Air Monitoring Survey: Asphalt Paving Operations ...asphaltrubber.org/ARTIC/Reports/RPA_A1600.pdf · air monitoring survey asphalt paving operations interstate 8 dateland. arizona

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AIR MONITORING SURVEY

ASPHALT PAVING OPERATlONS INTERSTATE 8

DATElAND. ARIZONA

WT JOB NO. 21S4JC248

Western Technologies Inc. Th<(@!lty_

Sinef 1955

PHOENIX - ARIZONA

3737 East Broadway Road Phoenix, Arizona 85040 (601) 437·3737 • fax 470-1341

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ASPHALT PAVING OPERATIONS INTERSTATE 8

DATELAND. ARIZ ONA

WT JOB NO. 2184JC248

Prepared for:

FNF CONSTRUCTION, INC. 115 SOUTH 48TH STREET TEMPE, ARIZONA 85281

Prepared by:

WESTERN TECHNOLOGIES INC. 3737 EAST BROADWAY ROAD

PHOENIX, ARIZONA 85040

JANUARY 6 , 1995

Mlltht(/Jpd Brjan K. Gladhart. CI H, CSP

Industrial Hygiene Services Industrial Hygiene Services

G

TABLE OF CONTENTS

Page No.

' .0 INTRODUCTION ........... .• .... ••• .. • •...••... •• ...••. . ...•. . ..

2 .0 SURVEY PROCEDURES ......•.. ..•... ..•....•...• •...•....• ... • ... 1

3 .0 SURVEY RESULTS ........ • •••• •• • • • • •• • • •• ••• •• • •• •• ••• • ••• • • •.. 4

4 .0 SUMMARY OF FINDINGS . . . . . • . . . . . • . . . . • . . . . • . . . • • . . . • • . • . • . . . • . .. 8

ATTACHMENTS

Appendix A: Sampling Equipment Information

Appendix B: Laboratory Reports

Appendix C: Photographs

Appendix 0 : Sampling Protocol


FNF CONSTRUCTION, INC. A SPHALT PAVING OPERATIONS

INTERSTATE-8 DATElAND, ARIZONA

WT JOB NO . 21S4JC248

1.0 INTRODUCTION

This report presents the results of an air monitoring survey conducted during asphalt paving operations on Interstate B near Dateland, Arizona. Western Technologies Inc. (WT) was retained

by Mr. Mark Belshe of FNF Construct ion. Inc. (FNF) for the air monitoring survey. WT was

authorized t o proceed with the scope of work as stipulated in WT's Proposal No. 2184PC863

dated November 1" 1994.

The objective of the air monitoring survey was to obtain additional information about potential air contaminants associated with the application of rubberized asphalt and 416 base asphaltic

concrete paving mixtures .

Air monitoring was performed under the supervision of Mr. Brian Gladhart , Certified Industrial

Hygienist (CIH). Mr. George Hall, Industrial Hygiene Technician with WT performed the air monitoring on November 16·17, 1994 and December 9-11, 1994. Mr. Gladhart, CIH , conducted

a site visit on November 17 , 1994 to review the site activities.

The air samples were analyzed by Galson Laboratories in East Syracuse, New York and D&M

Laboratories in Petaluma, California. Both laboratories are acc redited by the American Industrial

Hygiene Association . 2.0 SURVEY PROCEDURES

Prior to the air monitoring survey. WT interviewed with Mr. Belshe of FNF to discuss the project. W T was furnished a protocol for the air sampling and analytical methods by Mr. M ichael Connor ,

CIH, CSP with ACUMEN Industrial Hygiene Inc. A copy of this protocol is presented in Appendix

D. Following the interview and discussion of the protocol with Mr. Connor, WT conducted a review of the site to obse rved current operating conditions. A ir monitoring was performed to

measure the ambient concentrations of certain chemical compounds associated with asphalt

paving operations.

FNF Construction, Inc. WT Job No. 2184JC248

In summary, personnel and area air samples were collected at the following areas :

• At the rear of the asphalt paving machine

• The Breathing Zone of Tom Potriowski, Asphalt Paving Machine Assistant Operator

Based on ACUMEN Industrial Hygiene, Inc's protocol, the airborne concentrations ofthe following contaminants were collected and analyzed using the unique sample numbers and methods on the

following page.

All samples were maintained under a chain-ot-custody and in accordance with the anlaytical

methods. WT submitted f ield blanks to the laboratories for Quality control purposes. A summary

of the air monitoring resul t s and sample locations is presented in Section 3.0 . A copy of the

analytical laboratory reports are presented in Appendix B.

Photographs of the paving operations were taken by Mr. Hall, WT. Copy of these photographs is presented in Appendix C.

2


SAMPLE NO. CQlltMni"."VA".ytical M .....

FNF.OI Voit_l. O,g"';o

Compou"ds/GC·MS

FNF.02 Crcloh.,..". EltlrM:t.bl. P.,ticul.tfl/NfOSH 5023

FNF-03 Po/r"ucl • ., A,om.tic Hrdrourbo"s/NIOSH 5506

FNF·04 A.ph';, Fumfl/NIOSH 0500

FNF-05 VoIt';l. O'9.flic

Compou"ds/GC·MS

FNF·06 Crcloh.,..". E,.rr_t.bI.

P.,ticul.te/N/OSH 5023

FNF·07 PoIy"ucl .. r ATOm.tlc Hrciroc.,bo"s/NIOSH 5506

FNF-OtJ A.ph.t Fumfl/NIOSH 0500

FNF.09 PoIr"ucl .. , Atom.tic

Hrdrocwbo".tNIOSH 5506

FNF· 10 Volt .. ". 0'9"';':

Compou"d"'GC·MS

FNF. " PoIr"ucl • ., Atom.tic

Hrd'QC.,bo".tNfOSH 5506

FNF. 12 Creloh.x.". ExlrltC/.bf.

P.rtJoul.t';NfOSH 5023

8'1' ;

SAMPLE NO.

FNF· 13

FNF-14

FNF·15

FNF· '6

FNF_,7

FNF· ltJ

FNF·,g

FNF.20

FNF·21

FNF·22

FNF·23

FNF·24

NIOSH ... Nelionelln. litulII lor Occupational Sefety and Health

GCIMS ... Ge. Chromatography . Ma .. Spllc t rophotomatry

3

CO" t.ml"." VA "alrtlc aI M.thod

A.phalt Fum.tNIOSH 0500

Volt_I. Ort/llllio

Compou"dS/GC-MS

Poir"ucl • ., A,om.tic Hrd,oc.,bo,,';NfOSH 6606

Cre/oh.It.". Eltlr_t.bI. P.,tloul.tfI/NIOSH 5023

A.phalt Fumfl/NIOSH 0500

PoIr"ucl .... Arom.tlc

Hyci,oc.,bo",fNfOSH 5506

Cycloh.It.". ExIr_t.bI. P"';cul .,.tNJOSH 6023

A.phal, Fum';NIOSH 0500

Voit.JI. Ort/Mllo

Compou"d';QC·MS

A.phMf Fum.;NIOSH 0500

Crcloh.,..". EXlrltCt.bI. p.rri.:ul.,';NIOSH 5023

Vo"';I. Ort/."fc

Compou"d.tGC·MS


3.0 SURVEY RESULTS

The following tables present the summaries of the analytical results of air samples collected during the survey. The results are as follows:

SAMPLE

NUMBER

FNF·Q4

FNF·08

FNF·22

FNF· 13

FNF· 17

FNF-20

Asphalt Fume-NIOS H Method 0500

Sample Results

SAMPLE DA TE PAVING SAMPLE TYPE PROCESS

11116/94 416 Base Personal

Asphaftic

Concre/a M i>(

11/ 17/94 416 BaSil Personlll

Asphllflic

Concralll Mix

11/17/94 Fillid Blllnk Field Blllnk

12/09/94 Rubber Asphalt Personal

12/11194 Rubber Asphalt Pllrsonal

12/11/94 Blank Field Blank

SAMPLE

VOLUME

750 filerS

870 litllrs

N/A

822 liters

541 lilllrs

NfA

m!;llm' - m ill i!;lfSmS per cubic meter

SAMPLE

NUMBER

FNF·02

FNF·06

FNF-23

FNF-I2

Coal Tar Pitch Volatiles As Cyclohexane

N10SH Method 5023

Sample Results

SAMPLE DA TE PAVING SAMPLE TYPE SAMPLE

PROCESS VOLUME

11/16/94 4 16 Basil A'1I11 871.1 Litllls

Asphllltic

Concrete Mi>(

11/17/94 41 6 Basil A'''II 820.0 Litars

Asphaltic Concrate Mi>(

1//17/94 Field Blank Field Blank NfA

12/09/94 Rubber Asphalt Arall 834.3 Lit/us

4

ANALYTICAL

RESULT

0.86 mg/m'

0.94 mg/rrt'

N/A

0.44 mg/rrt'

30 m(l/m~

N/A

ANALYTICAL

RESULT

1.2 mr;/mJ

I . ' mr;/mJ

N/A

0.74 maim'


SAMPLE SAMPLE DA TE PAVING SAMPLE TYPE NUMBER PROCESS

FNF· I6 12/11/ 94 Rubber Asphalt Are.

FNF· I 9 12/11/ 94 Fi~/d Blank Fi~/d 81_"k

mg/m' . mill igram. pl r <;ubi<; m.tl'

Polynuclear Aromatic Hydrocarbons

NIOSH Method 5506

Sample Results

SAMPLE ANALYTICAL VOLUME RESULT

556.2 LirHs 5.7 mglm"

NlA NlA

SAMPLE SAMPLE PAVING SAMPLE SAMPLE ANAL YTICAL RESUL T NUMBER DATE PROCESS TYPE VOLUME

FNF·03 11/ 16/94 416 B.s. A,e. 871 . I N¥h/hal.". >3.0 JJglm' Asph.'tic liters A CM/lPhthyl4lle < 2 . 0JJ(Jlm~

COrlCrflrfl Mill ACM/lPhrn.o. > 7.0 JJ(}im3

Fluo,~". 2.0 JJ(JIrri'

Ph."an/h,.". 2.0 J.IfJ/m1 A"rh,"c"" . < 2 .0 JJ(JIm3

Fluor""th.". < O. 7 JJfJ/m3

Py,.". < ' .0 JJfl/m3

B.rlzo I.' anth'fIe"". <0.07 w l m3

Chrys"". < O. 7 JJfJ/m'

8411zo Ibl fluo,."th4ll. <0.07 wlm3

8411zo (k/ fluo,."the"e < 0.07 JJQ/m3

8""zo /_1 py'.". <0.07 w/m3

Oib4llzo I.,hl _"th,.ce". < O. , JJ(JIm ~

B."zo Ighi/ p.,yl.". <0.2 JJ(}im 3

I"de"o ",2.3·cd/ py,e". < O. , JJ(JIm3

5

FNF Cons truction, Inc. WT Job No. 2184JC248

SAMPLE SAMPLE PAVING NUMBER DA TE PROCESS

FNF·07 , III 7194 4'6 8Ma Asphlf{(ic

Concf8te Mix

FNF·09 , 1/17194 416 Bllse

Asphilltic

Conc,8le M ix

FNF· ' I 12/09194 Rubbe,

A sphillt

1l,\REPORl5'L4JC2o<e

SAMPLE SAMPLE TYPE VOLUME

A,~~ 816.0

lir"" s

Field NlA BIlJnk

Arelf 834.3

lilMs

6

ANAL YTICAL RESUL T

Nllphthlllen~ > 7.0 /Jg!m~ Ac~n~phthylen .. <:2.0PQlm~

Ac~nsphth "'ne > 10.0wlm3 Fluo,en8 1.0 pg!m' PhMlfnrhrene 1.0 pg!m~

Anthrlfcene <2.0pr1lm~

FluoflmrhMe <0.7wlm~

Py,ene < ' .Ol4Jlm~

8enzo fel Ifnrh'lfcene <0.07/Jg!m' Ch,ys8n8 < D. 7 /JQlm' 8enzo fbI f/uorlfnthene <0.07 PQlm~

Benzo Ikl f/uo,enthtlne <0.07PQlm~

Benzo leI pyren8 <0.07 wlm'

