f)lC--I

Gr~( l V1cJ iN l fe Jshy

J2 --37

Environmental Division (ALS LvC-t-4 r CCJAY0 vCt~e 1-5t~~d

December 3 2009

Ms Kim Granzow New Mexico Environment Department DB 1183 Diamond Drive SUite B Los Alamos NM 87544

Re ALS Workorder 09-11-214 Project Name 644-111809(HWB R-37 VOCs) PAR Project Number 002731703

Dear Ms Granzow

Two water samples were received from New Mexico Environment Department DB on November 20 2009 The samples were scheduled for the following analysis

GCMS Volatiles pages 1-23

The results for this analysIs are contained in the enclosed report

Thank you for your confidence in ALS Laboratory Group Should you have any questions please calL

Sincerely

shy

ALS Laboratory Group Lance Steere Senior Project Manager

LRSmh Enclosure (s) Report and CD

ALS USA Corp 32300PM of the ALS Laborator4 Group

225 Commerce Drive Ft Collins Colorado 80524 Phone (970) 490middot1511 Fa (970) 490-1522 VJW alsenviro corn 11111111111111111111111111111111111

A Campbell amiddotwheTS Lmled CompMy

__~r~aa~~aIlItllli+middotI9Imlble~B~ --~--__

ALS Laboratory Group -- Fe

Sample Number(s) Cross-Reference Table

R-37 S~r 1-111809

New Mexico Environment Department OB 644-111809(HWB R-37 VOCs) PAR

r 002731703 06-667 -55-01754

CDC Number Matrix Date Time Collected Collected

ALS Laboratory Group -- FePage 1 of 1 Date Printed Monday November 232009

Chain of Custody Record I d- I 4 SKIP TO MAIL REPORT TO fliff9ff BILL TO

Kim Glanzow kG Oilvlgt CobrUD Dflve NMEOmiddotOOE OlefSI9hl 8lJlI~iU (51SI pound614008 New Melllco Enlfrol Dev j-Iuartlous Waste gUleltJll

fort Collins CO 8Q524 183 Diamond Orje- Surfe A 2~S Rodeo P2IriI Driv~ East Bldg 1

(9l0) 490middot1511 tos Alamos Nw Mexico S75u Santa Fe NM 8750$ 2561

kglanlowiafliQoi

~7t----1

IComments L bull ce PIase note tht VOC bullbullmplbullbullbullr not preserved with HCL~ Mmiddot elt~U 1~~

~ It I ~D ~ [11 _ ~~ ~I ~l sect

tltgtfttOt~ Project Number (Lab noice Us Dnly)

644--111809(HWB Rmiddot37 VOCsl PAR i ~ ~ ~ ~

j J~ i~ ~~1- ~1~ ~ltj ~8 g ___ ~j $ Btl_

iIt~ q s- D flt

rlN~( I ~ I itl)lJ I WiNIIC I fmA

--Lttl~ tem Nc ~l---=5SO--~ Pt1lt1 tJ(r Sample SFS 00

t~~Numbr ----NMED Sam~iro Dbull -------ITi~ --Rmiddot37 Scr 2middot11middot18middot09 11812009 _ ____ 1555+--_-+__

Imiddot~ Rmiddot37 Scr 1middot11middot18middot09 1111812009 1744=+_J-_+_+--=----__+-__f __+----_l _

HWB rnf God~ QQ27111J1

I ---------

3 46ml glU~ VOA val$ iQn~Preserved

--+--t---

-+-----~-~--~~ ----

tmiddot f +---

------------1

I ----------gt-----

-----~ --------1 1---+- ---+----+----t--~--t__

6 ) TIllaWo 01 $JfliM t 1----- _J__LJ__

Print NMEO DOE Oversiyh Bureau ~---lco 16g-J~pound[ ~~ Level Standard I i+-~ UV f_

DateTime Received By Required MS MSO BlAnk I b~Y L_- Tim~18ndord ____

1bik~0

j ~i~~Ff~6~~~~ Jq c=JPlace X in box fherbullbullrIbullbulls than 5 tolalsople for shipping costs_

Page 1 Of 1

ali containers received intact (not broken or

at samples requiring no beadspace (VOC GRO RSKfMEE Rx CNS radon) free Size of bubble lt

(a leas 113 of container required)

samples checked for and free from the presence of residual chlorine when PM has indicated sample are from a chlorinatec water source note if fIeld preservation

sodIum thiosulfate was not observed)

Were cooler temperatures measured at O1-60degC IR lun used 2

Cooler I---shy

Temperature (C) 3 ~ No of custodv seals 01 cooler 0

External ~lRJhr reading

Backgrouncl ~lRhr reading 3 i Were exemai111Uhr readllljs S rwo lim backlTCltmri nnd within DOT acceptance criterin

NO

NO

NO

NO

---1

A-S Laboratory Group - Fort Collins

CONDITION OF SAMPLE UPO) RECEIPT FOMl

Client _Nyen-M---f=D~_______ Workordet No D4 I ~ I L --~--~-----~------

Prolecl Manager __LS_____________ Initials C DI Date 1 -gt= 0- () CJ

Additionallnformatiml PHOVlDE DETAILS BElOW FOR A NO RESIONS[ TCJ ANY (JUESTION ABOV EXCEPT III Al[ 16

---------~-----

If hbilt W ru YES 0 I NA (If Ijrojcct Manager Signature I Date -----l-f---1-tl__--~~_l_4I(--2_)-lt-(_middota_I_----------

DnteTimc

in Gun 112 Oakton SN 299225[l020)middot()()66 m Cllll1li1 Oakton S~~ 2372220lOl(J002

Form 201r22xls (61109) Page 1 of i

FecEx~ US Airbill 9439 4324 BmipiennpoundUpyExpress 4a ExpressPeckageService

~ ~=~~l~h1 ~~DeJeIt1tlflrlMonallmiddot J~eSS SAilJR1JAYUI~~I_wt

n te~~~~P~afYmiddotrrursdtrj( 5tlllJlMnttw~brWIMtlIfnMlgtI1O

UU~ SATIJRDAY UfliPVIIV IS awetmc

Comoanv

__ Packages up to 1511 Js Fed StaMard Overnight [J r~~xr~~~~tnIiWJenamplUtrnoonmiddot SrumBvtIMyNtn illblt C~l3ryftM4eU(ICatlOOt~

StiJn1111 Oabwfy N~ 11lbIyen FedEx Express Saver ihfntlJUlnUtoo Sltl~ UttgtIlY Nffi 6VIIiIfble

~ fedEx 30m freroht ThnibuslnfuGS- ~YOOnlt(VNOT twll1bfI

5 Packaging ~1iDt

FedEx FadExPek FedEx Box C redEx Tuba omr ---J1fAliurIof~snDPIU~Your 1111811181 Billing Rsfarence Envelope urgtPetfIOdftdfxStltuvflt1i

Adortlss J ~

Address

City

_______~~~l--~bullbull~~--~----~~re~~~~--~------~

111111

8700 9439 4324

6 Special Handlillgand Delivery Signature Olllions

=J ~~~tr~~ ow MmINomht sx lD fnri1r

Ind~ctllnBtureC ~d=~~~-~~

~tlIII$IQfuJ~kIr ~cHIMnum

Dry Ice Dlflt~9UN11M~ ___ bull ___

L Caflo Aircraft Only

TOIBIPacbges lotlllWeight

I--r-- 1If shy ______

Tawhbiiity~JamJnldtnl100lJnlmyO(jowm~t~SurmttFodfxSMlftGIKIktl1Wit

ALS Labofaton1 Group

Environmental Division Fort Cofiins Colorado

GCMS Volatiles Case Narrative

New Mexico Environmental Department OB 644-111809(HWB R-37 VOCs) PAR -- 002731703

Work Order Number 0911214

1 This report consists of 2 water samples The samples were received cool and intact by ALS on 1120109 The vial for sample 0911214-1 contained headspace prior to analysis because it was not received headspace free into the voatiles laboratory

The samples provided for volatiles had a pH gt 2 at the time of analysis

2 These samples were prepared according to SW-846 3rd Edition procedures Specifically the water samples were prepared by purging 10 mL using purge and trap procedures based on Method 5030C

3 The samples were analyzed using GCMS with an RTX-624 RTX-VMS or equivalent capillary column according to SOP 525 Revision 14 based on SW-846 Method 8260B All positive results were quantitated against the initial calibration standards using the intemal standard technique The identification of positive results was achieved by a comparison of the retention time and mass spectrum of trle sample versus the daily calibration standard

4 All initial calibration criteria for SPCCs and CCCs were met If average response factors were used in the initial calibration RSO was 15 If linear or higher order regression calibrations were used in the initial calibration the coefficient of determination (r2) ~099

5 All initial calibrations are verified by comparing a second source standard calibration verrrication (ICV) against the calibration curve All target compounds in the second source verification had a 0 of less than 25

6 All criteria for SPCCs and CCCs were met in daily (continuing) calibration verifications (CCV)

7 Methylene chloride acetone and 2-butanone are common laboratory contaminants In order to minimize the levels of these compounds detected in the gclms analysis ALS has designated its volatile laboratory as a restricted access area In addition the laboratory has been equipped with a dedicated air intake and exhaust system that operates under positive pressure in order to

1

minimize cross contamination of these compounds Due to fluctuations in ambient laboratory conditions reported sample values for common laboratory contaminants may be due to lab contamination even if the compound in question is not detected in the associated method blankmiddot

All method blank criteria were met

8 All laboratory control sample and laboratory control sample duplicate recoveries and RPDs were within the acceptance criteria

9 Since a sample from this order number was not the selected qualITy control (QC) sample matrix specific QC results are not included in this report

10 The samples were analyzed within the established holding time

11 All surrogate recoveries were within acceptance criteria

12 All internal standard recoveries were within acceptance criteria

14 Manual integrations are performed when needed to provide consistent and defensible data following the guidelines in SOP 939 ReVision 3

The data contained in the following report have been reviewed and approved by the personnel listed below In addition ALS certifies that the analyses reported herein are true complete and correct within the limits of the methods employed

n-o3-o5Sha~JobeS Date Organics Primary Data Reviewer

l~-O 1-01TAamp1~Orga~cs Final Data Reviewer Date

2

ALS Data Qualifier Flags Chromatography and Mass Spectrometry

U or NO This flag indicates that the compound was analyzed for but not detected

J This flag indicates an estimated value This flag is used as follows (1) when estimating a concentration for tentatively identified compounds (TICs) where a 11 response is assumed (2) when the mass spectral and retention time data indicate the presence of a compound that meets the volatile and semivolatile GCMS identification criteria and the result is less than the reporting limit (RL) but greater than the method detection limit (MOL) (3) when the retention time data indicate the presence of a compound that meets the GC identification criteria and the result is less than the RL but greater than the MOL and (4) the reported value is estimated

B This flag is used when the analyte is detected in the associated method blank as well as in the sample It indicates probable blank contamination and warns the data user This flag shall be used for a tentatively identified compound (TIC) as well as for a positively identified target compound

E This flag identifies compounds whose concentration exceeds the upper level of the calibration range

A This flag indicates that a tentatively identified compound is a suspected aldol-condensation product

X This flag indicates that the analyte was diluted below an accurate quantitation level

This flag indicates that a spike recovery is equal to or outside the control criteria used

+ This flag indicates that the relative percent difference (RPO) equals or exceeds the control criteria

3

ALS Laboratory Group -- Fe Sample Number(s) Cross-Reference Table

Paragon OrderNum 0911214 Client Name New Mexico Environment Department OB

Client Project Name 644-111809(HWB R-37 VOCs) PAR Client Project Number 002731703

Client PO Number 06-667-55-01754

Client Sample Number

Lab Sample Number

COC Number Matrix Date Collected

Time Collected

R-37 Scr 2-1 11809 0911214-1 WATER 18-Nov-09 1555 R-37 Scr 1-111809 0911214-2 WATER 18-Nov-09 1744

Page 1 of 1 ALS Laboratory Group -- Fe Date Printed Wednesday December 02 2009 LlMS Version 6317 A

4

ALS Laboratory Group -- Fe

Sample Number(s) Cross-Reference Table

R-37 S~r 1-111809

New Mexico Environment Department OB 644-111809(HWB R-37 VOCs) PAR

r 002731703 06-667 -55-01754

CDC Number Matrix Date Time Collected Collected

ALS Laboratory Group -- FePage 1 of 1 Date Printed Monday November 232009

Chain of Custody Record I d- I 4 SKIP TO MAIL REPORT TO fliff9ff BILL TO

Kim Glanzow kG Oilvlgt CobrUD Dflve NMEOmiddotOOE OlefSI9hl 8lJlI~iU (51SI pound614008 New Melllco Enlfrol Dev j-Iuartlous Waste gUleltJll

fort Collins CO 8Q524 183 Diamond Orje- Surfe A 2~S Rodeo P2IriI Driv~ East Bldg 1

(9l0) 490middot1511 tos Alamos Nw Mexico S75u Santa Fe NM 8750$ 2561

kglanlowiafliQoi

~7t----1

IComments L bull ce PIase note tht VOC bullbullmplbullbullbullr not preserved with HCL~ Mmiddot elt~U 1~~

~ It I ~D ~ [11 _ ~~ ~I ~l sect

tltgtfttOt~ Project Number (Lab noice Us Dnly)

644--111809(HWB Rmiddot37 VOCsl PAR i ~ ~ ~ ~

j J~ i~ ~~1- ~1~ ~ltj ~8 g ___ ~j $ Btl_

iIt~ q s- D flt

rlN~( I ~ I itl)lJ I WiNIIC I fmA

--Lttl~ tem Nc ~l---=5SO--~ Pt1lt1 tJ(r Sample SFS 00

t~~Numbr ----NMED Sam~iro Dbull -------ITi~ --Rmiddot37 Scr 2middot11middot18middot09 11812009 _ ____ 1555+--_-+__

Imiddot~ Rmiddot37 Scr 1middot11middot18middot09 1111812009 1744=+_J-_+_+--=----__+-__f __+----_l _

HWB rnf God~ QQ27111J1

I ---------

3 46ml glU~ VOA val$ iQn~Preserved

--+--t---

-+-----~-~--~~ ----

tmiddot f +---

------------1

I ----------gt-----

-----~ --------1 1---+- ---+----+----t--~--t__

6 ) TIllaWo 01 $JfliM t 1----- _J__LJ__

Print NMEO DOE Oversiyh Bureau ~---lco 16g-J~pound[ ~~ Level Standard I i+-~ UV f_

DateTime Received By Required MS MSO BlAnk I b~Y L_- Tim~18ndord ____

1bik~0

j ~i~~Ff~6~~~~ Jq c=JPlace X in box fherbullbullrIbullbulls than 5 tolalsople for shipping costs_

Page 1 Of 1

ali containers received intact (not broken or

at samples requiring no beadspace (VOC GRO RSKfMEE Rx CNS radon) free Size of bubble lt

(a leas 113 of container required)

samples checked for and free from the presence of residual chlorine when PM has indicated sample are from a chlorinatec water source note if fIeld preservation

sodIum thiosulfate was not observed)

Were cooler temperatures measured at O1-60degC IR lun used 2

Cooler I---shy

Temperature (C) 3 ~ No of custodv seals 01 cooler 0

External ~lRJhr reading

Backgrouncl ~lRhr reading 3 i Were exemai111Uhr readllljs S rwo lim backlTCltmri nnd within DOT acceptance criterin

NO

NO

NO

NO

---1

A-S Laboratory Group - Fort Collins

CONDITION OF SAMPLE UPO) RECEIPT FOMl

Client _Nyen-M---f=D~_______ Workordet No D4 I ~ I L --~--~-----~------

Prolecl Manager __LS_____________ Initials C DI Date 1 -gt= 0- () CJ

Additionallnformatiml PHOVlDE DETAILS BElOW FOR A NO RESIONS[ TCJ ANY (JUESTION ABOV EXCEPT III Al[ 16

---------~-----

If hbilt W ru YES 0 I NA (If Ijrojcct Manager Signature I Date -----l-f---1-tl__--~~_l_4I(--2_)-lt-(_middota_I_----------

DnteTimc

in Gun 112 Oakton SN 299225[l020)middot()()66 m Cllll1li1 Oakton S~~ 2372220lOl(J002

Form 201r22xls (61109) Page 1 of i

FecEx~ US Airbill 9439 4324 BmipiennpoundUpyExpress 4a ExpressPeckageService

~ ~=~~l~h1 ~~DeJeIt1tlflrlMonallmiddot J~eSS SAilJR1JAYUI~~I_wt

n te~~~~P~afYmiddotrrursdtrj( 5tlllJlMnttw~brWIMtlIfnMlgtI1O

UU~ SATIJRDAY UfliPVIIV IS awetmc

Comoanv

__ Packages up to 1511 Js Fed StaMard Overnight [J r~~xr~~~~tnIiWJenamplUtrnoonmiddot SrumBvtIMyNtn illblt C~l3ryftM4eU(ICatlOOt~

StiJn1111 Oabwfy N~ 11lbIyen FedEx Express Saver ihfntlJUlnUtoo Sltl~ UttgtIlY Nffi 6VIIiIfble

~ fedEx 30m freroht ThnibuslnfuGS- ~YOOnlt(VNOT twll1bfI

5 Packaging ~1iDt

FedEx FadExPek FedEx Box C redEx Tuba omr ---J1fAliurIof~snDPIU~Your 1111811181 Billing Rsfarence Envelope urgtPetfIOdftdfxStltuvflt1i

Adortlss J ~

Address

City

_______~~~l--~bullbull~~--~----~~re~~~~--~------~

111111

8700 9439 4324

6 Special Handlillgand Delivery Signature Olllions

=J ~~~tr~~ ow MmINomht sx lD fnri1r

Ind~ctllnBtureC ~d=~~~-~~

~tlIII$IQfuJ~kIr ~cHIMnum

Dry Ice Dlflt~9UN11M~ ___ bull ___

L Caflo Aircraft Only

TOIBIPacbges lotlllWeight

I--r-- 1If shy ______

Tawhbiiity~JamJnldtnl100lJnlmyO(jowm~t~SurmttFodfxSMlftGIKIktl1Wit

ALS Labofaton1 Group

Environmental Division Fort Cofiins Colorado

GCMS Volatiles Case Narrative

New Mexico Environmental Department OB 644-111809(HWB R-37 VOCs) PAR -- 002731703

Work Order Number 0911214

1 This report consists of 2 water samples The samples were received cool and intact by ALS on 1120109 The vial for sample 0911214-1 contained headspace prior to analysis because it was not received headspace free into the voatiles laboratory

The samples provided for volatiles had a pH gt 2 at the time of analysis

2 These samples were prepared according to SW-846 3rd Edition procedures Specifically the water samples were prepared by purging 10 mL using purge and trap procedures based on Method 5030C

3 The samples were analyzed using GCMS with an RTX-624 RTX-VMS or equivalent capillary column according to SOP 525 Revision 14 based on SW-846 Method 8260B All positive results were quantitated against the initial calibration standards using the intemal standard technique The identification of positive results was achieved by a comparison of the retention time and mass spectrum of trle sample versus the daily calibration standard

4 All initial calibration criteria for SPCCs and CCCs were met If average response factors were used in the initial calibration RSO was 15 If linear or higher order regression calibrations were used in the initial calibration the coefficient of determination (r2) ~099

