70790 Diethyl Ether - Pigment · 70790 Diethyl Ether Version: 20 1. Identification of the Substance/Mixture and of the Company/Undertaking 1. 1. Product Identifier Product Name: Diethyl

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Revised edition: 13.07.2018

Safety Data SheetAccording to regulation (EC) No. 1907/2006 (REACH)

70790 Diethyl Ether

Version: 20

Identification of the Substance/Mixture and of the Company/Undertaking 1.

Product Identifier 1. 1.

Product Name: Diethyl Ether

Article No.: 70790

Relevant identified Uses of the Substance or Mixture and Uses advised against 1. 2.

Identified uses:Reagent for analysis, chemical production

Uses advised against:

Details of the Supplier of the Safety Data Sheet (Producer/Importer) 1. 3.

Company: Kremer Pigmente GmbH & Co. KG

Address: Hauptstr. 41-47, 88317 Aichstetten, Germany

Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606

Internet: www.kremer-pigmente.de

EMail: [email protected]

Importer: --

Emergency No. 1. 4.

Emergency No.: +49 7565 914480 (Mon-Fri 8:00 - 17:00)

Hazards Identification 2.

Classification of the Substance or Mixture 2. 1.

Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS)

Flammable liquids, hazard category 1Acute toxicity (oral), hazard category 4Specific Target Organ Toxicity (single exposure), hazard category 3Extremely flammable liquid and vapour.H224

Cat.: 1Harmful if swallowed.H302

Cat.: 4May cause drowsiness or dizziness.H336

Cat.: 3

Classification according to Directive No. 67/548/EC or No. 1999/45/EC

Extremely flammable.R12Extremely flammable (F+)May form explosive peroxides.R19Harmful if swallowed.R22Harmful (Xn)Repeated exposure may cause skin dryness or cracking.R66Vapours may cause drowsiness and dizziness.R67

Safety Phrases:

Possible Environmental Effects:

Label Elements 2. 2.

Classification according to Regulation 2 next page:


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Revised edition: 13.07.2018 Version: 20

(EC) No. 1272/2008 (CLP/GHS)

Hazard designation:

GHS02-2

GHS07

Signal word:Danger

Hazard designation:H224 Extremely flammable liquid and vapour.H302 Harmful if swallowed.H336 May cause drowsiness or dizziness.EUH019 May form explosive peroxides.EUH066 Repeated exposure may cause skin dryness or cracking.

Safety designation:P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No

smoking.P240 Ground/bond container and receiving equipment.P403+P233 Store in a well ventilated place. Keep container tightly closed.

Hazardous components for labelling:

Other Hazards 2. 3.

Composition/Information on Ingredients 3.

Substance 3. 1.

Mixture 3. 2.

Chemical Characterization: (C2H5)2O

Information on Components / Hazardous Ingredients:

CAS-Nr: 60-29-7EINECS-Nr: 200-467-2EC-Nr: 603-022-00-4

Diethyl ether (F+,Xn; R12-22-66-67; H224-302-336); REACH Reg. No. 01-2119535785-29-xxxx

Additional information:

First Aid Measures 4.

Description of the First Aid Measures 4. 1.

General information:Remove contaminated clothes immediately.If exposed or you feel unwell: Call a poison center or physician.Stable side position in case of unconsciousness.

After inhalation:Supply fresh air or give oxygen.

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After skin contact:Remove contaminated clothing immediately. Wash off immediately with plenty of water and soap.

After eye contact:Rinse open eyes with plenty of water. In case of discomfort seek medical help.

After ingestion:Careful when vomiting. Risk of aspiration. Keep respiratory tract open.Consult a doctor.If vomiting occurs spontaneously, keep head below hips to prevent aspiration.Pulmonary failure possible. Consult physician.

Most important Symptoms and Effects, both Acute and Delayed 4. 2.

