2- Units of Measurement

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    Measurements

    Units of Measurement 

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      Measurement You are making a measurement when you

    Check you weight

    Read your watch

    Take your temperature

    What kinds of measurements did you make

    today?

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    Standards of Measurement

    When we measure, we use a measuring tool

    to compare some dimension of an object to

    a standard.

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    Measurement in ChemistryIn chemistry we

    ♦do experiments

    ♦measure quantities

    ♦use numbers to report measurements

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    Metric System SI!

      Is a decimal system based on "#

      $sed in most of the world

      $sed by scientists and hospitals

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    $nits in the Metric System  length meter m

      %olume liter &

      mass gram g

      temperature Celsius 'C

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    Stating a MeasurementIn e%ery measurement there is a

    ♦(umber

     followed by a

    ♦ $nit from measuring de%ice

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    &earning Chec)What is the unit of measurement in each of the following

    examples*

    +. he patient-s temperature is "#'/.

    0. he sac) holds 1 lbs of potatoes.

    C.  It is 2 miles from your house to school.

    3. he bottle holds & of orange soda.

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    Solution+. '/ degrees /ahrenheit!

    0.  lbs pounds!

    C.  miles

    3.  & liters!

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     Measurements

    Measured (umbers and

    Significant /igures

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    Measured (umbersWhen you use a measuring tool is used to

    determine a quantity such as your height or

    weight, the numbers you obtain are calledmeasured numbers .

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    4eading a Meterstic) 

    . l. . . . I . . . . I5 . . . .I . . . . I6. . cm

    /irst digit )nown! 7 .** cmSecond digit )nown! 7 #.8 .8* cm

    hird digit estimated! between #.#19 #.#8

    &ength reported 7 .81 cm

    or .8: cm

    or .88 cm

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    ;nown < =stimated 3igits ;nown digits  and 8 are "##> certain

    he third digit : is estimated uncertain!

    In the reported length, all three digits

    .8: cm! are significant including the

    estimated one

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    =xact (umbers ?btained when you count objects

    soccer balls

    " watch

    6 pi@@as

    ?btained from a defined relationship

    " foot 7 " inches

    " meters 7 "## cm

     Not obtained with measuring tools

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    &earning Chec)Classify each of the following as an exact "!

    or a measured ! number.

    +.AAABold melts at "#:6'C

    0.AAA" yard 7 5 feet

    C.AAA+ red blood cell with diameter : x "#96 cm

    3.AAAhere were : hats on the shelf 

    =.AAA+ can of soda contains 511 m& of soda

     

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    SolutionClassify each of the following as an exact "! or a

    measured! number. Bi%e reason.

    +. 4equires a thermometermeasuring tool!

    0. " /rom a definition in $.S. system

    C. (eed measuring tool to determine

    3. " Counted the hats

    =. Measured

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    17

     Measurements

    Significant /igures in Calculations

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    18

    Significant /igures in

    Measurementhe numbers reported in a measurement

    are limited by the measuring tool

    Significant figures in a measurement include

    the )nown digits plus one estimated digit

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    19

    Counting Significant /igures  (umber of Significant /igures

    52."1 cm6

    1.: ft

    :1.: lb  AAA 

    ".11 m AAA 

    Complete +ll non9@ero digits in a measured number

    are significant or not significant!.

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    (umber of Significant /igures

    #.##2 mm "

    #.#"1: o@ 5

    #.##6 lb AAAA 

    #.###: m&  AAAA 

    Complete &eading @eros in decimal numbers are

    significant or not significant!.

    20

    &eading Deros

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    (umber of Significant /igures

    1#.2 mm 5

    ##" min 6

    #.8# lb  AAAA 

    #.##6#1 m  AAAA

    Complete Deros between non@ero numbers are

    significant or not significant!.

    21

    Sandwiched Deros

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      (umber of Significant /igures 

    1,### in.

      ## yr "

      62,:## gal 5

    1,##1,### g  AAAA 

      Complete railing @eros in numbers withoutdecimals are significant or not significant! if

    they are ser%ing as place holders.

