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AGA 5 Calculation Spreadsheet - Imperial Units of Meas molar mass Methane 0.906724 16.0425 Nitrogen 0.031284 28.0134 Carbon Dioxide 0.004676 44.0095 Ethane 0.045279 30.0690 Propane 0.008280 44.0956 Water (gas) 0.000000 18.0153 Hydrogen Sulfide 0.000000 34.0809 Hydrogen 0.000000 2.0159 Carbon Monoxide 0.000000 28.0101 Oxygen 0.000000 31.9988 Isobutane 0.001037 58.1222 Normal Butane 0.001563 58.1222 Isopentane 0.000321 72.1488 Normal Pentane 0.000443 72.1488 Hexane 0.000393 86.1754 Heptane 0.000000 100.2019 Octane 0.000000 114.2285 Nonane 0.000000 128.2551 Decane 0.000000 142.2817 Helium 0.000000 4.0026 Argon 0.000000 39.9480 2,2-Dimethyl Propane 0.000000 72.1488 2-Methyl Pentane 0.000000 86.1764 3-Methyl Pentane 0.000000 86.1764 2,2-Dimethyl Butane 0.000000 86.1764 2,3-Dimethyl Butane 0.000000 86.1764 Ethylene 0.000000 28.0532 Propylene 0.000000 42.0797 Methyl Alcohol 0.000000 32.0419 1.000000 Pressure Base (Pb) 14.73 psia Temperature Base (Tb) 60 °F Calculation Results Compressibility Factor (Z) at Pb, T 0.997776 Gross HV at Pb, Tb 1034.8 Net HV at Pb, Tb 933.6 Wobbe Number 1326.5 Ideal Gas Relative Density 0.6075 Real Gas Relative Density 0.6086 MON 1 (Linear Method) 127.4 MON 2 (CARB Method) 124.7 Methane Number (via MON 1 method) 87.8 mole fraction (xi) BTU(IT)/ft 3 BTU(IT)/ft 3 BTU(IT)/ft 3

AGA5 Calculation-Imperial Unit

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Page 1: AGA5 Calculation-Imperial Unit

AGA 5 Calculation Spreadsheet - Imperial Units of Measuremolar mass

Methane 0.906724 16.0425 14.5461Nitrogen 0.031284 28.0134 0.8764

Carbon Dioxide 0.004676 44.0095 0.2058Ethane 0.045279 30.0690 1.3615

Propane 0.008280 44.0956 0.3651Water (gas) 0.000000 18.0153 0.0000

Hydrogen Sulfide 0.000000 34.0809 0.0000Hydrogen 0.000000 2.0159 0.0000

Carbon Monoxide 0.000000 28.0101 0.0000Oxygen 0.000000 31.9988 0.0000

Isobutane 0.001037 58.1222 0.0603Normal Butane 0.001563 58.1222 0.0908

Isopentane 0.000321 72.1488 0.0232Normal Pentane 0.000443 72.1488 0.0320

Hexane 0.000393 86.1754 0.0339Heptane 0.000000 100.2019 0.0000Octane 0.000000 114.2285 0.0000Nonane 0.000000 128.2551 0.0000Decane 0.000000 142.2817 0.0000Helium 0.000000 4.0026 0.0000Argon 0.000000 39.9480 0.0000

2,2-Dimethyl Propane 0.000000 72.1488 0.00002-Methyl Pentane 0.000000 86.1764 0.00003-Methyl Pentane 0.000000 86.1764 0.0000

2,2-Dimethyl Butane 0.000000 86.1764 0.00002,3-Dimethyl Butane 0.000000 86.1764 0.0000

