

§ a:

.g 8 ,!!! II)

~ a, C: "(

--~ 0

~

0 en -::::, ::::,

U) s:: 0

.!!? c., Q)

C

.B s:: Q)

E s:: 0 11-·s: s:: w 0 :ii! <(

02 U-235

03 U-235

04 U-235

Sample Desc

LCS

MBL

DUP

DO



Client I Activity Results Error Estimate MDA

Identification I Units

LCS pCi/1 4.67E-01 1.87E-01 1.04E-01

BLANK pCi/1 5.76E-03 3.73E-02 1.02E-01

OU-1-008 pCi/1 1.14E-01 1.24E-01 1.S0E-01

OU-1-008 pCi/1 9.83E-02 1.19E-01 1.45E-01

LCS LCS

I Known ¾R


LCS RPD MDA Blank

Flag Flag Flag Flag

OK

OK OK

NA OK

OK

0113

Eberline Analytical


( Lab Nuclide

Fraction

01 U-235

§ a::

.g 0 u .!!,!

~ '"iii C: ct

~I

~

0

"' -::::, ::::,

ti) C: 0 ti)

·c:; Q)

0 iii -C: Q)

E C: 0 ... ·s; C: w 0 == <(

02 U-235

03 U-235

04 U-235

Sample Desc

LCS

MBL

DUP

DO



Sample Sample Radiometric Grav Mean

I Date Aliquot %Rec % Rec % Rec

03/23/18 00:00 1.00E+00 114.68 0.00 0.00

03/23/18 00:00 1.00E+00 106.37 0.00 0.00

03/19/18 18:02 5.00E-01 110.03 0.00 0.00

03/19/18 18:02 5.00E-01 102.43 0.00 0.00

I SeptO

SAF DatefTime


Sept1 DatefTime

0114



01 I U-235

C: :, a:

.g 8 .!!,!

~ ca C: q;

1: -!!! 0

T-

0 en -:::> :::>

1/) C: 0 ·;; ·c:; Cl)

C cu -C: Cl)

E C: 0 I-

> C: w 0 ::!!: <(

02 U-235

03 U-235

04 U-235

Sample Desc

LCS

MBL

DUP

DO



Counting Halflife Detect Carrier I

Count Counts


03/30/18 13:25 A_Spec Alpha_057 170 2.70 E+01

03/30/18 13:25 A_Spec Alpha_058 170 3.20 E-01

03/30/18 13:56 A_Spec Alpha_043 170 3.66 E+00

03/30/18 13:56 A_Spec Alpha_044 170 2.83 E+00

1 Bkg

I CPM

0.00 E+00

4.00 E-03

2.00 E-03

1.00 E-03


Eff

16.5

17.1

19

18.4

0115

Count Room Report Client: AMO Environmental Decisio

~E f' 11ntema~ \-sa~ple-\ Client

Fraction Desc I ID

01 LCS LCS

02 MBL BLANK

I 03 DUP OU-1-008

04 DO OU-1-008

18-03110-UUISO-1 (pCi/1) in WA

Tracer ID: U-1 0a

Sample

I Sample I Tracer

I Date Aliquot I

A/iquot(g)

03123118 00:00 I 1.0000 i 0.6058

03/23/18 00:00 I 1.0000 I 0.6057

03/19/18 18:02 I 0.5000 I 0.5941

03/19/18 18:02 0.5000 0.6001

: :

Tracer

I Radiometric

ACT(dpm) Tracer (pCi)

i 11.0316 I I

11.0298 I

10.8186

10.9278

:


I Radiometric-I SAF SAF

I %Rec I 1* 2*

I

0.00 . ' I i I I

0.00 !

0.00 r-----

0.00 -1 ----

I i i

l

•

I i i

I I

I I

t I _J___--i

-~---· -- ~- - -· 1-· - -- --- ~------·-----i·· -

!

:

I I )

I

:

I

1 I I

- I +-~-, ---,------1 !

r---L----~----------t-------i------

i i ,--7---i

. I

I

·----1= I i i I

I t----I !

I

I I ---

i r-·------------:

I I

----

l I ! !

0116

Eberline Analytical


Isotope I

So/# Activity

I dpmlg

U-234 I U-8a 32.000/

U-238 I U-8a 31.oool

fraction I

Isotope I So/# I 01 U-232 U-10a

02 U-232 U-10a

03 U-232 U-10a

04 U-232 U-10a

Version 2.0 08/99

Solution Approx Date Addition

3/28/2018 0.550

3/28/2018 0.550

Tracers Activity Solution

dpmlg Date

18.210 3/28/2018

18.210 3/28/2018

18.210 3/28/2018

18.210 3/28/2018

Spike and Tracer Worksheet

Analysis Code Date Technician

UUISO 3/28/2018 8:36 JHARVEY

LCS MS LCSD MSD LCS MS

Volume Volume Volume Volume

Used (g) Used(g) Used(g) Used (g) Known I Error Added I Error

I

pCi I Estimate pCi ! Estimate I

0.5053 I

oool 7.28/ 0.262 0.000 i

0.5053 7.061 0.254 oool 0.000

Balance Printer Tapes

Volume Approx Tracer Used (g) Addition

0.6058 0.6600

0.6057 0.6600

0.5941 0.6600

0.6001 0.6600

Page 1 of 1 Printed: 3/28/2018 8:39 AM

Witness Initials

LCSD -

MSD Known

I Error Added Error

pCi Estimate pCi Estimate

o.ooi 0.000 0.00 0.000

o.ooi 0.000 0.00 0.000

f I

LCS

Matrix Spike

0117


Lab I AMO Environmental Decisions

Fraction Client ID

01 LCS 02 BLANK 03 OU-1-008

04 OU-1-008

Comments

Analysis Code

UUISO

Sample Muffle Data Ratio

Type Post/Pre

LCS MBL DUP DO

Aliquot Worksheet

Rpt Units Lab Deadline

liters 4/12/2018

Dilution Data Aliquot Data

I No of Dils Oil Factor I Ratio Aliquot Net Equiv

1.0000E+OO 1.0000E+OO

1.0000E+OO 1.0000E+OO

5.0000E-01 5.0000E-01

5.0000E-01 5.0000E-01

Technician: ~~.3(&£(

Tech11ician

JHARVEY

MS Aliquot Data


H-3 Solids Only waterAaaea H30~

Aliquot Net Equiv (ml) Aliq

I

I

0118

~-~tlt'Apex-AI p ha™ Sample Description: Spectrum File: Batch Identification:

SPIKE \\OR-ALPHAl\Canberra\ApexAlpha\Root\Data\00002099

1803110A-UU

Sample Identification: Sample Geometry: Procedure Description:

Detector Name: Chamber Serial Number: Detector Serial Number: Env. Background: Reagent Blank:

Sample Size: Sample Date/Time: Acquisition Date/Time: Acquisition Live Time: Acquisition Real Time:

Tracer Certificate: Tracer Quantity: Effective Efficiency:

01 Shelf 2 U iso

Alpha_057 01017326A 57 System Bkgd 211478

<not performed>

l.000E+000 3/30/2018 3/30/2018

170.0

+/- 0.000E+000 liter 6:46:41 AM 1:25:57 PM

minutes 170.0 minutes

0.0110

Counting Efficiency:

U232 UU-l0A 0.606 mL 0.1895 +/-0.1653 +/-1.1468 +/-

0.0029 on 2/16/2018 0.0696

12:37:04 PM

Chem. Recovery Factor:

Control Certificate Name: NatU U-8A

Chem. Recov. of Control: U-238 0.764606 +/- 0.061860

Peak Match Tolerance: 0.150 MeV

Nuclide

U-232 T U-234 U-235 U-238

T =

Energy (MeV)

5.265 4.724 4.387 4.143

Tracer

PEAK AREA REPORT

Net Pk Area

352.66 432.66

27.00 439.66

Pk Area Error%

10.44 9.43

38.41 9.35

Ambient Backgnd

0.34 0.34 0.00 0.34

Reagent Backgnd

0.00E+000 0.00E+000 0.00E+000 0.00E+000

Peak used for Effective Efficiency

NUCLIDE ANALYSIS RESULTS

FWHM (keV)

29.2 28.3 4.5

46.5

Nuclide Id

Conf. Energy (keV)

Activity (pCi/liter )

MDA (pCi/liter

U-232 U-234 U-235 U-238

0.990 0.990 1.000 0.988

5302.50* 4761.50* 4385.50* 4184.40*

4.94E+000 6.06E+000 4.67E-001 6.13E+000

+/- 5.62E-001 +/- 8.95E-001 +/- 1. 87E- 001 +/- 9.03E-001

~ ef1Wrs

6.70E-002 +/- 7.62E-003 6.70E-002 +/- 7.62E-003 1. 04E-001 +/- l.18E-002 6.67E-002 +!- 7.59E-003

0119

60

55

50

45

40

35 V'l -I-' C :::,

8 30

25

20

15

10

5

0 I

3500 4000 4500

ROI Type: 1

0000209988.CNF

i /!

~ I

5000 Energy(kev)

5500

Live Time :10200.000 sec Real Time :10200.000 sec Start: 1:3442.S(keV) Stop : 1024:6481.S(keV) Acq. Start :Fri Mar 30 13:25:57 2018

6000

ROI Type: 3

0120

Channel Data Report 3/30/2018 4:51:44 PM Page 1

******************************************************* ***** s p E C T R A L DAT A R E P O R T ***** *******************************************************

Sample Title: 01

Elapsed Live time: 10200 Elapsed Real Time: 10200

Channell------l-------l-------l-------1-------1-------1-------I-------I 1: 0 0 0 0 0 0 0 0

9 : 0 0 0 0 0 0 0 0

17: 0 0 0 0 0 0 0 0

25: 0 0 0 0 0 0 0 0

33: 0 0 0 0 0 0 0 0

41: 0 0 0 0 0 0 0 0

49: 0 0 0 0 0 0 0 0

57: 0 1 0 0 0 0 0 0

65: 0 0 0 0 0 0 1 0

73: 0 0 0 0 0 0 0 0

81: 0 0 0 0 0 0 0 0

89: 0 0 0 0 0 0 0 0

97: 0 0 0 0 0 0 0 0

105: 0 1 0 0 0 1 0 1

113: 0 0 0 0 0 0 0 0

121: 0 0 0 0 0 1 0 1

129: 0 0 0 1 1 1 0 0

137: 0 0 0 0 1 0 0 0

145: 1 0 0 0 0 0 0 0

153: 0 0 0 0 0 1 0 0

161: 0 0 0 0 0 0 0 1

169: 1 2 0 0 0 0 1 0

177: 0 0 0 0 1 1 0 0

185: 1 1 2 1 2 2 0 1

193: 0 0 1 0 1 1 2 0

201: 0 0 2 2 1 0 3 0

209: 1 1 0 4 4 6 3 5

217: 0 5 6 6 1 4 4 4

225: 3 14 8 9 14 6 8 5

233: 6 16 16 10 9 13 13 10

241: 13 17 10 13 12 14 16 15

249: 13 18 10 11 8 9 10 7

257: 7 2 0 0 0 0 0 0

265: 0 1 0 0 0 0 0 0

273: 0 0 0 0 0 0 1 0

281: 0 0 0 0 0 0 0 0

289: 0 0 1 1 0 1 1 0

297: 0 0 0 0 0 1 0 0

305: 1 1 0 0 0 0 1 0

313: 0 1 1 0 2 1 1 3

321: 1 0 1 0 0 0 1 0

329: 0 0 0 1 1 1 0 0

337: 0 0 0 1 0 1 0 0

345: 0 1 0 0 0 0 0 0

353: 0 0 0 1 2 1 0 0

361: 1 0 0 1 0 0 0 1

0121

Channel Data Report

369: 1 0 0

Sample Title: 01

3/30/2018

0

4:51:44 PM

3 1 1

Page 2

0

Channell------l-------l-------l-------l-------l-------1-------1-------1

377: 0 0 0 0 0 0 3 0

385: 0 1 2 1 2 1 1 1

393: 0 2 1 1 2 1 0 1

401: 3 1 1 2 1 2 2 2

409: 4 4 2 3 1 6 1 3

417: 5 7 7 8 7 9 8 7

425: 8 17 3 12 15 12 12 9

433: 10 13 8 10 12 11 9 21

441: 12 16 20 14 14 12 16 15

44 9: 8 4 8 2 3 0 0 0

457: 0 0 0 0 0 0 0 0

465: 0 0 0 0 0 0 0 0

473: 0 0 1 0 0 0 0 0

481: 0 0 0 0 0 0 0 0

489: 0 0 0 0 0 0 0 0

497: 0 0 0 0 0 0 0 0

505: 0 0 0 0 0 0 0 0

513: 0 0 0 0 0 0 0 0

521: 1 0 0 0 0 0 0 1

52 9: 1 1 0 0 1 0 0 0

537: 1 0 1 1 0 0 0 0

54 5: 0 0 0 0 0 0 0 0

553: 0 1 1 0 0 0 2 0

561: 0 0 1 1 0 1 1 0

56 9: 1 0 0 0 0 1 1 0

577: 1 0 1 2 4 1 0 1

585: 2 0 2 3 2 2 1 2

593: 3 3 7 3 3 3 4 6

601: 7 10 10 6 3 4 5 4

609: 5 8 11 9 5 9 7 12

617: 12 12 8 13 8 14 12 12

625: 6 12 7 8 13 12 7 7

633: 3 4 4 2 2 1 2 0

641: 0 0 0 0 0 0 0 0

64 9: 0 0 0 0 0 0 0 0

657: 0 0 0 0 0 0 0 0

665: 0 0 0 0 0 0 0 0

673: 0 0 0 0 0 0 0 0

681: 0 0 0 0 0 0 0 0

689: 0 0 0 0 0 0 0 0

6 97: 0 0 0 0 0 0 0 0

705: 0 0 0 0 0 0 0 0

713: 0 0 0 0 0 0 0 0

721: 0 0 0 0 0 0 0 0

729: 0 0 0 0 0 0 0 1

737: 0 0 0 0 0 0 0 0

745: 0 0 0 0 0 0 0 0

753: 0 0 0 0 0 0 0 0

761: 0 0 0 0 0 0 0 0

769: 0 0 0 0 0 0 0 0

777: 0 0 0 0 0 0 0 0

785: 0 0 0 0 0 0 0 0

793: 0 1 0 0 0 0 0 0

0122


801: 0 0 0 0 0 0 0 0

Sample Title: 01

Channell------l-------l-------l-------l-------1-------1-------1-------I 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0

865: 0 0 0 0 0 0 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 0 0 0 0 0

897: 0 0 0 0 0 0 0 0

905: 0 0 0 0 0 0 0 0

913: 0 0 0 0 0 0 0 0

921: 0 0 0 0 0 0 0 0

929: 0 0 0 0 0 0 0 0

937: 0 0 0 0 0 0 0 0

945: 0 0 0 0 0 0 0 0

953: 0 0 0 0 0 0 0 0

961: 0 0 0 0 0 0 0 0

969: 0 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0123

_,A Al h TM ~-~~l""\pex- p a Sample Description: Spectrum File: Batch Identification:

BLANK \\OR-ALPHAl\Canberra\ApexAlpha\Root\Data\00002099

1803110A-UU





02 Shelf 2 U iso

Alpha_058 01017326B 58 System Bkgd 211479

<not performed>

l.000E+000 3/30/2018 3/30/2018

+/- 0.000E+000 liter 6:46:41 AM 1:25:58 PM

170.0 minutes 170.0 minutes

U232 UU-l0A 0.606 mL 0.1819 +/- 0.0107

Counting Efficiency: Chem. Recovery Factor:

0.1710 +/- 0.0030 on 2/16/2018 12:37:03 PM

1.0637 +/- 0.0656

Peak Match Tolerance:

Nuclide

U-232 T U-234 U-235 U-238

Energy (MeV)

5.275 4.716 4.431 4 .196

0.150 MeV

PEAK AREA REPORT

Net Pk Area

338.32 -0.68 0.32

-0.02

Pk Area Error%

10.67 304.44 646.93 10615.

Ambient Backgnd

0.68 0.68 0.68 1. 02

Reagent Backgnd

0.00E+000 0.00E+000 0.00E+000 0.00E+000

FWHM (keV)

9.8 0.0 3.0 3.0

T Tracer Peak used for Effective Efficiency

Nuclide

U-232 U-234 U-235 U-238

Id Conf.

0.995 0.986 0.985 0.999


Energy (keV)

5302.50* 4761.50* 4385.50* 4184.40*


4.94E+000 +/- 5.72E-001 -9.93E-003 +/- 3.02E-002

5.76E-003 +/- 3.73E-002 -2.91E-004 +/- 3.09E-002

fG 1!o1/~

MDA (pCi/liter

8.24E-002 +/- 9.54E-003 8.24E-002 +/- 9.54E-003 l.02E-001 +/- l.18E-002 9.16E-002 +/- l.06E-002

0124

60

55

50

45

40

35 VI .f.-1 C: :::s 8 30

25

20

15

10

5

0 I

3500 4000

= = ~ ' :::,

ROI Type: 1

4500

0000209989.CNF

5000 Energy ( kev)

5500

Live Time 10200.000 sec Real Time 10200.000 sec Start: 1 3453.S(keV) stop : 1024 6492. 7(kev) Acq. Start Fri Mar 30 13:25:58 2018

6000

ROI Type: 3

0125


******************************************************* ***** s P E C T R A L DAT A R E P O R T ***** *******************************************************

Sample Title: 02


Channell------l-------l-------l-------l-------1-------1-------1-------I 1: 0 0 0 0 0 0 0 0

9 : 0 0 0 0 0 0 0 0

17: 0 0 0 0 0 0 0 0

25: 0 0 0 0 0 0 0 0

33: 0 0 0 0 0 0 0 0

41: 0 0 0 0 0 0 0 0

49: 0 0 0 0 0 0 0 0

57: 0 0 0 0 0 0 0 1

65: 0 0 0 0 0 0 0 0

73: 0 0 0 0 0 0 0 0

81: 0 0 1 0 0 0 0 0

89: 0 0 0 0 0 0 0 0

97: 0 0 0 0 0 0 0 0

105: 0 0 0 0 0 0 0 0

113: 0 0 0 0 0 0 0 0

121: 0 0 0 0 0 0 0 0

129: 0 0 0 0 0 0 0 0

137: 0 0 0 0 0 0 0 0

145: 0 0 0 0 0 0 1 0

153: 0 0 0 0 0 0 0 0

161: 0 0 0 0 0 0 0 0

169: 0 0 0 0 0 0 0 0

177: 0 0 0 0 0 0 0 0

185: 0 0 0 0 0 0 0 0

193: 0 0 0 0 0 0 0 0

201: 0 0 0 0 0 0 0 0

209: 0 0 0 0 0 0 0 0

217: 0 0 0 0 0 0 0 0

225: 0 0 0 0 0 0 0 0

233: 0 0 0 0 0 0 0 0

241: 0 0 0 0 0 0 0 0

249: 0 0 1 0 0 0 0 0

257: 0 0 0 0 0 0 0 0

265: 0 0 0 0 0 0 0 0

273: 0 0 0 0 0 0 0 0

281: 0 0 0 0 0 0 0 0

289: 0 0 0 0 0 0 0 0

297: 0 0 0 0 0 0 0 0 305: 0 0 0 0 0 0 0 0

313: 0 0 0 0 0 0 0 0 321: 0 0 0 0 0 0 0 0 329: 0 1 0 0 0 0 0 0 337: 0 0 0 0 0 0 0 0 345: 0 0 0 0 0 0 0 0 353: 0 0 0 0 0 0 0 0 361: 0 0 0 0 0 0 0 0

0126


369: 0 0 0 0 0 0 0 0

Sample Title: 02

Channell------l-------l-------l-------l-------1-------1-------1-------I 377: 0 0 0 0 0 0 0 0

385: 0 0 0 0 0 0 0 0

393: 0 0 0 0 0 0 0 0

401: 0 0 0 0 0 0 0 0

409: 0 0 0 0 0 0 0 0

417: 0 0 0 0 0 0 0 0

425: 0 0 0 0 0 0 0 0

433: 0 0 0 0 0 0 0 0

441: 0 0 0 0 0 0 0 0

449: 0 0 0 0 0 0 0 0

457: 0 0 0 0 0 0 0 0

465: 0 0 0 1 0 0 0 0

473: 0 0 0 0 0 0 0 0

481: 0 0 0 0 0 0 0 0

489: 0 0 0 0 0 0 0 0

497: 0 0 0 0 0 0 0 0

505: 0 0 0 1 0 0 0 0

513: 0 0 0 0 1 0 0 0

521: 0 0 0 0 0 0 0 0

529: 0 0 0 0 0 0 0 0

537: 0 0 0 0 0 1 0 0

545: 0 0 0 0 0 0 0 0

553: 1 0 0 0 0 0 0 0

561: 0 0 0 0 1 0 1 0

569: 0 0 1 1 1 1 0 2

577: 2 0 1 2 2 1 0 0

585: 1 2 2 0 2 2 2 2

593: 4 0 4 5 3 3 4 5

601: 5 7 5 4 5 10 5 10

609: 4 10 8 14 7 6 8 6

617: 10 9 8 7 14 11 9 11

625: 12 7 4 15 13 16 4 8

633: 5 4 3 1 0 0 0 0

641: 0 0 0 0 0 0 0 0

649: 0 0 0 0 0 0 0 0

657: 0 0 1 0 0 0 0 0

665: 0 0 0 0 0 0 0 0

673: 0 0 0 0 0 0 0 0

681: 0 0 0 0 0 0 0 0

689: 0 0 0 0 0 0 0 0

697: 0 0 0 0 0 0 0 0

705: 0 0 0 0 0 0 0 0

713: 0 0 0 1 0 0 0 0

721: 0 0 0 0 0 0 0 0

729: 0 0 0 0 0 0 0 0

737: 0 0 0 0 0 0 0 0

745: 0 0 0 0 0 0 0 0

753: 0 0 0 0 0 0 0 0

761: 0 0 0 0 0 0 0 0

769: 0 0 0 0 0 0 0 0

777: 0 0 0 0 0 0 0 0

785: 0 0 0 0 0 0 0 0

793: 0 0 0 0 0 0 0 0

0127


801: 0 0 0 0 0 0 0 0

Sample Title: 02

Channell------l-------1-------1-------1-------I-------I-------I-------I 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0

865: 0 0 0 0 0 0 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 0 0 0 0 0

897: 0 0 0 0 0 0 0 0

905: 0 0 0 0 0 0 0 0

913: 0 0 0 0 0 0 0 0

921: 0 0 0 0 0 0 0 0

929: 0 0 0 0 0 0 0 0

937: 0 0 0 0 0 0 0 0

945: 0 0 0 0 0 0 0 0

953: 0 0 0 1 0 0 0 0

961: 0 0 0 0 0 0 0 0

969: 0 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0128

cittA Al h TM ~J-\pex- p a Sample Description: Spectrum File: Batch Identification:

OU-1-008 DUP \\OR-ALPHAl\Canberra\ApexAlpha\Root\Data\00002099

1803110A-UU Sample Identification: Sample Geometry: Procedure Description:




03 Shelf 2 U iso


<not performed>

5.000E-001 3/19/2018 3/30/2018

+/- 0:000E+000 liter 6:46:41 AM 1:56:21 PM


U232 UU-l0A 0.594 mL 0.2094 +/- 0.0118

Counting Efficiency: 0.1903 +/- 0.0033 on 2/16/2018 1.1003 +/- 0.0648

9:34:21 AM



Nuclide

U-232 U-234 U-235 U-238

T

Energy (MeV)

5.252 4. 716 4.372 4 .137

0.150 MeV

PEAK AREA REPORT

Net Pk Area

382.13 46.15

3.66 36.66

Pk Area Error%-

10.06 29.16

107.87 32.55

Ambient Backgnd

1. 87 0.85 0.34 0.34

Reagent Backgnd

0.00E+000 0.00E+000 0.00E+000 0.00E+000

FWHM (keV)

11.5 3.0 3.0 6.0

T = Tracer Peak used for Effective Efficiency

Nuclide

U-232 U-234 U-235 U-238

Id Conf.

0.982 0.985 0.999 0.984


Energy (keV)

5302.50* 4761.50* 4385.50* 4184.40*


9.69E+000 +/- l.07E+000 l.17E+000 +/- 3.65E-001 1.14E-001 +/- l.24E-001 9.26E-001 +/- 3.18E-001

4,/('t

MDA (pCi/liter

l.92E-001 +/- 2.12E-002 1. 52E-001 +!- l.67E-002 l.50E-001 +!- l.65E-002 l.21E-001 +!- l.33E-002

0129

0000209990.CNF

Live Time :10200.000 sec

60+ Real Time :10200.000 sec start: 1: 3497 .0(kev) Stop : 1024:6579.9(keV) Acq. Start :Fri Mar 30 13:56:21 2018

L 55

50

45

40

35 VI -I-' C:

8 30

25

20

15

10

5

0 I I I I I I I

3500 4000 4500 5000 5500 6000 6500 Energy(kev)

ROI Type: 1 ROI Type: 3

0130



Sample Title: 03


Channell------l-------1-------1-------1-------I-------I-------I-------I 1: 0 0 0 0 0 0 0 0

9 : 0 0 0 0 0 0 1 0

17: 0 0 0 0 0 0 0 0

25: 0 0 0 0 0 0 0 0

33: 0 0 0 0 1 0 0 0

41: 0 0 0 0 0 0 0 0

49: 0 0 0 0 0 0 0 0

57: 0 1 0 0 0 0 0 0

65: 0 0 0 0 0 0 0 0

73: 0 0 0 0 0 0 0 1

81: 0 0 0 0 0 0 0 0

89: 0 0 0 0 0 0 0 0

97: 0 0 0 0 0 0 0 0

105: 0 0 0 0 0 0 0 0

113: 0 0 0 0 0 0 0 0

121: 0 0 0 0 0 0 0 0

129: 0 0 0 0 0 0 0 0

137: 0 0 0 0 0 0 0 0

145: 0 0 0 0 2 0 0 0

153: 0 1 0 0 0 0 0 0

161: 0 0 0 0 0 0 0 0

169: 0 0 0 0 0 0 0 0

177: 0 1 0 1 0 0 0 1

185: 0 1 0 0 1 0 0 0

193: 0 0 0 0 0 0 0 0

201: 0 0 2 3 1 1 2 2

209: 1 0 0 0 0 1 0 0

217: 1 1 2 2 3 1 1 0

225: 0 0 1 0 1 1 0 0

233: 1 0 0 2 0 0 0 0

241: 1 0 1 0 0 0 0 0

249: 0 0 0 0 0 0 0 0

257: 0 0 0 0 1 0 0 0

265: 0 0 0 0 0 0 0 0

273: 0 0 0 0 0 0 1 0

281: 0 0 0 0 0 0 1 0

289: 0 0 0 0 0 0 0 1

297: 0 0 0 0 0 0 1 0

305: 0 0 0 0 0 0 0 0

313: 0 0 0 0 0 0 0 0

321: 0 0 0 0 0 0 0 0

329: 0 0 0 0 0 0 0 0

337: 1 1 0 0 0 0 0 0

345: 0 0 0 1 0 0 0 0

353: 0 0 0 0 0 0 0 0

361: 0 0 0 0 0 0 0 0

0131


369: 0 0 0 0 0 2 0 0

Sample Title: 03

Channell------l-------l-------l-------l-------1-------1-------1-------I 377: 0 0 0 1 0 0 1 0

385: 0 0 2 0 1 0 0 0

393: 1 1 1 0 1 1 1 0

401: 0 4 0 1 2 3 0 3

409: 1 1 2 0 2 3 1 1

417: 2 2 2 1 0 0 0 1

425: 0 1 0 1 0 0 0 0

433: 0 0 0 0 0 0 0 0

441: 0 0 0 0 0 0 0 0

449: 0 1 0 0 0 0 0 0

457: 0 0 0 0 0 0 0 0

465: 0 0 0 0 1 0 0 0

473: 0 0 0 0 0 0 0 0

481: 0 0 0 0 0 0 0 0

489: 1 0 0 0 0 0 0 0

497: 0 0 0 1 0 0 0 0

505: 1 0 0 0 0 0 0 0

513: 0 0 0 0 0 1 0 1

521: 0 0 0 0 0 0 0 0

529: 0 0 0 0 0 1 1 1

537: 0 0 1 1 1 0 0 0

545: 1 1 1 0 0 3 0 2

553: 3 3 0 0 0 1 2 2

561: 4 3 7 9 4 4 6 4

569: 2 9 8 8 7 2 12 9

577: 6 11 6 15 12 13 5 10

585: 10 11 5 10 12 9 18 13

593: 18 7 11 8 10 5 12 10

601: 8 3 3 5 0 1 1 1

609: 0 0 0 0 0 1 0 0

617: 0 0 0 0 0 0 0 0

625: 0 0 0 0 0 0 0 0

633: 1 0 0 0 0 0 0 0

641: 0 0 0 0 0 0 0 0

649: 0 0 0 0 0 0 0 0

657: 0 0 0 0 0 0 0 0

665: 0 0 0 0 0 0 0 0

673: 0 0 0 0 0 0 0 0

681: 0 0 0 0 0 0 0 0

689: 0 0 0 0 0 0 0 0

697: 0 0 0 0 0 0 0 0

705: 0 0 0 0 0 0 0 0

713: 1 0 0 0 0 0 0 0

721: 0 0 0 0 0 0 1 0

729: 0 0 0 0 0 0 0 0

737: 0 0 0 0 0 0 0 0

745: 0 0 0 0 0 0 0 0

753: 0 0 0 0 0 0 0 0

761: 0 0 0 0 0 0 0 0

769: 0 0 0 0 0 0 0 0

777: 0 0 0 0 0 0 0 0

785: 0 0 0 0 0 0 0 0

793: 0 0 0 0 0 0 0 0

0132


801: 0 0 0 0 0 0 0 0

Sample Title: 03

Channell------l-------l-------1-------1-------1-------I-------I-------I 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 1 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0

865: 0 0 0 0 0 0 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 0 0 0 0 0

897: 0 0 0 0 0 0 0 0

905: 0 0 0 0 0 0 0 0

913: 0 0 0 0 0 0 0 0

921: 0 0 0 0 0 0 0 0

929: 0 0 0 0 0 0 0 0

937: 0 0 0 0 0 0 0 0

945: 0 0 0 0 0 0 0 0

953: 0 0 0 0 0 0 0 0

961: 0 0 0 0 0 0 0 0

969: 0 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0133

~Apex-Alpha™ Sample Description: Spectrum File: Batch Identification:

OU-1-008 \\OR-ALPHAl\Canberra\ApexAlpha\Root\Data\00002099 1803110A-UU





04 Shelf 2 u iso


<not performed>

5.000E-001 3/19/2018 3/30/2018

+/- 0.000E+000 liter 6:46:41 AM 1:56:22 PM


U232 UU-l0A 0.600 mL 0.1885 +/- 0.0110


9:34:19 AM



Nuclide

U-232 T U-234 U-235 U-238

Energy (MeV)

5.261 4.705 4.435 4 .142

0.150 MeV

PEAK AREA REPORT

Net Pk Area

347.49 37.49

2.83 37.00

Pk Area Error%

10.52 32.26

120.53 32.65

Ambient Backgnd

0.51 0.51 0.17 0.00

Reagent Backgnd

0.00E+000 0.00E+000 0.00E+000 0.00E+000

FWHM (keV)

39.3 4.4 3.0 4.5


Nuclide

U-232 U-234 U-235 U-238

Id Conf.

