2011 P2

8/2/2019 2011 P2

http://slidepdf.com/reader/full/2011-p2 1/14

MAHESH JANMANCHI IIT JEE 2011 PAPER 2

visit us at http://www.chemistrycrest.com/ Page 1

8/2/2019 2011 P2




PAPER-2

Maximum Marks: 80

Question paper format and Marking scheme:

1. In Section I (Total Marks: 24), for each question you will be awarded 3 marks if you darken ONLY the

bubble corresponding to the correct answer and zero marks if no bubble is darkened. In all other cases,

minus one (–1) mark will be awarded.

2. In Section II (Total Marks: 16), for each question you will be awarded 4 marks if you darken ALL the

bubble(s) corresponding to the correct answer(s) ONLY and zero marks other wise. There are no negative

marks in this section.

3. In Section III (Total Marks: 24), for each question you will be awarded 4 marks if you darken ONLY the

bubble corresponding to the correct answer and zero marks otherwise There are no negative marks in this

section.

4. In Section IV (Total Marks: 16), for each question you will be awarded 2 marks for each row in which

you have darken ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marksotherwise. Thus each question in this section carries a maximum of 8 Marks. There are no negative marksin this section.

8/2/2019 2011 P2




SECTION – I (Total Marks : 24)

(Single Correct Answer Type)This Section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of

which ONLY ONE is correct.

1. The freezing point (inoC) of a solution containing 0.1 g of K3[Fe(CN)6 ](Mol. Wt. 329) in 100 g of

water (Kf = 1.86 K kg mol−−−−1

) is

(A) 22.3 10−− × (B) 25.7 10−− ×

(C) 35.7 10−− × (D) 21.2 10−− ×

Sol. (A)

( ) ( )3

36 63

K Fe CN K Fe CN −+ → +

i = 4∆Tf = i × Kf × m

1000 0.1 1000 21.86 4 2.3 10329 100

f

wT i k f M W

−∆ = × × × = × × × = ×

22.3 10 f T −= − × o

C

2. Amongst the compounds given, the one that would form a brilliant colored dye on treatment with

NaNO2 in dil. HCl followed by addition to an alkaline solution of ββββ-napthol is

(A) (B) (C) (D)

Sol. (C)

8/2/2019 2011 P2




3. The major product of the following reaction is

(A) a hemiacetal (B) an acetal

(C) an ether (D) an ester

Sol. (B)

4. The following carbohydrate is

(A) a ketohexose (B) an aldohexose

(C) an α-furanose (D) an α-pyranose

Sol. (B)

It is an aldohexose.It is in β-pyranose form.

5. Oxidation states of the metal in the minerals haematite and magnetite, respectively, are

(A) II, III in haematite and III in magnetite (B) II, III in haematite and II in magnetite(C) II in haematite and II, III in magnetite (D) III in haematite and II, III in magnetite

Sol. (D)Haematite : Fe2O3 :

2x + 3 × (-2) = 0 x =3

Magnetite : Fe3O4 [an equimolar mixture of FeO and Fe2O3]

FeO : x – 2 = 0 x = 2

Fe2O3 : 2x + 3 × (-2) = 0 x = 3

8/2/2019 2011 P2




6. Among the following complexes (K−−−−P)

K3[Fe(CN)6] (K), [Co(NH3)6]Cl3 (L), Na3[Co(oxalate)3] (M), [Ni(H2O)6]Cl2 (N), K2[Pt(CN)4] (O)

and [Zn(H2O)

6](NO

3)2

(P), the diamagnetic complexes are(A) K, L, M, N (B) K, M, O, P

(C) L, M, O, P (D) L, M, N, O

Sol. (C) K : K3[Fe(CN)6]. :

Fe3+

has 3d5

electronic configuration .

It contains one unpaired electron after pairing of electrons for d2sp

3hybridisation. paramagnetic.

L : [Co(NH3)6]3+ :

Co 3+ has 3d6 electronic configuration.

It contains no unapaired electron after pairing of electrons for d2sp

3hybridisation . diamagnetic

M : [Co(ox)3]3- : Co 3+ has 3d6 electronic configuration, d2sp3 hybridisation , diamagnetic.

N : [ Ni(H2O)6]2+

: Ni2+

has 3d8

electronic configuration, sp3d

2hybridisation with two unpaired

electrons ; paramagnetic.

O : [Pt(CN)4]2-

: 5d8

electronic configuration, dsp2

hybridisation ,diamagnetic.

P : [Zn(H2O)6]2+

: 3d10

electronic configuration, sp3d

2hybridisation ,diamagnetic.

7. Passing H2S gas into a mixture of Mn2+, Ni2+, Cu2+ and Hg2+ ions in an acidified aqueous solution

Precipitates (A) CuS and HgS (B) MnS and CuS

(C) MnS and NiS (D) NiS and HgS

Sol. (A)In presence of aqueous acidified solution, H2S precipitates as sulphides of Cu and Hg apart from Pb

+2,

Bi+3, Cd+2, As+3, Sb+3 and Sn+2.