Dibenzo [8.hI ilnfhr8cen8 < 0.1 /JQlm'

Benzo IQhO p8rylene <0.2/1g!m' Indtlno {1,2.3·cdl pyrene <O.lpg!m~

None Detected

NlJphrhlllene 0.7/J(J1m'

Acenlfphthylene <2.0 JJg/m~

Acenllphthlme < 2.0 p(Jlm3

Fluorene 1.0/J(Jlm'

Phenenthrtlne 2.0 PQlm'

A nthrilcen8 < 2.0 /J(Jlm' Fluortln rhene <0.7 /JQlm~ Pyrene < '.0 PQlm' Benzo {ill ilnrhrscene <0.07 wlm'

Ch~ene <0.7 JlQl ro' Benzo fbI (Iuorli!nthene <0.07 JlQlm' Benzo {kl f/uorenthene <0.07 JI(Jlm' Benzo (ill pyrene <0.07 JI(Jlm'

Dibenzo (If,h) lJnthrecene <0. ' pglm' Benzo (ghi) perylene <0.2 pglm'

Indeno 1/,2, 3 ·cd) pyrene <0.1 Jlglro'


SAMPLE SAMPLE PAVING NUMBER DATE PROCESS

FNF· 15 12/11/94 Rubber Asphalt

FNF· 18 12/11/94 Rubbllr

Asphalt

" 1m , - micro rams , , e r cubic me ter

SAMPLE SAMPLE DA TE

NUMBER

FNF·Ol 11/16/94

FNF·05 11/17/94

FNF·24 11/17/94

FNF·10 12/09/94

FNF· 14 12/11/94

FNF·21 12/11/94

K :IN:PORTS~.IC~48

SAMPLE SAMPLE ANAL YTiCAL RESUL T TYPE VOLUME

A rea 553.5 Naphthalene

liters Acenephthylene

Acenaphthene

Fluonlnfl

Phenenthrene Anthr.cena

Fluortlmlhene

PyrtlntJ

BtJnzo lal anthracene

Chrysene

Benzo IbJ fluor.nthene

BfnzO IkJ f!uoranthllne

Bfn20 lal pyrBne

Dib'lnzo {a,hI anthracflnll

Ben20 Ighil PtJry/Me

Indeno 1I.2.3·cdJ pyrene

Field NlA Nona D~lectad

Blank

Volatile Organic Compounds

Method GC/MS

Sample Results

PAVING SAMPLE TYPE SAMPLE

PROCESS VOLUME

416 Base Are .. 56.80 LiltJrs

Asphaltic

Concrele Mi.

416 Basil Area 53.20 Uters

Asphaltic

COnCrfllll Mi.

Filed Blank Field Blank NlA

Rubber AsphlJ/r ArlJa 54. 27 LitfHS

Rubb lJr AsphlJl/ ArtJa 36.72 Liters

Field Blank Field Blank NlA

7

> 10.0 ~alm$

< 4.0W/m $

< 4.0 iJfl/m3

3.0 ~fl/mJ

5.0 iJalm$

< 4.0 JJfl/m 3

< 1.0 JJfl/m'

<2,OJJfl/m'

<0.1 JJfl/m3

<1.0JJfl/m3

<0.1 JJalm3

<0.1 JJ(l/m3

<0.1 JJfl/m3

<0.2 JJg/m3

<0,4 JJt;Im3

<0.2 JJt;Im'

ANALYTICAL

RESULT

StJe Lab Report

See Lab Report

SlIe Lab Report

SfllJ Leb RlJport

SlIe LIIb RtJport

See L.b Report


4 .0 SUMMARY OF FINDINGS

Ocupational exposure to airborne contaminats is regulated under 29 CFR 1926.55 • Gases, Vapors, Fumes, Dusts, and Mists by the Industrial Commission of Arizona's Division of Occupation Safety and Health Ad ministration, commonly referred to as ADOSH, 1926.55, Appendix A lists

permissible exposure limits (PELs) expressed as eight-hour time·weighted average exposures. ADOSH has enforcement authority for these exposure limits.

Note: The information presen ted below does not include the sampling data collected on December

11, 1994. Field reports indica ted temperature control problems with the asphalt on December 10 and 1', 1994. This could have caused an environmental change resulting in the sudden high particula te concentrations in air.

To investigate this theory, historical data from past air sampling using similar materials and paving

processes were researched. Data was requested and recieved from ACUMEN Industrial Hygiene,

Inc. the originator of the sampling protocol. Results of this research found concentra tions in air at or slighlty above our analytical values. As such, the outlier samples collected on December 1"

1994 ¥vere not used in the process exposure comparison. The data collected on December 1" 1994 cannot, however, be dismissed completely until a suitable explana tion can be found for the

excess airborne concentrations found. Further sampling under like conditions is recommended (0 collect more data.


4.1 Asphalt Fumes

Four personal air samples were collected to measure and compare asphalt fume during the 416 base asphaltic concrete mix and rubber asphalt paving processes. Three of these samples were used for this final discussion. These samples were collected from the breathing zone - shirt collar of the paving machine operator on November 16 and 17, 1994 for the 416 base asphaltic

concrete mix process and on December 9,1994 for the rubber asphalt process.

Based on research of 29 CFA 1926.55. there is no specific PEL f or asphalt fumes. In this case. the Arizona Division of Occupational Safety and Health (ADOSH) will mandate complaince to the total nuisance dust (particulate) PEL of 15 milligrams per cubic meter found in 1926.55. Appendix A. Data collected as samples FNF-04, -08, and -13 showed personal exposures at well below the PEl.

A comparison between the 416 base asphaltic concrete mix and the rubber asphalt processes based upon the data collected - December 11, 1994 data not included - found that the rubber asphalt process appears to produce less asphalt fume than the 416 base asphaltic concrete mix process.

4 .2 Cyclohexane Extractable Particulates

Unlike the asphalt fu me samples described above, the four samples collected for cyclohexane extractable particulates were area samples. The sample pumps and sample media used to collect particulate release during the 416 base asphaltic concrete mix and rubber asphalt paving processes were placed near the base of the paving machine using duct tape. These samples were collected at the same time as the personal samples for asphalt fume. Three of these samples were used for this final discussion (FNF-02, -06, and · 12).

There are no established PELs in the OSHA Construction Standard, 1926.55, Appendix A for "cyclohexane extractable particulates". The analytical protocol used NIOSH Method 5023-Coal Tar Pitch Volatiles. The PEL for Coal Tar Pitch Volatiles is 0.2 milligrams per cubic meter (mg /m3

).

This method is nonspecific and measures all volatile substances collected in the sample that are soluable in the extraction solvent, benzene.

Results of area air sampling - collected at the base of the paving machine - found a high concentration of extractable particulate in all collected samples. The analytical results; however, should not be used as a comparison to the OSHA PEl.

The benzene soluable fraction of coal tar volatiles consist of antracene, benzo la} pyrene, phenantrene, acridene, chrysene, and pyrene, all polynuclear aromatic hydrocarbons (pAHs). These PAHs were anaJytes using the NIOSH Method 5506 described in the Summary of Findings,

9


Section 4.3. Based upon the analytical results discussed in Section 4 .3, we conclude that the

majority of volatiles measured gravimetrically were not PAHs. Thus no overexposure appears to have occured, even though that soluable fraction does show a high concentration of extractable particulate .

Based on the data collected from sample Nos. FNF-02, 06, and -12 it appears that the rubber asphalt process produces less volatiles that were extractable from collected particulate. The rubber asphalt produced extractables at a concentration of 0.074 milligrams per cubic meter, while

the 416 base asphaltic concrete mix produced extractables of 1.1 and 1.2 milligrams per cubic

meter of air.

4 .3 Polynuclear Aromatic Hydrocarbons

In accordance with NIOSH Method 5506, Galson Laboratiores analyzed area samples collected

from the base of the paving machine for polynuclear aromatic hydrocarbons. Four samples were coliected, three were used for this final discussion. The listed analytes found to have an OSHA PEL are described below.

Contaminant OSHA PEL

Antracene 200 mg/mJ

Benzo fa} Anthracene 200 mg/mJ

Benzo [a} Pyrene 200 mg/m J

Chrysene 200 mg/m3

Napthalene 50,000 mg/ml

Phenantrene 200 mg/m J

Key: mg/mJ = milligrams per cubic meter

Analytical results suggests that polynuclear aromatic hydrocarbons (PAHs) in air are present,

typically in microgram per cubic meter concentrations. A microgram is one/mi lli onth of a gram, whereas a milligram is equal to one/thousandth of a gram. The OSHA PELs for the above listed

PAHs fange from 200 to 50,000 micrograms per cubic meter.

Upon comparison between the two processes, it appears that the rubber asphalt process as measured on December 9, 1994 produces less PAHs during normal operations. To make the

comparison, PAHs that had detectable concentrations in air were added, the sums compared.

K:IREI'OIHSI4JC248 10

FNF Construction. Inc. WT Job No. 2184JC248

The 416 base asphaltic concrete mix process (FNF-0 3 and -0 7) had total PAHS of 14 and 19 micrograms/cubic meter, whereas the rubber asphalt process had a sum total of 3 .7 micrograms per cubic meter of air (FNF- l1).

4 ,4 Volatile Organic Compounds

Analyzing bygas chromatography/mass spectrophotometry (GC/MS)' O&M Laboratories measured

exposure to several dozen volatile organic compounds , some of which have established OSHA PELs. The table below describes those compounds detected that had an OSHA PEL.

Cont aminant OSHA PEL

1 ,2-Dichlorobenzene (ortho) 300 mglm' - Ceiling Value

1 ,4-0ichlorobenzene (para) 450 mg/ml

1.2.4-andl .2.3-trimethylbenzene 120 mg/m l

Xylenes (all isomers) 4 35 mg/ml

Carbon Disulfide 60 mg/ml

Key: mg/ml

:: milligrams per cubic meter

Analyt ical results for t he above compounds were measured in micrograms per cubic meter. None of t he detectable com pounds were found in concentrations exceeding the OSHA PELs.

Upon comparison bet ween the two processes, it appears that the rubber asphal t process as measured on December 9, 199 4 produces less volati le organic compounds during normal

ope rations. To make the comparison. volati le organic compounds that had detectable

concent rations in air were added, the sums compared. The 4 16 base asphalt ic concrete mix

process (FNF-01 and -05) had total volatile organic compounds of 948 and 2431

micrograms/cubic meter, respectively, whereas the rubber asphalt process has a sum tot al of 121.3 micrograms per cubic meter of air IFNF-10).

11

APPENDIX A SAMPLING EQUIPMENT INFORMATION

Oilian

The Gil-Air SampJer

Operating Manual for the Gil-Air

Constant Flow Air Sampling

System Non-Timet Models: Gil-Air S Gil-Air EF Gil-Air CF Gil-Air CP Gil-Air U

Timer Models : Gil-Air S C Gil-Air EF C Gil-Air CF C Gil-Air CP C Gil-Air U C

The Gil_Air (tn-mode) Air S;ampling System

Addendum (10/1519\) to page 20 of the operating manual fo rthe

Gil-Air Co nstant Flow (tri-mode) Air Sampling System booklet no. FPRO-2302

Figure 5 Addendum (additional leak test con~gurGtlon)

Purpose of test To measure leak.ageofoutslde air mto any permn of the pump. while the pump IS subjected to a vacuum pressure of 20" of H2O.

Acceptance criteria: In a 30 second pcnod there should be no discernible drop of the 20 "head.

Withdraw plunger !O a suCtion pressure of 20" as read on manometer or calibrator panel.

