290 South Wagner Road Organic Analysis ANN ARBOR … · 14'-15' TM ANN ARBOR TECHNICAL SERVICES, INC. 290 South Wagner Road Ann Arbor, Michigan 48103 Tel. 734/995-0995 Fax. 734/995-3731

Organic AnalysisData Summary Sheet

For: Mr. Steve Lucas ATS Project: Reach D PCAP #D052-TRPDow Chemical Report Date: 3/25/20071078 Building ATS SRF: 0315071Midland, MI 48667

Sample Identification:Sample Depth:

Sample Date: 3/12/07 Percent Total Solids: 79.1Laboratory Receipt Date: 3/15/07Sample Matrix: Sediment

Parameter (CAS #) Method Units ResultReporting

LimitBenzene (71-43-2) 8260B mg/kg <0.05 0.05Chlorobenzene (108-90-7) 8260B mg/kg <0.05 0.05Hexachlorobutadiene (87-68-3) 8270C mg/kg <0.33 0.33Hexachlorobenzene (118-74-1) 8270C mg/kg <0.33 0.33Tetrachloroethene (127-18-4) 8260B mg/kg <0.05 0.051,2-Dichlorobenzene (95-50-1) 8270C mg/kg <0.33 0.331,3-Dichlorobenzene (541-73-1) 8270C mg/kg <0.33 0.331,4-Dichlorobenzene (106-46-7) 8270C mg/kg <0.33 0.331,2,4-Trichlorobenzene (120-82-1) 8270C mg/kg <0.33 0.331,2,4,5-Tetrachlorobenzene (95-94-3) 8270C mg/kg <0.33 0.33

CommentsResults expressed on a dry weight basis.8260B analysis performed by TriMatrix Labs.

B-15.2'-6.0'

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ANN ARBOR TECHNICAL SERVICES, INC.

290 South Wagner RoadAnn Arbor, Michigan 48103Tel. 734/995-0995 Fax. 734/995-3731Michigan Laboratory ID: 9604Wisconsin Laboratory ID: 998321720

\\D052-TRP.07\Reach D\Reach D VOC SVOC Report March 07.xls rev. 3/25/07






LimitBenzene (71-43-2) 8260B mg/kg <0.05 0.05Chlorobenzene (108-90-7) 8260B mg/kg <0.05 0.05Hexachlorobutadiene (87-68-3) 8270C mg/kg <0.33 0.33Hexachlorobenzene (118-74-1) 8270C mg/kg 0.80 0.33Tetrachloroethene (127-18-4) 8260B mg/kg <0.05 0.051,2-Dichlorobenzene (95-50-1) 8270C mg/kg <0.33 0.331,3-Dichlorobenzene (541-73-1) 8270C mg/kg <0.33 0.331,4-Dichlorobenzene (106-46-7) 8270C mg/kg <0.33 0.331,2,4-Trichlorobenzene (120-82-1) 8270C mg/kg <0.33 0.331,2,4,5-Tetrachlorobenzene (95-94-3) 8270C mg/kg <0.33 0.33


B-113'-14'

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B-118'-19'

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B-24'-5'

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B-210.7'-11.7'

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B-214'-15'

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CommentsResults expressed on a dry weight basis.8260B analysis performed by TriMatrix Labs.Elevated reporting limit due to matrix interference for 8270C analysis.

B-36.5'-7.5'

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Sample Date: 3/12/07 Percent Total Solids: -Laboratory Receipt Date: 3/15/07Sample Matrix: Sediment


LimitBenzene (71-43-2) 8260B mg/kg <0.05 0.05Chlorobenzene (108-90-7) 8260B mg/kg <0.05 0.05Hexachlorobutadiene (87-68-3) 8270C mg/kg - 0.33Hexachlorobenzene (118-74-1) 8270C mg/kg - 0.33Tetrachloroethene (127-18-4) 8260B mg/kg <0.05 0.051,2-Dichlorobenzene (95-50-1) 8270C mg/kg - 0.331,3-Dichlorobenzene (541-73-1) 8270C mg/kg - 0.331,4-Dichlorobenzene (106-46-7) 8270C mg/kg - 0.331,2,4-Trichlorobenzene (120-82-1) 8270C mg/kg - 0.331,2,4,5-Tetrachlorobenzene (95-94-3) 8270C mg/kg - 0.33

CommentsResults expressed on a wet weight basis.8260B analysis performed by TriMatrix Labs."-" indicates sample not received for analysis.