Ethylene 0.000000 28.0532 0.0000Propylene 0.000000 42.0797 0.0000

Methyl Alcohol 0.000000 32.0419 0.0000

1.000000 17.5950

Pressure Base (Pb) 14.73 psiaTemperature Base (Tb) 60 °F

Calculation ResultsCompressibility Factor (Z) at Pb, Tb 0.997776

Gross HV at Pb, Tb 1034.8 corrected for compressibility

Net HV at Pb, Tb 933.6 corrected for compressibility

Wobbe Number 1326.5 corrected for compressibilityIdeal Gas Relative Density 0.6075Real Gas Relative Density 0.6086 corrected for compressibilityMON 1 (Linear Method) 127.4MON 2 (CARB Method) 124.7Methane Number (via MON 1 method) 87.8

mole fraction (xi) molar mass * xi

BTU(IT)/ft3

BTU(IT)/ft3

BTU(IT)/ft3

Page 2: AGA5 Calculation-Imperial Unit

Methane Number (via MON 2 method) 83.5

Gas Constant 8.314472Standard T for Hf and Cp 298.15 KelvinsHeat of Vaporization of Water 44.41 kJ/mole at 60delta H for Liquid Water -711.1 kJ/mole at 60Ideal Gas Molar Volume at Pb, Tb 23.6357 litresMolar Mass of Air 28.9625Compressibility Factor (Z) of Air at Pb, Tb 0.999566

Conversion Factorsconvert to multiply by

Volume 0.028316846592Mass lbm kg 0.45359237

Energy joules 1055.05585262Pressure psi kPa 6.894757293

Volumetric Heating Value 0.037258945808Length foot meter 0.3048

Notes1 Heating values calculated by this spreadsheet do not have uncertainties better than +/- 0.1%.2 In some cases, extra digits have been added to calculated values to achieve internal

consistency or to permit recalculation of experimental values.

J mol-1 K-1

ft3 m3

BTU(IT)

BTU(IT)/ft3 MJ/m3

Page 3: AGA5 Calculation-Imperial Unit

version 1.1 26-Feb-08

1012.344 917.9162 911.485 826.46540.000 0.0000 0.000 0.00000.000 0.0000 0.000 0.0000

1773.777 80.3149 1622.489 73.46472522.017 20.8823 2320.300 19.2121

50.429 0.0000 0.000 0.0000638.579 0.0000 588.150 0.0000324.912 0.0000 274.483 0.0000321.260 0.0000 321.260 0.0000

0.000 0.0000 0.000 0.00003259.500 3.3801 3007.354 3.11863269.926 5.1109 3017.780 4.71684010.166 1.2873 3707.591 1.19014018.033 1.7800 3715.457 1.64594767.048 1.8734 4414.043 1.73475515.269 0.0000 5111.835 0.00006263.365 0.0000 5809.501 0.00007012.573 0.0000 6508.281 0.00007760.953 0.0000 7206.231 0.0000

0.000 0.0000 0.000 0.00000.000 0.0000 0.000 0.0000

3994.021 0.0000 3691.446 0.00004758.674 0.0000 4405.669 0.00004761.307 0.0000 4408.303 0.00004745.848 0.0000 4392.843 0.00004754.732 0.0000 4401.727 0.00001603.421 0.0000 1502.562 0.00002338.936 0.0000 2187.648 0.0000868.813 0.0000 767.955 0.0000

1032.5451 931.54840

101.55977492589 kPa15.5555555555556 °C288.705555555556 Kelvins

corrected for compressibility

corrected for compressibility

corrected for compressibility

corrected for compressibility

Gross Ideal HV (BTU(IT)/ft3) Gross HV * xi Net Ideal HV (BTU(IT)/ft3) Net HV * xi

Page 4: AGA5 Calculation-Imperial Unit

°F°F

Page 5: AGA5 Calculation-Imperial Unit

Summation factor (s)0.044427 0.0402829309969750.016980 0.0005312147844264910.074855 0.0003500240934228720.091445 0.00414055086483640.133071 0.001101830597156330.249993 00.091778 00.024636 00.021610 00.027547 00.169195 0.0001754547066897460.180283 0.0002817830447213890.220899 7.09086486603424E-050.232519 0.0001030057585518270.297637 0.0001169712750767610.365001 00.433067 00.501436 00.597379 00.022007 00.027250 00.199233 00.279832 00.290531 00.267123 00.280156 00.079612 00.125619 00.293299 0

0.04715

Summation factor * xi

Page 6: AGA5 Calculation-Imperial Unit

Ideal Gas Molar Heating Value (kJ/mole)Gross HV at 298.15 K Net HV at 298.15 K Gross HV at Tb