0.988 0.978 0.983 0.987


Energy (keV)

5302.50* 4761.50* 4385.50* 4184.40*


9.79E+000 +!- l.12E+000 l.06E+000 +!- 3.62E-001 9.83E-002 +!- l.19E-001 l.04E+000 +!- 3.59E-001

ftj 1-(~rt

MDA (pCi/liter

l.48E-001 +!- l.69E-002 1. 48E-001 +!- 1. 69E-002 1. 45E-001 +!- l.66E-002 l.68E-001 +/- l.93E-002

0134

60

55

50

45

40

35 V> ,j-1 C: :::3

8 30

25

20

15

10

5 00

0 [I 1 ~! I I! I I I jd!' I'' 3 500 -~1Jc1 I :,\\f ::J.:i'Yulrh]j]ll[

1

(!( _..1,__J'Li....1-W..J.JJ1 I\ I ,1 ' . ' ,, I, I ! 111,

4000 4500

ROI Type: 1

0000209991.CNF

- ....,;,.,..:''_;LI Li _tLI!' IL ~11ullln___1 \ lo! Mlj!IU (m/V,111 I 1• 1

5000 Energy(kev)

Live Time :10200.000 sec Real Time :10200.000 sec Start: 1:3463.G(keV) Stop : 1024:6522.9(kev) Acq. Start :Fri Mar 30 13:56:22 2018

I n i i I I n I j 1 I I I I I

5500 6000 6500

ROI Type: 3

0135



Sample Title: 04


Channell------l-------l-------l-------l-------1-------1-------1-------I 1: 0 0 0 0 0 0 0 0

9 : 0 0 0 0 0 0 0 0

17: 0 0 0 0 0 0 0 0

25: 0 0 0 0 0 0 0 0

33: 0 0 0 0 0 0 0 0

41: 0 0 0 0 0 0 0 0

49: 0 0 0 0 0 0 0 0

57: 0 0 0 0 0 0 0 0

65: 0 0 0 0 0 0 0 0

73: 0 0 0 0 0 0 0 0

81: 0 0 0 0 0 0 0 0

89: 0 0 0 0 0 0 0 0

97: 0 0 0 0 0 0 0 0

105: 0 0 0 0 0 0 0 0

113: 0 0 0 0 0 0 1 0

121: 0 0 0 0 0 0 0 0

129: 0 0 0 0 0 0 0 0

137: 0 0 0 0 0 0 0 0

145: 0 0 0 0 0 0 0 0

153: 0 0 0 0 0 0 0 0

161: 0 0 0 0 0 0 0 0

169: 0 0 1 0 0 1 0 0

177: 0 0 0 0 0 0 0 0

185: 0 0 0 0 0 0 0 0

193: 0 0 0 1 0 0 0 0

201: 0 0 0 0 0 0 1 0

209: 0 2 0 0 0 0 2 1

217: 1 1 0 0 1 1 1 3

225: 1 1 0 2 1 1 0 2

233: 3 0 0 0 1 0 2 0

241: 2 2 0 1 2 0 0 1

249: 0 0 0 0 0 0 0 0

257: 0 0 0 0 0 0 0 0

265: 0 0 0 0 0 0 0 0

273: 0 0 0 0 0 0 0 0

281: 0 0 0 0 0 0 0 0

289: 0 0 0 0 0 0 0 0

297: 0 0 0 0 0 0 0 0

305: 0 0 0 0 1 0 0 0

313: 0 0 0 0 0 0 0 0

321: 0 0 0 0 0 0 0 0

329: 1 0 0 0 0 0 0 0

337: 0 0 1 0 0 0 0 0

345: 0 0 0 0 0 0 0 0

353: 0 0 0 0 0 0 0 0

361: 0 1 0 0 0 0 0 0

0136


369: 0 0 0 1 0 0 0 1

Sample Title: 04

Channell------l-------l-------1-------1-------1-------I-------I-------I 377: 0 0 0 0 0 0 0 0

385: 1 0 0 0 0 0 0 1

393: 1 1 1 0 0 0 0 1

401: 0 1 0 1 0 0 2 1

409: 0 1 0 0 1 2 2 5

417: 1 0 0 1 0 0 0 0

425: 0 1 1 2 2 1 2 0

433: 1 2 2 0 0 0 0 0

441: 0 0 0 0 0 0 0 0

449: 0 0 0 0 0 0 0 0

457: 0 0 0 0 0 1 0 0

465: 0 0 0 0 0 0 0 0

473: 0 0 0 0 0 0 0 0

481: 0 0 0 0 1 0 0 0

489: 0 0 0 0 1 0 0 1

497: 0 0 0 0 0 0 0 0

505: 0 1 0 0 2 1 0 0

513: 0 0 0 0 0 1 0 0

521: 0 0 0 0 0 1 1 1

529: 1 0 1 0 0 0 0 0

537: 2 0 1 0 0 0 0 0

545: 0 0 0 1 1 1 3 0

553: 2 0 1 0 0 0 0 2

561: 1 1 0 1 0 2 0 2

569: 2 1 6 3 2 0 1 2

577: 1 2 3 1 5 2 2 2

585: 4 5 3 3 5 6 9 8

593: 4 10 11 11 7 5 12 6

601: 8 4 8 6 7 11 10 11

609: 8 8 15 8 13 14 13 11

617: 8 8 6 8 3 5 2 2

625: 1 0 1 0 0 0 0 0

633: 0 0 0 0 0 0 0 0

641: 0 0 0 0 0 0 0 0

649: 0 0 0 0 0 0 0 0

657: 0 0 0 0 0 0 0 0

665: 0 0 0 0 0 0 0 0

673: 0 0 0 0 0 0 0 0

681: 0 0 0 0 0 0 0 0

689: 0 0 0 0 0 0 0 0

697: 0 0 0 0 0 0 0 0

705: 0 0 0 1 1 0 0 0

713: 0 0 0 0 0 0 0 0

721: 0 0 0 0 0 0 0 0

729: 0 0 0 0 0 0 0 0

737: 0 0 0 0 0 0 0 0

745: 0 0 0 0 0 0 0 0

753: 0 0 0 0 0 0 0 0

761: 0 0 0 0 0 0 0 0

769: 0 0 0 0 0 0 0 0

777: 0 0 0 0 0 0 0 0

785: 0 0 0 0 0 0 0 0

793: 0 0 0 0 0 0 0 0

0137


801: 0 0 0 0 0 0 0 0

Sample Title: 04

Channell------l-------l-------l-------l-------1-------1-------1-------I 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0

865: 0 0 0 0 0 0 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 0 0 0 0 0

897: 0 0 0 0 0 0 0 0

905: 0 0 0 0 0 0 0 0

913: 0 0 0 0 0 0 0 0

921: 0 0 0 0 0 0 0 0

929: 0 0 0 0 0 0 0 0

937: 0 0 0 0 0 0 0 0

945: 0 0 0 0 0 0 0 0

953: 0 0 0 0 0 0 0 0

961: 0 0 0 0 0 0 0 0

969: 0 0 0 1 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0138

!"'age I m L. 3/30/2018 5:55:22 AM

ex-Al OA .c::;111\AMARY REPORT

... ~ u • ~ ,, .... ,, "-. ~ - - •• -- -- - -

Review Of QA Results - Pulser Check

Date : 3/30/2018 Time : 5:55:22 AM

CHAMBER DEVICE PARAMETER FLAG DATE

Alpha 001 21f ALL Not Done


Alpha 003 21f ALL Passed 3/30/2018 5:03:13 AM






Alpha 009 2lf ALL Not Done








Alpha 033 Alpha Analystl 00DC ALL Passed 3/30/2018 5:03:19 AM


Alpha 035 Alpha Analystl00DC ALL Passed 3/30/2018 5:03:22 AM


Alpha 037 Alpha Analystl 00DC ALL Not Done


Alpha 039 Alpha Analystl00DC ALL Not Done

Alpha 040 Alpha Analyst! 00DC ALL Passed 3/30/2018 5:03:28 AM


Alpha 042 Alpha Analyst 1 00DC ALL Passed 3/30/2018 5:03:32 AM






Alpha 048 Alpha Analyst 1 00DC ALL Not Done











0139

Page 2 of 2 Kev1ew ot UA Kesu1ts - t-'Ulser L;necK 3/30/2018 5:55:22 AM




APPROVED BY:

APPROVAL DATE: <-S /3()/[ 8

0140

Library Listing Report 6/12/12 12:17:04 PM Page 1

*************************************************************************

***** L I B R A R Y L I S T I N G R E P O R T *****

*************************************************************************

Nuclide Library Title: Uranium

Nuclide Library Description: U-232,-234,-235,-238

Nuclide Half-Life Energy Energy Yield Yield

Name (Seconds) (keV ) Uncert. (keV ( % ) Uncert. (Abs.+-)

U-232 2.174E+009 5302.500* 0.000 99.8000 0.0000

U-234 7.731E+Ol2 4761.500* 0.000 99.8000 0.0000

U-235 2.221E+Ol6 4385,500* 0.000 80.9000 0.0000

U-238 1. 410E+Ol 7 4184.400* 0.000 100.2300 0.0000

* == key line

TOTALS: 4 Nuclides 4 Energy Lines

0141

SECTION IX

ANALYTICAL DATA (TOTAL URANIUM)

0142

Eberline Services Oak Ridge Laboratory Analysis Sheet

Work Order

Analysis Code

Run

Date Received

Lab Deadline

18-03110

KPA_LIQ I

1 3/23/2018

4/12/2018


Project WESTLAKE

Report Level 4

Activity Units ug

Aliquot Units

Matrix WA

Method ASTM D5174 Modified

Instrument Type KPA

Radiometric Tracer

Radiometric Sol#

Tracer Act (dprn/g)

Carrier


Internal Sample I Fraction Desc I

01 LCS

02 MBL

03 DUP

04 DO

I

j

18-03110 KPA_LIQ

Run 1

Client ID

LCS

BLANK

OU-1-008

OU-1-008

--·~---. ..



I

Login CPM

I

I '

I 38 i !

38

I

:

I I I

I

I I i I

I

I

i I I

I

I I

I

I I


Sample I Sample

Date I

Aliquot

03/23/18 00:00 1.0000E+00

03/23/18 00:00 1.0000E+00

03/19/18 18:02 1.0000E+00

03/19/18 18:02 I 1.0000E+00

I

'

I

I

I

I

i

! !

i

!

i

0143

Eberline Services


Analysis Sheet

Internal Sample Tracer

Fraction Desc Aliquot(g)

01 LCS

02 MBL

03 DUP

04 DO

i

Tracer Total ACT(dpm)

I

I

I

Radiometric Radiometric

Tracer (pCi) %Rec

0.00

0.00

0.00

0.00

I I I i !

I

i I i I

I

18-03110 KPA_LIQ

Run 1

Grav Carrier Grav Filter

Added(ml) Tare (g)

I I

I

I I

Grav Filter Final (g)

I

• SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. A Indicates estimated SAF value.


Grav Filter Grav Net(g) %Rec

I

I I I I I I

Printed: 4112120181:10 PM Page 2 of 3

Mean SAF SAF %Rec 1* 2*

0144


Internal Sample Fraction Desc

01 LCS

02 MBL

03 DUP

04 DO

Rough Prep Date

Rough Prep Prep

By Date

i

' I I I

i

I I

l

I

I

I i

I

18-03110 KPA_LIQ

Run 1

Prep By

I

Sep to Date/Time

-~·

* SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. h Indicates estimated SAF value.


Sep to By

I i

I I

'

\


Sep t1 Sep t1

Date/Time By

'

I

0145

Eberline Services Oak Ridge Laboratory

~ Lab

Nuclide Fraction

01 TOTAL U

i:: :::i ct:

.g 0

(.)

,!!: ~

<U i:: <t

it (.)

""""'

a -..J I

<C Q. ~

ti)

·u <1' 0 co -C: <1' E C: 0 ... ·s; C: w 0 :i!: <

OH TOTAL U

02 TOTAL U

03 TOTAL U

04 TOTAL U

I

Sample Oesc

LCS

LCSH

MBL

DUP

DO

'1

i I

···---


Work Order: 18-03110-KPA_LIQ-1

Client

I Activity

Results I Error Estimate[ MDA I LCS

I Identification Units Known

I 8.00E+ool LCS ug/1 8.65E+00 1.88E-01 1.01E+00

LCS-H ug/1 1.96E+02 3.99E+00 1.01E+00 2.00E+02

BLANK ug/1 0.00E+00 0.00E+00 1.01E+00 I !

OU-1-008 ug/1 4.12E+00 9.50E-02 1.01E+00 I OU-1-008 ug/1 4.23E+00 9.91E-02 1.01E+00

I I

I I

I I

I I i l

I I I

i I

I i I I

I I

I I

! I

-----

I I I

I I I I

LCS

I %R

108.14

98.04

I

I

I

i I

I I i

I

I I


LCS RPO

I MDA I Blank

Flag Flag Flag I Flag

OK I OK i

OK OK

OK OK

NA OK

OK

i i I

I

I I

I

I I

0146


( Lab I Nuclide Fraction

01 TOTAL U

i:: ::i ll:

G> ,:, 0

(.J

-~ ~ iu i:: q:

11 u

"""'"

0 -.J <Cl a. ~

en C: 0 en

·c:3 Cl)

C

B C: Cl)

E C: 0 I-

> C: w 0 ~ <

OH TOTAL U

02 TOTAL U

03 TOTAL U

04 TOTAL U

I I

Sample Desc

LCS

LCSH

MBL

DUP

DO




I SAF Date Aliquot %Rec %Rec %Rec

I

03/23/18 00:00 1.00E+00 0.00 0.00 98.691

03/23/18 00:00 1.00E+00 0.00 0.00 98.691 I

03/23/18 00:00 1.00E+00 0.00 0.00 98.69

I

03/19/18 18:02 1.00E+00 0.00 0.00 98.69

03/19/18 18:02 1.00E+00 0.00 0.00 98.69

I I I

I

I I

I !

I I I I I

I I I

I I I I !

i i

I I

I I

I I ·-~----I

i I

I I

I

SeptO


Sept1

Date/Time Date/Time

I

I

I

I i

I I

I

I

I

I

I

I

0147

.!!1 ~ Ill C: ct

II


Lab I Fraction

Nuclide

01 TOTAL U

OH TOTAL U

"""" 02 TOTAL U

a 03 TOTAL U

-..J <Cl

04 TOTAL U

a. ~

1/) s:: 0

-~ (.) Cl)

0

.!9 s:: Cl)

E s:: 0 ... > s:: w 0 ::l!:: <(

Sample Desc

LCS

LCSH

MBL

DUP

DO



Counting Halflife

I Detect Carrier

Count Counts

Date/Time {days) Time

03/27/18 09:51

03/27/18 09:53

03/27/18 09:55 I

03/27/18 10:01

03/27/18 09:57

I

I

I I

I I I

I Bkg CPM

I

I

I

I

I I

I

!

i

I I


Eff

0148

Count Room Report

Client: AMO Environmental Decisio

Internal Sample Client

Fraction Desc ID

01 LCS LCS

02 MBL BLANK

03 DUP OU-1-008

04 DO OU-1-008

i

!

I

-- -

I

···-

I !

i I

18-03110-KPA_LIQ-1 (ug/1) in WA

Tracer ID:

I I

Sample Sample Tracer

Date I Aliquot Aliquot (g)

03/23/18 00:00 1.0000

I

I 03123118 00:00 I 1.0000 I

03/19/18 18:02 \ 1.0000

03/19/18 18:02 t 1.0000

I I

I

I I

I

I I

I i

I I

I

i I

I I

I I I

I I

I !

I ! I

Tracer ACT(dpm)

I Radiometric Tracer (pC1)

I I

I

I !


I Radiometric SAF SAF

%Rec 1* 2*

0.00

0.00 1

o.oo I

0.00

I

I I

I I

I

I I

I --I I !

I

0149


Recovery Spike Cone. '

Isotope I Sol# I '

nglml

TOTAL U U-9-3 I 10

'

LCS Low Range

Isotope !

Sol# Cone.

I I nglml

TOTAL U LCS-L i sl

Solution Date

1/7/2004

Solution Date

1/7/2004

LCS High Range

I I Cone. I Solution

Isotope Sol# I

I ng/ml i Date

TOTAL U LSC-H I 2001 1/7/2004

Matrix Spikes

Sol# Cone. Solution

Isotope ng/ml Date

TOTAL U U-9-5 • 100 1 1/7/2004

Version 2.5 01/05

Dilution factor

1.000

I Dilution

' factor

1.000 '

1 Dilution factor

1.000

Dilution factor

0.500

KPA Spike Worksheet Page 1 of 1

Printed: 4/12/2018 1:09 PM


KPA_LIQ 4/12/2018 13:09 JPACHELLA

Current Sample Type Evaluation 1~hnicia9_:jnitials

Volume Theoretical LIQUID ~j/' Used (g) Yield ,,

1.0000 10.0000 Witness Initials

LCS LCSD LCS LCSD

Volume Volume Known I Error Known Error

Used(g) Used(g) ng Estimate ng I Estimate

' I 1.0000 8.0000 0.1600 i

LCSH LCSDH LCSH LCSDH

Volume Volume Known Error Known I Error

Used (g) Used (g) ng Estimate ng i Estimate I

I 1.0000 200.0000· 4.0000 I

MSD MS MSD

Volume Volume Added I

Error Added I Error

Used (g) Used (g) ng I Estimate ng Estimate

I

0150

Lab



Analysis Code

KPA_LIQ

Sample Muffle Data

Fraction Ratio

Client ID Type Post/Pre

01 LCS LCS

02 BLANK MBL

03 OU-1-008 DUP

04 OU-1-008 DO

Comments

0 )../~ ;J lilt

Technician: . t,1-t:(~L y

Aliquot Worksheet

Rpt \Jolts lab Dead!lne

liters 4/12/2018


Noof Dils Dil Factor Ratio Aliquot Net Equiv

1.0000E+00 1.0000E+00

i 1.0000E+00 1.0000E+00

! 1.0000E+00 1.0000E+00

: 1.0000E+00 1.0000E+00 '"·--··

/

'

: -·

~~·-

---·----·------

-

Date: ±_, ~ ; J 7f

Technician

JPACHELLA

MS Aliquot Data


H-3 Solids Only Water Added H3 Dist


---

I

---·· ·-·

0151

KPAWin© Single Sample Report - Sample

Customer ID: Sample ID: Description: Batch ID:

Configuration

Sample Unit: Performance: QC Limits:

None 1803110-00

RECOVERY SPIKE 5826

µg/1 1003 Config

1000 Release

Sample Preparation & Analysis

Procedure ID: Range: Calibration ID: Equation: Specific Gravity:

None Low

Default Y= +249.459X +68.687

1

Range Sample Results

Reference Lifetime: LSR Time Gates: Sample Lifetime (µsec): Sample R 2 Intensity: Reference Ratio: Sample Intercept: Analytical Result: Dilution Factor: Aliquot Factor: Final Result: Uncertainty:

Interpreted Results

Detection Limit(IDL): Detection Limit(MDL):

(Low)

1803110-00

5 211

- 49 375

.998 1.031

2531 9.869 1.00 1.00

9.869 .208

N/A N/A

Min Significant Sample Limit: 3.00E-01

Date Analyzed: Analyte: Analyst: Date Printed:

KPA Unit Calibration: Alarms:

03/27/2018 09:49 AM Uranium

JPachella 03/27/2018 09:51 AM

1001 Config 1000 Release

1003 Config

Specific Activity (Bq/g): 25000

Flags

IDL Flags: MDL Flags: Calibration: Sample:

0152

I n t e n s i t y

Net Intensities

Low: 1803110-00 3/27/2018 9:49:42 AM

10000

1000

' "-, '

100

10

1 --l----------+--------+---------1---------+--------1-------------a----'-

0 20 40 60 80 100 120

Time Gate

o Sample 0 Ref

0153

Lab: No Lab Date: 3/27/2018 9:49:42 AM

Net Intensities

Low: 1803110-00 Sample Intensities 0 1 2 3 4 5 6 7 8 9

0 2496 2314 2432 2217 2158 2087 2016 1949 1876

10 1840 1769 1706 1625 1580 1500 1430 1373 1344 1273

20 1233 1222 1170 1133 1101 1051 996 978 938 915

30 891 863 824 791 761 736 716 696 682 658

40 636 601 586 563 554 542 536 514 492 471

50 454 437 416 400 376 359 348 340 336 332

60 325 308 304 281 274 265 270 254 254 242

70 236 221 212 207 203 198 188 180 168 163

80 154 154 155 155 150 145 133 130 120 113

90 110 108 104 106 104 100 98 95 89 84

100 83 78 75 78 75 72 70 69 65 62

110 64 69 66 65 64 60 58 60 57 53

120 51 47 40 42 42 39 36 24

Low: 1803110-00 Reference Intensities 0 1 2 3 4 5 6 7 8 9

0 4095 1300 1056 1043 939 864 799 742 681

10 631 589 538 501 464 434 402 377 345 322

20 300 279 256 235 223 206 194 185 174 170

30 161 151 143 133 116 113 112 107 103 100

40 94 87 83 80 81 74 71 70 67 62

50 63 61 53 51 48 44 40 42 41 38

60 37 35 35 33 32 34 34 33 31 31

70 31 29 26 25 25 22 24 24 22 20

80 20 17 18 17 16 16 14 13 15 14

90 13 14 13 11 10 11 9 8 9 9

100 8 8 8 7 8 8 7 7 7 5

110 4 4 3 2 2 2 2 3 3 3

120 3 3 4 4 3 2 1 3

0154



Configuration


None 1803110-01

LCS LOW 5826

µg/1 1003 Config

1000 Release



None Low

Default Y= +249.459X +68.687

1



Interpreted Results


(Low)

1803110-01

5 213

- 49 335

.998 1.009

2199 8.538 1.00 1. 00

8.538 .186

N/A N/A




03/27/2018 09:51 AM Uranium

JPachella 03/27/2018 09:52 AM


1003 Config


Flags


0155

I n t e n s i t y

Net Intensities

Low: 1803110-01 3/27/2018 9:51:33 AM

100000

10000

1000

100

10

1 +-------i------/--------+----------------1------/------+---.J

0 20 40 60 80 100 120

Time Gate

o Sample 0 Ref

0156

Lab: No Lab Date: 3/27/2018 9:51:33 AM

Net Intensities


0 4047 2129 2016 1913 1957 1676 1699 1612 1568

10 1516 1442 1392 1325 1274 1225 1189 1144 1102 1047

20 1007 969 923 899 868 829 786 762 725 701

30 678 662 626 600 583 566 543 524 501 477

40 451 429 417 410 398 391 382 374 361 342

50 325 312 297 279 265 252 240 230 225 226

60 219 215 203 192 184 173 164 161 154 152

70 148 142 139 140 129 128 121 118 114 111

80 108 105 96 93 90 84 79 84 75 73

90 71 70 66 67 64 62 61 58 54 52

100 52 49 50 50 48 47 44 41 39 39

110 38 39 36 36 33 31 28 28 25 25

120 25 26 23 25 23 22 17 16


0 4044 1300 1146 999 871 841 768 715 667

10 613 578 538 501 457 426 391 362 337 312

20 293 269 246 231 220 207 203 197 189 179

30 168 154 145 135 130 121 113 108 105 97

40 96 91 86 78 74 69 68 66 65 62

50 60 59 55 54 50 46 42 43 40 41

60 41 40 39 34 34 33 33 32 31 28

70 27 26 24 26 26 25 24 20 16 15

80 15 13 13 15 16 15 15 15 14 13

90 13 12 13 11 9 9 10 8 7 7

100 6 6 6 7 7 7 7 6 6 6

110 6 6 6 5 4 4 4 3 3 3

120 3 3 3 3 3 3 3 1

0157



Configuration


None 1803110-0H

LCS HIGH 5826

µg/1 1003 Config

1000 Release



None Low

Default Y= +249.459X +68.687

1



Interpreted Results


(Low) 1803110-0H

211 5 - 49

291 1.000 1.015 48340

193.506 1.00 1.00

193.506 3.936

N/A N/A




03/27/2018 09:53 AM Uranium

JPachella 03/27/2018 09:54 AM


1003 Config


Flags


0158

I n t e n s i t y

Net Intensities

Low: 1803110-0H 3/27/2018 9:53:23 AM

100000

10000

1000

100

10

1 +--------+-------"!------+---------t-------1--------+-~

0 20 40 60 80 100 120

Time Gate

o Sample 0 Ref

0159

Lab: No Lab Date: 3/27/2018 9:53:23 AM

Net Intensities

Low: 1803110-0H Sample Intensities 0 1 2 3 4 5 6 7 8 9

0 33599 44066 42813 40781 38992 37643 35764 34084 32453

10 30934 29599 28241 27101 25877 24764 23547 22503 21460 20521

20 19640 18829 18014 17278 16569 15807 15157 14514 13866 13231

30 12648 12052 11517 10955 10516 10046 9611 9180 8813 8360

40 8041 7726 7406 7064 6813 6522 6251 6008 5772 5516

50 5272 5027 4794 4562 4387 4192 4030 3873 3716 3548

60 3414 3239 3089 2978 2832 2694 2600 2495 2381 2301

70 2203 2087 1987 1901 1803 1727 1664 1589 1525 1482

80 1424 1376 1331 1271 1210 1151 1087 1035 996 948

90 904 869 828 792 757 728 700 672 658 633

100 608 580 556 520 497 487 467 453 433 421

110 394 377 355 334 310 301 294 287 287 275

120 267 250 237 219 208 200 182 207

Low: 1803110-0H Reference Intensities 0 1 2 3 4 5 6 7 8 9

0 4150 1236 1124 1055 977 906 813 734 659

10 608 562 520 489 461 417 384 362 331 313

20 298 278 257 245 223 208 190 179 164 154

30 148 146 138 131 127 120 112 107 107 101

40 92 89 86 80 75 77 72 68 61 61

50 57 54 50 51 49 41 38 39 36 32

60 34 34 33 32 31 28 28 26 26 24

70 25 24 25 23 23 24 23 22 22 22

80 19 17 15 16 15 15 15 16 14 13

90 13 11 10 9 7 7 7 8 8 8

100 9 9 6 7 7 6 5 6 6 6

110 5 6 5 5 5 5 3 3 4 3

120 4 5 4 4 3 2 3 1

0160



Configuration


None 1803110-02

BLANK 5826

µg/1 1003 Config

1000 Release



None Low

Default Y= +249.459X +68.687

1



Interpreted Results


(Low)

1803110-02

214 5 - 5

0 .000 .997

.000 .00 .00

.000

.000

N/A N/A




03/27/2018 09:55 AM Uranium

JPachella 03/27/2018 09:56 AM


1003 Config


Flags

IDL Flags: MDL Flags: Calibration: Sample: E202, A72

0161

I n t e n s i t y

10000

1000

100

10

1

\

0 20

Net Intensities

Low: 1803110-02 3/27/2018 9:55:09 AM

,\ r-

II 40 60 80 100

Time Gate

i\ \! I

120

o Sample 0 Ref

0162

Lab: No Lab Date: 3/27/2018 9:55:09 AM

Net Intensities


0 606 -144 26 17 0 10 7 8 8

10 7 8 6 4 4 2 0 3 4 3

20 3 5 4 4 2 1 0 0 0 1

30 0 1 2 1 1 3 3 3 4 4

40 2 3 3 3 3 3 3 2 1 2

50 2 1 1 1 1 0 0 0 0 -1

60 0 0 0 0 1 0 1 1 1 0

70 0 0 0 -1 -1 0 -2 -1 -2 -1

80 0 1 1 1 1 -1 -1 -1 -2 0

90 1 1 0 1 0 0 0 0 0 0

100 0 0 1 0 0 -1 -1 -1 -1 -1

110 0 1 2 2 1 2 0 0 0 0

120 0 0 1 1 0 0 1 -2


0 4416 1315 1117 1017 944 868 785 712 651

10 604 557 512 478 439 405 380 354 326 305

20 281 267 259 245 229 218 204 186 177 172

30 162 152 142 133 125 122 115 111 107 102

40 95 90 86 83 77 73 71 66 59 58

50 58 57 54 55 53 49 45 44 42 38

60 41 38 36 32 31 27 25 24 22 22

70 20 19 21 22 20 21 21 19 18 17

80 17 15 13 14 13 12 12 14 13 12

90 11 12 11 9 10 10 8 8 8 8

100 7 7 7 7 7 6 5 5 5 5

110 6 6 5 5 5 6 6 6 6 4

120 4 4 3 2 2 3 1 5

0163



Configuration


None 1803110-03

OU-1-008 5826

µg/1 1003 Config

1000 Release



None Low

Default Y= +249.459X +68.687

1



Interpreted Results


(Low)

1803110-03

5 209

- 49 278

.997 1.029

1084 4.069

1.00 1.00

4.069 .094

N/A N/A




03/27/2018 10:01 AM Uranium

JPachella 03/27/2018 10:34 AM


1003 Config


Flags


0164

I n t e n s i t y

Net Intensities

Low: 1803110-03 3/27/2018 10:01:11 AM

100000

10000

1000

100

10

l"-l-------1-------+------+---------1-------t-------i--

0 20 40 60 80 100 120

Time Gate

o Sample 0 Ref

0165

Lab: No Lab Date: 3/27/2018 10:01:11 AM

Net Intensities


0 18877 1626 1092 986 942 892 813 751 701

10 669 636 599 583 554 530 499 480 454 432

20 407 395 385 372 356 345 328 307 288 271

30 256 247 232 226 221 211 199 198 187 179

40 175 170 158 145 141 130 128 120 114 106

50 106 97 97 97 96 91 88 83 76 73

60 69 63 59 58 57 57 59 60 62 59

70 55 53 53 46 42 39 37 34 33 35

80 33 29 27 28 25 25 30 31 28 29

90 28 23 20 22 19 19 17 18 16 16

100 16 16 15 14 14 13 13 13 13 13

110 13 14 14 13 11 12 10 8 9 9

120 7 8 8 7 8 10 16 10


0 4350 1278 1113 1032 945 869 812 746 684

10 635 585 529 483 450 409 369 346 324 300

20 283 270 252 242 226 209 196 184 172 168

30 162 155 147 139 127 122 118 110 105 101

40 94 83 82 76 70 68 66 65 62 59

50 53 50 46 43 43 43 44 41 39 36

60 35 34 34 34 35 34 33 32 30 27

70 26 25 26 24 26 24 21 19 20 16

80 17 16 15 14 13 11 11 11 11 11

90 11 12 10 11 12 12 10 10 9 6

100 6 7 8 7 8 8 7 7 7 6

110 6 6 5 4 4 3 3 4 4 5

120 5 4 4 4 4 3 3 0

0166



Configuration


None 1803110-04

OU-1-008 5826

µg/1 1003 Config

1000 Release



None Low

Default Y= +249.459X +68.687

1


Reference Lifetime: LSR Time Gates: Sample Lifetime (µsec) Sample R 2 Intensity: Reference Ratio: Sample Intercept: Analytical Result: Dilution Factor: Aliquot Factor: Final Result: Uncertainty:

Interpreted Results


(Low)

1803110-04

5 215

- 49 285

.997 1.004

1109 4.171

1. 00 1. 00

4.171 .098

N/A N/A




03/27/2018 09:57 AM Uranium

JPachella 03/27/2018 10:45 AM


1003 Config

Specific Activity (Bq/g) 25000

Flags


0167

I n t e n s l

t y

100000

10000

1000

100

10

\

'

Net Intensities

Low: 1803110-04 3/27/2018 9:57:17 AM

1 +----------1------+-------+-------------t------+------+-LJ-

0 20 40 60 80 100 120

Time Gate

o Sample 0 Ref

0168

Lab: No Lab Date: 3/27/2018 9:57:17 AM

Net Intensities


0 20302 1701 1115 1025 929 875 824 792 749

10 720 687 649 602 581 560 535 518 505 470

20 436 420 390 364 350 344 324 316 304 296

30 274 266 254 248 235 228 210 197 183 177

40 172 175 171 164 156 150 144 137 127 118

50 112 102 98 99 101 97 96 91 83 75

60 74 72 68 65 66 64 60 54 56 56

70 50 50 51 44 41 42 38 39 42 40

80 39 39 35 33 33 30 30 31 30 29

90 27 25 24 23 23 23 22 20 20 18

100 18 19 21 20 20 19 15 15 15 14

110 15 16 15 15 14 15 14 14 13 12

120 11 10 9 9 9 9 9 7


0 4270 1302 1160 992 967 859 804 739 684

10 63 9 594 534 488 445 406 379 359 330 309

20 286 261 243 229 224 219 207 193 182 164

30 151 148 143 138 132 125 117 108 102 98

40 93 89 88 86 83 80 75 69 65 58

50 53 53 52 48 46 46 42 40 40 41

60 41 41 38 36 34 29 28 27 26 24

70 23 22 22 20 18 18 17 16 16 19

80 19 18 18 18 14 15 15 14 12 13

90 12 13 12 13 12 11 10 10 9 7

100 5 5 4 5 7 8 8 7 7 5

110 4 4 4 3 4 4 3 3 3 3

120 3 2 2 1 1 1 3 2

0169

KPAWin© (Version 1.2.9) Multiple Sample Report

Laboratory: ANALYTE: Uranium ANALYST: JPachella

Calibration Report Results

Low Calibration ID - Default High Calibration ID - None Date - 3/27/2018 9:32:50 AM

Calibration Report Results

Std Std Percent Time Reference

Range!Used!Sample IDI Cone I ID I Intercept I Uncert IDiscrepjGatesl Ratio jLifetimej R 2 L liW F_l..ags

Low + BCKGRND 0.000 24 5 .000 5-49 1.0000 248 .9240

Low + CAL STD 1 1. 000 U-12-1 381 20 25.076 5-49 1.0275 355 .9926

Low + CAL STD 2 5.000 U-12-2 1271 36 -3.625 5-49 1.0060 362 .9983

Low + CAL STD 3 10.000 U-12-3 2544 50 -.774 5-49 1.0182 375 .9987

Low + CAL STD 4 50.000 U-12-4 12572 112 .242 5-49 .9986 352 .9997

Low + CAL STD 5 100.000 U-12-5 24970 158 -.180 5-49 1.0177 368 .9998

Low + CAL STD 6 200.000 U-12-6 49977 224 .033 5-49 1.0341 293 .9999

Page 1 Date Printed - 3/27/2018 9:31:58 AM

0170

Low Range Calibration Curve

50000T

40000

. 30000 Intensity Intercept

20000

10000 __ ,/)±f

Qi illq:(,,, :

0 50

__ ,,,,,,//

,,,,,,-',,,,,,

,,,----m,,, ,,,," ,'

I I I

I I I

100 150 200

Concentration

0171

KPAWin© Single Sample Report - BckGnd


Configuration


None BCKGRND

BACKGROUND 5826

µg/1 1003 Config

1000 Release


Procedure ID: None Low

Default 1

Range: Calibration ID: Specific Gravity:


Reference Lifetime: LSR Time Gates: Sample Lifetime (µsec): Sample R 2 Intensity: Reference Ratio: Sample Intercept:

Interpreted Results

(Low)

BCKGRND

221 5 - 49

248 .924

1.000 24



03/27/2018 09:10 AM Uranium

JPachella 03/27/2018 09:12 AM


1003 Config


Flags

Sample:

0172

I n t e n s i t y

10000

1000

100

10

1 0 20

Net Intensities

Low: BCKGRND 3/27/2018 9:10:55 AM

"\

J\JlA ·11 ' \ \

;/ ·~ I~

\i

40 60 80

Time Gate

I I 100 120

I

o Sample 0 Ref

0173

Lab: No Lab Date: 3/27/2018 9:10:55 AM

Net Intensities

Low: BCKGRND Sample Intensities 0 1 2 3 4 5 6 7 8 9

0 7269 478 37 31 32 18 19 15 13

10 12 11 10 11 11 11 11 9 8 9

20 8 6 7 7 7 8 8 7 6 5

30 5 5 5 5 5 4 4 3 3 3

40 3 2 3 3 3 3 2 1 2 2

50 2 3 3 3 2 2 2 2 2 3

60 3 3 3 3 2 3 2 2 2 2

70 2 2 1 2 2 1 2 2 2 2

80 2 2 2 1 1 2 2 1 2 1

90 0 0 1 0 1 1 1 1 1 1

100 1 1 0 1 1 1 1 1 1 1

110 1 0 0 0 1 0 1 1 1 1

120 1 1 1 1 1 1 1 2

Low: BCKGRND Reference Intensities 0 1 2 3 4 5 6 7 8 9

0 4117 1168 1116 1009 941 832 796 738 681

10 627 581 542 503 467 432 410 374 345 327

20 313 286 268 251 234 221 208 203 193 189

30 173 162 150 140 128 123 117 113 106 103

40 96 90 87 87 80 82 85 83 77 75

50 69 60 56 54 54 53 52 51 51 47

60 43 44 43 39 37 39 36 36 36 36

70 34 33 31 30 29 28 27 25 22 24

80 21 20 20 23 21 23 24 23 22 21

90 19 18 19 18 18 17 18 15 14 14

100 13 12 12 13 13 13 14 13 13 14

110 14 13 14 13 11 11 10 10 11 13

120 11 11 10 9 9 9 14 8

0174

KPAWin© Single Sample Report - CalStd


Configuration


None CAL STD 1 CAL STD 1

5826

µg/1 1003 Config

1000 Release


Procedure ID: Range: Calibration ID: Specific Gravity:



Interpreted Results


None Low

Default 1

(Low) CAL STD 1

5 222

- 49 355

.993 1. 028

381

N/A N/A



03/27/2018 09:16 AM Uranium

JPachella 03/27/2018 09:17 AM


1003 Config

Standard ID: U-12-1 Standard Cone (µg/1): 1.000E+00


Flags

IDL Flags: MDL Flags: Sample:

