3 Mass Balance Agro1

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    Mass and Energy Balances 1

    Supratomo

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    Mass and Energy Balances 2

    • The study of process engineering is an attempt to combine all forms of physical

    processing into a small number of basic operations, which are called unit

    operations

    • The essential concept is therefore to divide physical food processes into basicunit operations, each of which stands alone and depends on coherent physical

    principles

    • Because of the dependence of the unit operation on a physical principle, or a

    small group of associated principles, quantitative relationships in the form of 

    mathematical equations can be built to describe them. The equations can beused to follow what is happening in the process, and to control and modify the

    process if required.

    • Two very important laws which all unit operations obey are the laws of  

    conservation of mass and energy.

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    Mass and Energy Balances 3

    BASIC PRINSIPLES

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    Mass and Energy Balances 4

    CONSERVATION of MASS

    Mass can be neither created nor destryed. However , its

    composition can be altered from one form to another.

    Rate of mass

    entering

    through the

    boundary of asystem

    Rate of mass

    exiting through

    the boundary

    of a system

    Rate of mass

    accumulation

    within the

    system

    - =

    ∑=

    =n

    1i

    .

    inlet

    .

    imm   ∑=

    =n

    1i

    .

    outlet

    .

    ommdt

    mm

    system

    onaccumulati

    d =

    dt

    mmm

    system

    outletinlet

    d =−

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    Mass and Energy Balances 5

    CONSERVATION of MASS for an Open System

    Consider a section of pipe used in transporting a fluid.

    dAvdm o ρ =   ∫∫   ==v

    o dVdAvm   ρ  ρ  A

    ∫∫∫   =V

    oo dVdt

    d  dAv-dAv   ρ  ρ  ρ 

    outlet inlet    A A

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    Mass and Energy Balances 6

    ∫∑∑   = Vo

    outleto

    inletdVdt

     dAv-dAv   ρ  ρ  ρ 

    For a uniform flow :

    For a steady state flow flow does not change with time

    dAvdAv ooutlet

    o

    inlet∑∑   =   ρ  ρ 

    If we are dealing with and incompressible fluid there is no change in density.

    dAvdAvoutlet

    o

    inlet

    o   ∑∑   =

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    Mass and Energy Balances 7

    CONSERVATION of MASS for a Closed System

     A closed system mass cannot cross system bounderies. Therefore,

    there is no time rate of change of mass in the system.

    0

    dt

    msystem =d 

    msystem = constant

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    Discusion

    Mass and Energy Balances 8

    Which of the following statements are true and which are false?1. The mass balance is based on the law of conservation of mass.

    2. Mass balance may refer to total mass balance or component

    mass balance.

    3. Control volume is a region in space surrounded by a control

    surface through which the fluid flows.

    4. Only streams that cross the control surface take part in the mass

    balance.

    5. At steady state, mass is accumulated in the control volume.

    6. In a component mass balance, the component generation termhas the same sign as the output streams.

    7. It is helpful to write a mass balance on a component that goes

    through the process without any change.

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    Mass and Energy Balances 9

    Laws of Thermodynamics

    1st Law

    Energy can be neither created nor detroyed but can

    be transformed from one form to another 

    2nd Law by Rudolf Clausius and Lord Kelvin

    No process is possible where sole result is the

    removal of heat from a reservoir (system) at one

    temperature and the absorption of an equal quantity

    of heat by reservoir at a higher temperature.

    The 2nd law of thermodynamics help explain why heat

    always flow from a hot object to a cold object.

    CONSERVATION of ENERGY

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    Mass and Energy Balances 10

    Forms of Energy

    Potensial Energy of a system is by vitue of its location with respect to the

    gravitational field.

    mgh E PE  =Kinetic Energy of an object is due to its velocity.

    2

    2

    1

    mv E KE   =

    Internal Energy is due to the microscopic nature of the system . They move in

    random direction, collide each other, vibrate and rotate.

    T mc E   pi  ∆=

    Total Energy of a system can be written in the form of an equation as :

    Etotal = EKE + EPE + Eelectrical + Echemical + …….. + Ei

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    Mass and Energy Balances 11

    ENERGY BALANCE

    The first law of thermodynamics states that energy can be

    neither created nor destryed.

    Total energy

    entering the

    system

    Total energy

    leaving the

    system

    Change in the

    total energy at

    the system- =

    systemoutin Ê ÊÊ ∆=−For a system is in a steady state, there is no change in the energy of the

    system with time.

