10X121- · Lab Code: ___ Case No.: _ SAS No.: ___ SDG No.: AES02 Matrix (soil/water)-: WATER Lab Sample ID: 2538242 Level (low/med): LOW Date Received: 06/28/96 % Solids:

10X121-

GROUND WATER SAMPLING REPORT

JACK'S CREEK SITE

MIFFLIN COUNTY, PENNSYLVANIA

VOLUME 2TYPE IV INORGANICS DATA PACKAGE

Prepared for submittal to:

United States Environmental Protection AgencyPennsylvania Department of Environmental Protection

Submitted by:

Jack's Creek PRP Group, Technical Committee

August 9, 1996

Alliance Environmental Services, Inc.

Data PackageContract Lab Program Data Package

forAlliance Environmental Svcs.

TYPE IV INORGANICS DATA PACKAGE

Jack's Creek / Sitkin - PAWater Samples

Collected on 06/28/96Sample No. 2538238-2538242

PA Cert. # 36-037NY Cert. # 10670NJ Cert. # 77011

Prepared by _ . _______________ ________CD

Quality Assurance Review _ —^ _____——— 7* cnDate 21 /?(.

Delivery Date <R ]

Lancaster LaboratoriesA Thermo Analytical Laboratory

Lancaster Laboratories • 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 • 717-656-2300 Fax: 717-656-2681

Lancaster LaboratoriesA division of Thermo Analytical Inc.II /)(~li • < ;i, l/.'.'v ;s ,1 ',( -':'/)( r

Sample Reference List for SDG # AES02with a Package Type of IV-I

LabSample sampleNumber Code Client Sample Description

2538238 JC306 GMW-306 Filtered Grab Water Sample2538239 JC206 GMW-206 Filtered Grab Water Sample2538240 JCEIC Eich. Well Filtered Grab Water Sample .2538241 JC305 GMW-305 Filtered Grab Water Sample2538242 JCTBB Trip Blank B Filtered Grab Water Sample

CT»

CT»-=»•CDCOCC .

Shipping Acl'lt'".v1 .I:H j .Id ! r'l-i 'Mi- ui'1.M.'SII.'.v ||..||.ii,,ll'ili Etwiiorirnental-Foods •Pliann.-iceuticals ILincdotiM. PA I 'MM ''!\7-(-rft ?'co i . i « ,7l / r.'.i" .•'."I A îiliîili.nv of Ihonno rwrnlpch Inr , .1 Ihcnno !l<" lion i

TABLE OF CONTENTS

A. Case Narrative-Conformance/Nonconformance Summary............1

B. Sample Data..................................................4

C. Quality Control Data........................................ 10

D. Verification of Instrument Parameters.......................27

E. Preparation and Run Logs....................................38

F. Raw Data....................................................46

1. ICP Data............................................ 47

2. Mercury Data.......................................108

3. Extraction/Distillation/Digestion Logs............. 121

G. Chain-of-Custody Record....................................124

Case NarrativeConformance/Nonconformance Summary

AR30l*95l

Lancaster LaboratoriesA Thermo Analytical LaboratoryWhere quality is a science,

CASE NARRATIVE FOR INORGANICS

Laboratory Name: Lancaster Laboratories

SDG Number: AES02

Date Received: 06/28/96

Calibration Standards;Instrument calibration standards are prepared monthly from stock

solutions purchased from Spex Industries Inc., JT Baker, AldrichChemical, VWR Scientific, EM Science, or VHG Laboratories.

Case Narrative reviewed and approved by:_______Date ~| \ 2x5.1 9k

Diane L. Lockard, Specialist IInorganic Data Packages

Lancaster Laboratories • 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 • 717-656-2300 Fax: 717-656-2681A subsidiary of Thermo Process Systems Inc., a Thermo Electron company flRQflJi Q'-IO

U.S. EPA - CLP

COVER PAGE - INORGANIC ANALYSES DATA PACKAGE

Name: LANCASTER LABORATORIES Contract:

