ADDITIVE COATINGS · 2020. 7. 28. · alternate technologies, growing awareness among users and formulators about the benefits of coating additives, and strong growth in end user

ADDITIVE COATINGS MARKET

TECHNICAL POLYMER SOLUTIONS

The world is becoming more extreme™

The major drivers of the coating additives are growing demand for multifunctional

additives, strict environmental regulations, emerging transition from solvent-borne to

alternate technologies, growing awareness among users and formulators about the benefits of coating additives, and strong growth in end user markets.

The global market size of coating additives is

projected to reach USD 9.19 Billion by 2021,

registering a CAGR of 6.1% between 2016 and 2021

MARKET DRIVERS

FOCUS ON ORGASOL® POWDERS

FOCUS ON RILSAN® FINE POWDERS

4 ADDITIVE COATING MARKET PRESENTATION

ORGASOL® - LARGE NUMBER OF APPLICATIONS

5 ADDITIVE COATINGS MARKET PRESENTATION

MARKET DRIVERS




ORGASOL® - BENEFITS IN ADDITIVE COATINGS


Abrasion Resistance

ScratchResistance

Dry Lubricant Effect / COF drop

Gloss Control

Texturing Effect

Pleasant Hand Touch

ORGASOL® - ROUND SHAPED PARTICLES


GRINDED POLYAMIDE ORGASOL®

ORGASOL® 2002 ES5 NAT3 (50 µm)

Obtained by a unique patented polymerization process

Obtained by a grinding step

ORGASOL® - NARROW PARTICLE SIZE DISTRIBUTION


0

0,5

1

1,5

2

2,5

3

3,5

4

1 10 100

Particle Diameter (µm)

Volu

me

(%)

Orgasol®

Grinded Polyamide

ORGASOL® - PROCESS ABILITY IN COATINGS


0

50

100

150

200

250

0% 2% 5% 10%

Visc

osity

(mPa

.s)

Amount of additive100% UV-curing formulation

Ref Varnish (no additive)+ Orgasol® 2001 EXD NAT1+ Orgasol® 2001 UD NAT1+ Orgasol® 3501 EXD NAT1+ treated Silica

Influence of ultra-fine Polyamide Powders● Example

– 100% solid UV formulation

Viscosity as a function of Orgasol® nature and concentration

Orgasol® powders

Concentration < 5%very low impact on viscosity

Concentration > 5%Slight impact of SSA on viscosity

Benefit:• Select the Orgasol® powder according to targeted application

viscosity

ORGASOL® - ABRASION/SCRATCH RESISTANCE


0

200

400

600

800

1000

1200

Reference 10% PP wax 10% PE-PTFEwax

5% treatedsilica

5% Orgasol®2001 UD NAT1

num

ber o

f cyc

les

to re

ach

the

subs

trate Abrasion (Taber, CS17, 500g)

0

5

10

15

20

25

30

35

40

Reference 10% PP wax 10% PE-PTFEwax

5% treatedsilica

5% Orgasol®2001 UD NAT1

Scra

tch

dept

h (m

m)

Scratch resistance (Load 150g)

100% solids UV formulation Orgasol® powders

Mechanical propertiesHardnessFlexibility

better

worse

better

worse

Abrasion

ORGASOL® - MATTING EFFECT

Addition of Orgasol® Particles

High Gloss Finish Satin Finish(30 to 50 @ 60°)

A matting agent

Orgasol® enables to limit an increase in viscosity level

Optimum gloss reduction for coating thickness 10 µm to 25 µm: ● Because Orgasol® has a limited tendency to migrate at the surface

2001 EXD NAT1, 2001 UD NAT1

ORGASOL® VS INDIRECT COMPETITION

ADDITIVE POWDERS

PE/PP PMMA Silica PTFE - PE

Abrasion resistance ~

Scratch resistance ~ ~

Gloss reduction ~ ~ ~

Texturing effect ~

Other properties

Good slip control Improved clean ability Poor solvent resistance Increase in viscosity Poor stability

Recoat ability issue

ORGASOL® - LUBRICANT EFFECT


Formulation : 2K Polyurethane, WB Dispersion

0

0.2

0.4

0.6

0.8

1

1.2

1.4

1.6

0 1 2 3 4 5 6 7 8 9 10

Cf variation vs Orgasol® particle size and concentration – Coating thickness : 20 microns

20 microns 5 microns

Drop of the friction coefficient (Cf) with low Orgasol® addition (<1-2%)

Cf

% of Orgasol®

ORGASOL® - WOOD COATING APPLICATIONS


Abrasion & Scratch Resistance

Gloss Control

Silky TextureFormulation : WB Polyurethane Acrylic Dispersion

0

10

20

30

40

50

60

70

0 100 200 300 400 500 600 700 800 900 1000

Abrasion ResistanceTaber test CS17-1kg/Coating Thickness=50 microns

Polyurethane-Acrylic Coating 0,75% 2001EXD NAT1(10µm) 0,75% 2001UD NAT1 (5µm)Number of Cycles

Wei

ght l

oss (

mg)

ORGASOL® - METAL CAN COATINGS


Lubricant effect – Gloss control and better flexibility (expected)

