196183266 Physics Project

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    Project Prepared By:

    Sushruta Dey

    XII A

    Roll Number :46Boards Roll Number:

    Kendriya Vidyalaya Fort William

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    AIM

    To study and

    understand the working

    of a semiconductor.

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    CERTIFICATE

    It is hereby to certify that, the originaland genuine project work has been carried

    out to study about the subject matter and

    the related data collection and

    investigation has been completed solely,

    sincerely and satisfactorily by Sushruta

    Dey of CLASS XII A, Kendriya Vidyalaya

    Fort William , regarding his project titled

    N type ,P Type and working theory of

    semiconductors.

    TeachersSignature

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    Acknowledgement

    It would be my utmost pleasure to express

    my sincere thanks to My Physics Teacher

    Mrs. J Sahooand our dearest Mr. A.K Das

    Sir in providing a helping hand in this

    project. Their valuable guidance, supportand supervision all through this project titled

    N type ,P Type and working theory of

    semiconductors.are responsible for

    attaining its present form.

    Sushruta Dey

    XII A

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    PURPOSEIn recent days, Semiconductors are the most

    used things which are used in electronics, so I

    wanted to know its working.

    Another fact which inspired me to do this

    project is that I am in touch with qualitativeanalysis whose knowledge with other factors

    helped me to do so.

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    CONTENTS

    IntroductionTheory and DefinitionEffect of temperature on conductivity

    of Semiconductor

    Intrinsic SemiconductorsN-type SemiconductorP-type SemiconductorElectrical Resistivity of

    Semiconductors

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    INTRODUCTION

    Most of the solids can be placed in

    one of the two classes: Metals and

    insulators. Metals are those through

    which electric charge can easily flow,

    while insulators are those through which

    electric charge is difficult to flow. This

    distinction between the metals and the

    insulators can be explained on the basis

    of the number of free electrons in them.

    Metals have a large number of free

    electrons which act as charge carriers,

    while insulators have practically no freeelectrons.

    There are however, certain solids

    whose electrical conductivity is

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    Theory and Definition

    Semiconductors are the materials

    whose electrical conductivity lies in

    between metals and insulator. The

    energy band structure of the

    semiconductors is similar to the

    insulators but in their case, the size of

    the forbidden energy gap is much

    smaller than that of the insulator. In

    this class of crystals, the forbidden gap is

    of the order of about 1ev, and the two

    energy bands are distinctly separate

    with no overlapping. At absolute o0, noelectron has any energy even to jump

    the forbidden gap and reach the

    conduction band. Therefore the

    substance is an insulator. But when we

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    heat the crystal and thus provide some

    energy to the atoms and their electrons,

    it becomes an easy matter for some

    electrons to jump the small ( 1 ev)

    energy gap and go to conduction band.

    Thus at higher temperatures, the crystal

    becomes a conductors. This is the

    specific property of the crystal which is

    known as a semiconductor.

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    Effect of temperature on

    conductivity of Semiconductor

    At 0K, all semiconductors are

    insulators. The valence band at absolute

    zero is completely filled and there are no

    free electrons in conduction band. At

    room temperature the electrons jump to

    the conduction band due to the thermal

    energy. When the temperature

    increases, a large number of electrons

    cross over the forbidden gap and jump

    from valence to conduction band. Hence

    conductivity of semiconductor increases

    with temperature.

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    INTRINSIC SEMICONDUCTORS

    Pure semiconductors are called

    intrinsic semi-conductors. In a pure

    semiconductor, each atom behaves as if

    there are 8 electrons in its valence shell

    and therefore the entire material

    behaves as an insulator at low

    temperatures.

    A semiconductor atom needs energy

    of the order of 1.1ev to shake off the

    valence electron. This energy becomes

    available to it even at room

    temperature. Due to thermal agitation

    of crystal structure, electrons from a few

    covalent bonds come out. The bond

    from which electron is freed, a vacancy

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    is created there. The vacancy in the

    covalent bond is called a hole.

    This hole can be filled by some other

    electron in a covalent bond. As an

    electron from covalent bond moves to fill

    the hole, the hole is created in the

    covalent bond from which the electron

    has moved. Since the direction of

    movement of the hole is opposite to thatof the negative electron, a hole behaves

    as a positive charge carrier. Thus, at

    room temperature, a pure

    semiconductor will have electrons andholes wandering in random directions.

    These electrons and holes are called

    intrinsic carriers.