    0ˆˆˆ =∆=− systemout in   E  E  E 

    out in   E  E ˆˆ =

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    Mass and Energy Balances 12

    Energy Balance for an Open System

    Movement of a liquid volume

    Force to push a liquid through the system boundary is : F = P.A

     A : cross-sectional area

    P : pressure of the fluid

    The work done on the fluid element is : Wmass flow = F.L = P.A.L = PV

    The total energy of the fluid element :

    ET = EPE + EKE + Ei + PV   PV  E mv

    mgz E  iT    +++=2

    2

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    Mass and Energy Balances 13

    The overall energy balance equation for a system with one inlet (point 1)

    and one outlet (point 2) is:

    The overall energy balance equation for a system at steady state with more

    than two streams can be written as:

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    Mass and Energy Balances 14

    Where :

    In most of the cases, the overall energy balance ends up as an enthalpy balancebecause the terms of kinetic and potential energy are negligible compared to the

    enthalpy term, the system is assumed adiabatic (Q = 0), and there is no shaft work

    (Ws = 0). Then:

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    Discusion

    Mass and Energy Balances 15

    Which of the following statements are true and which are false?1. The energy in a system can be categorize as internal energy,

    potentialenergy, and kinetic energy.

    2. A fluid stream carries internal energy, potential energy, and

    kinetic energy.

    3. A fluid stream entering or exiting a control volume is doing PV

    work.

    4. The internal energy and the PV work of a stream of fluid make

    up the enthalpy of the stream.

    5. Heat and shaft work may be transferred through the control

    surface to or from the control volume.

    6. Heat transferred from the control volume to the surroundings isconsidered positive by convention.

    7. For an adiabatic process, the heat transferred to the system is

    zero.

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    Mass and Energy Balances 16

    Steps in problem solving a Material Balance

    1. Collect all known data on mass and composition of all inlet and exit streamsfrom the statement of the problem.

    2. Draw a block diagram, indicating the process, with inlet and exit streams

    properly identified. Draw the system boundary.

    3. Write all available data on the block diagram

    4. Select a suitable basis (such as mass or time) for calculations. The selection

    of basis depends on the convenience of the computations.

    5. Using equation of mass balance, write material balance in term of the

    selected basis for calculating unknowns. For each unknown, an independent

    material balance is required.

    6. Solve material balances to determine the unkowns.

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    17

    Example 1.

     A wet food product contains 70 % water. After drying, it is found that 80 % of

    original water has been removed. Determine (a) mass of water removed per

    kilogram of wet food, and (b) composition of dried food.

    Given :

    Initial water content : F = 70 %

    Water removed : R = 80 % of original water content

    Feed (F)intial water

    content 70 %

    R : water removed 80 % oforiginal water content

    Product (P)composition ?

    Solution :

    1. Select basis 1 kg wet food

    2. Mass of water in inlet stream : Fwater = 70 % x 1 kg = 0.70 kg

    3. Water removed in drying : R = 80 % x Fwater = 0.8 x 0.7 = 0.56 kg H2O / kg ofwet food material

    4. Write material balance on water : Fwater – Pwater = R (a) Pwater = 0.14 kg

    5. Write material balance on solid : Fsolid = Psolid Psolid = 0.3 kg

    6. (b) the dried food contains 0.14 kg water and 0.3 kg solids

    dryer 

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    18

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    Mass and Energy Balances 19

    Example 2.

    Potato flakes (moisture content (mc) 75 % wet basis) are being dried in a

    concurrent flow drier. The mc of the air entering the drier is 0.08 kg H2O/kg dry air.

    The mc leaving the drier is 0.18 kg H2O/kg dry air. The air flow rate in the drier is

    100 kg dry air per hour. At steady state, calculate the following :

    a. What is the mass flow rate of dried potatoes ?

    b. What is the mc, dry basis, of dried potatoes exiting the drier ?

    Inlet air 0.08 kg H2O/kg dry air 100 kg/h dry air 

    Feed50 kg wet potato flakes/h

    MC 75 % wet basis

    Exit air 0.18 kg H2O/kg dry air 

    Productmoisture content ?

    dryer 

    Given :

    Weight of potato flakes entetring the dryer F = 50 kg with 75 % of MC wb

    Moisture content of air entering the dryer is 0.08 kg H2O/kg dry air and the flow

    rate is 100 kg dry air/h

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    Mass and Energy Balances 20

    Solution :

    1. Basis = 1 hour 

    2. Mass of air entering the dryer = mass of dry air + mass of water 

    I = 100 + 0.08 x 100 = 108 kg

    3. Mass of air leaving the dryer = mass of dry air + mass of water 

    E = 100 + 0.18 x 100 = 118 kg

    4. Total balance on the dryer 

    I + F = E + P 108 + 50 = 118 + P (a) P = 40 kg/h

    5. Solid balance on the dryer Mass of dry solids entering the dryer = mass of dry solid leaving the dryer 

    (1 – 0.75) F = y P

    6. Therefore, moisture content (wet basis) of the product : 1 – 0.3125 =0.6875 kg

    7. The dry basis MC of the Product

    kg3125.040

    5025.0==

      x y

    solidsdryO/kgHkg2.23125.0

    6875.0

    solidsdryof mass

     water of mass2 _    ===basisdry MC 

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    21

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    Mass and Energy Balances 22

    Example 3.