Lab Code: _____ Case No.: _______ SAS No.: _____ SDG No.: AES02SOW No.: ILM04.0

'EPA SAMPLE No. Lab Sample ID._JC206___ _2538239___JC305___ _2538241___JC306____ _2538238___JCEIC___ _2538240__JCTBB 2538242

re ICP interelement corrections applied ? Yes/No YESWere ICP background corrections applied ? Yes/No YES

If yes - were raw data generated beforeapplication of background corrections ? Yes/No NO_

Comments:

I certify that this data package is in compliance with the terms andconditions of the contract, both technically and for completeness, for otherthan the conditions detailed above. Release of the data contained in thishardcopy data package and in the computer-readable data submitted ondiskette has been authorized by the Laboratory Manager or the Manager'sdesignee, as verified by the following signature.

c *C»- >v Name: Diane L. Lockard_____

Date: ____ vy'SCX.V ________ Title: _Specialist I_"inorganic Data Packages

COVER PAGE - IN • ILM04.0

flR30l*953

Sample Data

ran!)

U.S. EPA - CLP

1 EPA SAMPLE NO.INORGANIC ANALYSIS DATA SHEET

JC206Name: LANCASTER LABORATORIES Contract:

Lab Code: _____ Case No.: ________ SAS No.: _____ SDG No.: AES02

Matrix (soil/water). : WATER Lab Sample ID: 2538239

Level (low/med): LOW Date Received: 06/28/96

% Solids: 0.0

Concentration Units (ug/L or mg/kg dry weight): UG/L__

GAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-07440-66-6

Analyte

AluminumAntimonyArsenicBerylliumCadmiumChromiumCopperLeadManganeseMercuryNickelSeleniumSilverThalliumZinc

Concentration

77.31.91.90.560.630.582.62.2208

0.0211.32.30.723.411.5

C

BUUUBUBU

UUUUUB

Q

N

M

PPPPPPPPPCVPPPPP

Color Before: COLORLESS_ Clarity Before: CLEAR____ Texture:

Color After: COLORLESS_ Clarity After: CLEAR____ Artifacts:

Comments:

FORM I - IN ILM04.0

5AR30lf955

U.S. EPA - CLP


JC305Lab Name: LANCASTER LABORATORIES Contract:


Matrix (soil/water): WATER Lab Sample ID: 2538241


% Solids: 0.0


CAS NO.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-3.7440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-97440-66-6

Analyte


Concentration

41.21.91.90.560.383.02.72.20.250.0211.32.30.723.48.7

C

UUUUUBBUBUUUUUB

Q

N

M

PPPPPPPPPCVPPPPP



Comments:

FORM I - IN ILM04.0

ftR30i»956

U.S. EPA - CLP


KUDJC306


Lab Code: _____ Case No. : _______ SAS No.: _____ SDG No.: AES02



% Solids: 0.0


GAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-07440-66-6

Analyte


Concentration

41.21.91.9

0.560.460.585.22.22.1

0.0211.42.3

0.723.4

16.7

C

UUUUBUBUBUBUUUB

Q

N

M

PPPPPPPPPCVPPPPP



Comments:

FORM I - IN ILM04.0

AR304957

U.S. EPA - CLP


JCEICLab Name: LANCASTER LABORATORIES Contract:

Lab Code: _____ Case No. : ________ SAS No.: _____ SDG No.: AES02



% Solids: 0.0

Concentration Units (ug/L or rag/kg dry weight): UG/L__

GAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-97440-66-6

Analyte


Concentration

41.2• 1.91.9

0.560.380.581.72.2

0.510.0211.32.3

0.723.4

10.9

C

UUUUUUBUBUUUUUB

Q

N

M

PPPPPPPPPCVPPPPP



Comments:

FORM I - IN ILM04.0

8

ftR30l*958

U.S. EPA - CLP


JCTBBLab Name: LANCASTER LABORATORIES Contract:

Lab Code: _____ Case No.: _______ SAS No.: _____ SDG No.: AES02

Matrix (soil/water)-: WATER Lab Sample ID: 2538242


% Solids: 0.0


GAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-67440-66-6

Analyte


Concentration

41.21.91.90.560.380.580.742.20.180.0211.32.30.723.42.8

C

UUUUUUBUUUUUUUB

Q

N

M

PPPPPPPPPCVPPPPP



Comments:

