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Hazardous Materials ProgramsHazardous Materials ProgramsHazardous Materials ProgramsHazardous Materials Programs

2009 2009 2009 2009

CUPA Packet Training CUPA Packet Training CUPA Packet Training CUPA Packet Training

Welcome

Agenda

� Introductions

� Overview of CCHS Programs

� Background on Regulations

� What’s Inside the 2009 CUPA Packet

� Step-by-Step Instructions

� Q & A Session

� CUPA Inspections (Time Permitting)

� Today’s Instructors…

� Melissa J. Hagen

� Eric Jonsson

� June Cox

� Today’s “Class”

� Your Name

� Type of Business

� New to CUPA Programs? Returning?

• Please silence…

• Restrooms…

• Ask questions when you think of

them.

Introductions

� HazMat Business Plans

� Hazardous Waste

� Underground Storage Tanks

� Cal/ARP

� Article 80 (Copy to FD)

� Aboveground Storage Tanks (New)

� Incident Response Team (24/7 for Co Co County)

� Clean Water

� Green Business

Overview of CCHS Programs

Background

� Community-Right-to-Know Regulations

� Bhopal, India accident 12/3/1984� Union Carbide Plant - Methyl Isocyanate

release (40t)

� 3,800 deaths immediately

� 15,000 deaths from after-effects

� 500,000 people exposed

Purpose

1. Emergency Preparedness� Business Level

� Community Level

2. Community Right-To-Know

Bhopal, India 12/3/1984

Background

� AB 2185, 1986

� California Health & Safety Code -Chapter 6.95, Section 2550-25520

� California Code of Regulations (CCR Title 19, Chapter 4)

Vocabulary

� What is a “Hazardous Material?”

� What are “thresholds?”

Vocabulary

“Hazardous materials include any material that, because of its quantity, concentration, or physical or chemical characteristics, poses a significant present or potential hazard to human health and safety or to the environment if released into the workplace or the environment.”

Ch 6.95 H&S Code, Sect 25509

Vocabulary

�AB 2185 Thresholds

�55 gallons (Liquids)

�500 pounds (Solids)

�200 cubic feet (Compressed Gases)�1000 cubic feet (STP) for Oxygen, Nitrogen,

and Nitrous Oxide for physicians, dentists, veterinarians or pharmacists

Vocabulary

Exemptions:• Consumer size packaged goods, for direct sale to

the general public MAY be exempt

• Product Motor oil over 55 gallons provided that there is no more than 55 gallons per weight.

(275 Gallons)

•Certain unstaffed remote facilities

What’s

in the Packet

Cover Letter

What’s

in the Packet

Instructions

(Double Sided)

INSTRUCTIONS FOR COMPLETING

HAZARDOUS MATERIALS

BUSINESS PLAN 2008 FORMS

(ADDITIONAL LOCALLY COLLECTED INFORMATION)

The purpose of these instructions is to assist you with completing the following forms: Business Owner/Operator

Identification and Hazardous Materials Inventory-Chemical Description. This addendum to the instructions will alert

you to our modifications and assist you with the form completion. Most modifications are restricted to the

ADDITIONAL LOCALLY COLLECTED INFORMATION sections, Data Element Box #133 on the Business

Owner/Operator Identification and Data Element Box #246 on the Hazardous Materials Inventory-Chemical

Description form. To fill out electronic version of the forms, use the tab key to move the cursor to the next data

element box. The original OES INSTRUCTIONS are reprinted on the reverse side of the forms.

You must complete a Business Plan for each facility (location) at which your business handles hazardous

materials in reportable quantities.

READ THE INSTRUCTIONS CAREFULLY BEFORE COMPLETING

For the Business Owner/Operator Identification form each data element is associated with an identifying number

marked in each box. This number is referenced below under “DATA ELEMENT BOXES”. An explanation of the

information required can be found under the adjacent “INFORMATION REQUIRED” heading. For example, the

first data element is “FACILITY ID# (1). By looking under the heading “BUSINESS OWNER/OPERATOR

IDENTIFICATION PAGE”, you will find the line description under “DATA ELEMENT BOXES”, and the

associated information necessary to complete the entry under “INFORMATION REQUIRED”.