    22

    railing Deros

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    23

    &earning Chec)

    +. Which answers contain 5 significant figures*

    "! #.68:# ! #.##68: 5! 68:# 

    0. +ll the @eros are significant in"! #.##5#8 ! 1.5## 5! .#1# x "#5

    C. 156,:81 rounded to 5 significant figures is  "! 151 ! 151,### 5! 1.51 x "#1

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    24

    Solution

    +. Which answers contain 5 significant figures*

    ! #.##68: 5! 68:#

    0. +ll the @eros are significant in! 1.5## 5! .#1# x "#5

    C. 156,:81 rounded to 5 significant figures is ! 151,### 5! 1.51 x "#1

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    + calculated answer cannot be more precise

    than the measuring tool.

    + calculated answer must match the least

    precise measurement.

    Significant figures are needed for final answers

    from  "! adding or subtracting

    ! multiplying or di%iding

    25

    Significant (umbers in Calculations

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    26

    +dding and Subtractinghe answer has the same number of decimal

    places as the measurement with the fewest

    decimal places. 

    1.  one decimal place

    < ".56 two decimal places  :.16

    answer :.1 one decimal place

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    In each calculation, round the answer to the

    correct number of significant figures.

    +. 51.#1 < "E.: < ." 7

    "! 1:.81 ! 1:.2 5! 18

    0. 12.E1 9 "2. 7

    "! 6#.81 ! 6#.85 5! 6#.8

    27

    &earning Chec)

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    28

    Solution+. 51.#1 < "E.: < ." 7

    ! 1:.2

    0. 12.E1 9 "2. 7

    5! 6#.8

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    29

    Multiplying and 3i%iding

    4ound or add @eros! to the calculated answer

    until you ha%e the same number of significantfigures as the measurement with the fewest

    significant figures.

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    30

    &earning Chec)

    +. ."E F 6. 7"! E ! E. 5! E."E2

    0. 6.5"" G #.#8 7"! :".12  ! : 5! :# 

    C. .16 F #.##2 7

    #.#"#1 F #.#:#

    "! "".5 ! "" 5! #.#6"

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    31

    Solution

    +. ."E F 6. 7 ! E.

    0. 6.5"" G #.#8  7 5! :#

    C. .16 F #.##2 7 ! "" 

    #.#"#1 F #.#:#

    Continuous calculator operation 7

    .16 x #.##2 ÷  #.#"#1 ÷  #.#:# 

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    Measurements+ccuracy and Hrecision

    32

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    ow close a measurement is to the actual or true %alue

    good accuracy

    true %alue

      poor accuracy

    true %alue

    33

    +ccuracy

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    ow well se%eral measurements agree with

    each other

    good precision

      poor precision

    34

    Hrecision

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      What can you say about the accuracy and

    precision in each of the following

    Bood precision, poor accuracy

    Bood precision, good accuracy35

    +ccuracy and Hrecision

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      Match the following terms

    "! +ccuracy ! Hrecision

      AAA ow close a measurement is to the  true %alue.

     AAA ow close se%eral measurements

      are to each other.

      Can you ha%e data that are precise, but not

    accurate* Why or why not*36

    &earning Chec) 

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      Match the following terms

    "! +ccuracy ! Hrecision

      A"A   Is how close a measurement is to the  true %alue.

     AA   Is how close se%eral measurements

      are to each other.

      Jes. 3ata can be precise, but not come close to

    the true %alue.37

    Solution

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    38

    &earning Chec) rue"! or false !. Measurements can ha%e

    poor accuracy and poor precision

    good accuracy and poor precision

    poor accuracy and good precision

    good accuracy and good precision

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    40

    Measurements

    Hrefixes and

    =qualities

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    Increase or decrease basic unit by "#

    /orm new units larger or smaller than the basic

    units

    Indicate a numerical %alue

     prefix = value

    " )ilometer 7 "### meters

    " )ilogram 7 "### grams

    41

    Metric Hrefixes

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    42

    Hrefixes that Increase A $nitHrefix Symbol Kalue

    giga9 B " ### ### ###

    mega9 M " ### ###

    )ilo9 ) " ###

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    43

    Hrefixes that Decrease A $nitHrefix Symbol Kalue

    deci9 d #."

    centi9c #.#"

    milli9 m #.##"

    micro9   mu! #.### ##"

    nano n #.### ### ###"

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    Indicate the prefix to use for

    ". + mass that is "### times greater than " gram

    "! )ilo ! milli 5! mega

    . + length that is "L"## of " meter*

    "! deci ! centi 5! milli

    5. + unit of time that is "L"### of a second.