FORM I - IN ILM04.0

• •• 9AR30(*959

Quality Control Data

10AR30W60

U.S. EPA - CLP

2AINITIAL AND CONTINUING CALIBRATION VERIFICATION


Lab Code: _____ Case JNo. : _______ SAS No.: _____ SDG No.: AES02

Cnitial Calibration Source: LLI_____-

Continuing Calibration Source: LLI

Concentration Units: ug/L

1Analyte

AluminumAntimonyArsenicBerylliumCadmiumChromiumCopperLeadManganeseMercuryNickel•eleniumRiverThalliumZinc—— . ———— . —

Initial CalibrationTrue Found %R(1)

30000.0600.0600.0600.0600.0600.0600.0600.0600.02.0

600.0600.0600.0600.0600.0

30165.97625.98616.04596.43601.15619.02613.54592.38600.90

1.99601.29587.88613.346Q1.09599.19

100.6104.3102.799.4100.2103.2102.398.7100.299.5100.298.0102.2100.299.9

Continuing CalibrationTrue Found %R(1) , Found %R(1)

25000.0500.0500.0500.0500.0500.0500.0500.0500.01.0

500.0500.0500.0500.0500.0

25412.35506.56502.33481.59488.19505.10504.78501.29492.331.04

493.72506.94503.89500.33486.88

101.6101.3100.596.397.6101.0101.0100.398.5104.098.7101.4100.8100.197.4

25519.97508.69503.97480.55483.76501.89512.26510.38490.831.04

489.07509.77502.34502.27483.02

102.1101.7100.896.196.8100.4102.5102.198.2104.097.8102.0100.5100.596.6

M

P~PPPPPPPPCVPPPPP

(1) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115

FORM II (PART 1) - IN ILM04.0

SIAR30l»96l

U.S. EPA - CLP


Lab Name: LANCASTER LABORATORIES Contract:


Initial Calibration Source: LLI____'

Continuing Calibration Source: LLI_______


Analyte

AluminumAntimonyArsenicBerylliumCadmiumChromiumCopperLeadManganeseMercuryNickelSeleniumSilverThallium_Zinc


Continuing CalibrationTrue Found %R(1) Found %R(1)

25000.0500.0500.0500.0500.0500.0500.0500.0500.01.0

500.0500.0500.0500.0500.0

25415.00499.00470.01470.23480.39508.63521.95509.93495.23

1.03486.22507.76497.25472.95466.13

101.799.894.094.096.1101.7104.4102.099.0103.097.2101.699.494.693.2

1.01

————

101.0

M

P~PPPPPPPPCVP_

PP_



AR30U962

U.S. EPA - CLP




Initial Calibration Source: LLI________

Continuing Calibration Source: LLI______


Analyte

AluminumAntimony_Arsenic _BerylliumCadmium _ChromiumCopperLeadManganeseMercuryNickelSteleniumBilverThalliumZinc


«


1.0 1.02

— ——

102.0 1.03 103.0

M

NRNRNRNRNRNRNRNRNRCVNRNRNRNRNR



13Afl30l»963

U.S. EPA - CLP

2BCRDL STANDARD FOR AA AND ICP



\A CRDL Standard Source: LLI________

ICP CRDL Standard Source: LLI


Analyte


CRDL SI

True

0.2

:andard fo]

Found

0.17

r AA

%R

85.0

True

120.020.010.010.020.050.06.0

30.0

80.010.020.020.040.0

CRDL StarInitialFound

124.3421.209.6410.0020.5151.615.3230.46

81.9110.5020.3820.3241.54

idard J

%R

103.6106.096.4100.0102.6103.288.7101.5

102.4105.0101.9101.6103.8

for ICPFinal

Found

127.1519.968.569.9920.3053.905.8930.51

80.6111.7320.2819.3642.45

%R

106.099.885.699.9101.5107.898.2101.7

100.8117.3101.496.8106.1


14

' i

U.S. EPA - CLP

3BLANKS

Lab Name: LANCASTER LABORATORIES ' Contract:


