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EFFICIENT AIR CONDITIONING SYSTEM
FOR AUTOMOBILE BY RECYCLING OF
ENGINE WASTE HEAT
A THESIS SUBMITTED IN PARTIAL FULFILLMENT OF THE
REQUIREMENTS FOR THE DEGREE OF
M-Tech
In
Heat Power Ther!a" En##$
SAN%EEB &UMAR SHAW
REGD$ NO$ ' 1407225016
Under the guidance o
Pro($ SASHI&ANTA NAYA&
De!art"ent o Mechanica# Engineering
Ba#a$ore %o##ege o Engineering & Techno#og'Sergarh(Ba#a$ore)*+,-,-
.-/,
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Ba#a$ore %o##ege o Engineering & Techno#og'Sergarh,Balasore-756060
CERTIFICATE
This is to certify that the thesis entitled “ EFFICIENT AIR
CONDITIONING SYSTEM FOR AUTOMOBILE BY RECYCLING
OF ENGINE WASTE HEAT ” Submitted by Mr. SANJEEB
KUMAR SHAW in partial fulllment of the re!uirements for the
a"ard of M-Tech in Heat Power and Ter!a" En#$neer$n# at
the Ba"a%ore Co""e#e o& En#$neer$n# ' Te(no"o#) *
Ba"a%ore #$nder B%$T, &our'ela( is an authentic "or' carried
out by him under my super)ision and guidance. To the best of
my 'no"ledge, the matter embodied in the thesis has not been
submitted to any other $ni)ersity * +nstitute for the a"ard of
any egree or iploma.
Date0
External Examiner Prof. S.K.Nayak
Dept. of Mech.En.
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!"i#e
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A(+now"ed#e!e
nt
+ epress my deep sense of gratitude and indebtedness to my thesis
super)isor %rof S../aya', epartment of Mechanical ngineering for
pro)iding precious guidance, inspiring discussions and constant
super)ision throughout the course of this "or'. 1is timely help,
constructi)e criticism, and conscientious e2orts made it possible to
present the "or' contained in this thesis.
+ epress my sincere than's to %rof.%.3.Singh 3ice %rincipal B4T,
Balasore for pro)iding me the necessary facilities in the department. +
epress my sincere gratitude to %rof. %..Mohanty 4oordinator of M-Tech
course for his timely help during the course of "or'. + am also than'ful to
all the sta2 members of the department of Mechanical ngineering and to
all my "ell "ishers for their inspiration and help.
+ feel pleased and pri)ileged to fulll my parents ambition and +
am greatly indebted to them for bearing the incon)enience during my
M-Tech. course.
Date) SAN$EE%K&MARS'A(
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Re#.. No. )1407225016
ABSTRA%T
An auto"o1i#e air conditioning $'$te" genera##' 2or3$ on 4a!or co"!re$$ion c'c#e
co"!ri$ing o co"!re$$or( conden$er( e5!an$ion de4ice and e4a!orator6 The o17ecti4e o
!ro7ect i$ to u$e 4a!or a1$or!tion $'$te" in$tead o 4a!or co"!re$$ion $'$te" ha4ing 2ater
a$ the rerigerant and #ithiu" 1ro"ide a$ a1$or1ent6 The air conditioning $'$te" co"!re$$e$o a generator( a $egregator( a conden$er( an e4a!orator( an a1$or1er( a heat e5changer and a
!#ura#it' o conduct$ interco""unicated thereto 1et2een to or" a circu#ated coo#ed air
!roduction $'$te"6 The i"!ro4e"ent i$ characteri8ed in uti#i8ing the re$idua# heat ro" the
e5hau$t !i!e o an engine o an engine 1' he#ica##' 2inding a coi# tu1e around the "ain
!ortion o the e5hau$t !i!e $o that the #i9uidi8ed rerigerant 2ater :H.-; ro" the generator
2i## #o2 through and 1e heated into a "i5ture o the 4a!or and #ithiu" 1ro"ide and enter
into the $egregator or a !roce$$ o $e!aration6 Then( the 4a!or enter$ into the conden$er 4ia a
ca!i##ar' tu1e and ro" there enter$ into the e4a!orator or a !roce$$ o 4a!ori8ation6 %oo#ed
air i$ thereore !roduced and 4ented into the interior o the auto"o1i#e6 The 4a!or ro" thee4a!orator 2i## then go to the a1$or1er and re)enter the generator ater it i$ "i5ed 2ith
#ithiu" 1ro"ide 2hich i$ returned ro" the $egregator ater 1eing !roce$$ed there to6
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%ONTENTS
%ERTIFI%ATE i
A%=NOIE< /
CHAPTER + INTRODU%TION +
.6/ rerigeration "ethod$ +
.6/6/ natura# "ethod$ +
.6/6/6/ ice "a3ing 1' nocturna# coo#ing +
.6/6/6. e4a!orati4e coo#ing ,
.6/6. aeriicia# "ethod$ ,
.6. air conditioning $'$te"$ ,
.6? 4a!or co"!re$$ion $'$te" *
.6@ 4a!or a1$or!tion $'$te"
.6+ ad4antage$ ar$ o4er 4cr /-
.6, !ractica# !ro1#e"$ in #i1r $'$te" //
.6* cr'$ta##i$ation //
.6 ca!acit' contro# /.
8
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.6 co""ercia# $'$te"$ /.
9
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CHAPTER , STUDC OF AUTMOBILE AIR %ONDITIONING /+
?6/ de$cri!tion o a1$or!tion #a'out /,
?6. 2a$te heat reco4er' generator
A#ternati4e$ /
CHAPTER THERMODCNAMI% ANALCSIS OF ABSORPTION SCSTEM //
@6/ ir$t #a2 ana#'$i$ .@
@6. ther"od'na"ic !ro!ertie$ .@
@6? !eror"ance ca#cu#ation$ .+
@6@ "ode# ca#cu#atio$ .
@6+ con4entiona# ca#cu#ation ?
CHAPTER . RESULTS AND DIS%USSIONS ?*
CHAPTER / FABRI%ATION OF ABSORPTION AIR %ONDITIONING
SCSTEM @/
,6/ A1$or1er @.
,6. Generator @?
,6?
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LIST OF FIGURES
FIGURE NO$ DESCRIPTION PAGE NO$
.6/ >a!or co"!re$$ion $'$te"
.6. >a!or a1$or!tion $'$te"
.6? T2in dru" t'!e #i1r $'$te" /?
?6/ %o"!onent$ o air coo#ed a1$or!tion
$'$te" or tran$!ort /*
?6. Generator $'$te" 2ith additiona# 1urner /
?6? Direct reco4er' generator $'$te" /
?6@ Generator 2ith air a$ inter"ediate #uid .-
?6+ Generator 2ith inter"ediate #uid) c#o$ed .-
@6/ La'out o a1$or!tion $'$te" .?
@6. F#o2 diagra" o #i1r a1$or!tion $'$te" .,
@6? Sche"atic re!re$entation o 4a!or a1$or!tion
2ith regenerator HE ?.
@6@ Re!re$entation o a1$or!tion c'c#e on !)/T diagra" ??
+6/ Heat tran$er in each co"!onent ?
+6. >ariation o %OP at dierent generator te"!erature$ ?
+6? >ariation o %OP at dierent conde$er te"!erature$ @-
+6@ >ariation o %OP at dierent e4a!orator te"!erature$ @-
,6/ Modiied #a'out o a1$or!tion $'$te" @/
,6. A1$or1er @.
,6? Generator @?
,6@
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LIST OF TABLES
TABLE NO$ DESCRIPTION PAGE
NO$
@6/ %o"!ari$ion 1et2een con4entiona# and ca#cu#ated re$u#t$ ?,
+6/ Ther"od'na"ic !ro!ertie$ o each !oint ?*
+6. Heat tran$er rate o co"!onent$ and !eror"ance !ara"eter$ ?