0175

10000

I 1000 I ' ' n ' ' ' ' t ' ' e ' \

n \ s ' l i '·· , ... ,

t ~ y "

100

10

1 0

' ' " ' ' •,

', ' ' '

20

Net Intensities

Low: CAL STD 1 3/27/2018 9:16:15 AM

' ' ' " '· '"\

40 60 80

Time Gate

100 120

o Sample 0 Ref

0176

Lab: No Lab Date: 3/27/2018 9:16:15 AM

Net Intensities

Low: CAL STD 1 Sample Intensities 0 1 2 3 4 5 6 7 8 9

0 1106 363 355 373 304 320 297 295 285

10 284 273 257 243 227 218 211 201 191 183

20 174 170 165 161 156 148 144 142 133 133

30 125 116 110 112 106 103 104 102 92 89

40 88 82 76 77 74 74 75 75 70 69

50 65 61 58 59 57 52 49 49 47 46

60 48 47 42 39 37 32 32 33 31 31

70 33 34 35 32 29 27 23 24 26 28

80 27 26 22 21 19 18 18 21 21 19

90 20 20 17 17 17 17 17 17 17 17

100 16 14 13 11 12 13 13 12 13 11

110 11 12 14 13 11 12 11 9 9 11

120 10 10 10 11 10 9 7 3

Low: CAL STD 1 Reference Intensities 0 1 2 3 4 5 6 7 8 9

0 3790 1343 1120 1058 962 886 820 753 698

10 640 598 556 512 468 441 404 371 353 337

20 313 291 273 256 234 218 212 205 197 190

30 182 171 165 155 144 138 135 124 115 114

40 108 101 96 93 90 85 77 73 70 67

50 66 66 70 68 66 64 63 57 52 51

60 49 46 45 44 40 38 36 33 34 34

70 32 33 32 30 28 29 28 29 29 29

80 26 27 26 25 25 26 23 24 24 22

90 21 19 18 19 18 18 18 16 17 17

100 16 16 16 13 12 12 10 12 12 11

110 12 13 12 14 13 14 12 12 10 11

120 9 10 10 9 9 10 9 15

0177



Configuration



5826

µg/1 1003 Config

1000 Release



Default 1




Interpreted Results


(Low) CAL STD 2

5 223

- 49 362

.998 1.006

1271

N/A N/A



03/27/2018 09:20 AM Uranium

JPachella 03/27/2018 09:24 AM


1003 Config



Flags


0178

10000

I 1000

n t e n s i t y

100

10

1 0

Net Intensities

Low: CAL STD 2 3/27/2018 9:20:17 AM

20 40 60 80

Time Gate

100 120

o Sample 0 Ref

0179

Lab: No Lab Date: 3/27/2018 9:20:17 AM

Net Intensities


0 1455 1274 1203 1210 1086 1041 1001 959 912

10 877 854 825 793 772 752 717 687 670 651

20 617 603 585 560 538 517 501 481 468 446

30 424 402 386 373 368 358 351 335 323 306

40 298 293 282 266 259 252 242 244 241 230

50 217 204 198 188 181 178 173 160 152 147

60 138 134 133 128 126 124 121 116 118 112

70 106 99 94 83 83 82 78 78 80 72

80 71 71 67 66 66 62 57 58 53 52

90 51 51 47 45 43 45 43 42 44 40

100 37 35 30 28 30 28 28 30 28 26

110 28 27 25 24 23 22 20 21 20 20

120 20 20 19 19 17 14 17 6


0 3897 1302 1151 1083 978 868 811 740 688

10 651 600 552 507 461 424 392 372 355 334

20 309 288 268 251 235 225 205 189 176 167

30 155 158 153 150 146 141 132 125 120 112

40 106 101 98 87 85 82 80 74 72 70

50 66 62 58 57 55 54 49 48 45 41

60 37 37 36 35 36 35 32 35 32 29

70 28 30 26 25 23 21 19 17 16 16

80 15 15 15 14 13 13 11 11 11 13

90 14 14 12 13 13 11 11 13 12 11

100 11 11 10 10 8 8 7 7 7 8

110 7 7 6 6 5 5 4 4 4 5

120 6 6 6 6 6 6 8 7

0180



Configuration



5826

µg/1 1003 Config

1000 Release



Default 1



Reference Lifetime: LSR Time Gates: Sample Lifetime (µsec) Sample R 2 Intensity: Reference Ratio: Sample Intercept:

Interpreted Results

Detection Limit(IDL) Detection Limit(MDL)

(Low) CAL STD 3

5 220

- 49 375

.999 1.018

2544

N/A N/A



03/27/2018 09:24 AM Uranium

JPachella 03/27/2018 09:26 AM


1003 Config

Standard ID: U-12-3 Standard Cone (µg/1): 1.000E+0l

Specific Activity (Bq/g) 25000

Flags


0181

I n t e n s i t y

10000

1000

100

10

1 0 20

Net Intensities

Low: CAL STD 3 3/27/2018 9:24:48 AM

40 60 80 100

Time Gate

120

o Sample 0 Ref

0182

Lab: No Lab Date: 3/27/2018 9:24:48 AM

Net Intensities


0 2590 2403 2326 2263 2144 2139 1994 1928 1838 10 1788 1741 1687 1627 1584 1522 1465 1409 1361 1317 20 1278 1234 1184 1136 1089 1046 1006 977 955 929 30 899 874 848 816 785 770 738 717 689 653 40 621 597 573 551 547 536 527 511 494 480 50 467 447 428 421 408 387 368 359 347 334 60 327 314 298 294 284 272 274 264 248 237 70 224 217 215 206 201 196 188 181 174 168 80 164 160 156 152 151 152 147 141 137 131 90 121 116 116 114 109 104 105 99 94 90

100 89 81 81 79 81 80 77 76 74 74 110 69 71 67 63 56 55 50 48 46 44 120 48 48 46 44 42 37 39 28


0 4026 1250 1123 1047 975 831 803 731 694 10 637 588 536 508 460 433 416 393 369 344 20 319 283 263 236 228 225 215 203 190 180 30 164 165 158 151 138 129 118 112 110 103 40 101 91 88 84 84 81 82 82 74 70 50 66 65 63 62 59 57 56 51 50 49 60 47 44 43 40 38 36 34 32 34 33 70 32 30 29 25 23 22 23 24 25 26 80 25 25 24 22 21 20 17 15 16 15 90 16 14 15 14 12 13 15 16 16 17

100 15 14 12 12 11 11 10 9 9 9 110 9 9 9 9 8 7 8 8 7 6 120 6 5 5 5 6 6 12 7

0183



Configuration



5826

µg/1 1003 Config

1000 Release


Procedure ID: Range: Calibration ID: Specific Gravity:



Interpreted Results


None Low

Default 1

(Low)

CAL STD 4

5 223

- 49 352

1.000 .999

12572

N/A N/A



03/27/2018 09:26 AM Uranium

JPachella 03/27/2018 09:29 AM


1003 Config

Standard ID: U-12-4 Standard Cone (µg/1): 5.000E+0l


Flags


0184

I n t e n s i t y

100000

1000

100

10

1 0 20

Net Intensities

Low: CAL STD 4 3/27/2018 9:26:59 AM

40 60 80 100

Time Gate

120

o Sample 0 Ref

0185

Lab: No Lab Date: 3/27/2018 9:26:59 AM

Net Intensities


0 9735 11881 11456 10762 10422 10217 9817 9490 9118 10 8750 8396 8059 7732 7449 7186 6966 6720 6456 6231 20 5980 5737 5503 5351 5134 4962 4808 4654 4457 4329

30 4160 3981 3837 3686 3522 3390 3279 3166 3066 2961

40 2869 2768 2677 2570 2490 2387 2319 2237 2174 2079

50 2028 1945 1868 1794 1743 1657 1608 1554 1495 1443

60 1404 1350 1294 1246 1203 1167 1129 1091 1065 1028

70 979 93 9 927 890 854 828 794 748 724 708

80 689 659 644 624 591 563 559 534 519 503

90 492 462 452 433 429 411 400 385 377 353

100 342 331 315 298 285 276 267 260 257 249

110 234 230 227 216 216 213 202 188 179 170

120 165 160 159 157 153 150 144 145


0 4017 1192 1106 1008 933 846 785 724 672

10 635 584 551 514 474 432 403 369 341 323

20 304 287 265 251 233 222 210 200 192 183

30 173 160 156 144 137 128 121 117 111 105

40 103 101 98 93 91 83 78 73 71 67

50 66 63 62 58 53 50 47 42 40 38

60 41 41 41 41 38 35 34 32 34 34

70 33 34 33 30 30 27 24 23 23 21

80 21 19 18 19 17 17 16 15 12 12

90 10 11 11 12 15 14 14 13 13 11

100 11 10 9 8 9 10 10 10 10 9

110 8 7 6 7 6 6 7 8 6 7

120 7 7 7 8 7 7 11 6

0186



Configuration



5826

µg/1 1003 Config

1000 Release



Default 1




Interpreted Results


(Low) CAL STD 5

220 5 - 49

368 1.000 1.018 24970

N/A N/A



03/27/2018 09:29 AM Uranium

JPachella 03/27/2018 09:31 AM


1003 Config



Flags


0187

I n t e n s i t y

Net Intensities

Low: CAL STD 5 3/27/2018 9:29:54 AM

100000

10000

1000

100

10

1 +---------1------1--------+--------l------+-----+--

0 20 40 60 80 100 120

Time Gate

o Sample 0 Ref

0188

Lab: No Lab Date: 3/27/2018 9:29:54 AM

1\T .-.. .._ ,.. _ _...,..._,......_..._.,: ..J-..: ,...._,.... .l'-.IC l- .L.L.LL,.C.::,.J..LCI .l. l-.l.~CI


0 17901 23097 22756 21936 21114 20337 19603 18904 18231

10 17594 17005 16378 15770 15203 14621 14118 13591 13112 12652

20 12249 11824 11486 11119 10732 10392 10018 9648 9231 8920

30 8560 8229 7932 7720 7448 7199 6967 6757 6474 6252

40 6047 5860 5646 5542 5355 5144 4958 4779 4552 4408

50 4249 4094 3911 3795 3646 3579 3474 3369 3253 3146

60 3003 2890 2814 2729 2642 2564 2494 2415 2336 2242

70 2146 2082 2008 1945 1901 1873 1793 1724 1660 1595

80 1522 1471 1434 1382 1348 1317 1265 1200 1164 1107

90 1052 1044 1023 986 956 940 887 857 828 790

100 757 731 708 684 672 650 633 615 592 568

110 540 524 497 483 472 460 444 434 421 404

120 386 377 369 362 348 341 312 305


0 3982 1350 1213 981 923 851 789 728 673

10 642 590 550 516 487 448 419 388 357 327

20 305 287 262 245 231 210 195 186 181 171

30 170 167 161 154 149 138 132 127 116 106

40 103 97 88 87 85 79 76 74 68 65

50 66 62 58 57 55 50 48 48 46 47

60 49 46 45 43 40 35 36 32 33 33

70 33 29 29 30 27 27 28 26 22 20

80 18 16 20 21 21 21 21 17 18 17

90 16 15 16 14 14 13 14 14 15 14

100 14 16 14 13 11 10 8 9 8 9

110 10 10 9 9 9 8 7 6 6 6

120 5 6 5 6 5 5 4 6

0189



Configuration



5826

µg/1 1003 Config

1000 Release



Default 1




Interpreted Results


(Low) CAL STD 6

5 217

- 49 293

1.000 1.034 49977

N/A N/A



03/27/2018 09:32 AM Uranium

JPachella 03/27/2018 09:34 AM


1003 Config



Flags


0190

I n t e n s i t y

Net Intensities

Low: CAL STD 6 3/27/2018 9:32:50 AM

100000

10000

1000

100 '-, __

10

1+------+.--------+.--------1-------t-------+------f---

0 20 40 60 80 100 120

Time Gate

o Sample 0 Ref

0191

Lab: No Lab Date: 3/27/2018 9:32:50 AM

!:'!et T,-,t-0,-,c-1; t--: C('""t ..l- ........... - ...... 1---'...I.. '-"...I..._.'"-'


0 34153 45378 44175 42508 40923 38444 36803 35085 33612 10 32200 30785 29547 28156 26849 25577 24479 23368 22354 21369 20 20482 19582 18731 17965 17160 16410 15676 15023 14333 13677 30 13091 12515 11943 11457 11012 10499 10103 9671 9235 8832 40 8508 8110 7738 7423 7136 6826 6523 6279 5980 5677 50 5418 5193 4998 4815 4647 4450 4272 4039 3852 3667 60 3509 3358 3227 3093 2959 2840 2713 2607 2499 2385 70 2285 2185 2091 1994 1910 1820 1733 1649 1582 1531 80 1476 1420 1367 1319 1253 1190 1151 1104 1061 1017 90 979 928 906 859 821 784 749 702 674 647

100 629 602 569 541 514 485 473 456 437 416 110 395 376 362 350 338 337 326 312 304 297 120 278 263 248 238 225 213 214 183


0 3959 1335 1119 1028 944 975 827 769 691 10 636 585 551 508 474 437 405 372 346 318 20 303 288 274 257 237 219 203 190 177 172 30 160 156 144 138 133 127 120 117 113 110 40 107 102 99 92 84 82 77 72 67 62 50 56 52 51 54 53 51 53 53 47 47 60 47 43 38 37 34 33 31 30 30 32 70 27 27 26 25 25 26 23 21 19 17 80 15 15 16 17 16 17 18 18 17 18 90 17 15 14 13 14 13 13 13 13 10

100 11 11 12 11 12 11 10 9 10 9 110 9 11 9 9 9 11 10 8 7 6 120 4 4 5 5 5 6 7 5

0192

SECTIONX

ANALYTICAL DAT A (ISOTOPIC THORIUM)

0193

Eberline Analytical


Analysis Sheet

Work Order

Analysis Code

Run

Internal Fraction

01

02

I

! Sample

Desc

LCS

18-03110 ThlSO Run 1

Client ID

LCS -

---------------t

MBL : BLANK i

Login CPM


Sample Date

03/23/18 00:00

03/23/18 00:00

Sample Aliquot

1.0000E+00

1.0000E+00

I I 3/23/2018 I 03 DUP I~- ___ ou_-_1-_00_8 ___ ---,----+-------+----------1

4/12/2018 04 DO I OU-1-008 I I---------------~

Date Received

Lab Deadline

38

38

03/19/18 18:02 5.0000E-01

03/19/18 18:02 5.0000E-01


Project WESTLAKE

Report Level 4

Activity Units pCi

Aliquot Units

Matrix WA

Method EPA 907 .0 Modified


Radiometric Tracer Th-229

Radiometric Sol# Th-18a


Carrier


I I I

!

I

--·-- I I I • ···

• SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. h Indicates estimated SAF value.


0194

Eberline Analytical

Oak Ridge Laboratory Analysis Sheet

Internal Sample J Tracer

Fraction Desc I Aliquot(g)

01 LCS 0.4666

02 MBL 0,2337

03 DUP 0,2314

04 DO 0,2306

I


10,5

52

5,2

52

i !

i i

!

I

Radiometric Tracer (pCi)

18-03110 ThlSO Run 1

i Radiometric [ Grav Carrier I Grav Filter

%Rec Added(ml) [ Tare (g)

' I 0,00 I I I

0,00

' 0,00

0,00

I I

i

I

' '

I


I I

• SAF1 is used for-Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. A Indicates estimated SAF value,

** Actual mass exceeded the calibration curve range. Results should be qualified as appropriate,

i Grav Filter Grav

Net(g) %Rec

I i

I


i i

Mean

I

SAF SAF %Rec 1* 2*

i I !

-

i --

!

I

I !

I '

I

!

I

0195


Analysis Sheet


01 LCS

02 MBL

03 DUP

04 DO

1---

i I

~--

Rough Prep Date

I I i

Rough Prep I

Prep

I By I

Date

i

03/28/18 08:36 j

I 03/28/18 08:36 '

03/28/18 08:36

03/28/18 08:36

I

I

I I

18~03110 ThlSO Run 1

Prep By

JHARVEY

JHARVEY

JHARVEY

JHARVEY

Sep to Date/rime

* SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. " Indicates estimated SAF value.


I Sep to

By

'

i I I

i

i

I

!

' !

'


I Sep t1

I Sep t1

Date/rime By

--

0196


<( Lab Fraction

Nuclide

01 TH-228

~

a, "0

8 -!!! ~ "iii C: q:

i1 0

T"'"

0 ti) -.c I-

1/) C .Q .!!? (.) Q)

C iii -C Q)

E C 0

·= > C w 0 ~ <(

02 TH-228

03 TH-228

04 TH-228

Sample Desc

LCS

MBL

DUP

DO


Work Order: 18-03110-ThlSO-1

Client Activity Error Estimate MDA

Identification Units Results

LCS pCi/1 5.81E+00 1.09E+00 1.20E-01

BLANK pCi/1 5.29E-03 3.43E-02 9.33E-02

OU-1-008 pCi/I -3.87E-02 7.02E-02 2.14E-01

OU-1-008 pCi/I 3.44E-03 1.14E-01 2.74E-01

LCS LCS Known %R

4.80E+00 121.11


I LCS RPD MDA Blank Flag Flag Flag Flag

OK OK

OK OK

NA OK

OK

0197


,: Lab Nuclide

Fraction

01 TH-228

;r-~ 0::

02 TH-228

03 TH-228

-04 TH-228

{: 0 0 0 u, .!!,!

~ -CII .c C: I-q;

1/) C: 0

-~ (.J Cl> C ns -11 C: Cl>

0 E C: 0 ... ·s;: C: w 0 :s <(

Sample Desc

LCS

MBL

DUP

DO




I Date Aliquot %Rec %Rec %Rec

03/23/18 00:00 1.00E+00 71.01 0.00 0.00

03/23/18 00:00 1.00E+00 85.02 0.00 0.00

03/19/18 18:02 5.00E-01 95.72 0.00 0.00

03/19/18 18:02 5.00E-01 90.10 0.00 0.00

SAF I


SeptO

I Sept1

DatefTime DatefTime

0198


~ Lab

Nuclide Fraction

01 TH-228

~ I ~ 02 TH-228

03 TH-228

04 TH-228 .g 0 0 0 en ,!!! ~ -111 .c i::: I-'CC

u, C 0

.!!? (.) Q)

0 iu -~I C Q)

E C 0 ... '> C w 0 :ii: <(

Sample Desc

LCS

MBL

DUP

DO



Counting

I Halflife

Detect Carrier Count I Counts Date/Time (days) Time

1

03/30/18 08:10 A_Spec Alpha_040 170 2.73 E+02

03/30/18 08: 10 A_Spec Alpha_041 170 3.20 E-01

03/30/18 08:10 A_Spec Alpha_042 170 -1.19 E+00

03/30/18 08:10 A_Spec Alpha_043 170 1.10 E-01

I Bkg CPM

4.00 E-03

4.00 E-03

7.00 E-03

1.70 E-02


Eff

17.6

18.8

17.2

19

0199


~ Lab I Nuclide

Fraction

01 TH-230

;r~ a:

02 TH-230

03 TH-230

04 TH-230

.g 0 0 0 UJ .!!!

i -Cll ..c: C: I-q:

fl) C: 2

.!:!? 0 Q)

C ni -~I C: Q)

E C: 0 ... "> C: w 0 ~ <(

Sample Desc

LCS

MBL

DUP

DO


Work Order: 18-0311 0-ThlSO-1

Client Activity Results Error Estimate I MDA

Identification Units I

LCS pCi/I 6.64E+00 1.22E+00 1.34E-01

BLANK pCi/I 1.07E-01 9.52E-02 1.18E-01

OU-1-008 pCi/I 1.S0E-01 1.59E-01 2.03E-01

OU-1-008 pCi/I 2.83E-01 1.99E-01 1.SSE-01

LCS LCS

Known %R

5.37E+00 123.56


LCS RPD MDA Blank

Flag Flag Flag Flag

OK OK

OK OK

NA OK

OK

..

0200


( Lab Nuclide

Fraction

01 TH-230

§ a::

.g 0 0 -r!? ~ ai C: ct

II

"'"""

0 en -.c ~

1/) C: 0

:~ c., Cl)

C cu -C: Cl)

E C: 0 ... ·s: C: w 0 :i: <(

02 TH-230

03 TH-230

04 TH-230

Sample Desc

LCS

MBL

DUP

DO



Sample Sample Radiometric Grav Mean I

Date Aliquot %Rec %Rec %Rec I

03/23/18 00:00 1.00E+00 71.01 0.00 0.00

03/23/18 00:00 1.00E+00 85.02 0.00 0.00

03/19/18 18:02 5.00E-01 95.72 0.00 0.00

03/19/18 18:02 5.00E-01 90.10 0.00 0.00

SAF


SeptO

I Sept1

Date/Time Date/Time

0201


~ ~

§ a:

-t 0 0 -!!! ~ iii i::: q:

1: -~ 0

~

0 U) -.c I-

rn C: 0

.!!? (.) Q)

C nJ -C: Q)

E C: 0 ... . > C: w 0 ~ <(

Lab Nuclide

Fraction

01 TH-230

02 TH-230

03 TH-230

04 TH-230

! Sample

Desc

LCS

MBL

DUP

DO



Counting

I Halflife

Detect Carrier Count

Counts DatefTime (days) Time

03/30/18 08:10 A_Spec Alpha_040 170 3.12 E+02

03/30/18 08:10 A_Spec Alpha_041 170 6.47 E+00

03/30/18 08:10 A_Spec Alpha_042 170 4.98 E+00

03/30/18 08:10 A_Spec Alpha_043 170 9.15 E+00

8kg CPM

6.00 E-03

9.00 E-03

6.00 E-03

5.00 E-03


Eff

17.6

18.8

17.2

19

0202


~ Lab

Nuclide Fraction

01 TH-232

;r~ 0::

02 TH-232

03 TH-232

04 TH-232 Cl) 0 "0 0 0 en -!!! ~ -QI .c c:: I-q;

1/) C: .2

.!!? (.) Q)

C

.fi

~I C: Q)

E C: 0 ... ·s: C: w 0 :E <i:

Sample Oesc

LCS

MBL

DUP

DO



Client Activity Results I Error Estimate

I Identification Units MDA

LCS pCi/I 5.S0E+00 1.09E+00 1.65E-01

BLANK pCi/I -3.S0E-03 6.11E-02 1.S0E-01

OU-1-008 pCi/I 1.58E-02 6.57E-02 1.69E-01

OU-1-008 pCi/I -5.87E-03 6.64E-02 2.04E-01

LCS LCS Known %R

4.80E+00 120.87


LCS RPO MDA Blank

Flag Flag Flag Flag

OK OK

OK OK

NA OK

OK

0203


~ ~ I ~ -

Cl> 'ti 0

(.)

,!!! .; <II c::

C(

-~

0 en -.c I-

in C: .2 .!!! (.) Q)

C ns -C: Q)

E C: 2 ·s: C: w 0 :i: <(

Lab Nuclide

Fraction

01 TH-232

02 TH-232

03 TH-232

04 TH-232

Sample Desc

LCS

MBL

DUP

DO




I Date Aliquot %Rec %Rec %Rec

03/23/18 00:00 1.00E+00 71.01 0.00 0.00

03/23/18 00:00 1.00E+00 85.02 0.00 0.00

03/19/18 18:02 5.00E-01 95.72 0.00 0.00

03/19/18 18:02 5.00E-01 90.10 0.00 0.00

SAF


SeptO Sept1

DatefTime DatefTime

0204


( Lab I

Fraction Nuclide

01 TH-232

;r~ a::

02 TH-232

03 TH-232

04 TH-232 CII 0 b 0 0 u, -!!! ~ -Ill .c t: ..... q:

II) C:

.2 -~ (.) Cl>

C ns -ll C: Cl> E C: 0 ... ·s; C: w 0 :!!: <

I Sample Desc

LCS

MBL

DUP

DO



Counting Halflife i Count

DatefTime (days) Detect Carrier

Time Counts

03/30/18 08:10 A_Spec Alpha_040 170 2.73 E+02

03/30/18 08:10 A_Spec Alpha_041 170 -2.30 E-01

03/30/18 08:10 A_Spec Alpha_042 170 4.90 E-01

03/30/18 08:10 A_Spec Alpha_043 170 -1.90 E-01

Bkg I CPM '

1.20 E-02

1.90 E-02

3.00 E-03

7.00 E-03


Eff

17.6

18.8

17.2

19

0205

y /

0 ·S::

Count Room Report


Internal Sample Client

Fraction Desc ID

01 LCS LCS

02 MBL BLANK

03 DUP OU-1-008

04 DO OU-1-008

...

I i I

I

18-0311 0-ThlSO-1 (pCi/I) in WA

Tracer ID: Th-18a

I

I I Sample I Sample Tracer I Date I

Aliquot Aliquot (g) i

03/23/18 00:00 1.0000 0.4666

03/23/18 00:00 1.0000 0.2337

03/19/18 18:02 0.5000 0.2314 I

03/19/18 18:02 0.5000 0.2306

I I I ;

I

I

I I I I

i I

!

i I

i I

Tracer Radiometric ACT(dpm) Tracer (pC1J

10.4798

5.2489

5.1972

5.1793

I

i

--·------- --

_, - --- ----- ..

-·---------

Printed: 3/30/2018 4:59 AM

Page 1 of 1

\ Radiometric I

SAF i SAF

I %Rec 1· I 2· I

0.00

0.00

0.00 I I

0.00

I

I I !

i I I I !

I

I

!

I

I

0206


Activity Isotope

I Sol#

dpmlg

Th-228 i Th-Sb 103.560

Th-230 I Th-1b 23.520

Th-232 I Th-8b 103.560

fraction Isotope I

Sol#

01 Th-229 Th-18a

02 Th-229 Th-18a

03 Th-229 Th-18a

04 Th-229 Th-18a

I I

Version 2.0 08/99

Solution i Approx Date I Addition

3/28/20181 0.100

3/28/20181 0.500 !

3/28/2018! 0.100

Tracers Activity I Solution dpm/g Date

22.460 3/28/2018

22.460 3/28/2018

22.460 3/28/2018

22.460 3/28/2018

!

' ' i



ThlSO 3/28/2018 8:31 JHARVEY

LCS MS LCSD MSD LCS MS Volume Volume Volume Volume Known

1 Error Added i Error

Used{g) Used (g) Used{g) Used (g) pCi I Estimate pCi ! Estimate

0.1028 4.8of 0.173 0.00 0.000

0.5070 I

5 371 0.145 0.00 0.000

0.1028 4.801 0.173 0.00 0.000

Balance Printer Tapes Volume Approx Tracer Used(g) Addition

0.4666 0.2200

0.2337 0.2200

0.2314 0.2200

0.2306 0.2200


Technician Initials Witness Initials

LCSD MSD Known Error I Added Error

pCi Estimate pCi I Estimate

o.oo I 0.0001 o.oo, 0.000

o.oo I 0.0001 o.oo ! 0.000

0.00 I 0.0001 0.00 i 0.000

LCS

Matrix Spike

0207

Lab



Fraction Client ID

01 LCS

02 BLANK

03 OU-1-008 04 OU-1-008

~-

Comments

Sample

Type

LCS MBL

DUP DO

Aliquot Worksheet

Analysis Code Rpt Units Lab Deadline

ThlSO liters 4/12/2018

Muffle Data Dilution Data Aliquot Data Ratio

Post/Pre No of Dils Oil Factor Ratio Aliquot Net Equiv

1.0000E+OO 1.0000E+OO

1.0000E+OO 1.0000E+OO

5.0000E-01 5.0000E-01·

5.0000E-01 5.0000E-01

Technician: ~Ll,N-(~~

Technician

JHARVEY

MS Aliquot Data


H-3 Solids Only

Aliquot Net Equiv WaterAaaeai-A~

(ml) , Aliq

!

i

I

!

l

0208

Jt;Apex-Alpha,. Sample Description: Spectrum File: Batch Identification:


1803110A-TH Sample Identification: Sample Geometry: Procedure Description:




01 Shelf 2 Th iso


<not performed>

1. 000E+000 +!- 0.000E+000 3/30/2018 6:43:14 3/30/2018 8:10:31


Th229 S TH-18A 0.467 mL 0.1248 +/- 0.0093

AM AM

liter


9:34:27 AM


Control Certificate Name: NatTh Th-8 Chem. Recov. of Control: TH-232 1.208730 +/- 0.121742


Nuclide

TH-227 TH-228 TH-229 T TH-230 TH-232

Energy (MeV)

5.783 5.394 4.872 4.645 3.970

PEAK AREA REPORT

Net Pk Area

8.98 273.32 222.26 311. 98 272.96

Pk Area Error%

69.62 11. 87 13.28 11.12 11. 92

Ambient Backgnd

1. 02 0.68 3.74 1. 02 2.04

Reagent Backgnd

0.00E+000 0.00E+000 0.00E+000 0.00E+000 0.00E+000

FWHM (keV)

0.0 10.4 12.0

4.5 10.4


Nuclide

TH-227 TH-228 TH-229 TH-230 TH-232

Id Conf.

0. 977 1.000 1.000 0. 996 0. 996


Energy (keV)

5850.00* 5400.00* 4872.00* 4672.00* 3997.00*


l.96E-001 +/- l.39E-001 5.81E+000 +/- l.09E+000 4.74E+000 +!- 6.92E-001 6.64E+000 +!- l.22E+000 5.80E+000 +/- l.09E+000

114 3/.Jrjri

MDA (pCi/liter

l.37E-001 +/- 2.00E-002 1. 20E-001 +!- 1. 75E-002 2.05E-001 +/- 2.99E-002 1. 34E-001 +/- l.96E-002 l.65E-001 +/- 2.41E-002

0209

60

55

50

45

40

35 V) .µ C: ::::s 8 30

25

20

15

10

5

0000209931.CNF

9 i=

O l,\~lft\llllMmw nil \NI wwum, 1 '" , r 1" ,I w Mlll\!111111!\mVII m1r I 'I . " ,, 3500 l/1. i Iii iliilmJ,r:', 111ill/111VIEll 11

4000

ROI Type: 1

4500 5000 Energy(kev)

Live Time :10200.000 sec Real Time :10200.300 sec start: 1:3473.6(kev) Stop : 1024:6542.9(keV) Acq. start :Fri Mar 30 08:10:31 2018

1 1 ~ I 111!1\IVIIIWll rn:;, ,'1 q ' ·1 II I ! ! 111,111111nm1 I 11 I

5500 6000 6500

ROI Type: 3

0210

Channel Data Report 3/30/2018 11:10:39 AM Page 1


Sample Title: 01


Channell------l-------1-------1-------1-------1------- 1-------1-------1 1: 1 1 0 1 0 0 1 0

9 : 1 0 1 0 1 1 1 0

17: 4 0 1 0 2 1 0 0

25: 1 1 0 0 0 1 1 0

33: 0 1 0 0 1 0 0 2

41: 0 1 2 1 2 0 1 0

49: 2 2 2 1 2 0 1 0

57: 0 0 3 3 0 2 2 1

65: 1 1 1 1 2 1 0 0

73: 1 0 1 1 1 1 3 3

81: 1 2 2 2 2 0 1 0

89: 1 1 0 1 0 3 2 2

97: 0 0 2 1 0 1 4 0

105: 3 2 0 2 5 0 4 3

113: 3 5 1 1 0 2 1 3

121: 1 3 2 2 3 2 6 3

129: 4 5 3 4 3 2 4 4

137: 6 6 6 3 6 8 8 4

145: 1 9 3 5 4 5 2 7

153: 12 5 9 2 5 7 5 11

161: 5 8 9 8 5 8 11 5

169: 5 6 7 6 6 7 7 5

177: 11 12 13 4 5 1 6 3

185: 5 4 1 1 1 0 2 0

193: 0 0 1 0 0 0 0 0

201: 0 0 0 1 0 0 0 0

209: 0 0 0 0 0 0 0 0

217: 0 0 0 0 1 0 0 0

225: 0 1 0 0 0 0 1 0

233: 0 0 0 0 0 0 0 0

241: 0 0 1 0 1 0 0 0

249: 0 3 1 0 0 0 0 0

257: 1 1 0 0 1 0 0 0

265: 0 0 1 1 1 2 1 1

273: 0 0 0 0 0 0 0 0

281: 0 0 2 1 2 0 0 2

289: 1 1 2 0 1 1 0 0

297: 0 0 0 1 0 1 1 0

305: 3 1 1 0 1 1 2 1

313: 1 0 1 1 2 2 3 2

321: 0 0 4 1 1 2 3 1

329: 1 2 0 1 0 1 3 4

337: 0 5 2 4 0 1 6 4

345: 4 2 0 1 2 1 2 6

353: 4 1 6 2 2 5 2 3

361: 3 6 3 5 1 1 3 3

0211


369: 6 9 8 2 3 3 5 7

Sample Title: 01

Channell------l-------1-------1-------1-------I-------I-------I-------I 377: 5 10 9 7 4 12 4 4

385: 6 9 7 4 5 4 12 10

393: 9 11 7 11 7 11 6 10

401: 6 7 9 8 4 8 8 5

409: 7 4 2 3 3 1 0 2

417: 4 2 1 3 0 0 2 5

425: 1 1 1 2 2 3 3 0

433: 1 4 3 1 1 2 1 1

441: 3 5 5 1 2 5 5 6

449: 4 1 1 0 3 5 4 4

457: 4 0 3 2 2 3 5 3

465: 2 5 6 3 3 3 1 4

473: 1 0 2 2 4 2 4 0

481: 1 3 1 4 1 4 1 0

489: 2 1 1 4 2 1 4 0

497: 2 0 1 0 2 0 1 3

505: 0 0 2 2 0 1 1 0

513: 0 0 1 1 0 1 1 2

521: 1 2 1 2 1 4 1 1

529: 0 1 1 0 0 0 0 0

537: 1 0 1 0 0 0 0 3

545: 1 1 3 0 0 0 1 1

553: 1 1 1 1 1 0 3 2

561: 1 1 3 3 1 0 0 1

569: 1 0 1 3 1 0 0 1

577: 0 2 0 4 2 4 2 2

585: 0 3 2 2 3 1 0 3

593: 2 1 2 2 3 3 5 6

601: 0 4 5 2 2 4 3 6

609: 5 6 4 6 3 6 6 8

617: 11 9 5 5 3 8 6 5

625: 8 5 7 7 7 10 9 5

633: 7 12 5 10 4 5 6 6

641: 8 12 7 4 11 10 6 14

649: 11 16 5 11 10 5 10 1

657: 3 3 3 2 1 0 0 0

665: 0 0 0 0 0 0 0 0

673: 0 0 1 0 0 0 0 0

681: 0 0 0 0 0 1 0 0

689: 0 0 0 0 1 1 1 0

697: 0 0 0 2 0 1 0 0

705: 1 1 0 0 0 1 1 0

713: 1 2 0 0 2 0 2 0

721: 1 0 1 1 1 0 2 3

729: 0 3 1 1 3 3 1 4

737: 3 1 0 1 1 2 1 1

745: 0 1 1 0 0 1 1 0

753: 0 0 0 0 0 0 0 0

761: 0 0 0 0 0 0 0 0

769: 0 0 0 0 0 1 0 0

777: 0 0 0 0 0 0 0 0

785: 0 0 0 0 0 0 0 0

793: 0 0 0 0 0 0 0 0

0212


801: 0 0 0 1 0 0 0 0

Sample Title: 01

Channell------l-------l-------l-------l-------l-------1-------1-------1 809: 1 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 1 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0

865: 1 1 0 0 0 0 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 1 0 0 0 0

897: 0 0 0 0 1 0 0 0

905: 0 0 0 0 0 0 0 1

913: 0 1 0 1 0 0 0 0

921: 2 0 1 0 1 0 1 1

929: 1 1 1 1 0 0 0 0

937: 2 0 1 2 1 2 4 1

945: 0 0 1 0 0 1 1 0

953: 1 0 0 0 1 0 0 0

961: 0 0 0 0 0 0 0 0

969: 0 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 1 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0213

~!t'Apex-Alpha"' Sample Description: Spectrum File: Batch Identification:






02 Shelf 2 Th iso


<not performed>

1. 000E+000 3/30/2018 3/30/2018

170.0

+/- 0.000E+000 liter 6:43:14 AM 8:10:27 AM


Th229 S TH-18A

0.0143

Counting Efficiency:

0.234 mL 0.1603 +/-0.1885 +/-0.8502 +/-

0.0033 on 2/16/2018 0.0775

9:34:24 AM



Nuclide

TH-227 TH-228 TH-229 T TH-230 TH-232

Energy (MeV)

5.792 5.304 4.878 4.600 4.039

0.175 MeV

PEAK AREA REPORT

Net Pk Area

3.83 0.32

142.98 6.47

-0.23

Pk Area Error%

102.72 646.93

16.46 87.07

1605.4

Ambient Backgnd

0.17 0.68 1. 02 1. 53 3.23

Reagent Backgnd

0.00E+000 0.00E+000 0.00E+000 0.00E+000 0.00E+000

FWHM (keV)

3.0 3.0 5.9 3.0 3.0


Nuclide

TH-227 TH-228 TH-229 TH-230 TH-232

Id Conf.