5 All initial calibrations are verified by comparing a second source standard calibration verrrication (ICV) against the calibration curve All target compounds in the second source verification had a 0 of less than 25

6 All criteria for SPCCs and CCCs were met in daily (continuing) calibration verifications (CCV)

7 Methylene chloride acetone and 2-butanone are common laboratory contaminants In order to minimize the levels of these compounds detected in the gclms analysis ALS has designated its volatile laboratory as a restricted access area In addition the laboratory has been equipped with a dedicated air intake and exhaust system that operates under positive pressure in order to

1

minimize cross contamination of these compounds Due to fluctuations in ambient laboratory conditions reported sample values for common laboratory contaminants may be due to lab contamination even if the compound in question is not detected in the associated method blankmiddot

All method blank criteria were met

8 All laboratory control sample and laboratory control sample duplicate recoveries and RPDs were within the acceptance criteria

9 Since a sample from this order number was not the selected qualITy control (QC) sample matrix specific QC results are not included in this report

10 The samples were analyzed within the established holding time

11 All surrogate recoveries were within acceptance criteria

12 All internal standard recoveries were within acceptance criteria

14 Manual integrations are performed when needed to provide consistent and defensible data following the guidelines in SOP 939 ReVision 3

The data contained in the following report have been reviewed and approved by the personnel listed below In addition ALS certifies that the analyses reported herein are true complete and correct within the limits of the methods employed

n-o3-o5Sha~JobeS Date Organics Primary Data Reviewer

l~-O 1-01TAamp1~Orga~cs Final Data Reviewer Date

2

ALS Data Qualifier Flags Chromatography and Mass Spectrometry

U or NO This flag indicates that the compound was analyzed for but not detected

J This flag indicates an estimated value This flag is used as follows (1) when estimating a concentration for tentatively identified compounds (TICs) where a 11 response is assumed (2) when the mass spectral and retention time data indicate the presence of a compound that meets the volatile and semivolatile GCMS identification criteria and the result is less than the reporting limit (RL) but greater than the method detection limit (MOL) (3) when the retention time data indicate the presence of a compound that meets the GC identification criteria and the result is less than the RL but greater than the MOL and (4) the reported value is estimated

B This flag is used when the analyte is detected in the associated method blank as well as in the sample It indicates probable blank contamination and warns the data user This flag shall be used for a tentatively identified compound (TIC) as well as for a positively identified target compound

E This flag identifies compounds whose concentration exceeds the upper level of the calibration range

A This flag indicates that a tentatively identified compound is a suspected aldol-condensation product

X This flag indicates that the analyte was diluted below an accurate quantitation level

This flag indicates that a spike recovery is equal to or outside the control criteria used

+ This flag indicates that the relative percent difference (RPO) equals or exceeds the control criteria

3

ALS Laboratory Group -- Fe Sample Number(s) Cross-Reference Table

Paragon OrderNum 0911214 Client Name New Mexico Environment Department OB

Client Project Name 644-111809(HWB R-37 VOCs) PAR Client Project Number 002731703

Client PO Number 06-667-55-01754

Client Sample Number

Lab Sample Number

COC Number Matrix Date Collected

Time Collected

R-37 Scr 2-1 11809 0911214-1 WATER 18-Nov-09 1555 R-37 Scr 1-111809 0911214-2 WATER 18-Nov-09 1744

Page 1 of 1 ALS Laboratory Group -- Fe Date Printed Wednesday December 02 2009 LlMS Version 6317 A

4

Chain of Custody Record I d- I 4 SKIP TO MAIL REPORT TO fliff9ff BILL TO

Kim Glanzow kG Oilvlgt CobrUD Dflve NMEOmiddotOOE OlefSI9hl 8lJlI~iU (51SI pound614008 New Melllco Enlfrol Dev j-Iuartlous Waste gUleltJll

fort Collins CO 8Q524 183 Diamond Orje- Surfe A 2~S Rodeo P2IriI Driv~ East Bldg 1

(9l0) 490middot1511 tos Alamos Nw Mexico S75u Santa Fe NM 8750$ 2561

kglanlowiafliQoi

~7t----1

IComments L bull ce PIase note tht VOC bullbullmplbullbullbullr not preserved with HCL~ Mmiddot elt~U 1~~

~ It I ~D ~ [11 _ ~~ ~I ~l sect

tltgtfttOt~ Project Number (Lab noice Us Dnly)

644--111809(HWB Rmiddot37 VOCsl PAR i ~ ~ ~ ~

j J~ i~ ~~1- ~1~ ~ltj ~8 g ___ ~j $ Btl_

iIt~ q s- D flt

rlN~( I ~ I itl)lJ I WiNIIC I fmA

--Lttl~ tem Nc ~l---=5SO--~ Pt1lt1 tJ(r Sample SFS 00

t~~Numbr ----NMED Sam~iro Dbull -------ITi~ --Rmiddot37 Scr 2middot11middot18middot09 11812009 _ ____ 1555+--_-+__

Imiddot~ Rmiddot37 Scr 1middot11middot18middot09 1111812009 1744=+_J-_+_+--=----__+-__f __+----_l _

HWB rnf God~ QQ27111J1

I ---------

3 46ml glU~ VOA val$ iQn~Preserved

--+--t---

-+-----~-~--~~ ----

tmiddot f +---

------------1

I ----------gt-----

-----~ --------1 1---+- ---+----+----t--~--t__

6 ) TIllaWo 01 $JfliM t 1----- _J__LJ__

Print NMEO DOE Oversiyh Bureau ~---lco 16g-J~pound[ ~~ Level Standard I i+-~ UV f_

DateTime Received By Required MS MSO BlAnk I b~Y L_- Tim~18ndord ____

1bik~0

j ~i~~Ff~6~~~~ Jq c=JPlace X in box fherbullbullrIbullbulls than 5 tolalsople for shipping costs_

Page 1 Of 1

ali containers received intact (not broken or

at samples requiring no beadspace (VOC GRO RSKfMEE Rx CNS radon) free Size of bubble lt

(a leas 113 of container required)

samples checked for and free from the presence of residual chlorine when PM has indicated sample are from a chlorinatec water source note if fIeld preservation

sodIum thiosulfate was not observed)

Were cooler temperatures measured at O1-60degC IR lun used 2

Cooler I---shy

Temperature (C) 3 ~ No of custodv seals 01 cooler 0

External ~lRJhr reading

Backgrouncl ~lRhr reading 3 i Were exemai111Uhr readllljs S rwo lim backlTCltmri nnd within DOT acceptance criterin

NO

NO

NO

NO

---1

A-S Laboratory Group - Fort Collins

CONDITION OF SAMPLE UPO) RECEIPT FOMl

Client _Nyen-M---f=D~_______ Workordet No D4 I ~ I L --~--~-----~------

Prolecl Manager __LS_____________ Initials C DI Date 1 -gt= 0- () CJ

Additionallnformatiml PHOVlDE DETAILS BElOW FOR A NO RESIONS[ TCJ ANY (JUESTION ABOV EXCEPT III Al[ 16

---------~-----

If hbilt W ru YES 0 I NA (If Ijrojcct Manager Signature I Date -----l-f---1-tl__--~~_l_4I(--2_)-lt-(_middota_I_----------

DnteTimc

in Gun 112 Oakton SN 299225[l020)middot()()66 m Cllll1li1 Oakton S~~ 2372220lOl(J002

Form 201r22xls (61109) Page 1 of i

FecEx~ US Airbill 9439 4324 BmipiennpoundUpyExpress 4a ExpressPeckageService

~ ~=~~l~h1 ~~DeJeIt1tlflrlMonallmiddot J~eSS SAilJR1JAYUI~~I_wt

n te~~~~P~afYmiddotrrursdtrj( 5tlllJlMnttw~brWIMtlIfnMlgtI1O

UU~ SATIJRDAY UfliPVIIV IS awetmc

Comoanv

__ Packages up to 1511 Js Fed StaMard Overnight [J r~~xr~~~~tnIiWJenamplUtrnoonmiddot SrumBvtIMyNtn illblt C~l3ryftM4eU(ICatlOOt~

StiJn1111 Oabwfy N~ 11lbIyen FedEx Express Saver ihfntlJUlnUtoo Sltl~ UttgtIlY Nffi 6VIIiIfble

~ fedEx 30m freroht ThnibuslnfuGS- ~YOOnlt(VNOT twll1bfI

5 Packaging ~1iDt

FedEx FadExPek FedEx Box C redEx Tuba omr ---J1fAliurIof~snDPIU~Your 1111811181 Billing Rsfarence Envelope urgtPetfIOdftdfxStltuvflt1i

Adortlss J ~

Address

City

_______~~~l--~bullbull~~--~----~~re~~~~--~------~

111111

8700 9439 4324

6 Special Handlillgand Delivery Signature Olllions

=J ~~~tr~~ ow MmINomht sx lD fnri1r

Ind~ctllnBtureC ~d=~~~-~~

~tlIII$IQfuJ~kIr ~cHIMnum

Dry Ice Dlflt~9UN11M~ ___ bull ___

L Caflo Aircraft Only

TOIBIPacbges lotlllWeight

I--r-- 1If shy ______

Tawhbiiity~JamJnldtnl100lJnlmyO(jowm~t~SurmttFodfxSMlftGIKIktl1Wit

ALS Labofaton1 Group

Environmental Division Fort Cofiins Colorado

GCMS Volatiles Case Narrative

New Mexico Environmental Department OB 644-111809(HWB R-37 VOCs) PAR -- 002731703

Work Order Number 0911214

1 This report consists of 2 water samples The samples were received cool and intact by ALS on 1120109 The vial for sample 0911214-1 contained headspace prior to analysis because it was not received headspace free into the voatiles laboratory

The samples provided for volatiles had a pH gt 2 at the time of analysis

2 These samples were prepared according to SW-846 3rd Edition procedures Specifically the water samples were prepared by purging 10 mL using purge and trap procedures based on Method 5030C

3 The samples were analyzed using GCMS with an RTX-624 RTX-VMS or equivalent capillary column according to SOP 525 Revision 14 based on SW-846 Method 8260B All positive results were quantitated against the initial calibration standards using the intemal standard technique The identification of positive results was achieved by a comparison of the retention time and mass spectrum of trle sample versus the daily calibration standard

4 All initial calibration criteria for SPCCs and CCCs were met If average response factors were used in the initial calibration RSO was 15 If linear or higher order regression calibrations were used in the initial calibration the coefficient of determination (r2) ~099

5 All initial calibrations are verified by comparing a second source standard calibration verrrication (ICV) against the calibration curve All target compounds in the second source verification had a 0 of less than 25

6 All criteria for SPCCs and CCCs were met in daily (continuing) calibration verifications (CCV)

7 Methylene chloride acetone and 2-butanone are common laboratory contaminants In order to minimize the levels of these compounds detected in the gclms analysis ALS has designated its volatile laboratory as a restricted access area In addition the laboratory has been equipped with a dedicated air intake and exhaust system that operates under positive pressure in order to

1

minimize cross contamination of these compounds Due to fluctuations in ambient laboratory conditions reported sample values for common laboratory contaminants may be due to lab contamination even if the compound in question is not detected in the associated method blankmiddot

All method blank criteria were met

8 All laboratory control sample and laboratory control sample duplicate recoveries and RPDs were within the acceptance criteria

9 Since a sample from this order number was not the selected qualITy control (QC) sample matrix specific QC results are not included in this report

10 The samples were analyzed within the established holding time

11 All surrogate recoveries were within acceptance criteria

12 All internal standard recoveries were within acceptance criteria

14 Manual integrations are performed when needed to provide consistent and defensible data following the guidelines in SOP 939 ReVision 3

The data contained in the following report have been reviewed and approved by the personnel listed below In addition ALS certifies that the analyses reported herein are true complete and correct within the limits of the methods employed

n-o3-o5Sha~JobeS Date Organics Primary Data Reviewer

l~-O 1-01TAamp1~Orga~cs Final Data Reviewer Date

2

ALS Data Qualifier Flags Chromatography and Mass Spectrometry

U or NO This flag indicates that the compound was analyzed for but not detected

J This flag indicates an estimated value This flag is used as follows (1) when estimating a concentration for tentatively identified compounds (TICs) where a 11 response is assumed (2) when the mass spectral and retention time data indicate the presence of a compound that meets the volatile and semivolatile GCMS identification criteria and the result is less than the reporting limit (RL) but greater than the method detection limit (MOL) (3) when the retention time data indicate the presence of a compound that meets the GC identification criteria and the result is less than the RL but greater than the MOL and (4) the reported value is estimated

B This flag is used when the analyte is detected in the associated method blank as well as in the sample It indicates probable blank contamination and warns the data user This flag shall be used for a tentatively identified compound (TIC) as well as for a positively identified target compound

E This flag identifies compounds whose concentration exceeds the upper level of the calibration range

A This flag indicates that a tentatively identified compound is a suspected aldol-condensation product

X This flag indicates that the analyte was diluted below an accurate quantitation level

This flag indicates that a spike recovery is equal to or outside the control criteria used

+ This flag indicates that the relative percent difference (RPO) equals or exceeds the control criteria

3

ALS Laboratory Group -- Fe Sample Number(s) Cross-Reference Table

Paragon OrderNum 0911214 Client Name New Mexico Environment Department OB

Client Project Name 644-111809(HWB R-37 VOCs) PAR Client Project Number 002731703

Client PO Number 06-667-55-01754

Client Sample Number

Lab Sample Number

COC Number Matrix Date Collected

Time Collected

R-37 Scr 2-1 11809 0911214-1 WATER 18-Nov-09 1555 R-37 Scr 1-111809 0911214-2 WATER 18-Nov-09 1744

Page 1 of 1 ALS Laboratory Group -- Fe Date Printed Wednesday December 02 2009 LlMS Version 6317 A

4

ali containers received intact (not broken or

at samples requiring no beadspace (VOC GRO RSKfMEE Rx CNS radon) free Size of bubble lt

(a leas 113 of container required)

samples checked for and free from the presence of residual chlorine when PM has indicated sample are from a chlorinatec water source note if fIeld preservation

sodIum thiosulfate was not observed)

Were cooler temperatures measured at O1-60degC IR lun used 2

Cooler I---shy

Temperature (C) 3 ~ No of custodv seals 01 cooler 0

External ~lRJhr reading

Backgrouncl ~lRhr reading 3 i Were exemai111Uhr readllljs S rwo lim backlTCltmri nnd within DOT acceptance criterin

NO

NO

NO

NO

---1

A-S Laboratory Group - Fort Collins

CONDITION OF SAMPLE UPO) RECEIPT FOMl

Client _Nyen-M---f=D~_______ Workordet No D4 I ~ I L --~--~-----~------

Prolecl Manager __LS_____________ Initials C DI Date 1 -gt= 0- () CJ

Additionallnformatiml PHOVlDE DETAILS BElOW FOR A NO RESIONS[ TCJ ANY (JUESTION ABOV EXCEPT III Al[ 16

---------~-----

If hbilt W ru YES 0 I NA (If Ijrojcct Manager Signature I Date -----l-f---1-tl__--~~_l_4I(--2_)-lt-(_middota_I_----------

DnteTimc

in Gun 112 Oakton SN 299225[l020)middot()()66 m Cllll1li1 Oakton S~~ 2372220lOl(J002

Form 201r22xls (61109) Page 1 of i

FecEx~ US Airbill 9439 4324 BmipiennpoundUpyExpress 4a ExpressPeckageService

~ ~=~~l~h1 ~~DeJeIt1tlflrlMonallmiddot J~eSS SAilJR1JAYUI~~I_wt

n te~~~~P~afYmiddotrrursdtrj( 5tlllJlMnttw~brWIMtlIfnMlgtI1O

UU~ SATIJRDAY UfliPVIIV IS awetmc

Comoanv

__ Packages up to 1511 Js Fed StaMard Overnight [J r~~xr~~~~tnIiWJenamplUtrnoonmiddot SrumBvtIMyNtn illblt C~l3ryftM4eU(ICatlOOt~

StiJn1111 Oabwfy N~ 11lbIyen FedEx Express Saver ihfntlJUlnUtoo Sltl~ UttgtIlY Nffi 6VIIiIfble

~ fedEx 30m freroht ThnibuslnfuGS- ~YOOnlt(VNOT twll1bfI

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FedEx FadExPek FedEx Box C redEx Tuba omr ---J1fAliurIof~snDPIU~Your 1111811181 Billing Rsfarence Envelope urgtPetfIOdftdfxStltuvflt1i

Adortlss J ~

Address

City

_______~~~l--~bullbull~~--~----~~re~~~~--~------~

111111

8700 9439 4324

6 Special Handlillgand Delivery Signature Olllions

=J ~~~tr~~ ow MmINomht sx lD fnri1r

Ind~ctllnBtureC ~d=~~~-~~

~tlIII$IQfuJ~kIr ~cHIMnum

Dry Ice Dlflt~9UN11M~ ___ bull ___

L Caflo Aircraft Only

TOIBIPacbges lotlllWeight

I--r-- 1If shy ______

Tawhbiiity~JamJnldtnl100lJnlmyO(jowm~t~SurmttFodfxSMlftGIKIktl1Wit

ALS Labofaton1 Group

Environmental Division Fort Cofiins Colorado

GCMS Volatiles Case Narrative

New Mexico Environmental Department OB 644-111809(HWB R-37 VOCs) PAR -- 002731703

Work Order Number 0911214

1 This report consists of 2 water samples The samples were received cool and intact by ALS on 1120109 The vial for sample 0911214-1 contained headspace prior to analysis because it was not received headspace free into the voatiles laboratory

The samples provided for volatiles had a pH gt 2 at the time of analysis

2 These samples were prepared according to SW-846 3rd Edition procedures Specifically the water samples were prepared by purging 10 mL using purge and trap procedures based on Method 5030C

3 The samples were analyzed using GCMS with an RTX-624 RTX-VMS or equivalent capillary column according to SOP 525 Revision 14 based on SW-846 Method 8260B All positive results were quantitated against the initial calibration standards using the intemal standard technique The identification of positive results was achieved by a comparison of the retention time and mass spectrum of trle sample versus the daily calibration standard

4 All initial calibration criteria for SPCCs and CCCs were met If average response factors were used in the initial calibration RSO was 15 If linear or higher order regression calibrations were used in the initial calibration the coefficient of determination (r2) ~099

5 All initial calibrations are verified by comparing a second source standard calibration verrrication (ICV) against the calibration curve All target compounds in the second source verification had a 0 of less than 25

6 All criteria for SPCCs and CCCs were met in daily (continuing) calibration verifications (CCV)

7 Methylene chloride acetone and 2-butanone are common laboratory contaminants In order to minimize the levels of these compounds detected in the gclms analysis ALS has designated its volatile laboratory as a restricted access area In addition the laboratory has been equipped with a dedicated air intake and exhaust system that operates under positive pressure in order to

1

minimize cross contamination of these compounds Due to fluctuations in ambient laboratory conditions reported sample values for common laboratory contaminants may be due to lab contamination even if the compound in question is not detected in the associated method blankmiddot

All method blank criteria were met

8 All laboratory control sample and laboratory control sample duplicate recoveries and RPDs were within the acceptance criteria