7
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%HAPTER/
LITERATURE SUR1EY
Se4era# e"inent !eo!#e ha4e !eror"ed re$earch $tudie$ on
energ' eicient $ource or coo#ing and rerigeration6 M6G6 Ra$u# and
A6 Mur!h' / ha4e e4a#uated the ea$i1i#it' o an a1$or!tion
rerigeration unit on $o#ar !o2er6 A !rotot'!e "ode# that i$ ca!a1#e o
!roducing a te"!erature change in the e4a!orator 2a$ de$igned(
a1ricated and te$ted6 The !eror"ance$ and eecti4ene$$ o the unit2a$ $tudied 1' deter"ining rerigeration eect :RE;( coeicient o
!eror"ance :%OP; and e5!#aining o!erationa# i$$ue$ o the unit6
ohnn' L6 =ir1' . $tudied the 2or3ing o a1$or!tionad$or!tion air
conditioning rerigeration $'$te"6 He ound that rec#ai"ing the 2a$te
energ' i$ a great co$t)eecti4e ad4antage o the ad$or!tion
a1$or!tion $'$te"( o4er a con4entiona# air)conditioning $'$te"6 And
ini$hed 1' #oo3ing at 4ariou$ "ethod$ o !o2ering $'$te"$ 2ith
"ini"a# or 1etter 'et no( grid !o2er a$$i$tance6 Dr6 Eng6 %hiara
Bocca#etti ? ai"ed at indi4iduating the "ain heat tran$er and
ther"od'na"ic !heno"ena( at the 1a$i$ o o!eration o rerigerating
"achine$6 He !articu#ar#' ana#'8ed A1$or!tion "achine$ and
$ugge$ted de$ign "odiication$ and ada!tation$i"!ro4e"ent$ o
$che"e$ !re$ent#' u$ed6 The ina# o17ecti4e o hi$ $tud' 2a$ to attain
de$ign o "achine$ characteri8ed 1' higher !eror"ance( #o2er
$!eciic energ' con$u"!tion and higher re#ia1i#it'6
:
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>6 Mitta#( =6 S6 =a$ana( N6 S6Tha3ur @ $tudied a detai#ed
re4ie2 on the !a$t eort$ in the ie#d o $o#ar a1$or!tion coo#ing
$'$te"$ 2ith the a1$or!tion !air o #ithiu")1ro"ide and 2ater6 The'
ha4e in4e$tigated the in#uence o 3e' !ara"eter$ on the o4era##
$'$te" !eror"ance6 The' a#$o !eror"ed the "ode#ing and
$i"u#ation o a $o#ar a1$or!tion coo#ing $'$te" o a $o#ar)!o2ered(
$ing#e $tage( a1$or!tion coo#ing $'$te"( u$ing a #at !#ate co##ector
and 2ater#ithiu" 1ro"ide $o#ution6 The' de4e#o!ed a co"!uter
!rogra" or the a1$or!tion $'$te" to $i"u#ate 4ariou$ c'c#e
coniguration$ 2ith the he#! o 4ariou$ 2eather data or the 4i##age
Baha#( Di$trict Bhi2ani( Har'ana( India6 The' ha4e a#$o $tudied the
eect o hot 2ater in#et te"!erature$ on the coeicient o
!eror"ance :%OP; and the $urace area o the a1$or!tion coo#ing
co"!onent6 ean Phi#i!!e Praene( A#ain Ba$tide( Franc3 Luca$(Franoi$ Garde( Harr' Bo'er +
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e5ergoecono"ic ana#'$i$ o a dou1#e)eect a1$or!tion rerigeration
$'$te" 2ith the 2ater)#ithiu" 1ro"ide !air( o!erating 2ith the direct
co"1u$tion o natura# ga$6 The "ethod co"1ine$ e5ergetic and
econo"ic ana#'$i$ and thi$ $tud' 2a$ done ater the energetic ana#'$i$
o a## $'$te"J$ co"!onent$6 The' !eror"ed e5ergoecono"ic
e4a#uation o the ther"od'na"ic #o2$( 2hich go through thi$ c'c#e(
or o!erationa# condition$ ai"ed at a rerigerating ca!acit' ro" + to
/+ TR6 And a!!#ied to the !re$ent $'$te" to re4ea# 2hich co"!onent
in the c'c#e 2ou#d 1e 2a$ting energ'6 Thi$ "ethod 2a$ a#$o 1a$ed on
the incidence "atri5 that re!re$ent$ the !h'$ica# $tructure o the
a1o4e)"entioned $'$te"6
Guo8hen Kie Guogang Sheng Guang Li Shu'uan Pan* Ha4e
ado!ted an i"!ro4ed c'c#e 2a$ ado!ted to rai$e the !re$$ure in$ide
the a1$or1er o the "achine in order to inten$i' the a1$or!tion eect
o thic3 Lithiu" 1ro"ide $o#ution and enhance the %OP o the
a1$or!tion rerigeration $'$te"6 A "athe"atica# "ode# that i$ u$ed or
!redicting the !eror"ance o the $'$te" 2a$ de4e#o!ed( and the
in#uence o !re$$ure change on the o4era## !eror"ance o the
"achine 2a$ $tudied6 O"er =a'na3#i and Rece! Ca"an3aradeni8
ha4e done the ir$t and $econd #a2 ther"od'na"ic ana#'$i$ o a
$ing#e)$tage a1$or!tion rerigeration c'c#e 2ith 2ater#ithiu" 1ro"ide
a$ 2or3ing #uid !air6 Ther"od'na"ic !ro!ertie$ o each !oint in the
c'c#e 2ere ca#cu#ated u$ing re#ated e9uation$ o $tate6 Heat tran$er
rate o each co"!onent in the c'c#e and $o"e !eror"ance !ara"eter$
2ere ca#cu#ated ro" the ir$t #a2 ana#'$i$6 Fro" the $econd #a20
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ana#'$i$( the entro!' generation o each co"!onent and the tota#
entro!' generation o a## the $'$te" co"!onent$ 2ere o1tained6 The'
e5a"ined the >ariation o the !eror"ance and entro!' generation o
the $'$te" at 4ariou$ o!erating condition$6 D6S6 =i"( %6H6M6
Machie#$en ha4e $tudied $e4era# air)coo#ed $o#ar a1$or!tion coo#ing
$'$te"$ and co"!ared the" in ter"$ o co$t and !eror"ance . The'
ound that %o"!ared to $ing#e eect $'$te" o the $a"e coo#ing
ca!acit'( ha# eect $'$te"$ 2ou#d re9uire a1out @- "ore heat
e5change $urace and )/-,- "ore co##ector area6 So#ar raction o
a $ing#e eect $'$te" 2ou#d 1e #o2er than ha# eect $'$te"( un#e$$
4acuu" tu1e co##ector$ or co"!ara1#e t'!e$ are u$ed6
In the "ean 2hi#e another $'$te" gained i"!ortance 2hich u$e$
the 2a$te energ' a4ai#a1#e to !roduce the coo#ing eect and air
conditioning 2hich i$ the 4a!or ad$or!tion $'$te"6 R66
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$o#ar regeneration i$ "ade in the a"1ient air or the regeneration(
aS=/@ $o#ar coo3er i$ con$idered6
B' Li Cong and Ru8hu /.
ha4e $tudied "ore than /-- !atent$
i#ed "ain#' $ince 'ear .--- that !ro!o$e techno#ogie$ to i"!ro4e
ad$or!tion $'$te" and "a3e it 1eco"e a rea#i$tic a#ternati4e6 And the
!atent$ $ur4e'ed 2ere c#a$$iied into our "ain grou!$0 ad$or!tion
$'$te" de4e#o!"ent( ad$or1ent 1ed inno4ation( ad$or1entad$or1ate
"ateria# de4e#o!"ent and no4e# a!!#ication o ad$or!tion coo#ing
$'$te"6 The 4ariou$ techno#og' o!tion$ are di$cu$$ed and e4a#uated6
Hot $!ot$ and 3e' in4entor$a!!#icant$ are identiied6 An
a$$e$$"ent i$ "ade a1out current and uture de4e#o!"ent o
ad$or!tion rerigeration techno#ogie$6 %raig %hri$t' and Re8a Too$$i
/? ha4e !eror"ed an in4e$tigation into the ea$i1i#it' o "eeting the
coo#ing need$ or co""ercia# tractor trai#er rerigeration and tran$it
1u$ air conditioning :A%; 1' uti#i8ing their o2n e5hau$t heat to dri4e
an ad$or!tion rerigeration $'$te"6 An e5!eri"enta# 4a!or
co"!re$$ion A% $'$te" uti#i8ing ad$or!tion co"!re$$ion 2a$
reur1i$hed and o!erated at %SULB to 4eri' !re4iou$#' re!orted
coeicient o !eror"ance :%OP; and $!eciic coo#ing !o2er :S%P;4a#ue$ and to gain 3no2#edge( e5!erience( and in$ight into !roduct
de$ign i$$ue$6
P6 Seiert DBI Ga$) und U"2e#ttechni3 /@ ha4e 2or3ed on a
ne2 and inno4ati4e conce!t o the $u!!#' 2ith !o2er( heat and
chi##ine$$ the %ore o their de"on$tration !ro7ect are a ue# ce##( an
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ad$or!tion Rerigeration "achine a$ 2e## a$ "u#ti)$o#ar co##ector$6
Fir$t e5!erience$ 2ith thi$ conce!t $ho2( that an o!ti"i8ed co)
o!eration o the co"!onent$ 2ith an ada!ti4e contro# $'$te" 1a$ed on
the 2eather oreca$t a$ 2e## a$ 4ariou$ $torageJ$ or heat and
chi##ine$$ can 1e achie4ed6 A continuou$#' o!eration( high ue#
uti#i8ation and reduced en4iron"enta# !o##ution can 1e de"on$trated6
6 R6 %a"argo /+ had 2or3ed on the 1a$ic !rinci!#e$ o the
e4a!orati4e coo#ing !roce$$ or hu"an ther"a# co"ort( the !rinci!#e$
o o!eration or the direct e4a!orati4e coo#ing $'$te" and the
"athe"atica# de4e#o!"ent o the e9uation$ o ther"a# e5change$(
a##o2ing the deter"ination o the eecti4ene$$ o $aturation6 He a#$o
!re$ented $o"e re$u#t$ o e5!eri"enta# te$t$ in a direct e4a!orati4e
coo#er that ta3e !#ace in the Air %onditioning La1orator' at the
Uni4er$it' inatuate Mechanica# Engineering De!art"ent( and thee5!eri"enta# re$u#t$ are u$ed to deter"inate the con4ecti4e heat
tran$er coeicient and to co"!are 2ith the "athe"atica# "ode#6
P6 =6 Ban$a# /, in4e$tigated the !eror"ance characteri$tic$ o
three do"e$tic rerigerator$( na"e#' the 4a!or co"!re$$ion :>%;( the
ther"oe#ectric :TE; and the a1$or!tion rerigeration :AR;6 AR and TErerigerator$ are the re$u#t o re$earch and de4e#o!"ent in
rerigeration $'$te" in the 9ue$t to ind a coo#ing $'$te" 2hich doe$
not u$e an' rerigerant that da"age$ the o8one #a'er6 Three
rerigerator$ o $i"i#ar ca!acit' 2ere co"!ared or their u$age in the
hote# indu$tr' in 4ie2 o their energ' eicienc'( noi$e !roduced and
co$t68
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Fro" the a1o4e #iterature re4ie2 it 2a$ ound the air
conditioning o auto"o1i#e$ can 1e !ro4ided either 1' 4a!or
a1$or!tion $'$te" or ad$or!tion $'$te"6
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CHAPTER) +
INTRODUCTION
The $u17ect o rerigeration and air conditioning ha$ e4o#4ed out o
hu"an need or ood and co"ort( and it$ hi$tor' date$ 1ac3 to
centurie$6 Rerigeration "a' 1e deined a$ the !roce$$ o achie4ing
and "aintaining a te"!erature 1e#o2 that o the $urrounding$( the ai"
1eing to coo# $o"e !roduct or $!ace to the re9uired te"!erature6 One
o the "o$t i"!ortant a!!#ication$ o rerigeration ha$ 1een the