SK 180"9

Synnge GOcc 19663) arc G~oan PH 401674

Gj·Ar Sam~(l<

/

----

·0 \99 \ G<harl Irl5lfumenl Co,p . IOfm riO FAD D·430

Addendum - 4.J le;ak Teu CQnfiguntiQn

W.l1er Trap

~20. H.od

Manometer

APPENDIX B LABORATORY REPORTS

3700 LakeYille Highway. Petaluma. CA 94954 Telephone: {70l} 763-8245 FAX {70l} 763-4065

Mike Campbell Western Technologies 3737 E. Broadway Rd. Phoenix, AZ 85040

Customer Project: 2184JC248 Laboratory Job: L9411169

December 5, 1994

On November 19, 1994 we received 3 sample(s) for analysis. Samples were analyzed by the following method (s) :

VOC's (GC/MS Semi-Quantitative Analysl's)

Project Manager Laboratory Director Robert Peak

0'" Laboratories AULTTICAl PATA REPORT

Preparea for: ~estern Technologies Project Id, 2184JC248

Pu_t'e;r . . --Vatue

R~rted : 05-0eC-94

Rill. ". "-unJ.tt" .. ," .... :_l!i_(tiK:_tilf!Wt~'"

Lab ld: L9411169-1 S"""le ld: fNF-Ol

GC/IIS semi -",,$nt i tat i ve

'" UNKNOWN ORGANIC COMPOUNDS l'ethyl-2-methyl-benzene XYLENES OECANE 1 , 2,3 - TR I/IETHYLBENZENE 1,2,4- Trin:thylbenlene 1-methyl-l-propyl-benlene BUTYL BENZENE UNOECAN£ l-Ethyl-2,3-0imethylbenzene Z-ethyl-l,3-dimethyl-benzene 2,3-0IHYORO-4-IIETKYL-1H-INOENE

Cornnents :

Lab Id, 19411169-Z SaIIJI1e Id: fNf-05

GC/IIS Sem;-""antlt~t;ve

". Propyl benzene '- ethyl-Z-methyl-benzene XYLEN£S I,Z-Oichlorobenzene l,l-Oichlorobenlene 1,4-0ichlorobenlene 1,2,4-Trinethylbenlene 1,2,3-TR1ME1HllBENZENE 1- ethyl - 3- methyl -benzene l-methyl-l-propyl-benlene l-Ethy l-Z,3-0imethy lbenzene (I-Methylethyl)-Benlene

Cc:mtents :

Lab Id: 19411169-3 S"""le Id: '"' GC/IIS Semi-quantitative

'" NO PEAKS DETECTED

Cc:mtents,

56.80

"'. rr. 20. 52.

'" 53. n.

'10 OS. " . ,'-

'50

<o~

53.Z0

'" '" 11.

'" lO.

". '" ". 14. ". '" '10

"~

BLA)jK

" <

"~

Collected: 16-NOV-94

'-' 1 ,., UII/~

'-' ",03 '-' ug/ml '-' """" '-' "',"" ,., ""'" ,., "',"" '-' "',"" '-' "',"" ,., "',"" ,., "',"" '-' "',""

Collected: 16-NDV-94

U 1 U """, U ""'" U ,,"'" U ug/ml U ug/ml U ug/ml U ug/ml U ug/ml U ug/ml U ull/ml U "',"" U "',""

Collec ted: 16-1IOV-94

0.25

.f

1 ug/tube

Received: 19-NOV-94

01-0£C-94 01-0EC-94 01-0£C-94 01-0EC-94 01-0EC-94 01-0EC-94 01-0EC-94 01-0EC-94 01-0EC-94 01-0EC-94 01-0EC-94 01-0£C-94 01 -0EC-94 01-0EC-94 01-0£C-94 01-0EC-94 01-0EC-94 01-0EC -94 01-0EC-94 01-0£C-94 01-0EC-94 01-0EC'94 01-0EC-94 01-0EC-94 01-0EC-94 01-0£C-94

Received: 19-Nov-94

01-0EC-94 01-0EC-94 01 -0£C-94 01-0£C-94 01-0£C-94 01-0£C-94 01-0£C'94 01-0EC-94 01-0£C-94 01-0EC-94 01-OEC-94 01-0£C-94 OI-OEC-94 01-0£C-94 01-0EC-94 01-0£C'94 01-0EC-94 01-0£C-94 01 -OEC-94 01-OEC-94 01-0EC -94 OI-OEC-94 01-0 EC -94 01-0EC-94 01-0£C-94 0\-OEC-94

Received, 19-NOV-94

OZ-PEC-94 OZ-OEC-94 02-0EC-94 02-0EC-94

3700 Lakeville Highway, Pe!aluma. CA 94954 Telephone: (707) 763-8245 F,tJ( (707) 763-4065

Mike Campbell Western Tec hno l ogies 3 7 37 E. Broadway Rd . Phoenix, AZ 850 40

Customer proj ect: 2184J C248 Laborato ry J ob: L9412126

De c ember 30, 1994

On Dec ember 14, 1994 we received 3 sample (s ) f o r analysis. Samples were analyzed by t he followi ng method es ) :

VOC's (GC / MS Semi-Quanti t at i ve Analysis)

Laborato ry Direc t o r Robert Peak

Project Id: 2184JC248

Lab Id : L9412126-1 S~le td:

G.C/MS Sml-q.l.ntitative

'" ~YlENES

OECANE Carbon Disul f ide 1- ethyl- 2-methyl- bentene 1,2,3-TRIMETHYLBENZENE

Ccmnenu:

Lab Id: L9412126-2. S~\e Id:

GC/MS semi-q.uu>t l tat ive

'" XYLENES Carbon Oisulfide \-ethyl-2-methy l -ben~ene Of CANE l-ethyL-4-methyl-ben~ene

0'" L&bcra tor ies ANALY TICAL OATA REPORT

?repared for: ~estern Technologies

fNf- l0 Collected:

54.27 , ". '-' ug/m3

". '-' ug/m3 10. '-' .. I'" 36. , .. ""'" ' .3 , .. ",I'"

.~

fNF -1 4 COlle.: ted:

36_72 , ". .. , ",I'" 13. .. , ug/m3 22. .. , ug/m3 .s. .. , ug/r.3

". .. , ",I'" l-methyl-3-prcpyl-benzene ". .. , ug/m3

Ccmnents:

Lab Id: L9412 126-3 5~le Id: FNF-2 1

GC/MS Semi -quant i tat ive

'" NO PEAKS OETECTEO

CClln'llents:

"M

BLANK

"' .~.

Co l lected:

0.25

, 0'

, ug/ tube

Reported: 30-0EC-94

Extrac:tCd;Analy_Utt ,.

RlI'Ceived: 14-0EC-94

23-0EC-94 23-0£C-94 23-0EC-94 23-0EC-94 23-0£C-94 23-0EC -94 23-0EC-94 23-0Ec-94 23-0EC-94 23-0fC -94 23-0EC-94 23-0EC-94

Received: 14-0EC-94

23-0EC-94 23-0EC-94 23-0EC-94 23-0£C-94 23-0EC-94 23-0EC-94 23-0£C-94 23-0EC-94 23-0EC-94 23-0EC-94 23·0EC-94 23-0EC-94 2.3-0EC-94 23-0EC-94

Re.:e ived: 14·0EC-94

23-DEC-94 23-0fC-94 23-0EC-94 23-DEC·94

HOO L .... _ 1iiQh ..... ,,,,,,,",", CA .. U~ ·0 10 < 1010l ' . ,,,_. CA ",n·IOl'

-_ .... '101)11)·1105 , .. : ,101111)·..,'5

TELEPHONE NO:

. ..

RELINQUISHED FROM LAB BY: (SIGNATURE)

SAMPLING DATA · ANALYSIS REQUEST

SAMPLE LOCATION OR DESCRIPTION

". if

I PO. NUMBER:

: RELEASE NO:

i SURVEY NO.

, ~L

~ Vt>C )-

I,)'. z.. ,= , JOc.!

~ I lo r.tL-~'f

AUTl-IORI ZED SIGNATURE:

OATEITIME

RECEIVED BY LAB BY: (SIGN JUR

R IVEOBY: (SIGNATURE)

" /1 ~

l 700 LoO. ...... ~" .... , P., ......... CA ,UM >,0 . .... 101014. P"_o, '.0.14175-'01'

' " .. ..,... : 07011 7U·11'5 ~."' 007) 763·0065

SAMPLING DATA - ANALYSIS REQUEST

Y7J'/ E W P'-'')Y 12'" I'ik...;:)<. 42- "0'/0

SAMPLE lOCATION OR OESCRIPTION

P.O. NUMBER: ;l.18,{)C2~8

RELEASE NO:

SURVEY NO:

:5:6#

d-

H/ &-:;4'1. 75 To AI,ke ~/'~/J 45'¥

!;t~ '# &o:L - '170 -/.7'1/ ' p~ 602. - ,/.1/-37//

(GIVE

. ,

AUTHORIZED SIGNATURE:

REu;;~eo BY: DArEITIME " IVEO 6Y LAB BY:

(51 ArURE) ~ 1 . pJJ-14 W:.;, l (SIGNATURI;:) \2 h k c, '':-/c. .{/ ~Yv\ \~ AeUN~~ISHED'FROM LAB BY: OATEITIME RECI::%~D BY:

(SIGNATURE) (SIGNATURE)

!eGaISOn Request For Industrial Hygiene Analysis Laboratories 6801 KlrIcviIIe Road east E. SY'.cuse. N_ York 13057 (31S)-C2'()506 Of (800)·950-0506 Fu:(31S}-431-0571

Company

Sampled ,/ '/ I Project No.

Send Invoice to:

Please check all that apply: Turn-Around Time

IZf -Standard Service (10 Workmg Days)

o . Rush Service. Date results requested bY:====:::~:~::~~i~~E~~~= I2f:""Fax results IO:_~j'.~~""~---'---'-r----- Please Provide Fax If (601.. 1 - J~9/ 0- Phone results to: ;;rA.~1/ Please Provide Ph 11 - 3'"7:J:J

• Please refer to our tee sche<h,lle tor rusn service charges. Please InqUire lor capaclly of rusn analYSIs.

OSHA Compliance? Y N (Please Clfcle) Samples collected In New York Stale? Y N (Please Circle)

Sample Identification Date Sampled : Sample Medium:

FII/;=: -0<... WesteYn Technologies, Inc. L21 0e.S-l 11/19/ 94 *Filtpy F~F-O~

p./;=: - 06 I lf-I>-'1'f I \ 320.0 Technolog l e:: , . nc . L2 10£,'S-3

.: Fi lter L?B BLANK Wes tern Techn o logies, In c . L2 10(.5-:! . ~e st£lr n

1

11/19/ 94 ~ F:iltey FNF -06 ~~~1

F.M~ - O'f 11/76 -~" II~:-~c AI~ We s teyn Technologies , Inc. L210E.S- l 11 / 19/ 94 *Fi lter FNF -04

I p,uf'-pg i /I-i)-ff' Western Technologies, Inc . l21 0bS- "· Wester-n Ted.nologier. , In c. L210e.S-e. 11 / 19/94 *Filter FNF -08 .i ' , 13,'O< *F ilt£lY LA.B BLANK _~, IF.LV-03 IIt-Ib-9f I"\&\""';(.i)( 37J.1 I \~ - rJ7J?

L210e.5-7 \ 'J "7' We s tern Technologies , I nc. 11/19/94 Filt£l-rTube nlF-03

1 FAlr-O/ 1,1-J7-1Y I Western Technologie s , Inc. ! Filter-Tube FHF- 07

Cham

I d by LAB:

L2106S-B

I received after 3pm will be

'Ofb,O

i as neKt day.l'!! i

Tkfo wh,t_ I'!nnv WIll ........ " .......... ",~ '''' .. ~ ... ..... ... 0 1 .................. ........... ,. ---" '- ' "-'" ._-_ ... .

A Galson Request For Industrial Hygiene Analysis ~ Laboratories

v~,;: 6601 Kifltv,ntl ROlla East - ~. E. Syracu$e. N~ York 13057 (315)·432-<1506 or (800).95Q-{lS06

Sampled By: (; P'ojecl NO,~" ;!. 'IS Fu,(31 S)·~37.()571 i,(~/I

Seo. Report 10' ~ Send Invoice to: r,>;Ve

P.O. No.1

Please check all thai apply: Turn-Around Time

18l- Standard Service (10 Working Days)

D ' Rush Service. Date results requested b\

~ - Fax results to: Aik ~~¥,,r. // Please Provide Fax N (&,!..l) l iV/

r;:J -Phone results to: /0//4- a.~,PDo/J Please Provide Ph" 1,(, ~ I '>

• Please reler 10 our lee schedule for rush seMee chargeS. Please mqulre to( capacity ot rush analysIs.

