2008 Midwest Regional Collings Refinery Units Streams

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    Refinery Units and Streams

    Jacobs Process PIT

    Dave CollingsSeptember 22, 2008

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    Refinery Units and Streams

    Session ObjectivesOverall function of Oil Refinery

    Refining terminology, including Crude Oiland Product description

    Function of individual Refinery Units

    Interrelationship between Refinery UnitsNot a detailed course in Refining Technology

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    Refinery Units and Streams

    RefineryCrude Oil Products

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    Refinery Units and Streams

    RefineryCrude Oil

    LPG

    Chemical FeedstockGasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

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    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical FeedstockGasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    CH3 CH3

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    Refinery Units and Streams

    Crude Oil CharacterizationBoiling Point Curve

    API GravitySulfur Content

    Nitrogen ContentMetals (Nickel/Vanadium)

    Conradson Carbon Residue (CCR)PONA Analysis

    (Paraffins/Olefins/Naphthenes/Aromatics)Viscosity Curve

    Carbon/Hydrogen Ratio

    Crude Assay is used to define characteristics

    Crude Oil

    LPG

    Chemical FeedstockGasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

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    HIBERNIA - SUMMARY OF MAJOR CUTS

    Whole Light Medium Heavy Kero Atm Light Heavy Vacuum Atm

    Crude Naphtha Naphtha Naphtha Gas Oil VGO VGO Resid Resid

    TBP Temp At Start, C 10 80 150 200 260 340 430 570 340

    TBP Temp At End, C 80 150 200 260 340 430 570 End End

    TBP Temp At Start, F 55 175 300 400 500 650 800 1050 650

    TBP Temp At End, F 175 300 400 500 650 800 1050 End End

    Yield at Start, vol% 1.6 7.3 21.3 30.9 41.6 56.7 69.9 86.6 56.7

    Yield at End, vol% 7.3 21.3 30.9 41.6 56.7 69.9 86.6 100.0 100.0

    Yield of Cut (wt% of Crude) 4.5 12.6 8.9 10.4 15.1 13.8 18.0 15.6 47.3

    Yield of Cut (vol% of Crude) 5.7 14.0 9.6 10.7 15.1 13.2 16.6 13.4 43.3

    Gravity, API 35.8 81.0 53.9 48.6 40.7 35.2 28.9 23.5 13.0 21.6

    Specific Gravity 0.8458 0.6660 0.7632 0.7857 0.8218 0.8489 0.8821 0.9127 0.9791 0.9240Sulfur, wt% 0.36 0.0003 0.0007 0.0080 0.0231 0.154 0.391 0.499 1.07 0.656

    Mercaptan Sulfur, ppm 1 2 2 3 3 3

    Nitrogen, ppm 1030 51 600 1600 4200 2200

    Hydrogen, wt% 16.1 15.9 15.4 14.6 14.0 13.3 12.6

    Viscosity @ 40 C (104 F), cSt 5.20 1.07 1.73 4.06 13.3

    Viscosity @ 50 C (122 F), cSt 3.50 0.938 1.47 3.26 9.79 64.9 20100 141

    Viscosity @ 100 C (212 F), cSt 0.929 0.563 0.797 1.46 3.29 11.0 465 19.1Viscosity @ 135 C (275 F), cSt 0.0276 0.438 0.591 0.994 2.00 5.16 110 8.21

    Total Acid Number, mg KOH/g 0.11 0.00 0.01 0.02 0.03 0.04 0.10 0.22

    Cetane Index, ASTM D976 37 46 52 46

    Diesel Index 61 57 56

    Characterization Factor (K Factor) 11.9 12.7 11.6 11.8 11.8 11.9 12.0 12.1 12.0 12.0

    Research Octane Number, Clear 64.8 56.4 34.2

    Motor Octane Number, Clear 63.0

    Paraffins, vol% 83.1 48.1 51.2 46.9 40.0

    Naphthenes , vol% 16.9 35.2 30.4 31.8 33.0

    Aromatics, vol% 0.0 16.7 18.4 21.2 27.0

    Molecular Weight 233 103 112 143 176 227 310 441 824 436

    Heptane Asphaltenes, wt% 0.88 5.6 1.9

    Micro Carbon Res idue, wt% 1.25 8.01 2.63

    Ramsbottom Carbon, wt% 1.2 7.6 2.5

    Vanadium, ppm 0.9 6 2

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    Refinery Units and Streams