0. 983 0.953 1. 000 0.973 0. 991


Energy (keV)

5850.00* 5400.00* 4872.00* 4672.00* 3997.00*


6.49E-002 +!- 6.77E-002 5.29E-003 +!- 3.43E-002 2.38E+000 +/- 4.17E-001 l.07E-001 +!- 9.52E-002

-3.80E-003 +!- 6. llE-002

1t4S .3/3bf1

MDA (pCi/liter

7.08E-002 +/- l.24E-002 9.33E-002 +!- 1. 64E-002 l.05E-001 +/- l.84E-002 l.18E-001 +/- 2.07E-002 1. 50E-001 +!- 2.64E-002

0214

60

55

50

45

40

35 V> ...... s:::: :::I

8 30

25

20

15

10

5

0000209917.CNF

Live Time :10200.000 sec Real Time :10200.300 sec start: 1:3471.S(kev) stop : 1024:6544.G(kev) Acq. Start :Fri Mar 30 08:10:27 2018

0 [I I I I I j'" I ~ . ,, ., I I r ., .. :,·· .··· . ~

3500 I I ·- ,- ,, I I I l>A1 I \NI' !!\:\Ii!,, 1i,1J! ~ :::::. , . ,I ,,1 . II/iii il'i !r y ' I! ,_. ~ I',,,. I' "' I 1\ I i= I! I !I I, :q!, I

4000 4500 5000 Energy(kev)

5500 I I ! I I I I I

6000 6500

ROI Type: 1 ROI Type: 3

0215



Sample Title: 02


Channell------l-------l-------l-------l-------1-------1-------1-------I 1: 0 0 0 0 0 0 0 0

9: 0 0 0 0 0 0 0 0

17: 0 0 0 0 0 0 0 0

25: 0 0 0 0 0 0 0 0

33: 0 0 0 0 0 0 0 0

41: 0 0 0 0 0 0 0 0

49: 0 0 0 0 0 0 0 0

57: 0 0 0 0 0 0 0 0

65: 0 0 0 0 0 0 0 0

73: 0 0 0 0 0 0 0 0

81: 0 0 0 0 0 0 0 0

89: 0 0 0 0 0 0 0 0

97: 0 0 0 0 0 0 0 0

105: 0 0 0 0 0 0 0 0

113: 0 0 0 0 0 0 0 0

121: 0 0 0 0 0 0 0 0

129: 0 0 0 0 0 0 0 0

137: 0 0 0 0 0 0 0 0

145: 0 0 0 0 0 0 0 0

153: 0 0 0 0 0 0 0 0

161: 0 0 0 0 0 0 0 0

169: 0 0 0 0 0 0 0 0

177: 0 0 1 0 0 0 0 0

185: 0 0 0 0 0 1 0 0

193: 0 0 0 0 0 0 0 1

201: 0 0 0 0 0 0 0 0

209: 0 0 0 0 0 0 0 0

217: 0 0 0 0 0 0 0 0

225: 0 0 0 0 0 0 0 0

233: 0 0 0 0 0 0 0 0

241: 0 0 0 0 0 0 0 0

249: 0 0 0 0 0 0 0 0

257: 0 0 0 0 0 0 0 0

265: 0 0 0 0 0 0 0 0

273: 0 0 0 0 0 0 0 0

281: 0 0 0 0 0 0 0 0

289: 0 0 0 0 0 0 0 0

297: 0 0 0 0 0 0 0 0

305: 0 0 0 0 0 0 0 0

313: 0 0 0 0 0 0 0 0

321: 0 0 0 0 0 0 1 0

329: 0 0 0 0 0 0 0 0

337: 0 0 0 0 0 0 0 0

345: 0 0 0 0 0 0 0 0

353: 0 0 0 0 0 2 0 0

361: 0 1 0 0 0 0 0 0

0216


369: 0 0 0 0 0 0 0 0

Sample Title: 02

Channell------l-------1-------1-------1-------I-------I-------I-------I 377: 0 0 0 1 0 0 0 0

385: 0 0 0 0 0 0 0 0

393: 0 0 0 0 0 0 0 0

401: 1 0 0 0 0 0 0 0

409: 0 1 0 0 0 0 0 0

417: 1 0 0 0 0 0 0 0

425: 0 0 2 0 0 2 1 1

433: 2 1 1 0 0 1 0 1

441: 2 2 0 1 1 0 4 3

449: 5 4 1 2 2 6 3 3

457: 2 2 7 4 2 2 1 1

465: 2 1 2 3 0 4 3 4

473: 3 2 0 2 3 0 1 0

481: 1 3 3 0 1 2 1 1

489: 0 3 1 2 2 0 1 1

497: 0 2 0 0 1 0 0 0

505: 0 1 0 0 1 2 0 0

513: 1 1 2 0 0 0 0 3

521: 1 0 2 1 0 0 0 0

529: 0 0 1 1 0 0 0 0

537: 0 0 0 0 0 0 0 0

545: 0 0 1 0 0 0 0 0

553: 0 0 0 0 0 0 0 0

561: 0 0 0 0 0 0 0 0

569: 0 0 0 0 0 0 0 0

577: 0 0 0 0 0 0 0 0

585: 0 0 0 0 0 0 0 0

593: 0 0 0 0 0 0 0 0

601: 0 0 0 0 0 0 0 0

609: 0 0 1 0 0 0 0 0

617: 0 0 0 0 0 0 0 0

625: 0 0 0 0 0 0 0 0

633: 0 0 0 0 0 0 0 0

641: 0 0 0 0 0 0 0 0

649: 0 0 0 0 0 0 0 0

657: 0 0 0 0 0 0 0 0

665: 0 0 0 0 0 0 0 0

673: 0 0 0 0 0 0 0 0

681: 0 0 0 0 0 1 0 0

689: 0 0 0 0 0 0 0 0

697: 0 0 0 0 0 0 0 0

705: 0 0 0 0 0 0 0 0

713: 0 0 0 0 0 0 0 0

721: 0 0 0 0 0 0 0 0

729: 0 0 0 0 0 0 0 0

737: 1 0 0 0 0 0 0 0

745: 0 0 0 0 0 0 0 0

753: 0 0 0 0 0 0 0 0

761: 0 0 0 0 1 0 0 0

769: 0 0 0 0 1 1 0 0

777: 0 0 0 0 0 1 0 0

785: 0 0 0 0 0 0 0 0

793: 0 0 0 0 0 0 0 0

0217


801: 0 0 0 0 0 0 0 0

Sample Title: 02

Channell------l-------l-------l-------l-------1-------1-------1-------I 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0

865: 0 0 0 0 0 0 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 0 0 0 0 0

897: 0 0 0 0 0 1 0 0

905: 0 0 0 0 0 0 0 0

913: 0 0 0 0 0 0 0 0

921: 0 0 0 0 0 0 0 0

929: 0 0 0 0 0 0 0 0

937: 0 0 0 0 0 0 1 0

945: 0 0 0 0 0 0 0 0

953: 0 0 0 0 0 0 0 0

961: 0 0 0 0 0 0 0 0

969: 0 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0218

¢t(A Al h TM ~~~~J-\pex- p a Sample Description: Spectrum File: Batch Identification:


1803110A-TH





03 Shelf 2 Th iso


<not performed>

5.000E-001 3/19/2018 3/30/2018

170.0

+/- 0.000E+000 liter 6:43:14 AM 8:10:29 AM


Th229 S TH-18A 0.231 mL 0.1649 +/- 0.0147


9:34:23 AM



Nuclide

TH-227 TH-228 TH-229 T TH-230 TH-232

Energy (MeV)

5.879 5.335 4.870 4.644 3.955

0.175 MeV

PEAK AREA REPORT

Net Pk Area

0.98 -1.19

145.64 4.98 0 .49

Pk Area Error%

294.85 180.60

16.33 97.79

416.98

Ambient Backgnd

1.02 1.19 1.36 1.02 0.51

Reagent Backgnd

0.00E+000 0.00E+000 0.00E+000 0.00E+000 0.00E+000

FWHM (keV)

3.0 0.0 3.4 3.0 3.0


Nuclide

TH-227 TH-228 TH-229 TH-230 TH-232

Id Conf.

0.996 0.978 1.000 0. 996 0.991


Energy (keV)

5850.00* 5400.00* 4872.00* 4672.00* 3997.00*


3.23E-002 +/- 9.55E-002 -3.87E-002 +!- 7.02E-002

4.70E+000 +!- 8.20E-001 1.60E-001 +!- 1.59E-001 1.58E-002 +!- 6.57E-002

Af1 3/3o/(~

MDA (pCi/liter

2.08E-001 +/- 3.62E-002 2.14E-001 +!- 3.73E-002 2.21E-001 +!- 3.86E-002 2.03E-001 +!- 3.53E-002 1.69E-001 +!- 2.94E-002

0219

60

55

50

45

40

35 V)

-1-' s::: :::J

8 30

25

20

15

10

5 ~ = ~ ' cc l-

0000209932.CNF

Live Time :10200.000 sec Real Time :10200.300 sec Start: 1:3502. ?(kev) Stop : 1024:6565.S(kev) Acq. Start :Fri Mar 30 08:10:29 2018

' ,, I ' ' " I I ' ' 'l'I 'I" I~ ,I 11 I IA I I I A I I, I I I A I I I o I I I I ,I I I I <' Iii 11 1 I I

4000

ROI Type: 1

4500 5000 Energy(kev)

5500 6000 6500

ROI Type: 3

0220


******************************************************* ***** s P E C T R A L DAT A R E P O R T ***** *******************************************************

Sample Title: 03


Channell------l-------1-------1-------1-------I-------I-------I-------I 1: 0 0 0 0 0 0 0 0

9 : 0 0 0 0 0 0 0 0

17: 0 0 0 0 0 0 0 0

25: 0 0 0 0 0 0 0 0

33: 0 0 0 0 0 0 0 0

41: 0 0 0 0 0 0 0 0

49: 0 0 0 0 0 0 0 0

57: 0 0 0 0 0 0 0 0

65: 0 0 0 0 0 0 0 0

73: 0 0 0 0 0 0 0 0

81: 0 0 0 0 0 0 0 0

89: 0 0 0 0 0 0 0 0

97: 0 0 0 0 0 0 0 0

105: 0 0 0 0 0 0 0 0

113: 0 0 0 0 0 0 0 0

121: 0 0 0 0 0 0 0 0

129: 0 0 0 0 0 0 0 0

137: 0 0 0 0 0 0 0 0

145: 0 0 0 0 0 0 0 1

153: 0 0 0 0 0 0 0 0

161: 0 0 0 0 0 0 0 0

169: 0 0 0 0 0 0 0 0

177: 0 0 0 0 0 0 0 0

185: 0 0 0 0 0 0 0 0

193: 0 0 0 0 0 0 0 0

201: 0 0 0 0 0 0 0 0

209: 0 0 0 0 0 0 0 0

217: 0 0 0 0 0 0 0 0

225: 0 0 0 0 0 0 0 0

233: 0 0 0 0 0 0 0 0

241: 0 0 0 0 0 0 0 0

249: 0 0 0 0 0 0 0 0

257: 0 0 0 0 0 0 0 0

265: 0 0 0 0 0 0 0 0

273: 0 0 0 0 0 0 0 0

281: 0 0 0 0 0 0 0 0

289: 0 0 0 0 0 0 0 0

297: 0 0 0 0 0 0 0 0

305: 0 0 0 0 0 0 0 0

313: 0 0 0 0 0 0 0 0

321: 0 0 0 0 0 0 0 0

329: 0 0 0 0 0 0 0 0

337: 0 0 0 0 0 0 0 0

345: 0 0 0 0 0 0 0 0

353: 0 0 0 0 0 0 0 1

361: 0 0 0 0 0 0 0 0

0221


369: 0 0 1 0 0 0 1 0

Sample Title: 03

Channell------l-------l-------l-------1-------1-------1-------I-------I 377: 0 0 0 0 0 0 0 0

385: 0 0 0 0 0 1 0 0

393: 0 0 0 1 0 0 0 0

401: 1 0 0 0 0 0 0 0

409: 0 0 0 0 0 2 0 1

417: 1 1 0 0 1 0 1 2

425: 1 0 2 1 3 2 0 2

433: 1 1 5 0 2 3 5 2

441: 5 5 3 1 3 4 3 2

449: 3 1 3 4 2 1 1 0

457: 3 2 3 3 5 2 1 1

465: 3 1 0 1 1 2 1 3

473: 1 1 0 1 0 1 0 0

481: 1 2 1 2 0 0 3 0

489: 2 0 2 1 1 1 1 1

497: 0 1 0 0 0 1 0 0

505: 0 0 1 0 1 1 1 1

513: 2 1 0 1 0 1 0 0

521: 0 0 0 0 1 0 0 0

529: 0 0 0 0 0 0 0 0

537: 0 0 0 0 0 0 0 0

545: 0 0 0 0 0 0 0 0

553: 0 0 0 0 0 0 0 0

561: 0 0 0 0 0 0 0 0

569: 0 0 1 0 0 0 0 0

577: 0 0 0 0 0 0 0 0

585: 0 0 0 0 0 0 0 0

593: 0 0 0 0 0 0 0 0

601: 0 0 0 0 0 0 0 0

609: 0 0 0 0 0 0 0 0

617: 0 0 0 0 0 0 0 0

625: 0 0 0 0 0 0 0 0

633: 0 0 0 0 0 0 0 0

641: 0 0 0 0 0 0 0 0

649: 0 0 0 0 0 0 0 0

657: 0 0 0 0 0 0 0 0

665: 0 0 0 0 0 0 0 0

673: 0 0 0 0 0 0 0 0

681: 0 0 0 0 0 0 0 0

689: 0 0 0 0 0 0 0 0

697: 0 0 0 0 0 0 0 0

705: 0 0 0 0 0 0 0 0

713: 0 0 1 0 0 0 0 0

721: 0 0 0 0 0 0 0 0

729: 0 0 0 0 0 0 0 0

737: 0 0 0 0 0 0 0 0

745: 0 0 0 0 0 0 0 0

753: 0 0 0 0 0 0 0 0

761: 0 0 0 0 0 0 0 0

769: 0 0 0 1 0 0 0 0

777: 0 0 0 0 0 0 0 0

785: 0 0 0 0 0 0 0 0

793: 0 0 0 0 0 0 0 0

0222


801: 0 0 0 0 0 0 0 0

Sample Title: 03

Channell------l-------1-------1-------1-------I-------I-------I-------I 809: 0 0 0 0 0 0 0 0

817: 1 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0

865: 0 0 0 0 0 0 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 0 0 0 0 0

897: 0 0 0 0 0 0 0 0

905: 0 0 0 0 0 0 0 0

913: 0 0 0 0 0 0 0 0

921: 0 0 0 0 0 0 0 0

929: 0 0 0 0 0 0 0 0

937: 0 0 0 0 0 0 0 0

945: 0 0 0 0 0 0 0 1

953: 0 0 0 0 0 0 0 0

961: 0 0 0 0 0 0 0 0

969: 0 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0223

ct!,A Al h TM ~-~---1""\pex- p a Sample Description: Spectrum File: Batch Identification:

OU-1-008 \\OR-ALPHAl\Canberra\ApexAlpha\Root\Data\00002099





04 Shelf 2 Th iso


<not performed>

5.000E-001 3/19/2018 3/30/2018

170.0

+/- 0.000E+000 liter 6:43:14 AM 8:10:25 AM


Th229 S TH-18A 0.231 mL 0.1715 +/- 0.0150


9:34:21 AM



Nuclide

TH-227 TH-228 TH-229 T TH-230 TH-232

Energy (MeV)

5.840 5.325 4.860 4.662 3.955

0.175 MeV

PEAK AREA REPORT

Net Pk Area

3.30 0.11

150.96 9.15

-0.19

Pk Area Error%

136.59 3329.3 16.08 68.23

1131.1

Ambient Backgnd

1.70 2.89 2.04 0.85 1.19

Reagent Backgnd

0.00E+000 0.00E+000 0.00E+000 0.00E+000 0.00E+000

FWHM (keV)

6.0 3.0 9.2 3.0 3.0


Nuclide

TH-227 TH-228 TH-229 TH-230 TH-232

Id Conf.

0.999 0. 971 0.999 0.999 0.991


Energy (keV)

5850.00* 5400.00* 4872.00* 4672.00* 3997.00*


l.05E-001 +!- l.44E-001 3.44E-003 +/- l.14E-001 4.69E+000 +!- 8.06E-001 2.83E-001 +!- 1. 99E-001

-5.87E-003 +!- 6.64E-002

f4 3(so{r1

MDA (pCi/liter

2.33E-001 +/- 4.0lE-002 2.74E-001 +!- 4.70E-002 2.42E-001 +/- 4.16E-002 l.85E-001 +!- 3.19E-002 2.04E-001 +/- 3.50E-002

0224

60

55

50

45

40

35

0000209920.CNF

Live Time 10200.000 sec Real Ti me 10200. 300 sec start: 1 3497 .0(kev) stop : 1024 6579.9(kev) Acq. Start Fri Mar 30 08:10:25 2018

V) .µ C :::::s

8 30

25

20

15

10

5 = . "" f-

0 ' ~ ,, I ~

3500 ,u,,, ' , , ~ -~ /\ ,i, A

4000 4500

ROI Type: 1

5000 Energy(kev)

5500

ROI Type: 3

6000 6500

0225



Sample Title: 04


Channell------l-------l-------l-------l-------1-------1-------1-------I 1: 0 0 0 0 0 0 0 0

9 : 0 0 0 0 0 0 0 0

17: 0 0 0 0 0 0 0 0

25: 0 0 0 0 0 0 0 0

33: 0 0 0 0 0 0 0 0

41: 0 0 0 0 0 0 0 0

49: 0 0 0 0 0 0 0 0

57: 0 0 0 0 0 0 0 0

65: 0 0 0 0 0 0 0 0

73: 0 0 0 0 0 0 0 0

81: 0 0 0 0 0 0 0 0

89: 0 0 0 0 0 0 0 0

97: 0 0 0 0 0 0 0 0

105: 0 0 0 0 0 0 0 0

113: 0 0 0 0 0 0 0 0

121: 0 0 0 0 0 0 0 0

129: 0 0 0 0 0 0 0 0

137: 0 0 0 0 0 0 0 0

145: 0 0 0 0 0 0 0 0

153: 1 0 0 0 0 0 0 0

161: 0 0 0 0 0 0 0 0

169: 0 0 0 0 0 0 0 0

177: 0 0 0 0 0 0 0 0

185: 0 0 0 0 0 0 0 0

193: 0 0 0 0 0 0 0 0

201: 0 0 0 0 0 0 0 0

209: 0 0 0 0 0 0 0 0

217: 0 0 0 0 0 0 0 0

225: 0 0 0 0 0 0 0 0

233: 0 0 0 0 0 0 0 0

241: 0 0 0 0 0 0 0 0

249: 0 0 0 0 0 0 0 0

257: 0 0 0 0 0 0 0 0

265: 0 0 0 0 0 0 0 0

273: 0 0 0 0 0 0 0 0

281: 0 0 0 0 0 0 0 0

289: 0 0 0 0 0 0 0 0

297: 0 0 0 0 0 0 0 0

305: 0 0 0 0 0 0 0 0

313: 0 0 0 0 0 0 0 0

321: 0 0 0 0 0 0 0 0

329: 0 0 0 0 0 0 0 0

337: 0 0 0 0 0 0 0 0

345: 0 0 0 0 0 0 0 0

353: 0 0 0 0 0 0 0 0

361: 0 0 0 0 0 1 0 0

0226


369: 0 0 0 0 0 0 0 0

Sample Title: 04

Channell------l-------l-------l-------l-------1-------1-------1-------I 377: 1 0 0 1 0 0 0 1

385: 0 0 0 0 1 0 1 1

393: 0 0 2 0 0 0 0 0

401: 0 0 0 0 0 0 1 0

409: 1 0 0 0 0 2 1 0

417: 3 1 1 2 1 1 0 3

425: 3 1 2 4 0 2 1 2

433: 1 5 0 4 1 3 2 4

441: 3 7 5 4 1 3 6 3

449: 1 2 1 1 1 1 1 2

457: 4 0 3 4 1 2 3 2

465: 0 3 2 0 1 1 0 1

473: 1 0 0 1 2 1 1 2

481: 2 0 0 1 3 1 0 1

489: 1 0 0 0 0 0 1 1

497: 0 0 0 1 0 2 1 1

505: 2 1 0 0 2 1 0 1

513: 0 0 0 2 0 0 0 0

521: 0 0 0 0 0 0 0 0

529: 0 0 0 0 0 0 0 0

537: 0 0 0 0 0 0 0 0

545: 0 0 0 0 0 0 0 0

553: 0 0 0 0 0 0 0 0

561: 0 0 0 0 0 0 0 0

569: 0 0 0 0 0 0 0 0

577: 0 0 0 0 0 0 0 0

585: 0 0 0 1 0 0 0 0

593: 0 0 0 0 0 0 0 0

601: 0 0 0 0 0 0 0 0

609: 0 0 1 0 0 0 0 0

617: 0 0 0 0 0 0 0 1

625: 0 0 0 0 0 0 0 0

633: 0 0 0 0 0 0 0 0

641: 0 0 0 0 0 0 0 0

649: 0 0 0 0 0 0 0 0

657: 0 0 0 0 0 0 0 0

665: 0 0 0 0 0 0 0 0

673: 0 0 0 0 0 0 0 0

681: 0 0 0 0 0 0 0 0

689: 0 0 0 0 0 0 0 0

697: 0 0 0 0 0 0 0 0

705: 0 0 0 0 0 0 0 0

713: 0 0 0 0 0 0 0 0

721: 0 0 0 0 0 0 0 0

729: 0 0 0 0 0 0 0 0

737: 0 0 0 0 0 0 0 0

745: 0 0 0 0 0 0 0 0

753: 0 0 1 1 0 0 0 0

761: 0 0 0 0 0 0 1 0

769: 0 0 0 0 0 0 0 0

777: 0 1 0 0 0 0 0 0

785: 0 0 0 0 0 0 0 0

793: 0 0 0 0 0 0 0 0

0227


801: 0 0 0 0 0 0 0 0

Sample Title: 04

Channell------l-------l-------l-------1-------1-------1-------I-------I 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 1 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 1 0

865: 0 0 0 0 0 0 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 1 0 0

889: 0 0 0 0 0 0 0 0

897: 0 0 0 0 0 0 0 0

905: 0 0 0 0 0 0 0 0

913: 0 0 0 0 0 0 0 0

921: 0 0 0 0 0 0 0 0

929: 0 0 0 0 0 0 0 0

937: 1 0 0 0 0 0 0 0

945: 0 0 0 0 0 0 0 0

953: 0 0 0 0 0 0 0 0

961: 0 0 0 0 0 0 0 0

969: 0 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0228

t-'age I OT ,:. 3/30/2018 5:55:22 AM

OA .<::;/ 11\A/\AARY REPORT .~., " . . -..- - ~ " ~ " .. "" . - ,. . - .. "". .

Review Of QA Results - Pulser Check

Date : 3/30/2018 Time : 5:55:22 AM




Alpha 003 2lf ALL Passed 3/30/2018 5:03:13 AM


















Alpha 037 Alpha AnalystlO0DC ALL Not Done



Alpha 040 Alpha Analvstl 00DC ALL Passed 3/30/2018 5:03:28 AM









Alpha 049 Alpha Analvstl 00DC ALL Passed 3/30/2018 5:03:44 AM



Aloha 052 Alpha Analystl00DC ALL Passed 3/30/2018 5:03:52 AM







0229

Page 2 of 2 Kev1ew ot UA Kesu1ts - 1-'Ulser 1_.;necK 3/30/2018 5:55:22 AM


Aloha 059 Aloha AnalvstlO0DC ALL Not Done

Aloha 060 Aloha Analvstl 00DC ALL Not Done

APPROVED BY:

APPROVAL DATE:'<) /30/175

0230

Library Listing Report 6/12/12 12:16:29 PM Page 1

*************************************************************************


*************************************************************************

Nuclide Library Title: Thorium

Nuclide Library Description: Th-227,-228,-229,-230,-232



TH-227 6.873E+008 5850.000* 0.000 97.5000 0.0000

TH-228 6.034E+007 5400.000* 0.000 99.9400 0.0000

TH-229 2.487E+Oll 4872.000* 0.000 99.5200 0,0000

TH-230 2.379E+012 4672.000* 0.000 99.8200 0.0000

TH-232 4.434E+017 3997.000* 0.000 100.0000 0.0000

* ::::: key line


0231

SECTION XI

ANALYTICAL DAT A (RADIUM-226)

0232


Work Order 18-03110

Analysis Code ~_Ra226··~ J

Run 1 Date Received 3/23/2018



Project WESTLAKE

Report Level 4

Activity Units pCi

Aliquot Units

Matrix WA



Radiometric Tracer Ba-133

Radiometric Sol# Ba-Ga


Carrier


I I

Internal i Sample Fraction Desc

01 LCS

02 MBL

03 DUP

04 DO

I

18-03110 Ra226 Run 1

Client ID

LCS

BLANK

OU-1-008

OU-1-008



Login CPM

38

38

i

I


Sample Sample Date Aliquot

03/23/18 00:00 1.0000E+00

03/23/18 00:00 1.0000E+00 i

03/19/18 18:02 1.0000E+00

03/19/18 18:02 1.0000E+00

:

i

0233


Tracer Internal I Sample Fraction Desc Aliquot(g)

01 LCS 1.0027

02 MBL 1.0065

03 DUP 1.0011

04 DO 1.0043


490.8

492.6

490.0

491.6

Radiometric Tracer (pC1)

297.0

339.0

352.0

277.0

18-03110 Ra226 Run 1

Radiometric I Grav Carrier I Grav Filter % Rec Added (ml) Tare (g)

134.35 0.0210

152.77 0.0210

159.48 0.0210

125.10 0.0215

I Grav Filter Final (g)

0.0311

0.0312

0.0272

0.0265

i

I

* SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. "Indicates estimated SAF value.

- Actual mass exceeded the calibration curve range. Results should be qualified as appropriate.

i Grav Filter I Grav Net(g) %Rec

0.0101

0.0102

0.0062

0.0050

I

Printed: 41212018 3:54 PM Page 2 of 3

Mean SAF I

SAF %Rec 1* I 2*

I

110.00 3.oo" I 1.00

110.00 3.00" 1.00

110.00 2.23 1.00

110.00 1.71 1.00

0234



01 LCS

02 MBL

03 DUP

04 DO

Rough Prep Rough Prep

Date By

i

I Prep I

I Date

I 03128118 08:31 I

03/28/18 08:31

03/28/18 08:31

03/28/18 08:31

18-03110 Ra226 Run 1

Prep By

JHARVEY

JHARVEY

JHARVEY

JHARVEY

I SeptO Date/Time

I

04/02/18 14:31

04/02/18 14:31

04/02/18 14:31

04/02/18 14:31

• SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. "Indicates estimated SAF value.


I Sep to I By

I

EBAILEY

EBAILEY

EBAILEY

EBAILEY

I

Sep t1


Sep t1 I Date/Time By I

0235


~ Lab I Nuclide

Fraction

01 RA-226

i:: :, a::

.g 8 ,!!! ~ iii i:: <:(

~I

"""""

<D N N ns 0::

"' C 0

.!!? (.) Q)

C ni -C Q)

E C 0 ... > C w 0 :ii: <(

02 RA-226

03 RA-226

04 RA-226

[ Sample

1 Desc

LCS

MBL

DUP

DO


Work Order: 18-0311 0-Ra226-1

Client

I Activity

Results I Error Estimate MDA Identification Units

LCS pCi/1 9.91E+00 1.37E+00 4.41E-01

BLANK pCi/I 2.23E-01 2.41E-01 3.62E-01

OU-1-008 pCi/I 1.19E-01 1.54E-01 2.44E-01

OU-1-008 pCi/I 1.47E-01 1.29E-01 1.SSE-01

LCS LCS

Known ¾R

1.00E+01 98.94


LCS

I RPO MDA Blank

Flag Flag Flag Flag

OK OK

OK OK

NA OK

OK

0236


,: Lab Nuclide

Fraction

01 RA-226

C: ~ 0::

.g 8 .!(!

~ cii C: q;

~I

~

(0 N N CG ~

U) C:

.!2 U)

·o a, C ltl -C: a, E C:

_g > C: w 0 ~ <(

02 RA-226

03 RA-226

04 RA-226

Sample Desc

LCS

MBL

DUP

DO


Work Order: 18-0311 0-Ra226-1



03/23/18 00:00 1.00E+00 100.00 0.00 110.00

03/23/18 00:00 1.00E+00 100.00 0.00 110.00

03/19/18 18:02 1.00E+00 100.00 0.00 110.00

03/19/18 18:02 1.00E+00 100.00 0.00 110.00

SAF


SeptO Sept1

DatefTime DatefTime

4/2/2018 14:31

4/2/2018 14:31

4/2/2018 14:31

4/2/2018 14:31

0237



01 RA-226

~

.g 0 0 -!!! ~ c\i C: Cl:

~I

~

(0 N N ca ~

1/) C .2 1/)

·c:; Q)

C ns -C Q)

E C 0 ... ·:,; C w 0 :i1!E <(

02 RA-226

03 RA-226

04 RA-226

Sample Desc

LCS

MBL

DUP

DO


Work Order: 18-0311 0-Ra226-1

Counting I Halflife

I Count

1

Detect Carrier Counts DatefTime (days) Time

04/02/18 16:08 A_Spec Alpha_040 170 2.19 E+02

04/02/1816:08 A_Spec Alpha_041 170 5.28 E+00

04/02/18 16:08 A_Spec Alpha_042 170 3.47 E+00

04/02/18 16:08 A_Spec Alpha_044 170 5.98 E+00

Bkg CPM

2.30 E-02

1.60 E-02

9.00 E-03

6.00 E-03


Eff

17.6

18.8

17.2

18.4

0238

Count Room Report


.~

-~1 I

;fl Sample [ Internal Client

Fraction Desc ID

01 LCS LCS

02 MBL BLANK

03 DUP OU-1-008

04 DO ' OU-1-008

I

18-0311 0-Ra226-1 (pCi/1) in WA

Tracer ID: Ba-6a

I Sample Sample Tracer

Date Aliquot Aliquot(g)

03/23/18 00:00 1.0000 1.0027

03/23/18 00:00 1.0000 1.0065

03/19/18 18:02 1.0000 1.0011

03/19/18 18:02 1.0000 1.0043

Tracer Radiometric

ACT(dpm) Tracer (pCi)

490.7715 297.0000

492.6314 339.0000

489.9884 352.0000

491.5546 277.0000


I I

I I Radiometric i SAF SAF

%Rec I 1* I 2*

I

134.35 3.00" 1.00

152.77 3.00" 1.00

159.48 2.23 1.00

125.10 1.71 1.00

i

I

0239


Isotope So/# Activity dpmlg

Solution Date

Ra-226 Ra-Sb 43. 980 I 3/28/2018

Tracers i Activity

fraction Isotope So/# dpm/g

01 Ba-133 Ba-Ga 489.450

02 Ba-133 Ba-Ga 489.450

03 Ba-133 Ba-Ga i 489.450

04 Ba-133 Ba-Ga 489.450

I

Version 2.0 08/99

i !

Approx Addition

0.500

Solution Date

3/28/2018

3/28/2018

3/28/2018

3/28/2018


Analysis Code

Ra226 LCS

Volume Used{g)

0.5056

Volume Used(g)

1.0027

1.0065

1.0011

1.0043

I !