    "! nanosecond ! microsecond 5!millisecond

    44

    &earning Chec)

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    ". "! )ilo

    . ! centi

    5. 5! millisecond

    45

    Solution

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    46

    =qualities 

    State the same measurement in two different units

    length

    "#.# in.

    1.6 cm

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     Lengt

    " m 7 "## cm

     Mass

    " )g 7 "### g

    !olume" &7 "### m&

    47

    Some Metric =qualities

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    +. "### m 7 " AAA  "! mm ! )m 5! dm

    0. #.##" g 7 " AAA "! mg ! )g 5! dg

    C. #." & 7 " AAA  "! m& ! c& 5! d&

    3. #.#" m 7 " AAA "! mm ! cm 5! dm

    48

    &earning Chec)

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    49

    +. "### m 7 " AAA  ! )m

    0. #.##" g 7 " AAA "! mg

    C. #." & 7 " AAA  5! d&

    3. #.#" m 7 " AAA ! cm

    Solution

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    Bi%e the %alue of the following units

    +. " )g 7 AAAA g

    "! "# g ! "## g 5! "### g

    0. " mm 7 AAAA m

    "! #.##" m ! #.#" m 5! #." m 

    50

    &earning Chec)

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    +. " )g 7 AAAA g

    5! "### g

    0. " mm 7 AAAA m

    "! #.##" m

     

    51

    Solution

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    52

    Some +merican =qualities" ft 7 " inches

    " lb 7 ": o@

    " quart 7 pints

    " quart 7 6 cups

    he quantities in each pair gi%e the same

    measured amount in two different units.

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    " in. 7 .16 cm

    " qt 7 E6: m&

    " & 7 ".#: qt

    " lb 7 616 g

    " )g 7 .# lb

     Remember these for exams.

    53

    Some Metric9+merican =qualities

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     "xample #

    +t the store, the price of one pound of red peppers is

    .5E.=quality " lb red peppers 7 .5E

     "xample $ 

    +t the gas station, one gallon of gas is ".56.

     =quality " gallon of gas 7 ".56

    54

    =qualities gi%en in a Hroblem 

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    /ractions in which the numerator and denominator arequantities expressed in an equality between those units

    =xample " in. 7 .16 cm

    /actors " in. and .16 cm

    .16 cm " in.

    55

    Con%ersion /actors

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    Write con%ersion factors that relate each of

    the following pairs of units

    +. &iters and m&

    0. ours and minutes

    3. Meters and )ilometers

    56

    &earning Chec)

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    +. liters and m& " & 7 "### m&

      " & and "### m&

      "### m& " &

    0. hours and minutes " hr 7 :# min

      " hr and :# min

      :# min " hr

    C. meters and )ilometers " )m 7 "### m

      " )m and "### m

    "### m " )m

    57

    Solution

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    58

     Measurements

    Hroblem Sol%ing

    $sing Con%ersion /actors

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    ". + person has a height of .# meters. What is

    that height in inches*

      Initial unit 7 m /inal unit 7 AAAAAAA ! 0lood has a density of #.#1 gLm&. If a person

    lost #.5# pints of blood at "2'C, how many

    ounces of blood would that be*

    Initial 7 pints /inal unit 7 AAAAAAA  

    59

    Initial and /inal $nits

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     Initial unit  .1 hr

      Conversion Final  

      factor unit  .1 hr x :# min 7 "1# min

    " hr

    cancel Answer (2 SF) 

    !

    ow many minutes are in .1 hours*

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    "

    &earning Chec)

    + rattlesna)e is .66 m long. ow long is the

    sna)e in cm*

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    #

    Solution

    + rattlesna)e is .66 m long. ow long is the

    sna)e in cm*

    ! 66 cm

    .66 m x "## cm 7 66 cm

    " m

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    ow many seconds are in ".6 days*

    $

    &earning Chec)

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    $nit plan days hr min seconds

    $ %& "xact 

    ".6 day x 6 hr x :# min x :# sec

      " day " hr " min

      7 ". x "#1 sec

    %

    Solution

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    5

    $nit Chec) 

    What is wrong  with the following setup*

    ".6 day x " day x :# min x :# sec  6 hr " hr " min

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    $nit Chec) 

    ".6 day x " day  x :# min x :# sec

      6 hr " hr " min

    $nits 7 day.