Symptoms:Irritant effects, respiratory paralysis, dizziness, unconsciousness, intoxication, euphoria, collapse, drowsiness, ataxia (impaired locomotor coordination), salivation, coma, death.

Effects:

Indication of any Immediate Medical Attention and special Treatment needed 4. 3.

Treatment:No information available.

Fire-Fighting Measures 5.

Extinguishing Media 5. 1.

Suitable extinguishing media:Foam, CO2, dry extinguishing powder.

Unsuitable extinguishing media:Water

Special Hazards arising from the Substance or Mixture 5. 2.

Special hazards:Vapor is heavier than air and spreads along the ground.In case of fire: formation of carbon monoxide and dioxide.Formation of hazardous combustion gases or vapors possible in the event of fire.

Advice for Firefighters 5. 3.

Protective equipment:Wear self-contained respiratory protective device.Wear suitable protective clothing.

Further information:Avoid contamination of sewage system, open water ways and ground water.Do not inhale explosion and fire gases.

Accidential Release Measures 6.4 next page:


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Personal Precautions, Protective Equipment and Emergency Procedures 6. 1.

Personal precautions:Avoid contact with skin, eyes and clothing.Evacuate the danger area, observe emergency procedures, consult an expert.Do not inhale aerosol/fumes/vapors.Ensure adequate ventilation.

Environmental Precautions 6. 2.

Environmental precautions:Do not discharge into drains; risk of explosion!

Methods and Material for Containment and Cleaning Up 6. 3.

Methods and material:Cover drains. Collect, bind and pump off spills.Contain carefully with absorbent material (e.g. Chemizorb®) and dispose accordingly. Clean remains.

Reference to other Sections 6. 4.

See Section 13 for information on disposal.

Handling and Storage 7.

Precautions for Safe Handling 7. 1.

Instructions on safe handling:Work under an extractor hood.Do not swallow or inhale.Avoid formation of vapors/aerosols.

Hygienic measures:Take off contaminated clothing immediately.Wash hands at the end of work. Preventive skin protection recommended.

Conditions for Safe Storage, including any Incompatibilities 7. 2.

Storage conditions: Store in tightly sealed containers in a well ventilated location.Protect from direct exposure to light.Keep away from ignitable sources, heat and fire.Store between 15-25°C.

Requirements for storage areas and containers:

Store in a cool place.

Information on fire and explosion protection:

Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges.

Storage class (VCI):3: Flammable liquids

Further Information:The product is slightly hazardous to water. Consider national

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regulations regarding handling and storage.

Specific End Use(s) 7. 3.

Further information:See Section 1.2.; no other uses provided

Exposure Controls/Personal Protection 8.

Parameters to be Controlled 8. 1.

Parameters to be controlled (DE):Diethyl ether, CAS 60-29-7; TWA 400 mg/m3, 1200 mg/m3

Parameters to be controlled:ECTLV: Short term exposure limit (STEL): 200 ppm; 616 mg/m3; Time weighted average (TWA): 100 ppm; 308 mg/m3

Derived No-Effect Level (DNEL):616 mg/m3 (worker, inhalation, short-term exposition - systemic effects)44 mg/kg (worker, skin contact, long-term exposition - systemic effects)308 mg/m3 (worker, inhalation, long-term exposition - systemic effects)15.6 mg/kg (consumer, skin contact, long-term exposition -systemic effects)54.5 mg/m3 (consumer, inhalation, long-term exposition - systemic effects)15.6 mg/kg (consumer, swallowing, long-term exposition - systemc effects)

Predicted No-Effect Concentration (PNEC):

Fresh water: 2 mg/lSeawater: 0.2 mg/lFresh water sediment: 9.14 mg/kg Seawater sediment: 0.914 mg/kgSoil: 0.66 mg/kg

Additional Information:

Exposure Controls 8. 2.

Technical protective measures:Use local exhaust ventilation in case of dust and/or fume formation.