Methane 890.63 802.60 891.51Nitrogen 0.00 0.00 0.00

Carbon Dioxide 0.00 0.00 0.00Ethane 1560.69 1428.64 1562.06

Propane 2219.17 2043.11 2220.99Water (gas) 44.016 0.00 44.41

Hydrogen Sulfide 562.01 517.99 562.36Hydrogen 285.83 241.81 286.13

Carbon Monoxide 282.98 282.98 282.91Oxygen 0.00 0.00 0.00

Isobutane 2868.20 2648.12 2870.45Normal Butane 2877.40 2657.32 2879.63

Isopentane 3528.83 3264.73 3531.51Normal Pentane 3535.77 3271.67 3538.44

Hexane 4194.95 3886.84 4198.06Heptane 4853.43 4501.30 4856.97Octane 5511.80 5115.66 5515.77Nonane 6171.15 5730.99 6175.56Decane 6829.77 6345.59 6834.61Helium 0.00 0.00 0.00Argon 0.00 0.00 0.00

2,2-Dimethyl Propane 3514.63 3250.53 3517.302-Methyl Pentane 4187.57 3879.46 4190.683-Methyl Pentane 4189.87 3881.76 4193.00

2,2-Dimethyl Butane 4176.27 3868.16 4179.392,3-Dimethyl Butane 4184.07 3875.96 4187.21

Ethylene 1411.15 1323.12 1412.04Propylene 2058.43 1926.38 2059.76

Methyl Alcohol 764.17 676.14 765.11

Page 7: AGA5 Calculation-Imperial Unit

Net HV at Tb Gross HV at Tb Net HV at Tb Gross HV at Tb802.69 23892 21511 1012.3

0.00 0 0 0.00.00 0 0 0.0

1428.83 22334 20429 1773.82043.35 21654 19922 2522.0

0.00 1060 0 50.4517.95 7094 6534 638.6241.72 61022 51551 324.9282.91 4342 4342 321.3

0.00 0 0 0.02648.40 21232 19590 3259.52657.58 21300 19658 3269.93265.05 21044 19456 4010.23271.98 21085 19497 4018.03887.19 20944 19393 4767.04501.69 20839 19315 5515.35116.08 20760 19255 6263.45731.46 20701 19212 7012.66346.10 20652 19176 7761.0

0.00 0 0 0.00.00 0 0 0.0

3250.84 20959 19371 3994.03879.81 20907 19356 4758.73882.13 20918 19367 4761.33868.52 20850 19300 4745.83876.34 20889 19339 4754.71323.22 21640 20279 1603.41926.53 21044 19683 2338.9676.29 10266 9074 868.8

Ideal Gas Mass Heating Value (BTU(IT)/lbm) Ideal Gas Volumetric Heating Value (BTU(IT)/ft3)

Page 8: AGA5 Calculation-Imperial Unit

Net HV at Tb911.5

0.00.0

1622.52320.3

0.0588.1274.5321.3

0.03007.43017.83707.63715.54414.05111.85809.56508.37206.2

0.00.0

3691.44405.74408.34392.84401.71502.62187.6768.0

Ideal Gas Volumetric Heating Value (BTU(IT)/ft3)

Page 9: AGA5 Calculation-Imperial Unit

Enthalpy ChangeCp at 298.15 K Cp at Tb term 1

Methane 35.7086 35.3376 -329.3462Nitrogen 29.1253 29.1203 -274.9876

Carbon Dioxide 37.1409 36.7131 -339.6859Ethane 52.4746 51.3143 -467.9204

Propane 73.3368 71.4681 -647.2926Water (gas) 33.5873 33.5423 -316.3010

Hydrogen Sulfide 34.1086 33.9956 -319.6602Hydrogen 28.8339 28.7758 -270.2418

Carbon Monoxide 29.1388 29.1299 -275.0435Oxygen 29.3759 29.3265 -276.4437

Isobutane 96.6394 94.0494 -849.4108Normal Butane 98.4809 96.0555 -871.5422

Isopentane 118.8894 115.6580 -1041.7129Normal Pentane 120.0358 117.0855 -1063.1037