9 Since a sample from this order number was not the selected qualITy control (QC) sample matrix specific QC results are not included in this report

10 The samples were analyzed within the established holding time

11 All surrogate recoveries were within acceptance criteria

12 All internal standard recoveries were within acceptance criteria

14 Manual integrations are performed when needed to provide consistent and defensible data following the guidelines in SOP 939 ReVision 3

The data contained in the following report have been reviewed and approved by the personnel listed below In addition ALS certifies that the analyses reported herein are true complete and correct within the limits of the methods employed

n-o3-o5Sha~JobeS Date Organics Primary Data Reviewer

l~-O 1-01TAamp1~Orga~cs Final Data Reviewer Date

2

ALS Data Qualifier Flags Chromatography and Mass Spectrometry

U or NO This flag indicates that the compound was analyzed for but not detected

J This flag indicates an estimated value This flag is used as follows (1) when estimating a concentration for tentatively identified compounds (TICs) where a 11 response is assumed (2) when the mass spectral and retention time data indicate the presence of a compound that meets the volatile and semivolatile GCMS identification criteria and the result is less than the reporting limit (RL) but greater than the method detection limit (MOL) (3) when the retention time data indicate the presence of a compound that meets the GC identification criteria and the result is less than the RL but greater than the MOL and (4) the reported value is estimated

B This flag is used when the analyte is detected in the associated method blank as well as in the sample It indicates probable blank contamination and warns the data user This flag shall be used for a tentatively identified compound (TIC) as well as for a positively identified target compound

E This flag identifies compounds whose concentration exceeds the upper level of the calibration range

A This flag indicates that a tentatively identified compound is a suspected aldol-condensation product

X This flag indicates that the analyte was diluted below an accurate quantitation level

This flag indicates that a spike recovery is equal to or outside the control criteria used

+ This flag indicates that the relative percent difference (RPO) equals or exceeds the control criteria

3

ALS Laboratory Group -- Fe Sample Number(s) Cross-Reference Table

Paragon OrderNum 0911214 Client Name New Mexico Environment Department OB

Client Project Name 644-111809(HWB R-37 VOCs) PAR Client Project Number 002731703

Client PO Number 06-667-55-01754

Client Sample Number

Lab Sample Number

COC Number Matrix Date Collected

Time Collected

R-37 Scr 2-1 11809 0911214-1 WATER 18-Nov-09 1555 R-37 Scr 1-111809 0911214-2 WATER 18-Nov-09 1744

Page 1 of 1 ALS Laboratory Group -- Fe Date Printed Wednesday December 02 2009 LlMS Version 6317 A

4

FecEx~ US Airbill 9439 4324 BmipiennpoundUpyExpress 4a ExpressPeckageService

~ ~=~~l~h1 ~~DeJeIt1tlflrlMonallmiddot J~eSS SAilJR1JAYUI~~I_wt

n te~~~~P~afYmiddotrrursdtrj( 5tlllJlMnttw~brWIMtlIfnMlgtI1O

UU~ SATIJRDAY UfliPVIIV IS awetmc

Comoanv

__ Packages up to 1511 Js Fed StaMard Overnight [J r~~xr~~~~tnIiWJenamplUtrnoonmiddot SrumBvtIMyNtn illblt C~l3ryftM4eU(ICatlOOt~

StiJn1111 Oabwfy N~ 11lbIyen FedEx Express Saver ihfntlJUlnUtoo Sltl~ UttgtIlY Nffi 6VIIiIfble

~ fedEx 30m freroht ThnibuslnfuGS- ~YOOnlt(VNOT twll1bfI

5 Packaging ~1iDt

FedEx FadExPek FedEx Box C redEx Tuba omr ---J1fAliurIof~snDPIU~Your 1111811181 Billing Rsfarence Envelope urgtPetfIOdftdfxStltuvflt1i

Adortlss J ~

Address

City

_______~~~l--~bullbull~~--~----~~re~~~~--~------~

111111

8700 9439 4324

6 Special Handlillgand Delivery Signature Olllions

=J ~~~tr~~ ow MmINomht sx lD fnri1r

Ind~ctllnBtureC ~d=~~~-~~

~tlIII$IQfuJ~kIr ~cHIMnum

Dry Ice Dlflt~9UN11M~ ___ bull ___

L Caflo Aircraft Only

TOIBIPacbges lotlllWeight

I--r-- 1If shy ______

Tawhbiiity~JamJnldtnl100lJnlmyO(jowm~t~SurmttFodfxSMlftGIKIktl1Wit

ALS Labofaton1 Group

Environmental Division Fort Cofiins Colorado

GCMS Volatiles Case Narrative

New Mexico Environmental Department OB 644-111809(HWB R-37 VOCs) PAR -- 002731703

Work Order Number 0911214

1 This report consists of 2 water samples The samples were received cool and intact by ALS on 1120109 The vial for sample 0911214-1 contained headspace prior to analysis because it was not received headspace free into the voatiles laboratory

The samples provided for volatiles had a pH gt 2 at the time of analysis

2 These samples were prepared according to SW-846 3rd Edition procedures Specifically the water samples were prepared by purging 10 mL using purge and trap procedures based on Method 5030C

3 The samples were analyzed using GCMS with an RTX-624 RTX-VMS or equivalent capillary column according to SOP 525 Revision 14 based on SW-846 Method 8260B All positive results were quantitated against the initial calibration standards using the intemal standard technique The identification of positive results was achieved by a comparison of the retention time and mass spectrum of trle sample versus the daily calibration standard

4 All initial calibration criteria for SPCCs and CCCs were met If average response factors were used in the initial calibration RSO was 15 If linear or higher order regression calibrations were used in the initial calibration the coefficient of determination (r2) ~099

5 All initial calibrations are verified by comparing a second source standard calibration verrrication (ICV) against the calibration curve All target compounds in the second source verification had a 0 of less than 25

6 All criteria for SPCCs and CCCs were met in daily (continuing) calibration verifications (CCV)

7 Methylene chloride acetone and 2-butanone are common laboratory contaminants In order to minimize the levels of these compounds detected in the gclms analysis ALS has designated its volatile laboratory as a restricted access area In addition the laboratory has been equipped with a dedicated air intake and exhaust system that operates under positive pressure in order to

1

minimize cross contamination of these compounds Due to fluctuations in ambient laboratory conditions reported sample values for common laboratory contaminants may be due to lab contamination even if the compound in question is not detected in the associated method blankmiddot

All method blank criteria were met

8 All laboratory control sample and laboratory control sample duplicate recoveries and RPDs were within the acceptance criteria

9 Since a sample from this order number was not the selected qualITy control (QC) sample matrix specific QC results are not included in this report

10 The samples were analyzed within the established holding time

11 All surrogate recoveries were within acceptance criteria

12 All internal standard recoveries were within acceptance criteria

14 Manual integrations are performed when needed to provide consistent and defensible data following the guidelines in SOP 939 ReVision 3

The data contained in the following report have been reviewed and approved by the personnel listed below In addition ALS certifies that the analyses reported herein are true complete and correct within the limits of the methods employed

n-o3-o5Sha~JobeS Date Organics Primary Data Reviewer

l~-O 1-01TAamp1~Orga~cs Final Data Reviewer Date

2

ALS Data Qualifier Flags Chromatography and Mass Spectrometry

U or NO This flag indicates that the compound was analyzed for but not detected

J This flag indicates an estimated value This flag is used as follows (1) when estimating a concentration for tentatively identified compounds (TICs) where a 11 response is assumed (2) when the mass spectral and retention time data indicate the presence of a compound that meets the volatile and semivolatile GCMS identification criteria and the result is less than the reporting limit (RL) but greater than the method detection limit (MOL) (3) when the retention time data indicate the presence of a compound that meets the GC identification criteria and the result is less than the RL but greater than the MOL and (4) the reported value is estimated

B This flag is used when the analyte is detected in the associated method blank as well as in the sample It indicates probable blank contamination and warns the data user This flag shall be used for a tentatively identified compound (TIC) as well as for a positively identified target compound

E This flag identifies compounds whose concentration exceeds the upper level of the calibration range

A This flag indicates that a tentatively identified compound is a suspected aldol-condensation product

X This flag indicates that the analyte was diluted below an accurate quantitation level

This flag indicates that a spike recovery is equal to or outside the control criteria used

+ This flag indicates that the relative percent difference (RPO) equals or exceeds the control criteria

3

ALS Laboratory Group -- Fe Sample Number(s) Cross-Reference Table

Paragon OrderNum 0911214 Client Name New Mexico Environment Department OB

Client Project Name 644-111809(HWB R-37 VOCs) PAR Client Project Number 002731703

Client PO Number 06-667-55-01754

Client Sample Number

Lab Sample Number

COC Number Matrix Date Collected

Time Collected

R-37 Scr 2-1 11809 0911214-1 WATER 18-Nov-09 1555 R-37 Scr 1-111809 0911214-2 WATER 18-Nov-09 1744

Page 1 of 1 ALS Laboratory Group -- Fe Date Printed Wednesday December 02 2009 LlMS Version 6317 A

4

ALS Labofaton1 Group

Environmental Division Fort Cofiins Colorado

GCMS Volatiles Case Narrative

New Mexico Environmental Department OB 644-111809(HWB R-37 VOCs) PAR -- 002731703

Work Order Number 0911214

1 This report consists of 2 water samples The samples were received cool and intact by ALS on 1120109 The vial for sample 0911214-1 contained headspace prior to analysis because it was not received headspace free into the voatiles laboratory

The samples provided for volatiles had a pH gt 2 at the time of analysis

2 These samples were prepared according to SW-846 3rd Edition procedures Specifically the water samples were prepared by purging 10 mL using purge and trap procedures based on Method 5030C

3 The samples were analyzed using GCMS with an RTX-624 RTX-VMS or equivalent capillary column according to SOP 525 Revision 14 based on SW-846 Method 8260B All positive results were quantitated against the initial calibration standards using the intemal standard technique The identification of positive results was achieved by a comparison of the retention time and mass spectrum of trle sample versus the daily calibration standard

4 All initial calibration criteria for SPCCs and CCCs were met If average response factors were used in the initial calibration RSO was 15 If linear or higher order regression calibrations were used in the initial calibration the coefficient of determination (r2) ~099

5 All initial calibrations are verified by comparing a second source standard calibration verrrication (ICV) against the calibration curve All target compounds in the second source verification had a 0 of less than 25

6 All criteria for SPCCs and CCCs were met in daily (continuing) calibration verifications (CCV)

7 Methylene chloride acetone and 2-butanone are common laboratory contaminants In order to minimize the levels of these compounds detected in the gclms analysis ALS has designated its volatile laboratory as a restricted access area In addition the laboratory has been equipped with a dedicated air intake and exhaust system that operates under positive pressure in order to

1

minimize cross contamination of these compounds Due to fluctuations in ambient laboratory conditions reported sample values for common laboratory contaminants may be due to lab contamination even if the compound in question is not detected in the associated method blankmiddot

All method blank criteria were met

8 All laboratory control sample and laboratory control sample duplicate recoveries and RPDs were within the acceptance criteria

9 Since a sample from this order number was not the selected qualITy control (QC) sample matrix specific QC results are not included in this report

10 The samples were analyzed within the established holding time

11 All surrogate recoveries were within acceptance criteria

12 All internal standard recoveries were within acceptance criteria

14 Manual integrations are performed when needed to provide consistent and defensible data following the guidelines in SOP 939 ReVision 3

The data contained in the following report have been reviewed and approved by the personnel listed below In addition ALS certifies that the analyses reported herein are true complete and correct within the limits of the methods employed

n-o3-o5Sha~JobeS Date Organics Primary Data Reviewer

l~-O 1-01TAamp1~Orga~cs Final Data Reviewer Date

2

ALS Data Qualifier Flags Chromatography and Mass Spectrometry

U or NO This flag indicates that the compound was analyzed for but not detected

J This flag indicates an estimated value This flag is used as follows (1) when estimating a concentration for tentatively identified compounds (TICs) where a 11 response is assumed (2) when the mass spectral and retention time data indicate the presence of a compound that meets the volatile and semivolatile GCMS identification criteria and the result is less than the reporting limit (RL) but greater than the method detection limit (MOL) (3) when the retention time data indicate the presence of a compound that meets the GC identification criteria and the result is less than the RL but greater than the MOL and (4) the reported value is estimated

B This flag is used when the analyte is detected in the associated method blank as well as in the sample It indicates probable blank contamination and warns the data user This flag shall be used for a tentatively identified compound (TIC) as well as for a positively identified target compound

E This flag identifies compounds whose concentration exceeds the upper level of the calibration range

A This flag indicates that a tentatively identified compound is a suspected aldol-condensation product

X This flag indicates that the analyte was diluted below an accurate quantitation level

This flag indicates that a spike recovery is equal to or outside the control criteria used

+ This flag indicates that the relative percent difference (RPO) equals or exceeds the control criteria

3

ALS Laboratory Group -- Fe Sample Number(s) Cross-Reference Table

Paragon OrderNum 0911214 Client Name New Mexico Environment Department OB

Client Project Name 644-111809(HWB R-37 VOCs) PAR Client Project Number 002731703

Client PO Number 06-667-55-01754

Client Sample Number

Lab Sample Number

COC Number Matrix Date Collected

Time Collected

R-37 Scr 2-1 11809 0911214-1 WATER 18-Nov-09 1555 R-37 Scr 1-111809 0911214-2 WATER 18-Nov-09 1744

Page 1 of 1 ALS Laboratory Group -- Fe Date Printed Wednesday December 02 2009 LlMS Version 6317 A

4

minimize cross contamination of these compounds Due to fluctuations in ambient laboratory conditions reported sample values for common laboratory contaminants may be due to lab contamination even if the compound in question is not detected in the associated method blankmiddot

All method blank criteria were met

8 All laboratory control sample and laboratory control sample duplicate recoveries and RPDs were within the acceptance criteria

9 Since a sample from this order number was not the selected qualITy control (QC) sample matrix specific QC results are not included in this report

10 The samples were analyzed within the established holding time

11 All surrogate recoveries were within acceptance criteria

12 All internal standard recoveries were within acceptance criteria

14 Manual integrations are performed when needed to provide consistent and defensible data following the guidelines in SOP 939 ReVision 3

The data contained in the following report have been reviewed and approved by the personnel listed below In addition ALS certifies that the analyses reported herein are true complete and correct within the limits of the methods employed

n-o3-o5Sha~JobeS Date Organics Primary Data Reviewer

l~-O 1-01TAamp1~Orga~cs Final Data Reviewer Date

2

ALS Data Qualifier Flags Chromatography and Mass Spectrometry

U or NO This flag indicates that the compound was analyzed for but not detected

J This flag indicates an estimated value This flag is used as follows (1) when estimating a concentration for tentatively identified compounds (TICs) where a 11 response is assumed (2) when the mass spectral and retention time data indicate the presence of a compound that meets the volatile and semivolatile GCMS identification criteria and the result is less than the reporting limit (RL) but greater than the method detection limit (MOL) (3) when the retention time data indicate the presence of a compound that meets the GC identification criteria and the result is less than the RL but greater than the MOL and (4) the reported value is estimated

B This flag is used when the analyte is detected in the associated method blank as well as in the sample It indicates probable blank contamination and warns the data user This flag shall be used for a tentatively identified compound (TIC) as well as for a positively identified target compound

E This flag identifies compounds whose concentration exceeds the upper level of the calibration range

A This flag indicates that a tentatively identified compound is a suspected aldol-condensation product

X This flag indicates that the analyte was diluted below an accurate quantitation level

This flag indicates that a spike recovery is equal to or outside the control criteria used

+ This flag indicates that the relative percent difference (RPO) equals or exceeds the control criteria

3

ALS Laboratory Group -- Fe Sample Number(s) Cross-Reference Table

Paragon OrderNum 0911214 Client Name New Mexico Environment Department OB

Client Project Name 644-111809(HWB R-37 VOCs) PAR Client Project Number 002731703

Client PO Number 06-667-55-01754

Client Sample Number

Lab Sample Number

COC Number Matrix Date Collected

Time Collected

R-37 Scr 2-1 11809 0911214-1 WATER 18-Nov-09 1555 R-37 Scr 1-111809 0911214-2 WATER 18-Nov-09 1744

Page 1 of 1 ALS Laboratory Group -- Fe Date Printed Wednesday December 02 2009 LlMS Version 6317 A

4

ALS Data Qualifier Flags Chromatography and Mass Spectrometry

U or NO This flag indicates that the compound was analyzed for but not detected

J This flag indicates an estimated value This flag is used as follows (1) when estimating a concentration for tentatively identified compounds (TICs) where a 11 response is assumed (2) when the mass spectral and retention time data indicate the presence of a compound that meets the volatile and semivolatile GCMS identification criteria and the result is less than the reporting limit (RL) but greater than the method detection limit (MOL) (3) when the retention time data indicate the presence of a compound that meets the GC identification criteria and the result is less than the RL but greater than the MOL and (4) the reported value is estimated

B This flag is used when the analyte is detected in the associated method blank as well as in the sample It indicates probable blank contamination and warns the data user This flag shall be used for a tentatively identified compound (TIC) as well as for a positively identified target compound

E This flag identifies compounds whose concentration exceeds the upper level of the calibration range

A This flag indicates that a tentatively identified compound is a suspected aldol-condensation product

X This flag indicates that the analyte was diluted below an accurate quantitation level

This flag indicates that a spike recovery is equal to or outside the control criteria used

+ This flag indicates that the relative percent difference (RPO) equals or exceeds the control criteria

3

ALS Laboratory Group -- Fe Sample Number(s) Cross-Reference Table

Paragon OrderNum 0911214 Client Name New Mexico Environment Department OB

Client Project Name 644-111809(HWB R-37 VOCs) PAR Client Project Number 002731703

Client PO Number 06-667-55-01754

Client Sample Number

Lab Sample Number

COC Number Matrix Date Collected

Time Collected

R-37 Scr 2-1 11809 0911214-1 WATER 18-Nov-09 1555 R-37 Scr 1-111809 0911214-2 WATER 18-Nov-09 1744

Page 1 of 1 ALS Laboratory Group -- Fe Date Printed Wednesday December 02 2009 LlMS Version 6317 A

4

ALS Laboratory Group -- Fe Sample Number(s) Cross-Reference Table

Paragon OrderNum 0911214 Client Name New Mexico Environment Department OB

Client Project Name 644-111809(HWB R-37 VOCs) PAR Client Project Number 002731703

Client PO Number 06-667-55-01754

Client Sample Number

Lab Sample Number

COC Number Matrix Date Collected

Time Collected

R-37 Scr 2-1 11809 0911214-1 WATER 18-Nov-09 1555 R-37 Scr 1-111809 0911214-2 WATER 18-Nov-09 1744

Page 1 of 1 ALS Laboratory Group -- Fe Date Printed Wednesday December 02 2009 LlMS Version 6317 A

4

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cI yl iComments Lanc~v fiias not~ that foe samples life not preg~-d with HCL bull