    API Gravity

    Measure of Crude Oil Density

    Higher API Gravity = Lower Density

    Light Crude > 40API

    Medium Crude

    Heavy Crude < 20API

    Crude Oil

    LPG

    Chemical FeedstockGasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

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    Refinery Units and Streams

    Light Sweet Crude Oil

    Oso (Nigerian)

    47.4API

    0.046 % Sulfur

    Crude Oil

    LPG

    Chemical FeedstockGasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    7.05 %

    35.24 %

    24.46 %

    14.74 %

    81.49 %Total

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    Refinery Units and Streams

    Medium Sweet Crude Oil

    Brent (North Sea)

    38.5API

    0.43 % Sulfur

    Crude Oil

    LPG

    Chemical FeedstockGasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    3.4 %

    28.8 %

    14.9 %

    14.7 %

    Total 61.8 %

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    Refinery Units and Streams

    Medium Sour Crude Oil

    Maya (Mexico)

    22.2API

    3.3 % Sulfur

    Crude Oil

    LPG

    Chemical FeedstockGasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    1.1 %

    15.6 %

    11.4 %

    12.7 %

    Total 40.8 %

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    Refinery Units and Streams

    Heavy Sour Crude Oil

    Merey (Venezuela)

    16.0API

    2.28 % Sulfur

    Crude Oil

    LPG

    Chemical FeedstockGasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    0.61 %

    8.55 %

    8.64 %

    15.50 %

    Total 33.30 %

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    Refinery Units and Streams

    Bitumen from Oil Sands

    Athabasca NFT

    8.6API

    4.55 % Sulfur

    Crude Oil

    LPG

    Chemical FeedstockGasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    0.00 %

    0.30 %

    2.90 %

    12.10 %

    Total 15.30 %

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    Refinery Units and Streams

    Full Conversion Refinery

    Converts less valuable fractions intotransportation fuels

    Can process heavier, cheaper crude oil

    Modern refinery can convert ~90% of crude oil

    into fuels and products

    Crude Oil

    LPG

    Chemical FeedstockGasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    $$$$$$$$

    $$$$$$$$

    $$$$$$$$

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    Refinery Units and Streams

    RefineryCrude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

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    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    CrudeDistillation Conversion ProductFinishing

    Byproduct Recovery

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    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    CrudeDistillation Conversion

    Byproduct Recovery

    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

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    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Conversion

    Byproduct Recovery

    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    CrudeDistillation

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    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Conversion

    Byproduct Recovery

    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    CrudeDistillation

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    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Conversion

    Byproduct Recovery

    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    CrudeDistillation

    Function of Crude Unit

    Remove salts and solids fromCrude Oil

    Preheat Crude Oil andproducts to downstreamprocessing temperatures

    Separate Crude Oil into wide-boiling cuts for further

    processing

    Also known as Crude/Vac orCrude Pipestill

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Conversion

    Byproduct Recovery

    CrudeDistillation

    PreheatAnd

    Desalter

    AtmosphericTower

    VacuumTower

    Light Ends

    Naphtha

    Distillate

    Gas Oil

    Residual

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Conversion

    Byproduct Recovery

    CrudeDistillation

    PreheatAnd

    Desalter

    AtmosphericTower

    VacuumTower

    Light Ends

    Naphtha

    Distillate

    Gas Oil

    Residual

    Off Gas

    Straight-RunNaphtha

    Straight-RunKerosene

    Straight-RunDiesel

    AGO

    ATB(Atmos Resid)

    LVGO

    HVGO

    VTB

    (Vac Resid)