OSHA Compliance? Y N (please Circle) Samples collected in New York Stale? Y@{PleaseCirCle)

Sample Idenllficauon Date Sampled: Sample MedIum: Air Sample AnalysIs Method

Volume (li ters)" ReqUired; Reference:

I-tJF -II 17-(; ;- -'1'0/ :l3U \'~ ; -

jes t~rn T eehnol ogll~s, Inc. L21369-! . 2/14/94 FilterTube Ftl F- l l

I F,vr -15' I 1 2-j1.~4 I ))3) t6

j~stcrn Tee hnol~gles, Inc. 1.21369-2 1::14/94 FllterTube ~'NF-15

1 ;-1); - , 2- ltJ. <L;'~ I :3J" J 1~ \Y <"', £¥{l. 'Ies te rn Teehnolog l£.S, Inr:. '.:136'3-4 ':114/94 ;,Filter FHF ·1 :

~ I Ao'F-/L I 1 ~1/' '1~ , sn J.-- d , ,

este r n Tee hno log i as, Inc, l:13£,1-'" ·:/ 14 /94 ~F i lter FHF-16

I F I' . ./r: -IJ I') -<'7-7')1 I I ,?N. ~ \.\"::::. .. "",-C5C'£ '

'~es te rn T ee ~,nol og les. lnc. l21369-7

'"' -'Filter S:-HF-13

f'l./F - 17 I : )-11 -"'-/ I 5'11, / 6l)Z't-'1 . ' - -. -'4e .. tern Technologies. Inc . l21 '3':'9-8

' - I·', ' - - . ~~'1 ~/94 .. S:-ilter FNF-17 , 1"0< paSSive monllOfS please IIsl lime exposecl ln minutes.

Comments:

Ct"" ' 0",' I lb, !::ft , ,/. ,,, 'dl ,IHj '?

i ",I '(I! flu j.> I' /2- ". ' ,

I received aiter iI be considered as next day's business."

eGalson Request For Industrial Hygiene Analysis Laboratories 660 1 Kil'lntlile Road East

Company Name: /: c=7k~" - ..-e. Sy'f&cuse. N_ YOl~ 13057 /~-h ~'L',"';: ES (315)...:l2-0506 or {800j-950-0S06

Sampled By:C:;::;:. __ .---/,w/ I Pmj'" NO.2;j'fX'_;>''fY F.,. ,(315)-43Hl571

Send Report to: ~~~C~$c, Send Invoice to: ~4..-~

P.O. NO.N

Please check a1llhal apply: Turn-Around Time

~ • Standard Serv ice (10 Working Days)

o . Rush SeNiee. D~te results requested by:

(2g. Fax results to: HI:<'" (?Wk,/ Please Provide Fax If (60)"') - y>c,;' -I..J<iI /

IS3 -Phone results to: r~~,:-, Please Provide Ph If (~1' ) -~". ..., - "''7~./'''''

• Please refer to our lee schedule lor rush service charges. Please Inquire for capacity of rush analysIs.

OSHA Compliance? y N (Please Circle) Samples collecled In New York State? y N (Please Circle)

Sample Identification Date Sampled : Sample Medium: Air Sample AnalYSIs Method

Volume (liters)' ReqUired : Refemnce:

- , ~ :;j ;..1 ... ,- _ / . /J, -I/J} 'f -G- \'~~ :rrC'(, West;;>)'"n Tachnologies, Inc. L2 1369-3 12/ 14 ,)4 Fll tE'l'illbe FIlF-IB [(LAHK

I p,;=- / i I Il -II ~19 I -;;.- <:. ~ ":::':' )0'-'3 ,Jestel'n Technolog1.9s, Inc. L21369-f. l 2/14/'?.:l *Filhl' FNF-t') BLM~K

I hL'F -J. u Ii.?· '11-;77' I -?- ~~ O§"O <.J

\Jestel'n rec~,n ol og i es, Inc . LZl:;69-~

12114/ 0 11 .'!Fi::' tel' FHF-:O BLANK

:¥<' This 5p«;'fJ fa LAB USB only .

Thl$ Spacs for LAB USB only • ~"

. " ",-This 5p«;'fJ for LAB use only "

. , •

• . For passIve mOnitors please list time exposed In mmutes

Comments:

Cham 01 Custody: (ff'G(/ /0

~ Ignature' Date:

Relinquished by: ~ '.,t.;y (/ p r I/L -,;-7'f Recetved by LAB: 1\Ct t I ' .. Kr., ,,.,, •• q

MSamples received atter 3pm will be considered as next day's bU5 iness. ~

Galson Laboratories

6601 Klfkv~1e Road E.S~.NYl3057 Tel. (315) 432·0506 '·800·950·0506

DOH ELAP # 10186

Mr. Mike Campbell Western Technologies, Inc. 3737 East Broadway Road Phoe nix, AZ 85040-2966

Re: Client Account # i0185

Dear Mr. Campbell:

December 5, 1994

Login # [21065

Enclosed are the results of the analyses performed on the samples received by our laboratory November 19, 1994.

Please contact OUf Industrial Hygiene Client Services, at (800) 724-0669 extension 305 or 200. if you require additional information regarding Ihis report.

Thank you for using Galson Laboratories.

Enclosurc(s)

Sincerely.

Caison La boratories

Gale G. SUllon, CIH LaboralOry Director

Galson Laboratories

DOH ELAP # 10186

Mr. Mike Campbell Western Technologies, inc. 3737 East Broadway Road Phoenix, AZ 85040-2966

Re: Client Account # 10185

Dear Mr. Campbell:

December 29, 1994

Login # 121369

Enclosed are the results of the analyses performed on the samples received by OUf

laboratory December 14, 1994.

Please contact our Industrial Hygiene Client Services, at (BOO) 724-0669 extension 305 or 200, if you require additional information regarding this repon.

Thank you for using Galson Laboratories.

Enclosure(s)

Sincerely,

Caison Laboratories

Gale G. Sutton, CIH Laboratory Director

,:., dMSIOf\ 01 Galson Corooralkln . Inc.

Galson LABORATORY ANALYS IS REPORT Laboratories

client : Western Technologies, Inc. Site : NS Date Sampled Date Received

Acenaphthene

16 -NOV-94 - 1 7 -NOV-94 19-NOV- 94

Account No .: 10185 Login No. L21065

Air Vol Filter Front Back Total Sample ID Lab ID 1 "9 "9 "9

1"1'11"-03 7 811 .1 < 2 . D 4.4 > 2. 1 FNF-07 8 8 16 . 0 < 2. D 6 . 5 > 1.6 FNF-09 BLANK 9 NA < 2.D 1.5 < D. 7

"; OMMENTS: Front section va l ues have been corrected for the blan k in the t otal ug and mg/m3 va l ues .

" 9

> 5 . D > 6.6 < 2.0

* Total ug reported as ( » designates possible breakthrough or migration.

Level o f quant itation: Analytical Method OSHA PEL (TW .... ) Collection Media

2 "9 NIOSH 5506 NA Filter & Tube

Submitted by : ES Approved by : DB Date : OS-DEC-9 4 QC by: .:.;;. l Faxed: ttl: t ~ '3S~Phoned:

mg/m3

> 0 . 007 > 0 . 01

NA

< -Less T han mg -Milligrams ug -Micrograms ND -Not Detect ed

mJ -Cubic Meters 1 -Lit ers

kg -Kilograms > -Greater Than :111. -Not Appl i cable ppm -Parts per Mil l ion

NS -Not Specified

Fi e l d s ampling was not performed by Ga l son. Ga lson present s results based on sampling data ? rovided by c lients .

page 1 o f 18

o

Galson L~BORATORY ANALYSIS REPORT Laboratories

Client : Western Site 'NS Date Si!lmpled Date Received

Acenaphthylene

Sampl e m Lab m

FNF-03 7 FNF-07 8 FNF-09 BLANK 9

Technologies, Inc .

16-NOV-9 4 - 11-NOV-94 19-NOV- 94

Air Vol Filter 1 09

811. 1 < 2 . 0 816 .0 < 2 . 0

'" < 2.0

Level of quantitation: 2 ug Ana lytica l. Method NIOSH 5506 OSHA PEL (TWA) NA Collection Media Filter & Tube

Account NO.: 10185 Login No . L2l06S

Front Back Total 09 09 09

< 0.7 < 0.7 < 2 . 0 < 0 . 7 < 0 . 7 < 2.0 < 0.7 < 0 . 7 < 2.0

mg/m3

< 0 . 002 < 0.002

NA

Submitted by : ES Approved by : DB Date : 05-DEC-94 QC by: ,;;-" i Fax ed UC 06 T!l. Phoned:

<: -Less Than > -Greater Than ,lA -Not Applicable

mg -Milligrams ug -Micrograms NO -Not Oet ected

m3 -Cubic Met ers 1 -Liters ppm -Parts per Million

kg -Kilograms NS -Not Specified

Field s ampling was not performed by Galson. Galson presents results b a sed on sampling data provided by clients .

page 2 o f 18

o

Galson LABORATORY ANALYSIS REPORT Laboratories

Cl ient : Western Technologies, Inc . Site : NS Date Sampled Date Received

16-NOV- 9 4 - 17-NOV-9 4 19 -NOV- 94

Account No .: 10185 Login NO. L21065

Anthracene

Air Vol Filter Sample ID Lab m 1 u9

FNF-03 , 871.1 < 2.D FNF-07 8 B16. 0 < 2 .0 PNF-09 BLANK 9 NA < 2 . 0

Leve l of qu ant itation : 2 ug NIOSH 5506

'" Analytical Method OSHA PEL (TWA)

Co l lec tion Media Filter 6< Tube

< -Less Than ~ -Greater Than 'IA -Not Applicable

m9 -Milligrams ug -M i crogI"3mS NO -Not Detected

Fr ont Back. Total m9/m3 u9 ug u9

< D.' < D. , < 2 . D < 0 . 002 < D. , < 0.' < 2 . D < 0 . 002 < 0.' < 0.' < 2 . D NA

Submitted by: ES Approved by : DB Date : 05-DEC-94 QC by : :.. ' I Faxed:i:£t J"o 'i~_ Phoned :

m3 -Cubic Meters 1 -Lit ers ppm -Farts per Mil l ion

kg -Kilograms NS -Not Spe cified

Field sampling was no t performed by Ga lson. Galson presents results based on sampling data ?rovided by clients .

page 3 of 18


Client: ''''estern Technologies, I nc . Site NS Date Sampled Date Received

16-NOV-94 - 17-NOV-94 19 - NOV-94

Benzo(a)anthracene

Sample 10

FNF-03 FNF-07 FNF - 09 BLANK

Lob

7 8 9

Air Vol ID 1

871 . 1 8 16. 0

NA

Level of quantitation: 0 . 06 ug Analytical Method !HOSH 5506 OSHA PEL (TWA) NA

Filter ug

< 0 .06 < 0.06 < 0 . 06

Collection Media Filter," 'rube

Account No.: 10185 Login No. L21065

Fronc Back Total ug ug ug

< 0.02 < 0.02 < 0.06 < 0 .02 < 0.02 < 0.06 < 0.02 < 0.02 < 0 . 06

mg/m3

< 0.00007 < 0.00007

NA

Submitted by: ES Approved by : OS Date : OS-DEC-94 QC by: _ ", -' Faxed: DEt: .,; 5 994 Phoned:

<: -Less Than > -Greater Than -fA -Not Applicable

mg -Milligl."ams ug -Micrograms NO -Not Detect ed

m3 -cubic Meters 1 -Liters ppm -Parts per Million


?ield sampling was not pe~formed by Ga l son . Gal son presents results based on sampling data ? rov ided by clients.

page 4 of 18

Galson LABORATORY ANALysts REPORT Laboratories

Client : Western Technologies, lnc. Site : tlS Dace Sampled Date Recel.ved

BenZO(ll)pyrene

Sample 10 Lab 10

FNF-OJ 1 FNF-07 8 FNF-09 BLANK 9

Level of quantitation: Analytical Method OSHA PEL (TWA) Collection Media

16-NOV-94 - 1 ~ - !10V-9 4

19-NOV-94

Air Vol , . 871.1 816 . 0

NA

0 . 06 ug NIOSH 5506 ,.