~ 4_~~~~S5 V~~~Vi~I_$ ~~~~5s~rvd __

3 4()ml glau VOA vials Non-PrlttIrv~d -----~--

OC Level Standard f 0~Y ~-t-~ (fv f_ QC Required MS MSD Bla~k

irU11 Around TieJTAT) ~_dbullr_d__~______

cJPlace X In bOK If there are less than 5 lotal sample for shipping cosls

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---- ---- ---

ALS Laboratory GrouP - Fort Collins

CONDITIO] OF SAMPLE UPO) RECEIPT FORM

Client _-=-N--M---f-=-D________ IVorkorde No D4 J I 4 --~~~~~~------

PrO1 cc Manager L 5 lnitiais C D Date 1 -) ()- () C --~~~---------------------

1 there a cae Are the coe and bottle labels

Is the coe in agreement with samples received) of containers matrix requested anaiyses etc)

documents presen1 andor removable)

Are all aqueous samples requiring preservation preserved correctly ~- ----~-~~--- -~ -~-- ----~~~---------

volatiles)

14 Are all samples requiring no headspace (VOC GRG RSKlVIEE lb eNS radon)

free Size of bubble lt

$ Do perchlorate LCMS-MS samples have headspace (a~ least ]3 of container required)

NO

]6 Were samples checked for and free from the presence of residual chlorine (Appiicaole when PM has Indicated samples are from a chlonnated wat~ source note if field preservallor

witb sodIUm tlllosulfate wa not observed)

17 Were the lljIV~IOU on ice

IS Were cooler temperatures measured at 01-60degC IR ~Illl used 2

Coole I---

Temperature (C) 3 ~

NO

NO

NO

NO

NO

NO

NO

No of custodv seals Ol~ cooler 0 OOT ---- --- --- --l Surveyl EXlemlli flRhr n~ading I i AcceplanCfiltnforma tlon Background ulJhr reading 3 Were eX lema uRhf readl1lf5 tW(l tm bnckl1Ound and withllllxyr acceptance criterill

Additional Iuformation OVIDE DETAILS BELOW FOR A ND RESPONSE TO ANY (UESTION A80VE EXCEPT 1 ANI) 16

If applicable was the clienl contacted) YES i NO I

Project Manager Signature I Date

(1 Gun 112 Oaktoll SN 2992250020 jmiddot0066 lR Gun lie Oakton S~ 23n220101middot0(J02