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Conversion

    Byproduct Recovery

    CrudeDistillation

    PreheatAndDesalter

    AtmosphericTower

    VacuumTower

    Light Ends

    Naphtha

    Distillate

    Gas Oil

    Residual

    Off Gas

    Straight-RunNaphtha

    Straight-RunKerosene

    Straight-RunDiesel

    AGO

    ATB(Atmos Resid)

    LVGO

    HVGO

    VTB

    (Vac Resid)

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Conversion

    Byproduct Recovery

    CrudeDistillation

    PreheatAndDesalter

    AtmosphericTower

    VacuumTower

    Off Gas

    Straight-RunNaphtha

    Straight-RunKerosene

    Straight-RunDiesel

    AGO

    ATB(Atmos Resid)

    LVGO

    HVGO

    VTB

    (Vac Resid)

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation

    Conversion

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation

    Conversion

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation

    Function of Conversion Units

    Convert low-value intermediate streams tohigh-value products

    Provide net volumetric gain (Volume Swell)

    Conversion units are the Economic Drivers ofthe Refinery

    Primary Conversion Modes are HydrogenAddition and Carbon Rejection

    Conversion

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation

    Typical Conversion Units

    Fluid Catalytic Cracking Unit (FCCU or CatCracker)

    Alkylation Unit (HF or H2SO4)

    Hydrocracker (MHC or Full Conversion)

    Delayed Coker

    Conversion

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation

    Fluid Catalytic Cracking Unit (FCCU)

    Cracks Gas Oil feeds into Gasoline andvaluable byproducts

    Uses finely powdered catalyst to crack

    feedstocks to products

    Gasoline product has high (85-87) octane

    Products may or may not meet sulfur specsdepending on feed quality

    Conversion is based on Carbon Rejection

    Conversion

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation Conversion

    Light Ends

    Naphtha

    Distillate

    Gas Oil

    Residual

    Riser

    Reactor

    Regenerator

    Air

    AGO

    LVGO

    HVGOOther Gas Oil

    MainFractionator

    Heavy Cat Naphtha (HCN)

    FCC Wet Gas

    Light Cycle Oil (LCO)

    Clarified Slurry Oil (CSO)

    Fractionator Overhead

    (Decant Oil)

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation Conversion

    Light Ends

    Naphtha

    Distillate

    Gas Oil

    Residual

    Riser

    Reactor

    Regenerator

    Air

    AGO

    LVGO

    HVGOOther Gas Oil

    MainFractionator

    Heavy Cat Naphtha (HCN)

    FCC Wet Gas

    Light Cycle Oil (LCO)

    Clarified Slurry Oil (CSO)

    Fractionator Overhead

    (Decant Oil)

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation Conversion

    Light Ends

    Naphtha

    Distillate

    Gas Oil

    Residual

    FCC Wet Gas

    Fractionator Overhead

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation Conversion

    Light Ends

    Naphtha

    Distillate

    Gas Oil

    Residual

    FCC Wet Gas

    Fractionator Overhead

    Wet Gas Compressor

    FCC Gas Plant(Unsat Gas Plant)

    (Cat Light Ends Unit)

    FCC Dry Gas

    FCC C3s

    FCC C4s

    FCC C3sP/P OlefinsC3 Olefins

    Refinery Grade Propylene

    FCC C4sB/B OlefinsC4 Olefins

    Refinery Butylenes

    Light CatNaphtha

    (LCN)

    Coker LPG

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation Conversion

    FCC Wet Gas

    Fractionator Overhead

    Wet Gas Compressor

    FCC Gas Plant(Unsat Gas Plant)

    (Cat Light Ends Unit)

    FCC Dry Gas

    FCC C3s

    FCC C4s

    FCC C3sP/P OlefinsC3 Olefins

    Refinery Grade Propylene

    FCC C4sB/B OlefinsC4 Olefins

    Refinery Butylenes

    Light CatNaphtha

    (LCN)

    Coker LPG

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation

    Typical Conversion Units

    Fluid Catalytic Cracking Unit (FCCU or CatCracker)

    Alkylation Unit (HF or H2SO4)

    Hydrocracker (MHC or Full Conversion)

