3rd Year Courses

8/9/2019 3rd Year Courses

1/9

SESSION: 2010-2011, 2011-2012, 2012-2013

Course No. Chem. 310F 1 Unit, 4 Credits

Physical Chemistry III (Selected Topics in Physical Chemistry) 70 + 20 + 10 = 100 Marks

1. Eletri !r"!erties "# $"le%les: &i!"le $"$ent' !"lari(ati"n' !"lari(a)ilities' &e)*e e%ati"n'

Cla%si%s-M"ss"tti e%ati"n' de!endene "# !"lari(a)ilit* "n #re%en*' deter$inati"n "# di!"le$"$ent' )"nd $"$ents and $"le%lar di!"le $"$ents, a!!liati"n "# di!"le $"$ent in

el%idati"n "# i"ni arater and e"$etr* "# $"le%les' interati"n )eteen di!"les' !"tentialener* "# interati"n, di!"le-di!"le, di!"le-ind%ed-di!"le and ind%ed-di!"le-ind%ed-di!"le

interati"ns.

2. Maneti !r"!erties "# s%)stanes: Maneti !er$ea)ilit* and s%se!ti)ilit*' !ara$aneti,

dia$aneti and #err"$aneti s%)stanes' te"ries "# $anetis$s' $eas%re$ent "# $aneti

s%se!ti)ilit*' a!!liati"n "# $aneti s%se!ti)ilit* $eas%re$ents.

3. /"t"e$istr*: /"t"e$ial !r"esses' las "# !"t"e$istr*' %ant%$ e##iien*' !ri$ar*

and se"ndar* !"t"e$ial !r"esses' #l%"resene' !"s!"resene' !"t"-diss"iati"n'e$il%$inesene' !"t"sensiti(ati"n' !"t"e$ial e%ili)ri%$' !"t"e$ial !r"esses:"$$"n !"t"!*sial !r"esses and teir ti$esales, $eanis$ "# dea* "# eited sinlet

states' %enin' ener* trans#er and eletr"n trans#er !r"esses' !"t"e$ial ain reati"ns:

*dr"en-l"rine and *dr"en-)r"$ine reati"ns, !"t"l*sis "# aetalde*de' lasers anda!!liati"ns "# lasers in e$istr*

4. Catal*sis and kinetis "# eter"ene"%s reati"ns: *!es and arateristis "# atal*sis' te"r* "#"$"ene"%s atal*sis' #%nti"n "# a atal*st in ter$s "# i))s #ree ener* "# atiati"n' te"r* "#

eter"ene"%s atal*sis' kinetis "# eter"ene"%s reati"ns' e##et "# te$!erat%re "n

eter"ene"%s reati"ns' a)s"l%te rate te"r* in eter"ene"%s as reati"ns' aid-)ase atal*sis'

$eanis$ and kinetis "# aid-)ase atal*sis.

. S%r#ae e$istr*: 5ds"r!ti"n, a)s"r!ti"n and s"r!ti"n' !*sis"r!ti"n and e$is"r!ti"n' ads"r!ti"n

is"ter$s: 6re%ndli, an$%ir8s and 9E is"ter$s' !r"!erties "# li%id s%r#aes: s%r#ae tensi"n,%red s%r#aes, a!illar* ati"n' s%r#ae #il$s' s%r#ae !ress%re, s%r#ae eess' s%r#ae #ree ener*.

. C"ll"ids: C"ll"idal dis!ersi"ns, lassi#iati"n "# "ll"ids' l*"!ili and l*"!")i "ll"ids'!re!arati"n and !r"!erties "# s"ls' "!tial !r"!erties: *ndall e##et' eletrial !r"!erties:

eletr"!"resis, eletr""s$"sis, strea$in and sedi$entati"n !"tential' eletrial d"%)le la*er, (eta

!"tential' sta)ilit* "# s"ls' els' e$%lsi"ns' $ielles' &"nnan $e$)rane e%ili)ri%$.