Form 201r22gt15 (61109) Page 1 of _1

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6 Special Handlmlllilld Delivery SignalUlll Options

~~~l~__Iint_dUSabulld)IjhL Indirect Sianarurc ttMtrttISMIllFtdlHrtS ~~tlltl~ eeelMllnllrl$ICIIltctdeiMv-kll lt_noaIllaIMInt$ ~

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_____-----------~bull---~----- -------~~-------------------

7

GCMS Volatiles Method SW8260 _25B

Method Blank

Lab Name ALS Laboratory Group bullbull FC

Work Order Number 0911214

Client Name New Mexico Environment Department DB

ClientProject 10 644-111809(HWB Rmiddot37 VOCs) PAR 002731703

Lab 10 VL091125-4MB Sample Matrix WATER

Moisture NA Prep Batch VL091125-4

QCBatchlO VL091125-4-5

Sample Aliquot

Final Volume

10 ml

10 ml Date Collected NA Run 10 VL091125-4A Result Units UGL Date Extracted 25-Nov-09 Cleanup NONE Clean OF 1

Date Analyzed 25middotNov-09 Basis NA

File Name 028043

CASNO Target Analyte DF

75-71-8 DICHLORODIFLUOROMETHANE

74-87-3 CHLOROMETHANE

75-01-4 VINYL CHLORIDE

74-83-9 BROMOMETHANE

75-00-3 CHLOROETHANE

75-69-4 TRICHLOROFLUOROMETHANE

107-02-8 ACROLEIN

75-35-4 11middotDICHLOROETHENE

67-64-1 ACETONE

74-88-4 IODOMETHANE

75-15-0 CARBON DISULFIDE

METHYLEN E CHLORIDE 75-09-2

156-60-5 TRANS-12middotDICHLOROETHENE

1634-04-4 METHYL TERTIARY BUTYL ETHER

107-13-1 ACRYLONITRILE

75-34-3 11-DICHLOROETHANE

108-05-4 VINYL ACETATE

156-59middot2 CIS-12middotDICHLOROETHENE

78-93-3 2middotBUTANONE

~ BROMOCHLOROMETHANE

67-66-3 CHLOROFORM

71-55-6 111middot TRICHLOROETHANE

594-20-7 22middotDICHLOROPROPANE

56-23-5 CARBON TETRACHLORIDE

563-58-6 11middotDICHLOROPROPENE

107-06middot2 l2middotDICHLOROETHAN E

71-43-2 BENZENE

79-01-6 TRICHLOROETHENE

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

Result Reporting Limit

05 05

05 05

05 05

1 1

05 05

05 05

100 100

05 05

10 10

5 5

10 10

1 1

05 05

1 1

10 10

05 05

10 10

05 05

5 5

1 1

05 05

1 1

05 05

05 05

05 05

05 05

05 05

05 05

MDL Result EPA Qualifier Qualifier

017 U

017 U

017 U

017 U

017 U

017 U

17 U

017 U

33 U

017 U

017 U

017 U

017 U

017 U

17 U

017 U

067 U

017 U

17 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

Data Package 10 VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- Fe Page 1 of 4

llMS Version 6317 A

8

GCMS Volatiles Method SW8260 _25B

Method Blank

Lab Name ALS Laboratory Group -- FC

Work Order Number 0911214

Client Name New Mexico Environment Department 08

ClientProject 10 644-111809(HWEI R-37 voes) PAR 002731703

Lab 10 VL091125-4MB Sample Matrix WATER

Moisture NIA Prep Batch VL091125-4

QCBatchIO VL091125-4-5

Sample Aliquot

Final Volume

10 ml

10 ml Oate Collected NIA Run 10 VL091125-4A Result Units UGL Oate Extracted 25-Nov-09 Cleanup NONE Clean OF 1

Date Analyzed 25-Nov-09 Basis NIA

File Name 028043

CASNO Target Analyte OF Result Reporting Limit

MOL Result Qualifier

EPA Qualifier

78-87-5 12middotDICHLOROPROPANE 1 05 05 017 U

74-95-3 DIBROMOMETHANE 1 05 05 017 U

75-27-4 BROMODICHLOROMETHANE 1 05 05 017 U

10061-01-5 CISmiddot13middotDICHLOROPROPENE 1 05 05 017 U

108-10-1 4-METHYL-2-PENT ANONE 1 5 5 17 U

108-88-3 TOLUENE 1 05 05 017 U

10061-02-6 TRANS-13-DICHLOROPROPENE 1 05 05 017 U

79-00-5 112-TRICHLOROETHANE 1 05 05 017 U

591-78-6 2-HEXANONE 1 10 10 17 U

127-18-4 TETRACHLOROETHENE 1 05 05 017 U

142-28-9 13-DICHLOROPROPANI 1 05 05 017 U

124-48-1 DIBROMOCHLOROMETHANE 1 1 1 017 U

106-93-4 12-DIBROMOETHANE 1 1 1 017 U

108-90-7 CHLOROBENZENE 1 05 05 017 U

630-20-6 1112-TETRACHLOROETHANE 1 05 05 017 U

100-41-4 ETHYLBENZENE 1 05 05 017 U

136777-61-2 M+P-XYLENE 1 1 1 017 U

95-47-6 O-XYLENE 1 05 05 017 U

100-42-5 STYRENE 1 05 05 017 U

75-25-2 BROMOFORM 1 05 05 017 U

98-82-8 ~YLBENZENE 1 05 05 017 U

96-18-4 123-TRICHLOROPROPANE 1 2 2 017 U

79-34-5 1122middot TETRACHLOROETHANE 1 05 05 017 U

108-86-1 BROMOBENZENE 1 05 05 017 U

103-65-1 N-PROPYLBENZENE 1 05 05 017 U

95-49-8 2-CHLOROTOLUENE 1 05 05 017 U

108-67-8 135-TRIMETHYLBENZENE 1 05 05 017 U

106-43-4 4-CHLOROTOLUENE 1 05 05 017 U

Data Package 10 VL0911214-1

Date Printed Wednesday December n 2009 AlS Laboratory Group -- FC Page 2 of 4

lMS VeCSiOIY 6317A

9

GCMS Volatiles Method SW8260 _258

Method Blank

Lab Name ALS Laboratory Group - FC

Work Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject 10 644-111B09(HWB R-37 VOCs) PAR 002731703

Lab 10 VL091125-4MB Sample Matrix WATER

Moisture NIA

Prep Batch VL091125-4

QCBatchlD VL091125-4-5

Sample Aliquot

Final Volume

10 ml

10 ml

Date Collected NIA Run ID VL091125-4A Result Units UGL

Date Extracted 25-Nov-09 Cleanup NONE Clean DF 1

Date Analyzed 25-Nov-09 Basis NA

File Name 028043

CASNO Target Analyte OF Result Reporting Limit

MOL Result Qualifier

EPA Qualifier

98-06-6 TERT-BUTYLBENZENE 1 05 05 017 U

95-63-6 124-TRIMETHYLBENZENE 1 05 05 017 U

135-98-8 SEC-BUTYLBENZENE 1 05 05 017 U

541-73-1 13-DlCHLOROBENZENE 1 05 05 017 U

99-87-6 P-ISOPROPYLTOLUENE 1 05 05 017 U

106-46-7 1 A-DICHLOROBENZENE 1 05 05 017 U

104-51-8 N-BUTYLBENZENE 1 05 05 017 U

95-50-1 12-DICHLOROBENZENE 1 05 05 017 U

96-12-B 12-DIBROMO-3-CHLOROPROPANE 1 2 2 067 U

120-82-1 124-TRiCHLOROBENZENE 1 05 05 017 U

87-68-3 HEXACHLOROBUTADIENE 1 05 05 017 U

91-20-3 NAPHTHALENE 1 05 05 017 U

87-61-6 123-TRICHLOROBENZENE 1 05 05 017 U

75-05-B ACETONITRILE 1 50 50 83 U

107-05-1 ALLYL CHLORIDE 1 50 50 017 U

110-57-6 TRANS-14-DICHLORO-2-BUTENE 1 5 5 17 U

64-17-5 ETHANOL 1 200 200 78 U

97-63-2 ETHYL METHACRYLATE 1 5 5 017 U

78-83-1 ISOBUTYL ALCOHOL 1 100 100 17 U

126-98-7 METHACRYLONITRILE 1 35 35 17 U

80-62-6 METHYL METHACRYLATE 1 5 5 17 U

107-12-0 PROPIONITRILE 1 25 25 33 U

126-99-8 CHLOROPRENE 1 5 5 017 U

75-65-0 TERT-BUTANOL 1 100 100 33 U

108-20-3 ISOPROPYL ETHER 1 2 2 033 U

637-92-3 ETHYL TERT-BUTYL ETHER 1 2 2 033 U

994-05-8 TERT-AMYL METHYL ETHER 1 2 2 033 U

67-72-1 HEXACHLOROETHANE 1 2 2 033 U

Data Package 10 VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -~ Fe Page 3 of 4

LlMS Version 6317 A

10

GCMS Volatiles Method SW8260 _258

Method Blank

Lab Name ALS Laboratory Group -- FC

Work Order Number 0911214

Client Name New Mexico Envirmment Department OB

ClientProject 10 644-111809(HWB R-37 VOCs) PAR 002731703

Lab 10 VL091125-4MB Sample Matrix WATER

Moisture NIA Prep Batch VL091125-4

QCBatchlO VL091125-4-5

Sample Aliquot

Final Volume

10 m

10m Date Collected NIA Run 10 VL091125-4A Result Units UGIL Date Extracted 25-Nov-09 Cleanup NONE Clean OF 1

Date Analyzed 25-Nov-09 BasisNIA

File Name 028043

CASNO Target Analyte Result Reporting MOL Result EPAOF Limit Qualifier Qualifier

Surrogate Recovery

CASNO Surrogate Analyte Result Flag Spike Amount

Percent Recovery

Control Limits

460-00-4 4-BROMOFLUOROBENZENE 25 25 100 82 - 121

1868-53-7 DIBROMOFLUOROMETHANE 248 25 99 80 - 123

2037-26-5 TOLUENE-D8 26 25 104 85 - 116

Data Package 10 VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- FC Page 4 of4

LlMS Version 6317A

11

GCMS Volati les Method SW8260 _258

Sample Results

Lab Name ALS Laboratory Group -- FC

Work Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject 10 644-111809(HWB R-37 VOCs) PAR 002731703

Field 10 Rmiddot37 Ser 2middot111809

Lab 10 0911214middot1

Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10 ml

Moisture NA QCBatchlO VL091125-4-5 Final Volume 10mi Date Collected 18-Nov-09 Run 10 VL091125-4A Result Units UGL

Date Extracted 25-Nov-09 Cleanup NONE Clean OF 1

Analysis ReqCode 104 Date Analyzed 25-Nov-09

Prep Method SW5030 Rev C Basis As Received

File Name 028044

CASNO Target Analyte Dilution Factor

75-71-8 DICHLORODIFLUOROMETHANE 1

74middot87-3 CHLOROMETHANE 1

75-01-4 VINYL CHLORIDE 1

74-83-9 BROMOMETHANE 1

75-00-3 CHLOROETHANE 1

75-69-4 TRICHLOROFLUOROMETHANE 1

107-02-8 ACROLEIN 1

75-35-4 11middotDICHLOROETHENE 1

67-64-1 ACETONE 1

74-88-4 IODOMETHANE 1

75-15-0 CARBON DISULFIDE 1

75-09-2 METHYLENE CHLORIDE 1

156-60-5 TRANSmiddot12middotDICHLOROETHENE 1

1634-04-4 METHYL TERTIARY BUTYL ETHER 1

107-13-1 ACRYLONITRILE 1

75-34-3 1-DICHLOROETHANE 1

i 108-05-4 VINYL ACETATE 1

156-59-2 CIS-12middotDICHLOROETHENE 1

78-93-3 2-BUTANONE 1

74-97-5 BROMOCHLOROMETHANE 67-66-3 CHLOROFORM 1

71-55-6 11-TRICHLOROETHANE 594-20-7 22-DICHLOROPROPANE 56-23-5 CARBON TETRACHLORIDE 563-58-6 -DICHLOROPROPENE 107-06-2 2-DICHLOROETHANE

Result Reporting Limit

05 05

05 05

05 05

1 1

05 05

05 05

100 100

05 05

10 10

5 5

10 10

1 1

05 05

1 1

10 10

05 05

10 10

05 05

5 5

1 1

05 05

1 1

05 05

05 05

05 05

05 05

MOL Result EPA Qualifier Qualifier

017 U

017 U

017 U

017 U

017 U

017 U

17 U

017 U

33 U

017 U

017 U

017 U

017 U

017 U

17 U

017 U

067 U

017 U

17 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

Data Package ID VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- Fe Page 1 of 8

UMS Version 6317A

12

GCMS Volatiles Method SW8260 _25B

Method Blank

Lab Name ALS Laboratory Group -- FC

Work Order Number 0911214

Client Name New Mexico Environment Department 08

ClientProject 10 644-111809(HWEI R-37 voes) PAR 002731703

Lab 10 VL091125-4MB Sample Matrix WATER

Moisture NIA Prep Batch VL091125-4

QCBatchIO VL091125-4-5

Sample Aliquot

Final Volume

10 ml

10 ml Oate Collected NIA Run 10 VL091125-4A Result Units UGL Oate Extracted 25-Nov-09 Cleanup NONE Clean OF 1

Date Analyzed 25-Nov-09 Basis NIA

File Name 028043

CASNO Target Analyte OF Result Reporting Limit

MOL Result Qualifier

EPA Qualifier

78-87-5 12middotDICHLOROPROPANE 1 05 05 017 U

74-95-3 DIBROMOMETHANE 1 05 05 017 U

75-27-4 BROMODICHLOROMETHANE 1 05 05 017 U

10061-01-5 CISmiddot13middotDICHLOROPROPENE 1 05 05 017 U

108-10-1 4-METHYL-2-PENT ANONE 1 5 5 17 U

108-88-3 TOLUENE 1 05 05 017 U

10061-02-6 TRANS-13-DICHLOROPROPENE 1 05 05 017 U

79-00-5 112-TRICHLOROETHANE 1 05 05 017 U

591-78-6 2-HEXANONE 1 10 10 17 U

127-18-4 TETRACHLOROETHENE 1 05 05 017 U

142-28-9 13-DICHLOROPROPANI 1 05 05 017 U

124-48-1 DIBROMOCHLOROMETHANE 1 1 1 017 U

106-93-4 12-DIBROMOETHANE 1 1 1 017 U

108-90-7 CHLOROBENZENE 1 05 05 017 U

630-20-6 1112-TETRACHLOROETHANE 1 05 05 017 U

100-41-4 ETHYLBENZENE 1 05 05 017 U

136777-61-2 M+P-XYLENE 1 1 1 017 U

95-47-6 O-XYLENE 1 05 05 017 U

100-42-5 STYRENE 1 05 05 017 U

75-25-2 BROMOFORM 1 05 05 017 U

98-82-8 ~YLBENZENE 1 05 05 017 U

96-18-4 123-TRICHLOROPROPANE 1 2 2 017 U

79-34-5 1122middot TETRACHLOROETHANE 1 05 05 017 U

108-86-1 BROMOBENZENE 1 05 05 017 U

103-65-1 N-PROPYLBENZENE 1 05 05 017 U

95-49-8 2-CHLOROTOLUENE 1 05 05 017 U

108-67-8 135-TRIMETHYLBENZENE 1 05 05 017 U

106-43-4 4-CHLOROTOLUENE 1 05 05 017 U

Data Package 10 VL0911214-1

Date Printed Wednesday December n 2009 AlS Laboratory Group -- FC Page 2 of 4

lMS VeCSiOIY 6317A

9

GCMS Volatiles Method SW8260 _258

Method Blank

Lab Name ALS Laboratory Group - FC

Work Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject 10 644-111B09(HWB R-37 VOCs) PAR 002731703

Lab 10 VL091125-4MB Sample Matrix WATER

Moisture NIA

Prep Batch VL091125-4

QCBatchlD VL091125-4-5

Sample Aliquot

Final Volume

10 ml

10 ml

Date Collected NIA Run ID VL091125-4A Result Units UGL

Date Extracted 25-Nov-09 Cleanup NONE Clean DF 1

Date Analyzed 25-Nov-09 Basis NA

File Name 028043

CASNO Target Analyte OF Result Reporting Limit

MOL Result Qualifier

EPA Qualifier

98-06-6 TERT-BUTYLBENZENE 1 05 05 017 U

95-63-6 124-TRIMETHYLBENZENE 1 05 05 017 U

135-98-8 SEC-BUTYLBENZENE 1 05 05 017 U

541-73-1 13-DlCHLOROBENZENE 1 05 05 017 U

99-87-6 P-ISOPROPYLTOLUENE 1 05 05 017 U

106-46-7 1 A-DICHLOROBENZENE 1 05 05 017 U

104-51-8 N-BUTYLBENZENE 1 05 05 017 U

95-50-1 12-DICHLOROBENZENE 1 05 05 017 U

96-12-B 12-DIBROMO-3-CHLOROPROPANE 1 2 2 067 U

120-82-1 124-TRiCHLOROBENZENE 1 05 05 017 U

87-68-3 HEXACHLOROBUTADIENE 1 05 05 017 U

91-20-3 NAPHTHALENE 1 05 05 017 U

87-61-6 123-TRICHLOROBENZENE 1 05 05 017 U

75-05-B ACETONITRILE 1 50 50 83 U

107-05-1 ALLYL CHLORIDE 1 50 50 017 U

110-57-6 TRANS-14-DICHLORO-2-BUTENE 1 5 5 17 U

64-17-5 ETHANOL 1 200 200 78 U

97-63-2 ETHYL METHACRYLATE 1 5 5 017 U

78-83-1 ISOBUTYL ALCOHOL 1 100 100 17 U

126-98-7 METHACRYLONITRILE 1 35 35 17 U

80-62-6 METHYL METHACRYLATE 1 5 5 17 U

107-12-0 PROPIONITRILE 1 25 25 33 U

126-99-8 CHLOROPRENE 1 5 5 017 U

75-65-0 TERT-BUTANOL 1 100 100 33 U

108-20-3 ISOPROPYL ETHER 1 2 2 033 U

637-92-3 ETHYL TERT-BUTYL ETHER 1 2 2 033 U

994-05-8 TERT-AMYL METHYL ETHER 1 2 2 033 U

67-72-1 HEXACHLOROETHANE 1 2 2 033 U

Data Package 10 VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -~ Fe Page 3 of 4

LlMS Version 6317 A

10

GCMS Volatiles Method SW8260 _258

Method Blank

Lab Name ALS Laboratory Group -- FC

Work Order Number 0911214

Client Name New Mexico Envirmment Department OB

ClientProject 10 644-111809(HWB R-37 VOCs) PAR 002731703

Lab 10 VL091125-4MB Sample Matrix WATER

Moisture NIA Prep Batch VL091125-4

QCBatchlO VL091125-4-5

Sample Aliquot

Final Volume

10 m

10m Date Collected NIA Run 10 VL091125-4A Result Units UGIL Date Extracted 25-Nov-09 Cleanup NONE Clean OF 1

Date Analyzed 25-Nov-09 BasisNIA

File Name 028043

CASNO Target Analyte Result Reporting MOL Result EPAOF Limit Qualifier Qualifier

Surrogate Recovery

CASNO Surrogate Analyte Result Flag Spike Amount

Percent Recovery

Control Limits

460-00-4 4-BROMOFLUOROBENZENE 25 25 100 82 - 121

1868-53-7 DIBROMOFLUOROMETHANE 248 25 99 80 - 123

2037-26-5 TOLUENE-D8 26 25 104 85 - 116

Data Package 10 VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- FC Page 4 of4

LlMS Version 6317A

11

GCMS Volati les Method SW8260 _258

Sample Results

Lab Name ALS Laboratory Group -- FC

Work Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject 10 644-111809(HWB R-37 VOCs) PAR 002731703

Field 10 Rmiddot37 Ser 2middot111809

Lab 10 0911214middot1

Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10 ml

Moisture NA QCBatchlO VL091125-4-5 Final Volume 10mi Date Collected 18-Nov-09 Run 10 VL091125-4A Result Units UGL

Date Extracted 25-Nov-09 Cleanup NONE Clean OF 1

Analysis ReqCode 104 Date Analyzed 25-Nov-09

Prep Method SW5030 Rev C Basis As Received

File Name 028044

CASNO Target Analyte Dilution Factor

75-71-8 DICHLORODIFLUOROMETHANE 1

74middot87-3 CHLOROMETHANE 1

75-01-4 VINYL CHLORIDE 1

74-83-9 BROMOMETHANE 1

75-00-3 CHLOROETHANE 1

75-69-4 TRICHLOROFLUOROMETHANE 1

107-02-8 ACROLEIN 1

75-35-4 11middotDICHLOROETHENE 1

67-64-1 ACETONE 1

74-88-4 IODOMETHANE 1

75-15-0 CARBON DISULFIDE 1

75-09-2 METHYLENE CHLORIDE 1

156-60-5 TRANSmiddot12middotDICHLOROETHENE 1

1634-04-4 METHYL TERTIARY BUTYL ETHER 1

107-13-1 ACRYLONITRILE 1

75-34-3 1-DICHLOROETHANE 1

i 108-05-4 VINYL ACETATE 1

156-59-2 CIS-12middotDICHLOROETHENE 1

78-93-3 2-BUTANONE 1

74-97-5 BROMOCHLOROMETHANE 67-66-3 CHLOROFORM 1

71-55-6 11-TRICHLOROETHANE 594-20-7 22-DICHLOROPROPANE 56-23-5 CARBON TETRACHLORIDE 563-58-6 -DICHLOROPROPENE 107-06-2 2-DICHLOROETHANE

Result Reporting Limit

05 05

05 05

05 05

1 1

05 05

05 05

100 100

05 05

10 10

5 5

10 10

1 1

05 05

1 1

10 10

05 05

10 10

05 05

5 5

1 1

05 05

1 1

05 05

05 05

05 05

05 05

MOL Result EPA Qualifier Qualifier

017 U

017 U

017 U

017 U

017 U

017 U

17 U

017 U

33 U

017 U

017 U

017 U

017 U

017 U

17 U

017 U

067 U

017 U

17 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

Data Package ID VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- Fe Page 1 of 8

UMS Version 6317A

12

GCMS Volatiles Method SW8260 _258

Method Blank

Lab Name ALS Laboratory Group - FC

Work Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject 10 644-111B09(HWB R-37 VOCs) PAR 002731703

Lab 10 VL091125-4MB Sample Matrix WATER

Moisture NIA

Prep Batch VL091125-4

QCBatchlD VL091125-4-5

Sample Aliquot

Final Volume

10 ml

10 ml

Date Collected NIA Run ID VL091125-4A Result Units UGL

Date Extracted 25-Nov-09 Cleanup NONE Clean DF 1

Date Analyzed 25-Nov-09 Basis NA

File Name 028043

CASNO Target Analyte OF Result Reporting Limit

MOL Result Qualifier

EPA Qualifier

98-06-6 TERT-BUTYLBENZENE 1 05 05 017 U

95-63-6 124-TRIMETHYLBENZENE 1 05 05 017 U

135-98-8 SEC-BUTYLBENZENE 1 05 05 017 U

541-73-1 13-DlCHLOROBENZENE 1 05 05 017 U

99-87-6 P-ISOPROPYLTOLUENE 1 05 05 017 U

106-46-7 1 A-DICHLOROBENZENE 1 05 05 017 U

104-51-8 N-BUTYLBENZENE 1 05 05 017 U

95-50-1 12-DICHLOROBENZENE 1 05 05 017 U

96-12-B 12-DIBROMO-3-CHLOROPROPANE 1 2 2 067 U

120-82-1 124-TRiCHLOROBENZENE 1 05 05 017 U

87-68-3 HEXACHLOROBUTADIENE 1 05 05 017 U

91-20-3 NAPHTHALENE 1 05 05 017 U

87-61-6 123-TRICHLOROBENZENE 1 05 05 017 U

75-05-B ACETONITRILE 1 50 50 83 U

107-05-1 ALLYL CHLORIDE 1 50 50 017 U

110-57-6 TRANS-14-DICHLORO-2-BUTENE 1 5 5 17 U

64-17-5 ETHANOL 1 200 200 78 U