    Delayed Coker

    Conversion

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation

    Alkylation (Alky) Unit

    Converts light end byproducts from FCCU togasoline blending components

    Uses strong acid (HF or H2SO4) as catalyst to

    convert feedstocks to products

    Gasoline product has very high (94-97) octane

    Products will contain no sulfur

    Conversion is based on Hydrogen Addition(using isobutane as H2 Donor)

    Conversion

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation Conversion

    Light Ends

    Naphtha

    FeedPreparation

    Isobutane

    FCC C4s

    FCC C3s

    FCC C5s

    ReactorsFraction

    ation

    Propane

    N-Butane

    Recycle Isobutane

    Alkylate

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation Conversion

    FeedPreparation

    Isobutane

    FCC C4s

    FCC C3s

    FCC C5s

    ReactorsFraction

    ation

    Propane

    N-Butane

    Recycle Isobutane

    Alkylate

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation

    Typical Conversion Units

    Fluid Catalytic Cracking Unit (FCCU or CatCracker)

    Alkylation Unit (HF or H2SO4)

    Hydrocracker (MHC or Full Conversion)

    Delayed Coker

    Conversion

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation

    Hydrocracker Unit

    Converts Gas Oil and other low-value Refinerystreams to diesel and gasoline

    Uses hydrogen and solid catalyst to convertfeedstocks to products

    Gasoline product has medium (80-85) octane -makes good CCR feedstock

    Diesel product has excellent cetane properties

    Products will meet low-sulfur specs

    Conversion is based on Hydrogen Addition

    Conversion

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation Conversion

    Light Ends

    Naphtha

    Distillate

    Gas Oil

    Residual

    HDS/HDNReactors

    AGO

    Coker GO

    HVGO/LVGO

    Hydrogen

    HydrocrkgReactors

    Separators

    Recycle Compressor

    Fractionation

    Fuel Gas

    HCU LPG

    Lt Naphtha

    Hvy Naph

    Hydrocracker Naphtha - Hydrocrackate

    Lt Distillate

    HCU Diesel

    Unconverted Oil

    Full Conversion

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation Conversion

    Light Ends

    Naphtha

    Distillate

    Gas Oil

    Residual

    HDS/HDNReactors

    AGO

    Coker GO

    HVGO/LVGO

    Hydrogen

    HydrocrkgReactors

    Separators

    Recycle Compressor

    Fractionation

    Fuel Gas

    HCU LPG

    Lt Naphtha

    Hvy Naph

    Hydrocracker Naphtha - Hydrocrackate

    Lt Distillate

    HCU Diesel

    Partial (MHC) Conversion

    FCC Feed

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation Conversion

    HDS/HDNReactors

    AGO

    Coker GO

    HVGO/LVGO

    Hydrogen

    HydrocrkgReactors

    Separators

    Recycle Compressor

    Fractionation

    Fuel Gas

    HCU LPG

    Lt Naphtha

    Hvy Naph

    Hydrocracker Naphtha - Hydrocrackate

    Lt Distillate

    HCU Diesel

    Partial (MHC) Conversion

    FCC Feed

    R fi U i d S

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation

    Typical Conversion Units

    Fluid Catalytic Cracking Unit (FCCU or CatCracker)

    Alkylation Unit (HF or H2SO4)

    Hydrocracker (MHC or Full Conversion)

    Delayed Coker

    Conversion

    R fi U it d St

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation

    Delayed Coker Unit

    Cracks Residual feeds into Gasoline, Dieseland other byproducts

    Uses high temperature (thermal cracking) to

    crack feedstocks to products

    Coker liquid products all require downstreamprocessing to meet specifications

    Petroleum coke can be high-value (AnodeGrade) or low-value (Fuels Grade)

    Conversion is based on Carbon Rejection

    Conversion

    R fi U it d St

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation Conversion

    Light Ends

    Naphtha

    Distillate

    Gas Oil

    Residual

    Heater

    Vacuum Btms

    CokeDrums

    Petroleum Coke

    MainFractio

    nator

    CokerGas

    Plant

    Fuel Gas

    Coker LPG

    Coker Naphtha

    Coker Distillate

    (Coker Diesel)