Filt.er ug

< 0.06 < 0 . 06 < 0 . 06

Filter &- Tube

Account No.: 10185 L09'1n No. L21065

Front Back Total u9

< < <

u9 ug

0 . 02 < 0.02 < 0.02 < 0.02 < 0.02 < 0.02 <

Submitted by : ES Approved by : DB Date : OS-DEC-94 QC by : - '

0.06 0.06 0 . 06

mg/m3

< 0 . 00007 < 0.00001 ,.

Faxed: lEt 0 E ...... Phoned:

<: -Le88 Than -, -Greater Than I]; -Not Applicable

mg -Hl.lligrams ug - rHcrogr ams NO -Not Detected

m3 -cubic Meters 1 -Liters ppm -Parts per Million

kg - Kilograms NS -Not Specified

~ie ld s ampling was not performed by Galson . Galson presents resu lts based on sampling data )rovid~d by clients .

page S of 18

o


Client , Wescern Technologies. Inc . Site : NS Date Sampled 16- NOV-94 - !~-NOV-94

Date ReCGLVed 19-NOV-94

Ben zo(b)fluoranehene

Sample 10 Lab IO

FHF- OJ 7 FNP-07 8 I"N.- 09 BLANK 9

Level o f quantitation : Ana lytical Method OSHA PEL ( TWA)

Collection Media

Air Vol 1

871 . 1 816 . 0

"'

0 .06 1.19 NIOSH 5506 NA

F ilter ug

< 0 . 06 < 0 . 06 < 0 .06

Filtor & Tube

Account tlo . : Login No.

IDles L21065

Front Back Total yo uo u 9

< 0 . 02 < 0.02 < 0 . 06 < 0 . 02 < 0.02 < 0.06 < 0 . 02 < 0 . 02 < 0 . 06

mg/m3

< 0 . 00007 < 0.00007

"'

Submitted by : £5 Approved by : OS Date : OS - DEC- 94 QC by: - " Faxeddit O'e ~ Phoned :

< -Less Than > -Greater Than lA -Not Applicable

mg -Milligrams 1.19 -Micrograms NO -Not Detected

mJ -Cubic Meters 1 - Liter s ppm -Parts pe r Mill ion

kg - Kiloqrams NS -Not Specified

field s ampling was not performed by Calson . Calson presents results based on s ampling data ? r ovlded by c lients.

page 6 of 18


Client : Western TechnologLes, Inc . Site ,NS Date Sampled Date Received

16- NOV- 9 4 - 17 - NOV-94 19-NOV-94

Accoun t No.: 10 185 Log in NO . L21065

genzo(gni)perylene

Sample m L.b m

FNF-OJ 7 FNF-07 8 FNF-09 BLANK 9

Level o f quant i tat ion :

Ai r Vol 1

871 . 1 816. 0

"'

0 .2 ug N!OSH 5506

'"

Filter

"9

< o. , < o. , < 0 . 2

Analytica l Method OSHA PE L (TWA )

Col lection Media Filter & Tube

< -Less Than ~ -Greate r Than ~A -Not Applicable

mg -Mi l ligrams ug -M i crograms NO -Not Detected

Front Back Total mg/mJ "9 "9 "9

< 0 . 07 < 0 . 07 < o. , < 0 .0002 < 0 . 07 < 0 . 07 < 0 .2 < 0 .0002 < 0 . 07 < 0 . 07 < 0 .2 NA

Submitted by : ES Appr oved by : DB Date : OS-DEC- 94 QCby: - . ,- ' Faxed: 00:: '- c :r,. Phoned :

m3 -cubic Meters kg -Kilograms 1 - Liters NS -Not Specified ppm -Parts p e r Million

Fie ld sampling was not performe d by Galson . Galson presents results based on sampling data ~rov ided by cl ients.

pa ge 7 of 18

Galson :".>,.BORATORY ANALYSIS REPORT

Laboratories Client : Weste rn Technologie s, Inc . Site : tIS Date Sampled 16-NOV-94 - 17-NOV-9 4 Date Received 19-NOV-94

Benzo(k)fluoranthene

Samp l e ID Lob 10

FNF-OJ , FNF-01 a FNF-09 BLANK 9

Level of quantitation:

"ir Vol 1

871.1 816 . 0

"'

0 . 06 ug NIOSH 5506

N'

Filter vg

< D.06 < 0 .06 < D. 06

Analytical Method OSHA PEL (TWA )

Collection Media Fi lter & Tube

<; -Less Than > -Greater Than 'Ill. -Not Applicable

mg - Mi ll i grams ug - Micrograms NO - Not Detected

m3 1 ppm

Account No.: 1 0185 Login NO. L21065

Front Back Total ug ug ug

< 0 . 02 < 0 . 02 < 0.06 < 0 . 02 < 0 . 02 < 0.06 < D. 02 < 0 . 02 < D. 06

mg/m3

< 0.00007 < 0 . 00007

"'

Submitted by : ES Approved by : DB Date : 05-DEC-94 QC by : .. :..a. L , Faxed: - . Phoned :

-Cubic He ters kg -Kilograms -Liters NS -Not Specified -Parts per Million

F ield sampling was not performed by Galson. Galson presents results based on sampling dat a ?rovided by clients .

page 8 of 18

o

Galson ~~BORATOR¥ ANALYSIS REPORT Laboratories

Client : We ste r n Technologies, Inc . Site : NS Date Sampled Date RecElJ.ved

16-NOV-94 - 17-NOV-94 19-NOV-94

Account 110.: 10165 Login No . L2 1065

Chrysene

Sample ID L . b I D


Leve l of quantitation:

Ai l:" Vo l 1

871 . 1 816 . 0

NA

O. £' ug NIOSH 5506 NA

Filter u g

< D. ' < 0.' < 0.'

Analytica l Method OSHA PEL I TW A) Co l l ection Hedia Filter & Tube

< -Less Than ~ -Greater Than 1A -NOt Applica ble

mg -Milligrams ug - Micrograms ND -Not Detected

Front ug

< D. 2 < 0.2 < 0 . 2

Back Tota l ug ug

< D. 2 < < 0 . 2 < < 0 . 2 <

Submitted by : ES Approved by : DB Date : OS-DEC- 9 4 QC by: ' .

0 . ' 0 .' 0 . '

mg/m3

< 0 . 0007 < 0 . 0007

NA

Faxed $ f) ~ 'nI. Phoned :

m3 -Cubic Meters 1 -Liters ppm -Parts p er Million

kg - Kilo grams NS - Not Specified

?ie l d sampl ing was not pe r formed by Ga l son , Ga lso n present s results based on sampling data ?rov~ded by c l ients,

page <;> o t 18

o

Galson LABORATORY ANALYSIS REPORT

Laboratories Client : Wester n Technologies. Inc . Site : NS Da te Sampled Da t e Received

Dibenzo(a,h)anthracene

Sample 10 Lob ID

FNF- OJ , FNF- 07 a FNF-09 BLANK 9

Level of quantitat~on :

16- NOV-94 - 17 -NOV-9 4 19-NOV-94

Ai r Vo l 1

871 . 1 816.0

"'

0.09 ug NIOSH 5506 ,,.

Filter vg

< 0 . 09 < 0 . 0 9 < 0 . 09

Account No .: 10185 Login No. L21065

Front Back Total vg vg vg

< O. OJ < 0 . 03 < 0.09 < 0 . 0) < 0 . 03 < 0.09 < 0 . 03 < 0.03 < 0.09

mg/m3

< 0 . 000 1 < 0 . 0001

NA

Analytica l Met hod OSHA PEL ( TWA ) Collection Media Filter & Tube

submitted by: ES Approved by : DB Date : 05 - 0EC- 94 QC by : ~- •. Faxed: iJ£C • (. ~ ,. Phoned:

< -Less T han > - Grea ter Than NA -Not Applicable

mg -Milligrams ug -Micrograms NO -NOt Detected

mJ -Cub i c Heters 1 -Lite r s ppm - Farts per Mi l l ion


?ield sampling was not performed by Galson. Galson presents results based on sampling data 9 rovided by clients.

page 10 of 18


Laboratories Client : Western Technologies, Inc . Site NS Date Samp l ed :6-NOV-94 - 17-110V-94 Account No. : 10185

Login NO. L21065 Date Received 19 - NOV-94

F luoranthene

sample m Lab m



Air Vol 1

871.1 816.0

NA

0 .6 ug NIOSH 5506

"

Filter

" 9

< o. , < 0 . ' < 0 . '

Analytical Method OSHA PEL (TWA) Collection Media filter & Tube

<: -Less Than > -G reate r Than :lA -Not Applicable

mg -Milligrams ug - Micrograms NO -Not Detected

Front "9

< 0 . 2 < 0.2 < 0 . 2

Sack Total "9 " 9

< 0 . 2 < < 0 . 2 < < 0 . 2 <

Submitted by : ES Approved by : DB Date : OS-OEC-94 QC by : •

0 . ' 0 .' 0 .'

mg/ro3

< 0.0007 < 0 . 0007

NA

Faxed : r:EC .~!:. ¥>- Phoned :

m3 -CubiC Meters 1 -L iters ppm -Part s per Million


?ield sampling was not performed by Galson. Galson presents results based on sampling data ?~ovLded by clients.

page 11 o f 18

Fluorene

Sample 10

FliP-OJ FIIF-a?

Galson Laboratories

Client ; Mestern Site : liS

Date Sampled Date Recel.ved

Lab rp

, •

~'NF-09 BLANK ,

Level o f quant i tation: Analyt ica l Method OSHA PEL (TWA) Collection Media

LABORATORY AllA.!.YS!S REPORT

Technologies, Inc.

16 -NOV-94 - 17 -NOV- 94 19-NOV-94

Air vol 1

871 . 1 8 16.0

"'

0.6 ug tHOSH 5506 NA

Filter u g

< 0.' < 0 . ' < 0 . '

fil ter & Tube

.'1ccount No.: 10185 Login No . L21065

f"rOnt Back Total ug

I. ' 1.0

< 0.2

u g uo

0 . 2 < 0 . 2 < 0 . 2 <

Submitted by : ES Approved by : DB Date : D5 - 0EC-94 QC by: .

I., 1. 0 0 .'

mg/m3

0 . 002 0.001

NA

Faxed: tit r:: Phoned:

< -Le86 Than > -Greate r Than I", -Not Applicable

mg -Milligr ams ug - Micrograms NO -Not Detected

m3 -Cubic Heters 1 -Liters ppm -Partl per Million


Field sampling was not pe rf ormed by Galson . Galson presents results based on sampling data pr ovided by clients.

page 12 o f 18

o

Galson LABORATORY ANALYS IS REPORT Laboratories

Client : Western Technologies, Inc . Site : NS Date Sampled ;late Rece ived

16-NOV-94 - 17-NQV-94

19-NOV-94 Account NO.: 10185 Login No. L21065

Indeno(123-cd)pyrene

Air Vol Filter Sample ID Lob 10 1 "9

FNF-OJ , 871.1 < 0 .1 FNF-D7 8 816 . 0 < 0 . 1 FNF-09 BLANK 9 "' < 0 . 1

Leve l of quantitation : 0.1 ug Ana l yt ica l Method NIOSH 5506 OSHA PEL (TWA ) NA

col lection Media Filter & Tuba

< - Le ss Than > -Great er Than II'. -Not Applicable

mg - Milligrams ug - Microgr ams ND -Not Detect ed

Front ug

< 0.1 < 0 . 1 < 0.1

Back Tota l

"9 "9

< 0 .03 < < 0.03 < < O.OJ <

Submitted by: ES Approved by : DB Date : OS-DEC-9 4 QC by, "'

0 . 1 0 . 1 0.1

mgJm3

< 0.0001 < 0.0001

NA

Faxed: ~ r:J 6 9J4 Phoned :

m3 -Cubic Meters 1 -Liters ppm -Parts per Million


Field samp l ing was not performed by Gal son . Galson presents results based on sampl i ng data ?rovided by clients.

page 13 o f 18

Galson LABORATORY M1ALYSIS REPORT

Laboratories Client : Western Techno log~es, :nc . Site : NS Date Sampled Date Received

Naphthalene

Sample ID L.b ,D

FNF-03 7 FNF-07 8 FNF- 09 BLANK 9

16-NOV-94 - 17-NOV-94 19- NOV- 94

Air Vol Filter 1 " 9

87 1. 1 , 2.0 816 . 0 , 2.0

NA , 2 . 0 ,

.'l.ccount No.: 10185 Login No. L21065

Front Back Total

"9 "9 "9

2.1 > D.a > 2 . 9 4.0 > La > s.a 0 . 7 , D. 7 , 2 . 0

rng/mJ

> 0.003 > 0 . 007

NA

~OMMENTS: • Total ug reported as (» designates possib le breakthrough or migration.

