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New developments of biocomposites as structural composites
Conference Paper · October 2009
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4 authors, including:
Some of the authors of this publication are also working on these related projects:
Several projects related to plastic materials. View project
Sergio Fita Bravo
AIMPLAS-Instituto Tecnologico Del Plastico
30 PUBLICATIONS 16 CITATIONS
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Enrique Díaz Escriche
AIMPLAS-Instituto Tecnologico Del Plastico
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Thermosets 2009
Enrique DíazAIMPLAS
NEW DEVELOPMENTS OF BIOCOMPOSITES AS STRUCTURAL
COMPOSITES
Enrique Díaz (AIMPLAS) [email protected]
OVERVIEW
IntroductionAIMPLASBIOMATERIALS
R + D ProjectsNATEXBIOCAR
Conclusions
Enrique Díaz (AIMPLAS) [email protected]
• Non – Profit Association• Was founded in 1990• Main Objective:
Create Knowledge to Improve Plastic Materials, Processes and Products for our Partners
Technological ConsultingFeasibility StudiesMarket and State of the Art AnalysisR&D ProjectsRaw Materials and Products Characterisation
AIMPLAS
Enrique Díaz (AIMPLAS) [email protected]
• Thermoplastic Material• Compounding• Injection Moulding• Extrusion
• Thermosetting Material• Composites
• RTM, VARTM, Infusion• Pultrusion• SMC• Rapid Tooling (CNC Machine)• Solid Surface
AIMPLAS
TRADITIONAL MATERIALS
BIOMATERIALS
Enrique Díaz (AIMPLAS) [email protected]
Biomaterials are materials which are based either completely or to relevant proportion on agricultural raw materials. Typical biomaterials are starch, sugar, vegetable oils, cellulose and biomoleculessuch lignin or natural rubber.Innovative biomaterials, in contrast to traditional ones are often processed by using modern polymer technologies such as extrusion, injection, blow film, rtm, pultrusion, etc…
BIOMATERIALS
M. Carus (NOVA INSTITUT)
Enrique Díaz (AIMPLAS) [email protected]
• Natural Fibre Reinforced Plastics• Compression Moulding• Injection Moulding• Resin Transfer Moulding
• Wood Plastic Compounds• Extrusion Moulding• Injection Moulding
• Bioplastics• Thermoforming• Blow Moulding
INNOVATIVE BIOMATERIALS
Enrique Díaz (AIMPLAS) [email protected]
INNOVATIVE BIOMATERIALS
Density (g/cm3)
Tensile Strength (MPa)
Modulus (GPa)
Specific Strength
(MPa·cm3/g)
Specific Modulus
(GPa·cm3/g)
Elongation (%)
E-Glass 2,55 2400 73 940 29 3Flax 1,4 800 - 1500 60 - 80 570 - 1070 26 - 46 1,2 - 1,6Hemp 1,48 550 - 900 70 372 - 608 47 1,6Jute 1,46 400 - 800 10 - 30 274 - 548 7 - 21 1,8Ramie 1,5 550 44 367 29 2Coir 1,25 220 6 176 5 15 - 25Sisal 1,33 600 - 700 38 451 - 526 29 2 - 3Cotton 1,51 400 12 265 8 3 - 10
Property
Fibre
Enrique Díaz (AIMPLAS) [email protected]
R & D PROJECTS
• BIOCARInvestigation on Ecological Materials and Processes in the Automotive and Transport Sector.
• NATEXNatural Aligned Fibres and Textiles for Use in Structural Composite Applications
R & D PROJECTS
Enrique Díaz (AIMPLAS) [email protected]
• IMPROVE ENERGY EFFICIENCY• Analysis of the most common processes
in the automotive sector.• Take advantage of the non – employed
energy.• Reuse the energy• Use new sources
• Optimize the cost of energy (selection).• Employ renewable sources.
BIOCAR: OBJECTIVES
Enrique Díaz (AIMPLAS) [email protected]
• IMPROVED PLASTIC MATERIALS• Biomaterials• Recyclable materials• Introduction of thermosetting materials
and processes• Thermosetting Bio - resins and Bio –
reinforcements• Thermoplastics resins. Anionic PA.