7. Eletr"e$ial eni%es: ;"lta$$etr*: "lta$$etri instr%$entati"n, $ir"eletr"des,"lta$$"ra$s, *dr"d*na$i "lta$$$etr*, a!!liati"ns "# *dr"d*na$i "lta$$etr*,

a$!er"$etri titrati"ns, *li "lta$$etr*. /"lar"ra!*: !rini!le "# !"lar"ra!*, $ass trans#er!r"ess, #at"rs a##etin li$itin %rrents, Ilk"i e%ati"n, al# ae !"tential, instr%$entati"n,

!"lar"ra!i anal*sis, 5dataes and a!!liati"ns "# !"lar"ra!*, r"n"!"tenti"$etr*.

Suggested eadings!

1. Ele$ents "# /*sial Ce$istr*, S. lasst"ne and &. eis, Ma$illan Ed%ati"n.

2. /*sial Ce$istr*, /. Aa").

D. /rini!les "# Instr%$ental 5nal*sis 6i#t editi"nF: & 5 Sk"", 6 A "ller and 5 Nie$an.10.Instr%$ental Met"ds "# Ce$ial 5nal*sis: Ga%r.

20


2/9

SESSION: 2010-2011, 2011-2012, 2012-2013

Course No. Chem. 31"# H Unit, 2 Credits

$uantum Chemistry and Statistical Thermodynamics 3 + 10 + = 0 Marks

%! $uantum Chemistry

1. &eel"!$ent "# %ant%$ $eanis: 6ail%re "# lassial $eanis' )lak )"d* radiati"n'!"t"eletri e##et' Ca$!t"n e##et' de-9r"lie8s "ne!t "# d%al nat%re "# eletr"n' eisen)er8s

%nertainl* !rini!le' Sr"diner ae e%ati"ns' eien al%es and eien #%nti"ns' n"r$ali(ati"n'

"rt""nalit*' "!erat"rs' !"st%lates "# %ant%$ $eanis.

2. 5!!liati"n "# %ant%$ $eanis: !artile in a "ne-di$ensi"nal )"' eletr"n in a rin' !artile in a

tree-di$ensi"nal )", si$!le ar$"ni "sillat"r' ae #%nti"ns "# te ar$"ni "sillat"r'

a!!liati"n "# Sr"diner e%ati"n t" te *dr"en at"$' se!arati"n "# aria)les, sini#iane "#

F, F and ?rF e%ati"n, %ant%$ n%$)ers and t"tal ener* "# an "r)ital, s!ae ae #%nti"ns

and radial distri)%ti"n %res.

3. 5!!r"i$ate $et"ds: /ert%r)ati"n Met"d, ;ariati"n Met"d and sel# "nsistent 6ield Met"d'5!!liati"n "# a!!r"i$ate $et"ds #"r al%latin eneries "# eli%$ at"$, *dr"en $"le%le i"n

and *dr"en $"le%le.

&! Statistical Thermodynamics

1. /r")a)ilit* distri)%ti"n "# !artiles: /r")a)ilit* and ter$"d*na$i !r")a)ilit*' !r")a)ilit*distri)%ti"n "# !artiles in ener* states' $"st !r")a)le distri)%ti"n' deriati"n "# Maell-9"lt($ann

distri)%ti"n la.

2. /artiti"n #%nti"ns: &e#initi"n and !*sial sini#iane "# !artiti"n #%nti"n' se!arati"n "# !artiti"n

#%nti"ns' translati"nal, r"tati"nal, i)rati"nal, eletr"ni, and t"tal !artiti"n #%nti"n' relati"nsi!

)eteen !artiti"n #%nti"ns and ter$"d*na$i #%nti"ns' $"lar !artiti"n #%nti"ns' a!!liati"n "#

!artiti"n #%nti"n t" $"n"at"$i and diat"$i $"le%les' statistial e!ressi"n #"r e%ili)ri%$"nstant' e%i!artiti"n "# ener*.

3. %ant%$ statistis: Maell-9"lt($ann statistis' 9"se-Einstein statistis' 6er$i-&ira statistis'eletr"n as in $etals' s!ei#i eat "# s"lids' Einstein and &e)*e te"r* "# s!ei#i eat.

Suggested eadings!

1. e"retial Ce$istr*, S. lasst"nes.