Hexane 142.5899 139.0632 -1262.2604Heptane 165.1814 161.0296 -1460.5135Octane 187.7820 183.0120 -1658.9727Nonane 210.4144 204.9974 -1856.0551Decane 233.0274 227.0026 -2054.9807Helium 20.7862 20.7862 -196.3139Argon 20.7862 20.7862 -196.3139

2,2-Dimethyl Propane 120.9160 117.4484 -1052.14402-Methyl Pentane 142.2604 138.3102 -1244.21573-Methyl Pentane 140.2468 136.3416 -1225.9059

2,2-Dimethyl Butane 141.7290 137.8415 -1240.92572,3-Dimethyl Butane 139.3867 135.2344 -1210.0531

Ethylene 42.8526 41.9354 -383.0710Propylene 64.3181 62.8273 -571.1120

Methyl Alcohol 44.0214 43.3992 -401.8774Sulfur Dioxide 39.8686 39.5271 -368.0291

Page 10: AGA5 Calculation-Imperial Unit

term 3 term 3 dHi O2 Term H2O Term (GHV)-5.7052 -0.5813 -335.6327 554.4597 -1422.1444444444-0.0480 -0.0168 -275.0525 0.0000 0-9.1969 0.1672 -348.7156 0.0000 0

-21.7610 -0.5655 -490.2468 970.3044 -2133.2166666667-36.0599 -0.5862 -683.9388 1386.1491 -2844.2888888889-0.6308 -0.0901 -317.0220 0.0000 0-1.8300 -0.1473 -321.6376 415.8447 -711.07222222222-2.0072 0.2655 -271.9836 138.6149 -711.07222222222-0.0928 -0.0280 -275.1643 138.6149 0-0.6845 -0.1016 -277.2298 0.0000 0

-50.5918 -0.6169 -900.6196 1801.9939 -3555.3611111111-46.4283 -0.8804 -918.8509 1801.9939 -3555.3611111111-65.9839 0.1462 -1107.5506 2217.8386 -4266.4333333333-55.6022 -1.3512 -1120.0570 2217.8386 -4266.4333333333-66.5536 -1.5869 -1330.4009 2633.6834 -4977.5055555556-78.5461 -1.8056 -1540.8652 3049.5281 -5688.5777777778-90.4677 -2.0017 -1751.4421 3465.3728 -6399.65

-104.2400 -1.7928 -1962.0878 3881.2176 -7110.7222222222-115.8326 -2.0273 -2172.8405 4297.0623 -7821.7944444445

0.0000 0.0000 -196.3139 0.0000 00.0000 0.0000 -196.3139 0.0000 0

-74.4867 1.3344 -1125.2963 2217.8386 -4266.4333333333-80.8957 0.2540 -1324.8573 2633.6834 -4977.5055555556-80.5360 0.4312 -1306.0108 2633.6834 -4977.5055555556-79.4101 0.1854 -1320.1504 2633.6834 -4977.5055555556-87.6019 1.0888 -1296.5662 2633.6834 -4977.5055555556-16.9015 -0.5426 -400.5151 831.6895 -1422.1444444444-28.9944 -0.3952 -600.5016 1247.5342 -2133.2166666667-10.3989 -0.7097 -412.9860 415.8447 -1422.1444444444-6.8852 -0.0130 -374.9273 0.0000 0

Page 11: AGA5 Calculation-Imperial Unit

H2O Term (LHV) CO2 Term SO2 Term dH (GHV) dH (LHV)-634.0440 -348.7156 0 -880.768 -92.667

0.0000 0.0000 0 275.052 275.0520.0000 0.0000 0 348.716 348.716

-951.0660 -697.4313 0 -1370.097 -187.946-1268.0880 -1046.1469 0 -1820.348 -244.147

0.0000 0.0000 0 317.022 317.022-317.0220 0.0000 -374.927 -348.517 45.533-317.0220 0.0000 0 -300.474 93.577