BUSINESS OWNER/OPERATOR IDENTIFICATION PAGE

DATA ELEMENT BOXES INFORMATION REQUIRED

1. FACILITY ID# Enter the unique six (6) digit number assigned to your

facility in the last six sections of the element box. The

number can be found on all correspondence you

receive from the CUPA.

100. BEGINNING DATE The beginning date and year of the report. This will be

01/01/08 for this report. For your convenience, we

have completed this line for you.

101. ENDING DATE The ending date and year of the report. This will be

12/31/08 for this report. For your convenience, we

have completed this line for you.

133. ADDITIONAL LOCALLY COLLECTED INFORMATION

• NUMBER OF EMPLOYEES Enter the total number of employees at each site. This

number must include temporary part-time, contract and

full-time workers. Officers, partners and owners of the

business are to be included in this number as well. To

calculate, sum the hours for which employees were paid

during the calendar year and divide by 2080 (number of work

hours per year).

What’s

in the Packet

Check Sheet

(Page one)

What’s

in the Packet

Check Sheet

(Page two)

What’s

in the Packet

Site Layout

Instructions

What’s

in the Packet

Site Layout

Example

What’s

in the Packet

Conversion Factors

• Common Conversion Factors

What’s

in the Packet

What’s

in the Packet

Table 1. Federal Regulated Substances List and Threshold Quantities

for Accidental Release Prevention

Chemical Name

Also on

Table 3 f

CAS

Number

Threshold

quantity (lbs)