B-314'-15'

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B-318'-19'

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LimitBenzene (71-43-2) 8260B mg/kg 8.4 0.5Chlorobenzene (108-90-7) 8260B mg/kg 4.7 0.5Hexachlorobutadiene (87-68-3) 8270C mg/kg 65 3.3Hexachlorobenzene (118-74-1) 8270C mg/kg <3.3 3.3Tetrachloroethene (127-18-4) 8260B mg/kg 4.0 0.51,2-Dichlorobenzene (95-50-1) 8270C mg/kg 89 3.31,3-Dichlorobenzene (541-73-1) 8270C mg/kg <3.3 3.31,4-Dichlorobenzene (106-46-7) 8270C mg/kg 110 3.31,2,4-Trichlorobenzene (120-82-1) 8270C mg/kg 18 3.31,2,4,5-Tetrachlorobenzene (95-94-3) 8270C mg/kg 5.0 3.3


B-48'-9'

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LimitBenzene (71-43-2) 8260B mg/kg 4.9 0.05Chlorobenzene (108-90-7) 8260B mg/kg <0.05 0.05Hexachlorobutadiene (87-68-3) 8270C mg/kg <0.33 0.33Hexachlorobenzene (118-74-1) 8270C mg/kg <0.33 0.33Tetrachloroethene (127-18-4) 8260B mg/kg <0.05 0.051,2-Dichlorobenzene (95-50-1) 8270C mg/kg <0.33 0.331,3-Dichlorobenzene (541-73-1) 8270C mg/kg <0.33 0.331,4-Dichlorobenzene (106-46-7) 8270C mg/kg <0.33 0.331,2,4-Trichlorobenzene (120-82-1) 8270C mg/kg <0.33 0.331,2,4,5-Tetrachlorobenzene (95-94-3) 8270C mg/kg <0.33 0.33


B-412'-13'

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LimitBenzene (71-43-2) 8260B mg/kg 27 1Chlorobenzene (108-90-7) 8260B mg/kg 160 1Hexachlorobutadiene (87-68-3) 8270C mg/kg 18 3.3Hexachlorobenzene (118-74-1) 8270C mg/kg <3.3 3.3Tetrachloroethene (127-18-4) 8260B mg/kg 10 11,2-Dichlorobenzene (95-50-1) 8270C mg/kg 160 3.31,3-Dichlorobenzene (541-73-1) 8270C mg/kg <3.3 3.31,4-Dichlorobenzene (106-46-7) 8270C mg/kg 150 3.31,2,4-Trichlorobenzene (120-82-1) 8270C mg/kg 7.1 3.31,2,4,5-Tetrachlorobenzene (95-94-3) 8270C mg/kg <3.3 3.3


B-59'-10'

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LimitBenzene (71-43-2) 8260B mg/kg 3.2 0.05Chlorobenzene (108-90-7) 8260B mg/kg 2.0 0.05Hexachlorobutadiene (87-68-3) 8270C mg/kg <0.33 0.33Hexachlorobenzene (118-74-1) 8270C mg/kg <0.33 0.33Tetrachloroethene (127-18-4) 8260B mg/kg <0.05 0.051,2-Dichlorobenzene (95-50-1) 8270C mg/kg 0.81 0.331,3-Dichlorobenzene (541-73-1) 8270C mg/kg <0.33 0.331,4-Dichlorobenzene (106-46-7) 8270C mg/kg 1.3 0.331,2,4-Trichlorobenzene (120-82-1) 8270C mg/kg <0.33 0.331,2,4,5-Tetrachlorobenzene (95-94-3) 8270C mg/kg <0.33 0.33