In acidic medium, ionisation of H2S is suppressed. So less number of S2- ions are produced. So only

those sulphides which have low solubility product (Ksp) are precipitated, for example CuS and HgS.

8. Consider the following cell reaction:

2

2 02 ( ) ( ) 4 ( ) 2 ( ) 2 ( ) 1.672

Fe s O g H aq Fe aq H O l E V + ++ + → + =

At [Fe2+

] = 10-3

M, P(O2) = 0.1 atm and pH = 3, the cell potential at 25oC is

(A) 1.47 V (B) 1.77 V

(C) 1.87 V (D) 1.57 V

Sol. (D)

( ) ( ) ( ) ( ) ( )22 4 2 22 2

Fe s O g H aq Fe aq H O l+ ++ + → +

n = 4 (No. of moles of electrons involved)

8/2/2019 2011 P2




From Nernst’ equation,

[ ]

[ ]

0Pr0.0591

log

Re tancell cell

oducts E E

n ac ts

= −

2

22

4

0.0591log

4

o

O

Fe E E

p H

+

+

= − ×

( )

( ){ }

3

43

100.05911.67 log 10

4 0.1 10

pH H

−

+ −

− = − =

×Q

= 1.67 – 0.106 = 1.57 V

SECTION – II (Total Marks : 16)

(Multiple Correct Answer(s) Type)

This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of

which ONE OR MORE may be correct.

9. Reduction of the metal centre in aqueous permanganate ion involves(A) 3 electrons in neutral medium (B) 5 electrons in neutral medium(C) 3 electrons in alkaline medium (D) 5 electrons in acidic medium

Sol. (A, C, D)In acidic medium,

MnO4

-

→ Mn

2+

(n factor =5)In neutral / weakly alkaline medium,

MnO4- → MnO2 (n factor =3)

In strongly alkaline medium

MnO4 - → MnO4

2- (n factor =1)

10. The correct functional group X and the reagent/reaction conditions Y in the following scheme are

(A) , / / 3 2

X COOCH Y H Ni heat = = (B) , / / 2 2

X CONH Y H Ni heat = =

(C) , / 2 2

X CONH Y Br NaOH = = (D) , / / 2

X CN Y H Ni heat = =

Sol. (A,B,C,D) Condensation polymers are formed by repeated condensation reactions between two different bi-

functional or tri-functional monomeric units. In these polymerisation reactions, the elimination

of small molecules such as water, alcohol, hydrogen chloride, etc.take place.

8/2/2019 2011 P2




∆ ∆( ) ( )

( )HOOC- CH COOHH /Ni 22 4NH OC CH CONH NH CH NH2 2 2 2 2 24 6

−− − → − − →

( ) ( )

O O|| ||

NH CH NH C CH C2 26 4

− − − − − − −

( ) ( )( )HOOC CH COOHBr 22 4NH OC CH CONH NH NH

2 2 2 2 2 24 4CH

− −− − → − − − →

∆NaOH/ ∆

( ) ( )

O O|| ||


− − − − − − −

( 1st

step is Hofmann Bromamide reaction )

( ) ( )

( )HOOC CH COOH / 22 4NC CH CN NH NH2 2 2 24 6

H NiCH

− −− − → − − →

∆∆

( ) ( )

O O|| ||


− − − − − − −

11. For the first order reaction ( ) ( ) ( )2 5 2 22N O g 4NO g +O g→ (A) the concentration of the reactant decreases exponentially with time

(B) the half-life of the reaction decreases with increasing temperature(C) the half-life of the reaction depends on the initial concentration of the reactant

(D) the reaction proceeds to 99.6% completion in eight half-life duration

Sol. (A,B,D)For first order reaction

[ ] [ ]0

.kt

A A e −=

Hence concentration of [NO2] decreases exponentially.

8/2/2019 2011 P2




Also 1/2

0.693t

K = . Which is independent of concentration and t1/2 decreases with the increase of

temperature.

99.6

2.303 100log

0.4t

K

=

( )99.6 1/2

2.303 0.6932.4 8 8t t

K K = = × =

12. The equilibrium02 I II

Cu Cu Cu+

In aqueous medium at 25

o

C shifts towards the left in the presence of (A)3NO− (B) Cl− (C) SCN− (D) CN−

Sol. (B,C,D)

Cu2+ ions will react with CN− and SCN− forming [Cu(CN)4]3− and [Cu(SCN)4]

3− leading the reaction in

the backward direction.

( )2+

2Cu +2CN Cu CN− →

( ) ( )2 2

2Cu 2CuCN+ CNCN →

( )3-

4CuCN+3CN Cu CN− →

( )3-

2

4Cu +4SCN Cu SCN+ − →

2Cu + also combines with CuCl2 which reacts with Cu to produce CuCl pushing the reaction in the

backward direction.