    Coker Gas Oil

    Recycle

    R fi U it d St

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation Conversion

    Heater

    Vacuum Btms

    CokeDrums

    Petroleum Coke

    MainFractio

    nator

    CokerGas

    Plant

    Fuel Gas

    Coker LPG

    Coker Naphtha

    Coker Distillate

    (Coker Diesel)

    Coker Gas Oil

    Recycle

    Refinery Units and Streams

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    Byproduct Recovery

    CrudeDistillation Conversion

    Refinery Units and Streams

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    LPG

    CrudeDistillation Conversion

    Byproduct Recovery

    Light Ends

    Naphtha

    Distillate

    Gas Oil

    Residual

    Refinery Units and Streams

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    LPG

    CrudeDistillation Conversion

    Byproduct Recovery

    Light Ends

    Naphtha

    Distillate

    Gas Oil

    Residual

    Off Gas

    SR Naphtha

    SR Kero

    SR Diesel

    Refinery Units and Streams

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    ProductFinishing

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    CrudeDistillation Conversion

    Byproduct Recovery

    Light Ends

    Naphtha

    Distillate

    Gas Oil

    Residual

    Off Gas

    SR Naphtha

    SR Kero

    SR Diesel

    Delayed

    Coker

    Vac Btms

    FCCULVGO

    HVGO

    Hydro-cracker

    AGO

    Alkylation

    Refinery Units and Streams

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    Refinery Units and Streams

    Crude Oil

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    LPG

    CrudeDistillation Conversion

    Byproduct Recovery

    Light Ends

    Naphtha

    Distillate

    Gas Oil

    Residual

    Off Gas

    SR Naphtha

    SR Kero

    SR Diesel

    Delayed

    Coker

    Vac Btms

    FCCULVGO

    HVGO

    Hydro-cracker

    AGO

    Alkylation

    Petroleum Coke

    Coker Gas OilCoker DistillateCoker NaphthaCoker LPG

    Clarified Slurry Oil

    Light Cycle OilHvy Cat NaphthaLt Cat NaphthaFCC C4s

    FCC C3sFCC Feed

    HCU DieselHvy HydrocrackateLt HydrocrackateHCU LPG

    Isobutane

    PropaneN-Butane

    Alkylate

    Refinery Units and Streams

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    CrudeDistillation

    Byproduct Recovery

    Delayed

    Coker

    FCCU

    Conversion

    Hydro-cracker

    AlkylationLight Ends

    Naphtha

    Distillate

    Gas Oil

    Residual

    Crude Unit Off GasAlky Propane/n-ButaneHCU LPGFCC C3s

    SR NaphthaAlkylateLt/Hvy HydrocrackateLt/Hvy Cat NaphthaCoker Naphtha

    ProductFinishing

    SR KeroseneSR Diesel

    HCU DieselLight Cycle OilCoker Distillate

    Clarified Slurry OilPetroleum Coke

    Refinery Units and Streams

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    Light Ends

    Naphtha

    Middle Distillates

    Gas Oils

    Residuals

    Refinery Units and Streams

    Crude Oil

    LPG

    Chemical Feedstock

    Gasoline

    Jet Fuel / Kerosene

    Diesel

    Fuel Oil

    Lube / Specialty Oil

    Byproducts

    CrudeDistillation

    Byproduct Recovery

    Delayed

    Coker

    FCCU

    Conversion

    Hydro-cracker

    AlkylationLight Ends

    Naphtha

    Distillate

    Gas Oil

    Residual

    Crude Unit Off GasAlky Propane/n-ButaneHCU LPGFCC C3s

    SR NaphthaAlkylateLt/Hvy HydrocrackateLt/Hvy Cat NaphthaCoker Naphtha

    ProductFinishing

    SR KeroseneSR Diesel

    HCU DieselLight Cycle OilCoker Distillate

    Clarified Slurry OilPetroleum Coke

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    Refinery Units and Streams

    Jacobs Process PIT

    Questions and Comments?