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312 CHAPTER 18 Chemical Bonds Have you ever seen an object with rust on it? What was the object made of? Why do you think rust formed on it? What You’ll Learn about elements in a compound chemical formulas how electric forces help form compounds why a chemical bond forms Before You Read Read to Learn Combined Elements Have you ever noticed that the Statue of Liberty is green? Was it painted green? Is it made of green stone? Actually, the Statue of Liberty is made of the metal copper. Copper is an element. Pennies are also made of copper. If copper usually has a shiny, metallic color, then why is the Statue of Liberty green? Do compounds look like their elements? Some matter around you is in the form of elements. For example, oxygen, copper, and sulfur are all elements. All three exist by themselves. They can also combine with other elements in a chemical reaction to form compounds. When copper, sulfur, and oxygen combine in a chemical reaction, they produce the green coating like on the Statue of Liberty. This compound is copper sulfate, which is a green solid. It is nothing like the elements that combined to make it. Copper is a shiny, copper-colored solid. Sulfur is a yellow solid. Oxygen is a colorless, odorless gas. When elements combine, they form compounds with their own properties. Do compounds have new properties? Compounds may have different properties from the elements that form them. Sodium chloride, or table salt, is a compound made from the elements sodium and chlorine. Sodium is a shiny, soft, silvery metal that reacts violently with water. Chlorine is a greenish-yellow, poisonous gas. These two elements combine to form the salt that people use in their food. Make Flash Cards As you read, make a flash card of each element mentioned in the text. Include the name of the element, its chemical symbol, and its electron dot diagram. Study Coach A Find Main Ideas Make a Foldable like the one below. As you read this section, write down the main ideas about combined elements, formulas, and atomic stability. Combined Elements Formulas Atomic Stability chapter Chemical Bonds section Stability in Bonding 1 Copyright © Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc. 18

312 335 Ch18 RE 896315.qxd 3/26/10 3:44 AM Page 312 S ... do atoms form compounds? Look at the periodic table on the inside back cover of this book. It lists all the known elements

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312 CHAPTER 18 Chemical Bonds

Have you ever seen an object with rust on it? What was theobject made of? Why do you think rust formed on it?

What You’ll Learn

■ about elements in acompound

■ chemical formulas ■ how electric forces help

form compounds■ why a chemical bond

forms

Before You Read

Read to LearnCombined Elements

Have you ever noticed that the Statue of Liberty is green?Was it painted green? Is it made of green stone? Actually, theStatue of Liberty is made of the metal copper. Copper is an element. Pennies are also made of copper. If copper usually hasa shiny, metallic color, then why is the Statue of Liberty green?

Do compounds look like their elements?Some matter around you is in the form of elements.

For example, oxygen, copper, and sulfur are all elements.All three exist by themselves. They can also combine withother elements in a chemical reaction to form compounds.

When copper, sulfur, and oxygen combine in a chemicalreaction, they produce the green coating like on the Statue ofLiberty. This compound is copper sulfate, which is a greensolid. It is nothing like the elements that combined to makeit. Copper is a shiny, copper-colored solid. Sulfur is a yellowsolid. Oxygen is a colorless, odorless gas. When elementscombine, they form compounds with their own properties.

Do compounds have new properties?Compounds may have different properties from the elements

that form them. Sodium chloride, or table salt, is a compoundmade from the elements sodium and chlorine. Sodium is ashiny, soft, silvery metal that reacts violently with water.Chlorine is a greenish-yellow, poisonous gas. These two elements combine to form the salt that people use in their food.

Make Flash Cards As youread, make a flash card of each element mentioned in the text.Include the name of the element, its chemical symbol,and its electron dot diagram.

Study Coach

●A Find Main Ideas Makea Foldable like the one below. As you read this section, writedown the main ideas aboutcombined elements, formulas,and atomic stability.

CombinedElements

Formulas

AtomicStability

chapter Chemical Bonds

section ● Stability in Bonding1

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Reading Essentials 313

FormulasThe formula for sodium chloride is NaCl. Na is the

chemical symbol for the element sodium. Cl is the chemicalsymbol for the element chlorine. Written together, they makeup the formula for sodium chloride. A chemical formula tellswhat elements are in a compound and how many atoms ofeach element are in one unit of the compound.

What is the formula for water?Let’s look at the formula for a compound you use every

day. H2O is the chemical formula for water. H is the symbolfor the element hydrogen. O is the symbol for the elementoxygen. The number 2 in the formula is called a subscript.Subscript means “written below.” A subscript written after asymbol tells how many atoms of that element are in one unitof the compound. In H2O, the 2 tells you there are two atomsof hydrogen in one unit of water. If there is no subscript aftera symbol in a formula, there is only one atom of that elementin the compound. So, in one unit of H2O there are two hydrogen atoms and one oxygen atom.

The table shows some familiar compounds and theirformulas. Notice that each kind of atom can be combinedwith other atoms in many different kinds of compounds. Forinstance, oxygen is a part of the compounds of sand, milk ofmagnesia, cane sugar, and vinegar.

Atomic StabilityRecall that protons have a positive charge and electrons

have a negative charge. These opposite electric forces attracteach other. They are the forces that hold atoms and moleculestogether. The kinds of electric forces that hold atoms togetheralso bring atoms together to form compounds.