Personal Protection

General protective measures:Remove contaminated clothing immediately.Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work.

Respiratory protection:In case of formation of dust/vapor.Recommended: filter AX.

Hand protection:6 next page:


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Protective gloves

Protective glove material:For short-term exposure:Fluoro carbon rubber - FKM (Viton, > 30 min; 0.7 mm).

Eye protection:Tightly fitting safety goggles (EN 166).

Body protection:Protective clothing (flame-proof, antistatic).

Environmental precautions:Do not allow entering sewerage system.

Physical and Chemical Properties 9.

Information on Basic Physical and Chemical Properties 9. 1.

Form: liquid

Color: colorless

Odor: characteristic

Odor threshold: 0.3 - 8.8 ppm

pH-Value:not available

Melting temperature: -116.3°C

Boiling temperature: 34.6°C (1013 hPa)

Flash point: - 40°C

Evaporation rate:No information available.

Flammability (solid, gas):not available

Upper explosion limit: 36 Vol.%

Lower explosion limit: 1.7 Vol.%

Vapor pressure: 587 hPa (20°C)

Vapor density: 2.65 (20°C)

Density: 0.71 g/cm3 (20°C)

Solubility in water: 69 g/l (20°C)

Coefficient of variation (n-Octanol/Water):

0.89 logPOW

Auto-ignition temperature: 180°C

Decomposition temperature:No data available.

Viscosity, dynamic: 0.23 mPa.s (20°C)

Explosive properties:7 next page:


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Product presents an explosion hazard.

Oxidizing properties:none

Bulk density:not determined

Further Information 9. 2.

Solubility in solvents:

Viscosity, kinematic

Burning class:

Solvent content:

Solid content:

Particle size:

Other information:

Stability and Reactivity10.

Reactivity10.1.

Vapors in combination with air can form an explosive compound.

Chemical Stability10.2.

Sensitive to light.Sensitive to air.Stabilized with butylhyroxytoluol (BHT)

Possibility of Hazardous Reactions10.3.

Risk of explosion with azides, halogens, halogen-halogen compounds, non-metals, non-metallic oxyhalides, strong oxidizing agents, chromium(VI) oxide, halogen oxides, peroxy compounds, perchloric acid, perchlorates, nitric acid, nitrating acid.Ignition hazard and formation of inflammable gases or vapors with:chromyl chloride, peroxides.

Conditions to Avoid10.4.

Conditions to avoid:Heating.

Thermal decomposition:No further information available.

Imcompatible Materials10.5.

Rubber, various plastics.

Hazardous Decomposition Products10.6.

Peroxides.

Further Information10.7.

Toxicological Information11.

Information on Toxicological Effects11. 1.

Acute Toxicity

LD50, oral: 1215 mg/kg (rat; RTECS)8 next page:


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LD50, dermal: > 2000 mg/kg (ECHA)No information available.

LC50, inhalation:Symptoms: mucosal irritations

Primary effects

Irritant effect on skin:Non irritating (rabbit; OECD 404)Repeated contact can cause brittle and cracked skin.

Irritant effect on eyes:Non-irritating to eyes (rabbit; OECD 405)

Inhalation:No information available.

Ingestion:No information available

Sensitization:Non sensitizing (mouse; OECD 429).

Mutagenicity:In vitro genetic-toxicity: Ames-Test negative (Salmonella typhimurium; IUCLID)In vivo genetic-toxicity: negative (OECD 474, mouse)In vitro Mammalian Cell Micronucleus Test (OECD 487): negativeIn vitro genetic-toxicity: negative (OECD 476, mouse lymphona cells)

Reproductive toxicity:No information available.

Carcinogenicity:No relevant data found.

Teratogenicity:No information available.

Specific target organ toxicity (STOT):Single exposure: may cause drowsiness or dizziness.Repeated exposure: no information available.