BIOCAR: OBJECTIVES
Enrique Díaz (AIMPLAS) [email protected]
• IMPROVED METALLIC MATERIALS• Lighter Alloys
• Reduce Weight• Improve Impact Properties
• High Resistance Steel• Titanium Alloys• Magnesium Alloys
• New Parts Design• New processes
BIOCAR: OBJECTIVES
Enrique Díaz (AIMPLAS) [email protected]
BIOCAR: CONSORTIUM
Parts Design
Resin Manufacturer
Sports Car Manufacturer
Bio - reinforcementManufacturer
Enrique Díaz (AIMPLAS) [email protected]
• WP1 State of the Art• WP2 Biomaterials Selection• WP3 Characterization of Composites• WP4 Process Adaptation• WP5 Industrial Scale – Up• WP6 Prototype Characterization
BIOCAR: WORK PLAN
SUBPROJECT 1: PLASTICS
Enrique Díaz (AIMPLAS) [email protected]
BIOCAR: WP1 State of the Art
• Thermosetting BioResins• BioReinforcements• Anionic Poliamides
Enrique Díaz (AIMPLAS) [email protected]
BIOCAR: WP2 BioMaterials Selection
• Natural Fibres• Flax• Jute
• Thermosetting BioResin• Soybean Oil (AESO)
• Thermoplastic Resin• Anionic Polyamide
Enrique Díaz (AIMPLAS) [email protected]
BIOCAR: WP3 Characterization
AESO Resin Polyester Reinf. AESO (0º) Reinf. Polyester (0º)
Flexural Strength (MPa) 19,3 100
Tensile Strength (MPa) 16,7 65 465 460
Tensile Modulus (GPa) 0,52 3,2 25 24
Flax (±45º) Glass (±45º)
Flexural Strength (MPa) 62,2 102
Flexural Modulus (GPa) 2,8 4,8
Tensile Strength (MPa) 35,6 74,4
Enrique Díaz (AIMPLAS) [email protected]
• 1st Year has already finished (2 years)• There exist materials and processes
available.• First characterization has been finished.• Promising results.• SMC and RTM processes are the most
suitable.• Next year to obtain and characterize
demonstrators.
BIOCAR: Conclusions
Enrique Díaz (AIMPLAS) [email protected]
NATEX: GENERAL INFORMATIONFull title: Natural Aligned Fibres and Textiles for Use in
Structural Composites Applications
Funding scheme: Collaborative project targeted to
SMEs
FP7-Cooperation – Theme 4 – NMP - Nanosciences,
Nanotechnologies, Materials and new Production
Technologies
Call identifier: FP7-NMP-2007-SME-1
Topic: NMP-2007-4.0-2 Application of new materials
including bio-based fibres in high-added value textile
products
Number of partners : 16
Funding:: € 3.097 M, budget: € 4.180 M (42 Months)
Enrique Díaz (AIMPLAS) [email protected]
NATEX
STRUCTURAL COMPOSITES
OBJECTIVES
FIBRESBIO OIL
RESINSTHERMOPLASTIC
Enrique Díaz (AIMPLAS) [email protected]
NATEX: PARTNERSBeneficiary
no.Partner name Abbreviation Type Count
ry
1 Asociación de Materiales Plásticos y Conexas (Coordinator)
AIMPLAS RTD ES
2 NetComposites Ltd. NETCOMP SME UK
3 European Plastics Convertes EuPC ASSO BE
4 AGCO S.A AGCO LARGE
FR
5 Formax UK Ltd. FORMAX SME UK
6 MAREK RADWANSKI, EKOTEX EKOTEX SME PL
7 Technical University of Denmark DTU RTD DK
8 Chemowerk GmbH CHEM SME DE
9 Institute für Verbundwekstoffe GmbH IVW RTD DE
10 Asfibe S.A ASFIBE SME ES
11 John L. Brierley Ltd. BRIERLEY SME UK
12 Piel.S.A. PIELSA SME ES
13 TransFurans Chemicals TFC SME BE
14 Helsinki University of Technology TKK RTD FI
15 Instytut Włókien Naturalnych i Roślin Zielarskich
INFMP RTD PL
16 Abensi Energía, S.L. ABENSI SME ES
Enrique Díaz (AIMPLAS) [email protected]
NATEX: MAIN INNOVATIONS
Development of new and innovative chemical/enzymatic treatments to obtain desired interface properties when combined with polymer matrices;
Specific treatment of the yarn (chemical & natural) during wrapping process, including new methods for low twist yarns production, film stacking and commingling;
Natural fibres’ modification with the aim of enhancing yarns’mechanical properties;
Development of new weaving techniques to improve fibre impregnation by the polymer and obtaining of innovative 3Dtextiles;
Control of resin viscosity by using thermal conductive additives while increasing their compatibility with natural fibres by using coupling agents and surfactant additives
Enrique Díaz (AIMPLAS) [email protected]
• WP1 Development of Natural Fibres.• WP2 Development of Thermoplastic
Resin System.• WP3 Development of NF Preforms.• WP4 Development of Thermosetting
Resin System.• WP5 Processes Development.• WP6 Enabling Technologies• WP7 Case Study Demonstration
NATEX: WORK PLAN
Enrique Díaz (AIMPLAS) [email protected]
NATEX: CASE STUDIES
Transport systemsTransport systems
Agricultural equipmentAgricultural equipment
Energy systemEnergy system
ShipbuildingShipbuilding
Enrique Díaz (AIMPLAS) [email protected]
• AIMPLAS develops several projects related to Biocomposites.
• Promising products in construction and automotive sectors.
• Properties similar to traditional composites (Fibre Glass).
• Sustainability is a key factor.• There a lot of business opportunities
with biomaterials
CONCLUSIONS