2CuCl +Cu 2CuCl→ ↓

SECTION-III (Total Marks : 24)(Integer Answer Type)

This section contains 6 questions. The answer to each of the questions is a single-digit integer, ranging from 0

to 9. The bubble corresponding to the correct answer is to be darkened in the ORS.

13. The maximum number of isomers (including stereoisomers) that are possible on monochlorination

of the following compound is

Sol. (8)

8/2/2019 2011 P2




2+CH CH C CH CH +CH CH CH CH CH3 2 2 3 3 2 3− − − − − − −

CH3

CH2Cl

Cl

Total = 2 + 4 + 1 + 1 = 8

14. The total number of contributing structures showing hyperconjugation (involving C−−−−H bonds) forthe following carbocation is

Sol. (6)There are 6 Hyperconjugable H atoms.

15. Among the following, the number of compounds than can react with PCl5 to give POCl3 isO2, CO2, SO2, H2O, H2SO4, P4O10

Sol. 4 PCl5 produces POCl3 on reaction with the following compounds

PCl5 + SO2 → POCl3 + SOCl2PCl5 + H2O → POCl3 + 2HCl

PCl5 + H2SO4 → SO2Cl2 + 2POCl3 + 2HCl

6PCl5 + P4O10 → 10POCl3

8/2/2019 2011 P2




16. The volume (in mL) of 0.1 M AgNO3 required for complete precipitation of chloride ions present

in 30 mL of 0.01 M solution of [Cr(H2O)5Cl]Cl2, as silver chloride is close to

Sol. (6)

Number of ionisable Cl− in [Cr(H2O)5Cl]Cl2 is 2

∴ Millimoles of Cl− = 30 × 0.01 × 2 = 0.6

∴ Millimoles of Ag+ required = 0.6

∴ 0.6 = 0.1 VV = 6 ml

17. In 1 L saturated solution of AgCl [Ksp(AgCl) = 1.6 ×××× 10−−−−10

], 0.1 mol of CuCl [Ksp(CuCl) = 1.0

×××× 10−−−−6] is added. The resultant concentration of Ag+ in the solution is 1.6 ×××× 10−−−−x. The value of “x” is

Sol. (7)

Let the solubility of AgCl is x mol litre-1

AgCl Ag Cl+ −+

and that of CuCl is y mol litre-1 x x

y y

CuCl Cu Cl+ −+

∴Ksp of AgCl = [Ag+][Cl–1]

( )101.6 10 x x y−× = + ……….(i)

Similarly Ksp of CuCl = [Cu+][Cl-]

( )61.6 10 y x y−× = + ……….(ii)

On solving (i) and (ii)71.6 10 Ag + − = × 7 x∴ =

18. The number of hexagonal faces that are present in a truncated octahedron is

Sol. (8)In geometry, the truncated octahedron is an Archimedean solid.

It has 14 faces (8 regular hexagonal and 6 square), 36 edges, and 24 vertices.

8/2/2019 2011 P2




SECTION-IV (Total Marks : 16)

(Matrix-Match Type)

This section contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and

five statements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct matching

with ONE or MORE statement(s) given in Column II. For example, if for a given question, statement B

matches with the statements given q and r, then for the particular question, against statement B, darken the

bubbles corresponding to q and r in the ORS.

19. Match the transformations in column I with appropriate options in column II.Column-I Column-II

(A) ( ) ( )2 2

CO s CO g→ (p) phase transition

(B) ( ) ( ) ( )3 2

CaCO s CaO s CO g→ + (q) allotropic change

(C) ( )22

H H g• → (r) H ∆ is positive

(D)( ) ( )white,solid red,solid

P P→ (s) S ∆ is positive

(t) ∆S is negative

Sol. (A) →→→→ (p, r, s) (B) →→→→ (r, s) (C) →→→→ (t) (D) →→→→ (p, q, t)

(A) CO2 (s) → CO2 (g)This is phase transition(sublimation).

This process is endothermic

Gas is produced, so entropy increases. Entropy of s < l < gJ

10411Page # 10 (B) CaCO3 decomposes on heating. So this process is endothermic.

Entropy increases as gaseous product is formed.

(C) 2H• →H2(g)Entropy decreases as the number of gaseous particles is decreasing.

(D)( ) ( )white,solid red,solid

P P→

This is phase transition.

White and red P are allotopes.

Red P is more stable than white phosphorous.So ∆H is - ve.

8/2/2019 2011 P2




20. Match the reactions in column I with appropriate types of steps/reactive intermediate involved in

these reactions as given in column II.Column-I Column-II

(A) (p) Nucleophilic substitution

(B) (q) Electrophilic substitution

(C) (r) Dehydration

(D) (s) Nucleophilic addition

(t) Carbanion

Sol.

(A) →→→→ (r, s, t)

(B) →→→→ (p, s)

(C) →→→→ (r, s)

(D) →→→→ (q, r)

8/2/2019 2011 P2




A :

B :

C :

8/2/2019 2011 P2




D :

Documents

2011 P2