97-63-2 ETHYL METHACRYLATE 1 5 5 017 U

78-83-1 ISOBUTYL ALCOHOL 1 100 100 17 U

126-98-7 METHACRYLONITRILE 1 35 35 17 U

80-62-6 METHYL METHACRYLATE 1 5 5 17 U

107-12-0 PROPIONITRILE 1 25 25 33 U

126-99-8 CHLOROPRENE 1 5 5 017 U

75-65-0 TERT-BUTANOL 1 100 100 33 U

108-20-3 ISOPROPYL ETHER 1 2 2 033 U

637-92-3 ETHYL TERT-BUTYL ETHER 1 2 2 033 U

994-05-8 TERT-AMYL METHYL ETHER 1 2 2 033 U

67-72-1 HEXACHLOROETHANE 1 2 2 033 U

Data Package 10 VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -~ Fe Page 3 of 4

LlMS Version 6317 A

10

GCMS Volatiles Method SW8260 _258

Method Blank

Lab Name ALS Laboratory Group -- FC

Work Order Number 0911214

Client Name New Mexico Envirmment Department OB

ClientProject 10 644-111809(HWB R-37 VOCs) PAR 002731703

Lab 10 VL091125-4MB Sample Matrix WATER

Moisture NIA Prep Batch VL091125-4

QCBatchlO VL091125-4-5

Sample Aliquot

Final Volume

10 m

10m Date Collected NIA Run 10 VL091125-4A Result Units UGIL Date Extracted 25-Nov-09 Cleanup NONE Clean OF 1

Date Analyzed 25-Nov-09 BasisNIA

File Name 028043

CASNO Target Analyte Result Reporting MOL Result EPAOF Limit Qualifier Qualifier

Surrogate Recovery

CASNO Surrogate Analyte Result Flag Spike Amount

Percent Recovery

Control Limits

460-00-4 4-BROMOFLUOROBENZENE 25 25 100 82 - 121

1868-53-7 DIBROMOFLUOROMETHANE 248 25 99 80 - 123

2037-26-5 TOLUENE-D8 26 25 104 85 - 116

Data Package 10 VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- FC Page 4 of4

LlMS Version 6317A

11

GCMS Volati les Method SW8260 _258

Sample Results

Lab Name ALS Laboratory Group -- FC

Work Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject 10 644-111809(HWB R-37 VOCs) PAR 002731703

Field 10 Rmiddot37 Ser 2middot111809

Lab 10 0911214middot1

Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10 ml

Moisture NA QCBatchlO VL091125-4-5 Final Volume 10mi Date Collected 18-Nov-09 Run 10 VL091125-4A Result Units UGL

Date Extracted 25-Nov-09 Cleanup NONE Clean OF 1

Analysis ReqCode 104 Date Analyzed 25-Nov-09

Prep Method SW5030 Rev C Basis As Received

File Name 028044

CASNO Target Analyte Dilution Factor

75-71-8 DICHLORODIFLUOROMETHANE 1

74middot87-3 CHLOROMETHANE 1

75-01-4 VINYL CHLORIDE 1

74-83-9 BROMOMETHANE 1

75-00-3 CHLOROETHANE 1

75-69-4 TRICHLOROFLUOROMETHANE 1

107-02-8 ACROLEIN 1

75-35-4 11middotDICHLOROETHENE 1

67-64-1 ACETONE 1

74-88-4 IODOMETHANE 1

75-15-0 CARBON DISULFIDE 1

75-09-2 METHYLENE CHLORIDE 1

156-60-5 TRANSmiddot12middotDICHLOROETHENE 1

1634-04-4 METHYL TERTIARY BUTYL ETHER 1

107-13-1 ACRYLONITRILE 1

75-34-3 1-DICHLOROETHANE 1

i 108-05-4 VINYL ACETATE 1

156-59-2 CIS-12middotDICHLOROETHENE 1

78-93-3 2-BUTANONE 1

74-97-5 BROMOCHLOROMETHANE 67-66-3 CHLOROFORM 1

71-55-6 11-TRICHLOROETHANE 594-20-7 22-DICHLOROPROPANE 56-23-5 CARBON TETRACHLORIDE 563-58-6 -DICHLOROPROPENE 107-06-2 2-DICHLOROETHANE

Result Reporting Limit

05 05

05 05

05 05

1 1

05 05

05 05

100 100

05 05

10 10

5 5

10 10

1 1

05 05

1 1

10 10

05 05

10 10

05 05

5 5

1 1

05 05

1 1

05 05

05 05

05 05

05 05

MOL Result EPA Qualifier Qualifier

017 U

017 U

017 U

017 U

017 U

017 U

17 U

017 U

33 U

017 U

017 U

017 U

017 U

017 U

17 U

017 U

067 U

017 U

17 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

Data Package ID VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- Fe Page 1 of 8

UMS Version 6317A

12

GCMS Volatiles Method SW8260 _258

Method Blank

Lab Name ALS Laboratory Group -- FC

Work Order Number 0911214

Client Name New Mexico Envirmment Department OB

ClientProject 10 644-111809(HWB R-37 VOCs) PAR 002731703

Lab 10 VL091125-4MB Sample Matrix WATER

Moisture NIA Prep Batch VL091125-4

QCBatchlO VL091125-4-5

Sample Aliquot

Final Volume

10 m

10m Date Collected NIA Run 10 VL091125-4A Result Units UGIL Date Extracted 25-Nov-09 Cleanup NONE Clean OF 1

Date Analyzed 25-Nov-09 BasisNIA

File Name 028043

CASNO Target Analyte Result Reporting MOL Result EPAOF Limit Qualifier Qualifier

Surrogate Recovery

CASNO Surrogate Analyte Result Flag Spike Amount

Percent Recovery

Control Limits

460-00-4 4-BROMOFLUOROBENZENE 25 25 100 82 - 121

1868-53-7 DIBROMOFLUOROMETHANE 248 25 99 80 - 123

2037-26-5 TOLUENE-D8 26 25 104 85 - 116

Data Package 10 VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- FC Page 4 of4

LlMS Version 6317A

11

GCMS Volati les Method SW8260 _258

Sample Results

Lab Name ALS Laboratory Group -- FC

Work Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject 10 644-111809(HWB R-37 VOCs) PAR 002731703

Field 10 Rmiddot37 Ser 2middot111809

Lab 10 0911214middot1

Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10 ml

Moisture NA QCBatchlO VL091125-4-5 Final Volume 10mi Date Collected 18-Nov-09 Run 10 VL091125-4A Result Units UGL

Date Extracted 25-Nov-09 Cleanup NONE Clean OF 1

Analysis ReqCode 104 Date Analyzed 25-Nov-09

Prep Method SW5030 Rev C Basis As Received

File Name 028044

CASNO Target Analyte Dilution Factor

75-71-8 DICHLORODIFLUOROMETHANE 1

74middot87-3 CHLOROMETHANE 1

75-01-4 VINYL CHLORIDE 1

74-83-9 BROMOMETHANE 1

75-00-3 CHLOROETHANE 1

75-69-4 TRICHLOROFLUOROMETHANE 1

107-02-8 ACROLEIN 1

75-35-4 11middotDICHLOROETHENE 1

67-64-1 ACETONE 1

74-88-4 IODOMETHANE 1

75-15-0 CARBON DISULFIDE 1

75-09-2 METHYLENE CHLORIDE 1

156-60-5 TRANSmiddot12middotDICHLOROETHENE 1

1634-04-4 METHYL TERTIARY BUTYL ETHER 1

107-13-1 ACRYLONITRILE 1

75-34-3 1-DICHLOROETHANE 1

i 108-05-4 VINYL ACETATE 1

156-59-2 CIS-12middotDICHLOROETHENE 1

78-93-3 2-BUTANONE 1

74-97-5 BROMOCHLOROMETHANE 67-66-3 CHLOROFORM 1

71-55-6 11-TRICHLOROETHANE 594-20-7 22-DICHLOROPROPANE 56-23-5 CARBON TETRACHLORIDE 563-58-6 -DICHLOROPROPENE 107-06-2 2-DICHLOROETHANE

Result Reporting Limit

05 05

05 05

05 05

1 1

05 05

05 05

100 100

05 05

10 10

5 5

10 10

1 1

05 05

1 1

10 10

05 05

10 10

05 05

5 5

1 1

05 05

1 1

05 05

05 05

05 05

05 05

MOL Result EPA Qualifier Qualifier

017 U

017 U

017 U

017 U

017 U

017 U

17 U

017 U

33 U

017 U

017 U

017 U

017 U

017 U

17 U

017 U

067 U

017 U

17 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

Data Package ID VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- Fe Page 1 of 8

UMS Version 6317A

12

GCMS Volati les Method SW8260 _258

Sample Results

Lab Name ALS Laboratory Group -- FC

Work Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject 10 644-111809(HWB R-37 VOCs) PAR 002731703

Field 10 Rmiddot37 Ser 2middot111809

Lab 10 0911214middot1

Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10 ml

Moisture NA QCBatchlO VL091125-4-5 Final Volume 10mi Date Collected 18-Nov-09 Run 10 VL091125-4A Result Units UGL

Date Extracted 25-Nov-09 Cleanup NONE Clean OF 1

Analysis ReqCode 104 Date Analyzed 25-Nov-09

Prep Method SW5030 Rev C Basis As Received

File Name 028044

CASNO Target Analyte Dilution Factor

75-71-8 DICHLORODIFLUOROMETHANE 1

74middot87-3 CHLOROMETHANE 1

75-01-4 VINYL CHLORIDE 1

74-83-9 BROMOMETHANE 1

75-00-3 CHLOROETHANE 1

75-69-4 TRICHLOROFLUOROMETHANE 1

107-02-8 ACROLEIN 1

75-35-4 11middotDICHLOROETHENE 1

67-64-1 ACETONE 1

74-88-4 IODOMETHANE 1

75-15-0 CARBON DISULFIDE 1

75-09-2 METHYLENE CHLORIDE 1

156-60-5 TRANSmiddot12middotDICHLOROETHENE 1

1634-04-4 METHYL TERTIARY BUTYL ETHER 1

107-13-1 ACRYLONITRILE 1

75-34-3 1-DICHLOROETHANE 1

i 108-05-4 VINYL ACETATE 1

156-59-2 CIS-12middotDICHLOROETHENE 1

78-93-3 2-BUTANONE 1

74-97-5 BROMOCHLOROMETHANE 67-66-3 CHLOROFORM 1

71-55-6 11-TRICHLOROETHANE 594-20-7 22-DICHLOROPROPANE 56-23-5 CARBON TETRACHLORIDE 563-58-6 -DICHLOROPROPENE 107-06-2 2-DICHLOROETHANE

Result Reporting Limit

05 05

05 05

05 05

1 1

05 05

05 05

100 100

05 05

10 10

5 5

10 10

1 1

05 05

1 1

10 10

05 05

10 10

05 05

5 5

1 1

05 05

1 1

05 05

05 05

05 05

05 05

MOL Result EPA Qualifier Qualifier

017 U

017 U

017 U

017 U

017 U

017 U

17 U

017 U

33 U

017 U

017 U

017 U

017 U

017 U

17 U

017 U

067 U

017 U

17 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

Data Package ID VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- Fe Page 1 of 8

UMS Version 6317A

12

GCMS Volatiles Method SW8260_25B

Sample Results

Lab Name ALS Laboratory Group - FC

Work Order Number 0911214

Client Name New Mexico nvironment Department OB

ClientProject 10 644-111809(HWB R-37 VOCs) PAR 002731703

Field 10 R-37 Scr 2-111809

Lab 10 0911214-1

Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10ml

Moisture NA QCBatchlD VL091125-4-5 Final Volume 10ml

Date Collected l8-Nov-09 Run 10 VL091125-4A Result Units UGL

Date Extracted 25-Nov-09 Cleanup NONE Clean OF 1

Analysis ReqCode 104 Date Analyzed 25-Nov-09 Basis As Received

Prep Method SW5030 Rev C File NameD28044

CASNO Target Analyte Dilution Factor

Result Reporting Limit

MDL Result Qualifier

EPA Qualifier

I

71-43-2 BENZENE 1 05 05 017 U

79-01-6 TRICHLOROETHENE 1 05 05 017 U

78-87-5

74middot95-3

75-27-4

10061-01-5

108middot10middot1

108middot88-3

10061-02middot6

79-00-5

591-78-6

12-DICHLOROPROPANE

DIBROMOMETHANE

BROMODCHLOROMETHANE

CIS-13-DICHLOROPROPEI~E

4-METHYL-2-PENTANONE

TOLUENE

TRANS-13-DICHLOROPROPENE

112-TRICHLOROETHANE

2-HEXANONE

1

1

1

1

1

1

1

1

1

05

05

05

05

5

031

05

05

10

05

05

05

05

5

05

05

05

10

017

017

017

017

17

017

017

017

17

U

U

U

U

U

J

U

U

U

127-18-4

142-28-9

124-48-1

106-93-4

108-90-7

630-20-6

100-41-4

136777-61-2

95-47-6

100-42middot5

75-25-2

98-82middot8

96-18-4

79-34-5

108-86-1

TETRACHLOROETHENE

13-DICHLOROPROPANE

DIBROMOCHLOROMETHANE

12-DIBROMOETHANE

CHLOROBENZENE

11 12-TETRACHLOROETHANE

ETHYLBENZENE

M+PmiddotXYLENE

OmiddotXYLENE

STYRENE

BROMOFORM

ISOPRO PYLBENZENE

123middotTRICHLOROPROPANE

1122-TETRACHLOROETHANE

BROMOBENZENE

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

05

05

1

1

05

05

05

1

05

05

05

05

2

05

05

05

05

1

1

05

05

05

1

05

05

05

05

2

05

05

017

017

017

017

017

017

017

017

017

017

017

017

017

017

017

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

i

Data Package 10 VL0911214-1

Date Printed Wednesday December 022009 AlS laboratory Group bullbull Fe Page 2 of 8

UMS Version 6317A

13

GCMS Volatiles Method SW8260_258

Sample Results

Lab Name ALS Laboratory Group bullbull FC

Work Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject ID 644-111809(HWB R-37 VOCs) PAR 002731703

Field 10 R-37 Sor 2-111809

Lab ID 0911214middot1

Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10 ml

Moisture NA QCBatchlD VL091125-4-5 Final Volume 10 ml

Date Collected 18-Nov-09 Run ID VL091125-4A Result Units UGL

Date Extracted 25-Nov-09 Cleanup NONE Clean DF 1

Analysis ReqCode 104 Date Analyzed 25-Nov-09 Basis As Received

Prep Method SW5030 Rev C File Name 028044

CASNO Target Analyte Dilution Factor

103-65-1 NmiddotPROPYLBENZENE 1

95-49-8 2-CHLOROTOLUENE 1

108-67-8 135-TRIMETHYLBENZENE 1

106-43-4 4-CHLOROTOLUENE 1

98-06-6 TER I-BUTYLBENZENE 1

95-63-6 124-TRIMETHYLBENZENE 1

135-98-8 SEC-BUTYLBENZENE 1

541-73-1 13-OICHLOROBENZENE 1

99-87-6 P-ISOPROPYLTOLUENE 1

106-46-7 lA-DICHLOROBENZENE 1

104-51-8 N-BUTYLBENZENE 1

95-50-1 12-DICHLOROBENZENE 1

96-12-8 l2-DIBROMOmiddot3-CHLOROPROPANE 1

120-82-1 12A-TRICHLOROBENZENE 1

187-68-3 HEXACHLOROBUTADIENE 1

91-20-3 NAPHTHALENE 1

87-61middot6 123-TRICHLOROBENZENE 1

75-05-8 ACETONITRILE 1

107middot05middot1 ALLYL CHLORIDE 1

110-57-6 TRANS-14-DICHLORO-2-BUTENE 1

164-17-5 ETHANOL 1

97-63-2 ETHYL METHACRYLATE 1

78-83-1 ISOBUTYL ALCOHOL 1

126-98-7 METHACRYLONITRILE 1

80-62-6 METHYL METHACRYLATE 1

107-12-0 PROPIONITRILE 1

Result Reporting Limit

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

2 2

05 05

05 05

05 05

05 05

50 50

50 50

5 5

200 200

5 5

100 100

35 35

5 5

25 25

MDL Result EPA Qualifier Qualifier

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

067 U

017 U

017 U

017 U

017 U

83 U

017 U

U u 78 U

017 U

17 U

17 U

17 U

33 U

Data Package 10 VL0911214-1

Date Printed Wednesday December 022009 ALS Laboratory Group MM Fe Page 3 of 8

LlMS VerSion 6317A

14

GCMS Volatiles Method SW8260_258

Sample Results

Lab Name ALS Laboratory Group bullbull FC

Work Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject ID 644-111809(HWB R-37 VOCs) PAR 002731703

Field 10 R-37 Sor 2-111809

Lab ID 0911214middot1

Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10 ml

Moisture NA QCBatchlD VL091125-4-5 Final Volume 10 ml

Date Collected 18-Nov-09 Run ID VL091125-4A Result Units UGL

Date Extracted 25-Nov-09 Cleanup NONE Clean DF 1

Analysis ReqCode 104 Date Analyzed 25-Nov-09 Basis As Received

Prep Method SW5030 Rev C File Name 028044

CASNO Target Analyte Dilution Factor

103-65-1 NmiddotPROPYLBENZENE 1

95-49-8 2-CHLOROTOLUENE 1

108-67-8 135-TRIMETHYLBENZENE 1

106-43-4 4-CHLOROTOLUENE 1

98-06-6 TER I-BUTYLBENZENE 1

95-63-6 124-TRIMETHYLBENZENE 1

135-98-8 SEC-BUTYLBENZENE 1

541-73-1 13-OICHLOROBENZENE 1

99-87-6 P-ISOPROPYLTOLUENE 1

106-46-7 lA-DICHLOROBENZENE 1

104-51-8 N-BUTYLBENZENE 1

95-50-1 12-DICHLOROBENZENE 1

96-12-8 l2-DIBROMOmiddot3-CHLOROPROPANE 1

120-82-1 12A-TRICHLOROBENZENE 1

187-68-3 HEXACHLOROBUTADIENE 1

91-20-3 NAPHTHALENE 1

87-61middot6 123-TRICHLOROBENZENE 1

75-05-8 ACETONITRILE 1

107middot05middot1 ALLYL CHLORIDE 1

110-57-6 TRANS-14-DICHLORO-2-BUTENE 1

164-17-5 ETHANOL 1

97-63-2 ETHYL METHACRYLATE 1

78-83-1 ISOBUTYL ALCOHOL 1

126-98-7 METHACRYLONITRILE 1

80-62-6 METHYL METHACRYLATE 1

107-12-0 PROPIONITRILE 1

Result Reporting Limit

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

2 2

05 05

05 05

05 05

05 05

50 50

50 50

5 5

200 200

5 5

100 100

35 35

5 5

25 25

MDL Result EPA Qualifier Qualifier

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

067 U

017 U

017 U

017 U

017 U

83 U

017 U

U u 78 U

017 U

17 U

17 U

17 U

33 U

Data Package 10 VL0911214-1

Date Printed Wednesday December 022009 ALS Laboratory Group MM Fe Page 3 of 8

LlMS VerSion 6317A

14

GCMS Volati las Method SW8260_258

Sample Results

Lab Name ALS Laboratory Group - FC

Work Order Number 0911214

Client Name New Mexico Environment Department 08

ClientProject 10 644-111B09(HWB R-37 VOGs) PAR 002731703

Field 10 R-37 Ser 2-111809 Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10ml

Lab 10 0911214-1 Moisture NA

Date Collected 1B-Nov-09 QCBatchlO VL091125-4-5

Run 10 VL091125-4A

Final Volume 10ml

Result Units UGIL Date Extracted 25-Nov-09 Cleanup NONE Clean OF

Analysis ReqCode 104 Date Analyzed 25-Nov-09

Prep Method SW5030 Rev G Basis As Received

File Name 028044

CASNO Target Analyte Dilution Factor

Result Reporting Limit

MDL Result Qualifier

EPA Qualifier

126-99-8 CHLOROPRENE 1 5 5 017 U

75-65-0 TERT-BUTANOL 1 100 100 33 U

108-20-3 ISOPROPYL ETHER 1 2 2 033 U

637-92-3 ETHYL TERT-BUTYL ETHER 1 2 2 033 U

994-05-8 TERT-AMYL METHYL ETHER 1 2 2 033 U

67-72-1 HEXACHLOROETHANE 1 2 2 033 U

Surrogate Recovery

CASNO Surrogate Analyte Result Flag Spike Amount

Percent Recovery

Control Limits

460-00-4 4-BROMOFLUOHOBENZENE 246 25 98 82 - 121

1868-53-7 DIBROMOFLUOHOMETHANE 248 25 99 BO - 123

2037-26-5 TOLUENE-DB 258 25 103 85middot116

Data Package 10 VL0911214-1

Date Printed Wednesday December 022009 ALS Laboratory Group bullbull FC Page 4 of 8

LIMS Version 0317 A

15

GCMS Volati les Method SW8260_25B

Sample Results

Lab Name ALS Laboratory Group -- FC

Worlt Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject 10 644-111809(HWB Rmiddot37 VOCs) PAR 002731703

Field 10 Rmiddot37 Scr jmiddot111809

Lab 10 0911214-2

Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10 ml Moisture NfA QCBatchID VL091125-4middot5 Final Volume 10 ml

Date Collected 18middotNov-09 Run 10 VL091125-4A Result Units UGfL Date Extracted 25-Nov-09 Cleanup NONE Clean OF 1

Analysis ReqCode 104 Date Analyzed 25middotNov-09 Basis As Received Prep Method SW5030 Rev C File Name 028045

CASNO Target Analyte Dilution Factor

Result Reporting Limit

MOL Result Qualifier

EPA Qualifier

75-71-8 DICHLORODIFLUOROMETHANE 1 05 05 017 U

74-87-3 CHLOROMETHANE 1 05 05 017 U

75-01middot4 VINYL CHLORIDE 1 05 05 017 U

74-83-9 BROMOMETHANE 1 1 1 017 U

75middot00middot3 CHLOROETHANE j 05 05 017 U

75-69-4 TRICHLOROFLUOROMETHANE 1 05 05 017 U

107-02-8 ACROLEIN 1 100 100 17 U

i 75-35-4 11-DICHLOROETHENE 1 05 05 017 U

67-64middot1 ACETONE 1 10 10 33 U

74-8S-4 IODOMETHANE 1 5 5 017 U

75-15-0 CARBON DISULFIDE 1 10 10 017 U

75-09-2 METHYLENE CHLORIDE 1 1 1 017 U

156-60-5 TRANS-12-DICHLOROETHENE 1 05 05 017 U

1634-04-4 METHYL TERTIARY BUTYL ETHER 1 1 1 017 U

107-13-1 ACRYLONITRILE 1 10 10 17 U

75-34middot3 11-DICHLOROETHANE 05 05 017 U

i 108-05-4 VINYL ACETATE 1 10 10 067 U