B-514'-15'

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LimitBenzene (71-43-2) 8260B mg/kg 79 5Chlorobenzene (108-90-7) 8260B mg/kg 950 5Hexachlorobutadiene (87-68-3) 8270C mg/kg 120 3.3Hexachlorobenzene (118-74-1) 8270C mg/kg 5.0 3.3Tetrachloroethene (127-18-4) 8260B mg/kg 75 51,2-Dichlorobenzene (95-50-1) 8270C mg/kg 390 3.31,3-Dichlorobenzene (541-73-1) 8270C mg/kg <3.3 3.31,4-Dichlorobenzene (106-46-7) 8270C mg/kg 310 3.31,2,4-Trichlorobenzene (120-82-1) 8270C mg/kg 11 3.31,2,4,5-Tetrachlorobenzene (95-94-3) 8270C mg/kg <3.3 3.3


B-68'-9'

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B-614'-15'

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LimitBenzene (71-43-2) 8260B mg/kg 0.2 0.1Chlorobenzene (108-90-7) 8260B mg/kg 12 0.1Hexachlorobutadiene (87-68-3) 8270C mg/kg 22 3.3Hexachlorobenzene (118-74-1) 8270C mg/kg <3.3 3.3Tetrachloroethene (127-18-4) 8260B mg/kg 0.6 0.11,2-Dichlorobenzene (95-50-1) 8270C mg/kg 22 3.31,3-Dichlorobenzene (541-73-1) 8270C mg/kg <3.3 3.31,4-Dichlorobenzene (106-46-7) 8270C mg/kg 18 3.31,2,4-Trichlorobenzene (120-82-1) 8270C mg/kg <3.3 3.31,2,4,5-Tetrachlorobenzene (95-94-3) 8270C mg/kg <3.3 3.3


B-79'-10'

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B-714'-15'

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LimitBenzene (71-43-2) 8260B mg/kg 0.10 0.05Chlorobenzene (108-90-7) 8260B mg/kg 8.4 0.05Hexachlorobutadiene (87-68-3) 8270C mg/kg 6.7 3.3Hexachlorobenzene (118-74-1) 8270C mg/kg <3.3 3.3Tetrachloroethene (127-18-4) 8260B mg/kg 0.77 0.051,2-Dichlorobenzene (95-50-1) 8270C mg/kg 18 3.31,3-Dichlorobenzene (541-73-1) 8270C mg/kg <3.3 3.31,4-Dichlorobenzene (106-46-7) 8270C mg/kg 14 3.31,2,4-Trichlorobenzene (120-82-1) 8270C mg/kg <3.3 3.31,2,4,5-Tetrachlorobenzene (95-94-3) 8270C mg/kg <3.3 3.3

CommentsResults expressed on a dry weight basis.8260B analysis performed by TriMatrix Labs.na - indicates not applicable.

Duplicatena

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Field Blankna

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Field Blankna

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Quality AssuranceData Summary

QC Batch Number: 702785 ATS Project: Reach D PCAP #D052-TRP

Parameter: Volatiles (USEPA 8260B) Report Date:

Results of QA Samples run concurrently with project samples

Spike and/or QC Check Samples

Sample

#D052-TRPLaboratory Control Sample 3/19/07

Benzene <0.05 mg/kg 2.0 mg/kg 2.1 mg/kg 104.5Chlorobenzene <0.05 mg/kg 2.0 mg/kg 2.2 mg/kg 108.01,1-Dichloroethene <0.05 mg/kg 2.0 mg/kg 2.0 mg/kg 101.0Toluene <0.05 mg/kg 2.0 mg/kg 2.1 mg/kg 103.5Trichloroethene <0.05 mg/kg 2.0 mg/kg 1.8 mg/kg 89.5

#D052-TRPLaboratory Control Sample 3/20/07


Comments: Control Limits:Results expressed on a dry weight basis. Benzene (70 - 130)(1) Calculations were performed prior to rounding. Chlorobenzene (70 - 130)(2) na = not applicable, inappropriate spike levels. 1,1-Dichloroethene (70 - 130)(3) nc = not calculated. Toluene (70 - 130)(*) asterisk = outside standard control limits. Trichloroethene (70 - 130)(**) double asterisk = outside optimal spike levels.