Product Chemical Name % w/wCN2610 Polyester acrylate 45%

SR454 Ethoxylated (3)Trimethylolpropane Triacrylate 18%

SR9003 Propoxylated (2) Neopentyl glycol diacrylate 13%

SR602 Ethoxylated (10) Bisphenol A Diacrylate 12%

SR9054 Acidic Acrylate 2%

Irgacure 184 1-Hydroxy-cyclohexyl-phenyl-ketone 3%

Photoinitiator Benzophenone 2%

Orgasol® 2001 UD NAT 1 Polyamide 12 5%

Formulation: UV coating on aluminium substrates @ 5-6 µm

Static COF Dynamic COF

Control 0,63 0,59

5% Orgasol®2001 UD NAT 1

0,52 0,34Divided by

2

ORGASOL® - PLASTIC COATING APPLICATIONS


Abrasion & Scratch Resistance for matte finishes in low Temperature Curing SystemsRecommended Grades: 2001 UD NAT1/ 2001 EXD NAT1 (1-3%)

Final Applications • PVC Profile• Laptop – cell phones –

TV/Stereo Appliances

Average Coating Thickness• 10-20 microns

A Large range of formulations • Acrylic, PU, PE• Solvent based / water

based / UV coating

ORGASOL® - INK & OVERPRINT VARNISHE APPLICATIONS


Recommended Grades: 2001 UD NAT1/ 2 (for food contact)

Focus on:• Gloss Control • Slip & Lubricity (Anti-blocking

effect, Drop of friction coefficient) • Scratch & rub resistance • Texture

Average Coating Thickness• 10 microns

Final Applications• Packaging for cosmetics • Magazines • Films

Improvement of Surface Properties

ORGASOL® - GLASS COATING APPLICATIONS


Recommended Grades: 2001 UD NAT1/ 2 (for food contact)

Solvent based epoxy resins

Possible use of Orgasol grades at 5,

10, 20, 30 microns

Average Coating Thickness: 15 microns

Improvement of Surface Properties

Gloss decreases with the Average Particle Size of Orgasol®

ORGASOL® RANGE


Polyamide Average particle size µm

Specific surface area m2/g Melting point °C Comments

2001 UD NAT1 12 5 9 177

2001 UD NAT2 12 5 9 177 Food contact approved

2001 EXD NAT1 12 10 4 177

2002 EXD NAT1 12 10 1.5 177 Food contact approved

2002 D NAT1 12 20 1 177

2002 ES3 NAT3 12 30 1 177

2002 ES4 NAT3 12 40 1 177

2002 ES5 NAT3 12 50 1 177

2002 ES6 NAT3 12 60 1 177

1002 D NAT1 6 20 2 217

1002 ES5 NAT1 6 50 <1 217

3501 EXD NAT1 6/12 10 20 143

3502 D NAT1 6/12 20 6 143

MARKET DRIVERS




RILSAN FINE POWDERS® - PRODUCT SUMMARY


Biomass origin

Requires less fossil energy and generate less CO2 or other greenhouse gases than most performance polymers

A Polyamide 11 range (high molecular weight thermoplastic polymer)

Unique process from a renewable raw material of plant origin

Various particle size from 20 to 50 µm (+ D80)

Low density (avoiding settlement)

Mass-colored grades for multicolored effect and opacity

Easy to disperse in all kind of liquid paints

PA11 – A SUSTAINABLE POLYMER PRODUCTION CHAIN


Castor plants (renewable source)

Castor seeds

Vegetal oil

Amino 11 (monomer)

Polyamide 11Arkema / Jayant Agro Joint Venture in the production of castor oil

RILSAN® FINE POWDERS – BENEFITS IN ADDITIVE COATINGS


Abrasion Resistance

ScratchResistance

Gloss Control

Recaot ability

Impact Resistance Bending Properties

Texturing Effect

RILSAN® FINE POWDERS – EASY TO USE


Rilsan is an additive in paint formulations incorporated:

Various Formulations

Various Processes

Various Substrates

• Solvent based• Water based• UV curable

• Roller• Brush• Spray

• Metal • Wood• Plastic• Rubber

RILSAN® FINE POWDER RANGE


Polyamide Average particle size µm

Specific surface area m2/g Melting point °C Comments

D30 NAT 11 21 – 27 < 1 186

D40 NAT 11 27 – 31 < 1 186

D50 NAT 11 40 – 46 < 1 186

D60 NAT 11 43 – 55 < 1 186

D80 NAT 11 95 – 105 < 1 186

ES MAC COLOR 11 28 – 36 < 1 186 Several colors

POWDER COATINGS & ADDITIVES MARKET

TECHNICAL POLYMER SOLUTIONS

ORGASOL® VS RILSAN® FINE POWDERS


RILSAN® FINE POWDERS ORGASOL®

Average particle size (µm) Grade reference Average particle size

(µm) Grade reference

2001 EXD NAT1 10

21 – 27 D30 NAT 2002 D NAT1 20

27 – 31 D40 NAT 2002 ES3 NAT3 30

40 – 46 D50 NAT 2002 ES4 NAT3 40

43 – 55 D60 NAT 2002 ES5 NAT3 50

2002 ES6 NAT3 60

* : Malvern Master size D50 ** : Coulter Multisizer II

Rilsan® D40 NAT

Orgasol® 2002 ES5

ORGASOL® VS RILSAN® FINE POWDER


PA12, PA6 PA6/12 PA11

Regular Texture

Easily Cleaned

Uniform spherical particle shape by a

unique patented polymerization

process

More textured effect

Improvement of opacity

Brighter white finish

Multi-colored stable effect

SIM

ILA

R A

BRA

SIO

N &

SC

RATC

H RE

SIST

AN

CE

Higher Melting PointGrinded Particles

White Rilsan Grades

MAC Colour Rilsan Grades

Documents

ADDITIVE COATINGS · 2020. 7. 28. · alternate technologies, growing awareness among users and formulators about the benefits of coating additives, and strong growth in end user