!re$er4ation o !eri$ha1#e ood !roduct$ 1' $toring the" at #o2
te"!erature$6 Rerigeration $'$te"$ are a#$o u$ed e5ten$i4e#' or
!ro4iding ther"a# co"ort to hu"an 1eing$ 1' "ean$ o air
conditioning6 Air %onditioning reer$ to the treat"ent o air $o a$ to
$i"u#taneou$#' contro# it$ te"!erature( "oi$ture content( c#ean#ine$$(
odor and circu#ation( a$ re9uired 1' occu!ant$( a !roce$$( or !roduct$
in the $!ace6
+$* REFRIGERATION METHODS
Genera##' rerigeration "ethod$ are c#a$$iied into t2o t'!e$
/6 Natura# "ethod$
.6 Artiicia# "ethod$
+$*$* NATURAL METHODS
5
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In o#den da'$ rerigeration 2a$ achie4ed 1' natura# "ean$ $uch a$
the u$e o ice or e4a!orati4e coo#ing6 In ear#ier ti"e$( ice 2a$
tran$!orted ro" co#der region$( har4e$ted in 2inter and $tored in
ice hou$e$ or $u""er u$e or( "ade during night 1' coo#ing o
2ater 1' radiation to $trato$!here6
+$*$*$* Art o( Ice !a23n# 45 Noct6rna" Coo"3n#
The art o "a3ing ice 1' nocturna# coo#ing 2a$ !erected in India6
In thi$ "ethod ice 2a$ "ade 1' 3ee!ing a thin #a'er o 2ater in a
$ha##o2 earthen tra'( and then e5!o$ing the tra' to the night $3'6
%o"!acted ha' o a1out -6? " thic3ne$$ 2a$ u$ed a$ in$u#ation6 The
2ater #oo$e$ heat 1' radiation to the $trato$!here 2hich i$ around
)++o% and 1' ear#' "orning hour$ the 2ater in the tra' ree8e$ to ice6
Thi$ "ethod o ice !roduction 2a$ 4er' !o!u#ar in India6
+$*$*$+ E7a8orat37e coo"3n#
A$ the na"e indicate$( e4a!orati4e coo#ing i$ the !roce$$ o
reducing the te"!erature o a $'$te" 1' e4a!oration o 2ater6 Hu"an
1eing$ !er$!ire and di$$i!ate their "eta1o#ic heat 1' e4a!orati4e
coo#ing i the a"1ient te"!erature i$ "ore than $3in te"!erature6
Ani"a#$ $uch a$ the hi!!o!ota"u$ and 1ua#o coat the"$e#4e$ 2ith
"ud or e4a!orati4e coo#ing6 E4a!orati4e coo#ing ha$ 1een u$ed in
India or centurie$ to o1tain co#d 2ater in $u""er 1' $toring the
2ater in earthen !ot$6 The 2ater !er"eate$ through the !ore$ o
earthen 4e$$e# to it$ outer $urace 2here it e4a!orate$ to the
6
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$urrounding( a1$or1ing it$ #atent heat in !art ro" the 4e$$e#( 2hich
coo#$ the 2ater6 It i$ $aid that Pat#i!utra Uni4er$it' $ituated on the
1an3 o ri4er Gange$ u$ed to induce the e4a!orati4e)coo#ed air ro"
the ri4er6 Suita1#' #ocated chi"ne'$ in the roo"$ aug"ented the
u!2ard #o2 o 2ar" air( 2hich 2a$ re!#aced 1' coo# air6
E4a!orati4e coo#ing 1' !#acing 2et $tra2 "at$ on the 2indo2$ i$
a#$o 4er' co""on in India6 The $tra2 "at "ade ro" 3hu$ add$ it$
inherent !eru"e a#$o to the air6 No2)a)da'$ de$ert coo#er$ are 1eing
u$ed in hot and dr' area$ to !ro4ide coo#ing in $u""er6
+$*$+ ARTIFICIAL METHODS
Rerigeration a$ it i$ 3no2n the$e da'$ i$ !roduced 1' artiicia#
"ean$6 Though it i$ 4er' diicu#t to "a3e a c#ear de"arcation
1et2een natura# and artiicia# rerigeration( it i$ genera##' agreed thatthe hi$tor' o artiicia# rerigeration 1egan in the 'ear /*++( 2hen the
Scotti$h !roe$$or
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+$+ AIR CONDITIONING SYSTEMS
Rerigeration $'$te"$ are a#$o u$ed or !ro4iding coo#ing and
dehu"idiication in $u""er or !er$ona# co"ort :air conditioning;6
The ir$t air conditioning $'$te"$ 2ere u$ed or indu$tria# a$ 2e## a$
co"ort air conditioning6 Ea$t"an =oda3 in$ta##ed the ir$t air
conditioning $'$te" in // in Roche$ter( Ne2 Cor3 or the $torage
o !hotogra!hic i#"$6 An air conditioning $'$te" 2a$ in$ta##ed in a
!rinting !re$$ in /-. and in a te#e!hone e5change in Ha"1urg in
/-@6 Man' $'$te"$ 2ere in$ta##ed in to1acco and te5ti#e actorie$
around /--6 The ir$t do"e$tic air conditioning $'$te" 2a$ in$ta##ed
in a hou$e in Fran3urt in /@6 A !ri4ate #i1rar' in St Loui$( USA
2a$ air conditioned in /+( and a ca$ino 2a$ air conditioned in
Monte %ar#o in /-/6 Eort$ ha4e a#$o 1een "ade to air condition
!a$$enger rai# coache$ u$ing ice6 The 2ide$!read de4e#o!"ent o air conditioning i$ attri1uted to the A"erican $cienti$t and indu$tria#i$t
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!re$ent da' air conditioning $'$te"$ u$e either a 4a!or co"!re$$ion
$'$te" or a 4a!or a1$or!tion $'$te"6
+$, 1APOR COMPRESSION SYSTEM
The 4a!or co"!re$$ion rerigeration $'$te" con$i$t$ o an
e4a!orator( co"!re$$or( conden$er and an e5!an$ion 4a#4e6 The
rerigeration eect i$ o1tained in the co#d region a$ heat
i$ e5tracted 1' the 4a!ori8ation o rerigerant in the e4a!orator6 The
rerigerant 4a!or ro" the e4a!orator i$ co"!re$$ed in the co"!re$$or
to a high !re$$ure at 2hich it$ $aturation te"!erature i$ greater than
the a"1ient or an' other heat $in36 Hence 2hen the high !re$$ure(
high te"!erature rerigerant #o2$ through the conden$er(
conden$ation o the 4a!or into #i9uid ta3e$ !#ace 1' heat re7ection to
the heat $in36 To co"!#ete the c'c#e( the high !re$$ure #i9uid i$ "adeto #o2 through an e5!an$ion 4a#4e6 In the e5!an$ion 4a#4e the
!re$$ure and te"!erature o the rerigerant decrea$e6 Thi$ #o2
!re$$ure and #o2 te"!erature rerigerant 4a!or e4a!orate$ in the
e4a!orator ta3ing heat ro" the co#d region6 It $hou#d 1e o1$er4ed
that the $'$te" o!erate$ on a c#o$ed c'c#e6 The $'$te" re9uire$ in!ut
in the or" o "echanica# 2or36 It e5tract$ heat ro" a co#d $!ace and
re7ect$ heat to a high te"!erature heat $in36
;
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Fig .6/ >a!or co"!re$$ion $'$te"
+$ 1APOR ABSORPTION REFRIGERATION SYSTEM
>a!or A1$or!tion Rerigeration S'$te"$ :>ARS; 1e#ong to the
c#a$$ o 4a!or c'c#e$ $i"i#ar to 4a!or co"!re$$ion rerigeration
$'$te"$6 Ho2e4er( un#i3e 4a!or co"!re$$ion rerigeration $'$te"$(
the re9uired in!ut to a1$or!tion $'$te"$ i$ in the or" o heat6 Hence
the$e $'$te"$ are a#$o ca##ed a$ heat o!erated or ther"a# energ'
dri4en $'$te"$6 >a!or a1$or!tion rerigeration $'$te"$ ha4e a#$o 1een
co""ercia#i8ed and are 2ide#' u$ed in 4ariou$ rerigeration and air
conditioning a!!#ication$6 Since the$e $'$te"$ run on #o2)grade
ther"a# energ'( the' are !reerred 2hen #o2)grade energ' $uch a$
2a$te heat or $o#ar energ' i$ a4ai#a1#e6 Since con4entiona# a1$or!tion
$'$te"$ u$e natura# rerigerant$ $uch a$ 2ater or a""onia the' are
en4iron"ent riend#'6
In the $i"!#e$t a1$or!tion rerigeration $'$te"( rerigeration i$
o1tained 1' connecting t2o 4e$$e#$( 2ith one 4e$$e# containing !ure
0
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$o#4ent and the other containing a $o#ution6 Since the !re$$ure i$
a#"o$t e9ua# in 1oth the 4e$$e#$ at e9ui#i1riu"( the te"!erature o the
$o#ution 2i## 1e higher than that o the !ure $o#4ent6 Thi$ "ean$ that i
the $o#ution i$ at a"1ient te"!erature( then the !ure $o#4ent 2i## 1e at
a te"!erature #o2er than the a"1ient6 Hence rerigeration eect i$
!roduced at the 4e$$e# containing !ure $o#4ent due to thi$ te"!erature
dierence6 The $o#4ent e4a!orate$ due to heat tran$er ro" the
$urrounding$( #o2$ to the 4e$$e# containing $o#ution and i$ a1$or1ed
1' the $o#ution6 The $o#ution u$ed in a1$or!tion rerigeration $'$te"$
"a' 1e con$idered a$ a ho"ogeneou$ 1inar' "i5ture o rerigerant
and a1$or1ent6
Fig .6. >a!or a1$or!tion $'$te"
The "o$t co""on#' u$ed rerigerant)a1$or1ent !air$ in co""ercia#
$'$te"$ are0
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/6
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/6 A1$or1er0
A1$or!tion o the rerigerant 4a!or 1' it$ 2ea3 $o#ution in a
$uita1#e a1$or1ent or"ing a $trong or rich $o#ution o the
rerigerant in the a1$or1ent6
.6Pu"!0
Pu"!ing o the rich $o#ution rai$ing it$ !re$$ure to the
conden$er !re$$ure6
?6 Generator 0
Di$ti##ation o the 4a!or ro" the rich $o#ution #ea4ing the !oor
$o#ution or rec'c#ing6
%o"!re$$or i$ connected to the cran3 $hat o the engine through a
1e#t dri4e6 I thi$ unit i$ re"o4ed( then the #oad engine decrea$e$6 Due
to thi$ the engine !eror"ance increa$e$6
• >a!or co"!re$$ion $'$te" traditiona##' u$e$ ha#ogenated
h'drocar1on rerigerant$( 2hich contri1ute to o8one de!#etion
and greenhou$e 2ar"ing6
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A$ "entioned 1eore to !re4ent cr'$ta##i8ation the conden$er
!re$$ure ha$ to 1e "aintained at certain #e4e#( irre$!ecti4e o coo#ing
2ater te"!erature6 Thi$ can 1e done 1' regu#ating the #o2 rate o
coo#ing 2ater to the conden$er6 Additi4e$ are a#$o added in !ractica#
$'$te"$ to inhi1it cr'$ta##i8ation6 Since the entire $'$te" o!erate$
under 4acuu"( out$ide air #ea3$ into the $'$te"6 Hence an air !urging
$'$te" i$ u$ed in !ractica# $'$te"$6 Nor"a##' a t2o)$tage e7ector t'!e
!urging $'$te" i$ u$ed to re"o4e air ro" the $'$te"6 Since the
o!erating !re$$ure$ are 4er' $"a## and $!eciic 4o#u"e o 4a!or i$
4er' high( !re$$ure dro!$ due to riction $hou#d 1e "ini"i8ed6 Thi$ i$
done 1' u$ing t2in and $ing#e dru" arrange"ent$ in co""ercia#
$'$te"$6
+$0 CRYSTALLI9ATIONThe !re$$ure)te"!erature)"a$$ raction and entha#!')