0.0000 -348.7156 0 65.064 65.0640.0000 0.0000 0 277.230 277.230

-1585.1100 -1394.8625 0 -2247.610 -277.359-1585.1100 -1394.8625 0 -2229.379 -259.128-1902.1319 -1743.5781 0 -2684.622 -320.321-1902.1319 -1743.5781 0 -2672.116 -307.814-2219.1539 -2092.2938 0 -3105.715 -347.363-2536.1759 -2441.0094 0 -3539.194 -386.792-2853.1979 -2789.7250 0 -3972.560 -426.108-3170.2199 -3138.4407 0 -4405.857 -465.355-3487.2419 -3487.1563 0 -4839.048 -504.495

0.0000 0.0000 0 196.314 196.3140.0000 0.0000 0 196.314 196.314

-1902.1319 -1743.5781 0 -2666.877 -302.575-2219.1539 -2092.2938 0 -3111.259 -352.907-2219.1539 -2092.2938 0 -3130.105 -371.754-2219.1539 -2092.2938 0 -3115.966 -357.614-2219.1539 -2092.2938 0 -3139.550 -381.198

-634.0440 -697.4313 0 -887.371 -99.271-951.0660 -1046.1469 0 -1331.328 -149.177-634.0440 -348.7156 0 -942.029 -153.929

0.0000 0.0000 0 374.927 374.927

Page 12: AGA5 Calculation-Imperial Unit

Summation Factor Calculationterm 1 term 2 term 3

Methane -4.9007801E-01 9.4776133E-01 -6.8415994E-01Nitrogen -2.2413260E-01 4.5930282E-01 -3.2713645E-01

Carbon Dioxide -1.7276675E+00 3.6961136E+00 -2.9096953E+00Ethane -1.9340481E+00 3.8460043E+00 -2.8874491E+00

Propane -5.0978896E+00 1.0785430E+01 -8.4322094E+00Water (gas) -2.0149330E+02 5.4961910E+02 -5.0734994E+02

Hydrogen Sulfide -2.5434289E+00 5.4605925E+00 -4.3187956E+00Hydrogen -1.1171849E-02 5.5234431E-02 -4.0194954E-02

Carbon Monoxide -2.5021661E-01 5.0094736E-01 -3.5295409E-01Oxygen -2.5663170E-01 5.0546615E-01 -3.6087331E-01

Isobutane -8.9921356E+00 1.9409973E+01 -1.5373242E+01Normal Butane -1.1403540E+01 2.5090221E+01 -2.0079644E+01

Isopentane -2.0234239E+01 4.5869946E+01 -3.7370614E+01Normal Pentane -2.3425658E+01 5.3425385E+01 -4.3672735E+01

Hexane -4.4762737E+01 1.0361251E+02 -8.5171273E+01Heptane -7.1893811E+01 1.6747850E+02 -1.3806255E+02Octane -1.0583461E+02 2.4743415E+02 -2.0425681E+02Nonane -1.4573558E+02 3.4165768E+02 -2.8244917E+02Decane -2.1770439E+02 5.1232288E+02 -4.2412778E+02Helium 1.3159012E-02 -1.6835244E-03 -2.5435854E-04Argon -2.4623380E-01 4.8395022E-01 -3.4525878E-01

2,2-Dimethyl Propane -1.4910420E+01 3.3401053E+01 -2.7081894E+012-Methyl Pentane -3.7543050E+01 8.6511642E+01 -7.1002797E+013-Methyl Pentane -8.3256687E+01 2.1204838E+02 -1.8682616E+02

2,2-Dimethyl Butane -5.9875080E+01 1.5072477E+02 -1.3196374E+022,3-Dimethyl Butane -7.2550109E+01 1.8399733E+02 -1.6175762E+02

Ethylene -1.5539888E+00 3.1640994E+00 -2.4269326E+00Propylene -4.5381793E+00 9.6405645E+00 -7.5779722E+00