115659-2 CISmiddot 2middotDICHLOROETHENE 1 05 05 017 U

178-933 2middotBUTANONE 1 5 5 17 U

74-97middot5 BROMOCHLOROMET HANE 1 1 1 017 U

67-66-3 CHLOROFORM 1 05 05 017 U

71-55middot6 111middotTRICHLOROETHANE 1 1 1 017 U

594-20-7 22middotDICHLOROPROPANE 1 05 05 017 U

56-23-5 CARBON TETRACHLORIDE 1 05 05 017 U

563-58-6 11middotDICHLOROPROPENE 1 05 05 017 U

107-06-2 12middotDICHL OROETHANE 1 05 05 017 U

Data Package ID VL0911214-1

Date Printed Wednesday December 022009 ALS Laboratory Group -- Fe Page 5 of 8

16

GCMS Volatiles Method SW8260_25B

Sample Results

Lab Name ALS Laboratory Group -- FC

Work Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject 10 644-111809(HW3 R-37 VOCs) PAR 002731703

Field 10 R-37 Scr 1-11 1809

Lab 10 0911214-2

Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10 ml

Moisture NIA QCBatchlO VL091125-4-5 Final Volume 10 ml

Date Collected 18-Nov-09 Run 10 VL091125-4A Result Units UGL

[late Extracted 25-Nov-09 Cleanup NONE Clean OF 1

Analysis ReqCode 104 Date Analyzed 25-Nov-09

Prep Method SW5030 Rev C Basis As Received

File Name 028045

CASNO Target Analyte Dilution Factor

71-43-2 BENZENE 1

79-01-6 TRICHLOROETHENE 1

78-87-5 12-DICHLOROPROPANE 1

74-95-3 DIBROMOMETHANE 1

75-27-4 BROMODICHLOROMETHANE 1

10061-01-5 CIS-13-DICHLOROPROPENE 1

108-10-1 4-METHYL-2-PtNTANON 1

108-88-3 TOLUENE 1

10061-02-6 TRANS-13-DICHLOROPROPENE 1

79-00-5 112-TRICHLOROETHANE 1

591-78-6 2-HEXANONE 1

127-18-4 TETRACHLOROETHENE 1

142-28-9 13-DICHLOROPROPANt 1

124-48-1 DI3ROMOCHLOROMETHANE 1

106-93-4 12-DIBROMOETHANE 1

108-90-7 CHLOROBENZENE 1

OETHANE 1

- 1

LENE 1

ENE 1

ENE 1

OFORM 1

OPYlBENZENE 1

96-18-4 123-TRICHLOROPROPANE 1

79-34-5 1122-TETRACHLOROETHANE 1

108-86-1 BROMOBENZENE 1

Result Reporting Limit

05 05

05 05

05 05

05 05

05 05

05 05

5 5

025 05

05 05

05 05

10 10

05 05

05 05

1 1

1 1

05 05

05 05

05 05

1 1

05 05

05 05

05 05

05 05

2 2

05 05

05 05

MDL Result EPA Qualifier Qualifier

017 U

017 U

017 U

017 U

017 U

017 U

17 U

017 J

017 U

017 U

17 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

Data Package 10 VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- Fe Page 6 of 8

317A

17

GCMS Volatiles Method SW8260 _258

Sample Results

Lab Name ALS Laboratory Group -- FC

Work Order Number 0911214

Client Name New Mexico Environment Department 08

ClientProject 10 644-11S09(HWB R-37 VOCs) PAR 002731703

Field 10 Rmiddot37 Scr 1-111809

Lab 10 0911214-2

Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10 ml Moisture NA QCBatchlD VL091125-4-5 Final Volume 10 ml

Date Collected 18-Nov-09 Run 10 VL091125-4A Result Units UGL Date Extracted 25-Nol-09 Cleanup NONE Clean OF

Analysis ReqCode 104 Date Analyzed 25-Nov-09 Basis As Received Prep Method SW5030 Rev C File Name D28045

CASNO Target Analyte Dilution Factor

103-65-1 N-PROPYLBENZENE 1

95-49-8 2-CHLOROTOLUENE 1

108-67-8 135-TRIMETHYLBENZENE 1

106-43-4 4-CHLOROTOLUENE 1

98-06-6 TERT-BUTYLBENZENE 1

95-63-6 124-TRIMETHYLBENZENE 1

135-98-8 SEC-BUTYLBENZENE 1

i 541-73-1 13middotDICHLOROBENZENE 1

99-87-6 PmiddotISOPROPYL TOLUENE 1

106-46-7 I 14-DICHLOROBENZENE 1

104-51-8 I N-BUTYLBENZENE 1

95-50-1 l2-DICHLOROBENZENE 1

96-12-8 I 12-DIBROMO-3-CHLOROPROPANE 1

120-82-1 124-TRICHLOROBENZENE 1

87-68-3 HEXACHLOROBUT ADIENE 1

91-20-3 NAPHTHALENE 1

87-61-6 123-TRICHLOROBENZENE 1

75-05-S ACETONITRILE 1

107-05-1 ALLYL CH LORIDE 1

110-57-6 TRAN S-14-DICHLORO-2-BUTENE 1

64-17-5 ETHANOL 1

97-63-2 ETHYL METHACRYLATE 1

78-83-1 ISOBUTYL ALCOHOL 1

126-98-7 METHACRYLONITRILE 1

80-62-6 METHYL METHACRYLATE 1

107-12-0 I PROPIONITRILE 1

Result Reporting Limit

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

2 2

05 05

05 05

05 05

05 05

50 50

50 50 I 5 5

200 200

5 5

100 100

35 35

5 5

25 25

MDL

017

017

017

017

017

017

017

017

017

017

017

017

067

017

017

017

017

83

017

17

78

017

17

17

17

33

Result EPA Qualifier Qualifier

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

Data Package 10 VL0911214-1

Date Printed Wednesday December 022009 ALS Laboratory Group -- Fe Page 7 of 8

LlMS Version 6317A

18

GCMS Volati les Method SW8260_25B

Sample Results

Lab Name ALS Laboratory Group -- FC

Worlt Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject 10 644-111809(HWB Rmiddot37 VOCs) PAR 002731703

Field 10 Rmiddot37 Scr jmiddot111809

Lab 10 0911214-2

Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10 ml Moisture NfA QCBatchID VL091125-4middot5 Final Volume 10 ml

Date Collected 18middotNov-09 Run 10 VL091125-4A Result Units UGfL Date Extracted 25-Nov-09 Cleanup NONE Clean OF 1

Analysis ReqCode 104 Date Analyzed 25middotNov-09 Basis As Received Prep Method SW5030 Rev C File Name 028045

CASNO Target Analyte Dilution Factor

Result Reporting Limit

MOL Result Qualifier

EPA Qualifier

75-71-8 DICHLORODIFLUOROMETHANE 1 05 05 017 U

74-87-3 CHLOROMETHANE 1 05 05 017 U

75-01middot4 VINYL CHLORIDE 1 05 05 017 U

74-83-9 BROMOMETHANE 1 1 1 017 U

75middot00middot3 CHLOROETHANE j 05 05 017 U

75-69-4 TRICHLOROFLUOROMETHANE 1 05 05 017 U

107-02-8 ACROLEIN 1 100 100 17 U

i 75-35-4 11-DICHLOROETHENE 1 05 05 017 U

67-64middot1 ACETONE 1 10 10 33 U

74-8S-4 IODOMETHANE 1 5 5 017 U

75-15-0 CARBON DISULFIDE 1 10 10 017 U

75-09-2 METHYLENE CHLORIDE 1 1 1 017 U

156-60-5 TRANS-12-DICHLOROETHENE 1 05 05 017 U

1634-04-4 METHYL TERTIARY BUTYL ETHER 1 1 1 017 U

107-13-1 ACRYLONITRILE 1 10 10 17 U

75-34middot3 11-DICHLOROETHANE 05 05 017 U

i 108-05-4 VINYL ACETATE 1 10 10 067 U

115659-2 CISmiddot 2middotDICHLOROETHENE 1 05 05 017 U

178-933 2middotBUTANONE 1 5 5 17 U

74-97middot5 BROMOCHLOROMET HANE 1 1 1 017 U

67-66-3 CHLOROFORM 1 05 05 017 U

71-55middot6 111middotTRICHLOROETHANE 1 1 1 017 U

594-20-7 22middotDICHLOROPROPANE 1 05 05 017 U

56-23-5 CARBON TETRACHLORIDE 1 05 05 017 U

563-58-6 11middotDICHLOROPROPENE 1 05 05 017 U

107-06-2 12middotDICHL OROETHANE 1 05 05 017 U

Data Package ID VL0911214-1

Date Printed Wednesday December 022009 ALS Laboratory Group -- Fe Page 5 of 8

16

GCMS Volatiles Method SW8260_25B

Sample Results

Lab Name ALS Laboratory Group -- FC

Work Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject 10 644-111809(HW3 R-37 VOCs) PAR 002731703

Field 10 R-37 Scr 1-11 1809

Lab 10 0911214-2

Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10 ml

Moisture NIA QCBatchlO VL091125-4-5 Final Volume 10 ml

Date Collected 18-Nov-09 Run 10 VL091125-4A Result Units UGL

[late Extracted 25-Nov-09 Cleanup NONE Clean OF 1

Analysis ReqCode 104 Date Analyzed 25-Nov-09

Prep Method SW5030 Rev C Basis As Received

File Name 028045

CASNO Target Analyte Dilution Factor

71-43-2 BENZENE 1

79-01-6 TRICHLOROETHENE 1

78-87-5 12-DICHLOROPROPANE 1

74-95-3 DIBROMOMETHANE 1

75-27-4 BROMODICHLOROMETHANE 1

10061-01-5 CIS-13-DICHLOROPROPENE 1

108-10-1 4-METHYL-2-PtNTANON 1

108-88-3 TOLUENE 1

10061-02-6 TRANS-13-DICHLOROPROPENE 1

79-00-5 112-TRICHLOROETHANE 1

591-78-6 2-HEXANONE 1

127-18-4 TETRACHLOROETHENE 1

142-28-9 13-DICHLOROPROPANt 1

124-48-1 DI3ROMOCHLOROMETHANE 1

106-93-4 12-DIBROMOETHANE 1

108-90-7 CHLOROBENZENE 1

OETHANE 1

- 1

LENE 1

ENE 1

ENE 1

OFORM 1

OPYlBENZENE 1

96-18-4 123-TRICHLOROPROPANE 1

79-34-5 1122-TETRACHLOROETHANE 1

108-86-1 BROMOBENZENE 1

Result Reporting Limit

05 05

05 05

05 05

05 05

05 05

05 05

5 5

025 05

05 05

05 05

10 10

05 05

05 05

1 1

1 1

05 05

05 05

05 05

1 1

05 05

05 05

05 05

05 05

2 2

05 05

05 05

MDL Result EPA Qualifier Qualifier

017 U

017 U

017 U

017 U

017 U

017 U

17 U

017 J

017 U

017 U

17 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

Data Package 10 VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- Fe Page 6 of 8

317A

17

GCMS Volatiles Method SW8260 _258

Sample Results

Lab Name ALS Laboratory Group -- FC

Work Order Number 0911214

Client Name New Mexico Environment Department 08

ClientProject 10 644-11S09(HWB R-37 VOCs) PAR 002731703

Field 10 Rmiddot37 Scr 1-111809

Lab 10 0911214-2

Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10 ml Moisture NA QCBatchlD VL091125-4-5 Final Volume 10 ml

Date Collected 18-Nov-09 Run 10 VL091125-4A Result Units UGL Date Extracted 25-Nol-09 Cleanup NONE Clean OF

Analysis ReqCode 104 Date Analyzed 25-Nov-09 Basis As Received Prep Method SW5030 Rev C File Name D28045

CASNO Target Analyte Dilution Factor

103-65-1 N-PROPYLBENZENE 1

95-49-8 2-CHLOROTOLUENE 1

108-67-8 135-TRIMETHYLBENZENE 1

106-43-4 4-CHLOROTOLUENE 1

98-06-6 TERT-BUTYLBENZENE 1

95-63-6 124-TRIMETHYLBENZENE 1

135-98-8 SEC-BUTYLBENZENE 1

i 541-73-1 13middotDICHLOROBENZENE 1

99-87-6 PmiddotISOPROPYL TOLUENE 1

106-46-7 I 14-DICHLOROBENZENE 1

104-51-8 I N-BUTYLBENZENE 1

95-50-1 l2-DICHLOROBENZENE 1

96-12-8 I 12-DIBROMO-3-CHLOROPROPANE 1

120-82-1 124-TRICHLOROBENZENE 1

87-68-3 HEXACHLOROBUT ADIENE 1

91-20-3 NAPHTHALENE 1

87-61-6 123-TRICHLOROBENZENE 1

75-05-S ACETONITRILE 1

107-05-1 ALLYL CH LORIDE 1

110-57-6 TRAN S-14-DICHLORO-2-BUTENE 1

64-17-5 ETHANOL 1

97-63-2 ETHYL METHACRYLATE 1

78-83-1 ISOBUTYL ALCOHOL 1

126-98-7 METHACRYLONITRILE 1

80-62-6 METHYL METHACRYLATE 1

107-12-0 I PROPIONITRILE 1

Result Reporting Limit

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

2 2

05 05

05 05

05 05

05 05

50 50

50 50 I 5 5

200 200

5 5

100 100

35 35

5 5

25 25

MDL

017

017

017

017

017

017

017

017

017

017

017

017

067

017

017

017

017

83

017

17

78

017

17

17

17

33

Result EPA Qualifier Qualifier

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

Data Package 10 VL0911214-1

Date Printed Wednesday December 022009 ALS Laboratory Group -- Fe Page 7 of 8

LlMS Version 6317A

18

GCMS Volatiles Method SW8260_25B

Sample Results

Lab Name ALS Laboratory Group -- FC

Work Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject 10 644-111809(HW3 R-37 VOCs) PAR 002731703

Field 10 R-37 Scr 1-11 1809

Lab 10 0911214-2

Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10 ml

Moisture NIA QCBatchlO VL091125-4-5 Final Volume 10 ml

Date Collected 18-Nov-09 Run 10 VL091125-4A Result Units UGL

[late Extracted 25-Nov-09 Cleanup NONE Clean OF 1

Analysis ReqCode 104 Date Analyzed 25-Nov-09

Prep Method SW5030 Rev C Basis As Received

File Name 028045

CASNO Target Analyte Dilution Factor

71-43-2 BENZENE 1

79-01-6 TRICHLOROETHENE 1

78-87-5 12-DICHLOROPROPANE 1

74-95-3 DIBROMOMETHANE 1

75-27-4 BROMODICHLOROMETHANE 1

10061-01-5 CIS-13-DICHLOROPROPENE 1

108-10-1 4-METHYL-2-PtNTANON 1

108-88-3 TOLUENE 1

10061-02-6 TRANS-13-DICHLOROPROPENE 1

79-00-5 112-TRICHLOROETHANE 1

591-78-6 2-HEXANONE 1

127-18-4 TETRACHLOROETHENE 1

142-28-9 13-DICHLOROPROPANt 1

124-48-1 DI3ROMOCHLOROMETHANE 1

106-93-4 12-DIBROMOETHANE 1

108-90-7 CHLOROBENZENE 1

OETHANE 1

- 1

LENE 1

ENE 1

ENE 1

OFORM 1

OPYlBENZENE 1

96-18-4 123-TRICHLOROPROPANE 1

79-34-5 1122-TETRACHLOROETHANE 1

108-86-1 BROMOBENZENE 1

Result Reporting Limit

05 05

05 05

05 05

05 05

05 05

05 05

5 5

025 05

05 05

05 05

10 10

05 05

05 05

1 1

1 1

05 05

05 05

05 05

1 1

05 05

05 05

05 05

05 05

2 2

05 05

05 05

MDL Result EPA Qualifier Qualifier

017 U

017 U

017 U

017 U

017 U

017 U

17 U

017 J

017 U

017 U

17 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

017 U

Data Package 10 VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- Fe Page 6 of 8

317A

17

GCMS Volatiles Method SW8260 _258

Sample Results

Lab Name ALS Laboratory Group -- FC

Work Order Number 0911214

Client Name New Mexico Environment Department 08

ClientProject 10 644-11S09(HWB R-37 VOCs) PAR 002731703

Field 10 Rmiddot37 Scr 1-111809

Lab 10 0911214-2

Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10 ml Moisture NA QCBatchlD VL091125-4-5 Final Volume 10 ml

Date Collected 18-Nov-09 Run 10 VL091125-4A Result Units UGL Date Extracted 25-Nol-09 Cleanup NONE Clean OF

Analysis ReqCode 104 Date Analyzed 25-Nov-09 Basis As Received Prep Method SW5030 Rev C File Name D28045

CASNO Target Analyte Dilution Factor

103-65-1 N-PROPYLBENZENE 1

95-49-8 2-CHLOROTOLUENE 1

108-67-8 135-TRIMETHYLBENZENE 1

106-43-4 4-CHLOROTOLUENE 1

98-06-6 TERT-BUTYLBENZENE 1

95-63-6 124-TRIMETHYLBENZENE 1

135-98-8 SEC-BUTYLBENZENE 1

i 541-73-1 13middotDICHLOROBENZENE 1

99-87-6 PmiddotISOPROPYL TOLUENE 1

106-46-7 I 14-DICHLOROBENZENE 1

104-51-8 I N-BUTYLBENZENE 1

95-50-1 l2-DICHLOROBENZENE 1

96-12-8 I 12-DIBROMO-3-CHLOROPROPANE 1

120-82-1 124-TRICHLOROBENZENE 1

87-68-3 HEXACHLOROBUT ADIENE 1

91-20-3 NAPHTHALENE 1

87-61-6 123-TRICHLOROBENZENE 1

75-05-S ACETONITRILE 1

107-05-1 ALLYL CH LORIDE 1

110-57-6 TRAN S-14-DICHLORO-2-BUTENE 1

64-17-5 ETHANOL 1

97-63-2 ETHYL METHACRYLATE 1

78-83-1 ISOBUTYL ALCOHOL 1

126-98-7 METHACRYLONITRILE 1

80-62-6 METHYL METHACRYLATE 1

107-12-0 I PROPIONITRILE 1

Result Reporting Limit

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

2 2

05 05

05 05

05 05

05 05

50 50

50 50 I 5 5

200 200

5 5

100 100

35 35

5 5

25 25

MDL

017

017

017

017

017

017

017

017

017

017

017

017

067

017

017

017

017

83

017

17

78

017

17

17

17

33

Result EPA Qualifier Qualifier

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

Data Package 10 VL0911214-1

Date Printed Wednesday December 022009 ALS Laboratory Group -- Fe Page 7 of 8

LlMS Version 6317A

18

GCMS Volatiles Method SW8260 _258

Sample Results

Lab Name ALS Laboratory Group -- FC

Work Order Number 0911214

Client Name New Mexico Environment Department 08

ClientProject 10 644-11S09(HWB R-37 VOCs) PAR 002731703

Field 10 Rmiddot37 Scr 1-111809

Lab 10 0911214-2

Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10 ml Moisture NA QCBatchlD VL091125-4-5 Final Volume 10 ml

Date Collected 18-Nov-09 Run 10 VL091125-4A Result Units UGL Date Extracted 25-Nol-09 Cleanup NONE Clean OF

Analysis ReqCode 104 Date Analyzed 25-Nov-09 Basis As Received Prep Method SW5030 Rev C File Name D28045

CASNO Target Analyte Dilution Factor

103-65-1 N-PROPYLBENZENE 1

95-49-8 2-CHLOROTOLUENE 1

108-67-8 135-TRIMETHYLBENZENE 1

106-43-4 4-CHLOROTOLUENE 1

98-06-6 TERT-BUTYLBENZENE 1

95-63-6 124-TRIMETHYLBENZENE 1

135-98-8 SEC-BUTYLBENZENE 1

i 541-73-1 13middotDICHLOROBENZENE 1

99-87-6 PmiddotISOPROPYL TOLUENE 1

106-46-7 I 14-DICHLOROBENZENE 1

104-51-8 I N-BUTYLBENZENE 1

95-50-1 l2-DICHLOROBENZENE 1

96-12-8 I 12-DIBROMO-3-CHLOROPROPANE 1

120-82-1 124-TRICHLOROBENZENE 1

87-68-3 HEXACHLOROBUT ADIENE 1

91-20-3 NAPHTHALENE 1

87-61-6 123-TRICHLOROBENZENE 1

75-05-S ACETONITRILE 1

107-05-1 ALLYL CH LORIDE 1

110-57-6 TRAN S-14-DICHLORO-2-BUTENE 1

64-17-5 ETHANOL 1

97-63-2 ETHYL METHACRYLATE 1

78-83-1 ISOBUTYL ALCOHOL 1

126-98-7 METHACRYLONITRILE 1

80-62-6 METHYL METHACRYLATE 1

107-12-0 I PROPIONITRILE 1

Result Reporting Limit

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

05 05

2 2

05 05

05 05

05 05

05 05

50 50

50 50 I 5 5

200 200

5 5

100 100

35 35

5 5

25 25

MDL

017

017

017

017

017

017

017

017

017

017

017

017

067

017

017

017

017

83

017

17

78

017

17

17

17

33

Result EPA Qualifier Qualifier

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

Data Package 10 VL0911214-1

Date Printed Wednesday December 022009 ALS Laboratory Group -- Fe Page 7 of 8

LlMS Version 6317A

18

GCMS Volatiles Method SW8260_258

Sample Results

Lab Name ALS Laboratory Group bullbull FC

Work Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject 10 644middot111B09(HWB R-37 VOCs) PAR 002731703

Sample Matrix WATER Prep Batch VL091125--4 Sample Aliquot 10 mlRmiddot37 Ser 1-111809 Moisture NA QCBatchlO VL091125--4-5 Final Volume 10 m

0911214-2 Date Collected 18-Nov-09 Run 10 VL091125--4A Result Units UGL Date Extracted 25-Nov-09 Cleanup NONE Clean OF 1 Date Analyzed 25-Nov-09 Basis As Received

10

Analysis ReqCode 104 Prep Method SW5030 Rev C File Name 028045

I

CASNO Target Analyte Dilution Factor

Result Reporting Limit

MDL Result Qualifier

EPA Qualifier

126-99-8 CHLOROPRENE 1 5 5 017 U

75-65-0 TERT-BUTANOL 1 100 100 33 U

108-20-3 ISOPROPYL ETHER 1 2 2 033 U

637-92-3 ETHYL TERT-BUTYL ETHER 1 2 2 033 U

994-05--8 TERT-AMYL MTHYL ETHER 1 2 2 033 U

67-72-1 HEXACHLOROETHANE 1 2 2 033 U

Surrogate Recovery

CASNO Surrogate Analyte Result Flag Spike Amount

Percent Control Recovery Limits

460-00-4 4middotBROMOFLUOROBENZENE 247 25 99 1

1868-53-7 DIBROMOFLUOROMETHANE 248 25 99 80 123

2037-26-5 TOLUENEmiddotDB 255 25 102 85 - 116

Data Package 10 VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- FC Page B of 8

LlMS Version 6317A

19

GCMS Volatiles Method SW8260_258

Laboratory Control Sample and Laboratory Control Sample Duplicate

Lab Name ALS Laboratory Group - FC