Leve l of quantitat ion: Analytical Method OSHA PEL (TWA)

Collection Media

< -Less Than

2 "9 NIOSH 5506 10 ppm Fi lter & Tube

Submitted by : ES Approved by : DB Da te : OS-DEC-94 QC by : '_ / Faxed: DEC 0'3 m4 Phoned:

kg -Ki lograms

ppm

> 0 . 0006 > 0.001

NA

> -Greater Than mg -Milligr ams ug -Micrograms NO -Not Detected

mJ -Cubic Meters 1 -Liters NS -Not Specif ied

-l A -Not Ap p licable ppm -Parts per Mi llion

?ie l d sampling was not performed by Galson. Galson presents results b a sed on s a mpling data ~rovided by client s .

page 1 4 ot 18

Galson LABORATORY ANALYS I S RE PORT

Laboratories Client, Western Techno logLes, Inc . Sit e 'US Date Sampled Date Received

Phenanth r ene

Samp le 10 Lob Ip

FNF-03 , FNF-D7 • FNF-09 BLANK 9

Level of quantit ation : Analytic al Method OS HA PEL (TWA) Collection Media

16- NOV - 94 - 17-NOV-94 19-NQV-94

Ai, vol 1

871.1 B16 . 0

NA

O. J u9 NI OSH 5506 NA

Filter " 9

< 0 .3 < 0 . 3 < 0 . 3

Filter & Tube

Account No .: 10185 Login NO. L21065

Front Ba ck Total

"9 " 9 " 9

L. < 0.1 L' 0.' < 0 .1 0 . '

< 0 .1 < 0 . 1 < 0 . 3

mq/m3

0.002 0 . 001

"'

Su bmitted by, ES Appr oved by : DB Date : D5 -0EC-9 4 QC by: ~

Faxed: 1Et L1.6 !& Phoned:

< - Less Than > -Gr eater Than 11\ -Not Applicable

mg -Hill ig r"'mB ug -Micrograms flO -Not Detected

mJ -Cubic Meters 1 -Liter s ppm -Part s per Mil lion

kg -Kilogr ams NS - Not Specified

;ie ld sampling was not performed by Galson . Ga lson present s results ba s ed on sampl ing data ?rovided by cl ients .

page lS o f 18


Client: Western Technologies, Inc . Site : NS Date Sampl ed Date Received

Pyrene

Sample to Lab 10

FNF-03 7 FNF- 01 8 FNF-09 BLANK 9

Level o f quantitation: Analytical Method OSHA PEL (TWA) Collection Media

16-NQV-94 - 17 - ~IOV-94

19-NOV- 94

Ai, vol 1

811 .1 316 . 0

NA

0 . 9 ug NIOSH 5506

'"

Filter " g

< 0.9 < 0 .9 < 0 . 9

Filter & tube

Account No.: Login NO.

10185 L2 1065

Fr ont Back Total "g ug "g

< 0 . 3 < 0.3 < 0 . 9 < 0 . 3 < 0 . 3 < 0.9 < 0 . 3 < 0.3 < 0.9

mq/m3

< 0.001 < 0 . 001

NA

Submitted by : ES Approved by : DB Date : OS-DEC-9 4 QC by: .- k' Fa:xed.: te:: 1,)"6 ffio Phoned :

< -Less Than > -Greater Than ~A -Not Applicable

mg -M illigrams ug -Microg r ams NO -Not Detected

m3 -Cubic Meters 1 - Lite rs ppm -Parts per Mil lion

kg -KiloqraInll tIS -Not Specified

~ield sampling was not performed by Ga lson . Galson p resents reaults based on sampling data ~rovided by client s .

p a ge lei o f 18


Coal Tn

Laboratories Client : Western Site , NS Date Samp led Date Rece ived

Pi t ch volatiles

Technologies, Inc .

16 - NOV-9 4 - 17-NOV- 94 19-NOV-94

Ai. r vol Sample 10 Lab 10 . 3

FNF-02 L2106 5 -1 0 . 8711 FNF-06 L21065 - 2 0 .8200 LAB BLANK L2106S-J "'

r.ccount No .: 1018 5 Login No. L21065

Total _9

1 . 13 1.00 0 . 105

!-Ig/ M3

1.2 1. 1

NA

:OMMENTS: The blank value wa s used ~o correct the s ample values i n the mg/mJ calculation .

Leve l o f quantitation: Anal ytical Method OSHA PEL ( TWA) Collection Media

0 . 005 mg « l aSH 5023 0 . 2 mg/m3 fUter

(G ravimet r ic) Submitted by : LMP Approved by : Wm Bu r ry Date : OS-OEC-9 4

< -Less Than > - Great er Than ;1 ;>' -Not Applicable

I\'IQ -Millig rams uq -Micrograms NO -Not Detected

_3 1 ppm

QC by: IIt't ~ ''''' Faxed: Phoned :

-Cubic Keter. kg - Kilograms -Liters NS -Not Specified -Parts per Killion

=ie ld s ampling was not per~ormed by Ga lson . Galson presents re8ults based o n sampling data ?rov~ded by clients.

page 17 o f 18

Galson ~ABORATORY ANALYSIS REPORT

Total Dust

Samp l e 10

FNF-04 FNF-08 LAB BLAN K

Laboratories Client : Western Technologies, I nc . Site : NS Date Sampled Date Received

16-NOV-94 - 17-NOV-94 19-NOV-94

Air Vol Lab IO 03

L21065- 4 0.750 48 L2 106S-S 0 .87000 L21065 -6 "'

Account No .: 10185 Log in No . L2106 5

Total 09

0 . 644 0 . 81 4

< 0 . 05

';OHMENTS: PNOR ~ Particulates Not Otherwise Regulated.

Level o f quantita tlon : Ana lyt ica l Method OSHA PEL (TWA)

Collect ion Media

0 . 0 5 mg lHOS H 0500 PNOR 15 mg/m3 Filt er

mg/m3

0.86 0 . 9 4

NA

Submitt ed by : ELI Approved by : SLS Date : Ol-DEC- 9 4 QCby: -'':' Fax ed : DEc" ':" ~4 Phoned :

< - Le ss Than > -Greate r Than ~A -Not Applicable

mg -Milligrams u g - Micrograms NO -Not Detected

m3 -Cubic Meters 1 -Liters ppm -Part s per Million

kg - Kilo grams NS -Not Specified

?ield s a mpling was not performed by Galson . Ga l son p resents result s based o n sampl ing data prOv ided by cl ient s .

page 18 of 18


Laboratories

Cl ient : Western Technologies, Inc. Site : NS Date Sampled Date Received

Acenaphthylene

Sample 10 Lab 10

FNF- ll 1 FNF-15 2 FNF-18 BLANK 3

Level of quantitation : Analytical Method OSHA PEL ( TWA) Collection Media

09-DEC-94 14-DEC-94

- ll-DEC-94

Air vol 1

834.3 553.5

NA

2 u. NIOSH 5506 NA

Filter ug

< 2 < 2 < 2

Filter & Tube

Project No.: Account No.; Login No.

Front Back ug ug

2184JC248 10185 L21369

Total ug

< 0 . 7 < 0.7 < 2 < D. 7 < 0 . 7 < 2 < 0 . 7 < 0 . 7 < 2

lIl9/mJ

< 0.002 < 0.004

NA

Submitted by : ES Approved by : DB Date : 27-DEC- 9 4 QC by: t-" ~1 Faxed: Phoned :

< - Leas Than > -Greater Than ~A -Not Applicab l e

mg -Milligrams ug -Micrograms NO -Not Detected

m3 -Cubic Metera 1 -Litera ppm -Parts per Million

kg -Kilograms NS - Not Specified

Pield sampling was not performed by Galson. Galson presents results based o n sampling data provided by clients.

page 1 of 18

o


Laboratories

Client: Western Technologies, Inc. Site : NS Project No.: Date Sampled Date Rec eived

09-DEC-9 4 - 11- OEC- 94 14-DEC-94

Account No . : Login No.

2184JC248 10185 L21369

Anthracene

Sample 10 L" 1D

P'NF-ll 1 FHF-lS 2 FNP- lS BLANK 3


Air Vol 1

83 4 . 3 553 . 5

NA

2 ug NIOSM 5506 NA

Filter U9

< 2 < 2 < 2

Analytical Hethod OSHA PEL (TWA) Collection Media Filter & Tube

< -Le.. Than > -Greater Than HI'. -Not Applicable

mg -Milligrame ug -Hicroqrar!lB NO -Not Detected

Front U9

< 0.7 < 0.7 < 0 . 7

Back Total U9 ug

< 0 . 7 < < 0.7 < < 0.7 <

Submitted by: ES Approved by : DB Date : 27-0EC-94 QC by: ~ ",t-/

2 2 2

mg/m3

< 0 . 002 < 0 . 004

NA

Faxed: I Phoned:

mJ -Cubic Hetere 1 -Litera ppm -Part a per Hillion

kg -Kilogram. NS -NOt Specified

Field sampling was not performed by Galaon. Galson presenta reaulta baaed on aampling data provided by clients.

page 2 of 18


Client : Western Technologies, Inc. Site ,NS Date Sampled Date Received

Beozo(a)anthracene

Sample ID Lab ID

FNF-ll 1 FNF-1S , FNF-18 BLANK 3


09-DEC-94 - 11-0EC-94 14-DEC-94

Air Vol 1

83 4. 3 553.5

NA

0.06 ug NIOSH 5506 NA

Filter 09

< 0.06 < 0 . 06 < 0 . 06

Filter & Tube

< -Leas Than > -Greater Than NA -Not Applicable


m3 1 ppm

Project No.; 2184JC248 Account No . : Login No.

10185 L21369

Front Back Total mg/m3 09 09 ug

< 0 . 02 < 0 . 02- < 0.06 < 0.00007 < 0.02 < 0 . 02 < 0 . 06 < 0 . 0001 < 0.02 < 0 . 02 < 0.06 NA

Submitted by: ES Approved by : DB Date : 27-DEC-94

OC by' f">! Faxed: Phoned:

-Cubic Meters -Lite r s -Parts per Million

kg NS

-Kilograms -Not Specified

Field sampling was not performed by Galson. Galson presents results based on sampling data provided by clients.

page 3 of 18

o


Laboratories

Client : We8tern Technologiea, rnc. Site : NS Date Sampled Date Received

BanzO{a)pyrene

Sample 10 L.b ID

VNF- ll 1 FNF-1S , FNY-1S BLANK J

Level of quantitation: Analytical Method OSHA PEL ( TWA ) Collection Media

09- 0EC-94 14-DEC-94

- ll-DEC-94

Air vol 1

834. 3 55J.S N.

0.06 u9 NIOSH 5506

N'

Filter og

< 0.06 < 0.06 < 0.06

Filter & Tube

Project No.: 21B4JC24B 10185 L21369

Account No.: Login NO.

Pront Back Total yg

< < <

og ),JQ

0.02 < 0 . 02 < 0.02 < 0 . 02 < 0.02 < 0.02 <

Submitted by : ES Approved by : DB Date : 27-DEC-94 QC by' ,,--'J

0 .06 0 .06 0 . 06

mg/ml

< 0.00007 < 0.0001

"'

Faxed: Phoned:

< -Le8a Than > - Greate r Than ~A -Not Applicable

mg -Milligrams u9 -Micrograms NO -Not Detected

mJ -cubic Metera 1 -Liters ppm -Parta per Million


Field ~amplin9 was not performed by Galson. Galson preeents results baaed on ~amplin9 data provided by clients .

page 4 o f 18


Client : Western Technologies, Inc. Site : NS Date Sampled Date Received

Benzo(b)fluoranthene

Sample 10 Lab 10

PN,.-11 1 FNF-15 2 FNY- 18 BLANK 3

Level o f quantitation: Analytical Method OSHA PEL (TWA ) collection Media

09-DEC-94 - 11-DEC-9 4 14 - DEC- 94

Air Vol 1

83 4 .3 553 . 5

"'

0 .06 ug NIOSH 5506 NA

Filter U9

< 0.06 < 0 .06 < 0.06

Filter & Tube

Project No.: 218 4JC2 48 Account No.: Login No .