2. %ant%$ Ce$istr*, M. ?. 5"de, S. Cand > C". td., Ne &eli.3. 5daned /*sial Ce$istr*, %rdee! ?a@, OE /%)lisin "%se, Meer%l, India.

4. 5daned C"ne!ts in /*sial Ce$istr*, E. &. Ga%#$ann.

. Intr"d%ti"n t" %ant%$ Meanis, . /a%lin and E. 9.


3/9

SESSION: 2010-2011, 2011-2012, 2012-2013

Course No. Chem. 3"0F 1 Unit, 4 Credits

Inorganic Chemistry III (%d'anced Concepts) 70 + 20 + 10 = 100 Marks

1. 5t"$i str%t%re: Nat%re "# ae $"ti"n, te SrJdiner ae e%ati"n, inter!retati"n "# te

ae #%nti"n, s"l%ti"n "# te ae e%ati"n, SrJdiner e%ati"n #"r *dr"en like at"$,se!arati"n "# aria)les, te radial and an%lar #%nti"ns and !r")a)ilit* #%nti"ns, re!resentati"n "#

s*$$etr* "r)itals, e##etie n%lear are and sieldin, eneral i$!liati"ns "# %ant%$ te"r*in e$istr*.

2. &etailed st%d* "# te )"nd t*!es: ritial st%dies "# di##erent )"nd t*!es and te"ries:aF I"ni )"nd, si(e "# te i"ns > i"ni str%t%res' inter-at"$i distanes and teir relati"nsi! it te

str%t%res "# "$!"%nds and r*stals.

)F e nat%re "# te "-alent )"ndin: ae $eanial !rini!le, alene )"nd te"r* ;9F "#

*dr"en $"le%le, *)ridi(ati"n, ;9 desri!ti"n %sin *)rid "r)itals, is"l")alit*, res"nane.F M"le%lar "r)ital te"r* MOF "# "$"- and eter"-diat"$i $"le%les, OMO and UMO,

$"le%lar "r)itals "# !"l*at"$i $"le%les it - and -)"ndin, te liand r"%! "r)ital a!!r"a,"$!aris"n "# ;9 and MO.

3. e e$istr* "# transiti"n $etals and "-"rdinati"n "$!"%nds:

aF e transiti"n ele$ents: Eletr"ni "n#i%rati"n, s!eial !r"!erties.

)F Ele$ents "# ""rdinati"n Ce$istr*: N"$enlat%re #"r ""rdinati"n "$!"%nds,


4/9

SESSION: 2010-2011, 2011-2012, 2012-2013

Course No. Chem. 3""# H Unit,2 Credits

Inorganic Chemistry I (Selected Topics) 3 + 10 + =0 Marks

1. 9"ndin in $etals and all"*s: e te"r* "# $etals, alene )"nd a!!r"a, te )and te"r* "#

$etals, $etalli !r"!erties, s"lid s"l%ti"ns, s%!!er str%t%re and inter$etalli "$!"%nds,n"nst"ii"$etri "$!"%nds.

2. N"n-a%e"%s s"lent s*ste$: Classi#iati"n "# s"lents, !r"!erties "# i"ni(in s"lents, s"l%)ilit*

riteria in i"ni(in s"lents, aid )ase !en"$en"n in n"n-a%e"%s s*ste$. St%dies "# s"$e t*!ialn"n-a%e"%s i"ni(in s"lents s% as li%id a$$"nia, li%id s%l!%r di"ide, li%id *dr"en

s%l!ide and an*dr"%s s%l!%ri aid.

3. Eletr"n de#iient and n"nst"ii"$etri "$!"%nds: aF 9"r"n *drides and teir deriaties,

!r"!erties and st%dies "# teir )"ndin and str%t%res' te )"r"*drides, )F Metal ar)ides'

lassi#iati"n, str%t%re, #"r$ati"n and %ses, ra!ite "$!"%nds.

4. In"rani !"l*$ers: Cain and net"rk !"l*$ers, Sili"n !"l*$ers' 9"r"n nitr"en !"l*$ers'

S%l!%r-Nitr"en !"l*$ers' /"s!"nitrili "$!"%nds' 6l%"r"ar)"ns: !re!arati"n, str%t%re and

%ses' Ce$istr* "# #%llerenes.