te"!erature)"a$$ raction chart$ $ho2 #ine$ "ar3ed a$ cr'$ta##i8ation
in the #o2er right $ection6 The region to the right and 1e#o2 the$e
cr'$ta##i8ation #ine$ indicate$ $o#idiication o LiBr $a#t6 In the
cr'$ta##i8ation region a t2o)!ha$e "i5ture :$#u$h; o 2ater)#ithiu"
1ro"ide $o#ution and cr'$ta#$ o !ure LiBr e5i$t in e9ui#i1riu"6 The
2ater)#ithiu" 1ro"ide $'$te" $hou#d o!erate a2a' ro" the
cr'$ta##i8ation region a$ the or"ation o $o#id cr'$ta#$ can 1#oc3 the
!i!e$ and 4a#4e$6 %r'$ta##i8ation can occur 2hen the hot $o#ution rich
in LiBr $a#t i$ coo#ed in the $o#ution heat e5changer to #o2
te"!erature$6 To a4oid thi$ the conden$er !re$$ure reduction 1e#o2 a
9
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certain 4a#ue due to $a'( #o2 coo#ing 2ater te"!erature in the
conden$er $hou#d 1e a4oided6 Hence in co""ercia# $'$te"$( the
conden$er !re$$ure i$ artiicia##' "aintained high e4en though the
te"!erature o the a4ai#a1#e heat $in3 i$ #o26 Thi$ actua##' reduce$ the
!eror"ance o the $'$te"( 1ut i$ nece$$ar' or !ro!er o!eration o
the $'$te"6 It $hou#d 1e noted ro" the !ro!ert' chart$ that the entire
2ater)#ithiu" 1ro"ide $'$te" o!erate$ under 4acuu"6
+$: CAPACITY CONTROL
%a!acit' contro# "ean$ ca!acit' reduction de!ending u!on #oad a$
the ca!acit' 2i## 1e "a5i"u" 2ithout an' contro#6 Nor"a##' under
1oth u## a$ 2e## a$ !art #oad$ the out#et te"!erature o chi##ed 2ater i$
"aintained at a near con$tant 4a#ue6 The rerigeration ca!acit' i$ then
regu#ated 1' either0
• Regu#ating the #o2 rate o 2ea3 $o#ution !u"!ed to the
generator through the $o#ution !u"!
• Reducing the generator te"!erature 1' thrott#ing the $u!!#'
$tea"( or 1' reducing the #o2 rate o hot 2ater
• Increa$ing the conden$er te"!erature 1' 1'!a$$ing $o"e o the
coo#ing 2ater $u!!#ied to the conden$er
Method / doe$ not aect the %OP $igniicant#' a$ the re9uired heat
in!ut reduce$ 2ith reduction in 2ea3 $o#ution #o2 rate( ho2e4er(
$ince thi$ "a' #ead to the !ro1#e" o cr'$ta##i8ation( "an' a ti"e a
5
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co"1ination o the a1o4e three "ethod$ are u$ed in co""ercia#
$'$te"$ to contro# the ca!acit'6
+$; COMMERCIAL SYSTEMS
%o""ercia# 2ater)#ithiu" 1ro"ide $'$te"$ can 1e0
/6 Sing#e $tage or $ing#e)eect $'$te"$( and
.6 Mu#ti $tage or "u#ti)eect $'$te"$
Sing#e $tage $'$te"$ o!erate under t2o !re$$ure$( one corre$!onding
to the conden$er and generator :high !re$$ure $ide; and the other
corre$!onding to e4a!orator and a1$or1er6
Sing#e $tage $'$te"$ can 1e either0
/6 T2in dru" t'!e( or
.6 Sing#e dru" t'!e
Since e4a!orator and a1$or1er o!erate at the $a"e !re$$ure the' can 1e hou$ed in a $ing#e 4e$$e#( $i"i#ar#' generator and conden$er can 1e
!#aced in another 4e$$e# a$ the$e t2o co"!onent$ o!erate under a
$ing#e !re$$ure6 Thu$ a t2in dru" $'$te" con$i$t$ o t2o 4e$$e#$
o!erating at high and #o2 !re$$ure$6 Figure .6? $ho2$ a co""ercia#(
$ing#e $tage( t2in dru" $'$te"6
6
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Fig .6? T2in dru" t'!e 2ater) LiBr a1$or!tion $'$te"
A$ $ho2n in the igure( the coo#ing 2ater :2hich act$ a$ heat
$in3; #o2$ ir$t to a1$or1er( e5tract$ heat ro" a1$or1er and then
#o2$ to the conden$er or conden$er heat e5traction6 Thi$ i$ 3no2n a$
$erie$ arrange"ent6 Thi$ arrange"ent i$ ad4antageou$ a$ the re9uired
coo#ing 2ater #o2 rate 2i## 1e $"a## and a#$o 1' $ending the coo#ing
2ater ir$t to the a1$or1er( the conden$er can 1e o!erated at a higher
!re$$ure to !re4ent cr'$ta##i8ation6 It i$ a#$o !o$$i1#e to ha4e coo#ing
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2ater #o2ing !ara##e# to conden$er and a1$or1er( ho2e4er( the
coo#ing 2ater re9uire"ent in thi$ ca$e 2i## 1e high6 A rerigerant
!u"! circu#ate$ #i9uid 2ater in e4a!orator and the 2ater i$ $!ra'ed
onto e4a!orator tu1e$ or good heat and "a$$ tran$er6 Heater tu1e$
:$tea" or hot 2ater or hot oi#; are i""er$ed in the $trong $o#ution
!oo# o generator or 4a!or generation6 Pre$$ure dro!$ 1et2een
e4a!orator and a1$or1er and 1et2een generator and conden$er are
"ini"i8ed( #arge $i8ed 4a!or #ine$ are e#i"inated and air #ea3age$ can
a#$o 1e reduced due to #e$$ nu"1er o 7oint$6
In "u#ti)eect $'$te"$ a $erie$ o generator$ o!erating at
!rogre$$i4e#' reducing !re$$ure$ are u$ed6 Heat i$ $u!!#ied to the
highe$t $tage generator o!erating at the highe$t !re$$ure6 The entha#!'