Additional toxicological information:Absortion: salivation, euphoria, ataxia (impaired locomotor coordination), intoxication, collapse, unconsciousness, coma.Cannot be excluded: respiratiory paralysis, death.Narcotic !Handle in accordance with good industrial hygiene and safety practice.

Ecological Information12.

Aquatic Toxicity12. 1.

Fish toxicity:LC50: 2840 mg/l (48h, Leuciscus idus) (ECOTOX Database)

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Daphnia toxicity: EC50: 1380 mg/l (48h, Daphnia magna) (IUCLID)NOEC: > 100 mg/l (21d; Daphnia magna; OECD 211)

Bacteria toxicity:EC50: 21000 mg/l (3h; active sludge; OECD 209)NOEC: 42 mg/l (3h; active sludge; OECD 209)

Algae toxicity:EC50: > 100 mg/l (72h, Desmodesmus subspicatus; OECD 201)

Persistency and Degradability12. 2.

Not readily biodegradable.

Bioaccumulation12. 3.

No bioaccumulation expected (log P(o/w) < 1).

Mobility12. 4.

No information available.

Results of PBT- und vPvP Assessment12. 5.

The contents of the preparation do not comply with the criteria for the classification as PBT or vPvB.

Other Adverse Effects12. 6.

Water hazard class:Do not let run into surface waters, waste water or soil.

Behaviour in sewage systems:

Further ecological effects:Henry Constant: 124.6 Pa.m3/mol (Lit.) Distribution preferentiallyin air.

AOX Value:

Disposal Considerations13.

Waste Treatment Methods13. 1.

Product:Dispose of according to official national and local regulations.Leave chemical in original containers. Do not mix with other waste.

European Waste Code (EWC):

Uncleaned packaging:Packaging may be disposed of in the same manner as the product.

Waste Code No.:

Transport Information14.

UN Number14. 1.

ADR, IMDG, IATA 1155

UN Proper Shipping Name14. 2.

ADR/RID: DIETHYLETHER

IMDG/IATA: DIETHYL ETHER10next page:


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Transport Hazard Classes14. 3.

ADR Class: 3

Hazard no.: 3

Classification code: F1

Tunnel restriction code: D/E

IMDG Class (sea): 3

Hazard no.: 3

EmS No.: F-E, S-D

IATA Class: 3

Hazard no.: 3

Packaging Group14. 4.

ADR/RID: I

IMDG: I

IATA: I

Environmental Hazards14. 5.

None

Special Precautions for User14. 6.

not applicable

Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code14. 7.

not applicable

Further Information14. 8.

Regulatory Information15.

Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture15. 1.

Water hazard class:1, slightly hazardous for water (German Regulation)

Local regulations on chemical accidents:Seveso III:Extremely flammable, 8Quantity 1: 10 t; Quantity 2: 50 t

Employment restrictions:The employment restrictions for young workers in accordance with the Youth Employment Protection Law (94/33/EC) are to be observed.The employment restrictions for expectant and nursing mothers in accordance with the Maternity Protection Guideline (94/85/EEC) are to be observed.

Restriction and prohibition of application:

Technical instructions on air quality:

Chemical Safety Assessment15. 2.

A Chemical Safety Assessment has not been carried out for this 11next page:


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product.EC SVHC-List: This product does not contain a substance in the candidate list for substances of very high concern above the legallimit value (> 0.1 % (w/w) REACH Regulation (EC) 1907/2006, Article 57).

Further Information15. 3.

Regulation (EC) 850/2004 - Persistent organic pollutants and amending Directive 79/117/EEC: not regulated / not applicableRegulation (EC) 1005/2009 - Substances that Deplete the Ozone Layer: not regulated / not applicable

Other Information16.This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our productfrom the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.

Documents

70790 Diethyl Ether - Pigment · 70790 Diethyl Ether Version: 20 1. Identification of the Substance/Mixture and of the Company/Undertaking 1. 1. Product Identifier Product Name: Diethyl