Basis

for listing

Acrolein [2-Propenal] yes 107-02-8 5,000 b

Acrylonitrile [2-Propenenitrile] yes 107-13-1 20,000 b

Acrylyl chloride [2-Propenoyl chloride] yes 814-68-6 5,000 b

Allyl alcohol [2-Propen-l-ol] yes 107-18-6 15,000 b

Allylamine [2-Propen-l-amine] yes 107-11-9 10,000 b

Ammonia (anhydrous) yes 7664-41-7 10,000 a,b

Ammonia (conc 20% or greater) yes 7664-41-7 20,000 a,b

Arsenous trichloride yes 7784-34-1 15,000 b

Arsine yes 7784-42-1 1,000 b

Boron trichloride [Borane, trichloro-] yes 10294-34-5 5,000 b

Boron trifluoride [Borane, trifluoro-] yes 7637-07-2 5,000 b

Boron trifluoride compound with methyl ether (1:1) [Boron,

trifluoro [oxybis[metane]]]-, T-4-

yes 353-42-4 15,000 b

Bromine yes 7726-95-6 10,000 a,b

Carbon disulfide yes 75-15-0 20,000 b

Chlorine yes 7782-50-5 2,500 a,b

Chlorine dioxide [Chlorine oxide (ClO2)] no 10049-04-4 1,000 c

Chloroform [Methane, trichloro-] yes 67-66-3 20,000 b

Chloromethyl ether [Methane, oxybis[chloro-]] yes 542-88-1 1,000 b

Chloromethyl methyl ether [Methane, chloromethoxy-] yes 107-30-2 5,000 b

Crotonaldehyde [2-Butenal] yes 4170-30-3 20,000 b

Crotonaldehyde, (E)- [2-Butenal, (E)-] yes 123-73-9 20,000 b

Cyanogen chloride no 506-77-4 10,000 c

Cyclohexylamine [Cyclohexanamine] yes 108-91-8 15,000 b

Diborane yes 19287-45-7 2,500 b

Dimethyldichlorosilane [Silane, dichlorodimethyl-] yes 75-78-5 5,000 b

1,1-Dimethylhydrazine [Hydrazine,1,1-dimethyl-] yes 57-14-7 15,000 b

Epichlorohydrin [Oxirane, (chloromethyl)-] yes 106-89-8 20,000 b

Ethylenediamine [1,2-Ethanediamine] yes 107-15-3 20,000 b

Ethyleneimine [Aziridine] yes 151-56-4 10,000 b

Ethylene oxide [Oxirane] yes 75-21-8 10,000 a,b

Fluorine yes 7782-41-4 1,000 b

Formaldehyde (solution) yes 50-00-0 15,000 b

Furan yes 110-00-9 5,000 b

Hydrazine yes 302-01-2 15,000 b

Hydrochloric acid (conc 37% or greater) no 7647-01-0 15,000 d

Hydrocyanic acid yes 74-90-8 2,500 a,b

Hydrogen chloride (anhydrous) [Hydrochloric acid] yes 7647-01-0 5,000 a

Hydrogen fluoride/Hydrofluoric acid (conc 50% or greater) [Hydrofluoric acid]

yes 7664-39-3 1,000 a,b

Hydrogen selenide yes 7783-07-5 500 b

Hydrogen sulfide yes 7783-06-4 10,000 a,b

Iron, pentacarbonyl- [Iron carbonyl (Fe(CO)5), (TB-5-11)-] yes 13463-40-6 2,500 b

Isobutyronitrile [Propanenitrile, 2-methyl-] yes 78-82-0 20,000 b

Isopropyl chloroformate [Carbonochloridic acid, 1-

methylethyl ester]

yes 108-23-6 15,000 b

Methacrylonitrile [2-Propenenitrile, 2-methyl-] yes 126-98-7 10,000 b

Methyl chloride [Methane, chloro-] no 74-87-3 10,000 a

Table 1

Federal Regulated

Substances

(Cal/ARP Program)

What’s

in the Packet

Business

Owner/Operator

Identification

What’s

in the Packet

Above Ground

Petroleum Storage

Above Ground Petroleum Storage Tanks

Businesses that handle petroleum products in above ground storage tanks (55 gallons or

greater vessels) with an accumulated total over 1320 gallons are required to develop and

implement a Spill Prevention Containment and Countermeasure (SPCC) Plan. This plan

is to be certified by a professional engineer. Businesses that have been required to do an

SPCC Plan were also required to submit fees to the State Water Resources Control Board

(SWRCB) each year to pay for the compliance inspections of the locations that fell under

these requirements. Lately the SWRCB has not had the resources to perform the SPCC

inspections.

Legislation (AB 1130) this year transfers the authority for inspecting the business that

requires a SPCC Plan from the SWRCB to the local Certified Unified Program Agencies

(CUPA) beginning on January 1, 2008. The legislation requires the CUPA’s to ensure

that businesses that are required to have a SPCC Plan are implementing that plan. There

will be a transition time for the CUPA’s to be able to perform the inspections. The

legislation requires that the CUPA inspectors are required to be trained and pass a test

before performing the inspections and there will be administrative functions that will

need to be completed by the CUPA’s prior to starting inspecting the business sites.

The money that was collected by the SWRCB during the years inspections were not

performed is being transferred to the CUPA’s to assist in the startup costs and training for

the CUPA’s. There is a two-year fee moratorium for businesses. So businesses that have

been paying fees to the SWRCB will not be required to submit the fees to the SWRCB

starting on January 1, 2008 and no fees will be charged by the CUPA’s until January 1,

2010. After January 1, 2010, the local CUPA’s may be charging the business that have

petroleum products stored in above ground storage tanks a fee, as part of the annual

CUPA fee.

Businesses that are subject to this program are required to submit their inventories using

the Business Inventory – Chemical Description page and Business Owner/Operator

Identification page, which are located in the package. When completing the inventory

information, check the appropriate box in Section 223 on the Business Inventory –

Chemical Description. The business is also required to submit the Business Activity

Page and mark the check box for question D, if that business is subject to the above

ground petroleum storage regulations.

D. ABOVE GROUND PETROLEUM STORAGE

Store greater than 1,320 gallons of petroleum products (new or

used) in aboveground tanks or containers. YES NO

8 NO FORM REQUIRED A SPCC Plan is required.

What’s

in the Packet

Hazardous

Materials

Inventory

One page per chemical

What’s

in the Packet

Business Activities

• Haz Mat Incident

Notification Policy

17 page-stapled

document

What’s

in the Packet

What’s

in the Packet

Hazardous Waste

Generator Report Form

(Return only if your

business generates HW)

Next…..