o the $tea" generated ro" thi$ generator i$ u$ed to generate $o"e"ore rerigerant 4a!or in the #o2er $tage generator and $o on6 In thi$
"anner the heat in!ut to the $'$te" i$ u$ed eicient#' 1' generating
"ore rerigerant 4a!or #eading to higher %OP$6 Ho2e4er( the$e
$'$te"$ are "ore co"!#e5 in con$truction and re9uire a "uch higher
heat $ource te"!erature$ in the highe$t $tage generator6
:
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CHAPTER ,
STUDY OF AUTOMOBILE AIR CONDITIONING
In the uture there 2i## 1e a #arger and #arger diu$ion o >%R
$'$te"$ 1ecau$e "ore and "ore !eo!#e 2i## 1e read' to $!end "one'
or tra4e##ing co"ort6 At the $a"e ti"e( there i$ the $trong de"and
or i"!ro4ed 4ehic#e !eror"ance and ue# con$u"!tion( reduced
noi$e( ea$' "aintenance and high re#ia1i#it'6
A con$idera1#e !ortion o the tota# energ' con$u"!tion o the
2e$tern 2or#d i$ centered in the tran$!ort $ector6 Auto"o1i#e$ and
truc3$ a#one account or a!!ro5i"ate#' - !ercent o a##
tran$!ortation energ' e5!enditure$6 The$e interna# co"1u$tion
engine$ t'!ica##' ha4e a ther"a# eicienc' o @- !ercent6 The
re"aining energ' i$ re7ected to the at"o$!here in the or" o hot
e5hau$t ga$e$ or a$ energ' con4ected ro" the radiator and the
engine6 Much 2or3 no2 in !rogre$$ i$ directed to the i"!ro4e"ent o
the ther"a# eicienc' 1' achie4ing 1etter con$u"!tion o the ue#6
So"e eort ha$ 1een de4oted to the uti#i8ation o the 4a$t a"ount o
2a$te energ' di$$i!ated in the e5hau$t ga$e$6 Unortunate#'( e2 ha4e
ocu$$ed on u$ing the 2a$te heat or air)conditioning and
rerigeration6 Auto"o1i#e$ and truc3$ a#one account or
a!!ro5i"ate#' - !ercent o a## tran$!ortation energ' e5!enditure$6
The$e interna# co"1u$tion engine$ t'!ica##' ha4e a ther"a# eicienc'
o @- !ercent6 The re"aining energ' i$ re7ected to the at"o$!here in
the or" o hot e5hau$t ga$e$ or a$ energ' con4ected ro" the radiator
;
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and the engine6 Much 2or3 no2 in !rogre$$ i$ directed to the
i"!ro4e"ent o the ther"a# eicienc' 1' achie4ing 1etter
con$u"!tion o the ue#6 So"e eort ha$ 1een de4oted to the
uti#i8ation o the 4a$t a"ount o 2a$te energ' di$$i!ated in the
e5hau$t ga$e$6 Unortunate#'( e2 ha4e ocu$$ed on u$ing the 2a$te
heat or air)conditioning and rerigeration6
Be$ide$ energ' u$age or tran$!ort rerigeration( another
concern 2hich ha$ e"erged in the #a$t i4e to ten 'ear$ i$ the $earch
or en4iron"enta##')1enign rerigerant$ and rerigeration techni9ue$6
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The !rinci!a# dierence 1et2een the a1$or!tion and the 4a!or)
co"!re$$ion c'c#e$ i$ the "echani$" or circu#ating the rerigerant
through the $'$te" and !ro4iding the nece$$ar' !re$$ure dierence
1et2een the 4a!ori8ing and conden$ing !roce$$e$6 The 4a!or
co"!re$$or e"!#o'ed in the 4a!or)co"!re$$ion c'c#e i$ re!#aced in
the a1$or!tion c'c#e 1' an a1$or1er and a generator or 1oi#er( 2hich
co"!re$$ the 4a!or a$ re9uired6 The energ' in!ut re9uired 1' the
4a!or)co"!re$$ion c'c#e i$ $u!!#ied to the co"!re$$or in the or" o
"echanica# 2or36 In the a1$or!tion c'c#e( the energ' in!ut i$ "o$t#'
in the or" o heat $u!!#ied to the generator6 In the !re$ent ca$e the
heat $ource i$ the e5hau$t heat o an interna# co"1u$tion 4ehic#e
engine6
In the generator a "i5ture o #ithiu" 1ro"ide and 2ater i$heated6 The 1oi#ing !oint o 2ater i$ #o2er than that o #ithiu"
1ro"ide( $o it 4a!ori8e$( $e!arating the rerigerant ro" the
a1$or1ent6 Since the 4a!or i$ not a !ure 2ater 4a!or( it "u$t 1e
!uriied a$ it #o2$ through a rectiication co#u"n6
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Fig ?6/ %o"!onent$ o the air)coo#ed a1$or!tion $'$te" or
tran$!ortation
The a#"o$t !ure 2ater 4a!or #o2$ ro" the to! o the co#u"n
to the conden$er a$ a high)te"!erature( high !re$$ure "i5ture6 A$
a"1ient air !a$$e$ o4er the conden$er( it re"o4e$ heat ro" the ga$)
"i5ture and the 4a!or conden$e$ to a #i9uid6 Ater the 4a!or i$
co"!#ete#' conden$ed( the #i9uid #ea4e$ the conden$er and !a$$e$ to
the #i9uid)$uction heat e5changer :LSHK;6 The LSHK i$ an a#u"inu"
!#ate)in heat e5changer6 It reduce$ the te"!erature o the #i9uid
1eore it reache$ the e4a!orator6
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4a!ori8e$6 Ater #ea4ing the e4a!orator( the 4a!or i$ urther heated a$
it !a$$e$ through the LSHK to the a1$or1er "i5ing 4e$$e#6
The high)!re$$ure 2ea3 a1$or1ent $o#ution #ea4ing the generator
enter$ a heat e5changer6 Here( it$ te"!erature i$ #o2ered 1' heat
e5change 2ith the $trong $o#ution co"ing ro" the a1$or1er6 The
2ea3 $o#ution te"!erature i$ #o2ered urther in the air coo#ed
a1$or1er $u1coo#er 2hich i$ a in)and tu1e heat e5changer #i3e the
conden$er and e4a!orator6 Fina##'( the 2ea3 $o#ution !a$$e$ through a
thrott#ing 4a#4e !rior to entering the "i5ing 4e$$e# and "i5ing 2ith
the rerigerant 4a!or co"ing ro" the e4a!orator and LSHK6 The
a1$or!tion o rerigerant into the a1$or1ent $o#ution $tart$ in thi$
4e$$e#( 2here the re#ea$ed heat o a1$or!tion $igniicant#' increa$e$
the te"!erature o the t2o)!ha$e 1inar' "i5ture6 The "i5ture i$di$tri1uted into the three circuit$ o the air coo#ed a1$or1er heat
e5changer6 Re"o4a# o heat 1' a"1ient air i$ nece$$ar' to co"!#ete
a1$or!tion o 2ater into the $o#ution6
The a1$or!tion o rerigerant into the a1$or1ent $o#ution $tart$ in thi$
4e$$e#( 2here the re#ea$ed heat o a1$or!tion $igniicant#' increa$e$
the te"!erature o the "i5ture6 The "i5ture i$ di$tri1uted into the
three circuit$ o the air coo#ed a1$or1er heat e5changer6 Re"o4a# o
heat 1' a"1ient air i$ nece$$ar' to co"!#ete a1$or!tion o 2ater into
the $o#ution6
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The $o#ution #ea4ing the a1$or1er i$ $trong 1ecau$e it ha$ the 2ater
rerigerant a1$or1ed into it6 Ater #ea4ing the air coo#ed a1$or1er( the
$trong $o#ution !re$$ure i$ rai$ed 1' a !u"!6 Pu"!ing !o2er in the
or" o 2or3 "u$t 1e in!ut to the $'$te"( 1ut thi$ !o2er re9uire"ent
i$ re#ati4e#' $"a## co"!ared to the !o2er in!ut into the co"!re$$or o
a 4a!or)co"!re$$ion c'c#e 1ecau$e #i9uid i$ near#' inco"!re$$i1#e6
The $o#ution !a$$e$ on to the rectiier 2here it e5tract$ the rectiier
coo#ing #oad( and to the $o#ution heat e5changer( 2here "ore heat i$
a1$or1ed ro" the 2ea3 $o#ution6 The !reheated $o#ution !a$$e$
through the $tri!!ing co#u"n $ection o the rectiier in order to re#ea$e
$o"e 4a!or 1eore entering the generator6
,$+ WASTE HEAT RECO1ERY GENERATOR
ALTERNATI1ESThe !o2er can 1e tran$erred ro" the e5hau$t ga$ to the 4a!or
generator either direct#' or 1' "ean$ o an inter"ediate "ediu"6
A"ong the $uita1#e $econdar' #uid$( air $ee"$ a good choice6
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Fig ?6. Generator $'$te" 2ith additiona# 1urner
In the ca$e o direct reco4er'( the te"!erature at the a1$or!tion
$'$te" generator i$ $o"e /.--% and "a' 1e a$$u"ed to 1e con$tant6
Fig ?6? Direct reco4er' generator $'$te"
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$o"e ad4antage$ "a' co"e i !ha$e change occur$ in the e5hau$t
!i!e heat e5changer a$ 2e## a$ in the a1$or!tion $'$te" generator6
Fig ?6+ Generator 2ith air a$ an inter"ediate #uid c#o$ed circuit
I the heat reco4er' de4ice i$ !#aced do2n$trea" o the cata#'$er( the
te"!erature at the cata#'$er in#et de!end$ on the engine o!erating
condition$ 62hen the heat tran$er occur$ 1et2een e5hau$t ga$ and a
$econdar' #uid( the u$eu# heat tran$er $urace cou#d 1e in$uicient
to o1tain the nece$$ar' a"ount o reco4ered heat6 Thu$ direct
reco4er' 4a!or generator i$ !reerred6
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CHAPTER
THERMODYNAMIC ANALYSIS OF ABSORPTION SYSTEM
The 1a$i$ o ther"od'na"ic$ i$ $tated in the ir$t and $econd