MS Volume Used (g)

Approx Addition

2.0700

2.0700

2.0700

2.0700

Date

3/28/2018 8:28

LCSD l MSD Volume l Volume Used{g) Used(g)

Technician

JHARVEY

T LCS --

MS

l Known Error Added Error pCi Estimate pCi Estimate

10.02 0.461 0.00 0.000


Tracer



-i:cso MSD Known

i Error Added Error

pCi Estimate pCi Estimate

o ool 0.000 0.00 0.000

LCS

Matrix Spike

0240

Lab



Fraction Client ID

01 LCS

02 BLANK

03 OU-1-008

04 OU-1-008

Comments

Sample

Type

LCS

MBL

DUP

DO

Aliquot Worksheet

Analysis Code Rpt Units Lab Deadline

Ra226 liters 4/12/2018

Muffle Data Dilution Data Aliquot Data Ratio

Post/Pre No of Dils Oil Factor Ratio Aliquot Net Equiv

1.0000E+OO 1.0000E+OO

1.0000E+OO 1.0000E+OO

1.0000E+OO 1.0000E+OO

1.0000E+OO 1.0000E+OO

Technician: s::Jl \ a~'Wd •aIB ~

Technician

JHARVEY

MS Aliquot Data


H-3 Solids Only

Aliquot Net Equiv water AaaejH3-D1st-

(ml) Aliq I

i

I

I

i

i

0241

Eberline Analytical - Oak Ridge Version 1.1 10/2015

Work Order

18-03110

TRetec AMO Environmental Decisions

Fraction Client ID

01 LCS

02 BLANK

03 DUP

04 OU-1-008

Technician: w&

Gravimetric Worksheet

-Sample

Type

LCS

MBL

DUP

DO

Analysis Code

Ra226

Carrier Data

Gravimetric Carrier

Filter Data

Carrier Added Filter Tare Filter Final

(ml) (g) (g)

0.0210 0.0311

0.0210 0.0312

0.0210 0.0272

0.0215 0.0265

Date: _:J_, 2_ / \8

I


Filter Net (g)

0.0101

0.0102

0.0062

0.0050


Technician

EBAILEY

Gravimetric %

Recovery

0242

~-~.,Apex-A Ip ha™ Sample Description: Spectrum File: Batch Identification:


1803110A-RA



Sample Size: Generic Mult. Factor: Sample Date/Time: Acquisition Date/Time: Acquisition Live Time: Acquisition Real Time:


01 Shelf 2 Ra


<not performed>

l.000E+000 +/- 0.000E+000 liter

3.000E+000 4/2/2018 4/2/2018

170.0

Generic Div. Factor: 3:20:11 PM 4:08:19 PM


1.0000 +/- 0.0000

l.000E+000

Counting Efficiency: 0.1757 +/- 0.0031 on 2/16/2018

0.1757 +/- 0.0031 9:34:27 AM

Effective Efficiency:

Control Certificate Name: Ra226 Ra-5b

Chem. Recov. of Control: RA-226 0.329818 +/- 0.025263


Nuclide

RA-224 RA-226

Nuclide

RA-224 RA-226

Energy (MeV)

Id Con£.

5.478 4.593

PEAK AREA REPORT

Net Pk Area

7.64 219.09

Pk Area Error%

77.95 13.38

Ambient Backgnd

1. 36 3.91


Energy (keV)


0.945 0.953

5685.50* 4785.00*

3.63E-001 +/- 2.84E-001 9.91E+000 +/- l.37E+000

Reagent Backgnd

0.00E+000 0.00E+000

FWHM (keV)

MDA

3.0 3.8

(pCi/liter

3.26E-001 +/- l.12E-002 4.41E-001 +/- l.51E-002

ft(P 4(3/18

0243

V) ...... C: ::::s

60

55

50

45

40

35

8 30

25

20

15

10

5

0 "'I'll 11111111111111111111

3500

ROI Type: 1

4000 4500

0000210090.CNF

5000 Energy(kev)

5500 :J

Live Time :10200.000 sec Real Time :10200.300 sec start: 1:3473.G(kev) stop : 1024:6542.9(kev) Acq. Start :Mon Apr 02 16:08:19 2018

6000 6500

0244


*******************************************************

***** s p E C T R A L DAT A R E P O R T *****

*******************************************************

Sample Title: 01

Elapsed Live time: 10200

Elapsed Real Time: 10200

Channell------l-------l-------l-------1-------1-------1-------I-------I

1: 1 1 2 0 3 1 1 0

9 : 1 4 0 1 3 1 1 1

17: 0 0 1 5 1 1 1 1

25: 0 0 1 0 0 1 1 1

33: 1 0 2 1 3 0 2 4

41: 0 0 1 1 2 1 0 1

49: 1 0 4 0 1 0 2 1

57: 1 1 2 0 1 2 0 1

65: 2 1 1 2 0 1 0 3

73: 2 1 1 0 2 1 2 2

81: 1 2 0 0 1 2 0 1

89: 1 2 2 1 4 1 1 3

97: 2 0 2 1 3 1 1 3

105: 1 1 2 0 3 1 4 1

113: 0 3 0 0 1 0 1 0

121: 0 2 0 1 1 2 0 1

129: 1 2 2 1 1 4 1 3

137: 0 0 0 0 0 0 1 1

145: 1 2 3 2 3 0 3 1

153: 3 1 1 1 1 3 2 3

161: 0 0 2 2 1 4 4 1

169: 0 0 1 2 0 1 0 2

177: 4 1 2 0 2 0 0 2

185: 2 1 1 3 5 2 2 1

193: 3 4 3 0 2 1 0 0

201: 0 4 0 1 0 2 0 6

209: 2 2 0 1 0 1 1 1

217: 4 2 1 3 3 1 2 4

225: 0 2 3 1 1 1 2 2

233: 0 4 0 3 1 0 2 2

241: 0 4 1 1 0 1 1 0

249: 1 3 1 3 0 3 0 0

257: 3 0 0 1 0 5 0 1

265: 2 0 0 0 4 3 1 0

273: 0 2 3 1 2 0 1 1

281: 2 5 1 1 2 1 2 1

289: 0 2 1 1 2 1 1 1

297: 2 2 2 0 1 3 1 1

305: 2 1 3 1 1 0 1 2

313: 1 1 2 2 2 0 1 3

321: 2 4 2 1 1 2 1 2

329: 1 0 2 3 1 2 0 2

337: 2 0 3 0 1 1 1 1

345: 2 0 3 2 2 0 0 3

353: 1 1 4 1 2 1 2 2

361: 1 1 3 3 3 2 1 0

0245


369: 0 1 0 3 3 0 0 3

Sample Title: 01

Channelj------l-------l-------l-------l-------1-------1-------1-------I

377: 1 4 1 3 2 2 3 0

385: 1 1 1 0 1 1 3 1

393: 2 1 1 2 0 2 0 1

401: 1 1 1 2 1 2 0 3

409: 1 1 1 1 4 1 3 1

417: 1 4 0 3 2 2 3 4

425: 1 1 1 3 4 1 5 1

433: 1 2 1 2 0 2 0 0

441: 1 3 0 2 1 0 0 0

449: 0 0 0 0 0 0 0 2

457: 1 0 0 0 0 0 0 0

465: 0 0 0 1 0 0 0 0

473: 0 0 0 1 0 0 0 0

481: 0 0 0 0 0 0 0 0

489: 0 0 0 0 0 0 0 1

497: 0 0 0 0 0 0 0 0

505: 0 0 0 0 0 0 0 0

513: 1 0 0 0 0 0 0 0

521: 0 1 0 0 0 0 0 0

529: 0 0 0 1 0 0 0 0

537: 0 0 2 0 0 0 0 0

545: 0 0 0 0 0 0 0 0

553: 0 0 0 0 0 0 0 0

561: 1 0 0 0 0 0 0 0

569: 0 0 0 0 0 0 0 0

577: 0 0 0 0 0 0 0 0

585: 0 0 1 0 0 0 0 1

593: 0 0 0 0 0 0 0 1

601: 0 0 0 0 0 0 0 0

609: 0 0 0 0 1 0 0 1

617: 0 0 0 0 1 0 0 0

625: 1 0 0 0 0 0 0 0

633: 0 1 0 0 0 0 0 0

641: 1 0 0 1 0 0 0 0

649: 0 0 0 0 0 0 0 1

657: 0 0 1 0 0 0 0 0

665: 0 1 0 0 0 0 0 0

673: 0 0 0 0 0 0 0 0

681: 0 0 0 0 0 1 0 0

689: 0 0 0 0 0 0 0 0

697: 0 0 0 0 0 0 0 0

705: 0 0 0 0 0 0 0 0

713: 0 0 0 1 0 0 0 1

721: 0 0 0 0 0 0 0 0

729: 0 0 0 0 0 0 0 0

737: 0 0 0 0 0 0 0 0

745: 0 0 0 0 0 0 0 0

753: 0 0 0 0 0 0 0 0

761: 0 0 0 0 0 0 0 1

769: 0 0 0 0 0 0 0 0

777: 0 0 0 0 0 0 0 0

785: 0 0 1 0 0 0 0 0

793: 0 0 0 0 0 1 0 0

0246


801: 0 0 0 0 0 0 0 0

Sample Title: 01

Channell------l-------l-------l-------l-------1-------1-------1-------I 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 1

865: 0 0 0 0 0 0 0 1

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 0 0 0 0 0

897: 0 0 0 0 0 0 0 0

905: 0 0 0 0 0 0 0 0

913: 0 0 0 0 0 0 0 0

921: 0 0 0 0 0 0 0 0

929: 0 0 0 0 0 0 0 0

937: 0 0 0 0 0 0 0 0

945: 1 0 0 0 0 0 0 0

953: 0 0 0 0 0 0 0 0

961: 0 0 0 0 0 0 0 0

969: 0 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0247

cfJ,A Al h TM ~~~---J-\pex- p a Sample Description: Spectrum File: Batch Identification: Sample Identification: Sample Geometry: Procedure Description:



Chem. Recovery Factor: Counting Efficiency: Effective Efficiency:


Nuclide

RA-224 RA-226

Energy (MeV)

5.689 4.510


1803110A-RA 02 Shelf 2 Ra


<not performed>

1.000E+000 +/- 0.000E+000 liter

3.000E+000 4/2/2018 4/2/2018

170.0



0.0000

1.000E+000

1. 0000 +/-0 .1885 +/-0.1885 +/-

0.0033 on 2/16/2018 0.0033

9:34:24 AM

0.350 MeV

PEAK AREA REPORT

Net Pk Area

0.15 5.28

Pk Area Error%

1397.8 107.99

Ambient Backgnd

0.85 2.72


Reagent Backgnd

0.00E+000 0.00E+000

FWHM (keV)

3.0 3.0

Nuclide Id

Conf. Energy (keV)


MDA (pci/liter

RA-224 RA-226

1.000 0.906

5685.50* 4785.00*

6.65E-003 +/- 9.30E-002 2.23E-001 +/- 2.41E-001

2.65E-001 +/- 9.04E-003 3.62E-001 +/- 1.23E-002

0248

60

55

50

45

40

35 V) ...., C :::s

8 30

25

20

15

10

5

0 I

3500

ROI Type: 1

1 Lill __ /'.

4000 4500

0000210088.CNF

5000 Energy(kev)

5500

Live Time :10200.000 sec Real Time :10200.200 sec Start: l:3471.8(keV) Stop : 1024:6544.G(kev) Acq. Start : Mon Apr 02 16: 08: 15 2018

.... ~ ~ ;;\;

6000 6500

0249



Sample Title: 02


Channell------l-------l-------1-------1-------1-------I-------I-------I

1: 0 0 0 0 0 0 0 0

9 : 0 0 0 0 0 0 0 0

17: 0 0 0 0 0 0 0 0

25: 0 0 0 0 0 0 0 0

33: 0 0 0 0 0 0 0 0

41: 0 0 0 0 0 0 0 2

49: 0 0 0 0 0 0 0 0

57: 1 0 0 0 0 0 0 0

65: 0 0 0 0 0 0 0 0

73: 0 0 0 0 0 0 0 0

81: 0 0 0 0 0 0 0 0

89: 0 0 0 0 0 0 0 0

97: 0 0 0 0 0 0 0 0

105: 0 0 0 0 0 0 0 0

113: 0 1 0 0 0 0 0 0

121: 0 0 0 0 0 0 0 0

129: 0 0 0 0 0 0 0 0

137: 0 0 0 0 0 0 0 0

145: 0 0 0 0 0 0 0 0

153: 0 0 0 0 0 0 0 0

161: 0 0 0 0 0 0 0 0

169: 0 0 0 0 0 0 0 0

177: 0 0 0 0 0 0 0 0

185: 0 0 0 0 0 0 1 0

193: 0 0 0 1 0 0 0 0

201: 0 0 0 0 0 0 1 1

209: 0 0 0 1 1 0 0 0

217: 1 0 0 0 0 0 0 0

225: 0 0 0 0 0 0 0 0

233: 0 0 0 0 0 0 0 0

241: 0 0 0 0 0 0 0 0

249: 1 0 0 0 0 0 0 0

257: 0 1 0 0 0 0 0 0

265: 0 0 0 0 0 0 0 0

273: 0 0 0 0 0 0 0 0

281: 0 0 0 0 0 0 0 0

289: 0 0 0 0 0 0 0 0

297: 0 0 0 0 0 0 0 0

305: 0 0 0 0 1 0 0 0

313: 0 0 1 0 0 0 0 0

321: 0 0 0 0 0 0 0 0

329: 0 0 0 0 0 0 1 0

337: 0 0 0 1 1 0 0 0

345: 0 0 0 0 0 0 0 0

353: 0 0 0 0 0 0 0 0

361: 0 0 0 1 0 0 0 0

0250


369: 0 0 0 0 0 0 0 1

Sample Title: 02

Channell------l-------l-------l-------1-------1-------1-------I-------I

377: 0 0 0 0 0 0 0 0

385: 0 0 0 0 0 0 0 1

393: 0 0 0 0 0 0 0 0

401: 0 0 0 0 0 0 0 0

409: 0 0 0 0 0 0 0 0

417: 0 0 0 0 0 0 0 0

425: 0 0 0 0 0 0 0 0

433: 0 0 0 0 0 0 0 0

441: 0 0 0 0 0 0 0 0

449: 0 0 0 0 0 0 2 0

457: 0 0 0 0 0 0 0 0

465: 0 0 0 0 0 0 0 0

473: 0 0 0 0 0 0 0 0

481: 0 0 0 0 0 0 0 0

489: 0 0 0 0 0 0 0 0

497: 0 0 0 0 1 0 0 0

505: 0 0 0 0 1 0 0 0

513: 0 1 0 0 1 0 0 0

521: 0 0 0 0 0 0 0 0

529: 0 0 0 0 0 0 0 0

537: 1 0 0 0 0 0 0 0

545: 1 0 0 0 0 1 0 0

553: 0 0 0 0 0 0 0 0

561: 0 0 0 1 0 0 0 0

569: 0 1 0 0 0 0 1 0

577: 1 0 0 0 0 0 0 0

585: 0 0 0 0 0 0 0 0

593: 1 0 0 0 0 0 0 0

601: 1 0 1 0 0 0 0 0

609: 0 0 0 0 0 0 0 0

617: 0 0 0 0 0 0 0 0

625: 0 0 0 0 0 0 0 0

633: 0 0 0 0 0 0 0 0

641: 0 0 0 0 0 0 0 0

649: 0 0 0 0 0 0 0 0

657: 0 0 0 0 0 0 0 0

665: 0 0 0 0 0 0 0 0

673: 0 0 0 0 0 0 0 0

681: 0 0 0 0 0 0 0 0

689: 0 0 0 0 0 0 0 0

697: 0 0 0 0 0 0 0 0

705: 0 0 0 0 0 0 0 0

713: 0 0 0 0 0 0 0 0

721: 0 0 0 0 0 0 0 0

729: 0 0 0 0 0 0 0 0

737: 0 0 1 0 0 0 0 0

745: 0 0 0 0 0 0 0 0

753: 0 0 0 0 0 0 0 0

761: 0 0 0 0 0 0 0 0

769: 0 0 0 0 0 0 0 0

777: 0 0 0 0 0 0 0 0

785: 0 0 0 0 0 0 0 0

793: 0 0 0 0 0 0 0 0

0251


801: 0 0 0 0 0 0 0 0

Sample Title: 02

Channell------l-------l-------l-------l-------1-------1-------1-------I 0

809: 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0

865: 0 0 0 0 0 0 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 0 0 0 0 0

897: 0 0 0 0 0 0 0 0

905: 0 0 0 0 0 0 0 0

913: 0 0 0 0 0 0 0 0

921: 0 0 0 0 0 0 0 0

929: 0 0 0 0 0 0 0 0

937: 0 0 0 0 0 0 0 0

945: 0 0 0 0 0 0 0 0

953: 0 0 0 0 0 0 0 0

961: 0 0 0 0 0 0 0 0

969: 0 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0252

c!!;'A Al h TM --=='J-\pex- p a Sample Description: Spectrum File: Batch Identification: Sample Identification: Sample Geometry: Procedure Description:





Nuclide

RA-224 RA-226

Energy (MeV)

5.493 4. 611




<not performed>

l.000E+000 +/- 0.000E+000 liter

2.230E+000 4/19/2018 4/2/2018

170.0



0.0000

l.000E+000

1. 0000 +/-0 .1722 +/-0.1722 +/-

0.0030 on 2/16/2018 0.0030

9:34:23 AM

0.350 MeV

PEAK AREA REPORT

Net Pk Area

2.15 3.47

Pk Area Error%

161.66 129.55

Ambient Backgnd

0.85 1. 53


Reagent Backgnd

0.00E+000 0.00E+000

FWHM (keV)

3.0 3.0

Nuclide Id

Conf. Energy (keV)


MDA (pCi/liter

RA-224 RA-226

0.953 0. 961

5685.50* 4785.00*

7.71E-002 +/- l.25E-001 l.19E-001 +/- l.54E-001

2.15E-001 +/- 7.40E-003 2.44E-001 +/- 8.39E-003

0253

60

55

50

45

40

35 V)

-1-' C: :::s

8 30

25

20

15

10

5

0 I

4000

ROI Type: 1

N,

4500

0000210089.CNF

,11 )

5000 Energy(kev)

5500

Live Time :10200.000 sec Real Time : 10200. 200 sec Start: 1:3502.?(kev) Stop : 1024:6565.S(keV) Acq. Start :Mon Apr 02 16:08:17 2018

6000 6500

0254



Sample Title: 03


Channell------l-------l-------l-------l-------1-------1-------1-------I 1: 0 0 0 0 0 0 0 0

9 : 0 0 0 0 0 0 0 0

17: 0 0 0 0 0 0 0 0

25: 0 0 0 0 0 0 0 0

33: 0 0 0 0 0 0 0 0

41: 0 0 0 0 0 0 0 0

49: 0 0 0 0 0 0 0 0

57: 0 0 0 0 0 0 0 0

65: 0 0 0 0 0 0 0 0

73: 0 0 0 0 0 0 0 0

81: 0 0 0 0 0 0 0 0

89: 0 0 0 0 0 0 0 0

97: 0 0 0 0 0 0 0 0

105: 0 0 0 0 0 0 0 0

113: 1 0 0 0 0 0 0 0

121: 0 0 0 0 0 0 0 0

129: 0 0 0 0 0 0 0 0

137: 0 0 0 0 0 0 0 0

145: 0 0 0 0 0 0 0 0

153: 0 0 0 0 0 0 0 0

161: 0 0 0 0 0 0 0 0

169: 0 0 0 0 0 0 0 0

177: 0 0 0 0 0 1 0 0

185: 0 0 0 0 0 0 0 0

193: 0 0 0 0 0 0 0 0

201: 0 0 0 0 1 0 0 0

209: 0 0 0 0 0 0 0 0

217: 1 0 0 0 0 0 0 0

225: 0 0 0 0 0 0 0 0

233: 0 0 0 0 0 0 0 0

241: 0 0 0 0 0 0 0 0

249: 0 0 0 0 0 0 0 0

257: 0 0 0 0 0 0 0 0

265: 0 0 0 0 0 0 0 0

273: 0 0 0 0 0 0 2 0

281: 0 0 0 0 0 0 0 0

289: 0 0 0 0 0 0 0 0

297: 0 0 0 0 0 0 0 0

305: 0 0 0 0 0 0 0 0

313: 0 0 0 0 0 0 0 0

321: 0 0 0 0 0 0 0 0

329: 0 0 0 0 0 0 0 1

337: 0 0 0 0 0 0 0 0

345: 0 0 0 0 1 0 1 0

353: 0 0 0 0 0 0 0 0

361: 0 0 0 0 0 0 0 0

0255


369: 0 0 0 0 0 0 0 0

Sample Title: 03

Channell------1-------1-------1-------I-------I-------I-------I-------I 377: 0 0 0 0 0 0 0 0

385: 0 0 0 0 0 0 0 0

393: 0 0 0 0 0 0 1 0

401: 0 0 0 0 0 0 0 0

409: 0 0 0 0 0 0 0 0

417: 0 0 0 0 1 0 0 0

425: 0 0 0 0 0 0 0 0

433: 0 0 0 0 0 0 0 0

441: 0 0 0 0 0 0 0 0

449: 0 0 0 0 0 0 0 0

457: 0 0 0 0 0 0 0 0

465: 0 0 0 0 0 0 0 0

473: 0 0 0 0 0 0 0 0

481: 0 0 0 0 0 0 0 0

489: 0 0 0 0 0 0 0 0

497: 0 0 0 0 0 0 0 0

505: 0 0 0 0 0 0 0 0

513: 0 0 0 0 0 0 0 0

521: 0 0 0 0 0 0 1 0

529: 0 0 0 0 0 0 0 0

537: 0 0 0 0 0 0 0 0

545: 0 0 0 1 0 0 0 0

553: 0 0 0 0 0 0 0 0

561: 0 0 0 0 0 0 0 0

569: 0 0 0 0 0 0 0 0

577: 0 0 0 0 0 0 0 1

585: 0 0 0 0 0 0 0 0

593: 0 0 0 0 0 0 0 0

601: 0 0 0 0 0 0 0 0

609: 0 0 0 0 0 0 0 0

617: 0 0 0 0 0 0 0 0

625: 0 0 0 0 0 0 0 0

633: 0 0 0 0 0 0 0 0

641: 0 0 0 0 0 0 0 0

649: 1 0 0 0 0 0 0 0

657: 0 0 0 0 0 0 0 0

665: 0 0 0 1 0 0 0 0

673: 0 0 0 0 0 0 0 1

681: 0 0 0 0 0 0 0 0

689: 0 0 0 0 0 0 0 0

697: 0 0 0 0 0 0 0 0

705: 0 0 0 0 0 0 0 0

713: 0 0 0 0 0 0 0 0

721: 0 0 0 0 0 0 0 0

729: 0 0 0 0 0 0 0 0

737: 0 0 0 0 0 0 0 0

745: 0 0 0 0 0 0 0 0

753: 0 0 0 0 0 0 0 0

761: 0 0 0 0 0 0 0 0

769: 0 0 0 0 0 0 0 0

777: 0 0 0 0 0 0 0 0

785: 0 1 0 0 0 0 0 0

793: 0 0 0 0 0 0 0 0

0256


801: 0 0 0 0 0 0 0 0

Sample Title: 03

Channell------l-------l-------l-------1-------1-------1-------I-------I 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0

865: 0 0 0 0 0 0 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 0 0 0 0 0

897: 0 0 0 0 0 0 0 0

905: 0 0 0 0 0 0 0 0

913: 0 0 0 0 0 0 0 0

921: 0 0 0 0 0 0 0 1

929: 0 0 0 0 0 0 0 0

937: 0 0 0 0 0 0 0 0

945: 0 0 0 0 0 0 0 0

953: 0 0 0 0 0 0 0 0

961: 0 0 0 0 0 0 0 0

969: 0 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 1 0 0 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0257

c!t(A Al h TM ~J-\pex- p a Sample Description: Spectrum File: Batch Identification: Sample Identification: Sample Geometry: Procedure Description:





Nuclide

RA-224 RA-226

Energy (MeV)

5.572 4.584

OU-1-008 \\OR-ALPHAl\Canberra\ApexAlpha\Root\Data\00002100



<not performed>

l.000E+000 +/- 0.000E+000 liter

l.710E+000 4/19/2018 4/2/2018

170.0



1.0000 +/- 0.0000

l.000E+000

0.1840 +/- 0.0032 on 2/16/2018

0.1840 +/- 0.0032 9:34:19 AM

0.350 MeV

PEAK AREA REPORT

Net Pk Area

-0.53 5.98

Pk Area Error%

415.13 87.78

Ambient Backgnd

1. 53 1. 02


Reagent Backgnd

0.00E+000 0.00E+000

FWHM (keV)

3.0 3.0

Nuclide Id

Con£. Energy (keV)


MDA (pCi/liter

RA-224 RA-226

0.983 0. 949

5685.50* -l.36E-002 +/- 5.66E-002

4785.00* l.47E-001 +/- l.29E-001 l.83E-001 +/- 6.29E-003 l.55E-001 +/- 5.32E-003

0258

60

55

50

45

40

35 U}

-1-' C:

8 30

25

20

15

10

5

0 I

3500 4000

ROI Type: 1

I/ .i.! ''il ~,,,

4500

0000210091.CNF

5000 Energy(kev)

5500

~

1

Live Time :10200.000 sec Real Time :10200.200 sec Start: l:3463.6(kev) Stop : 1024:6522.9(keV) Acq. Start :Mon Apr 02 16:08:13 2018

6000 6500

0259


******************************************************* ***** s p E C T R A L DAT A RE P O R T ***** *******************************************************

Sample Title: 04


Channell------l-------l-------l-------1-------1-------1-------I-------I 1: 0 0 0 0 0 0 0 0

9: 0 0 0 0 0 0 0 0

17: 0 0 0 0 0 0 0 0

25: 0 0 0 0 0 0 0 0

33: 0 0 0 0 0 0 0 0

41: 0 0 0 0 0 0 0 0

49: 0 0 0 0 0 0 0 0

57: 0 0 0 0 0 0 0 0

65: 0 0 0 0 0 0 0 0

73: 0 0 0 0 0 0 0 0

81: 0 0 0 0 0 0 0 0

89: 0 0 0 0 0 0 0 0

97: 0 0 0 0 0 0 0 0

105: 0 0 0 0 0 0 0 0

113: 0 0 0 0 0 0 0 0

121: 0 0 0 0 0 0 0 0

129: 0 0 0 0 0 0 0 0

137: 0 0 0 0 0 0 0 0

145: 0 0 0 0 0 0 0 0

153: 0 0 1 0 0 0 0 0

161: 0 0 0 0 0 0 0 0

169: 0 0 0 0 0 0 0 0

177: 0 0 0 0 0 0 0 0

185: 0 0 0 0 0 0 0 0

193: 0 0 0 0 0 0 0 0

201: 0 0 0 0 0 0 0 0

209: 0 0 0 0 0 0 0 0

217: 0 0 0 0 0 0 0 0

225: 0 0 1 0 0 0 0 0

233: 0 0 0 0 0 0 0 0

241: 0 0 0 0 0 0 0 1

249: 0 0 0 0 0 0 0 0

257: 0 0 0 0 0 0 0 0

265: 0 0 0 0 0 0 0 0

273: 0 0 0 0 0 0 0 0

281: 0 0 0 0 0 0 0 0

289: 0 0 0 0 0 0 0 0

297: 0 0 1 1 0 0 0 0

305: 0 0 0 0 0 0 0 0

313: 0 0 0 0 1 0 0 0

321: 0 1 0 0 0 0 0 0

329: 0 0 0 0 0 0 0 0

337: 0 0 0 0 0 1 0 0

345: 0 1 0 0 0 0 0 0

353: 0 0 0 0 0 0 0 0

361: 0 0 0 0 0 0 0 0

0260


369: 0 0 0 0 0 0 0 0

Sample Title: 04

Channell------l-------1-------1-------1-------I-------I-------I-------I 377: 0 0 0 0 0 0 0 0

385: 0 0 0 0 0 0 0 0

393: 0 0 0 0 0 0 0 0

401: 0 0 0 0 0 0 0 1

409: 0 0 0 0 0 0 0 0

417: 0 0 0 0 0 0 0 0

425: 0 0 0 0 0 0 0 0

433: 0 0 0 0 0 0 0 1

441: 0 0 0 0 0 0 0 0

449: 0 0 0 0 0 0 1 0

457: 0 0 0 0 0 0 0 0

465: 0 0 0 0 0 0 0 0

473: 0 0 0 0 0 0 0 0

481: 0 0 0 0 0 0 0 0

489: 0 0 0 0 0 0 0 0

497: 0 0 1 0 0 1 0 0

505: 0 0 0 0 0 0 0 0

513: 0 0 0 0 0 0 0 0

521: 0 0 0 0 0 0 0 0

529: 0 0 0 0 0 0 0 0

537: 0 0 0 0 0 0 0 0

545: 0 0 0 0 0 0 0 0

553: 0 0 0 0 0 0 0 0

561: 0 0 0 0 1 0 0 0

569: 0 0 0 0 0 0 0 0

577: 0 0 0 0 0 0 0 0

585: 0 0 0 0 1 0 0 1

593: 0 0 0 0 0 0 0 0

601: 0 0 0 0 0 0 0 1

609: 0 0 0 2 0 0 0 0

617: 0 0 0 0 0 0 0 0

625: 0 0 0 0 0 0 0 0

633: 0 0 0 0 0 0 0 0

641: 0 0 0 0 0 0 0 0

649: 0 0 0 0 0 0 0 0

657: 0 0 0 0 0 0 0 0

665: 0 0 0 0 0 0 0 0

673: 0 0 0 0 0 0 0 0

681: 0 0 0 0 0 0 0 0

689: 0 0 0 0 0 0 0 0

697: 0 0 0 0 0 0 0 0

705: 0 1 0 0 0 0 0 0

713: 0 0 0 0 0 0 0 0

721: 0 0 0 0 0 0 0 0

729: 0 0 0 0 0 0 0 0

737: 0 0 0 0 0 0 0 0

745: 0 0 0 0 0 0 0 0

753: 0 0 0 0 0 0 0 0

761: 0 0 1 0 0 0 0 0

769: 0 0 0 0 0 0 0 0

777: 0 0 0 0 0 0 1 0

785: 0 0 0 0 0 0 0 0

793: 0 0 0 0 0 0 0 0

0261


801: 0 0 0 0 0 0 0 0

Sample Title: 04

Channell------l-------l-------l-------1-------1-------1-------I-------I 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 1 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0

865: 0 0 0 0 0 1 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 0 0 0 0 0

897: 0 0 0 0 0 0 0 0

905: 0 0 0 0 0 0 0 0

913: 0 0 0 0 0 0 0 0

921: 0 0 0 0 0 0 0 0

929: 0 0 0 0 0 0 0 0

937: 0 0 0 0 0 0 1 0

945: 0 0 0 0 0 0 0 0

953: 0 0 0 0 0 0 0 0

961: 0 0 0 0 0 0 0 0

969: 0 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 1 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0262

Page 1 ot 2

Date : 4/2/2018

QA SU!Vlft.lA.RY REPORT Review Of QA Results - Pulser Check

Time : 5:27:26 AM

CHAMBER DEVICE PARAMETER FLAG



Alpha 003 21f ALL Passed














Alpha 033 Alpha Analystl00DC Peak Energy Action

Alpha 034 Alpha Analystl00DC ALL Passed

Alpha 035 Alpha Analystl 00DC ALL Passed

Alpha 036 Alpha Analvstl00DC ALL Passed

Alpha 037 Alpha Analvstl00DC ALL Not Done



Alpha 040 Alpha Analvstl 00DC ALL Passed




Alpha 044 Alpha Analvstl00DC ALL Passed




Alpha 048 Alpha Analvstl 00DC ALL Not Done



Alpha 051 Alpha Analyst 1 00DC ALL Passed








4/2/2018 5:27:26 AM

DATE

4/2/2018 5:09:30 AM 4/2/2018 5:09:31 AM

4/2/2018 5:09:31 AM 4/2/2018 5:09:32 AM 4/2/2018 5:09:33 AM

4/2/2018 5:09:34 AM

4/2/2018 5:09:35 AM 4/2/2018 5:09:37 AM 4/2/2018 5:09:38 AM

4/2/2018 5:09:40 AM

4/2/2018 5:09:41 AM

4/2/2018 5:09:43 AM 4/2/2018 5:09:45 AM 4/2/2018 5:09:46 AM 4/2/2018 5:09:48 AM 4/2/2018 5:09:50 AM 4/2/2018 5:09:52 AM 4/2/2018 5:09:53 AM

4/2/2018 5:09:55 AM 4/2/2018 5:09:57 AM 4/2/2018 5:09:59 AM 4/2/2018 5:10:02 AM 4/2/2018 5:10:04 AM 4/2/2018 5:10:07 AM 4/2/2018 5:10:09 AM 4/2/2018 5:10:12 AM 4/2/2018 5:10:15 AM 4/2/2018 5:10:17 AM

0263

t-'age L OT L Kev1ew OT UA Kesuns - t-'u1ser 1.,necK 4/2/2018 5:27:26 AM



Alpha 060 Alpha Analyst! 00DC ALL Not Done

APPROVED BY:

APPROVAL DATE: _l---'/ l_·z,,,~/_18_· --

0264

Library Listing Report 6/12/12 12:16:17 PM Page l

*************************************************************************


*************************************************************************

Nuclide Library Title: Radium

Nuclide Library Description: Ra-226, Po-218, Rn-222



PO-218 5.049E+0l0 6003.000* 0.000 99.9800 0.0000

RN-222 5.049E+010 5490.000* 0.000 99.9200 0.0000

RA-226 S.049E+0l0 4785.000* 0.000 100.0000 0.0000

* = key line


0265

SECTION XII

ANALYTICAL DATA (RADIUM-228)

0266


Analysis Sheet

Work Order

·····-----

Date Recei~ed I_ 3/23/2018

Lab Deadline l 4/12/2018


Project I WESTLAKE

Report Level / 4


01 LCS

02 MBL

03 i DUP

04 DO

18-03110 Ra228 Run 1

Client ID

LCS

BLANK

OU-1-008

i I

Printed: 4/9/201811:27 AM Page 1 of 3

Login Sample CPM Date

03/23/18 00:00

Sample Aliquot

1.0000E+00 -·--- ----·-···------ ----+----

03/23/18 00:00 1.0000E+00 ------~- --------- -- --

1.0000E+00 ·-' --··- --·· -----

i 38 i 03/19/18 18:02 ----------------- ' ·----~--·-·· I - -- - -- --- --+--------,

OU-1-008 i

. 38 . 03/19/18 18:02 1.0000E+00

----r-- _r-____ -_------------=- t =-- i ~ . -----"-I- . ----- --+--I ~

l----~--~--------+----------------1 ,_____ __ -+--------1------------ ---r------+---------·---~--. ----+--------'

Activity Units pCi

Aliquot Units

Matrix WA

Method EPA 904.0

Instrument Type Alpha/Beta GPC L~_:::-t. ____ !-------- =--1-= --=--L-------------+--------' Radiometric Tracer Ba-133 i

I

---- -+----------------+------!-----

Radiometric Sol# Ba-Ga -----

Tracer Act (dpm/g) 488.39 -----------+,- ----,-·----······ --··-

I Carrier Yttrium I ---··----,-- ···- --- ----·· ---·------i- '

Carrier Co~~~~~ml) I 30 11 l_ __ __ 1_____ ___________ +·-- _____ l __________________ ] _____ _ I I

I : i

··--- ----+--------------1 ,----~--------+ ----------------------;-- ------+-----· ··----·-·-·--+----------·-

I

-··· !-----····- :---··---·- ---, I I

i ' I

• SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. ' Indicates estimated SAF value.