. 9i"in"rani Ce$istr*: Metall"!"r!*rins: Cl"r"!*ll, C*t"r"$e, e$"l")in and

M*"l")in, ;ita$in 9 and 912"en(*$es' Ir"n-s%l!%r !r"teins. Nitr"en #iati"n.

. antanides: O%rrene, eletr"ni "n#i%rati"n, !"siti"n in !eri"di ta)le, eneral e$istr*,

se!arati"n teni%es, 5tinides: O%rrene, Eletr"ni "n#i%rati"ns, "idati"n states, eneralCe$istr*, "ran"$etalli e$istr* "# atinides' antanide "$!"%nds as NM? si#t reaents.

Suggested eadings!

1. 5daned In"rani Ce$istr*, 6. 5. C"tt"n and . Geiter.

3. Ce$istr* "# n"n-a%e"%s s"lents,


5/9

SESSION: 2010-2011, 2011-2012, 2012-2013

Course No. Chem. 330F 1 Unit, 4 Credits

rganic Chemistry III (%d'anced rganic Chemistry) 70 + 20 + 10 = 100 Marks

1. S!etr"s"!* in anal*sis "# "rani "$!"%nds: 5 )rie# intr"d%ti"n and a!!liati"ns "# I?, U;,NM? and Mass s!etr"s"!* in str%t%ral el%idati"n "# si$!le "rani "$!"%nds.

2. Stere"e$istr*: cis-transis"$eris$, C=C, C=N *l"alkane inter "nersi"n "# cis-transis"$ers,!*sial !r"!erties: &eter$inati"n "# "n#i%rati"n )* e$ial and !*sial $et"ds' "n#"r$ati"n

"# a*li $"le%les: !*sial and s!etral !r"!erties "# diastere"is"$ers and "n#"r$ers,

"n#"r$ati"n and reatiit*.

C"n#i%rati"n: relatie and a)s"l%te "n#i%rati"n, n"tati"n: ?LS, &L "n#i%rati"n deter$inati"n'

e$ial inter"nersi"n, e$ial "rrelati"n $et"ds.

3. Orani ?eati"n Meanis$s: Classes "# reati"n $eanis$' $et"ds #"r deter$inin reati"n

$eanis$s: Is"lati"n "# /r"d%ts, ra!!in and deteti"n "# Inter$ediates, Is"t"!e train, Ginetisand stere"e$ial eidene.

4. 9r"ad "ne!t "# te $eanis$ "# te #"ll"in lasses "# "rani reati"ns: aF N%le"!ili

s%)stit%ti"n reati"ns in ali!ati s*ste$: SN1 and SN2, SNi reati"ns-kinetis, E##et "# s"lent, E##et

"# str%t%re, E##et "# attakin reaents and leain r"%!s, stere"e$istr*, nei)"rin r"%!!artii!ati"n, steri e##et' all*li rearrane$ent. 5r"$ati N%le"!ili s%)stit%ti"n reati"ns'

)F Eli$inati"n reati"ns: E1 and E2 $eanis$s' "rientati"n in eli$inati"n reati"ns' "$!etiti"n

)eteen eli$inati"n and s%)stit%ti"n' intra$"le%lar isF eli$inati"n' F 5dditi"n ?eati"ns:

5dditi"n t" ar)"n-ar)"n $%lti!le )"nds: *drati"n "# "le#ins' additi"n "# *dr"en alides' !er"ideinitiated additi"n "# *dr"en )r"$ide' additi"n "# al"ens. Meanis$ > stere"e$istr* "#

n%le"!ili additi"ns, &ielKs -5lder reati"ns, *dr"*lati"n-is and trans.