#a2$6 The ir$t #a2 o ther"od'na"ic ana#'$i$ i$ $ti## the "o$t
co""on#' u$ed "ethod in the ana#'$i$ o ther"a# $'$te"$6 The ir$t
#a2 i$ concerned on#' 2ith the con$er4ation o energ'( and it gi4e$ no
inor"ation on ho2( 2here( and ho2 "uch the $'$te" !eror"ance i$
degraded6 The $econd #a2 o ther"od'na"ic ana#'$i$ i$ a !o2eru#
too# in the de$ign( o!ti"i8ation( and !eror"ance e4a#uation o energ'
$'$te"$6
A 1a$ic 4a!or a1$or!tion c'c#e i$ a t2o !re$$ure three
te"!erature$ #e4e# c'c#e 2hich "a3e$ u$e o a 4a!ori8a1#e #i9uid a$
the rerigerant and a $econd #i9uid or $o#id #i9uid a$ an a1$or1ent6 It
con$i$t$ o a generator( a conden$er( an a1$or1er( an e4a!orator( a
$o#ution !u"! and e5!an$ion 4a#4e$6
The $o#ution te"!erature in the generator and a1$or1er are not
unior" due to the 4ariation in $o#ution concentration ro" in#et to
out#et in the$e co"!onent$6 Thi$ cau$e$ heat tran$er irre4er$i1i#it'J$
in addition to tho$e due to interna# "a$$ e5change6 The regenerated
a1$or1ent #ea4e$ the generator at high te"!erature and i$ coo#ed to
a1$or1er te"!erature6 Si"i#ar#' the $o#ution #ea4ing the a1$or1er i$
heated to the #e4e# o the generator te"!erature6 A $o#ution heat
8:
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e5changer can 1e u$ed to tran$er the heat ro" the 2ea3 $o#ution
#ea4ing the generator to the $trong $o#ution #ea4ing the a1$or1er6 Thi$
reduce$ the in!ut heat re9uired in the generator6 Thi$ interna# heat
reco4er' i"!ro4e$ the %OP6
Figure @6/ La'out o a1$or!tion $'$te"
The "ain ther"od'na"ic$ !roce$$ in a a1$or!tion rerigeration c'c#e
can 1e $u""ari$ed a$ o##o2$0
) Pu"!ing( !re$$uri$ation and $en$i1#e heat re"o4a# o the rich
$o#ution6
) De$or!tion !roce$$ in the generator 2ith e5terna# heat in!ut( Qg at a
te"!erature tg( 2hich re!re$ent$ the "ain in!ut energ' in thi$ $'$te"6
) De$u!erheating and conden$ation at con$tant !re$$ure in the
conden$er( thu$ gi4ing an energ' Q% at a te"!erature tc6
) %oo#ing o the rerigerant #i9uid and it$ i$entha#!ic e5!an$ion
through a thrott#ing 4a#4e6
) E4a!oration o the rerigerant in the e4a!orator 2hich !roduce$ the
coo#ing #oad( Qe( at an e4a!orator te"!erature te6
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) A1$or!tion o the #o2 !re$$ure rerigerant 4a!or 2ithin the 2ea3
$o#ution in the a1$or1er at the a1$or1er te"!erature ta 2ith a heat
out!ut Qa6
In order to !eror" a ther"od'na"ic ana#'$i$ o thi$ c'c#e( the
o##o2ing a$$u"!tion$ are "ade0
• The generator( conden$er( e4a!orator and a1$or1er te"!erature$
are $u!!o$ed con$tant6
• The huge and #o2 !re$$ure$ o the c'c#e corre$!ond re$!ecti4e#'
to the $aturation te"!erature in the conden$er and in the
e4a!orator6
• The !re$$ure$ in the generator and in the a1$or1er are $u!!o$ed
to 1e $i"i#ar to the !re$$ure$ in the conden$er and in the
e4a!orator re$!ecti4e#'6
• The $trong $o#ution M$$ i$ deined a$ the $o#ution 2ith a high
concentration o the rerigerant :2ater; #ea4ing the a1$or1er i$
$u!!o$ed to 1e at a $aturation $tate6
• The 2ea3 $o#ution( "2$( i$ deined a$ the $o#ution 2ith a #o2
concentration o the rerigerant #ea4e$ the generator at a
te"!erature tg6
• The rerigerant :
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$* FIRST LAW ANALYSIS
In recent 'ear$( theoretica# and e5!eri"enta# re$earche$ on the
a1$or!tion rerigeration $'$te" ha4e increa$ed( 1ecau$e the$e $'$te"$
harne$$ ine5!en$i4e energ' $ource$ in co"!ari$on to 4a!or
co"!re$$ion $'$te"$6 The $'$te" i$ 1ounded 1' t2o concentration
#ine$ K/ and K. or a1$or1er and generator concentration$(
re$!ecti4e#'( and t2o con$tant !re$$ure$ !e and !c or e4a!orator and
conden$er re$!ecti4e#'6 For an eicient air conditioning a!!#ication(
the e4a!orator te"!erature te $hou#d 1e #o2 enough to dehu"idi' the
air6 In !ractice it range$ ro" @6+ to /--% according to the #oad
condition$6 The heat re7ection te"!erature$ ta and tc or the a1$or1er
and the conden$er re$!ecti4e#'( 4ar' according to the t'!e o coo#ing
"ediu"6 The generator te"!erature tg de!end$ on the $ource o heata4ai#a1#e6 Ho2e4er a "ini"u" te"!erature o --% $hou#d 1e
"aintained to !ro4ide eicient o!eration6 The o!erationa# unction o
a #i9uid #i9uid heat e5changer in the c'c#e 2i## 1e the reduction o
the 2ea3 $o#ution te"!erature t@( #ea4ing the generator and increa$ing
the $trong $o#ution te"!erature t/ #ea4ing the a1$or1er6
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$+ THERMODYNAMIC PROPERTIES
Entha#!ie$ o the 2ater :rerigerant; and LiBr :a1$or1ent; $o#ution$
2ere ca#cu#ated 2ith reerence te"!erature at .+-%6 The o##o2ing
e5!re$$ion$ 2ere deri4ed 1' F6L6Lan$ing /* to ca#cu#ate the c'c#e
!eror"ance6
/6 The entha#!' o !ure 2ater #i9uid at te"!erature t-% :t)
.+;@6/, =3g
.6 The entha#!' o $aturated 2ater 4a!or at te"!erature t-%
:.?*6*@/6*@+t; =3g
?6 The entha#!' or $u!erheated $tea" at te"!erature t-% and
!re$$ure e9ua# to $aturation !re$$ure o $tea" at te"!erature
t-% :.?*6*@/6.+t)6/* t; =3g
@6 The $!eciic heat o #ithiu" 1ro"ide2ater $o#ution o concentration K 3g LiBr3g $o#ution i$ gi4en 1' %5 @6..*)
+6/@K.6-/K. =3g
+6 The entha#!' o LiBr2ater $o#ution o concentration K 3g
LiBr3g $o#ution at .+-% i$ H5(.+ .@6)///6,.K/*@@6/K.
=3g $o#ution
,6 The entha#!' o LiBr2ater $o#ution o concentration K 3g
LiBr3g $o#ution at te"!erature t-% :/*6.)
/*.6K/,?6+K.;:@6.?)+6/+K.6-/K.;:t;
*6 In the range o concentration ro" -6+)-6,+ LiBr3g $o#ution(
rerigerant te"!erature tR -% :.-+6.)+,?6,@K;:@6*-)
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/6,*K;:t"-%;6 thi$ can 1e 2ritten a$ K:@6-@/6/.+t")tR ;
:/?@6,+-6@*t";
6 The $aturated 4a!our !re$$ure P in Bar corre$!onding to
$aturation te"!erature T-= or !ure 2ater i$ gi4en 1' #og/-P 1ar
-6-/):.6-,T;):/@6+/T.;
$, PERFORMANCE CALCULATION
The deter"ination o ther"od'na"ic !ro!ertie$ o each $tate in
the c'c#e( the a"ount o heat tran$er in each co"!onent( and the #o2
rate$ at dierent #ine$ de!end on the o##o2ing $et o in!ut
!ara"eter$0
/6 Generator te"!erature tg-%
.6 E4a!orator te"!erature te-%
?6 %onden$er te"!erature tc-
%
@6 A1$or1er te"!erature ta-%
+6 Li9uid)#i9uid heat e5changer eecti4ene$$ EL
,6 Rerigeration #oad Qe
The a1o4e $et can 1e deter"ined ro" actua# running
"ea$ure"ent$ or a$$u"ed 1' a ir$t rea$ona1#e e$ti"ate to c'c#e
!eror"ance6
Together 2ith the a$$u"!tion$ o neg#ecting the !u"! 2or3 and
neg#ecting the !re$$ure dro! in co"!onent$ and #ine$ and a$$igning
$aturation condition$ ater a1$or1er( generator :2ea3 $o#ution;(
conden$er and e4a!orator( the !ro!ertie$ are deter"ined a$ o##o2$0
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$,$* ABSORBER CONCENTRATION
Thi$ i$ deter"ined ro" concentration e9uation u$ing ta or the
$o#ution te"!erature and te or the 2ater te"!erature corre$!onding to
the e4a!orator !re$$ure Pe0
K/K.K? K $trong $o#ution
K/ :@6-@/6/.+ta)te; :/?@6,+-6@*ta; 3g LiBr3g
$o#ution66 :e96 @6/;
$,$+ GENERATOR CONCENTRATION
Thi$ i$ deter"ined ro" concentration e9uation u$ing tg or the
$o#ution te"!erature and tc or the rerigerant te"!erature
corre$!onding to the conden$er !re$$ure Pc0
K@K+K, K 2ea3 $o#ution
K@ :@6-@/6/.+tg)tc; :/?@6,+-6@*tg; 3g LiBr3g$o#ution6:e96 @6.;
Fig @6. #o2 diagra" o LiBr H.O a1$or!tion $'$te"
$,$, PRESSURE LIMITS IN THE CYCLE
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It i$ !o$$i1#e to e4a#uate the !re$$ure in the e4er' #ine a$ o##o2$0
Pe4a!orator (PeP/P,PP/- in 1ar 0
#og/-Pe -6-/):.6-,te.*?6/+;):/@6+/
:te.*?6/+;.;666666666666666666666666666666666666666666:e96 @6?;
Pconden$er PcP.P?P@P+P*P in 1ar0
#og/-Pc -6-/):.6-,tc.*?6/+;):/@6+/:tc.*?6/+;.;
6:e96 @6@;
$,$ FLOW RATES
Entha#!' o $aturated #i9uid 2ater ater conden$er :$tate ;( i$ gi4en
1' the conden$er te"!erature tc6
h :tc ).+; @6/,
33g666 :e96 @6+;
The thrott#ing !roce$$ ro" to gi4e HH