0267

Eberline Analytical


Analysis Sheet

18-03110 Ra228 Run 1

Printed: 4191201811:27 AM

Page 2 of 3

Internal Fraction

01

Sample Desc

LCS

Tracer Aliquot (g)

1.0027

I

I! Tracer Total

ACT(dpm)

489.7 ,


297.0

Radiometric Ii Grav Carrier % Rec Added (ml)

134.64

Grav Filter Tare (g)


Grav Filter I Net (g) I

Grav %Rec

Mean %Rec

I

SAF I 1• I

SAF 2·

1.00 2.0501 0.0109! __ 0.1320: 0.06111 99.35! 109.28 1.00

2.150\ o.0116t--~.1;61. o.0645 100~-~o.~·~,-1.-oo-+-l-1-.0-0--11 I

1------r--~·+---------,~- ·----·------··--- - -- . ·-~----·- -+------.-i

491.6 i 02 MBL 1.0065 339.0 153.10 1 --- --

· ·~r I ·- i

488.9 352.0 159.83 2.300, 0.0708, 0.1397 0.0689 99.86, 109.84 1.00 I I 03 DUP 1.0011

04 DO 1.0043 490.5 l- -277.0 125.37 2.050 0.0714 0.1329 0.0615 100.00 110.00 1.00

!

L--t--+---+---1---+-----r-1--r----i I

I

7

7 I

i 7

I

i I

7

-----+-------+-------+--------+------

i

I I

·•

I ······-···-·

~~--t-----;-1~· ~ -----+-----+---~



1.00

1.00

0268

Eberline Analytical


Analysis Sheet

18-03110 Ra228 Run 1

Printed: 4/9/2018 11 :27 AM Page 3 of3

Inter~ Sample I Rough Prep

Fraction I Desc Date

Rough Prep Prep

By Date Prep Sep to

By Date/Time Sep to

By Sep t1

Date/Time Sep t1

By

01 LCS

02 MBL

03 DUP

04/09/18 08:57 1 EBAILEY 04/02/1814:31 EBAILEY i 04/09/18 09:50 ·--'------+--- "-----~--!- .. --- ----·-- ---+--- -------+

i , I

04/09/18 08:57 I EBAILEY j 04/02/18 14:31 EBAILEY . 04/09/18 09:50 ----+------+--- ··· ----------~-~--------------·.....c_, __________ -- I --------·-1--·-

04/09/18 09:50

EBAILEY

EBAILEY

EBAILEY 04/09/18 08:57 I EBAILEY , 04/02/18 14:31 ' EBAILEY i -----<-------+-- I r---------- -----+---~-~· ------_.i...-------------·--

04 DO EBAILEY _j_ 04/02/18 14:31 EBAILEY ! 04/09/18 09:50 ---+-----

. I

04/09/18 08:57 EBAILEY

!

·-- ~----------+--------+-----------+--~ ·---··--~-

-1--------j-----1---~----------+----------+------------+-------~

1-------,-----1----~ -·-----~-----+--------+-----------+--------

l--------j-----1----· ··--···

---

--------+---------+------------+-----------+ ----------~---------+-----------+----------1

----i------+--------+-----· ··•··--···-

l--------j-----1-------

I I

f----



I

··--

0269


~ Lab

Nuclide Fraction

01 RA-228

§ a:

~ 0 0 .!!! ~ iii s:::: q:

II

""""

co N N ns 0:::

1/) C: .2 .!? (.) Cl)

C ns -C: Cl)

E C: 0 II.. ·s;: C: w 0 ~ <

02 RA-228

03 RA-228

04 RA-228

I Sample Desc

LCS

MBL

DUP

DO


Work Order: 18-0311 0-Ra228-1

Client I Activity

I Error Estimate I I Results MDA


LCS pCi/1 8.43E+00 7.20E-01 8.65E-01

BLANK pCi/1 2.64E-01 3.20E-01 6.54E-01

OU-1-008 pCi/1 9.25E-01 3.72E-01 6.SSE-01

OU-1-008 pCi/1 1.49E-01 3.36E-01 7.03E-01

LCS LCS Known %R

8.96E+00 94.01


LCS RPO

I MDA Blank

Flag Flag Flag Flag

OK OK

OK OK

NA OK

OK

0270


~ ~

~

{: 8 .!!/ ~ cu t:: q;

11 0

~

00 N N cu ~

1/) C: 0 1/) ·c:; Q)

C cu -C: Q)

E C: 0 ... > C: w 0 :iE <(

Lab Fraction

Nuclide

01 RA-228

02 RA-228

03 RA-228

04 RA-228

Sample Desc

LCS

MBL

DUP

DO


Work Order: 18-03110-Ra228-1

Sample

I Sample Radiometric Grav Mean

I Date Aliquot % Rec %Rec %Rec

03/23/18 00:00 1.00E+00 134.64 99.35 109.28

03/23/18 00:00 1.00E+00 153.10 100.00 110.00

03/19/18 18:02 1.00E+00 159.83 99.86 109.84

03/19/18 18:02 1.00E+00 125.37 100.00 110.00

I SAF

I

1.00

1.00

1.00

1.00


SeptO Sept1

Date/Time Date/Time

4/2/2018 14:31 4/9/2018 9:50

4/2/2018 14:31 4/9/2018 9:50

4/2/2018 14:31 4/9/2018 9:50

4/2/2018 14:31 4/9/2018 9:50

0271



01 RA-228

§ a:

.g 8 -!!! ~ iii C:

<:(

~

~

""""'"

co N N ca 0::

1/) C: 0

-~ (.) Q)

C cu -C: Q)

E C: 0 ... "> C: w 0 :l:: <(

02 RA-228

03 RA-228

04 RA-228

Sample Desc

LCS

MBL

DUP

DO


Work Order: 18-0311 0-Ra228-1

Counting Halflife Detect Carrier I

Count Counts


04/09/18 11 :42 LB4110A F1 I 120 948

04/09/18 11 :42 LB4110A F2 120 142

04/09/18 11 :42 LB4110A F3 120 224

04/09/18 11 :42 LB4110A F4 120 157

Bkg CPM

1.483333333

0.966666667

1.1

1.183333333

I


Eff

0.4754

0.4658

0.4713

0.4773

0272


18-0311 0-Ra228-1 (pCi/1) in WA

Tracer ID: Ba-Ga


Internal Sample I Client Sample Sample

1

, Tracer Tracer ---: Radiometric Radiometric

Fraction Desc i ID Date Aliquot Aliquot (g) ACT (dpm) j Tracer {pCi) % Rec SAF

1*

---- 02_j LCS i LCS I 03/23/18 00:00 1.00~~- I 1.0027 I 489.7087 297.0000 134.64 1.00

SAF 2*

1.00

-- : I I I

02 J MBL BLANK___ j 03/23/18 00:00 1.~000 I 1.0065 I 491.5645 339.000_~--~-1-53.10 1.00 1.00

03 DUP OU-1-008 03119/18 18:02 1.0000 I 1.0011 i 488.9272 352.0000 : 159.83 1.00 1.00

04 DO OU-1-008 I 03/19/18 18:02 1.0000 1.0043 I 490.4901 277.0000 i 125.37 1.00 1.00

1------I I -'---- --1-----------L..---'

j

,--·--·- I -// ______ _

I -~--·

I-~-- : l~==il--t--t--==t= I I ' I

--- I I ! I . - ' I i

T I ' ~J I - I -- ~ · 1

1

~+-___J

I --

1--·· --------+-- 1 ~ -,----+----+------1----~-- I I - - .. -- -i--- --------- -+-- ----- -----,----------,------l---------+----- ····--------···--+----+-----~

I

- - -- +-----------~-- ----- ____ ! - I -_ ~ ~-

0273

Eberline Analytical

Oak Ridge-Laboratory

LCS & Matrix Spikes

I Activity ! Solution

Isotope So/# : dpm/g i Date

Ra-228 Ra-12 I 56.230 4/9/2018

I :

i I

Tracers

I I I Activity

fraction Isotope !

So/# I

I dpm/g

01 Ba-133 Ba-6a 488.390

02 Ba-133 Ba-6a 488.390

03 Ba-133 Ba-6a 488.390

04 Ba-133 Ba-6a 488.390

I

i

Version 2.0 08/99

I Approx I Addition

0.360

\ Solution I I Date .

4/9/2018

4/9/2018

4/9/2018

4/9/2018

i I I !

I

I I



Ra228 4/9/2018 8:57 EBAILEY


Volume Volume Volume Volume Known I Error Added ! Error

Used(g) Used(g) Used(g) Used(g) pCi I Estimate pCi Estimate

0.3539 8.96[ 0.457 o.ooi 0.000

I I

i i .. ·- .....

I I I


Volume Approx Tracer Used(g) Addition

1.0027 2.0700

1.0065 2.0700

1.0011 2.0700

1.0043 2.0700

--··--·--



1(3

LCSD MSD

Known Error Added I Error pCi Estimate pCi , Estimate

0.00 0.000 o.oo( 0.000

i i

I

LCS

Matrix Spike

0274

Lab



Fraction Client ID

01 LCS

02 BLANK

03 OU-1-008

04 OU-1-008

Comments

Analysis Code

Ra228

Sample Muffle Data Ratio

Type Post/Pre

LCS MBL

DUP DO

Techn;cian cc_ ~j.;: kwo,

Aliquot Worksheet

Rpt Units Lab Deadline

liters 4/12/2018


No of Dils Dil Factor Ratio Aliquot Net Equiv I 1.0000E+OO 1.0000E+OO

1.0000E+OO' 1.0000E+OO

1.0000E+OO 1.0000E+OO

1.0000E+OO 1.0000E+OO

I

Date:~

Technician

JHARVEY

MS Aliquot Data


H-3 Solids Only vvater Aaaea A3u-.sr-

Aliquot Net Equiv (ml) I Aliq

!

i ! I :

!

0275


Work Order I

1s-03110 I TRetec AMO Environmental Decisions

Fraction Client ID

01 LCS

02 BLANK

03 DUP

04 OU-1-008

-

- --··-·---

~·-------·

--- ---

-- ... --····

/i ,,,-~, / 1_ //J ~✓

I ll/,, /. Technician: C:-:t / /(/ // l

Run

Sample

Type

LCS

MBL

DUP DO

Gravimetric Worksheet

I Analysis I Gravimetric

Code Carrier

Ra228 I Yttrium

Carrier Data Filter Data Carrier Added Filter Tare Filter Final

(ml) (g) (g)

2.0500 0.0109 I 0.1320

2.1500 0.0116 I 0.1361

2.3000 0.0708 0.1397

2.0500 0.0714 0.1329

f

I

I I i I

I

:

i

i

I ·---- ----··

-' I

Date: 11 I ti I /f./ V) ___ ,_.....,_._

Carrier Cone

(mg/ml)

30.0000

I Filter Net

(g)

0.0611

0.0645

0.0689 0.0615

I

I


Technician

EBAILEY

Gravimetric %

Recovery

99.35 100.00

99.86 100.00

0276

Detector ID Sample ID Alpha Beta Count Time Voltage TOD ·~

---t \-°" \vQ F1 1803110-01 33 948 120 1410 4/9/2018 11 :42:11 AM

F2 1803110-02 3 142 120 1410 4/9/2018 11 :42: 11 AM

F3 1803110-03 5 224 120 1410 4/9/2018 11 :42: 11 AM

F4 1803110-04 18 157 120 1410 4/9/2018 11 :42:11 AM

0277

Eberline Analytica Oak Ridge Labora·:ory

r J- Detector

LB4110A - Al

LB4110A - A2 -LB4110A - A3

LB4110A - A4

LB4110A - Bl

LB4110A - B2

LB4110A - B3 -l_B4110A - B4

LB4110A - Cl

LB4110A - C2 r-

LB4110A - C3

LB4110A - C4

LB4110A - D1

LB4110A - D2

LB4110A - D3

LB4110A - D4

LB4110A - El

l.B4110A - E2

l.B4110A - E3

LB4110A - E4

l.B4110A - Fl

LB4110A - F2

LB4110A - F3

LB4110A - F4

LB4110A - Gl

LB4110A - G2

LB4110A - G3 -LB4110A - G4 -

Alpha/Beta

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Calibration Date

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

GPC Detector Report (ALL Backgrounds)

Count Date Bkg CPM

4/9/2018 5.00E-02 j 4/9/2018 l.00E-01

4/9/2018 5.00E-02

4/9/2018 8.33E-02

4/9/2018 6.67E-02

4/9/2018 l.00E-01

4/9/2018 3.33E-02

4/9/2018 5.00E-02

4/9/2018 6.67E-02

4/9/2018 3.33E-02

4/9/2018 8.33E-02

4/9/2018 6.67E-02

4/9/2018 8.33E-02

4/9/2018 l.50E-01

4/9/2018 8.33E-02

4/9/2018 l.83E-01 I

3/23/2018 0.00E+00 i 3/23/2018 0.00E+00

3/23/2018 0.00E+00

3/23/2018 0.00E+00

4/9/2018 l.67E-02

4/9/2018 3.33E-02

4/9/2018 6.67E-02

4/9/2018 l.67E-02

4/9/2018 3.33E-02

4/9/2018 6.67E-02

4/9/2018 5.00E-02

4/9/2018 8.33E-02

PFW LCL Mean

p -5.83E-02 9.76E-02

p I -5.51E-02 8.94E-02

p -4.59E-02 l.05E-01

p -4.83E-02 9.12E-02

p -5.05E-02 l.06E-01

p j -3.02E-02 l.18E-01

p -6.47E-02 9.28E-02

p I -5.30E-02 8.43E-02

p -6.96E-02 9.57E-02

p -5.92E-02 7.03E-02

p -7.32E-02 9.30E-02

p -5.46E-02 8.29E-02

p -4.14E-02 l.54E-01

p -3.44E-02 l.39E-01

p -5.41E-02 l.14E-01

p -2.97E-02 l.43E-01

p ! -3.12E+0l 6.llE-01

p -3.93E-02 6.40E-02

p -6.26E-02 l.18E-01

p -3.22E+0l 5.72E-01

p -7.42E-02 9.58E-02

p -l.94E-01 7.50E-02

p -8.84E-02 l.25E-01

p I -5.45E-02 8.30E-02

p -5.85E-02 8.52E-02

p -5.46E-02 7.70E-02

p -5.29E-02 l.19E-01

p -3.18E-02 8.86E-02

i

I

µ_p Printed: 4/9/2018 6:44 AM L//Cf Ii §_i

Page 1 of 1

UCL

2.53E-01

2.34E-01

2.56E-01

2.31E-01

2.63E-01

2.65E-01

2.50E-01

2.22E-01

2.61E-01

2.00E-01

2.59E-01

2.20E-01

3.48E-01

3.12E-01 I 2.82E-01

3.15E-01 I 3.24E+0l

l.67E-01

2.99E-01 ,

3.34E+0l

2.66E-0·l

3.44E-01

3.38E-01

2.21E-01

2.29E-01

2.09E-01

2.90E-01

2.09E-01

0278


,... Detector

LB4110A - Al

LB4110A - A2

LB4110A - A3

LB4110A - A4

. LB4110A - Bl

LB4110A - B2

LB4110A - B3

l_B4110A - B4

LB4110A - Cl

LB4110A - C2

LB4110A - C3

LB4110A - C4

LB4110A - D1

LB4110A - D2

LB4110A - D3

LB4110A - D4

LB4110A - El

LB4110A - E2

LB4110A - E3

I_B4110A - E4

LB4110A - Fl

LB4110A - F2

i_B4110A - F3

LB4110A - F4

LB4110A - Gl

LB4110A - G2

LB4110A - G3

LB4110A - G4

Alpha/Beta Calibration Date

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015

Beta 10/20/2015


Count Date Bkg CPM

4/9/2018 l.00E+00

4/9/2018 l.27E+00

4/9/2018 l.67E+00

4/9/2018 l.47E+00

4/9/2018 l.87E+00

4/9/2018 l.32E+00

4/9/2018 l.18E+00

4/9/2018 l.52E+00

4/9/2018 9.67E-01

4/9/2018 l.13E+00

4/9/2018 l.50E+00

4/9/2018 l.28E+00

4/9/2018 1.lOE+00

4/9/2018 1.48E+00 I

4/9/2018 l.07E+00

4/9/2018 l.80E+00

3/23/2018 3.33E-02

3/23/2018 l.67E-02

3/23/2018 6.67E-02

3/23/2018 0.00E+00

4/9/2018 1.48E+001

4/9/2018 9.67E-01

4/9/2018 l.lOE+00

4/9/2018 l.18E+0Q

4/9/2018 1.33E+00

4/9/2018 2.15E+00

4/9/2018 1.40E+00

4/9/2018 l.52E+00

PFW LCL

p 8.59E-01

p I 9.03E-01

p l.05E+00

p 3.07E-02

p l.05E+00

p 7.76E-01

p 9.46E-01

p 8.15E-01

p 8.67E-01

p 2.37E-01

p 9.16E-01

p 8.05E-01

p -2.14E+00

p -l.30E+00

p -9.79E-01

p -1.44E+00

p -4.88E+0l

p 5.69E-01

p 6.34E-01

p -5.22E+0l

p 6.42E-01

p -3.95E+02

p -4.86E+00

p -4.26E+00

p 8.27E-01

F 1.14E+00

p 8.63E-01

p 7.13E-01

Mean

l.44E+00

1.49E+00

l.58E+00

l.53E+00

l.61E+00

l.54E+00

l.45E+00

1.44E+00

l.34E+00

l.19E+00

l.75E+00

1.27E+00

2.03E+00

2.lOE+00

l.75E+00

2.16E+00

2.19E+00

9.46E-01

1.19E+00

l.87E+00

1.44E+00

2.03E+0l

2.09E+00

1.77E+00

1.29E+00

1.66E+00

1.42E+00

1.36E+00

KD Printed: 4/9/2018 6:44 AM L{ /Cf /J e£,

Page 1 of 1

UCL

2.03E+00

2.09E+00

2.12E+00

3.04E+00

2.17E+00

2.30E+00

l.96E+00

2.06E+00

l.81E+00

2.14E+00

2.59E+00

l.74E+00

6.19E+00

5.51E+00

4.48E+00

5.75E+00

5.32E+0l

l.32E+00

l.75E+00

5.59E+0l

2.24E+00

4.35E+02

9.05E+00

7.80E+00

1.75E+00

2.17E+00

l.98E+00

2.0lE+00

0279

Eberline Analytical Oak Ridge Laboi-atory

~:tor

i LB4110A - Al

LB4110A - A2

LB4110A - A3

LB4110A - A4

LB4110A - Bl

LB4110A - B2

LB4110A - B3

LB4110A - B4

LB4110A - Cl

LB4110A - C2

LB4110A - C3

LB4110A - C4

LB4110A - D1

LB4110A - D2

LB4110A - D3

LB4110A - D4

LB411CA - El

LB411CA - E2

LB411CA - E3

LB411CA - E4

LB411CA - Fl

LB411CA - F2

LB411CA - F3

LB411CA - F4

LB4110A - Gl

LB4110A - G2

LB4110A - G3

LB4110A - G4

Alpha/Beta

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Calibration Date

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

GPC Detector Report (ALL Efficiencies)

Count Date Eff

4/9/2018 0.2252

4/9/2018 0.2096

4/9/2018 0.2000

4/9/2018 0.2292

4/9/2018 0.2288

4/9/2018 0.2002

4/9/2018 0.2385

4/9/2018 0.2279

4/9/2018 0.2079

4/9/2018 0.2132

4/9/2018 0.2427

4/9/2018 0.2123

4/9/2018 0.2204

4/9/2018 0.2558

4/9/2018 0.2529

4/9/2018 0.1932

3/23/2018 0.0000

3/23/2018 0.0000

3/23/2018 0.0000

3/23/2018 0.0000

4/9/2018 0.2109

4/9/2018 0.1805

4/9/2018 0.2390

4/9/2018 0.2153

4/9/2018 0.2006

4/9/2018 0.2066

4/9/2018 0.2:;307

4/9/2018 0.2040

Printed: 4/9/2018 6:44 AM KP Page 1 of t;/Cf/i e>

PFW LCL Mean UCL

p 0.2190 0.2299 0.2409

p 0.2029 0.2118 0.2207

p 0.1909 0.2007 0.2106 I

p 0.2195 0.2295 0.2394

p 0.2013 0.2214 0.2416

p 0.1831 0.2042 0.2253

p 0.2217 0.2363 0.2508

p 0.2135 0.2249 0.2363

p 0.2009 0.2106 0.2203

p I 0.0288 0.2230 0.4172

p 0.2343 0.2458 0.2573

p 0.2067 0.2188 0.2309

p 0.2103 0.2232 0.2360

p 0.2356 0.2521 0.2685

p 0.2399 0.2522 0.2646

p 0.1848 0.1955 0.2062

F 0.1959 0.2303 0.2648

F 0.1833 0.2089 0.2345

F 0.1855 0.2092 0.2330

F 0.2024 0.2394 0.2765

p 0.0510 0.1838 0.3166

p 0.1005 0.1800 0.2594

p 0.1678 0.2334 0.2989

p 0.1471 0.2100 0.2729

p 0.1919 0.2032 0.2144

p 0.1942 0.2057 0.2172 '

p 0.2171 0.2275 0.2378

p 0.1918 0.2017 0.2115

0280

Eberline Analytical Oak Ridge Labo,·atory

Dete,:tor

LB4110A - Al

LB4110A - A2

LB4110A - A3

LB4110A - A4

LB4110A - Bl

LB4110A - B2

LB4110A - B3

LB4110A - B4

LB4110A - Cl

LB4110A - C2

LB4110A - C3

LB4110A - C4

LB4110A - D1

LB4110A - D2

LB4110A - D3

LB4110A - D4

LB4110A - El

LB4110A - E2

LB4110A - E3

LB4110A - E4

LB4110A - Fl

LB4110A - F2

LB4110A - F3

LB4110A - F4

LB4110A - Gl

LB4110,I\ - G2

LB4110A - G3

LB4110A - G4

Alpha/Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Calibration Date

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015


Count Date Eff

4/9/2018 0.5328

4/9/2018 0.4651

4/9/2018 0.4793

4/9/2018 0.5356

4/9/2018 0.5397

4/9/2018 0.5071

4/9/2018 0.5872

4/9/2018 0.5506

4/9/2018 0.4813

4/9/2018 0.5255

4/9/2018 0.6052

4/9/2018 0.5300

4/9/2018 0.6321

4/9/2018 0.6437

4/9/2018 0.6456

4/9/2018 0.5040

3/23/2018 0.0436

3/23/2018 0.0428

3/23/2018 0.0551

3/23/2018 0.0569

4/9/2018 0.5242

4/9/2018 0.4434

4/9/2018 0.6177

4/9/2018 0.5364

4/9/2018 0.4642

4/9/2018 0.4834

4/9/2018 0.5380

4/9/2018 0.4830

Printed: 4/9/2018 6:44 AM

Page 1 of 1 J< p PFW I LCL Mean UCL 4/q)1 ~

p 0.5198 0.5427 0.5656

p 0.4457 0.4705 0.4952

p 0.4579 0.4783 0.4987

p 0.5294 0.5509 0.5724

p 0.5054 0.5379 0.5704

p 0.4714 0.5049 0.5385

p 0.5561 0.5849 0.6136

p 0.5274 0.5521 0.5767

p 0.4642 0.4906 0.5170

p 0.5045 0.5274 0.5503

p 0.5821 0.6110 0.6398

p 0.5064 0.5363 0.5661

w 0.6276 0.6526 0.6775

p 0.6171 0.6490 0.6809

p 0.6158 0.6409 0.6660

p 0.4643 0.5009 0.5374

F 0.4730 0.5519 0.6307

F 0.4450 0.5020 0.5591

F 0.4552 0.5070 0.5589

F 0.5130 0.5987 0.6844

p 0.2986 0.4669 0.6352

p 0.2966 0.4389 0.5812

p 0.4745 0.5896 0.7047

p 0.4114 0.5209 0.6305

p 0.4449 0.4650 0.4852

p 0.4729 0.4974 0.5219

p 0.5290 0.5538 0.5785

p 0.4706 0.4959 0.5213

0281

SECTION XIII

BARIUM-133 ANALYTICAL TRACER DATA

0282

4/2/2018 3:34:57PM Page I of6

pex-Gamma Analysis Report for 1803110-01

SPIKE

GAMMA SPECTRUM ANALYSIS

Sample Identification

Sample Description

Sample Type

Sample Size Facility

Sample Taken On

Acquisition Started

Procedure Operator Detector Name

Geometry Live Time Real Time

Dead Time

Peak Locate Threshold

Peak Locate Range (in channels)

Peak Area Range (in channels)

Identification Energy Tolerance

Energy Calibration Used Done On

Efficiency Calibration Used Done On

Efficiency Calibration Description

Sample Number

: 1803110-01

: SPIKE : RA RECOVERY

: 1.000E+00 units

: Countroom

: 4/2/2018 3: 18:22PM

: 4/2/2018 3:19:47PM

: BAFIL : Administrator

: GE1 : BAFIL : 900.0 seconds

: 900.2 seconds

: 0.02 %

: 2.50 : 1 - 4096 : 19 - 4096 : 1.000 keV

: 2/17/2018

: 2/17/2018

: 64152

PEAK ANALYSIS REPORT

Peak Analysis Performed on : 4/2/2018 3:34:50PM

Peak No.

Peak Analysis From Channel

Peak Analysis To Channel

Energy (keV)

ROI

start

ROI end

: 1 : 4096

Peak Centroid

Net Peak Area

Net Area Uncertainty

Continuum Counts

FWHM (keV)

0283

M m M m m M

M m

M m

m M m

M m

M m M m

4/2/2018 3:34:57PM Page 2 of6

Analysis Report for 1803110-01

SPIKE

Peak Energy ROI

No. (keV} start

1 30.68 27 -2 35.05 27 -3 53.08 50 -4 61.75 50 -5 65.84 50 -6 81.12 77 -7 93.08 91 -8 111.72 108 -9 115.73 108 -

10 160.44 158 -11 276.26 272 -12 303.05 299 -13 306.81 299 -14 334.45 330 -15 356.15 350 -16 384.81 382 -17 391.23 382 -18 414.54 411 -19 437.37 434 -20 456.70 455 -21 466.40 462 -22 606.28 605 -23 609.46 605 -24 1002.05 998 -25 1522.38 1518 -

M = First peak in a multiplet region

m = Other peak in a multiplet region

F = Fitted singlet Errors quoted at 2.000sigma

ROI Peak Net Peak Net Area Continuum

end Centroid Area Uncertainty Counts

40 31.18 l.17E+03 72. 52 1.32E+02

40 35.55 3.62E+02 59.52 1.22E+02

73 53.57 2.16E+0l 23.02 7.80E+0l

73 62.23 1.78E+02 34.15 7.80E+0l

73 66.31 5.96E+0l 32.35 9.l0E+0l

91 81.58 5.05E+02 51.40 1.35E+02

97 93.53 5.79E+0l 25.24 7.42E+0l

119 112.15 1.22E+02 29.08 7.85E+0l

119 116.15 2.0lE+0l 20.44 5.67E+0l

163 160.83 3.04E+0l 21. 21 6.52E+0l

282 276.54 5.51E+0l 25.86 5.78E+0l

318 303.31 7.14E+0l 20.90 2.98E+0l

318 307.07 1.80E+0l 17.46 2.26E+0l

340 334.69 7.07E+0l 29.39 7.85E+0l

367 356.36 3.52E+02 39.43 3.48E+0l

395 385.00 7.17E+0l 22.30 1.22E+0l

395 391.42 2.55E+0l 20.33 2.67E+0l

418 414.71 1.57E+0l 17.44 4.06E+0l

443 437.52 3.86E+0l 19.77 3.08E+0l

459 456.83 6.00E+00 4.90 0.00E+00

470 466.52 l.26E+0l 11. 69 1.28E+0l

611 606.29 5.06E+00 3.77 2.45E+00

611 609.47 8.90E+00 7.28 2.36E+00

1004 1001.78 9.00E+00 6.00 0.00E+00

1524 1521.80 5.00E+00 4.47 0.00E+00

BACKGROUND SUBTRACT REPORT

Peak Analysis Performed on

Env. Background File

Peak Energy

No. (keV)

1 30.68 2 35.05 3 53.08 4 61.75

: 4/2/2018 3:34:50PM

: \\OR-GAMMA 1 \ApexRoot\Countroom\Data\0000063824.CNF

Original Orig. Area Ambient Backgr. Subtracted

Area Uncertainty Background Uncert. Area

1.17E+03 72. 52 1.17E+03

3.62E+02 59.52 3.62E+02

2.16E+0l 23.02 2.16E+0l

l.78E+02 34.15 1.78E+02

FWHM (keV)

1. 74 2.08 2.15 2.13 2.18 2.01 1. 70 1. 70 1. 70 1. 60 2.02 2.05 2.06 1. 95 1. 94 1. 75 2.34 1. 34 1. 94 2.74 4.94 2.49 2.12 1. 77 2.75

Subtracted Uncert.

7.25E+0l 5.95E+0l 2.30E+0l 3.41E+0l

0284

4/2/2018 3:34:57PM Page 3 of6


SPIKE

Peak Energy Original Orig. Area Ambient Backgr. Subtracted Subtracted

No. {keV) Area Uncertainty Background Uncert. Area Uncert.

m 5 65.84 5.96E+0l 32.35 6.94E-0l 3.48E-01 5.89E+0l 3.24E+0l

M 6 81.12 5.05E+02 51.40 5.05E+02 5.14E+0l

7 93.08 5.79E+0l 25.24 3.26E+0l 2.92E+00 2.53E+0l 2.54E+0l

M 8 111.72 l.22E+02 29.08 l.22E+02 2.91E+0l

m 9 115.73 2.0lE+0l 20.44 2.0lE+0l 2.04E+0l

10 160.44 3.04E+0l 21. 21 3.04E+0l 2.12E+0l

11 276.26 5.51E+0l 25.86 5.51E+0l 2.59E+0l

M 12 303.05 7.14E+0l 20.90 7.14E+0l 2.09E+0l

m 13 306.81 l.80E+0l 17.46 l.80E+0l l.75E+0l

14 334.45 7.07E+0l 29.39 7.07E+0l 2.94E+0l

m 15 356.15 3.52E+02 39.43 3.52E+02 3.94E+0l

M 16 384.81 7.17E+0l 22.30 7.17E+0l 2.23E+0l

m 17 391.23 2.55E+0l 20.33 2.55E+0l 2.03E+0l

18 414.54 l.57E+0l 17.44 l.57E+0l l.74E+0l

19 437.37 3.86E+0l 19.77 3.86E+0l l.98E+0l

20 456.70 6.00E+00 4.90 6.00E+00 4.90E+00

21 466.40 l.26E+0l 11. 69 l.26E+0l l.17E+0l

M 22 606.28 5.06E+00 3.77 5.06E+00 3.77E+00

m 23 609.46 8.90E+00 7.28 2.56E+00 l.16E+00 6.33E+00 7.37E+00

24 1002.05 9.00E+00 6.00 9.51E-01 7.24E-01 8.05E+00 6.04E+00

25 1522.38 5.00E+00 4.47 5.00E+00 4.47E+00




NUCLIDE IDENTIFICATION REPORT

Nuclide Library Used : \\OR-GAMMA1\ApexRoot\Countroom\Library\WSRC.NLB

IDENTIFIED NUCLIDES

Nuclide Id Energy Yield(%) Activity Activity

Name Confidence (keV) (pCilunits) Uncertainty

SN-113 0.94 255.12 1. 93 391.69 * 61.90 l.52E+0l l.21E+0l

I-125 0.97 35.49 * 6.49 3.37E+00 5.53E-01

BA-133 0.99 30.80 * 97.60 2.l0E-01 l.30E-02

302.84 * 17.80 3.16E+02 l.66E+02

356.01 * 60.00 2.97E+02 4.65E+0l

PA-231 0.99 9.28 42.00 10.11 20.20

0285


SPIKE

Nuclide Id Energy

Name Confidence (keV)

PA-231 0.99 283.67 302.67

* = Energy line found in the spectrum.

- = Manually added nuclide.

? = Manually edited nuclide.