10185 L21369

Fr ont Back Total U9 u9 u9

< 0.02 < 0 . 02 < 0.06 < 0 . 02 < 0 . 02 < 0 . 06 < 0 . 02 < 0 . 02 < 0 . 06

mg/m3

< 0.00007 < 0.0001

NA

Submitted by : ES Approved by : DB Date : 27 - DEC-94 QC by: { -. <--/ Faxed : Phoned:

( -Less Than > -Greater Than NA -Not Applicable

mg -Kill igrams ug -Micrograms NO -Not Detected

m3 -Cubic Heters 1 -Liters ppm -Parts per Million


~ield sampling was not performed by Galson. Galson presents results based on sampling data ~rovided by cl ients.

page 5 of 18

o


Laboratories

Client: Western Technologies, Inc. Site : NS Date Sampled Date Received

09-DEC-9 4 - 11-OEC-94 14-DEC-94

Project No.: 2184JC2 48 Account No .: 10185 Login No . L21369

Benzo(ghi)perylene

Sample 10 Lab 10

P'NF- ll I FNY-lS 2 FNP'- lB BLANK 3

Level of quantitation :

Air Vol I

834. 3 553.5

NA

0.2 uq NIOSH 5506 NA

Filter ug

< 0.2 <: 0.2 < 0.2

Analytical Method OSHA PEL (TWA) Collection Media Filter & Tube

< -Leas Than > -Greater Than NA -Not Applicable


Front Back Total mq/ml ug ug ug

< 0 . 07 < 0.07 < 0 . 2 < 0 . 0002 < 0 . 07 < 0.07 < 0.2 < 0 . 000 4 < 0.07 < 0 .07 < 0.2 NA

Submitted by : ES Approved by : DB Date : 27 - DEC-94 QC by 'f -/l Faxed: Phoned:

mJ -Cubic Matera 1 -Litera ppm -Parte per Million

kg -Kilograms NS - Not Specified

Field sampling was not performed by Galson. Galson presents results baaed on sampling data provided by clients.

page 6 of IS


Client : Western Technologies, Inc . Site : NS Date Sampled Dilte Received

Benzo(k)fluoranthene

Sample ID Lab Ip

FNF-ll 1 FNF-1S 2 FNl"-18 BLANK 3


09- DEC- 94 - I1-DEC-94 14- DEC- 94

Air Vol 1

834 . 3 553.5

NA

0 . 06 ug NIOSH 5506 NA

Filter \,19

< 0 . 06 < 0.06 < 0 . 06

Filter & Tube

Project NO.: 2184JC248 10185 L21J69

Account No.: Login No .

Front BacK Total ug ug ug

< 0 . 02 < 0.02 < 0 . 06 < 0.02 < 0 . 02 < 0.06 < 0 . 02 < 0.02 < 0.06

rnq/m3

< 0 . 00007 < 0.0001

NA

Submitted by: ES Approved by : DB Date : 27-DEC-94 QC by : i 'I Faxed : Phoned :

< - Less Than > -Greater Than HI. -Not Applicable

109 -Milligrams ug -Micrograms NO -Not Detected

m3 -Cubic Heters 1 -Litera ppm -Parts per Million



page 7 o f 18

o

Galson LABORATORY ANALYSI S REPORT

Laboratories

Client : Western Technologies, Inc. Site : NS Project No. : Date Sampled Date Received

09 -DEC-94 - Il-DEC-94 l4-DEe-94

Account No .: Login No .

2184JC248 10185 L21369

Chryllene

Sample 10 Lab 10

I"NI"-l1 1 FN1"- 15 2 FNP-lS BLANK 3

Level o f quantitation :

Ai, Vol 1

834 .3 553.5 .A

0.6 1.19 NIOSH 5506 'A

Filter u9

< 0 . 6 < 0 . ' < 0 . 6

Analytical Method OSHA PEL (TWA) COllection Hedia Filter & Tube

< -LeS8 Than > -Greater Than NA -Not Applicable

mg -Milligrams u9 -Micrograms NO -Not Detected

Front u 9

< 0.2 < 0.2 < 0.2

Back Tota.l u9 u9

< 0.2 < < 0 .2 < < 0.2 <

Submitted by: ES Approved by : DB Date : 27-DEC-94 QC by: i '/

0 . 6 0.6 0.6

mq/m3

< 0 . 0007 < 0.001

.A

Faxed: Phoned:

m3 -Cubic Meters kg -Kilograms 1 -LiteJ::'e NS -Not Specified ppm -Parta per Million

Field sampling was not performed by Galson . Galson presents results based on sampling data provided by c lients.

page B of lB


Client : Weetern Technologies, Inc . Site : NS Date Sampled. Date Received

Dibenzo(a,h)anthracene

Sample 10 Lab ID

FNF-ll 1 FNF-15 , FNF- IB BLANK 3

Level of quantitation: Analytical Hethod OSHA PEL (TWA) COllection Media

09-DEC-94 - Il-DEC- 94 14- 0EC- 94

Air Vol 1

834.3 553.5

NA


Filter ug

< 0.09 < 0.09 < 0.09

Filter & Tube

Project No.: 2184 JC248 Account No.: 10165 Login No . L21369


< 0.03 < 0 . 03 <: 0.09 <: 0.03 < 0.03 < 0.09 < 0.03 < 0.03 <: 0.09

Submitted by: ES Approved by : DB Date : 27-DEC-94 QC by: 7-' I,.(

mg/mJ

<: 0.0001 <: 0.0002

NA

Faxed: Phoned :

<: -Less Than > -Greater Than NA -Not Applicable

mg -Milligrams ug -Kicrograms NO -Not Detected

m3 - Cubic Hetera 1 -Litera ppm -Parts per Million

kg - Kilograms NS - Not Specified

Field sampling was not performed by Galson. Galson presents results based on sampling data provided by cliento.

page 9 o f 18

Galson LABORATORY ANAL¥SIS REPORT

Laboratories

Client t Western Technologies, Inc. Site : NS Date Sampled Date Received

Fluoranthene

Sample ID Lab IP

FNF-ll 1 FNF-15 2 FNF-IB BLANK 3

Level of quantitation: Analytical Method OSHA PEL (TWA) Collection Med ia

0 9 - DEC- 94 - Il - DEC-94 14-0EC-94

Air vol 1

834. J 553.5

NA

0 .6 ug NIOSH 5506 NA

Filter u9

< 0.6 < 0.6 < 0.6

Filter & Tube

Pr oject No.: 21B4JC248 10185 L21369

Account NO . : Login No .

Front Back Total yo yg u9

< 0.2 < 0.2 < 0 . 6 < 0 .2 < 0.2 < 0.6 < 0.2 < 0.2 < 0 . 6

mg/m3

< 0 . 0007 < 0.001

NA

Submitted by: ES Appr oved by ; DB Date : 27-DEC-94 QC by , f- '/ Faxed: Phoned :

< -Lees Than > - Greater Than NA -Not Applicable

mg - Milligrams ug -Micrograms NO -Not Detected

mJ -Cubic Hetera 1 -Litera ppm - Parta per Million

kg -Kilograms NS -No t Specified

Field sampling waa not performed by Galeon. Galson presents results based on sampling data provided by clients.

page 10 of 18

o


Laboratories

Client : Western Technologies, Inc. Site : NS Oate Sampled Date Received

Fluorene

Sample 10 Lab IQ

FNP-ll 1 FNl'- 15 2 FNY-lS BLANK J

Level ot quantitation: Analytical Method OSHA PEL (TWA) COllection Media

09 - DEC-9 4 - Il- DEC-9 4 14-DEC-94

Al, Vol 1

83 4. 3 553 . 5

"'

0.6 ug NIPSH 5506

".

Filter ug

< 0.' < 0 . ' < 0.'

Filter & Tube

Pro ject No.: HS4JC248 10185 L21369

Account NO. : Login No .


1.2 < 0.2 1.2 1.7 < 0.2 1.7

< 0 . 2 < 0.2 < 0.'

!!191m3

0.001 0.003

NA

Submitted by: ES Approved by : 08 Date : 27-DEC-94 QC by: Cc' -"/ Faxed: Phoned:

C -Lea. Than > -Greater Than NA -Not Applicable

l1lg -Milligrams 1.19 -Micrograms NO -Not Detected

m3 -Cubic Hetera 1 - Litera ppm -Part a per Million


rield sampling was not performed by Galson. Gal Bon presents results based on sampling data provided by clients.

page 11 of 18


Laboratories

Client: Western Technologies, Inc. Site : NS Date SiUlIpled Date Received

Indeno(12J- cd)pyrene

Sample 1P Lab 10

FNF- ll 1 FNP- 15 2 FNP-IB BLANK 3

Level of quantitation: Analytical Method OSKA PEL ( TWA) Collection Media

09- 0EC-94 - Il-DEC-94 14 - DEC- 94

Air Vol I

834 . 3 553 .5

NA


Filter 09

< 0 . 1 < 0.1 < 0.1

Filter & Tube

Pro j ect No .: Account No.: Login No.

Front Back 09 09

21S4JC248 10185 L21369

Total 09

< 0.03 < 0 . 03 < 0.1 < 0.03 < 0.03 < 0.1 < 0.03 < 0.03 < 0.1

fNl/m3

< 0.0001 < 0.0002

NA

Submitted by: ES Approved by : DB Date : 27- 0EC-94 QC by: t:( )ll Faxed: I Phoned:

< -Less Than > -Greater Than NA - Not Applicable

mg - Milligrams ug -Micrograms NO -Not Detected

m3 -Cubic Heters 1 -Litera ppm - Parts per Million



page 12 of 18


Client: Western Technologies, I nc. Site ! NS Date Sampled Date Received

09-0EC-94 14-DEC-94

- ll-DEC-94

Naphthalene

Air vol Filter Sample 10 Lab IP 1 ug

FNF- ll 1 834 . 3 < , FNF-lS , 553 . 5 < , FNF-18 BLANK 3 NA < , <

Project No.: 21S4JC2 48 Account No.: 10185 Login NO. L21369


'.5 0 .7 3 . ,

4. ' > 1.1 > 6.0 0.7 < 0.7 < ,

mq/m3

0.004 > 0 . 01

NA

:OMMENIS: Total ug reported as (» designates possible breakthrough or migration.

Level of quantitation: Analytical Method OSHA PEL ( TWA) Collection Media

< -Less Than

, u, NIOSH 5506 10 ppm Filter & Tube

Submitted by: ES Approved by : DB Date : 27-DEC-94 QC by: E~ 1 Faxed: Phoned:

kg -Kilograms

ppm

0.0007 > 0 . 002

NA

~ -Greater Than ~A -Not Applicable


m3 -Cubic Meters 1 -Liters NS -Not Specified ppm -Parts per Million

Field sampling was not performed by Galson. Galson presents results based on sampling data Drovided by clients .

page 13 of 18

o


Laboratories

Client : Western Technologies, Inc. Slte : NS Date Sampled Date Received

Phenanthrene

Sample 10 Lab 10

FN!'- ll 1 FNP-1S 2 FMY-lS BLANX 3

Level o f quantitation: Analytical Method aSH), PEL (TW1r.) Collection Kedia

09 - DEC- 94 - Il-DEC-94 14-DEC- 94

Air Vol 1

83 4 .3 S5J.S

NA


Filter uq

0.3 O.B

< 0.3

rilter & Tube

Project No.: 218 4JC2 48 10185 L2 1369


Front Back Total ),JQ u q yo

1.3 < 0.1 1.. 2 . 2 < 0.1 3 . 0

< 0.1 < 0.1 < 0 . 3

mq/ml

0.002 0 . 005

NA

Submitted by : ES Approved by : DB Date : 27 - DEC-9 4 QC by: 'i: /-1 Faxed: ' Phoned:

< -Leaa Than > -Greater Than ~A -Not Applicable


m3 -Cubic Meters 1 -Litera ppm -Parts per Hillion

kg -Kilogram. NS -Not Specified

Field sampling was not per formed by GalBon. Galson preaents resulte baaed on sampling data provided by clients.

page 14 o f 18


Laboratories

Client : We. tern Technologies, Inc. Site : NS Date Sampled Date Received

Phenanthrene

SatJlple IP Lab IP

FNP-ll 1 FNF- IS 2 FNF-18 BLAN!< 3

Leval of quantitation: Analyt ical Hethod OSHA PEL (TWA) Collection Hadia

09-0EC-94 - Il-DEC-94 14-DEC-94

Air Vol 1

83 4. 3 553 . 5

NA


Filter og

0.3 0.6

< 0.3

Filter & Tube

Project No.: 2184JC248 10185 L21369

Account No.: Login No.