Preparation Blank Matrix (soil/water): WATER_

Preparation Blank Concentration Units (ug/L or mg/kg): UG/L_

Analyte

AluminumAntimonyArsenicBerylliumCadmiumChromiumCopperLeadManganeseMercuryIjickelPeleniumSilverThalliumZinc

InitialCalib.Blank(ug/L) c

41.21.91.90.560.380.580.482.20.180.0211.32.30.723.41.1

UUUUUUUUUUUUUUU

Continuing CalibrationBlank (ug/L)

1 C 2 C 3 C

1011.91.9

-0.700.380.580.482.20.180.0211.32.30.723.41.1

BUUBUUUUUUUUUUU

41.21.91.9-1.20.380.580.482.20.180.0211.32.30.723.41.1

UUUBUUUUUUUUUUU

41.21.91.90.560.380.581.42.20.180.0211.32.30.723.41.1

UUUUUUBUUUUUUUU

Prepa-rationBlank C

64.8701.9001.900-0.8800.3800.5800.4802.2000.1800.0251.3002.3000.7203.4002.260

BUUBUUUUUBUUUUB

M

PPPPPPPPPCVPPPPP

FORM III - IN ILM04.0

15AR30U965

U.S. EPA - CLP

3BLANKS


Lab Code: _______ Case No.: _______ SAS No.: _____ SDG No.: AES02

Preparation Blank Matrix (soil/water): ________

Preparation Blank Concentration Units (ug/L or mg/kg):

Analyte

AluminumAntimonyArsenicBerylliumCadmium _ChromiumCopper .LeadManganeseMercuryNickelSeleniumSilverThalliumZinc

InitialCalib.Blank(ug/L) C

—

—

—


1 C 2 C 3 C

0.021

—

U

—

0.021 U . 0.021U

—

—

Prepa-rationBlank C M



16AR30l»966

U.S. EPA - CLP

4ICP INTERFERENCE CHECK SAMPLE


Lab Code: _____ Case^No.: _______ SAS No.: _____ SDG No.: AES02

ICP ID Number: 05478______ ICS Source: LLI_________


Analyte

AluminumAntimonyArsenicBerylliumCadmiumCalciumChromiumCopperIronLeadMagnesiumManganeseMercury||ickel•PeleniumSilverThalliumZinc

TrueSol. Sol.A AB

5000000000

50000000

200000

5000000

0

000

500000600100500

1000500000

500500

200000

500000500

1000

200100

1000

Initial FoundSol. Sol.A AB %R

513320-1-3010

5070831

-2205843

5194034

-4

0810

520797.8621.8103.7463.8928.7

502051.0486.0559.4

204458.4

522529.0477.8

927.2

212.399.0966.9

104.2103.6103.792.892.9

100.497.2

111.9102.2

104.595.6

92.7

106.299.096.7

Final FoundSol. Sol.A AB '%R

525471-4-6-110

4989981-1

209282

5248754

-3

0310

530236.8629.698.6466.2925.0

505497.9486.0568.4

211602.4

530059.0478.7

924.3

211.9103.6962.5

106.0104.998.693.292,5

101.197.2

113.7105.8

106.095.7

92.4

106.0103.696.2

FORM IV - IN ILM04.0

17AR30l*967

U.S. EPA - CLP



Lab Code: _____ Case No.: _______ SAS NO.: _____ SDG No.: AES02

ICP ID Number: 05936______ ICS Source: LLI_______


Analyte

AluminumÂntimonyArsenic _BerylliumCadmiumCalcium _ChromiumCopperIronLeadMagnesiumManganeseMercuryNickelSeleniumSilverThallium_Zinc