*

@ = Energy line not used for Weighted Mean Activity

Energy Tolerance: 1.000 keV

Nuclide confidence index threshold = 0.30

Errors quoted at 2.000sigma

Yield(¾)

1. 60 2.30

4/2/2018 3:34:57PM Page 4 of 6

Activity

(pCilunits)

2.44E+03

Activity

Uncertainty

1.29E+03

INTERFERENCE CORRECTED REPORT

Nuclide Name

SN-113 I-125

Nuclide Id

Confidence

0.940 0.970

X I-129 0.681

? = X =

BA-133 PA-231

0.997 0.999

nuclide is part of an undetermined solution

nuclide rejected by the interference analysis

Wt mean Activity

(pCilunits)

1.52E+0l 3.37E+00

2.l0E-01 2.44E+03

@ = nuclide contains energy lines not used in Weighted Mean Activity


Wt mean Comments Activity

Uncertainty

1.21E+0l 5.53E-01

1.30E-02 1.29E+03

0286


M

m m M

M

m

m

M

M

m

SPIKE

Peak Locate Performed on

Peak Locate From Channel

Peak Locate To Channel

Peak No. Energy (keV)

3 53.08

4 61.75

5 65.84

6 81.12

7 93.08

8 111.72

9 115. 73

10 160.44

11 276.26

13 306.81

14 334.45

16 384.81

18 414.54

19 437.37

20 456.70

21 466.40

22 606.28

23 609.46

24 1002.05

25 1522.38



F = Fitted singlet


4/2/2018 3:34:57PM

UNIDENTIFIED PEAKS

: 4/2/2018 3:34:50PM

: 1 : 4096

Peak Size (CPS)

2.40359E-02

1.97417E-01

6.54781E-02

5.60890E-01

2.80855E-02

1.35124E-01

2.23089E-02

3.37566E-02

6.12103E-02

2.00002E-02

7. 85960E-02

7. 96880E-02

1. 74691E-02

4.28704E-02

6.66667E-03

1.40058E-02

5.61935E-03

7.03687E-03

8.94381E-03

5.55556E-03

Peak CPS(%)

Uncertainty

53. 21 9.61

27.45

5.09

50. 27

11. 96 50.90 34.91 23.47

48.51 20.77

15.55 55.45

25.62

40.82 46.39

37.32 58.20 37.54

44. 72

NUCLIDE MDA REPORT

Peak Type

Sum Sum

Sum

Sum


Page 5 of6

Tolerance Nuclide

0287

4/2/2018 3:34:57PM Page 6 of6


SPIKE

Nuclide Energy Yield(%) Line MDA Nuclide MDA Activity Dec. Level

Name (keV) (pCi/units) (pCilunits) (pCi/units) (pCi/units)

FE-55 5.89 24.50 l.90E-13 1.90E-13 0.00E+00 0.00E+00

CO-57 122.06 85.51 2.68E+0l 2.68E+0l -2.16E+00 1.22E+0l

136.48 10.60 2.82E+02 -3.88E+0l 1.29E+02

NI-59 6.92 29.80 2.77E-12 2.77E-12 0.00E+00 0.00E+00

MO-93 16.59 52.90 7.83E-06 7.83E-06 0.00E+00 3.47E-06

18.60 10.00 3.54E-04 -4.81E-04 l.67E-04

NB-93M 16.57 9.43 4.32E-05 4.32E-05 0.00E+00 l.92E-05

CD-109 88.03 3. 72 2. 78E+02 2. 78E+02 4.73E+0l 1.30E+02

+ SN-113 255.12 1. 93 1.40E+03 1.98E+0l 1.26E+02 6.26E+02

391.69 * 61.90 1.98E+0l 1.52E+0l 9.llE+00

SN-119M 23.87 16.10 6.46E-03 4.62E-03 1.23E-02 3.12E-03

25.10 22.70 4.62E-03 -1.04E-02 2.18E-03

+ I-125 35.49 * 6.49 8.26E-01 8.26E-01 3.37E+00 4.00E-01

I-129 29. 78 * 57.00 2.73E-02 2.73E-02 3.59E-0l 1.32E-02

33.60 13. 20 3.98E-01 -1.73E+00 1.95E-01

39.58 7.52 8.46E-01 9.55E-02 3.92E-01

+ BA-133 30.80 * 97.60 1.59E-02 1.59E-02 2.l0E-01 7.73E-03

302.84 * 17.80 2.37E+02 3.16E+02 1. 13E+02

356.01 * 60.00 4.53E+0l 2.97E+02 2.15E+0l

CE-139 165.85 80.35 4.36E+0l 4.36E+0l -3.19E+00 1.97E+0l

CE-144 133. 54 10.80 2.68E+02 2.68E+02 8.35E-01 1.23E+02

HG-203 279.19 77.30 4.89E+0l 4.89E+0l 5.36E+0l 2.28E+0l

PB-210 46.50 4.25 5.0lE+00 5.0lE+00 1.79E+00 2.31E+00

+ PA-231 9.28 42.00 2.61E-10 2.61E-10 0.00E+00 0.00E+00

10 .11 20.20 2.08E-09 0.00E+00 0.00E+00

283.67 1. 60 l.17E+03 -3.28E+02 5.10E+02

302.67 * 2.30 1.83E+03 2.44E+03 8.71E+02

TH-231 25.64 14.70 8. 96E-03 8.96E-03 -2.0lE-02 4.22E-03

84.21 6.40 1.66E+02 -9.94E+02 7.84E+0l

PA-234M 9.89 89.00 3.36E-10 3.36E-10 0.00E+00 0.00E+00

21. 72 64.90 5.99E-04 l.59E-03 2.90E-04

37.93 23.75 3.75E-01 5.19E-01 1.81E-01

131.42 20.40 l.34E+02 -4.17E+00 6.14E+0l

TH-234 63.29 3.80 9.02E+0l 9.02E+0l 5.84E+0l 4.34E+0l

NP-237 2 9. 37 14.00 1.34E-01 1.34E-01 8.67E-01 6.59E-02

86.50 12.60 8.23E+0l 1.88E+0l 3.86E+0l

U-237 97.08 16.30 7.35E+0l 5.97E+0l -7.24E+00 3.37E+0l

101.07 26.30 5.97E+0l 1.84E+0l 2.76E+0l

114.00 12.30 3.03E+02 4.64E+02 1.45E+02

208.01 22.00 1.68E+02 -7. 21E+0 1 7.62E+0l

AM-241 59.54 35.90 5.89E+00 5.89E+00 4.22E+00 2.82E+00

AM-243 74.67 66.00 6.79E+00 6.79E+00 5.13E-02 3.15E+00

+ = Nuclide identified during the nuclide identification

• = Energy line found in the spectrum

> = MDA value not calculated

@ = Half-life too short to be able to perform the decay correction

0288

105

104

~ lQ3t.~ ro <(

u !;:: Vl

en 0 ..-

1 Vl .µ C: ::;j

0 u 102

101

= = '";' ~

= = ...... ' ~

~ JI ;t

100 !fti $'~/~ fl ff I

500 1000

1111 ROI Type: 1

1500

0000064152.CNF

2000 channel

2500

Live Time :900.000 sec Real Time :900.210 sec start: 1: 0. S(kev) Stop : 4096: 4096. 9 (kev) Acq. start :Mon Apr 02 15:19:47 2018

3000

11111 ROI Type: 2

3500 4000

0289

4/2/2018 3:35:09PM Pagel of6 \~ \v\l 4Lv

f\pex-Gamma Analysis Report for 1803110-02

BLANK

GAMMA SPECTRUM ANAL YS/S


Sample Description

Sample Type

Sample Size

Facility

Sample Taken On

Acquisition Started

Procedure Operator

Detector Name

Geometry

Live Time

Real Time

Dead Time








Sample Number

: 1803110-02

: BLANK

: RA RECOVERY

: 1.000E+00 units

: Countroom

: 4/2/2018 3:18:32PM

: 4/2/2018 3:19:56PM



: 901.8 seconds

: 0.20 %

: 2.50

: 1 - 4096

: 9 - 4096 : 1.000 keV

: 2/17/2018

: 11/9/2014

: 64153



Peak No.



Energy (keV)

ROI start

ROI end

: 4096

Peak Centroid

Net Peak Area


Continuum Counts

FWHM (keV)

0290

4/2/2018 3:35:09PM Page 2 of6


M m M M m m

M m M m

M m M M m m

M m

BLANK

Peak Energy ROI

No. (keV) start

1 31.31 14 -2 61.98 54 -3 66.59 54 -4 80. 96 7 4 -5 105.41 104 -6 111.68 104 -7 116. 62 104 -8 183.40 1 74 -9 276.37 2 68 -

10 302.74 296 -11 308.30 296 -12 334.54 329 -13 355.78 329 -14 386.39 379 -15 416.56 410 -16 436.20 428 -17 468.32 4 63 -18 609.29 604 -




ROI end

41 72 72 99

119 119 119 191 286 326 326 367 367 400 424 442 475 614

Peak Net Peak Net Area Continuum

Centroid Area Uncertainty Counts

31.75 1. 51E+03 139.36 1.25E+03

62.39 2.20E+02 52.35 3.16E+02

67.00 6.99E+0l 48.59 2.43E+02

81.36 6.14E+02 52.91 1.48E+02

105.79 1.68E+0l 14.64 5.00E+0l

112.06 2.01E+02 40.60 1.40E+02

117. 00 5.45E+0l 22.00 6.53E+0l

183.74 3.28E+0l 41. 38 1. 96E+02

27 6. 64 4.88E+0l 35.92 9.65E+0l

303.00 2.37E+02 33.56 9.14E+0l

308.56 2.85E+0l 37.60 8.llE+0l

334.77 9.71E+0l 24.55 6.43E+0l

356.00 3.47E+02 39.33 4.27E+0l

386.60 2.20E+02 41.69 6.60E+0l

416.75 5.71E+0l 20.99 2.18E+0l

436.37 7.00E+0l 16.73 0.00E+00

468.47 3.13E+0l 13. 50 7.31E+00

609.36 1.22E+0l 11. 34 9.53E+00


Peak Analysis Performed on

Env. Background File

Peak Energy

No. (keV)

1 31.31 2 61.98 3 66.59 4 80. 96 5 105.41 6 111.68 7 116. 62 8 183.40 9 276.37

10 302.74 11 308.30

: 4/2/2018 3:35:05PM

: \\OR-GAMMA 1 \ApexRoot\Countroom\Data\0000063826.CNF

Original Orig. Area Ambient Backgr. Subtracted

Area Uncertainty Background Uncert. Area

1.51E+03 139.36 1.51E+03

2.20E+02 52.35 7.99E+0l 1.37E+00 1.40E+02

6.99E+0l 48.59 6.99E+0l

6.14E+02 52.91 6.14E+02

1.68E+0l 14.64 1.68E+0l

2.01E+02 40.60 2.01E+02

5.45E+0l 22.00 5.45E+0l

3.28E+0l 41.38 3.28E+0l

4.88E+0l 35.92 4.88E+0l

2.37E+02 33.56 2.37E+02

2.85E+0l 37.60 2.85E+0l

FWHM (keV)

2.08 3.84 6.93 2.63 3.99 4.04 6.55 7.49 2.26 5.61 6.15

11.77 2.89 2.59 3.51 1. 62 2.25 3.82

Subtracted Uncert.

1.39E+02 5.24E+0l 4.86E+0l 5.29E+0l 1.46E+0l 4.06E+0l 2.20E+0l 4.14E+0l 3.59E+0l 3.36E+0l 3.76E+0l

0291

4/2/2018 3:35:09PM Page 3 of6


M m

BLANK

Peak Energy Original

No. (keV) Area

12 334.54 9.71E+0l 13 355.78 3.47E+02 14 386.39 2.20E+02 15 416.56 5.71E+0l 16 436.20 7.00E+0l 17 468.32 3.13E+0l 18 609.29 1.22E+0l



F = Fitted singlet


Orig. Area Ambient Backgr. Subtracted

Uncertainty Background Uncert. Area

24.55 9.71E+0l

39.33 3.47E+02

41.69 2.20E+02

20.99 5.71E+0l

16.73 7.00E+0l

13. 50 3.13E+0l

11. 34 1.89E+00 1.35E+00 1.03E+0l



IDENTIFIED NUCLIDES

Nuclide Id Energy

Name Confidence (keV)

BA-133 0.97 30.80 302.84 356.01




* * *


Energy Tolerance : 1.000 keV



Yield(%)

97.60 17.80 60.00

Activity

(pCi/units)

1.31E+00 1.03E+03 3.39E+02

Activity

Uncertainty

1.21E-01 3.99E+02 5.19E+0l


Subtracted Uncert.

2.45E+0l 3.93E+0l 4.17E+0l 2.l0E+0l 1.67E+0l 1.35E+0l 1.14E+0l

0292


? =

X =

BLANK

Nuclide Name

BA-133

Nuclide Id

Confidence

0.974



4/2/2018 3:35:09PM

Wt mean Wt mean

Activity Activity

(pCi/units) Uncertainty

1.31E+00 1.21E-01



Page 4 of 6

Comments

0293


M

m M

M

m m

m M

BLANK




Peak No. Energy {ke V)

2 61.98

3 66.59

4 80. 96

5 105.41

6 111.68

7 116. 62

8 183.40

9 276.37

11 308.30

12 334.54

14 386.39

15 416.56

16 436.20

17 468.32

18 609.29



F = Fitted singlet


4/2/2018 3:35:09PM

UNIDENTIFIED PEAKS

: 4/2/2018 3:35:05PM

: 1 : 4096

Peak Size (CPS)

1.55904E-01

7.76879E-02

6.81897E-0l

1.86972E-02

2.23059E-01

6.05725E-02

3.64179E-02

5.41924E-02

3.16614E-02

1.07891E-01

2.44444E-01

6.34559E-02

7.77778E-02

3.48254E-02

1.14920E-02

Peak CPS(%)

Uncertainty

18.66

34.74

4.31

43.49

10 .11

20.18

63.12

36.83

65.98

12.64 9.47

18.38

11. 95 21.54

55.19

NUCLIDE MDA REPORT

Peak Type

Sum

Sum

Sum

Page 5 of6

Tolerance

Nuclide


Nuclide Name

Energy

(keV)

Yield(%) Line MDA

(pCi/units)

Nuclide MDA

(pCilunits)

Activity

(pCi/units)

Dec. Level

(pCi/units)

0294

4/2/2018 3:35:09PM Page 6 of 6


BLANK

Nuclide Energy Yield(¾) Line MDA Nuclide MDA Activity Dec. Level

Name (keV) (pCilunits) (pCi/units) (pCilunits) (pCi/units)

FE-55 5.89 24.50 4.27E-09 4.27E-09 5.68E-09 2.06E-09

CO-57 122.06 85.51 5.61E+0l 5.61E+0l -5.77E+0l 2.72E+0l

136.48 10.60 4.43E+02 3.03E+02 2.12E+02

NI-59 6.92 29.80 3.32E-08 3.32E-08 4.24E-08 l.60E-08

MO-93 16.59 52.90 6.83E-04 6.83E-04 6.38E-04 3.33E-04

18.60 10.00 l.39E-02 l.08E-02 6.79E-03

NB-93M 16.57 9.43 3.79E-03 3.79E-03 3.54E-03 l.85E-03

CD-109 88.03 3.72 7.97E+02 7.97E+02 3.29E+03 3.90E+02

SN-113 255.12 1. 93 2.13E+03 5.46E+0l -2.28E+02 l.00E+03

391.69 61.90 5.46E+0l l.32E+02 2.62E+0l

SN-119M 23.87 16.10 l.26E-01 l.26E-01 8.98E-01 6.22E-02

25.10 22.70 l.40E-01 l.04E+00 6.89E-02

I-125 35.49 6. 4 9 6.65E+00 6.65E+00 -3.29E+00 3.28E+00

I-129 29.78 57.00 2.17E-01 2.17E-01 l.70E+00 l.07E-01

33.60 13.20 2.23E+00 -5.81E-01 l.l0E+00

39.58 7.52 l.19E+0l -l.03E+0l 5.86E+00

+ BA-133 30.80 * 97.60 l.67E-01 l.67E-01 l.31E+00 8.25E-02

302.84 * 17.80 3.78E+02 l.03E+03 l.83E+02

356.01 * 60.00 l.03E+02 3.39E+02 5.0lE+0l

CE-139 165.85 80.35 6.82E+0l 6.82E+0l 4.14E+0l 3.26E+0l

CE-144 133.54 10.80 4.19E+02 4.19E+02 2.58E+02 2.01E+02

HG-203 279.19 77.30 5.58E+0l 5.58E+0l l.30E+00 2.64E+0l

PB-210 46.50 4.25 2.63E+0l 2.63E+0l -5.95E+0l l.28E+0l

PA-231 9.28 42.00 l.13E-06 l .13E-06 l.29E-06 5.49E-07

10.11 20.20 7.00E-06 7.51E-06 3.40E-06

283.67 1. 60 2.65E+03 l.89E+02 l.25E+03

302. 67 2.30 2.01E+03 2.85E+03 9.58E+02

TH-231 25.64 14.70 2.57E-01 2.57E-01 l.92E+00 l.27E-01

84.21 6.40 3.99E+02 l.64E+03 l.95E+02

PA-234M 9.89 89.00 l.15E-06 l.15E-06 l.31E-06 5.59E-07

21. 72 64. 90 l.33E-02 4.43E-03 6.58E-03

37.93 23.75 2.85E+00 -l.95E+00 l.41E+00

131.42 20.40 2.12E+02 -l.05E+02 l.02E+02

TH-234 63.29 3.80 l.66E+02 l.66E+02 -4.14E+02 8.l0E+0l

NP-237 29.37 14.00 7.93E-01 7.93E-01 6.22E+00 3.92E-01

86.50 12.60 2.22E+02 9.44E+02 l.09E+02

U-237 97.08 16.30 l.34E+02 l.01E+02 -l.51E+0l 6.42E+0l

101.07 26.30 l.01E+02 -l.05E+0l 4.88E+0l

114.00 12.30 3.53E+02 -l.42E+02 l.71E+02

208.01 22.00 2.47E+02 -7.29E+0l l.17E+02

AM-241 59.54 35.90 l.33E+0l l.33E+0l 9.72E-01 6.46E+00

AM-243 74.67 66.00 2.59E+0l 2.59E+0l 6.18E+0l l.27E+0l


* = Energy line found in the spectrum



0295

105

104

~ 103 ro u V)

O'I 0 r-

1 V)

-1-' C: :::s 0 u

102

101

100

¥ -ls

...... ' ;;!;

I

500 I

1000

-ROI Type: 1

0000064153.CNF

I ' ' 1500 2000 2500

channel

Live Time :900.000 sec Rea 1 Ti me : 901. 800 sec Start: 1: 0.S(kev) Stop : 4096:4097 .3(kev) Acq. Start :Man Apr 02 15:19:56 2018

' 3000 3500

tlllI . ROI Type: 2

4000

0296

4/2/2018 3:35:21PM Page 1 of6

~pex-Gamma Analysis Report for 1803110-03

OU-1-008

GAMMA SPECTRUM ANAL YS/S


Sample Description

Sample Type

Sample Size

Facility

Sample Taken On

Acquisition Started

Procedure

Operator

Detector Name

Geometry

Live Time

Real Time

Dead Time








Sample Number

: 1803110-03

: OU-1-008 : RA RECOVERY

: 1.000E+00 units

: Countroom

: 4/2/2018 3:18:44PM

: 4/2/2018 3:20:03PM



: 900.3 seconds

: 0.04 %

: 2.50 : 1 - 4096 : 15 - 4096

: 1.000 keV

: 2/24/2018

: 11/9/2014

: 64154



Peak No.



Energy (keV)

ROI

start ROI end

: 1 : 4096

Peak Centroid

Net Peak Area


Continuum Counts

FWHM (keV)

0297

4/2/2018 3:35:21PM Page 2 of6


M m m M m m

M m m m M m

M m m M m

OU-1-008

Peak Energy ROI

No. (keV) start

1 27.62 24 -2 31.10 24 -3 35.37 24 -4 53.61 4 7 -5 62.18 4 7 -6 66.73 4 7 -7 81. 20 75 -8 113.31 108 -9 180.44 177 -

10 304.30 2 99 -11 334.59 330 -12 356.57 350 -13 365.14 362 -14 374.66 371-15 384.58 371 -16 388.16 371 -17 392.15 371 -18 410.57 408 -19 414.66 408 -20 438.04 431 -21 459.59 455 -22 469.50 465 -23 511. 92 505 -24 588.31 584 -




ROI end

41 41 41 72 72 72 86

118 183 309 336 361 367 395 395 395 395 417 417 442 462 472 516 590

Peak Net Peak Net Area Continuum

Centroid Area Uncertainty Counts

26.68 2.62E+0l 38.16 1.27E+02

30.16 9.38E+02 67. 71 1.16E+02

34.43 2.41E+02 53.55 8.15E+0l

52.68 2. llE+0l 30.00 1.47E+02

61. 26 1.08E+02 36.00 1.36E+02

65.81 3.94E+0l 34.76 1.27E+02

80.30 4.37E+02 56.43 1. 7 9E+02

112.43 1.14E+02 39.12 1.44E+02

179.61 2.04E+0l 19.80 5.72E+0l

303.58 7.24E+0l 23.10 3.12E+0l

333.89 2.06E+0l 16.57 3.47E+0l

355.89 2.24E+02 35.10 4.13E+0l

364.47 9.79E+00 9.11 8.43E+00

374.00 1.00E+0l 7.40 9.86E+00

383.92 6.86E+0l 23.68 1.41E+0l

387.51 5.82E+0l 24.08 1.08E+0l

391.51 1.82E+0l 18.57 9.74E+00

409.93 8.67E+00 8.00 1.20E+0l

414.03 1.61E+0l 13.56 2.40E+0l

437.43 2.90E+0l 14.56 1.20E+0l

459.00 1.00E+0l 6.32 0.00E+00

468.92 1.20E+0l 6.93 0.00E+00

511.38 3.20E+0l 11. 31 0.00E+00

587.83 6.00E+00 4.90 0.00E+00


Peak Analysis Performed on : 4/2/2018 3:35: 17PM

Env. Background File : \\OR-GAMMA 1 \ApexRoot\Countroom\Data\0000063827. CNF

Peak Energy Original Orig. Area Ambient Backgr. Subtracted

No. (keV) Area Uncertainty Background Uncert. Area

1 27.62 2.62E+0l 38.16 2.62E+0l

2 31.10 9.38E+02 67.71 9.38E+02

3 35.37 2.41E+02 53.55 2.41E+02

4 53.61 2.llE+0l 30.00 2.llE+0l

5 62.18 1.08E+02 36.00 1.08E+02

FWHM (keV)

2. 72 2.17 2.49 2.78 2.80 2.81 2.25 2.04 2.65 2.69 2.24 2.02 2.79 2.34 2.84 2.80 2.85 2.60 2.60 1. 87 3.00 4.00 3.27 1. 98

Subtracted Uncert.

3.82E+0l 6.77E+0l 5.36E+0l 3.00E+0l 3.60E+0l

0298

4/2/2018 3:35:21PM Page 3 of6


OU-1-008


No. (keV) Area Uncertainty Background Uncert. Area Uncert.

m 6 66.73 3.94E+0l 34.76 3.94E+0l 3.48E+0l

7 81. 20 4.37E+02 56.43 4.37E+02 5.64E+0l

8 113. 31 1.14E+02 39.12 1.14E+02 3.91E+0l

9 180.44 2.04E+0l 19.80 2.04E+0l 1.98E+0l

10 304.30 7.24E+0l 23.10 7.24E+0l 2.31E+0l

11 334.59 2.06E+0l 16.57 2.06E+0l 1.66E+0l

12 356.57 2.24E+02 35.10 2.24E+02 3.51E+0l

13 365.14 9.79E+00 9 .11 9.79E+00 9.llE+00

M 14 374.66 1.00E+0l 7.40 1.00E+0l 7.40E+00

m 15 384.58 6.86E+0l 23.68 6.86E+0l 2.37E+0l

m 16 388.16 5.82E+0l 24.08 5.82E+0l 2.41E+0l

m 17 392.15 1.82E+0l 18.57 1.82E+0l 1.86E+0l

M 18 410.57 8.67E+00 8.00 8.67E+00 8.00E+00

m 19 414.66 1.61E+0l 13.56 1. 61E+0l 1.36E+0l

20 438.04 2.90E+0l 14.56 2.90E+0l 1.46E+0l

21 459.59 1.00E+0l 6.32 1.00E+0l 6.32E+00

22 469.50 1.20E+0l 6.93 1.20E+0l 6.93E+00

23 511. 92 3.20E+0l 11.31 1.30E+0l 9.71E-01 1.90E+0l 1.14E+0l

24 588.31 6.00E+00 4.90 6.00E+00 4.90E+00






IDENTIFIED NUCLIDES


Name Confidence (keV) (pCi/units) Uncertainty

SN-113 0.91 255.12 1. 93 391.69 * 61,90 2.86E+0l 2.95E+0l

1-125 0.99 35.49 * 6.49 2.16E+02 4.84E+0l

BA-133 0.92 30.80 * 97.60 4.29E+0l 3.20E+00

302.84 17.80 356.01 * 60.00 3.52E+02 7.18E+0l

0299


OU-1-008





Energy Tolerance : 1.000 keV



4/2/2018 3:35:21 PM


? = X = @ =

Nuclide Name

SN-113 I-125 BA-133

Nuclide Id

Confidence

0.914 0.998 0.920



Wt mean Activity

(pCi/units)

2.86E+0l 2.16E+02 4.35E+0l

nuclide contains energy lines not used in Weighted Mean Activity


Wt mean Activity

Uncertainty

2.95E+0l 4.84E+0l 3.20E+00

Page 4 of 6

Comments

0300


M

M

m m

M

m m M

m

OU-1-008





1 27. 62

4 53.61

5 62.18

6 66.73

7 81. 20

8 113.31

9 180.44

10 304.30

11 334.59

13 365.14

14 374.66

15 384.58

16 388.16

18 410.57

19 414.66

20 438.04

21 459.59

22 469.50

23 511.92

24 588.31



F = Fitted singlet


4/2/2018 3:35:21PM

UNIDENTIFIED PEAKS

: 4/2/2018 3:35:17PM

: 1 : 4096

Peak Size (CPS)

2.90804E-02

2.34171E-02

1.19923E-01

4.37535E-02

4.85230E-01

1.26392E-01

2.26644E-02

8.04419E-02

2.29240E-02

1.08730E-02

l. llll 7E-02

7.62156E-02

6.46793E-02

9.63757E-03

1.79225E-02

3.22222E-02

1. lllllE-02

1.33333E-02

2. 11004E-02

6.66667E-03

Peak CPS(%) Uncertainty

72. 90

71.17 16.68 44.13

6.46

17.20

48.53 15.95

40.15

46.55

36.99 17.26

20.69 46.12

42.05 25.10 31.62

28.87 29.90

40.82

NUCLIDE MDA REPORT

Peak Type

Sum Sum

Tol.

Sum


Page 5 of6

Tolerance Nuclide

U-237

0301

4/2/2018 3:35:21PM Page 6 of6


OU-1-008


Name (keV) (pCi/units) (pCilunits) (pCilunits) (pCi/units)

FE-55 5.89 24.50 5.43E-03 5.43E-03 0.00E+00 0.00E+00

CO-57 122.06 85.51 1.70E+0l 1.70E+0l 7.40E-01 7.83E+00

136.48 10.60 1.49E+02 5.13E+0l 6.84E+0l

NI-59 6.92 29.80 7.53E-03 7.53E-03 0.00E+00 0.00E+00

MO-93 16.59 52.90 8.43E-01 8.43E-0l l.03E-02 3.95E-01

18.60 10.00 7.92E+00 l.46E+0l 3.78E+00

NB-93M 16.57 9.43 4. 72E+00 4. 72E+00 5.77E-02 2.21E+00

CD-109 88.03 3. 72 2.80E+02 2.80E+02 -5.68E+0l 1.30E+02

+ SN-113 255.12 1. 93 1.09E+03 6.14E+0l 4.30E+02 4.89E+02

391.69 * 61.90 6.14E+0l 2.86E+0l 2.86E+0l

SN-119M 23.87 16.10 8.51E+00 6.30E+00 5.43E+00 4.05E+00

25.10 22.70 6.30E+00 5.69E-01 2.98E+00

+ I-125 35.49 * 6.49 7.99E+0l 7.99E+0l 2.16E+02 3.87E+0l

I-129 29.78 57.00 1.08E+0l 1.08E+0l 5.61E+0l 5.32E+00

33.60 13. 20 6.0lE+0l 3.11E+02 2.95E+0l

39.58 7.52 4.56E+0l -1.21E+02 2.15E+0l

+ BA-133 30.80 * 97.60 4.12E+00 4.12E+00 4.29E+0l 2.00E+00

302.84 17.80 2.05E+02 2.10E+02 9.58E+0l

356.01 * 60.00 5.15E+0l 3.52E+02 2.36E+0l

CE-139 165.85 80.35 2.41E+0l 2.41E+0l -7.81E+00 1.llE+0l

CE-144 133. 54 10.80 1.40E+02 1.40E+02 4.02E+0l 6.41E+0l

HG-203 279.19 77.30 3.49E+0l 3.49E+0l 1.88E+0l 1.60E+0l

PB-210 46.50 4.25 9.14E+01 9.14E+0l 1.19E+0l 4.25E+0l

PA-231 9.28 42.00 1.32E-02 1.32E-02 0.00E+00 0.00E+00

10 .11 20.20 3.53E-02 0.00E+00 0.00E+00

283.67 1. 60 1.30E+03 -1.32E+02 5.78E+02

302.67 2.30 1.59E+03 1.62E+03 7.42E+02

TH-231 25.64 14.70 1.06E+0l 1.06E+0l -1.59E+00 5.03E+00

84.21 6.40 3.93E+02 l.23E+03 1.91E+02

PA-234M 9.89 89.00 7.52E-03 7.52E-03 0.00E+00 0.00E+00

21. 72 64.90 1.78E+00 1.79E+00 8.48E-01

37.93 23.75 2.22E+0l 4.52E+0l 1.07E+0l

131.42 20.40 7.34E+0l 9.95E+00 3.37E+0l

TH-234 63.29 3.80 2. 91E+02 2.91E+02 3.24E+02 1.39E+02

NP-237 29.37 14.00 4.14E+0l 4.14E+0l 2. 21E+02 2.03E+0l

86.50 12.60 8.12E+0l 1.42E-01 3.77E+0l

U-237 97.08 16.30 6.53E+0l 4.47E+0l -5.13E+0l 3.00E+0l

101.07 26.30 4.47E+0l -1.96E+00 2.07E+0l

114.00 12.30 1.90E+02 3.06E+02 9.06E+0l

208.01 22.00 1.07E+02 2.29E+0l 4.91E+0l

AM-241 59.54 35.90 2.61E+0l 2.61E+0l 2.54E+0l 1.25E+0l

AM-243 74.67 66.00 1.33E+0l 1.33E+0l 7.40E-01 6.21E+00


* = Energy line found in the spectrum



0302

105

104

~ 103 ro u V)

en 0

..-I

V)

+-' s::: ::::s 0 u

102

500 1000

-ROI Type: 1

1500

0000064154.CNF

2000 channel

2500

Live Time :900.000 sec Real Time :900.320 sec Start: 1: 2.0(kev) stop : 4096:4091.G(kev) Acq. start :Mon Apr 02 15:20:03 2018

3000 3500

ROI Type: 2

4000

0303

4/2/2018 3:51 :24PM Page I of6

pex-Gamma Analysis Report for 1803110-04

OU-1-008

GAMMA SPECTRUM ANALYSIS


Sample Description

Sample Type

Sample Size

Facility

Sample Taken On

Acquisition Started

Procedure

Operator Detector Name

Geometry

Live Time

Real Time

Dead Time








Sample Number

: 1803110-04

: OU-1-008

: RA RECOVERY

: 1.000E+00 units

: Countroom

: 4/2/2018 3:18:55PM

: 4/2/2018 3:36: 14PM

: BAFIL

: Administrator

: GE4 : BAFIL

: 900.0 seconds

: 900.3 seconds

: 0.03 %

: 2.50

: 1 - 4096

: 15 - 4096

: 1.000 keV

: 2/24/2018

: 11/9/2014

: 64156



Peak No.



Energy (keV)

ROI

start

ROI end

: 1 : 4096

Peak Centroid

Net Peak Area


Continuum Counts

FWHM (keV)

0304

4/2/2018 3:51:24PM Page 2 of6


M m M m

m M m M m

M m

M m M m

OU-1-008

Peak Energy ROI

No. (keV) start

1 31.06 24 -2 35.34 24 -3 62.60 56 -4 66.61 56 -5 81.33 75 -6 113.10 107 -7 276.02 270 -8 286.93 282 -9 295.01 2 91 -

10 303.38 299 -11 333.28 328 -12 356. 72 350 -13 385.74 378 -14 391.89 378 -15 415.39 411 -16 418.95 411 -17 437.86 433 -18 510.34 507 -19 513.30 507 -20 521. 37 51 7 -21 610.36 605 -22 1069.42 1066 -23 1319.10 1316 -




ROI Peak Net Peak Net Area Continuum

end Centroid Area Uncertainty Counts

39 30.12 8.53E+02 65.37 1.33E+02

39 34.40 2.15E+02 51.55 9.44E+0l

68 61.69 8.39E+0l 37.26 1.49E+02

68 65.70 1.87E+0l 30.00 1.13E+02

85 80.43 2.91E+02 49.37 1.68E+02

118 112. 22 8.40E+0l 36.00 1.20E+02

281 275.28 3.86E+0l 19.90 3.08E+0l

289 286.19 1.llE+0l 13.71 2.38E+0l

298 294.28 l.80E+0l 12. 96 1.60E+0l

308 302.66 4.23E+0l 21.35 4.35E+0l

338 332.59 1.71E+0l 21.97 5.58E+0l

362 356.04 1.76E+02 27.78 1.20E+0l

396 385.09 7.92E+0l 22.93 7.89E+00

396 391.24 1.73E+0l 16.75 1.62E+0l

420 414.76 1.34E+0l 9.62 7.00E+00

420 418.33 7.69E+00 7.52 5.00E+00

441 437.25 2.65E+0l 14.87 1.70E+0l

516 509.80 1.70E+0l 9.43 2.00E+00

516 512.76 1.15E+0l 11.14 5.89E+00

524 520.83 6.25E+00 6.93 3.50E+00

615 609.90 1.35E+0l 11. 51 9.00E+00

1071 1069.42 3.30E+00 5.39 3.40E+00

1322 1319.36 5.36E+00 6.34 3.29E+00


Peak Analysis Performed on : 4/2/2018 3:51: 17PM

Env. Background File : \\OR-GAMMA 1 \ApexRoot\Countroom\Data\0000063827 .CNF

Peak Energy Original Orig. Area Ambient Backgr. Subtracted

No. (keV) Area Uncertainty Background Uncert. Area

1 31.06 8.53E+02 65.37 8.53E+02

2 35.34 2.15E+02 51.55 2.15E+02

3 62.60 8.39E+0l 37.26 8.39E+0l

4 66.61 1.87E+0l 30.00 1.87E+0l

5 81.33 2.91E+02 49.37 2. 91E+02

6 113.10 8.40E+0l 36.00 8.40E+0l

FWHM (keV)

2.20 2.32 3.06 2.22 2.17 2.29 2.56 2.70 2.22 1. 81 1. 86 2.04 3.44 2.85 2.86 2.26 1. 50 3.21 2.65 1.11 2.14 1. 65 3.30

Subtracted Uncert.

6.54E+0l 5.15E+0l 3.73E+0l 3.00E+0l 4.94E+0l 3.60E+0l

0305

4/2/2018 3:51:24PM Page 3 of6


OU-1-008


No. (keV) Area Uncertainty Background Uncert. Area Uncert.