Step-by-Step Instructions!

All Businesses Complete this

Form

SIC/NAICS info

on next slide

Binder Available for all NAICS Codes

Website for conversions:www.naics.com/search

Break Time

All Businesses Complete this

Form

Cal/ARP Quantities

On Tables 1, 2 & 3

Haz Waste forms

on Unidocs.org website

UST forms on

cchealth.org website

Table 1. Federal Regulated Substances List and Threshold Quantities

for Accidental Release Prevention

Chemical Name

Also on

Table 3 f

CAS

Number

Threshold

quantity (lbs)

Basis

for listing

Acrolein [2-Propenal] yes 107-02-8 5,000 b

Acrylonitrile [2-Propenenitrile] yes 107-13-1 20,000 b

Acrylyl chloride [2-Propenoyl chloride] yes 814-68-6 5,000 b

Allyl alcohol [2-Propen-l-ol] yes 107-18-6 15,000 b

Allylamine [2-Propen-l-amine] yes 107-11-9 10,000 b

Ammonia (anhydrous) yes 7664-41-7 10,000 a,b

Ammonia (conc 20% or greater) yes 7664-41-7 20,000 a,b

Arsenous trichloride yes 7784-34-1 15,000 b

Arsine yes 7784-42-1 1,000 b

Boron trichloride [Borane, trichloro-] yes 10294-34-5 5,000 b

Boron trifluoride [Borane, trifluoro-] yes 7637-07-2 5,000 b

Boron trifluoride compound with methyl ether (1:1) [Boron,

trifluoro [oxybis[metane]]]-, T-4-

yes 353-42-4 15,000 b

Bromine yes 7726-95-6 10,000 a,b

Carbon disulfide yes 75-15-0 20,000 b

Chlorine yes 7782-50-5 2,500 a,b

Chlorine dioxide [Chlorine oxide (ClO2)] no 10049-04-4 1,000 c

Chloroform [Methane, trichloro-] yes 67-66-3 20,000 b

Chloromethyl ether [Methane, oxybis[chloro-]] yes 542-88-1 1,000 b

Chloromethyl methyl ether [Methane, chloromethoxy-] yes 107-30-2 5,000 b

Crotonaldehyde [2-Butenal] yes 4170-30-3 20,000 b

Crotonaldehyde, (E)- [2-Butenal, (E)-] yes 123-73-9 20,000 b

Cyanogen chloride no 506-77-4 10,000 c

Cyclohexylamine [Cyclohexanamine] yes 108-91-8 15,000 b

Diborane yes 19287-45-7 2,500 b

Dimethyldichlorosilane [Silane, dichlorodimethyl-] yes 75-78-5 5,000 b

1,1-Dimethylhydrazine [Hydrazine,1,1-dimethyl-] yes 57-14-7 15,000 b

Epichlorohydrin [Oxirane, (chloromethyl)-] yes 106-89-8 20,000 b

Ethylenediamine [1,2-Ethanediamine] yes 107-15-3 20,000 b

Ethyleneimine [Aziridine] yes 151-56-4 10,000 b

Ethylene oxide [Oxirane] yes 75-21-8 10,000 a,b

Fluorine yes 7782-41-4 1,000 b

Formaldehyde (solution) yes 50-00-0 15,000 b

Furan yes 110-00-9 5,000 b

Hydrazine yes 302-01-2 15,000 b

Hydrochloric acid (conc 37% or greater) no 7647-01-0 15,000 d

Hydrocyanic acid yes 74-90-8 2,500 a,b

Hydrogen chloride (anhydrous) [Hydrochloric acid] yes 7647-01-0 5,000 a

Hydrogen fluoride/Hydrofluoric acid (conc 50% or greater) [Hydrofluoric acid]

yes 7664-39-3 1,000 a,b

Hydrogen selenide yes 7783-07-5 500 b

Hydrogen sulfide yes 7783-06-4 10,000 a,b

Iron, pentacarbonyl- [Iron carbonyl (Fe(CO)5), (TB-5-11)-] yes 13463-40-6 2,500 b