. Na$e ?eati"ns:


6/9

SESSION: 2010-2011, 2011-2012, 2012-2013

Course No. Chem. 33"# H Unit, 2 Credits

rganic Chemistry I (Chemistry o* Natural Products) 3 + 10 + = 0 Marks

1. Nat%ral !r"d%ts: &e#initi"n, "%rrene > i$!"rtane "# s"$e nat%ral !r"d%ts.

2. er!en"ids: &e#initi"n, lassi#iati"n, essential "ils, is"!rene r%le, is"lati"n and !%ri#iati"n,eneral $et"ds "# deter$inin str%t%res "# ter!en"ids. &etailed st%dies "# s"$e $"n"ter!en"ids :

iF a*li $"n"ter!en"ids like $*rene, itral' iiF $"n"*li $"n"ter!en"ids like li$"nene'iiiF )i*li $"n"ter!en"ids like a$!"r. 9i"s*ntesis "# $"n"ter!en"ids.

3. Car)"*drates: &e#initi"n' lassi#iati"n' $"n"saarides: str%t%re, "n#i%rati"n and

"n#"r$ati"n "# l%"se' reati"n' disaarides: str%t%res and "n#"r$ati"ns "# s%r"se and

$alt"se' !"l*saarides: !reli$inar* ideas "# star and ell%l"se.

4. 5$in" aids and !r"teins: Str%t%re, lassi#iati"n, s*ntesis, !*sial and e$ial )eai"%r "#a$in" aids' anal*sis "# a$in" aids' !e!tides: str%t%re and s*ntesis' !r"teins: eneral nat%re.

. /%rines and n%lei aids: Intr"d%ti"n' str%t%re and s*ntesis "# i$!"rtant deriaties "# !%rine)ases' str%t%ral el%idati"n "# %ri aid, n%le"sides, n%le"tides and n%lei aids' re!liati"n "#

&N5.

. 5lkal"ids: O%rrene, lassi#iati"n, etrati"n and !%ri#iati"n "# alkal"ids' eneral $et"ds "#

deter$inin str%t%re. Ce$istr* "# e!edrine, atr"!ine and $"r!ine.

Suggested eadings!

1. Orani Ce$istr* )* I. . 6inar, "n$ans, ;"l. 2, E9S, "n$an.

2. Nat%ral /r"d%t Ce$istr*, G. 9. . "rssell, A.


7/9

. Eletr"ni s!etr"s"!* "# $"le%les: Eletr"ni s!etra "# diat"$i $"le%les' i)rati"n "arse

str%t%re, 6rank-C"nd"n !rini!le' diss"iati"n ener* and diss"iati"n !r"d%ts' r"tati"nal #inestr%t%re "# eletr"ni i)rati"n transiti"n, eletr"ni an%lar $"$ent%$ in diat"$i $"le%les,

s!etr%$ "# *dr"en $"le%le, e$ial anal*sis )* eletr"ni s!etr"s"!*' re-e$issi"n "# ener*

)* eited $"le%les: #l%"resene and !"s!"resene.

7. S!in ?es"nane S!etr"s"!*: S!in and an a!!lied $aneti #ield, n%lear $aneti res"nane

s!etr"s"!*, 1 n%lear $aneti res"nane s!etr"s"!*' eletr"n s!in res"nane s!etr"s"!*:

intr"d%ti"n, te !"siti"n "# ES? a)s"r!ti"ns, te #ine str%t%re "# ES? a)s"r!ti"ns, *!er#inestr%t%re, d"%)le res"nane in ES?, teni%es "# ES? s!etr"s"!*.

Suggested eadings!

1. 6%nda$entals "# M"le%lar S!etr"s"!*, C. N. 9anell and E. M. Mas, ata Mra-ill.2. Intr"d%ti"n t" M"le%lar S!etr"s"!*, . M. 9arr".

3. M"dern S!etr"s"!*, A. Miael "llas, San 5nand.. M"le%lar S!etr"s"!*, /. S. Sind%, ata Mra-ill /%)lisin C"$!an* td., Ne &eli.

. Intr"d%ti"n t" S!etr"s"!*, 6. /. arkins.

7. 9asi /rini!les "# S!etr"s"!*, ?. Can.