     A tubular water blancher is being used to process lima beans. The product

    mass flow is 860 kg/h. it is found that the theoretical energy consumed

    for blanching process amounts to 1.19 GJ/h. the energy lost due to lack

    of insulation around the blancher is estimate to be 0.24 GJ/h. if the totalenergy input to blancher is 2.71 GJ/h,

    a. Calculate the energy required to reheat water 

    b. Determine the percent energy associated with each stream

    Water

    blancher 

    Energy losses from

    surface = 0.24 GJ/h

    Energy input =

    2.71 GJ/h

    Energy leaving the

    product = 1.19 GJ/h

    Energy leaving with water ?

    Given

    Product mass flow rate = 860 kg/h

    Theoritical energy consumed for blanching process = 1.19 GJ/h

    Energy loss due to lack of insulation = 0.24 GJ/h

    Energy input to blancher = 2.71 GJ/h

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    Mass and Energy Balances 23

    Solution

    Select 1 hour as a basis

    Write energy balance

    E input to blancher = E out with product + E out with water + E losses fromsurfaces

    2.71 = 1.19 + Eo_water + 0.24 Eo_water = 1.28 GJ/h

    a. E required to reheat water = E input – E o_water = 2.71 – 1.19 = 1.43 GJ/h

    b. Percent energy associate with :

    - Product (out) = 1.19/2.71 x 100 % = 43.91 %

    - Water (out) = 1.28/2.71 x 100 % = 47.23 %

    - Losses = 0.24/2.71 x 100 % = 8.86 %

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    Mass and Energy Balances 24

    Example 4.

    Steam is used for peeling of potatoes in a semicontinuous operation. Steam is

    supplied at the rate of 4 kg per 100 kg of unpeeled potatoes. The unpeeled

    potatoes enter the system with a temperature of 17 oC, and peeled pototoes

    leave at 35o

    C. A specific heat of unpeeled potatoes, waste stream, and peeledpotatoes are 3.7, 4.2 and 3.5 kJ/(kg.K), respectively. If the heat content

    (assuming 0 oC reference temperature) of the steam is 2750 kJ/kg, determine

    the quantities of the waste stream and peeled potatoes from the process.

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    Mass and Energy Balances 25

    Given : up unpeeled potatoes pp peeled potatoes waste steam wt

    Mass flow of steam = 4 kg per 100 kgup

    Tup = 17o

    C Tpp = 35o

    C Twt = 60o

    CCpup = 3.7 kJ/kg-K Cppp = 3.5 kJ/kg-K Cpwt = 4.2 kJ/kg-K

    Heat content of steam (H) = 2750 kJ/kg

     Assuming 0 oC as temperature’s reference

    Potato peeler 

    F = 100 kg

    Tf = 17oC

    W = ?

    Tw = 60oC

    Hs = 2750 kJ/kgS= 4 kg

    P = ?

    Tp = 35oC

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    Mass and Energy Balances 26

    Solution

    Select 100 kg of up as a basis

    From mass balance

    F + S = W + P

    100 + 4 = W + PW = 104 – P (I)

    From energy balance

    Einput_up + Einput_s = Eout_ws + Eout_pp

    F Cpup  ΔT + SH = W Cpwt  ΔT + P Cppp  ΔT

    100 x 3700 x (17-0) + 4 x 2750 = W x 4200 x (60-0) + P x 3500 x (35-0)

    6290 + 11000 = 252 W + 122.5 P

    (I) 17290 = 252 (104 – P) + 122.5 P P = 68.87 kg

    W = 35.14 kg

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    Mass and Energy Balances 27

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    Mass and Energy Balances 28

    1. 10 kg of food at a moisture content of 320% dry basis is dried to 50% wet

    basis. Calculate the amount of water removed.

    2. A batch of 5 kg of food product has a moisture content of 150% dry basis.Calculate how much water must be removed from this product to reduce its

    moisture content to 20% wet basis.

    3. A liquid product with 10% product solids is blended with sugar before being

    concentrated (removal of water) to obtain a final product with 15% product

    solids and 15% sugar solids. Determine the quantity of final product obtained

    from 200 kg of liquid product. How much sugar is required? Compute mass of

    water removed during concentration.

    4. 1000 kg/h of milk is heated in a heat exchanger from 45 oC to 72 oC. Water is

    used as the heating medium. It enters the heat exchanger at 90 oC and leaves

    at 75 oC. Calculate the mass flow rate of the heating medium, if the heat losses

    to the environment are equal to 1 kW. The heat capacity of water is given equalto 4.2 kJ/kgoC and that of milk 3.9 kJ/kgoC.

    5. How much saturated steam with 120.8 kPa pressure is required to heat 1000

    g/h of juice from 5 oC to 95 oC? Assume that the heat capacity of the juice is 4

    kJ/ kgoC.

    Exercises