    Lhr.

       Not te final unit needed 

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    +n adult human has 6:1# m& of blood. owmany gallons of blood is that*

     

    &

    &earning Chec)

    S l ti

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    $nit plan  m&  't gallon

    Setup6:1# m& x " qt x " gal 7 ".5 gal

      E6: m& 6 qt

    3 SF 3 SF exact 3 SF 

    8

    Solution

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      4ead problem

      Identify data

      Write down a unit plan from the initial unit

      to the desired unit

      Select con%ersion factors

      Change initial unit to desired unit

      Cancel units and chec) 

      3o math on calculator

      Bi%e an answer using significant figures

    9

    Steps to Hroblem Sol%ing

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    &!

    &earning Chec)

    If the s)i pole is 5.# feet in length, how long is

    the s)i pole in mm*

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    &"

    Solution

    5.# ft x " in x .16 cm x "# mm 7

      " ft " in. " cm

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    &earning Chec)

    If your pace on a treadmill is :1 meters per

    minute, how many seconds will it ta)e for you to

    wal) a distance of 261# feet*

    S l i

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     Initial 

    261# ft x " in. x .16 cm x " m

    " ft " in. "## cm

      x " min x :# sec 7 6## sec

      :1 m " min

     final '$ %&(

    &$

    Solution

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    &%

     Measurements

    3ensity

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    3ensity compares the mass of an object to its

    %olume

    3 7 mass 7 g or g

    %olume m& cm5

    (ote " m& 7 " cm5

    &5

    3ensity

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    &

    &earning Chec) 

    ?smium is a %ery dense metal. What is its

    density in gLcm5 if 1#.## g of the metal occupies

    a %olume of .cm5*

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    &&

    Solution

    ! Hlacing the mass and %olume of the osmium metal

    into the density setup, we obtain

    3 7 mass 7 1#.## g 7

    %olume . cm5

      7 .11 gLcm5 7 .1 gLcm5

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    + solid displaces a matching %olume of waterwhen the solid is placed in water.

     

    55 m&1 m&

    &8

    Kolume 3isplacement

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    What is the density gLcm5! of 62 g of a metal ifthe metal raises the le%el of water in a graduated

    cylinder from 1 m& to 55 m&*

    55 m&

      1 m&

    &9

    &earning Chec)

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    8!

    Solution

    ! : gLcm5

    Kolume m&! of water displaced 

    7 55 m& 9 1 m& 7 2 m&

    Kolume of metal cm5!7 2 m& x " cm5 7 2 cm5

      " m&

    3ensity of metal 7mass 7 62 g 7 : gLcm5

      %olume 2 cm5

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    Which diagram represents the liquid layers in

    the cylinder*

    ;! ;aro syrup ".6 gLm&!, K! %egetable oil

    #.E" gLm&,! W! water ".# gLm&!

    "! ! 5!

    8"

    &earning Chec)5

    W

    W

    W

    K

    K

    K( 

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    ;! ;aro syrup ".6 gLm&!, K! %egetable oil

    #.E" gLm&,! W! water ".# gLm&!

    "!

    8#

    Solution

    W

    K

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      + substance has a density of 5.2 gLm&.

    3ensity 7 5.2 gLm&

    =quality  5.2 g 7 " m&

    Con%ersion factors.5.2 g and " m&

    " m& 5.2 g

    8$

    3ensity as Con%ersion /actors

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    8%

    3ensity Connections

    Mass Kolume

    kg )

    g m) *cm$+

    mg

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    he density of octane, a component of

    gasoline, is #.8# gLm&. What is the

    mass, in )g, of 281 m& of octane*

    85

    &earning Chec)

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    8

    Solution

    "! #.:"6 )g

    $nit plan m& g )g

    =qualities " m& 7 #.8# g and " )g 7 "### g Setup

    281 m& x #.8# g x " )g 7 #.:"6 )g

      " m& "### g

    density metric

     factor factor

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    8&

      &earning Chec)

    If blood has a density of ".#1 gLm&, how

    many liters of blood are donated if 181 g of

    blood are gi%en*

    "!