TrueSol. Sol.A AB

500000

500000

2000000

500000

0

__ 500000

__ 500000

20000050

__ 500000

50


_ 536300

_ 522710

2114665

__ 549547

5

530052.7

509021.0

207251.257.4

540061.0

53.9

106.0

101.8

103.6114.8108.0

107.8

Final FoundSol. Sol.A AB '%R

__ 509361

_ 519014

2068083

__ 533825

5

526238.4

526075.3

210986.255.6

546172.5

57.1

105.2

105.2

105.5111.2109.2

114.2


18AR30(,968

U.S. EPA - CLP

5A EPA SAMPLE NO.SPIKE SAMPLE RECOVERY

*38140SLab Name: LANCASTER LABORATORIES Contract:


Matrix (soil/water): WATER_____ _. . . . . . Level (low/med) : LOW

% Solids for Sample: 0.0

Concentration Units (ug/L or mg/kg dry weight): UG/L_____

'Analyte

AluminumAntimonyArsenicBerylliumCadmiumChromiumCopperLeadManganeseMercuryJickel•feleniumSilverThalliumZinc

ControlLimit%R

75-125

Spiked SampleResult (SSR)

0.9960

CSample

Result (SR)

0.0290

C

B

SpikeAdded (SA)

1.00

%R

96.7

Q M


Comments:

FORM V (PART 1) - IN ILM04.0

A-R30I»969

U.S. EPA - CLP


JC306SLab Name: LANCASTER LABORATORIES Contract:


Matrix (soil/water): WATER_____ Level (low/med): LOW



Analyte


ControlLimit

%R

75-12575-12575-12575-12575-12575-12575-12575-12575-125

75-12575-12575-12575-12575-125


2247.6200510.040046.030046.650047.8300200.1600265.230021.8600489.6900

490.600012.800051.310050.4400498.0700

CSample

Result (SR)

41.20001.90001.90000.56000.46000.58005.18002.20002.1400

1.35002.30000.72003.400016.7400

C

UUUUBUBUB

BUUUB

SpikeAdded (SA)

2000.00500.0040.0050.0050.00200.00250.0020.00500.00

500.0010.0050.0050.00500.00

%R*

112.4102.0115.193.394.7100.1104.0109.397.5

97.8128.0102.6100.996.3

Q

N

M

PPPPPPPPPNRP4p^plp

Comments:

i


U.S. EPA - CLP

5B EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY

JC306ALab Name: LANCASTER LABORATORIES Contract:

Lab Code: _____ _ Case No.: _______ SAS No.: _____ SDG No.: AES02

Matrix (soil/water)": WATER_____ Level (low/med) : LOW


<

Analyte

AluminumAntimonyArsenicBerylliumCadmiumChromiumCopperLeadManganeseMercuryNickelSeleniumSilver•ha IliumWine

ControlLimit%R


11.65

CSample

Result (SR)

2.30

C

U

SpikeAdded (SA)

10.0

%R

116.5

Q M

NRNRNRNRNRNRNRNRNRNRNRPNRNRNR

Comments\


31AR30I»97I

U.S. EPA - CLP

6 EPA SAMPLE NO.DUPLICATES

*38140DLab Name: LANCASTER LABORATORIES Contract:


Matrix (soil/water) : WATER_____ Level (low/med) : LOW

% Solids for Sample: 0.0 % Solids for Duplicate: 0.0


Analyte


ControlLimit

.

Sample (S)

0.0290

C

B

Duplicate (D)

0.0210

C

U

RPD

200.0

Q M


FORM VI - IN ILM04.0

22AR30l»972

U.S. EPA - CLP


_ JC306DLab Name: LANCASTER LABORATORIES Contract:


Matrix (soil/water>: WATER_____ Level (low/med): LOW



Analyte


ControlLimit Sample (S)

41.20001.90001.90000.56000.46000.58005.18002.20002.1400

1.35002.30000.72003.400016.7400

C

UUUUBUBUB

BUUUB

Duplicate (D)

44.87001.90001.90000.56000.38000.58005.39002.2-0002.6100

1.62002.30000.72003.400016.7900

C

BUUUUUBUB

BUUUB

RPD

200.0

200.0

4.0

19.8

18.2

0.3

Q M

PPPPPPPPPNRPPPPP


AB30I»973

U.S. EPA - CLP

7LABORATORY CONTROL SAMPLE



Solid LCS Source: -

Aqueous LCS Source: LLI_

Analyte

AluminumAntimonyArsenicBerylliumCadmiumChromium_CopperLeadManganeseMercuryNickelSeleniumSilverThalliumZinc

Aqueous (ug/L)True Found %R

2000.0500.02000.050.050.0200.0250.050.0.0500.01.0

500.02000.050.0

2000.0500.0

2110.21520.812017.8048.4048.79205.06256.42506.05499.241.03

502.972028.2251.03

2026.66491.81

105.5104.2100.996.897.6102.5102.6101.299.8103.0100.6101.4102.1101.398.4

Solid (mg/kg)True Found C Limits %R

.