Methyl Alcohol -3.3786365E+02 9.2262789E+02 -8.5049998E+02

Page 13: AGA5 Calculation-Imperial Unit

term 4 B s1.7982573E-01 -4.6650896E-02 4.4426894E-028.5151262E-02 -6.8149683E-03 1.6980398E-028.0881050E-01 -1.3243872E-01 7.4855452E-027.7784569E-01 -1.9764721E-01 9.1445281E-022.3261288E+00 -4.1854010E-01 1.3307133E-011.5774699E+02 -1.4771511E+00 2.4999333E-011.2025420E+00 -1.9909007E-01 9.1778459E-021.0477347E-02 1.4344975E-02 2.4635754E-029.1185287E-02 -1.1038051E-02 2.1610368E-029.4102855E-02 -1.7936010E-02 2.7547289E-024.2787909E+00 -6.7661344E-01 1.6919451E-015.6247533E+00 -7.6820980E-01 1.8028346E-011.0581570E+01 -1.1533376E+00 2.2089922E-011.2395147E+01 -1.2778611E+00 2.3251864E-012.4227665E+01 -2.0938301E+00 2.9763683E-013.9328979E+01 -3.1488845E+00 3.6500123E-015.8224459E+01 -4.4328110E+00 4.3306747E-018.0584164E+01 -5.9429094E+00 5.0143600E-011.2107464E+02 -8.4346593E+00 5.9737869E-012.2566868E-04 1.1446798E-02 2.2006854E-028.9991199E-02 -1.7551159E-02 2.7250148E-027.6530726E+00 -9.3818878E-01 1.9923291E-012.0183395E+01 -1.8508109E+00 2.7983175E-015.6039431E+01 -1.9950417E+00 2.9053064E-013.9427532E+01 -1.6865175E+00 2.6712306E-014.8455294E+01 -1.8551041E+00 2.8015611E-016.6701801E-01 -1.4980395E-01 7.9611828E-022.1026119E+00 -3.7297519E-01 1.2561917E-012.6370249E+02 -2.0332395E+00 2.9329876E-01

Page 14: AGA5 Calculation-Imperial Unit

MON 1 (Linear Correlation Method)

coefficientMethane 0.906724 137.78Ethane 0.045279 29.948

Propane 0.00828 -18.193Butane(s) 0.0026 -167.062

Carbon Dioxide 0.004676 181.233Nitrogen 0.031284 26.994

MON 1 (Linear Correlation 127.4Methane Number 87.8

MON 2 (CARB Method)

HC RatioMethane 4 3.62689600Nitrogen 0 0.00000000

Carbon Dioxide 0 0.00000000Ethane 3 0.13583700

Propane 2.6667 0.02208000Water (gas) 0 0.00000000

Hydrogen Sulfide 4.0708 0.00000000Hydrogen 0 0.00000000

Carbon Monoxide 0 0.00000000Oxygen 0 0.00000000

Isobutane 2.5 0.00259250Normal Butane 2.5 0.00390750

Isopentane 2.4 0.00077040Normal Pentane 2.4 0.00106320

Hexane 2.3333 0.00091700Heptane 2.2857 0.00000000Octane 2.25 0.00000000Nonane 2.2222 0.00000000Decane 2.2 0.00000000Helium 0 0.00000000Argon 0 0.00000000

2,2-Dimethyl Propane 2.4 0.000000002-Methyl Pentane 2.3333 0.000000003-Methyl Pentane 2.3333 0.00000000

2,2-Dimethyl Butane 2.3333 0.000000002,3-Dimethyl Butane 2.3333 0.00000000

Ethylene 2 0.00000000Propylene 2 0.00000000

Methyl Alcohol 4 0.00000000Sulfur Dioxide 0 0.00000000

sum 3.79406360MON 2 (CARB Method) 124.7Methane Number 83.5

mole fraction (xi)

HC Ratio * xi

Page 15: AGA5 Calculation-Imperial Unit

124.928432721.356015492-0.15063804

-0.43436120.8474455080.844480296

coeff * xi

Page 16: AGA5 Calculation-Imperial Unit

Molar Masseskg/kg-mol

Methane 16.0425Nitrogen 28.0134

Carbon Dioxide 44.0095Ethane 30.0690

Propane 44.0956Water (gas) 18.0153

Hydrogen Sulfide 34.0809Hydrogen 2.0159

Carbon Monoxide 28.0101Oxygen 31.9988

Isobutane 58.1222Normal Butane 58.1222

Isopentane 72.1488Normal Pentane 72.1488

Hexane 86.1754Heptane 100.2019Octane 114.2285Nonane 128.2551Decane 142.2817Helium 4.0026Argon 39.9480