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    88

    Solution

    "!

    $nit Hlan g m& & 

    181 g x " m& x " & 7 #.162 &

      ".#1 g "### m&

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    , 55.9 kg person disp-aces 5&.# ) of water

    when sumerged in a water tank. What is

    the density of the person in g/cm$?

    89

    12amp-e3

    , 55 9 kg person disp-aces

    4nformation3

    i6en3 m 7 5 59 2 "!% g

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    ,pp-y the so-ution maps0e'uation.

    9!

    , 55.9 kg person disp-aces

    5&.# ) of water when

    sumerged in a water tank.

    What is the density of the person in g/cm$?

    i6en3 m 7 5.59 2 "!% g

    V  7 5. 2 "!% cm$ 

    ind3 density g/cm$

    :o-ution Map3 mV →  

    1'uation3

    $%

    %

    cm"!2.5

    g"!259.5==

    7 !.9&& g/cm$

    7 !.9&& g/cm$

    m  =

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    assignment

    ;ractice0What

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    9#

    &earning Chec) + group of students collected "1 empty

    aluminum cans to ta)e to the recycling center. If

    " cans ma)e ".# pound of aluminum, how many

    liters of aluminum 37.8# gLcm5! are obtained

    from the cans*

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    9$

    Solution

    "! ".# &

    "1 cans x ".# lb x 616 g x " cm5

      " cans " lb .8# g

    x " m& x " & 7 ".# &

      " cm5  "### m&

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    9%

    Hlatinum has become a popular metal for fine jewelry. + man gi%es a

    woman an engagement ring and tells her that it is made of platinum.

    (oting that the ring felt a little light, the woman decides to perform a

    test to determine the ring-s density before gi%ing him an answer

    about marriage. She places the ring on a balance and finds it has a

    mass of 1.26 grams. She then finds that the ring displaces #.11: cm5 

    of water. Is the ring made of platinum* 3ensity Ht 7 ".6 gLcm5!

    Sh l th i b l d fi d it h

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    95

    She places the ring on a balance and finds it has a

    mass of 1.26 grams. She then finds that the ring

    displaces #.11: cm5 of water. Is the ring made ofplatinum* 3ensity Ht 7 ".6 gLcm5!

    Bi%en Mass 7 1.26 grams

      Kolume 7 #.11: cm5

    /ind 3ensity in gramsLcm5

    =quation

    Solution Map

    m and !   d 

     

    m=

    m! V  

     V 

    m=

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    ;ractice0What 4s the =ensity of Meta- if a "!!.! g

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    9&

    y g

    :amp-e ,dded to a Cy-inder of Water Causes the

    Water )e6e- to Rise from #5.! m) to $&.8 m)?

    ind =ensity of Meta- if "!!.! g =isp-aces Waterfrom #5.! to $&.8 m)

    Bi" W i d h Bi i fi

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    from #5.! to $&.8 m)

    nits and magnitude arecorrect.

    Chec)&. Check.

    &.2"#5 g/cm$ 7 &.8" g/cm$4ound. :ignificant figures and round.

    Solution

    < 7 $&.8@#5.!

    7 "#.8 m)

    5. o--ow the so-ution map to

    Sol%e the pro-em.

    Solution

    Map

    %. Write a Solution Map.

    C/ N

    =quation

      g/cm$

    /ind#. Write down the 'uantity youwant to /ind and unit.

     m 7"!!.! g

    disp-aces #5.! to $&.8 m)

    Bi%en". Write down the Bi%en 

    'uantity and its unit.$ sig figs

    $ significant figures

    m! V  

    V m  =

    m  =" m) 7 " cm$

    $$ g/cm#5"8.&cm"#.8

    g!."!!== 

    $$

    cm.8#"m)"

    cm"m)"#.8   =×

    $. Write down the appropriateCon%. /actor and =quation.