Work Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject 10 644-111809(HWB R-37 VOCs) PAR 002731703

Lab 10 VL091125-4LCS Sample Matrix WATER

Moisture NA Prep Batch VL091125-4

QCBatchlD VL091125-4-5

Sample Aliquot

Final Volume

10ml

10ml Date Collected NA Run 10 VL091125-4A Result Units UGIL Date Extracted 111252009 Cleanup NONE Clean OF 1 Date Analyzed 11252009 Basis NA

Prep Method SW5030C File Name 028040

CASNO

74-87-3

75-01-4

74-83-9

75-69-4

75-35-4

75-15-0

156-60-5

75-34-3

108-05-4

156-59-2

78-93-3

67 -66-3

71-55-6

i 56-23-5

107-06-2

71-43-2

79-01-6

78-87-5

75-27-4

108-88-3

79-00-5

591-78-6

127-18-4

106-93-4

108-90-7

63Q20-6

Target Analyte Spike Added

CHLOROMETHANE 10

VINYL CHLORIDE 10

BROMOMETHANE 10

TRICHLOROFLUOROMETHANE 10

11-DICHLOROETHENE 10

CARBON DISULFIDE 10

TRANS-12-DICHLOROETHENE 10

11-DICHLOROETHANE 10

VINYL ACETATE 10

CIS-12-DICHLOROETHENE 10

2middotBUTANONE 40

CHLOROFORM 10

111-TRICHL ORO ETHANE 10

CARBON TETRACHLORIDE 10

12-DICHLOROETHANE 10

BENZENE 10

TRICHLOROETHENE 10

12-DICHLOROPROPANE 10

BROMODICHLOROMETHANE 10

TOLUENE 10

112-TRICHLOROETHANE 10

2-HEXANONE 40

TETRACHLOROETHENE 10

12-DIBROMOETHANE 10

CHLOROBENZENE 10

1112-TETRACHLOROETHANE 10

LCS Reporting Result Result Limit Qualifier

932 05

863 05

943 1

908 05

96 05

95 10 J

996 05

992 05

10 10

102 05

412 5

993 05

974 1

943 05

106 05

983 05

962 05

10 05

988 05

974 05

989 05

409 10

956 05

991 1

984 05

101 05

LCS Control Rec Limits

93 49 -129

86 46 134

94 32-121

91 67 -152

96 61 -135

95 61 -140

100 70 -122

99 76 -119

100 62 182

102 75 126

103 61 -137

99 79 120

97 76 - 114

94 58middot135

106 75middot132

98 70 shy 125

96 74 121

100 81 -119

99 79 - 123

97 76 - 120

99 81 -126

102 45 168

96 56 -128

99 79 -123

98 75 -120

101 82 - 123

Data Package 10 VL0911214middot1

-Date Printed Wednesday December 02 2009 ALS Laboratory Group -- Fe Page 1 of 4

LiMS Version 6317A

20

GCMS Volatiles Method SW8260_25B

Laboratory Control Sample and Laboratory Control Sample Duplicate

Lab Name ALS Laboratory Group - FC

Work Order Number 0911214

Client Name New Mexico Envircnment Department OB

ClientProject 10 644-111809(HWB R-37 VOes) PAR 002731703

Lab 10 VL091125-4LCS Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10 ml

Moisture NIA QCBatchlO VL091125-4-5 Final Volume 10 mi

Date Collected NA Run 10 VL091125-4A Result Units UGL Date Extracted 11252009 Cleanup NONE Clean OF 1 Date Analyzed 111252009 Basis NA

Prep Method SW5030e File Name 028040

CASNO Target Analyte Spike Added

LCS Result

Reporting Limit

Result Qualifier

LCS Rec

Control Limits

100-41-4 ETHYLBENZENE 10 981 05 98 79 -114

136777-61-2 M+P-XYLENE 20 197 1 98 81-115

95-47-6 O-XYLENE 10 101 05 101 81 -115

95-49-8 2-CHLOROTOLUENE 10 97 05 97 80 -128

541-73-1 13-DICHLOROBENZiNt 10 977 05 98 81-116

106-46-7 14-DICHLOROBENZENE 10 979 05 98 81 -119

95-50-1 12-DICHLOROBENZENE 10 987 05 99 79 - 116

91-20-3 NAPHTHALENE 10 993 05 99 69 -126

87-61-6 123-TRICHLOROBENZENE 10 999 05 100 60 -137

Data Package ID VL0911214-1

Date Printed Wecnesday December 02 2009 ALS Laboratory Group -- Fe Page 2 of 4

21

GCMS Volatiles Method SW8260_25B

Laboratory Control Sample and Laboratory Control Sample Duplicate

Lab Name ALS Laboratory Group bullbull FC

Work Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject 10 644-11 1809(HWB R-37 VOCs) PAR 002731703

Lab 10 VL091125middot4LCSD Sample Matrix WATER

Moisture NIA Prep Batch VL091125-4

QCBatchlD VL091125-4-5

Sample Aliquot

Final Volume

10 ml

10ml Date Collected NIA Run ID VL091125-4A Result Units UGIL Date Extracted 112512009 Cleanup NONE Clean DF 1 Date Analyzed 1112512009 Basis NIA

Prep Method SW5030C File Name 028041

CASNO Target Analyte Spike Added

LCSD Result

Reporting Limit

Result Qualifier

LCSD Rec

RPD Limit

RPD

74-87-3 CHLOROMETHANE 10 897 05 90 30 4

75-01-4 VINYL CHLORIDE 10 831 05 83 25 4

74-83-9 BROMO METHANE 10 945 1 94 25 0

75-69-4 TRICHLOROFLUOROMETHANE 10 873 05 87 22 4

75-35-4 11-DICHLOROETHENE 10 909 05 91 18 5

75-15-0 CARBON DISULFIDE 10 941 10 J 94 20 1

156-60middot5 TRANS-l2middotDICHLOROETHENE 10 961 05 96 25 4

75middot34middot3 11-DICHLOROETHANE 10 977 05 98 25 2

108-05-4 VINYL ACETATE 10 993 10 J 99 20 1

156middot59-2 CIS-12-DlCHLOROETHENE 10 995 05 99 25 3

i 78-93-3 2-BUTANONE 40 419 5 105 30 2

67-66-3 CHLOROFORM 10 985 05 99 25 1

71-55-6 lll-TRICHLOROETHANE 10 942 1 94 25 3

56-23-5 CARBON TETRACHLORIDE 10 922 05 92 25 2

107middot06-2 12middotDICHLOROETHANE 10 106 05 106 25 0

71-43middot2 BENZENE 10 971 05 97 10 1

79middot01middot6 TRICHLOROETHENE 10 939 05 94 10 2

78middot87middot5 l2middotDICHLOROPROPANE 10 101 05 101 25 1

i 75middot27-4 BROMODICHLOROMETHANE 10 992 05 99 25 0

1108-88-3 TOLUENE 10 962 05 96 9 1

I 79005 112middotTRICHLOROETHANE 10 986 05 99 25 0

591middot78middot6 2-HEXANONE 40 418 10 104 20 2

127middot18-4 TETRACHLOROETHENE 10 918 05 92 25 4

106-93-4 12middotDIBROMOETHANE 10 999 1 100 15 1

108middot90-7 CHLOROBENZENE 10 997 05 100 11 1

630-20middot6 1112-TETRACHLOROETHANE 10 101 05 101 15 0

100-41-4 ETHYLBENZENE 10 968 05 97 25 1

Data Package ID VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- FC Page 3 of 4

lIMS Version 6317 A

22

GCMS Volatiles Method SW8260_25B

Laboratory Control Sample and Laboratory Control Sample Duplicate

Lab Name ALS Laboratory 13roup -- FC

Work Order Number 0911214

Client Name New Mexico Environment Department OS

ClientProject 10 644-11 1809(HWB R-37 VOCs) PAR 002731703

Lab 10 VL091125-4LCSD Sample Matrix WATER

Moisture NA Prep Batch VL091125-4

QCBatchlO VL091125-4-5

Sample Aliquot

Final Volume

10 ml

10ml Date Collected NA Run 10 VL091125-4A Result Units UGL Date Extracted 11252009 Cleanup NONE Clean OF Date Analyzed 11252009 Basis NIA

Prep Method SW5030C File Name 028041

CASNO Target Analyte Spike Added

LCSD Result

Reporting Limit

Result Qualifier

LCSD Rec

RPD Limit

RPD

136777-61-2 M+P-XYLENE 20 193 1 97 25 2

95-47-6 O-XYLENE 10 983 05 98 25 2

95-49-8 2middotCHLOROTOLUENE 10 9A9 05 95 15 2

541-73-1 13middotDICHLOROBENZENE 10 997 05 100 25 2

106-46-7 14-DICHLOROBeNZENE 10 974 05 97 25 1

95-50middot1 12middotDICHLOROBENZeNE 10 101 05 101 25 2

91middot20-3 NAPHTHALENe 10 105 05 105 24 6

87-61-6 123-TRICHLOROBENZENE 10 102 05 102 33 3

Surrogate Recovery LCSLCSD

CASNO Target Analyte Spike Added

LCS Rec

LCS Flag

LCSD Rec

LCSD Flag

Control Limits

460middot00-4 4-BROMOFLUOROBeNZENE 25 100 100 82 - 121

1868-53middot7 DIBROMOFLUOROMeTHANE 25 101 100 80middot 123

2037middot26-5 TOLUENEmiddotD8 25 102 100 85middot 116

Data Package 10 VL0911214-

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- Fe Page 4 of 4

UMS Verslmt 6317A

23

GCMS Volatiles Method SW8260_25B

Laboratory Control Sample and Laboratory Control Sample Duplicate

Lab Name ALS Laboratory Group - FC

Work Order Number 0911214

Client Name New Mexico Envircnment Department OB

ClientProject 10 644-111809(HWB R-37 VOes) PAR 002731703

Lab 10 VL091125-4LCS Sample Matrix WATER Prep Batch VL091125-4 Sample Aliquot 10 ml

Moisture NIA QCBatchlO VL091125-4-5 Final Volume 10 mi

Date Collected NA Run 10 VL091125-4A Result Units UGL Date Extracted 11252009 Cleanup NONE Clean OF 1 Date Analyzed 111252009 Basis NA

Prep Method SW5030e File Name 028040

CASNO Target Analyte Spike Added

LCS Result

Reporting Limit

Result Qualifier

LCS Rec

Control Limits

100-41-4 ETHYLBENZENE 10 981 05 98 79 -114

136777-61-2 M+P-XYLENE 20 197 1 98 81-115

95-47-6 O-XYLENE 10 101 05 101 81 -115

95-49-8 2-CHLOROTOLUENE 10 97 05 97 80 -128

541-73-1 13-DICHLOROBENZiNt 10 977 05 98 81-116

106-46-7 14-DICHLOROBENZENE 10 979 05 98 81 -119

95-50-1 12-DICHLOROBENZENE 10 987 05 99 79 - 116

91-20-3 NAPHTHALENE 10 993 05 99 69 -126

87-61-6 123-TRICHLOROBENZENE 10 999 05 100 60 -137

Data Package ID VL0911214-1

Date Printed Wecnesday December 02 2009 ALS Laboratory Group -- Fe Page 2 of 4

21

GCMS Volatiles Method SW8260_25B

Laboratory Control Sample and Laboratory Control Sample Duplicate

Lab Name ALS Laboratory Group bullbull FC

Work Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject 10 644-11 1809(HWB R-37 VOCs) PAR 002731703

Lab 10 VL091125middot4LCSD Sample Matrix WATER

Moisture NIA Prep Batch VL091125-4

QCBatchlD VL091125-4-5

Sample Aliquot

Final Volume

10 ml

10ml Date Collected NIA Run ID VL091125-4A Result Units UGIL Date Extracted 112512009 Cleanup NONE Clean DF 1 Date Analyzed 1112512009 Basis NIA

Prep Method SW5030C File Name 028041

CASNO Target Analyte Spike Added

LCSD Result

Reporting Limit

Result Qualifier

LCSD Rec

RPD Limit

RPD

74-87-3 CHLOROMETHANE 10 897 05 90 30 4

75-01-4 VINYL CHLORIDE 10 831 05 83 25 4

74-83-9 BROMO METHANE 10 945 1 94 25 0

75-69-4 TRICHLOROFLUOROMETHANE 10 873 05 87 22 4

75-35-4 11-DICHLOROETHENE 10 909 05 91 18 5

75-15-0 CARBON DISULFIDE 10 941 10 J 94 20 1

156-60middot5 TRANS-l2middotDICHLOROETHENE 10 961 05 96 25 4

75middot34middot3 11-DICHLOROETHANE 10 977 05 98 25 2

108-05-4 VINYL ACETATE 10 993 10 J 99 20 1

156middot59-2 CIS-12-DlCHLOROETHENE 10 995 05 99 25 3

i 78-93-3 2-BUTANONE 40 419 5 105 30 2

67-66-3 CHLOROFORM 10 985 05 99 25 1

71-55-6 lll-TRICHLOROETHANE 10 942 1 94 25 3

56-23-5 CARBON TETRACHLORIDE 10 922 05 92 25 2

107middot06-2 12middotDICHLOROETHANE 10 106 05 106 25 0

71-43middot2 BENZENE 10 971 05 97 10 1

79middot01middot6 TRICHLOROETHENE 10 939 05 94 10 2

78middot87middot5 l2middotDICHLOROPROPANE 10 101 05 101 25 1

i 75middot27-4 BROMODICHLOROMETHANE 10 992 05 99 25 0

1108-88-3 TOLUENE 10 962 05 96 9 1

I 79005 112middotTRICHLOROETHANE 10 986 05 99 25 0

591middot78middot6 2-HEXANONE 40 418 10 104 20 2

127middot18-4 TETRACHLOROETHENE 10 918 05 92 25 4

106-93-4 12middotDIBROMOETHANE 10 999 1 100 15 1

108middot90-7 CHLOROBENZENE 10 997 05 100 11 1

630-20middot6 1112-TETRACHLOROETHANE 10 101 05 101 15 0

100-41-4 ETHYLBENZENE 10 968 05 97 25 1

Data Package ID VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- FC Page 3 of 4

lIMS Version 6317 A

22

GCMS Volatiles Method SW8260_25B

Laboratory Control Sample and Laboratory Control Sample Duplicate

Lab Name ALS Laboratory 13roup -- FC

Work Order Number 0911214

Client Name New Mexico Environment Department OS

ClientProject 10 644-11 1809(HWB R-37 VOCs) PAR 002731703

Lab 10 VL091125-4LCSD Sample Matrix WATER

Moisture NA Prep Batch VL091125-4

QCBatchlO VL091125-4-5

Sample Aliquot

Final Volume

10 ml

10ml Date Collected NA Run 10 VL091125-4A Result Units UGL Date Extracted 11252009 Cleanup NONE Clean OF Date Analyzed 11252009 Basis NIA

Prep Method SW5030C File Name 028041

CASNO Target Analyte Spike Added

LCSD Result

Reporting Limit

Result Qualifier

LCSD Rec

RPD Limit

RPD

136777-61-2 M+P-XYLENE 20 193 1 97 25 2

95-47-6 O-XYLENE 10 983 05 98 25 2

95-49-8 2middotCHLOROTOLUENE 10 9A9 05 95 15 2

541-73-1 13middotDICHLOROBENZENE 10 997 05 100 25 2

106-46-7 14-DICHLOROBeNZENE 10 974 05 97 25 1

95-50middot1 12middotDICHLOROBENZeNE 10 101 05 101 25 2

91middot20-3 NAPHTHALENe 10 105 05 105 24 6

87-61-6 123-TRICHLOROBENZENE 10 102 05 102 33 3

Surrogate Recovery LCSLCSD

CASNO Target Analyte Spike Added

LCS Rec

LCS Flag

LCSD Rec

LCSD Flag

Control Limits

460middot00-4 4-BROMOFLUOROBeNZENE 25 100 100 82 - 121

1868-53middot7 DIBROMOFLUOROMeTHANE 25 101 100 80middot 123

2037middot26-5 TOLUENEmiddotD8 25 102 100 85middot 116

Data Package 10 VL0911214-

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- Fe Page 4 of 4

UMS Verslmt 6317A

23

GCMS Volatiles Method SW8260_25B

Laboratory Control Sample and Laboratory Control Sample Duplicate

Lab Name ALS Laboratory Group bullbull FC

Work Order Number 0911214

Client Name New Mexico Environment Department OB

ClientProject 10 644-11 1809(HWB R-37 VOCs) PAR 002731703

Lab 10 VL091125middot4LCSD Sample Matrix WATER

Moisture NIA Prep Batch VL091125-4

QCBatchlD VL091125-4-5

Sample Aliquot

Final Volume

10 ml

10ml Date Collected NIA Run ID VL091125-4A Result Units UGIL Date Extracted 112512009 Cleanup NONE Clean DF 1 Date Analyzed 1112512009 Basis NIA

Prep Method SW5030C File Name 028041

CASNO Target Analyte Spike Added

LCSD Result

Reporting Limit

Result Qualifier

LCSD Rec

RPD Limit

RPD

74-87-3 CHLOROMETHANE 10 897 05 90 30 4

75-01-4 VINYL CHLORIDE 10 831 05 83 25 4

74-83-9 BROMO METHANE 10 945 1 94 25 0

75-69-4 TRICHLOROFLUOROMETHANE 10 873 05 87 22 4

75-35-4 11-DICHLOROETHENE 10 909 05 91 18 5

75-15-0 CARBON DISULFIDE 10 941 10 J 94 20 1

156-60middot5 TRANS-l2middotDICHLOROETHENE 10 961 05 96 25 4

75middot34middot3 11-DICHLOROETHANE 10 977 05 98 25 2

108-05-4 VINYL ACETATE 10 993 10 J 99 20 1

156middot59-2 CIS-12-DlCHLOROETHENE 10 995 05 99 25 3

i 78-93-3 2-BUTANONE 40 419 5 105 30 2

67-66-3 CHLOROFORM 10 985 05 99 25 1

71-55-6 lll-TRICHLOROETHANE 10 942 1 94 25 3

56-23-5 CARBON TETRACHLORIDE 10 922 05 92 25 2

107middot06-2 12middotDICHLOROETHANE 10 106 05 106 25 0

71-43middot2 BENZENE 10 971 05 97 10 1

79middot01middot6 TRICHLOROETHENE 10 939 05 94 10 2

78middot87middot5 l2middotDICHLOROPROPANE 10 101 05 101 25 1

i 75middot27-4 BROMODICHLOROMETHANE 10 992 05 99 25 0

1108-88-3 TOLUENE 10 962 05 96 9 1

I 79005 112middotTRICHLOROETHANE 10 986 05 99 25 0

591middot78middot6 2-HEXANONE 40 418 10 104 20 2

127middot18-4 TETRACHLOROETHENE 10 918 05 92 25 4

106-93-4 12middotDIBROMOETHANE 10 999 1 100 15 1

108middot90-7 CHLOROBENZENE 10 997 05 100 11 1

630-20middot6 1112-TETRACHLOROETHANE 10 101 05 101 15 0

100-41-4 ETHYLBENZENE 10 968 05 97 25 1

Data Package ID VL0911214-1

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- FC Page 3 of 4

lIMS Version 6317 A

22

GCMS Volatiles Method SW8260_25B

Laboratory Control Sample and Laboratory Control Sample Duplicate

Lab Name ALS Laboratory 13roup -- FC

Work Order Number 0911214

Client Name New Mexico Environment Department OS

ClientProject 10 644-11 1809(HWB R-37 VOCs) PAR 002731703

Lab 10 VL091125-4LCSD Sample Matrix WATER

Moisture NA Prep Batch VL091125-4

QCBatchlO VL091125-4-5

Sample Aliquot

Final Volume

10 ml

10ml Date Collected NA Run 10 VL091125-4A Result Units UGL Date Extracted 11252009 Cleanup NONE Clean OF Date Analyzed 11252009 Basis NIA

Prep Method SW5030C File Name 028041

CASNO Target Analyte Spike Added

LCSD Result

Reporting Limit

Result Qualifier

LCSD Rec

RPD Limit

RPD

136777-61-2 M+P-XYLENE 20 193 1 97 25 2

95-47-6 O-XYLENE 10 983 05 98 25 2

95-49-8 2middotCHLOROTOLUENE 10 9A9 05 95 15 2

541-73-1 13middotDICHLOROBENZENE 10 997 05 100 25 2

106-46-7 14-DICHLOROBeNZENE 10 974 05 97 25 1

95-50middot1 12middotDICHLOROBENZeNE 10 101 05 101 25 2

91middot20-3 NAPHTHALENe 10 105 05 105 24 6

87-61-6 123-TRICHLOROBENZENE 10 102 05 102 33 3

Surrogate Recovery LCSLCSD

CASNO Target Analyte Spike Added

LCS Rec

LCS Flag

LCSD Rec

LCSD Flag

Control Limits

460middot00-4 4-BROMOFLUOROBeNZENE 25 100 100 82 - 121

1868-53middot7 DIBROMOFLUOROMeTHANE 25 101 100 80middot 123

2037middot26-5 TOLUENEmiddotD8 25 102 100 85middot 116

Data Package 10 VL0911214-

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- Fe Page 4 of 4

UMS Verslmt 6317A

23

GCMS Volatiles Method SW8260_25B

Laboratory Control Sample and Laboratory Control Sample Duplicate

Lab Name ALS Laboratory 13roup -- FC

Work Order Number 0911214

Client Name New Mexico Environment Department OS

ClientProject 10 644-11 1809(HWB R-37 VOCs) PAR 002731703

Lab 10 VL091125-4LCSD Sample Matrix WATER

Moisture NA Prep Batch VL091125-4

QCBatchlO VL091125-4-5

Sample Aliquot

Final Volume

10 ml

10ml Date Collected NA Run 10 VL091125-4A Result Units UGL Date Extracted 11252009 Cleanup NONE Clean OF Date Analyzed 11252009 Basis NIA

Prep Method SW5030C File Name 028041

CASNO Target Analyte Spike Added

LCSD Result

Reporting Limit

Result Qualifier

LCSD Rec

RPD Limit

RPD

136777-61-2 M+P-XYLENE 20 193 1 97 25 2

95-47-6 O-XYLENE 10 983 05 98 25 2

95-49-8 2middotCHLOROTOLUENE 10 9A9 05 95 15 2

541-73-1 13middotDICHLOROBENZENE 10 997 05 100 25 2

106-46-7 14-DICHLOROBeNZENE 10 974 05 97 25 1

95-50middot1 12middotDICHLOROBENZeNE 10 101 05 101 25 2

91middot20-3 NAPHTHALENe 10 105 05 105 24 6

87-61-6 123-TRICHLOROBENZENE 10 102 05 102 33 3

Surrogate Recovery LCSLCSD

CASNO Target Analyte Spike Added

LCS Rec

LCS Flag

LCSD Rec

LCSD Flag

Control Limits

460middot00-4 4-BROMOFLUOROBeNZENE 25 100 100 82 - 121

1868-53middot7 DIBROMOFLUOROMeTHANE 25 101 100 80middot 123

2037middot26-5 TOLUENEmiddotD8 25 102 100 85middot 116

Data Package 10 VL0911214-

Date Printed Wednesday December 02 2009 ALS Laboratory Group -- Fe Page 4 of 4

UMS Verslmt 6317A

23