Entha#!' o $aturated 2ater 4a!our ater e4a!orator :$tate /-; i$ gi4en
1' the e4a!orati4e te"!erature te a$
h/- :.?*6*@/6*@+te;
33g6:e96 @6,;
According to the ir$t #a2 o ther"od'na"ic$ to the e4a!orator 2i##
gi4e
Qe"R :h/-)h;6666
666666:e96@6 *;
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"R Qe :h/-) h;66
6:e96 @6;
The #ithiu" 1ro"ide "a$$ 1a#ance in a1$or1er gi4e$
"2K,"R K/-"$K/:"2"R ;K/666
6:e96 @6;
B' u$ing the a1o4e e9uation$(
"2 :Qe :h/-) h;; :K/ :K@)
K/;; 666666666666666666666666666666666666666666666666666666666666666666666:e96 @6/-;
"$ :Qe :h/-) h;; :K@ :K@)
K/;;6666666666666666666666666666666666666666666666666666666666666666666666:e96 @6//;
$ince the concentration$ 5/ and K@ are re$tricted not to e5ceed certain
#i"it$ to a4oid cr'$ta##i8ation !ro1#e"$( and i the te"!erature$ o the
c'c#e are $et to 4ar' according the a"1ient and #oad condition$( the
"a$$ #o2 rate$ in the dierent #ine$ 2i## 1e 4arie$ according#'6
$,$. LI
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GENERATOR>
ABSORBER
The entha#!' o 2ater 4a!or #ea4ing the generator and entering the
conden$er :$tate*; i$ gi4en 1' h*.?*6/,/6.tg)
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-6/*tc666:e96
@6/;
The heat 1a#ance o the conden$er gi4e$
Qc"r :h*)h;
6
66:e96 @6/;
Heat 1a#ance or the co"1ined generator and heat e5changer contro#
4o#u"e gi4e$
Qg"/-h+"R h*)
"$h.66
:e96 @6.-;
Heat 1a#ance or the a1$or1er gi4e$ QA
Qa "2h,"R h/-)"$h/666
66:e96@6./;
The a1o4e e9uation$ are go4erned 1' the ir$t #a2 o ther"od'na"ic$
in the or"
QcQa
QgQe666
666:e96 @6..;
$,$0 COEFFICIENT OF PERFORMANCE?COP@
Thi$ i$ deined a$ %OP :rerigeration eect; :e5terna# heat in!ut;
9:
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%OP
QeQg6666:e96
@6.?;
$,$: IDEAL COEFFICIENT OF PERFORMANCE
The "a5i"u" coeicient o !eror"ance o the a1$or!tion c'c#e i$
gi4en 1'
%OP"a5 te :tg)ta; tg :tc)te;
6666:e96
@6.@;
The ratio %OPactua#%OP"a5 i$ ca##ed the re#ati4e !eror"ance ratioJ to
$ho2 the de4iation ro" re4er$i1#e c'c#e o!eration6
$ MODEL CALCULATION
K/:$trong $o#ution; :@6-@/6/.+ta)te; :/?@6,+-6@*ta; 3g
LiBr3g $o#ution
:@6-@ :/6/.+@-;)/-;:/?@6,+-6@*@-;
-6+@*
K@:2ea3 $o#ution; :@6-@/6/.+tg)tc; :/?@6,+-6@*tg; 3g
LiBr3g $o#ution
:@6-@:/6/.+*;)@-; :/?@6,+-6@**;
-6,++
#og/-Pe -6-/):.6-,te.*?6/+;):/@6+/:te.*?6/+;.;
-6-/):.6-,.?6/+;):/@6+/.?6/+.;
Pe *6 3Pa -6-* 1ar
9;
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#og/-Pc -6-/):.6-,tc.*?6/+;):/@6+/:tc.*?6/+;.;
-6-/):.6-,?/?6/+;):/@6+/?/?6/+.;
/6--@ 3Pa -6-/ 1ar
h :t).+;@6/, 33g
:@-).+;@6/,
,.6* 33g
h/- :.?*6*@/6*@+te; 33g
:.6*6*@/6*@+/-;
.@/+6/ 33g
"R QE :h/-) h;6 ?6+/,*:.@/+6/),.6*;
-6--/@ 3g$
"2 :QE :h/-) h;; :K/ :K@)K/;;
-6--/@:-6+@*:-6,++)-6+@*;;
-6--*+ 3g$
"$ :QE :h/-) h;; :K@ :K@)K/;;
-6--/@:-6,++:-6,++)-6+@*;;
-6-- 3g$
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%K/ @6..*)+6/@K/.6-/K/. 33g
@6..*):+6/@-6+@*;:.6-/-6+@*.;
.6-/ 33g
%K@ @6..*)+6/@[email protected]/K@. 33g
@6..*):+6/@-6,++;:.6-/-6,++.; /6*/ 33g
t+ tg) EL:tg)ta;
*):-6,:*)@-;
,.6-%
t? te : EL :K/%K@;:K@%K/;:tg)ta;;
/-:-6,:-6+@*/6*/;:-6,++.6-/;:*)@-;
,@6?-
%
h/ :/*6.)/*.6K//,?6+K/.;:@6.?)+6/+K/.6-/K/
.;:ta;
:/*6.):/*.6-6+@*;:/,?6+-6+@*.;;:@6.?)
:+6/+-6+@*;:.6-/-6+@*.;;@-
:/*6.)*+6.++-,6+;:@6.?).6/*-6,-/;@-
).-6,@ =73g
h+:/*6.)/*.6K@/,?6+K@.;:@6.?)+6/[email protected]/K@
.;:t+;
:/*6.):/*.6-6,++;:/,?6+-6,++.;; :@6.?)
:+6/+-6,++;:.6-/-6,++.;;,.6
:/*6.)//,*6,*.,6*@;:@6.?)?6?*-6,.;,.6
5
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)/+?6, =3g
h* .?*6/,/6.tg)-6/*tc .?*6/, :/6.*;):-6/*@-;
.+*,6.@ =3g
Qc "r :h*)h; -6--/@:.+*,6.@),.6*; ?6*@ 3<
Qg "2h+"R h*)"$h/ :-6--*+)/*?6.@;:-6--/@.+*,6.@;)
: -6--).-,6; @6++ 3<
Qa "2h,"R h/-)"$h/ :-6--*)/*?6.@;:-6--/@.@-@6*?.;)
:-6--).-,6; @6?/ 3<
%OP QEQG -6*,*
$. CON1ENTIONAL CALCULATION
The o!erting condition$ or #ithiu" 1ro"ide)2ater air conditioning
$'$te" are gi4en 1e#o2
Generator te"!erature *O%
%onden$er te"!erature @-o%
E4a!orator te"!erature /-o%
A1$or1er te"!erature @- o%
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Fig @6? $che"atic re!re$entation o o $i"!#e 4a!or a1$or!tion $'$te"
2ith Li9uid #i9uid regenerati4e heat e5changer
For" the ig @6? and or" the ta1#e o the 2ater 4a!our !re$$ure in the
A!!endi5 2e o1tain the conden$er and e4a!orator !re$$ure$
corre$!onding to their re$!ecti4e te"!erature$6
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%oden$er and generator !re$$ure
Pc*6?+* 3Pa :at @- o%; -6-*?+ 1ar
A1$or1er and e4a!orator !re$$ure
Pe/6..@ 3Pa -6-/. 1ar
Fig @6@ Re!re$entation o A1$or!tion c'c#e on the !)/T Diagra"
No2 ro" ig @6@ 2e get ir$t the #ithiu" 1ro"ide and then the
rerigerant 2ater concentration in rich and !oor $o#ution$ at $tate$ @
and .
State @ Saturated co#d $o#ution or" the a1$or1er at
Pe/6..@ 3Pa and t@-o%
K#i1r -6++ 3g o LiBr !er 3g o $o#ution
h@?6+ 33g:or" h)5 diagra";
Rich $o#ution concentration o 2ater
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Kr /)-6++-6@+ 3g o 2ater !er 3g o $o#ution
State . $aturated hot $o#ution ro" generator at
P*6?+* 3Pa and at tg* o%
K#i1r -6,+ 3g o LiBr !er 3g o $o#ution
h..@ =3g:ro" h)5 diagra";
Poor $o#ution concentration o 2ater
Kr -6?+ 3g o 2ater !er 3g o $o#ution
State / $aturated $o#ution at conden$er !re$$ure and -6++LiBr
concentration
t/*@ o% :ro" ig @6.;
h/,, =3g:h)5 diagra";
State ? $aturated $o#ution at e4a!orator !re$$ure and -6,+LiBr
concentration
T?,- o% :ro" ig @6.;
h?/- =3g:h)5 diagra";
State !oint ?a ha$ the $a"e entha#!'( te"!erature and co"!o$ition a$
$tate ?61ut i$ at generator !re$$ure6 It$ re!re$ent$ a $tate $u1 coo#ed
ro" . to ? at++6?."" hg !re$$ure
State @a te@ o% and K#i1r -6++
h@ah@?6+ =3g:neg#ecting !u"! 2or3;
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S!eciic $o#ution circu#ation rate$
:/)Ka;:Kr ) Ka;
6:e96 @6.+;
:/)-6?+;:-6@+)-6?+;
,6+ 3g 3g o 4a!our
Heat a4ai#a1#e in the hot $o#ution or tran$er :)/;:h.)h?;
6666666666666666:e96 @6.,;
+6+:.@)/-; ?*@ 3
Heat re9uired 1' co#d $o#ution or heating :h/)h@;
666:e96 @6.*;
,6+ :/,,)?6+; @*/ 3 V?*@
3Hence( co#d $o#ution at @a cannot 1e heated to /6#et it 1e heated
to /a6
State 1a6 energ' 1a#ance o the #i9uid #i9uid heat e5changer gi4e$
:h/a h@; :)/; :h.)h?;
2here h/a h@::)/;;:h.)h?;
66:e96 @6.;
?6+ :+6+,6+;:.@)/-; /+/ 33g
State + It i$ that o 2ater 4a!our at *6?+ 3Pa !re$$ure and *-%
te"!erature6 At the$e condition$ it re!re$ent$ a $u!erheated 4a!our
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$tate6 The entha#!' o 2ater 4a!our a1o4e the reerence $tate o
$aturated 2ater at --% had ta3en ro" e"!irica# re#ation6
h.-+//6t6
:e96 @6.;
h+.-+//6:*;.,? 33g
State ,
Saturated 2ater at @- o
%
h,@6/:@-; /,*6+ 33g
State * !/6..@ 3Pa and at t/- o% :#i9uid4a!or;
h*h,/,*6+ 33g
State !/6..@ 3Pa at t/- o% :$taturated 4a!or;
h.+-//6:/-;.+.- 33g
Rerigerating eect 9e h)h*.+.-)/,*6+.+?.6+ 33g
Heat added in the generator !er unit "a$$ o 4a!our di$ti##ed
9gh+)h. :h.)h/a;
66:e96@6?-;
.,?).@,6+:.@)/+/;
9g ?-,, 3 3g o 4a!our
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%oeicient o Peror"ance( %OP 9e 9g-6**
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Pro!ertie$ %on4entiona#
ca#cu#ation$
%a#cu#ation$ u$ing
"athe"atica# "ode#
Qc ?6** 3< ?6*@ 3<
Qg @6, 3< @6+, 3<
Qa @6?+ 3< @6?. 3<
%OP -6** -6*,*
Ta1#e @6/ co"!ari$ion 1et2een con4entiona# and ca#cu#ated re$u#t$
A$ it i$ $een that the 4a#ue$ o1tained ro" the con4entiona#
ca#cu#ation$ and that ro" the "athe"atica# ca#cu#ation are
a!!ro5i"ate#' $a"e( $o the "athe"atica# "ode# i$ u$ed or doing ir$t
#a2 ana#'$i$ o 4a!or a1$or!tion $'$te" and 1' u$ing thi$
"athe"atica# "ode# a 7a4a !rogra" ha$ 1een de4e#o!ed or the ea$e
o the ca#cu#ation$6
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CHAPTER .