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    99

     Measuring )emperature

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    "!!

    emperature

    Harticles are always mo%ing.

    When you heat water, the water molecules mo%e

    faster. 

    When molecules mo%e faster, the substance gets

    hotter.

    When a substance gets hotter, its temperature goes

    up.

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    Suppose you place water in a free@er.

    +. he water particles mo%e

      "! faster ! slower 5! the same

    0. he water will get

      "! hotter ! colder 5! stay the same

    C. he temperature of the water will be

      "! higher ! lower 5! the same

    "!"

    &earning Chec)

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    "!$

    emperature

    Measures the hotness or coldness of an object

    3etermined by using a thermometer that

    contains a liquid that expands with heat andcontracts with cooling.

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      /ahrenheit Celsius ;el%in

    Water boils AAAAA'/ AAAAA'C AAAAAA; 

    Water free@es AAAAA'/ AAAAA'C AAAAAA; 

     

    "!%

    emperature Scales

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      /ahrenheit Celsius ;el%in

    Water boils "'/ "##'C 585 ; 

    Water free@es 5'/ #'C 85 ;

    "!5

    emperature Scales

    $nits of emperature between

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      /ahrenheit Celsius ;el%in

    Water boils "'/ "##'C 585 ; 

      "2#' "##'C "##;  

    Water free@es 5'/ #'C 85 ;

    "!

    p

    0oiling and /ree@ing

    & i Ch )

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    +. emperature of free@ing water

    "! #'/ ! #'C 5! # ; 

    0. emperature of boiling water"! "##'/ ! 5'/ 5! 585; 

    C. (umber of Celsius units between the

      boiling and free@ing points of water

     "! "## ! "2# 5! 85

    "!&

    &earning Chec)

    S l ti

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    +. emperature of free@ing water! #'C

    0. emperature of boiling water5! 585; 

    C. (umber of Celsius units between the

      boiling and free@ing points of water

    "! "##

    "!8

    Solution

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    "!9

    /ahrenheit /ormula

    "2#'/ 7 E'/ 7 ".2'/ "##'C

    1'C "'C

    Dero point  #'C 7 5'/

    '/ 7 EL1 'C  < 5

    or'/ 7 ".2 'C < 5 

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    4earrange to find 'C

    '/ 7 ".2 'C < 5

    '/ 9 5 7 ".2'C

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    + person with hypothermia has a body temperature

    of E."'C. What is the body temperature in '/*

    """

    emperature Con%ersions

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    ""#

    &earning Chec)

    he normal temperature of a chic)adee is "#1.2'/.

    What is that temperature in 'C*

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      5! 6".# 'C

    Solution

    'C 7 '/ 9 5!

      ".2

    7 "#1.2 9 5!

      ".2

    7 85.2'/

    ".2' 7 6".#'C

    ""$

    Solution

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    ""%

    &earning Chec)

    Hi@@a is ba)ed at 611'/. What is that in 'C*

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    ""5

    Solution

    Hi@@a is ba)ed at 611'/. What is that in 'C*

    ! 51'C611 9 5! 7 51'C

      ".2

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    ""

    &earning Chec)

    ?n a cold winter day, the temperature falls to

    9"1'C. What is that temperature in '/*

    "

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    ""&

    Solution

    5! 1'/

    Solution'/ 7 ".29"1'C! < 5

    7 98 < 5

    7 1'/

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    ""8

    ;el%in Scale?n the ;el%in Scale

    "; 7 "'C

    # ; is the lowest temperature

    # ; 7 9 85'C

    ; 'C

    ; 7 'C < 85

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    ""9

    &earning Chec) 

    What is normal body temperature of 58'C in

    )el%ins*

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    What is normal body temperature of 58'C in

    )el%ins*

    ! 5"# ;

    ; 7 'C < 85

    7 58 'C < 857 5"#. ;

    "#!

    Solution

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    "@5 The density of titanium is %.5% g/cm$. What is

    the 6o-ume in mi--i-iters of "$ g of titanium? 5

     pts.

    . #5 A to (e-6in

    &. @#&$ AC to (e-6in

    8. ! A to (e-6in

    9. @#5! A to (e-6in

    "!. $&$ (e-6in @ A

    "#"

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