2,2-Dimethyl Propane 72.14882-Methyl Pentane 86.17643-Methyl Pentane 86.1764

2,2-Dimethyl Butane 86.17642,3-Dimethyl Butane 86.1764

Ethylene 28.0532Propylene 42.0797

Methyl Alcohol 32.0419Sulfur Dioxide 64.0638

Atomic WeightsHydrogen 1.00794

Helium 4.0026Carbon 12.0107Nitrogen 14.0067Oxygen 15.9994Sulfur 32.065Argon 39.948

Page 17: AGA5 Calculation-Imperial Unit

Enthalpies of Formation at 298.15 kelvinskJ/mole

Methane -74.54Nitrogen 0

Carbon Dioxide -393.51Ethane -83.82

Propane -104.68Water (gas) -241.814

Hydrogen Sulfide -20.63Hydrogen 0

Carbon Monoxide -110.53Oxygen 0

Isobutane -134.99Normal Butane -125.79

Isopentane -153.7Normal Pentane -146.76

Hexane -166.92Heptane -187.78Octane -208.75Nonane -228.74Decane -249.46Helium 0Argon 0

2,2-Dimethyl Propane -167.92-Methyl Pentane -174.33-Methyl Pentane -172

2,2-Dimethyl Butane -185.62,3-Dimethyl Butane -177.8

Ethylene 52.47Propylene 20.41

Methyl Alcohol -201Sulfur Dioxide -296.81

Page 18: AGA5 Calculation-Imperial Unit

Stoichiometric CoefficientsOxygen Water Carbon Dioxide

Methane -2 2 1Nitrogen

Carbon DioxideEthane -3.5 3 2

Propane -5 4 3Water (gas)

Hydrogen Sulfide -1.5 1 0Hydrogen -0.5 1 0

Carbon Monoxide -0.5 0 1Oxygen

Isobutane -6.5 5 4Normal Butane -6.5 5 4

Isopentane -8 6 5Normal Pentane -8 6 5

Hexane -9.5 7 6Heptane -11 8 7Octane -12.5 9 8Nonane -14 10 9Decane -15.5 11 10HeliumArgon

2,2-Dimethyl Propane -8 6 52-Methyl Pentane -9.5 7 63-Methyl Pentane -9.5 7 6

2,2-Dimethyl Butane -9.5 7 62,3-Dimethyl Butane -9.5 7 6

Ethylene -3 2 2Propylene -4.5 3 3

Methyl Alcohol -1.5 2 1Sulfur Dioxide

Page 19: AGA5 Calculation-Imperial Unit

Sulfur Dioxide0

00

100

000000000

00000000

Page 20: AGA5 Calculation-Imperial Unit

Equation Constants for the Ideal Gas Heat Capacity Correlation

a b x 100Methane 4.1941264 0.35829459 1.76836150Nitrogen 3.5018867 0.00301590 0.05114154

Carbon Dioxide 4.3257999 0.57757890 -0.50862361Ethane 5.9588285 1.36661730 1.72015700

Propane 8.2430809 2.26461070 1.78330360Water (gas) 4.0280005 0.03961628 0.27421031

Hydrogen Sulfide 4.0707790 0.11492711 0.44823055Hydrogen 3.4414503 0.12605524 -0.80754203

Carbon Monoxide 3.5025979 0.00582673 0.08532127Oxygen 3.5204293 0.04298729 0.30912462

Isobutane 10.8169970 3.17722960 1.87669950Normal Butane 11.0988330 2.91575680 2.67822360

Isopentane 13.2659070 4.14387400 -0.44459765Normal Pentane 13.5383120 3.49188670 4.11040320

Hexane 16.0745150 4.17965310 4.82740980Heptane 18.5992090 4.93279710 5.49265150Octane 21.1265290 5.68148970 6.08923990Nonane 23.6363150 6.54640460 5.45373580Decane 26.1695740 7.27443580 6.16707070Helium 2.5000000 0.00000000 0.00000000Argon 2.5000000 0.00000000 0.00000000