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    As the crystal is neutral, the number

    of free electrons will be equal to the

    number of holes. In an intrinsic

    semiconductor, if ne denotes the electron

    number density in conduction band, nh

    the hole number density in valence band

    and ni the number density or

    concentration of charge carriers, then

    ne

    = nh

    = ni

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    Extrinsic semiconductors

    As the conductivity of intrinsic semi-conductors is poor, so intrinsic semi-

    conductors are of little practical

    importance. The conductivity of pure

    semi-conductor can, however beenormously increased by addition of some

    pentavalent or a trivalent impurity in a

    very small amount (about 1 to parts

    of the semi-conductor). The process ofadding an impurity to a pure

    semiconductor so as to improve its

    conductivity is called doping. Such semi-

    conductors are called extrinsic semi-conductors. Extrinsic semiconductors are

    of two types :

    i) n-type semiconductor

    ii) p-type semiconductor

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    n-type semiconductor

    When an impurity atom belonging to

    group V of the periodic table like Arsenic

    is added to the pure semi-conductor,

    then four of the five impurity electrons

    form covalent bonds by sharing one

    electron with each of the four nearest

    silicon atoms, and fifth electron from

    each impurity atom is almost free to

    conduct electricity. As the pentavalent

    impurity increases the number of free

    electrons, it is called donor impurity. The

    electrons so set free in the silicon crystal

    are called extrinsic carriers and the n-

    type Si-crystal is called n-type extrinsic

    semiconductor. Therefore n-type Si-

    crystal will have a large number of free

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    electrons (majority carriers) and have a

    small number of holes (minority carriers).

    In terms of valence and conduction

    band one can think that all such electrons

    create a donor energy level just below the

    conduction band as shown in figure. As

    the energy gap between donor energy

    level and the conduction band is very

    small, the electrons can easily raise

    themselves to conduction band even at

    room temperature. Hence, the

    conductivity of n-type extrinsic

    semiconductor is markedly increased.

    In a doped or extrinsic semiconductor,

    the number density of the conduction

    band (ne) and the number density of

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    holes in the valence band (nh) differ from

    that in a pure semiconductor. If ni is the

    number density of electrons is conduction

    band, then it is proved that

    ne.nh=

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    p-type semiconductor

    If a trivalent impurity like indium is

    added in pure semi-conductor, the

    impurity atom can provide only three

    valence electrons for covalent bond

    formation. Thus a gap is left in one of

    the covalent bonds. The gap acts as a

    hole that tends to accept electrons. As

    the trivalent impurity atoms accept

    electrons from the silicon crystal, it is

    called acceptor impurity. The holes so

    created are extrinsic carriers and the p-

    type Si-crystal so obtained is called p-

    type extrinsic semiconductor. Again, as

    the pure Si-crystal also possesses a few

    electrons and holes, therefore, the p-type

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    si-crystal will have a large number of

    holes (majority carriers) and a small

    number of electrons (minority carriers).

    It terms of valence and conduction

    band one can think that all such holes

    create an accepter energy level just above

    the top of the valance band as shown in

    figure. The electrons from valence band

    can raise themselves to the accepter

    energy level by absorbing thermal energy

    at room temperature and in turn create

    holes in the valence band.

    Number density of valence band holes

    (nh) in p-type semiconductor is

    approximately equal to that of the

    acceptor atoms (Na) and is very large as

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    compared to the number density of

    conduction band electrons (ne). Thus,

    nh>> Na> > ne

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    Electrical Resistivity of Semiconductors

    Consider a block of semiconductor of length l1area

    of cross-section A and having number density ofelectrons and holes as neand nhrespectively. Suppose

    that on applying a potential difference, say V, a currentI flows through it as shown in figure. The electron

    current (Ic) and the hole current (Ih) constitute the

    current I flowing through the semi conductor i.e.

    I=Ie+Ih (i)

    It neis the number density of conduction band

    electrons in the semiconductor and ve, the drift velocity

    of electrons thenIe= eneAve

    Similarly, the hole current,Ih= enhAvh

    From (i)I = eneAve+ enhAvh

    I = eA(neve+ nhvh) (ii)

    If is the resistivity of the material of thesemiconductor, then the resistance offered by the

    semiconductor to the flow of current is given by :R = l/A (iii)

    Since V = RI, from equation (ii) and (iii) we have

    V = RI = l/A eA (neve + nhvh)

    V= le(neve+nhvh) (iv)

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    If E is the electric field set up across the semiconductor,then:

    E=V/l (v)

    from equation (iv) and (v), we haveE = e (neve+ nhvh)

    1/ = e (neve/E + nhvh/E)On applying electric field, the drift velocity

    acquired by the electrons (or holes) per unit strength ofelectric field is called mobility of electrons (or

    holes). Therefore, mobility of electrons and holes isgiven by :

    e= ve/E and h= vh/E

    1/ =e(ne e+nh h) (vi)Also, = 1/ is called conductivity of the material

    of semiconductor

    =e(ne e+nh h) (vii)The relation (vi) and (vii) show that the

    conductivity and resistivity of a semiconductor depend

    upon the electron and hole number densities and their

    mobilities. As neand nhincreases with rise in

    temperature, therefore, conductivity of semiconductor

    increases with rise in temperature and resistivitydecreases with rise in temperature.