SESSION: 2010-2011, 2011-2012, 2012-2013

Course No. Chem. 3,0# 1L2Unit, 2 Credits

Fundamentals o* Pharmaceutical Chemistry 3 + 10 + = 0 Marks

1. Intr"d%ti"n: /ar$ae%tial !r"ess: ra $aterial, lassi#iati"n, testin, !r"%re$ent, i$!"rtane

"# /ar$ae%tial e$ials and !r"essin "# /ar$ae%tial !r"d%ts, E%i!$ents.

2. /ar$a"l"*: &e#initi"n and r"%!s "# dr%s. /r"dr%s, lassi#iati"n "# dr%s. S"%re "# dr%s,

r"%tes "# ad$inistrati"n, /ar$a"enetis, /ar$a"d*na$is, !rini!le, $eanis$ "# dr% ati"n.

3. /ar$ae%tis: aF a)lets: &e#initi"n, "$!"nent "# ta)lets, #"r$%lati"n "# di##erent t*!e "# ta)lets,ran%lati"n ten"l"*, ta)let $akin and "atin, testin' )F Ca!s%les' 5dantae and disadantae,

$aterials #"r !r"d%ti"n "# ard elatin a!s%les, $et"d "# a!s%le #illin, s"#t elatin a!s%le #illin,

i$!"rtane, eal%ati"n "# a!s%les, sta)ilit* testin' F O!tal$i !re!arati"n' re%ire$ents,#"r$%lati"n, $et"ds "# !re!arati"n, "ntainers.

4. Ce$"tera!* "# $ir")ial diseases: aF S%l#"na$ides, tri$et"!ri$-s%l!a$et"a("le: S*ntesis,

$"de "# ati"n' )F /eniillin, e!al"s!arins and "ter -lata$ anti)i"tis' F &r%s %sed int%)er%l"%s and le!r"s*' dF 5nti#%nal aents: M"de "# ati"n and s*ntesis' eF Ce$"tera!* "#

ne"!lasti diseases: eneral "nsiderati"n, lassi#iati"n, $eanis$ "# ati"n, side e##ets' #F5ntidia)etis, ins%lin, s*ntesis, $"de "# ati"n.

. aF /ar$ae%tial anal*sis: Sini#iane "# %antitatie anal*sis in !ar$ae%tial %alit*

ass%rane. %alit* ass%rane and %alit* "ntr"l, te"r* and )asi "ne!ts "# M/, ISO D000, ISO

D001, M.' )F itri$etri anal*sis: 5id-)ase titrati"n in !ar$ae%tial anal*sis, "idati"n-red%ti"n titrati"n, i"di$etr* and i"d"$entr*, a!!liati"n in !ar$ae%trial anala*sis' F N"n-

a%e"%s titrati"n: /rini!le and a!!liati"n' dF Instr%$ental anal*sis: U;, I?, /C: 5!!liati"n in

dr% anal*sis s!ei#i ea$!lesF' eF Mir")i"l"ial assa*: !rini!le and a!!liati"n s!ei#iea$!lesF.

Suggested eadings!

1. e e"r* and /ratie "# Ind%strial /ar$a*, . a$an, 3rd Indian editi"n, ;arese

/%)lisin "%se, 9"$)a*.

2. 9asi and Clinial /ar$a"l"*, 9. . Gat(s%n, Dtediti"n, Mra ill, N.B.

3. eneral /rini!les "# /ar$a"l"*, tediti"n, Mir Mes)a%ddin and Md. ?a)i%l Isla$,9enal i)rar*, &aka.

4. Mediinal Ce$istr*, 9%rer.

. 6"*e8s /rini!les "# Mediinal Ce$istr*, &aid 5.


8/9

SESSION: 2010-2011, 2011-2012, 2012-2013

Course No. Chem. 31,-F 1 Unit, 4 Credits

Physical Chemistry Practical III 70 + 20 + 10 = 100 Marks

E!t. 1. &eter$inati"n "# te $"le%lar eit "# a s"lid )* e)%lli"s"!i $et"d.

Expt. 2. Determination of the adsorption isotherm of acetic acid from aqueous solution bycharcoal.

E!t. 3. &eter$inati"n "# te li%id-li%id $isi)ilit* "# !artiall* $isi)le tree li%id s*ste$.

E!t. 4. /ase diara$s #"r t"-"$!"nent s*ste$.