2,2-Dimethyl Propane 13.3987440 4.67786080 -4.059373002-Methyl Pentane 15.8447200 5.08035470 -0.772811513-Methyl Pentane 15.6115510 5.05776590 -1.31167140

2,2-Dimethyl Butane 15.8028240 4.98705580 -0.563952532,3-Dimethyl Butane 15.4096700 5.50151490 -3.31221940

Ethylene 4.8782970 1.06143470 1.65054910Propylene 7.2729431 1.82088540 1.20217140

Methyl Alcohol 5.1177910 0.65306439 2.15880560Sulfur Dioxide 4.6867423 0.43239642 0.03957661

c x 105

Page 21: AGA5 Calculation-Imperial Unit

Equation Constants for the 2nd Virial Coefficienta b c

Methane -4.9007801E-01 3.2827956E-03 -8.2081892E-06Nitrogen -2.2413260E-01 1.5909040E-03 -3.9248102E-06

Carbon Dioxide -1.7276675E+00 1.2802364E-02 -3.4908986E-05Ethane -1.9340481E+00 1.3321546E-02 -3.4642088E-05

Propane -5.0978896E+00 3.7357889E-02 -1.0116519E-04Water (gas) -2.0149330E+02 1.9037358E+00 -6.0869163E-03

Hydrogen Sulfide -2.5434289E+00 1.8914054E-02 -5.1814626E-05Hydrogen -1.1171849E-02 1.9131752E-04 -4.8223780E-07

Carbon Monoxide -2.5021661E-01 1.7351497E-03 -4.2345565E-06Oxygen -2.5663170E-01 1.7508016E-03 -4.3295672E-06

Isobutane -8.9921356E+00 6.7231035E-02 -1.8444003E-04Normal Butane -1.1403540E+01 8.6905916E-02 -2.4090495E-04

Isopentane -2.0234239E+01 1.5888141E-01 -4.4835287E-04Normal Pentane -2.3425658E+01 1.8505146E-01 -5.2396238E-04

Hexane -4.4762737E+01 3.5888646E-01 -1.0218399E-03Heptane -7.1893811E+01 5.8010141E-01 -1.6564015E-03Octane -1.0583461E+02 8.5704672E-01 -2.4505652E-03Nonane -1.4573558E+02 1.1834122E+00 -3.3886758E-03Decane -2.1770439E+02 1.7745515E+00 -5.0884609E-03Helium 1.3159012E-02 -5.8312851E-06 -3.0516593E-09Argon -2.4623380E-01 1.6762761E-03 -4.1422323E-06

2,2-Dimethyl Propane -1.4910420E+01 1.1569245E-01 -3.2491425E-042-Methyl Pentane -3.7543050E+01 2.9965354E-01 -8.5185402E-043-Methyl Pentane -8.3256687E+01 7.3447972E-01 -2.2414415E-03

2,2-Dimethyl Butane -5.9875080E+01 5.2207091E-01 -1.5832312E-032,3-Dimethyl Butane -7.2550109E+01 6.3731829E-01 -1.9406824E-03

Ethylene -1.5539888E+00 1.0959607E-02 -2.9117054E-05Propylene -4.5381793E+00 3.3392376E-02 -9.0916504E-05

Methyl Alcohol -3.3786365E+02 3.1957400E+00 -1.0203849E-02

Page 22: AGA5 Calculation-Imperial Unit

d7.4728523E-093.5385527E-093.3610994E-083.2324218E-089.6664796E-086.5553464E-064.9972930E-084.3539747E-103.7893031E-093.9105458E-091.7780978E-072.3374270E-074.3972857E-075.1509373E-071.0068068E-061.6343582E-062.4195803E-063.3487620E-065.0313874E-069.3779059E-123.7396815E-093.1803170E-078.3874277E-072.3287791E-061.6384537E-062.0136121E-062.7718654E-088.7376308E-081.0958442E-05

Page 23: AGA5 Calculation-Imperial Unit

Compressibility of Air at Pb, Tb

B -0.0102533110159876Z 0.999566193510363

Correlation from AGA Report #8, 2nd Edition