1. Explain What does a chemical formula tell you?

2. Describe The formula forcane sugar, or sucrose, isC12H22O11. Describe whatone unit of cane sugar ismade of.

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314 CHAPTER 18 Chemical Bonds

Why do atoms form compounds? Look at the periodic table on the inside back cover of this

book. It lists all the known elements. Most of these elementscan combine with others to form compounds that are morestable. Notice the six elements in Group 18. These elementsare gases called the noble gases. Atoms of the noble gases arevery stable. They are different from the other elementsbecause they almost never combine to form compounds.Compounds that are formed with a noble gas are less stablethan the original noble gas atom.

Why are the noble gases stable?A helpful way to picture the stability of the noble gases is

to look at the electron dot diagrams of those elements. Anelectron dot diagram shows the symbol of the element. It alsoshows the electrons in the outer energy level of an atom. Thenumber of electrons in the outer energy level of an atomdetermines if that atom will combine to form a compound.

How do you know how many dots to put in an electron dotdiagram? For elements in Groups 1 and 2 and 13 through 18,you can use the periodic table. The above shows two rows of theperiodic table. Look at the outer energy level of the elements in Group 1. All elements in Group 1 have one outerelectron. The elements in Group 2 have two outer electrons.Group 13 elements have three outer electrons, Group 14 elementshave four, and so on. The noble gases in Group 18 have eightouter electrons.

What makes an atom stable?An atom is chemically stable when its outermost energy level

has all the electrons it can hold. If an atom is chemically stable,it does not easily form compounds with other atoms.

3. Interpret ScientificIllustrations How manyelectrons are in the outerenergy level of an atom of carbon?

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Li Be B C N O F Ne

Na Mg Al Si P S Cl Ar

2

3

21 13 14 15 16 17 18

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Reading Essentials 315

Stable Noble Gases The figure to the rightshows electron dot diagrams of the noble gases.The first electron dot diagram is for helium.Notice that there are two electrons around thesymbol for helium, He. Hydrogen and heliumneed only two electrons in their outer level tobe stable. The outer energy levels of all theother elements are stable when they containeight electrons.

Now look at the electron dot diagram forneon, Ne. There are eight electrons in neon’souter energy level. Neon is stable as an atom.Neon does not become more stable if it forms acompound. The noble gases are stable becausethey already have the maximum number ofelectrons in their outer energy levels.

What elements have incomplete outer energy levels?

Hydrogen and helium are the only elements in the first row,or period, of the periodic table. Both hydrogen and heliumneed only two outer electrons to be stable. Helium has twoelectrons in its outer energy level and is stable. But hydrogenhas only one electron. Its outer level is not full. Therefore,hydrogen is more stable when it is part of a compound.

Look at the periodic table again. You can see that none ofthe elements in Group 13 through Group 17 have full outerenergy levels. These elements are more stable when they form compounds.

How do atoms become more stable?As you have learned, hydrogen is an element that does not

have a full outer energy level. How does hydrogen, or anyother element become stable? Atoms that do not have a stableouter energy level can do one of three things to completetheir outer level. They can gain electrons, lose electrons, orshare electrons to make a full outer level. Atoms combine withother atoms that also do not have complete outer levels. Thisway, each atom becomes more stable.

The figure on the next page shows electron dot diagramsfor sodium and chlorine. Sodium has one outer electron andchlorine has seven. When these two elements combine,sodium gives its outer electron to chlorine. Chlorine now haseight electrons in its outer level. This is a full, stable energylevel. But what about sodium?

He

Kr

Xe

Rn

Ar

Ne

4. Describe How many electrons are in the outerenergy level of xenon?

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5. Infer What makes noblegases stable?

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316 CHAPTER 18 Chemical Bonds

How can sodium become more stable?Sodium gave up the only electron in its outer level when it

combined with chlorine to form sodium chloride. If sodiumloses the electron in the outer energy level, what is left? Thenext energy level of the sodium atom has eight electrons. Whenthe one outer electron is removed, the next level becomes thenew outer level. Sodium now has a complete, stable outerenergy level. Sodium and chlorine exchanged an electron andare now both stable in the compound they formed.

What is another way atoms can become stable?

Remember that the formula for the compound water is H2O.Hydrogen atoms need one electron in their outer level to be stable. Oxygen atoms need two electrons to be stable. In thiscase, neither atom can give up an electron. Instead, they shareelectrons. Each hydrogen atom shares one electron from an oxygen atom to complete its outer level. In turn, the oxygenatom shares each of the two hydrogen atoms’ electrons to com-plete its outer level. The compound water is more stable than ahydrogen atom or an oxygen atom.

Atoms gain and lose electrons to become more stable.Recall that electrons have a negative charge and protons havea positive charge. Positive charges attract negative charges likethe opposite ends of a magnet. The force that holds atomstogether is called a chemical bond.

Na Cl

ClSodium

Sodium Combines with Chlorine to form Sodium Chloride

Chlorine

Na

6. Use a Model Draw an electron dot diagram ofsodium showing its newouter energy level after ithas given its outer electronto chlorine.

Picture This

7. Explain What happens toan atom’s charges when itgains or loses an electron?

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Reading Essentials 317

1. Review the terms and their definitions in the Mini Glossary. Find one chemical formula you learned about in this section and explain the parts of the formula.

2. Complete the concept web to organize the information from this section.

3. As you read this section, you made flash cards for the elements mentioned inthe text. Do you think that making flash cards would be a good way to learn the symbolsof all the elements in the periodic table? Why or why not?

Study Coach

They can do this by:

become morestable by:

Atoms

chemical bond: the force that holds atoms together in

a compound

chemical formula: a formula that tells what elements and

how many atoms of each element are in a compound

After You ReadMini Glossary

End of

Section

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