Isobutyronitrile [Propanenitrile, 2-methyl-] yes 78-82-0 20,000 b

Isopropyl chloroformate [Carbonochloridic acid, 1-

methylethyl ester]

yes 108-23-6 15,000 b

Methacrylonitrile [2-Propenenitrile, 2-methyl-] yes 126-98-7 10,000 b

Methyl chloride [Methane, chloro-] no 74-87-3 10,000 a

Table 1

Federal Regulated

Substances

(Cal/ARP Program)

Hazardous Material Inventory

(One chemical per page)

Conversion factors

on next Slide

• Common Conversion Factors

Other Sources for

Chemical

Information:

• MSDS

• Condensed

Chemical

Dictionary

• Call our Office with

a Question

(925) 646-2286

INSTRUCTIONS TO COMPLETE

SITE LAYOUT AND FACILITY DIAGRAMS

Use the sample provided for guidance. The diagrams should be suitable for placing in a 9-inch x

12-inch file folder and must be legible. At a minimum, the map should show the following:

1. Site Layout

• Scale of map

• Site orientation (north, south, etc.)

• Loading areas

• Parking lots

• Internal roads

• Storm and sewer drains

• Adjacent property use

• Locations and names of adjacent streets and alleys

• Ingress and egress points and closure type (gate, fire door, etc.)

2. Facility

• Location of each hazardous materials handling area where hazardous materials are

handled.

• Type of storage, including aboveground, below ground and partially buried (e.g.,

storage tanks, barrels, process tanks, pallets, cylinders, rail cars, truck trailers, etc.).

• Location of emergency response equipment, such as equipment for fire suppression,

approach and mitigation, protective clothing, and medical response.

INSTRUCTIONS TO COMPLETE

EMERGENCY RESPONSE AND EVACUATION PLAN

AND EMPLOYEE TRAINING PROGRAM

The following check sheet serves for guidance only. However, at a minimum, your plan should

address each of the items listed.

Example

Site Diagram

Emergency

Response

and

Evacuation

Plan

Check Sheet

(Page one)

Emergency

Response

and

Evacuation

Plan

Check Sheet

(Page two)

Sample

Contingency Plan

Contingency Plan for

Facility Name

Facility Address

CA

City State Zip Code

- Telephone Number

EPA Hazardous Waste Generator ID # Contra Costa Facility ID #

This Document Will Be Kept:

Location of Contingency Plan

Date of Plan:

Emergency Coordinator: Daytime Phone: Alternate

Emergency Coordinator: Daytime Phone: Emergency Coordinators are familiar with all aspects of the facility. These designated persons have unrestricted access to the facility and have the

authority to make decisions during an emergency. CCR 66265.52(d) & 66265.55

This

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esp

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Sample Training Log

Employee Training Log CCR 66265.16(d(4)

Employee Signature – Date

Employee Name

Job Title – Description

Date of Training

Training Type

Trainer's Initials

print

Initial or review

Description of Training: Initial

Review

5

Hazardous Material

Incident Notification Policy

17 page-stapled document

Approved by the Board of

Supervisors

More Information

� Electronic Version of forms via e-mail� ccchazmat@hsd.cccounty.us

� Webpage http://cchealth.org/groups/hazmat/

� (925) 646-2286

� Ask to Speak with a Hazardous Materials Specialist

� 4333 Pacheco Blvd, Martinez, CA 94553

Summary

CUPA Packet due date:

March 2, 2009

Late filing will result in penalties of 50% of the annual fee

Don’t be late!

Questions?Questions?Questions?Questions?

Thank you for coming!

HazMat Staff

What to expect during

an Inspection

Haz Mat

Business Plan

Inspection Form

Every 2-3 years

What to expect during

an Inspection

Haz Waste

Inspection Form

Every 2-3 years