E!t. . &eter$inati"n "# te ra$-$"le%lar "l%$e "# etan"l and its !artial $"ral "l%$e ina%e"%s s"l%ti"n at r""$ te$!erat%re.

E!t. . &eter$inati"n "# te s!ei#i r"tati"n "# s%r"se and te s!ei#i reati"n rate "# teinersi"n "# s%r"se in !resene "# an aid !"lari$etri $et"dF.

E!t. 7. &eter$inati"n "# te !erentae "# d-s%r"se and d-tartari aid in a ien s"l%ti"n

!"lari$etriall*.E!t. . aF &eter$inati"n "# te a)s"r!ti"n %re "# a "l"%red s%)stane in s"l%ti"n and t" eri#*

te alidit* "# 9eer8s la and )F &eter$inati"n "# te strent "# an %nkn"n s"l%ti"n.

E!t D. &eter$inati"n "# te "nentrati"n "# G2Cr2O7 and GMnO4 in a s"l%ti"n $it%re )*

s!etr"!"t"$etri $et"d.

E!t.10. &eter$inati"n "# te ell "nstant "# a "nd%tane ell and t" $eas%re te s"l%)ilit* "# a

s!arinl* s"l%)le salt )* "nd%t"$etri $et"d.

E!t.11. &eter$inati"n "# te s!ei#i reati"n rate "# te *dr"l*sis "# an ester )* NaO s"l%ti"n

"nd%t"$etri $et"dF.

E!t.12. &eter$inati"n "# te e%ialent "nd%tane at in#inite dil%ti"n and te diss"iati"n

"nstant "# a eak aid.

E!. 13 e e%ialent "nd%tane "# a str"n eletr"l*te and t" ea$ine te alidit* "# Onsaere%ati"n.

E!t.14. C"nd%tr"$etri titrati"n "# aF str"n and )F eak aids and t" dra teir ne%trali(ati"n%res.

E!t.1. C"nd%t"$etri titrati"n "# an aid $it%re.

E!t.1. &eter$inati"n "# te 6e+2i"n "nentrati"n in a ien s"l%ti"n )* !"tenti"$etri titrati"nand t" deter$ine te al%e "# E" 6e

2+L6e3+.

E!t.17. /"tenti"$etri titrati"n "# !"s!"ri aid and al%lati"n "# te diss"iati"n "nstant.

N.9.: E!eri$ents $a* )e added t" "r "$itted #r"$ te a)"e list i# neessar*.

Suggested eadings!

1. 5daned /*sial Ce$istr* E!eri$ents, A. N. %rt% > 5$it %rt%

2. /ratial /*sial Ce$istr*, 5. 6indla*, "n$ans, reen > C". td.

3. /ratial /*sial Ce$istr*, /alit, Siene 9""k 5en*.4. /ratial /*sial Ce$istr*, Sar$a, ;ikas /%)lisin "%se, Cal%tta.

. 5daned /ratial /*sial Ce$istr*, A. 9. Bada.

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9/9

SESSION: 2010-2011, 2011-2012, 2012-2013

Course No. Chem. 33,-F 1 Unit, 4 Credits

Identi*ication o* rganic compounds 70 + 20 + 10 = 100 Marks

1. /*sial a!!earane

2. Ele$ental anal*sis3. S"l%)ilit* est

4. 6%nti"nal r"%! anal*sis: aF Ce$ial $et"ds, )F S!etr"s"!i $et"ds. /re!arati"n "# deriaties

. iterat%re s%re*

7. &eter$inati"n "# /*sial C"nstants $.! > $ied $.! deter$inati"nF.

. Na$in "# te identi#ied "$!"%nds.

Suggested eadings!

1. and )""k "# Orani 5nal*sis, %alitatie and %antitatie, . . Clarke, 9. a*nes, E. C.9rik, . C. S"ne, Edard 5rn"ld, t Editi"n.

2. S*ste$ati Identi#iati"n "# Orani C"$!"%nds, ?. . Sriner, ?. C. 6%s"n and &. B. C%rtin,

A"n A"e Casad, e$edia, 20 5nsari ?"ad, Ne &eli-2.

2

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