Front Back Total og ug ug

1.3 < 0.1 I.' 2.2 < 0.1 3.0

< 0.1 < 0.1 < 0 . 3

mg/rn3

0 . 002 0.005

NA

Submitted by: ES Approved by : DB Date : 27-0EC-9 4 QC by: .::.,. -~i Faxed: Phoned:

< -LeBII Than > -Greater Than ~A -Not Applicable

mg -Kill igramlil ug -Micrograms NO -Not Detected

m3 -CUbic Hatera 1 -Litera ppm -Parte per Hillion


?ield sampling was not performed by Ga180n. Galson present. results baaed on sampling data provided by c lients.

page 15 of 18


Laboratories

Client : Western Technologies, Inc. Site : ItS Date Satllplec:l Date Received

09 -DEC-94 - I l-DEC-94 14-DEC-94

Pyrene

sample 10 Lab ID

PNY-ll 1 FNF-1S 2 FltY- lS BLANK 3

Level ot quantitation :

Air vol 1

834. J 553.5

N>

0 . 9 u9 NIOSH 5506 NA

Filter

"" < 0.' < 0.' < 0.'

Analytical Method OSHA PEL (TWA ) Collection Hedia Filter & Tube

< -L ••• Than ~ -Greater Than NA -Not Applicable

rng -Milligrams u9 -Micrograms NO -Not Detected

m3 1 ppm

Proj act No. : 2184JC248 10185 L21J69


Front BaCK Total YQ

< 0.3 < 0 . 3 < 0 . 3

UQ ua

< 0.3 < < 0.3 < < 0.3 <

Submitted by: ES Approved by : DB Date : 27-DEC-94 QC by; 'f:.-' • /

0 . ' 0.' 0 . '

mg/m3

< 0.001 < 0.002

NA

Faxed: Phoned :

-Cubic Hetera -Litera - Parta per Hillio n

kq NS

-Kilograms -Not Specified

Field sampling we. not performed by Galeon. Galson presenta re8ults baaed on sa.pling data p r o vided by client • .

page 16 of 18


Laboratories

Client : Western Technologies, Inc. site 1 NS Date Sampled Date Received

09 - 0EC-94 14-DEC-94

- ll - DEC-94

Coal Tar Pitch volatilea

Air Vol Sample 10 Lab 10 .3

FNF-12 L21369 - 4 0 . 83 43 FNF-16 L21369 - S 0.5562 FNF- 19 Bu.NK L21369-6 NA

Project No.: 2184JC248 10185 L21J69

Account No.: Login No.

Total

'" 0 . 635 3 . 21 0 . 020

mq/m3

0.74 5.7

NA

COMMENTS: The blank value was used to correct the sample values in the mgjml calculation.

Level ot quantitation: 0.005 mg NIOSH 5023 0 . 2 mq/m3 Filter

Analytical Method OSHA PEL (TWA) collection Hedia

<: -Loss Than > -Greater Than ~A -Not Applicable

mg - Milligrams ug -Micrograms NO - Not Detected

Submitted by: RJC Approved by : HGW Date : 29- 0EC- 9 4 QC by, ":~'I Faxed: Phoned:

m3 -Cubic Hetera 1 -Litera ppm -Parts per Hillion

kg -Kilograma NS -Not Specified

~ield aampling was not performed by Galaon. Galaon presents results baaed on sampling data pr ovided by clienta .

page 17 o f 18


Client : We.tern Technologies , Inc . Site : NS Date Sampled Data Received

0 9-DEC-94 - Il - DEC- 94 14-0EC-94

Total Duat

Air Vol SamPle 10 Lob 1P m3

FNP-13 L21369 - 7 0.8222 FNF- 17 L21369-8 0.5 411 FNP- 20 BLANK L21369-9 NA

Project No.; Account No. : Login No.

2184JC248 10185 L21J69

Total rnq

0 .361 15

< 0 . 05

COMMENTS : PNOR • Part iculates Not Otherwise Regulated .

Level o f quantitation: Analytical Method OSHA PEL (TWA) COllection Madia

0.05 mg NlOSH 0500 PNOR 15 mg/m3 Filter

mgJrn3

0.44 30 NA

Submitted by: RJC Approved by : SLS Date : 21-DEC-94 QCby: 'C/ Faxed: Phoned:

! -Lees Than > -Greater Than ~A -Not Applicable

1119 -Milligram. ug - Micrograms NO -Not Detected

m3 -Cubic Hetera 1 -Litera ppm - Parta per Killion

kg -Kilogr am. NS -Not Specified

?ield aampling was not performed by Galaon . Galson presents results based on sampling data pr ovided by clients.

page 18 of 18

APPENDIX C PHOTOGRAPHS

FNF Construction I Air Monitoring Survey During Asphalt Paving WT Job No. 2184JC248

Picture No . 2 Air Monitoring in Rear of Paver in Center of Equipment

Picture No. 1 Paver Moving in West Direction on Interstate 8

Picture No.3 Personal Pump on Worker on the Back of Paver

Western Technologies Inc.

APPENDIX D SAMPLING PROTOCOL

".. ..... --

•. :. Ted. Brudra' ).. " .tunenl oll"rantportahon j:~l.oii! III S&lcty Ind Haith .~ .1I. lkn tM2A14 .~;.-amcn1O CA 9(21'-0001

An.ctIod p8M find. tht 1a~llndlJ,n1i11 hn;iene air monUoring: pnlluwl for CRM ~- t)jJcat1DQ. J, tent 11115 protuool by facJJmlIe III Mk Rl"$Dlnu M ~ 1. M dic~

.:cr tDcby, T waulo11ndUdc SuUlU" ollidl: rnunitnring ONY U the: uphilit b known ID orif:inItit • · : .• 1 a supplier W"hosc uphah _ a nigh s:uilw" CQl\tt'Tu . If it wetI to t.1N:1Udcd. illOht\uld be

. -:.ed. as In.~ ample It ~ rur of tnc J"""'C"". Thtl umP'" mould be roU .. ;:-.I Ln __ J.rd,aru wi!,h MOSH Method fLlM ur USHA II) 200. I wuuld nut 'N1n~nd the VIR ul -. :<:~~r III~ tor L11i" purpnst,

:t"rl'ly • . . ~, ",,", . l.uhllll..rj,,1 H)"RlIfte, lDc: .

~~-,.;""~"1ael COMOr, CTH. CSP

· ,ci ~1

-"' , ........ ........ I ,.M

The objtcllve of the sm.plingpfotoccl is to obtain additiom.l infcm\.Uion about ;; ~t:f nt1al;i:r ccntammants assooatld. Wlth thR applic.ation of . ·-.~ 1Jhalts (alMs). Studiu to dati havt shawn law l.v.1s Hilh",05 :--i'tn3j and appronmatlly 4.5 IngJmJ asphalt fuml lltworst CUI iOC6tiOns. ::tis has brrn at th~ rur of the paVtngma.chin' (above mlXlnr; augt!f at the serlle!) on thr ~ ~wnwU'ld side. Pttsonil morutcnngon workrrs most lik.I!}y to be IxpoStd (saud wmXtrs, and iiphalt dumpm whnf bottom ciw:r.p truclu an wed to bring asphalt to th! jab) has shown ,COW" rnl.llb, Caruequmtly, bru.lahrt1Ut;h on sorbrnt tubu is not anfidpabd.

Table 1 duaibu thl revised air monitonng for the follow.up ltudin. Tht Uta l~pllS :..: ~ to be taktn on the pavlf at the loation dUClbed above 'pproxunu.ly 3 fut from the hot ;.::?halt mix. Pusonal samplts are to be collld,d on pmonnel most likely to br 'xpond. Th. ':' IIOW1ng is a suWsted s~o for t"w'o days of monitnring:

D'l"

Ara~lu 3 ptrsonal iU' sampling pumps, om for ilSphalt fo.une / cydohu:az\f extIac:table • partia.tl.ate and om for tach of thr other two m.tht!cU dtsc:nbed on Tabl. 1.

PawMi.samp/o : 1 ptrsonal. at: sunplirtg pwnp fat uphalt fume / CEP.

""" ",,",,'" 3 p.nona1 air samplirtgpwn?S, one for asphalt fume / cycloh,xlnl extIadable p~c:ul&tf and On! for n.dI. of th. othtr two methow described on Table 1.

PmonIll 5ampies ; 1 personal. iJr smlpling pu.m.p for asphalt fume, CEP,

To assure consistency of ru ulb.. the work shall be CDnQuded by a Cu'tlfitdIndwtnal :.' t 81tIUst (Amencan Boud ofIrtdustrial Hyghm, Compnhtnswt Pn.cna).

ThI! mOnitcring showd b. am.dud.d for &t lust Stvl'tlCONtcutive houn of opru.ticm.. A . : ord of wait time (fut asphalt to arrivt on site, pavin!:@qwp:nemdowntiml Itc.) shall be

',: ;mtainld,. as 5hall a t~(nrd of alIpha1t und (r.w:nDfI of loads), In.ttoralogu:al. data mptrahu:e, wind dittdlon Illative to WOfk,. ttc.), and asphalt t,m.prratw:e (windraws and

~. at), 1m latttt infonnation may bt obtalntd £:om th. UlTUN ReSldtntErtgineer <REl Or . -.JTaN impeder,

Pleas. hwe ynur laboratory ~aVf the CEP !mas for a plriod of nintty GO) chys in ,.a additional analYSIS is trqW:ed.

• Tn. &Aft" aIotaiM.t.y~Id:i:ft&1:M FVCfilI." ... I_p •• W>liM (lrpwtn....l oaMyoO' a.. .. I .... ~ " J.N ,an. N_~ ......... ..,.w. • .....u_ .. e "'1'_<1. •• -w. tor ,. ....... ta. • ....J.I •• ,.~

~.~""t.& .".nc.mzu,"","", .. c;rpV,{i ... PAH'H?"._l~. CJ!P ... NiU_ ....... L

~

" ~ ~ ~

c ~

0

~ • ~

;;

~ N -;; ~

, <

~ ~ ~ J ,

, , "

""' o ~ '" ~s

. ~ t:t--,

(~

O·,_"b.id

Asphalt rume

eEl'

Stlml-volo. tile orgal'\lcs (I .e . poiyaranl.'l tic hydroclIoJOIls)

VOCs

urrAL

TAIREI

CR M AIr Moniter irlg l':rotowl September I 9')14

Mda:clW. Anoo

NI OS H 0500 , NIOSI-I S023 ,

N10Sf/ 55150r , NIOSH 5506

GCfM S ,

•

~ 0 ,4::

2 conect personals on screedworblror dumper.

, Cyclohexitne extra<: table p<1ttlculo1tes from asphalt fume sample. SINE EXIIUICIS Irr UIII.

•

Must IdentUy predominant !:pcrles (e.g.benzo -a ' p)'Jent:>. etx.)

Collect onlo single I DO/SO Ing Tenax tube. ftevlous ffiOl1l torlng ~assho"'n 8 to 400v.g/m] lotal VOCs .

Area sl.mplea to be collec ted on a V/Olllt case locatIon on asphalt paver (Egat feRt , neat screed above a uger). One blank per two clay (or each of the four Air sampling methods shall be submitted to the laboratory for analysis.

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Air Monitoring Survey: Asphalt Paving Operations ...asphaltrubber.org/ARTIC/Reports/RPA_A1600.pdf · air monitoring survey asphalt paving operations interstate 8 dateland. arizona