Known Concentration

Spiked Concentration

Analyzed Concentration

Percent Recovery

3/25/07

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Sample

#D052-TRPB-1 5.2'-6.0' 3/12/07 Matrix Spike


#D052-TRPB-1 5.2'-6.0' 3/12/07 Matrix Spike Duplicate


Comments: Control Limits:Results expressed on a dry weight basis. Benzene (70 - 130)(1) Calculations were performed prior to rounding. Chlorobenzene (70 - 130)(2) na = not applicable, inappropriate spike levels. 1,1-Dichloroethene (70 - 130)(3) nc = not calculated. Toluene (70 - 130)(*) asterisk = outside standard control limits. Trichloroethene (70 - 130)(**) double asterisk = outside optimal spike levels.

Known Concentration



Percent Recovery

3/25/07

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Replicate Analysis

Sample

#D052-TRPB-1 5.2'-6.0' 3/12/07 Matrix Spike Benzene 2.7 mg/kg 2.6 mg/kg 2.7 mg/kg 1.1

Chlorobenzene 2.7 mg/kg 2.7 mg/kg 2.7 mg/kg 2.51,1-Dichloroethene 2.8 mg/kg 2.8 mg/kg 2.8 mg/kg 1.1Toluene 2.6 mg/kg 2.6 mg/kg 2.6 mg/kg 0.4Trichloroethene 2.4 mg/kg 2.3 mg/kg 2.3 mg/kg 0.4

Comments: Control Limits:Results expressed on a dry weight basis. Relative Range < or = 35%.(1) Calculations were performed prior to rounding.(3) nc = not calculated.(*) asterisk = outside standard control limits.

Replicate 1 Replicate 2 MeanRelative Range

(percent)

3/25/07

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Blank Analysis

Sample Analyzed Concentration QC Decision

#D052-TRPMethod Blank 3/19/07 Less than detectable for all analytes Acceptable Method Blank 3/20/07 Less than detectable for all analytes Acceptable

Comments:

3/25/07

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Surrogate Recovery

Sample

#D052-TRPMethod Blank 3/19/07 Method Blank 3/20/07 Laboratory Control Sample 3/19/07 Laboratory Control Sample 3/20/07 B-1 5.2'-6.0' 3/12/07 Spike B-1 5.2'-6.0' 3/12/07 Spike Duplicate B-1 5.2'-6.0' 3/12/07 B-1 13'-14' 3/12/07 B-1 18'-19' 3/12/07 B-2 4'-5' 3/12/07 *B-2 10.7'-11.7' 3/12/07 *B-2 14'-15' 3/12/07 *B-3 6.5'-7.5' 3/12/07 *B-3 14'-15' 3/12/07 *B-3 18'-19' 3/12/07 *B-4 8'-9' 3/13/07 B-4 12'-13' 3/13/07 *B-5 9'-10' 3/13/07 B-5 14'-15' 3/13/07 B-6 8'-9' 3/13/07 B-6 14'-15' 3/13/07 *B-7 9'-10' 3/13/07 B-7 14'-15' 3/13/07 *Duplicate 3/13/07 Field Blank 3/12/07 Field Blank 3/13/07 *

Comments: Control Limits:(1) Calculations were performed prior to rounding. (86 - 118)

(3) nc = not calculated. TOL = Toluene-d8 (88 - 110)(*) asterisk = outside standard control limits. BFB = Bromofluorobenzene (86 - 115)

TOL BFB DBFM

99 90 101100 89 9999 96 101

101 94 10298 96 9798 97 9699 89 88

100 89 8899 90 8899 91 85

100 92 8499 89 8599 91 8499 91 8499 89 8498 93 9296 88 8199 92 9499 93 8498 90 9699 92 80