7 276.02 3.86E+0l 19.90 3.86E+0l 1.99E+0l

8 286.93 1.llE+0l 13.71 1.llE+0l 1.37E+0l

9 295.01 1.80E+0l 12. 96 1.80E+0l 1.30E+0l

10 303.38 4.23E+0l 21.35 4.23E+0l 2.14E+0l

11 333.28 1.71E+0l 21.97 1.71E+0l 2.20E+0l

m 12 356.72 1.76E+02 27. 78 1.76E+02 2.78E+0l

M 13 385.74 7.92E+0l 22.93 7.92E+0l 2.29E+0l

m 14 391.89 1.73E+0l 16.75 1.73E+0l 1.67E+0l

M 15 415.39 1.34E+0l 9.62 1.34E+0l 9.62E+00

m 16 418.95 7.69E+00 7.52 7.69E+00 7.52E+00

17 437.86 2.65E+0l 14.87 2.65E+0l 1.49E+0l

M 18 510.34 1.70E+0l 9.43 1.70E+0l 9.43E+00

m 19 513.30 1.15E+0l 11.14 1.15E+0l 1. llE+0l

20 521.37 6.25E+00 6.93 6.25E+00 6.93E+00

21 610.36 1.35E+0l 11. 51 1.29E+00 1.12E+00 1.22E+0l 1.16E+0l

22 1069.42 3.30E+00 5.39 3.30E+00 5.39E+00

23 1319.10 5.36E+00 6.34 5.36E+00 6.34E+00



F = Fitted singlet




IDENTIFIED NUCLIDES


Name Confidence (keV) (pCilunits) Uncertainty

SN-113 0.94 255.12 1.93 391.69 * 61.90 2. 72E+0l 2.66E+01

I-125 0.99 35.49 * 6.49 1.92E+02 4.64E+0l

BA-133 0. 96 30.80 * 97.60 3.89E+0l 3.07E+00

302.84 * 17.80 2.08E+02 1.23E+02

356.01 * 60.00 2.77E+02 5.66E+01

PA-231 0.99 9.28 42.00 10 .11 20.20

283.67 1. 60 302.67 * 2.30 1.61E+03 9.53E+02

TH-234 0.92 63.29 * 3.80 3.64E+02 1.64E+02

0306


OU-1-008





Energy Tolerance: 1.000 keV



4/2/2018 3:51 :24PM


? = X =

Nuclide Name

SN-113 I-125 BA-133 PA-231 TH-234

Nuclide Id

Confidence

0.941 0. 996 0. 962 0.995 0.927



Wt mean Activity

(pCi/units)

2.72E+0l 1.92E+02 3.96E+0l 1.31E+03 3.64E+02



Wt mean Activity

Uncertainty

2.66E+0l 4.64E+0l 3.07E+00 9.53E+02 1.64E+02

Page 4 of6

Comments

0307


m

M

M

m

M

m

OU-1-008





4 66.61

5 81.33

6 113.10

7 276.02

8 286.93

9 295.01

11 333.28

13 385.74

15 415.39

16 418.95

17 437.86

18 510.34

19 513.30

20 521.37

21 610.36

22 1069.42

23 1319.10



F = Fitted singlet


4/2/2018 3:51:24PM

UNIDENTIFIED PEAKS

: 4/2/2018 3:51:17PM

: 1 : 4096

Peak Size (CPS)

2.07732E-02

3.23101E-01

9.33333E-02

4.29012E-02

1.23188E-02

2.00000E-02

1.90247E-02

8. 7 9683E-02

1.48468E-02

8.54903E-03

2.94444E-02

1.89280E-02

1.27578E-02

6.94444E-03

1.35676E-02

3.66667E-03

5.95238E-03

Peak CPS(%) Uncertainty

80.24 8.49

21.43

25.77

61.84

36.00 64.14 14.48

35.99 48.85

28.05 27.69

48.49

55.43 47.36

81.59 59.21

NUCLIDE MDA REPORT

Peak Type

Sum

Tol.

Sum


Page 5 of6

Tolerance Nuclide

U-237

0308

4/2/2018 3:51:24PM Page 6 of6


OU-1-008


Name (keV) (pCilunits) (pCi/unlts) (pCilunits) (pCl/units)

FE-55 5.89 24.50 5.43E-03 5.43E-03 0.00E+00 0.00E+00

CO-57 122.06 85.51 1.61E+0l 1.61E+0l -3.70E-01 7.41E+00

136.48 10.60 1.53E+02 -l.30E+0l 7.07E+0l

NI-59 6.92 29.80 7.53E-03 7.53E-03 0.00E+00 0.00E+00

MO-93 16.59 52.90 8.43E-01 8,43E-01 3.65E-01 3.95E-01

18.60 10.00 7.40E+00 1.05E+0l 3.51E+00

NB-93M 16.57 9.43 4. 72E+00 4. 72E+00 2.04E+00 2.21E+00

CD-109 88.03 3. 72 2.40E+02 2.40E+02 -9.13E+0l 1.10E+02

+ SN-113 255.12 1. 93 9.91E+02 4.20E+0l -4. 13E+02 4.40E+02

391.69 * 61.90 4.20E+0l 2.72E+0l 1.89E+0l

SN-119M 23.87 16.10 7.95E+00 6.05E+00 1.03E+00 3.77E+00

25.10 22.70 6.05E+00 -1.23E+00 2.86E+00

+ I-125 35.49 * 6.49 7.69E+0l 7.69E+0l 1.92E+02 3.73E+0l

I-129 29.78 57.00 1.03E+0l 1.03E+0l 4.79E+0l 5.05E+00

33.60 13. 20 5.69E+0l 2.82E+02 2.79E+0l

39.58 7.52 3.89E+0l -1.51E+00 1.82E+0l

+ BA-133 30.80 * 97.60 3.97E+00 3.97E+00 3.89E+0l 1.92E+00

302.84 * 17.80 1.51E+02 2.08E+02 6.87E+0l

356.01 * 60.00 4.0lE+0l 2.77E+02 1.79E+0l

CE-139 165.85 80.35 2.12E+0l 2.12E+0l -1.14E+0l 9.63E+00

CE-144 133. 54 10.80 1.47E+02 1.47E+02 4.19E+0l 6.78E+0l

HG-203 279.19 77.30 3.45E+0l 3.45E+0l 2.49E+0l 1.58E+0l

PB-210 46.50 4.25 9.14E+0l 9.14E+0l 9.89E+00 4.25E+0l

+ PA-231 9.28 42.00 1.32E-02 1.32E-02 0.00E+00 0.00E+00

10.11 20.20 3.53E-02 0.00E+00 0.00E+00

283.67 1. 60 l.30E+03 2.43E+02 5.78E+02

302.67 * 2.30 l.17E+03 1.61E+03 5.31E+02

TH-231 25.64 14.70 1.09E+0l 1.09E+0l -1.39E+00 5.18E+00

84.21 6.40 3.37E+02 9.23E+02 1.63E+02

PA-234M 9.89 89.00 7.52E-03 7.52E-03 0.00E+00 0.00E+00

21. 72 64.90 1.67E+00 5.67E-01 7.92E-01

37.93 23.75 2.02E+0l 3.81E+0l 9.71E+00

131.42 20.40 7.l0E+0l -1.20E+0l 3.25E+0l

+ TH-234 63.29 * 3.80 3.05E+02 3.05E+02 3.64E+02 1.47E+02

NP-237 29.37 14.00 4.00E+0l 4.00E+0l 2.07E+02 1.96E+0l

86.50 12.60 7.30E+0l 1.34E+0l 3.36E+0l

U-237 97.08 16.30 6.67E+0l 4.56E+0l -4.43E+0l 3.07E+0l

101.07 26.30 4.56E+0l 1.06E+0l 2.llE+0l

114.00 12.30 1.66E+02 2.57E+02 7.89E+0l

208.01 22.00 9.26E+0l 1.29E+00 4.21E+0l

AM-241 59.54 35.90 2.35E+0l 2.35E+0l 2.46E+0l 1.12E+0l

AM-243 74.67 66.00 1.30E+0l 1.30E+0l -1.77E+00 6.07E+00

+ = Nuclide identified during the nuclide identification . = Energy line found in the spectrum



0309

105

104

~ 103 rd u V)

O'l 0 r-

1 V)

+-' C :::I 0 u

102

101

~

~ ~ :r-

'7 ;;'i -~

-i

~·1 ~

100 WI "1'12 • , r,

500 1000

1111 ROI Type: 1

1500

0000064156.CNF

2000 channel

2500

Live Time :900.000 sec Real Ti me : 900. 290 sec Start: 1: 2. 0(kev) Stop : 4096: 4091. 6(kev) Acq. Start :Mon Apr 02 15:36:14 2018

3000 3500

ROI Type: 2

4000

0310

SECTION XIV

ANALYTICAL DATA (GROSS ALPHA/BETA)

0311


Analysis Sheet

Work Order 18-031.10 Analysis Code I GaGbT _ThSr J

Run 1 Date Received 3/23/2018



Project WESTLAKE

Report Level 4

Activity Units pCi

Aliquot Units

Matrix WA


Instrument Type Alpha/Beta GPC

Radiometric Tracer

Radiometric Sol#

Tracer Act (dpm/g)

Carrier


Internal Fraction

01 --

02

03

04

I.

....,__ ____ ,.......

I ,__ !

I I ! l ·, I

i L i I I -

i ' i

I

Sample / Desc I

I

LCS I

MBL

DUP

DO

18-03110 GaGbT_ThSr

Run 1

Client ID

I

I ! Login CPM

LCS i -~+- . -- _____ !

BLANK j

OU-1-008 i 38 7

I i

OU-1-008 i

38

I

' l

-- .

I




Sample Sample Date Aliquot

03/23/18 00:00 1.0000E+00 ·-··-·~-

03/23/18 00:00 1.0000E+00

03/19/18 18:02 2.0000E-01

03/19/18 18:02 2.0000E-01 --

--

·-

I

0312


Analysis Sheet

I Internal Sample l Tracer

Fraction Desc [ Aliquot(g)

01 LCS

02 MBL

03 DUP

04 DO


i I


I

18-03110 GaGbT_ThSr

Run 1

Radiometric I Grav Carrier I Grav Filter

% Rec Added (ml) [ Tare (g)

0.00 7.7518

0.00 7.7368

' 0.00 7.7136

0.00 7.7781


7.7519

7.7369

7.7914

7.8585

* SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. "Indicates estimated SAF value.


I I I Grav Filter Grav

Net(g) %Rec

0.0001

0.0001

0.0778

0.0804


I

I Mean

I

SAF SAF %Rec 1* 2*

1.00 1.00

1.00 1.00

1.00 1.00

1.00 1.00

0313

Eberline Services


Analysis Sheet

Internal [ Sample Fraction Desc

01 LCS

02 MBL

03 DUP

04 DO

I Rough Prep

I Rough Prep

Date By I Prep

I Date

03/27/18 03:01

03/27/18 03:01

03/27/18 03:01

03/27/18 03:01

I I

18-03110 GaGbT_ThSr

Run 1

I I

Prep

l By i

MHIGHTOWER

MHIGHTOWER

MHIGHTOWER

MHIGHTOWER

-·

l

I Sep to

I Date/Time

I

I I

i I

i I

I



I Sep to

I By I

Printed: 3/2712018 4:09 AM Page 3 of 3

Sep t1 Sep t1 Date/Time By

I

I

0314


~ Lab Nuclide

Fraction

01 GROSS ALPHA

i::: 02 GROSS ALPHA

::: ""'" a:: 03 GROSS ALPHA

1--04 GROSS ALPHA

.c ~ C) ~ Ill ca i::: q; C)

II) s::: 0 II)

·c:; a, C ca -ii s::: a, E s::: 0 ... ·s: s::: w 0 :E <(

I Sample Oesc

LCS

MBL

DUP

DO


Work Order: 18-03110-GaGbT-1

Client Activity Results Error Estimate I MOA


LCS pCi/1 3.10E+02 3.98E+00 2.54E-01

BLANK pCi/1 3.97E-02 1.35E-01 3.01E-01

OU-1-008 pCi/1 2.S0E+00 1.94E+00 3.35E+00

OU-1-008 pCi/1 4.25E+00 1.96E+00 2.55E+00

LCS

I LCS

Known %R

2.68E+02 115.57


LCS

I RPO MOA Blank

Flag Flag Flag Flag

OK OK

OK OK

NA OK

OK

0315


~ Lab

Nuclide Fraction

01 GROSS ALPHA

§ a::

~ 8 ,!!? ~ cii C: <:t

~I

~

1-.c C) ca

C)

(/) C

.2

.!!? (.J Cl)

C ca -C Q)

E C 0 a..

"> C w 0 :!: <(

02 GROSS ALPHA

03 GROSS ALPHA

04 GROSS ALPHA

I Sample Desc

LCS

MBL

DUP

DO


Work Order: 18-0311 0-GaGbT-1

Sample Sample I Radiometric

I Grav Mean


03/23/18 00:00 1.00E+00 0.00 0.00 0.00

03/23/18 00:00 1.00E+00 0.00 0.00 0.00

03/19/18 18:02 2.00E-01 0.00 0.00 0.00

03/19/18 18:02 2.00E-01 0.00 0.00 0.00

SAF

1.00

1.00

2.62

2.68

SeptO


Sept1

DatefTime DatefTime

0316


( Lab Nuclide

Fraction

01 GROSS ALPHA

c:: ::,

0::

.g 0 0 -!!! ~ Ill c::

Cl;

j 0

~

I-..a (!) ns

(!)

1/j C: 0

.!!? CJ Q)

C

s C: Q)

E C: 0 ... ·s: C: w 0 :ii: <(

02 GROSS ALPHA

03 GROSS ALPHA

04 GROSS ALPHA

I Sample Desc

LCS

MBL

DUP

DO



Halflife

I I Bkg

Counting Detect CalTier Count

Counts DatefTime (days) Time CPM

03/27/18 07:02 LB4110A B1 120 2330510.066666667

03/27/18 07:02 LB4110A B2 120 15 0.1

03/27/18 07:02 LB4110A B3 120 24 0.066666667

03/27/18 07:02 LB4110A B4 120 28 0.033333333

I

I


Eff

0.2821

0.2835

0.2804

0.2843

0317



01 GROSS BETA

§ II::

.g 8 -~ ~ qj c:: "(

--~ 0

~

1-.c (!) «s

(!)

(/) C .2 .!!? (.) Q)

C

s C Q)

E C e

·s;: C w 0 :iii: <(

02 GROSS BETA

03 GROSS BETA

04 GROSS BETA

Sample Desc

LCS

MBL

DUP

DO



I

Client Activity Results Error Estimate I MDA


LCS pCi/1 2.82E+02 3.15E+00 6.12E-01

BLANK pCi/I -2.37E-01 2.57E-01 5.78E-01

OU-1-008 pCi/I 1.95E+01 2.46E+00 3.43E+00

OU-1-008 pCi/I 1.69E+01 2.31E+00 3.30E+00

I LCS LCS Known %R i

2.77E+02 101.91


I I LCS RPD MDA Blank

Flag Flag Flag Flag

OK OK

OK OK

OK OK

OK

0318


( Lab Nuclide

Fraction

01 GROSS BETA

i::: 02 GROSS BETA

::s T"'" 0:: 03 GROSS BETA

Cl> I-"0

8 .c 04 GROSS BETA

,!2 C) ~ 111 ca i::: C) "'(

II) C .2 .!!! 0 Cl)

C

.l!! jl C Cl)

0 E C 0 ... "> C w 0 :!?: <(

Sample Desc

LCS

MBL

DUP

DO


Work Order: 18-03110-GaGbT-1

Sample Sample Radiometric Grav

I Mean


03/23/18 00:00 1.00E+00 0.00 0.00 0.00

03/23/18 00:00 1.00E+00 0.00 0.00 0.00

03/19/18 18:02 2.00E-01 0.00 0.00 0.00

03/19/18 18:02 2.00E-01 0.00 0.00 0.00

SAF

1.00

1.00

1.17

1.18

SeptO


Sept1 I Date/Time I

Date/Time

0319


~ Lab I Nuclide

Fraction

01 GROSS BETA

C: ::s a:

.g 8 ,!!? ~ ai C: ct

~I

""""'

1-.c (!)

CG (!)

,,, C: 0

-~ c., Q)

C ni -C: Q)

E C: 0 ... ·s; C: w 0 :iii: <(

02 GROSS BETA

03 GROSS BETA

04 GROSS BETA

Sample Desc

LCS

MBL

DUP

DO



Counting Halflife Detect Carrier

I Count

Counts DatefTime (days) Time

03/27/18 07:02 LB4110A B1 120 42352

03/27/18 07:02 LB4110A B2 120 131

03/27/18 07:02 LB4110A B3 120 568

03/27/18 07:02 LB4110A B4 120 519

Bkg CPM

1.466666667

1.35

1.266666667

1.233333333


Eff Ato B, Cor

0.4817 302.8858458

0.4903 1.091666667

0.4703 4. 733333333

0.484 4.325

0320


18-03110-GaGbT_ThSr-1 (pCi/1) in WA Tracer ID:


Internal Sample Client Sample i Sample Tracer Tracer I

Radiometric I Radiometric

11 SAF

11 SAF

Fraction Desc ID Date Aliquot Aliquot {g) ACT (dpm) Tracer (pCi) % Rec 1* 2• I I

01 LCS LCS 03/23/18 00:00 1.0000 l 0.00 1.00 1.00

02 MBL BLANK 03/23/18 00:00 1.0000 0.00 1.00 1.00

03 DUP OU-1-008 03/19/1818:02 0.2000 0.00 1.00 1.00 I

04 DO OU-1-008 03/19/18 18:02 0.2000 I 0.00 1.00 1.00

I I

! !

--- i i

0321


LCS & Matrix Spikes

I Sol# Actwity I Solution

Isotope dpmlg ! Date

Am-241 NB-07 I

593.680! 3/27/2018

SrY-90 NB-07 612.180 3/27/2018 -

I IC-::J::J 1v1v IC-La .:.,u.,_,.4'! _,, //LU I I

Tracers

fraction Isotope I Sol# I Activity dpmlg

i i I

I i I I I

I

Version 2.0 08/99

\ Approx 1 Addff.ion

0.800

0.900

U. I

Solution Date



GaGbT ThSr 3/27/2018 3:00 MHIGHTOWER


Volume Volume Volume Volume Known I Error Added i Error

Used (g) Used (g) Used(g) Used(g) pCi [ Estimate pCi I Estimate

1.0030 268.231 11.534 O.OOi 0.000

1.0030 276.58! 8.298 0.00 0.000

I i


Volume Approx Tracer Used (g) Addition



Jltlf, LCSD MSD

Known Error Added i Error

pCi Estimate pCi I Estimate

0 00 0.000 I 0.00! 0.000

0.00 0.000 o.ooi 0.000 I

i I

LCS

Matrix Spike

0322

Lab



GaGbT_ThSr

Sample Muffle Data

Fraction Ratio

Client ID Type Post/Pre

01 LCS LCS 02 BLANK MBL 03 OU-1-008 DUP

04 OU-1-008 DO

--·---

-------

--------------

··-··----··

------------~--- ---

-----

Comments

/-----i ;/ ,., !'\'</ j// - ;J -- ~.

Technician: ~ {,,U.-,/'vl!l--,,0,

J

Aliquot Worksheet

liters 4/12/2018


No of Dils I Dil Factor ! Ratio Aliquot Net Equiv

! 1.0000E+00 1.0000E+00 . ---··----··---··-·--·--

1----·-----------· I 1.0000E+00 1.0000E+00

2.0000E-01 2.0000E-01

2.0000E-01 2.0000E-01

--- --- -- --------

---···-------

i

i -----·-------

---+. --r -·-·· -1- ···-··· -- - ---·-- --

-------

----·--------

__ ,, _______ ----------

Date: '2:) / ~ / ~

Printed: 3/26/201811:47 AM Page 1 of 1

JPACHELLA

MS Aliquot Data H-3 Solids Only Water Added H3 Dist


·-------·-·--··-----

------·-··--·-~-

-.--~----

-- . -·--------·--··-·-· -

---~--l

0323

Eberline Services - Oak Ridge Version 1.09/1999 Gravimetric Worksheet

Work Order

18-03110 ~ Analysis

Code

GaGbT_ThSr

Gravimetric

Carrier

TRetec AMO Environmental Decisions Sample Carrier Data Filter Data

Carrier Added Filter Tare Filter Final

Fraction Client ID Type (ml) (g) (g)

01 LCS LCS 7.7518 7.7519

02 BLANK MBL 7.7368 7.7369

03 DUP DUP 7.7136 7.7914

04 OU-1-008 DO 7.7781 7.8585

Technician: h:n Date: J_;l 1 1_!1

Carrier Cone {mg/m!)

Filter Net (g)

0.0001 0.0001 0.0778 0.0804


Technician

MHIGHTOWER

Gravimetric %

Recovery

0324


TRetec AMO Environmental Decisions

Fraction Client ID

04 OU-1-008

-----

' .. -'1 ,, f-L..J-o l /l ;J

Technician: ~ t).J-fve,/(_J__L,e____ I

I >" V

TDS / TSS Worksheet

Cede

GaGbT ThSr

Filter Data Aliquot Filter Tare Filter Final

I Filter Net

ml (g) (g) (g)


JPACHELLA

TDS/TSS Maximum Aliq

(mg/L) (ml)

100.0000 7.7727 7.7728 +--- -__ 0.0001_

1.0000 100000.00 ---- ---- - - ···- - --···-·-- ------ -···--- - -------. -

- -··- _______ ,, _________________

-------· -------------- ---·---- ---·--·---------------·- ______ ,. ______ . __ --- . --"··· - - --·--·--

·-·--------·--·- --- ---- ----------·-

-·---- ---- -- - -------------··- ----------------- -------·----------

----· ------- ----

---- - --------- ----- . .. ·--- "--- -·- -------- ----

------- ----·-- --------

_I ______ ·---~------ --- -----------

------------- ------------·-------·--- ------~-----------·-·--

-··-··-· - --- ------ ---------·-··--·- ---- --~~ --··-- - -~

--··~-·· ---·-·------- .~

i ---~-·----

Date: 0 I ~l_jj_

0325

Detector ID Sample ID Alpha Beta Count Time Voltage TOD K? B1 1803110-01 23305 42352 120 1410 3/27/2018 7:02:03 AM

B2 1803110-02 15 131 120 1410 3/27/2018 7:02:03 AM ·5 ;-zt-/! t:) B3 1803110-03 24 568 120 1410 3/27/2018 7:02:04 AM

B4 1803110-04 28 519 120 1410 3/27/2018 7:02:04 AM

0326

Eberline Analytica Oak Ridge Laboracory

[ Detector

LB4110A - Al

LB4110A - A2

LB4110A - A3

LB4110A - A4

LB4110A - Bl

LB4110A - B2

LB4110A - B3

LB4110A - B4

LB4110A - Cl

LB4110A - C2

LB4110A - C3

LB4110A - C4

LB4110A - D1

LB4110A - D2

LB4110A - D3

LB4110A - D4

LB4110A - El

LB4110A - E2

LB4110A - E3

LB4110A - E4

I_B4110A - Fl

LB4110A - F2

LB4110A - F3

LB4110A - F4

LB4110A - Gl

LB4110A - G2

LB4110A - G3

L.B4110A - G4

Alpha/Beta Calibration Date

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015

Alpha 10/20/2015


Count Date Bkg CPM

3/27/2018 1.00E-01

3/27/2018 5.00E-02

3/27/2018 6.67E-02

3/27/2018 1.33E-01

3/27/2018 6.67E-02,

3/27/2018 1.00E-01

3/27/2018 6.67E-02'

3/27/2018 3.33E-02,

3/27/2018 1.17E-01

3/27/2018 5.00E-02

3/27/2018 5.00E-02

3/27/2018 1.17E-01

3/27/2018 1.00E-01

3/27/2018 1.67E-01

3/27/2018 1.17E-01

3/27/2018 1.33E-01

3/23/2018 0.00E+00

3/23/2018 0.00E+00

3/23/2018 0.00E+00

3/23/2018 0.00E+00

1/13/2017 1.67E-02

1/13/2017 3.33E-02

1/13/2017 3.33E-02

1/13/2017 6.67E-02

3/27/2018 1.67E-02

3/27/2018 1.00E-01

I

3/27/2018 1.00E-01 j 3/27/2018 1.67E-02

PFW LCL

p -5.87E-02

p -5.59E-02

p -4.69E-02

p -4.78E-02

p , -5.02E-02

p -3.05E-02

p -6.53E-02

p -5.37E-02

p -7.06E-02

p -6.00E-02

p -7.35E-02

p -5.51E-02

p -4.22E-02

p -3.58E-02

p -5.50E-02

p -2.92E-02

p -3.12E+0l

p -3.93E-02

p -6.26E-02

p -3.22E+0l

p -7.24E-02

p -1.97E-01

p -8.54E-02

p -5.55E-02

p -5.76E-02

p -5.47E-02

p -5.33E-02

p -3.00E-02

Mean

9.77E-02

8.94E-02

1.05E-01

9.16E-02

1.06E-01

1.18E-01

9.26E-02

8.44E-02

9.56E-02

7.03E-02

9.34E-02

8.30E-02

1.54E-01

1.38E-01

1.14E-01

1.43E-01

6.llE-01

6.40E-02

1.18E-01

5.72E-01

9.77E-02

7.60E-02

1.27E-01

8.28E-02

8.59E-02

7.74E-02

1.19E-01

8.94E-02

Printed:

KP 3/27/2018 6:54 AM)!Zt-/18

Page 1 of 1

UCL

2.54E-01

2.35E-01

2.57E-01 I 2.31E-01 I 2.63E-01

2.67E-01

2.50E-01

2.23E-01

2.62E-01

2.0lE-01 I 2.60E-01

2.21E-01

3.50E-01

3.13E-01

2.84E-01

3.16E-01

3.24E+0l

1.67E-01

2.99E-01

3.34E+0l

2.68E-01

3.49E-01

3.40E-01

2.21E-01

2.29E-01

2.l0E-01

2.91E-01

2.09E-01

0327


lF h Detector

LB4110A - Al

LB4110A - A2

LB4110A - A3

LB4110A - A4

LB4110A - Bl

LB4110A - B2

LB4110A - B3

LB4110A - B4

LB4110A - Cl

LB4110A - C2

LB4110A - C3

LB4110A - C4

LB4110A - D1

LB4110A - D2

LB4110A - D3

LB4110A - D4

_B4110A - El

i_B4110A - E2

_B4110A - E3

_B4110A - E4

_B4110A - Fl

_B4110A - F2

_B4110A - F3

_B4110A - F4

LB4110A - Gl

LB4110A - G2

LB4110A - G3

I_B4110A - G4 -

Alpha/Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Calibration Date

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015


Count Date Bkg CPM

3/27/2018 1.48E+OO

3/27/2018 1.42E+OO

3/27/2018 1.28E+OO

3/27/2018 1.55E+OO

3/27/2018 1.47E+OO•

3/27/2018 1.35E+OO'

3/27/2018 1.27E+OO

3/27/2018 1.23E+OO ·

3/27/2018 1.18E+OO

3/27/2018 1.20E+OO

3/27/2018 2.12E+OO

3/27/2018 1.lOE+OO

3/27/2018 l.33E+OO

3/27/2018 1.47E+OO

3/27/2018 l.07E+OO

3/27/2018 1.45E+OO

3/23/2018 3.33E-02

3/23/2018 1.67E-02

3/23/2018 6.67E-02

3/23/2018 O.OOE+OO

1/13/2017 5.50E-01

1/13/2017 3.42E+OO

1/13/2017 8.52E+OO

1/13/2017 6.57E+OO

3/27/2018 1.35E+OO

3/27/2018 1.75E+OO

3/27/2018 1.43E+OO

3/27/2018 1.25E+OO

I PFW I LCL

p 8.58E-01

p I 9.14E-01

p I 1.04E+OO

p 2.37E-02

p 1.05E+OO

p 7.79E-01

p 9.46E-01

p 8.18E-01

p 8.76E-01

p 2.32E-01

F 9.13E-01

p 8.02E-01

p -2.15E+OO

p -l.31E+OO

p -9.89E-01

p -1.44E+OO

p -4.88E+Ol

p 5.69E-01

p 6.34E-01

p -5.22E+Ol

p 6.30E-01

F -4.00E+02

F -4.94E+OO

f -4.32E+OO

p 8.24E-01

p 1.14E+00

p 8.60E-01

p 7.12E-01

Mean

1.44E+OO

1.50E+OO

1.58E+OO

1.54E+OO

1.61E+OO

1.54E+OO

1.45E+OO

1.44E+OO

1.34E+OO

1.19E+OO

1.75E+OO

l.27E+OO

2.04E+OO

2.12E+OO

1.76E+OO

2.17E+OO

2.19E+OO

9.46E-01

1.19E+OO

1.87E+OO

1.44E+OO

2.09E+Ol

2.12E+OO

l.79E+OO

l.29E+OO

1.65E+OO

1.42E+OO

1.36E+OO

{\y Printed: 3/27/2018 6:54 AM '5/ZM8

Page 1 of 1

UCL

2.03E+OO

2.08E+OO

2.12E+OO

3.05E+OO

2.17E+OO

2.30E+OO

1.96E+OO

2.07E+00

1.81E+OO

2.15E+OO

2.59E+OO

1.74E+OO

6.23E+OO

5.54E+OO

4.51E+OO

5.78E+OO

5.32E+Ol

l.32E+OO

1.75E+OO

5.59E+Ol

2.25E+OO

4.42E+02

9.17E+OO

7.90E+OO

1.75E+OO

2.17E+OO

1.98E+OO

2.02E+OO

0328

Eberline Analytical Oak Ridge Labo-atory

I Dete:tor

LB4110A - Al

LB4110A - A2

LB4110A - A3

LB4110A - A4

LB4110A - Bl

LB4110A - B2

LB4110A - B3

LB4110A - B4

LB4110A - Cl

LB4110A - C2

LB4110A - C3

LB4110A - C4

LB4110A - D1

LB4110.A - D2

LB4110.A - D3

LB4110A - D4

LB4110A - El

LB4110A - E2

LB4110A - E3

LB4110.A - E4

LB4110A - Fl

LB4110A - F2

LB4110A - F3

LB4110A - F4

LB4110A - Gl

LB4110/\ - G2

LB4110J\ - G3

LB4110A - G4

Alpha/Beta

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Calibration Date I 10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015


Count Date Eff

3/27/2018 0.2265

3/27/2018 0.2101

3/27/2018 0.1984

3/27/2018 0.2248

3/27/2018 0.2260

3/27/2018 0.2019

3/27/2018 0.2361

3/27/2018 0.2204

3/27/2018 0.2067

3/27/2018 0.2201

3/27/2018 0.2398

3/27/2018 0.2126

3/27/2018 0.2200

3/27/2018 0.2534

3/27/2018 0.2549

3/27/2018 0.1958

3/23/2018 0.0000

3/23/2018 0.0000

3/23/2018 0.0000

3/23/2018 0.0000

1/13/2017 0.0095

1/13/2017 0.0912

1/13/2017 0.1614

1/13/2017 0.1342

3/27/2018 0.1984

3/27/2018 0.1992

3/27/2018 0.2227

3/27/2018 0.1953

Printed: 3/27/2018 6:55 AM f'(_ p Page 1 of ½ {-z,':f-/(8

I PFW LCL Mean UCL I I

p I 0.2190 0.2300 0.2410 I , i p I 0.2030 0.2119 0.2207 I I p I 0.1909 0.2008 0.2106 i

I I p I 0.2194 0.2295 0.2395

p 0.2011 0.2213 0.2415

p 0.1830 0.2043 0.2255

p 0.2216 0.2363 0.2509

p 0.2134 0.2249 0.2363

p 0.2009 0.2106 0.2204

p 0.0275 0.2231 0.4187

p 0.2342 0.2458 0.2573

p 0.2068 0.2189 0.2310

p 0.2102 0.2232 0.2361

p 0.2355 0.2520 0.2686

p 0.2398 0.2522 0.2646

p 0.1848 0.1955 0.2063

F 0.1959 0.2303 0.2648

F 0.1833 0.2089 0.2345

F 0.1855 0.2092 0.2330

F 0.2024 0.2394 0.2765

F 0.0488 0.1829 0.3169

F 0.0992 0.1799 0.2605

F 0.1667 0.2332 0.2997

f 0.1462 0.2100 0.2738

p 0.1919 0.2032 0.2145

p 0.1943 0.2057 0.2171

p 0.2171 0.2275 0.2379

p 0.1918 0.2017 0.2116

0329


Detector

LB411CA - Al

LB411CA - A2

LB411CA - A3

LB411CA - A4

LB411CA - Bl

LB411CA - B2

LB411CA - B3

LB411CA - B4

LB4110A - Cl

LB4110A - C2

LB4110A - C3

LB4110A - C4

LB4110A - D1

LB4110A - D2

LB4110A - D3

LB4110A - D4

LB4110A - El

LB4110A - E2

LB4110A - E3

• LB4110A - E4

LB4110A - Fl

LB4110A - F2

LB4110A - F3

LB4110A - F4

LB4110A - Gl

LB4110!.\ - G2

LB411OA - G3

LB4110A - G4

Alpha/Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Calibration Date

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015

10/20/2015


Count Date Eff

3/27/2018 0.5375

3/27/2018 0.4598

3/27/2018 0.4786

3/27/2018 0.5399

3/27/2018 0.5565

3/27/2018 0.5041

3/27/2018 0.5869

3/27/2018 0.5628

3/27/2018 0.4773

3/27/2018 0.5129

3/27/2018 0.6067

3/27/2018 0.5266

3/27/2018 0.6394

3/27/2018 0.6510

3/27/2018 0.6411

3/27/2018 0.5035

3/23/2018 0.0436

3/23/2018 0.0428

3/23/2018 0.0551

3/23/2018 0.0569

1/13/2017 0.2843

1/13/2017 0.2896

1/13/2017 0.5003

1/13/2017 0.4054

3/27/2018 0.4575

3/27/2018 0.4874

3/27/2018 0.5436

3/27/2018 0.4954

Printed: 3/27/2018 6:55 AM t(p Page 1 of1/2,t-/f@

PFW LCL Mean UCL

p i 0.5198 0.5428 0.5658

p 0.4456 0.4705 0.4955

p 0.4581 0.4782 0.4983

p 0.5311 0.5511 0.5712

p i 0.5052 0.5379 0.5705

p 0.4712 0.5049 0.5386

p 0.5560 0.5848 0.6136

p 0.5274 0.5520 0.5767

p 0.4647 0.4906 0.5166

p 0.5045 0.5275 0.5504

p 0.5821 0.6111 0.6400

p I 0.5063 0.5364 0.5664

p 0.6277 0.6527 0.6776

p 0.6169 0.6491 0.6812

p 0.6157 0.6407 0.6658

p 0.4640 0.5008 0.5377

F 0.4730 0.5519 0.6307

F 0.4450 0.5020 0.5591

F 0.4552 0.5070 0.5589

F 0.5130 0.5987 0.6844

F 0.2965 0.4651 0.6337

F 0.2942 0.4385 0.5828

w 0.4726 0.5889 0.7052

F 0.4095 0.5204 0.6312

p 0.4455 0.4650 0.4846

p 0.4732 0.4976 0.5219

p 0.5292 0.5539 0.5786

p 0.4706 0.4960 0.5214

Documents

AMO ENVIRONMENTAL DECISIONS AUXIER & ASSOCIATES, …0001 amo environmental decisions auxier & associates, inc. west lake landfill stormwater st and ard level iv report of analysis