RESULTS AND DISCUSIONS
The ir$t #a2 ana#'$i$ i$ done on #ithiu" 1ro"ide2ater 4a!or
a1$or!tion $'$te"6 Ta1#e +6/ and +6. $ho2$ the re$u#t$ or the
ther"od'na"ic !ro!ertie$ and heat tran$er rate$ o each co"!onent
re$!ecti4e#'6 In thi$ ana#'$i$ (ca#cu#ation 2ere !eror"ed or ?6+32
coo#ing #oad and the !ara"eter$ 2ere ta3en a$ t e@o%( tc@-
o%((ta@-
o%( tg* o% eecti4ene$$ W-66 in ta1#e +6/ che"ica# co"!o$ition
and "a$$ #o2 rate are !ro4ided a#ong 2ith te"!erature(
concentration and entha#!' 4a#ue$ o the 2or3ing #uid$6 A$ $een ro"
the ta1#e +6. co"!ared to other co"!onent$ the generator heat
tran$er rate i$ the highe$t6
State !oint%he"ica#
co"!o$ition
Te"!erature
TO%
%oncentration
Entha#!'
33g
/
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>a!our /- - .+.-
Ta1#e +6/ ther"od'na"ic !ro!ertie$ o each !oint
%o"!onent Heat tran$er rate$ :3
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Fig +6/ heat tran$er rate in each co"!onent$
Fig +6. $ho2$ the re#ation 1et2een the generator te"!erature and
coecient o !eror"ance it $ho2$ that a$ the generator te"!erature
increa$e$ the %OP increa$e$ 3ee!ing the e4a!orator te"!erature te at
,o% conden$er te"!erature Tc at @-o% and the a1$or1er te"!erature ta
at @-o%
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Fig +6. 4ariation o %OP at dierent generator te"!erature$
A$ the generator te"!erature increa$e$ the net eect change in the
entha#!ie$ o 4a!our and 2ea3 $o#ution decrea$e$ there1' Qg
decrea$e$ re$u#ting in increa$e o %OP6
Fig +6? $ho2$ the re#ation 1et2een the conden$er te"!erature and
coeicient o !eror"ance it $ho2$ that a$ the conden$er te"!erature
increa$e$ the %OP 4a#ue$ decrea$e$ 3ee!ing tg-o% te,o% W-6,
Qe?6+ $o the conden$er$ $hou#d 1e "aintained at #o2 te"!erature$
in order to attain high %OP 4a#ue$ at #o2 generator te"!erature$6
Fig +6? 4ariation o %OP at dierent conden$er te"!erature$
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generator i$ 3e!t con$tant and the 4ariation in %OP i$ o1$er4ed 1'
4ar'ing the e4a!orator te"!erature6 A$ the e4a!orator te"!erature
increa$e$ the conden$ation re9uired i$ #e$$6
Fig +6@
>ariation o %OP at dierent e4a!orator te"!erature$
CHAPTER /
FABIRICATION OF ABSORPTION AIR CONDITIONING
SYSTEM
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The 4a!or a1$or!tion $'$te" genera##' con$i$t$ o a generator( a
conden$er( an a1$or1er an e4a!orator( a !u"! and a $egregator6 The
conden$er u$ed i$ a con4entiona# air coo#ed conden$er u$ed in
auto"o1i#e$ and co"ing to the e4a!orator in$tead o 1u'ing
indi4idua# co"!onent$ $uch a$ e4a!orator( an( e5!an$ion de4ice the
2ho#e e4a!orator unit had 1een 1ought 2ith an and the e5!an$ion
de4ice connected to the e4a!orator !#aced in$ide a ca1inet6 For the an
to run a /.4 1atter' i$ !ro4ided6 The $e#ection o the conden$er and
the e4a!orator i$ 1a$ed on the ca#cu#ation$ or" the ir$t #a2 ana#'$i$
o 4a!or a1$or!tion $'$te" a$ ho2 "uch heat need$ to 1e tran$erred
1' the"6
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circu#ation o the rerigerant 2i## no2 1e ha!!ening on#' due to it$
4a!or !re$$ure6
Fig ,6/ Modiied #a'out o a1$or!tion $'$te"
/$* ABSORBER
The a1$or1er u$ed i$ a c'#inder "ade o "i#d $tee#( the "ain unction
o the a1$or1er i$ it 2or3$ a$ a $torage tan3 or LiBr2ater $o#ution
and or the !ur!o$e o re)circu#ation6it con$i$t$ o three 4a#4e$ one or
co##ecting the $egregated LiBr $o#ution that i$ the 2ea3 $o#ution ro"
the $egregator( the $econd or co##ecting 2ater 4a!or co"ing ro" the
e4a!orator and the third or $ending the LiBr2ater $o#ution to the
generator or heating6 %o!!er tu1e o "" dia"eter i$ u$ed or
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connecting the a1$or1er and the generator to $end LiBr2ater $o#ution
to the generator or heating( genera# ru11er tu1e$ u$ed auto"o1i#e$ o
dia"eter /+"" i$ u$ed or connecting the e4a!orator out#et and the
a1$or1er in#et through 2hich 2ater 4a!or #o2$6 A #o2 indicating
4a#4e i$ u$ed or chec3ing 2hether the $trong $o#ution i$ again 1eing
$ent to the generator $
F3# /$+ A4or4er
/$+ GENERATOR
The generator i$ a#$o c'#indrica# in $ha!e "ade o "i#d $tee#X here it
2or3$ a$ 1oth generator and $egregator6 The "ain unction o the
generator i$ to heat the LiBr2ater $o#ution to $aturation te"!erature
and the unction o the $egregator i$ to $e!arate 2ater 4a!or or" the
$o#ution and $end the 2ea3 $o#ution 1ac3 to the a1$or1er6 The
generator a#$o ha$ three 4a#4e$ one or co##ecting o $trong $o#ution
ro" the a1$or1er( the $econd one or $ending 1ac3 the 2ea3 $o#ution
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1ac3 into the a1$or1er and the third one or $ending the 2ater 4a!or
into the conden$er or urther !roce$$6 The generator 3e!t in a ti#ted
!o$ition 2here the u!!er !art 2hen ti#ted act$ a$ a $egregator 2hich
co##ect$ the 2ater 4a!or and $end$ it to the conden$er a tu1e i$ itted
in$ide the generator and ga$ 2ie#ded through 2hich the 2ater 4a!or
!a$$e$ to go to the conden$er6
Fig ,6? Generator
/$, WOR&ING MODEL
Fig ,6@
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"ateria# 1' 2hich the heat i$ not #ea3ed to the en4iron"ent6 B'
!ro4iding the in$u#ation( ti"e re9uired to 1oi# the 2ater i$ reduced6
The $trong $o#ution 2ou#d #o2 ro" the a1$or1er to generator 1'
gra4it' on#'6 Thu$ the a1$or1er i$ !#aced a1o4e the generator6 The
in$u#ated generator i$ !#aced in c#o$ed ca1inet6
Due to the high te"!erature in the generator( the 2ater in the $o#ution
2i## 1oi# and 4a!or i$ or"ed6 Then the 4a!or i$ co##ected at the u!!er
!art o generator( thi$ !art 2i## act a$ a rectiier6 The #i9uid "o#ecu#e$
!re$ent in the 2ater 4a!or are $e!arated 1' !ro4iding 1a#e$ in the
rectiier :u!!er !art o generator;6
Air coo#ed conden$er 2i## recei4e hot 4a!or ro" the rectiier6 A
$ing#e #at tu1e o a conden$er 2i## ha4e + tu1e$ o +"" dia"eter6
>a!or enter$ the conden$er at the to! o!ening and a##o2ed to #o26 In
thi$ conden$ation !roce$$ #atent heat o 4a!or i$ re"o4ed and the
4a!or or"$ into #i9uid6
Ater conden$ation( the rerigerant enter$ the need#e 4a#4e :e5!an$ion
de4ice;6 Thi$ e5!an$ion de4ice i$ !ro4ided at the in#et o e4a!orator6
%onden$er and e5!an$ion de4ice i$ connected through a ""
#e5i1#e !i!e6 Air conditioning o auto"o1i#e$ u$e the$e t'!e$ o tu1e$
on#'6 Thi$ thrott#ing i$ an i$entha#!ic !roce$$6 B' e5!anding( the
rerigerant !re$$ure reduce$ and the #o2 !re$$ure rerigerant enter$ the
e4a!orator6
CHAPTER 0
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CONCLUSION
Ater $tud'ing and !ractica# a1rication o 4a!or a1$or!tion $'$te"
the o##o2ing conc#u$ion can 1e "ade
To reduce the cr'$ta##i8ation eect o #ithiu" 1ro"ide( $trong
$o#ution$ $hou#d not 1e "aintained at #o2 te"!erature$6
For 1etter !eror"ance the conden$er te"!erature $hou#d 1e
"aintained in 1et2een ?+ to @-- %6
For $"a## ca!acit' a1$or!tion $'$te"$( !u"! $hou#d not 1e u$ed
in order to "aintain 4acuu" !re$$ure$6
Direct heat reco4er' i$ !reerred due to the a1$ence o
inter"ediate 2or3ing #uid6
FUTURE SCOPE
For 1etter !eror"ance o the LiBr a1$or!tion $'$te"( dou1#e eect
generation cou#d 1e u$ed6 For !ro4iding air conditioning at #o2
generator te"!erature$ 4a!or ad$or!tion $'$te" can u$ed ha4ing R)
/?@a a$ rerigerant and acti4ated car1on a$ ad$or1ent6