8899 90 82

85

99 91 8798 89 88

3/25/07

DBFM = Dibromofluoromethane

98 98

100 92

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QC Batch Number: QC0RG0316071-D ATS Project: Reach D PCAP #D052-TRP

Parameter: Semivolatiles (USEPA 8270C) Report Date:



Sample

#D052-TRPLaboratory Fortified Blank 3/16/07

Hexachlorobutadiene <0.33 mg/kg 4.0 mg/kg 3.4 mg/kg 84.0Hexachlorobenzene <0.33 mg/kg 4.0 mg/kg 3.8 mg/kg 94.31,2-Dichlorobenzene <0.33 mg/kg 4.0 mg/kg 3.4 mg/kg 84.81,3-Dichlorobenzene <0.33 mg/kg 4.0 mg/kg 3.6 mg/kg 90.81,4-Dichlorobenzene <0.33 mg/kg 4.0 mg/kg 3.5 mg/kg 87.01,2,4-Trichlorobenzene <0.33 mg/kg 4.0 mg/kg 3.6 mg/kg 89.81,2,4,5-Tetrachlorobenzene <0.33 mg/kg 4.0 mg/kg 6.8 mg/kg 171.0 *

Comments: Control Limits:Results expressed on a dry weight basis. Hexachlorobutadiene (50 - 130)(1) Calculations were performed prior to rounding. Hexachlorobenzene (50 - 130)(2) na = not applicable, inappropriate spike levels. 1,2-Dichlorobenzene (50 - 130)(3) nc = not calculated. 1,3-Dichlorobenzene (50 - 130)(*) asterisk = outside standard control limits. 1,4-Dichlorobenzene (50 - 130)(**) double asterisk = outside optimal spike levels. 1,2,4-Trichlorobenzene (50 - 130)

1,2,4,5-Tetrachlorobenzene (50 - 130)

Known Concentration



Percent Recovery

3/25/07

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Sample

#D052-TRPB-2 14'-15' 3/12/07 Matrix Spike

Hexachlorobutadiene <0.33 mg/kg 4.2 mg/kg 3.6 mg/kg 84.6Hexachlorobenzene <0.33 mg/kg 4.2 mg/kg 2.8 mg/kg 65.91,2-Dichlorobenzene <0.33 mg/kg 4.2 mg/kg 3.1 mg/kg 73.91,3-Dichlorobenzene <0.33 mg/kg 4.2 mg/kg 3.2 mg/kg 76.11,4-Dichlorobenzene <0.33 mg/kg 4.2 mg/kg 3.1 mg/kg 73.21,2,4-Trichlorobenzene <0.33 mg/kg 4.2 mg/kg 3.7 mg/kg 86.71,2,4,5-Tetrachlorobenzene <0.33 mg/kg 4.2 mg/kg 3.8 mg/kg 90.0

#D052-TRPB-2 14'-15' 3/12/07 Matrix Spike Duplicate

Hexachlorobutadiene <0.33 mg/kg 4.2 mg/kg 4.1 mg/kg 95.8Hexachlorobenzene <0.33 mg/kg 4.2 mg/kg 4.2 mg/kg 99.81,2-Dichlorobenzene <0.33 mg/kg 4.2 mg/kg 3.3 mg/kg 77.41,3-Dichlorobenzene <0.33 mg/kg 4.2 mg/kg 3.3 mg/kg 76.71,4-Dichlorobenzene <0.33 mg/kg 4.2 mg/kg 3.3 mg/kg 77.11,2,4-Trichlorobenzene <0.33 mg/kg 4.2 mg/kg 3.8 mg/kg 90.61,2,4,5-Tetrachlorobenzene <0.33 mg/kg 4.2 mg/kg 3.0 mg/kg 69.8

Comments: Control Limits:Results expressed on a dry weight basis. Hexachlorobutadiene (50 - 130)(1) Calculations were performed prior to rounding. Hexachlorobenzene (50 - 130)(2) na = not applicable, inappropriate spike levels. 1,2-Dichlorobenzene (50 - 130)(3) nc = not calculated. 1,3-Dichlorobenzene (50 - 130)(*) asterisk = outside standard control limits. 1,4-Dichlorobenzene (50 - 130)(**) double asterisk = outside optimal spike levels. 1,2,4-Trichlorobenzene (50 - 130)

1,2,4,5-Tetrachlorobenzene (50 - 130)

3/25/07

Known Concentration



Percent Recovery

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Replicate Analysis

Sample

#D052-TRPB-2 14'-15' 3/12/07 Matrix Spike Hexachlorobutadiene 3.6 mg/kg 4.1 mg/kg 3.8 mg/kg 12.6

Hexachlorobenzene 2.8 mg/kg 4.2 mg/kg 3.5 mg/kg 41.0 *1,2-Dichlorobenzene 3.1 mg/kg 3.3 mg/kg 3.2 mg/kg 4.71,3-Dichlorobenzene 3.2 mg/kg 3.3 mg/kg 3.2 mg/kg 0.91,4-Dichlorobenzene 3.1 mg/kg 3.3 mg/kg 3.2 mg/kg 5.31,2,4-Trichlorobenzene 3.7 mg/kg 3.8 mg/kg 3.8 mg/kg 4.51,2,4,5-Tetrachlorobenzene 3.8 mg/kg 3.0 mg/kg 3.4 mg/kg 25.1

Comments: Control Limits:Results expressed on a dry weight basis. Relative Range < or = 35%.(1) Calculations were performed prior to rounding.(3) nc = not calculated.(*) asterisk = outside standard control limits.

Replicate 1 Replicate 2 MeanRelative Range

(percent)

3/25/07

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Blank Analysis

Sample Analyzed Concentration QC Decision

#D052-TRPLaboratory Reagent Blank 3/16/07 Less than detectable for all analytes Acceptable

Comments:

3/25/07

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Surrogate Recovery

Sample

Laboratory Reagent Blank 3/16/07 Laboratory Fortified Blank 3/16/07 B-2 14'-15' 3/12/07 Matrix Spike B-2 14'-15' 3/12/07 Matrix Spike Duplicate B-1 5.2'-6.0' 3/12/07 B-1 13'-14' 3/12/07 B-1 18'-19' 3/12/07 B-2 4'-5' 3/12/07 B-2 10.7'-11.7' 3/12/07 B-2 14'-15' 3/12/07 B-3 6.5'-7.5' 3/12/07 B-3 18'-19' 3/12/07 B-4 8'-9' 3/13/07 B-4 12'-13' 3/13/07 B-5 9'-10' 3/13/07 B-5 14'-15' 3/13/07 B-6 8'-9' 3/13/07 B-6 14'-15' 3/13/07 B-7 9'-10' 3/13/07 B-7 14'-15' 3/13/07 Duplicate 3/13/07 Field Blank 3/12/07 Field Blank 3/13/07

Comments: Control Limits:(1) Calculations were performed prior to rounding. (50-150)(3) nc = not calculated. FBP = 2-Fluorobiphenyl (50-150)(*) asterisk = outside standard control limits.

87.8 91.8 91.8 101.4

74.5 94.4 77.3 86.7

59.7 78.9 67.4 79.5

78.2 89.4 88.1 85.5

75.2 82.6 84.2 81.8

74.9 87.8 98.7 102.3

72.2 82.9 86.7 86.1

72.6 81.2 74.2 84.6

71.2 85.7 81.6 89.8

79.0 90.9 70.0 82.5

83.6 94.2 79.6 86.5

NBZ FBP

86.5 99.2

3/25/07

NBZ = D5-Nitrobenze

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Documents

290 South Wagner Road Organic Analysis ANN ARBOR … · 14'-15' TM ANN ARBOR TECHNICAL SERVICES, INC. 290 South Wagner Road Ann Arbor, Michigan 48103 Tel. 734/995-0995 Fax. 734/995-3731