FORM VII - IN ILM04.0

24AR301*97l»

U.S. EPA - CLP

8STANDARD ADDITION RESULTS

Contract:

Lab Code : Case No . : SAS No. : SDG No. : .?


EPASampleNo.

P=

An

—

—

—

—

—

—

—

0 ADDABS

1 ADDCON ABS

*

2 ADDCON ABS

3 ADDCON ABS

FinalCone.

.

r Q

—

—

—

—

—

—

—

—

—

FORM VIII - IN . ILM04.0

25AR3Qlt975

U.S. EPA - CLP

9 EPA SAMPLE NO.ICP SERIAL DILUTIONS


Lab Code: _____ Case No.: •_____ SAS No.: _____ SDG No.: AES02

Matrix (soil/water\ : WATER________ Level (low/med) : LOW_


Analyte


Initial SampleResult (I)

41.201.901.900.560.460.585.182.202.14

1.352.300.723.40

16.74*

C

UUUUBUBUB

BUUUB

SerialDilutionResult (S)

206.009.509.502.801.902.906.45

11.009.45

10.8511.50

3.6017.0047.05

C

UUUUUUBUB

BUUUB

%Differ-ence

100.0

24.5

341.6

703.7

181.1

Q M

PPPPPPPPP

PPPPP

FORM IX - IN ILM04.0

26AR30I*976

Verification of Instrument Parameters

27ftE30l»977

U.S. EPA - CLP

10INSTRUMENT DETECTION LIMITS (QUARTERLY)


Lab Code: _____ Case No.: _______ SAS No.: _____ SDG No.: AES02.

ICP ID Number: . __________ Date: 04/15/96

Flame AA ID Number: __05220___

Furnace AA ID Number:

Comments:

Analyte


Wave-length(nm)

254.00

Back-ground

CRDL(ug/L)

0.2

IDL(ug/L)

0.021

M


FORM X - IN ILM04.0

28AR30U978

U.S. EPA - CLP



Lab Code: _____ Case No.: ________ SAS No.: _____ SDG No.: AES02_

ICP ID Number: . __05478___ Date: 07/15/96

Flame AA ID Number: __________


AnalyteAluminumAntimonyArsenicBerylliumCadmiumChromiumCopperLeadManganeseMercuryNickelSeleniumSilverThalliumZinc

Wave-length(nm)

308.21206.83189.04313.04226.50267.71324.75

257.61

231.60

328.06190.86213.85

Back-ground

CRDL(ug/L)

2006010551025

15

40

101020

IDL(ug/L)

41.21.91.9

0.560.380.580.48

0.18

1.3

0.723.41.1

M

PPPPPPPNRPNRPNRPPP

Comments:

FORM X - IN ILM04.0

'29AR30l»979

U.S. EPA - CLP


Lab Name: LANCASTER_LABORATORIES__ Contract: _________ ^^


ICP ID Number: - __05936___ Date: 07/15/96



Comments:

Analyte


Wave-length(nm)

220.35

196.02

Back-ground

CRDL(ug/L)

3

5

IDL(ug/L)

2.2

2.3

M

NRNRNRNRNRNRNRPNRNRNRPNRNRNR

FORM X - IN ILM04.0

30AR301t980

U.S. EPA - CLP

11AICP INTERELEMENT CORRECTION FACTORS (ANNUALLY)

Name: LANCASTER LABORATORIES ; Contract:


ECP ID Number: __Q5478 __ Date: 09/19/95

Analyte

AluminumAntimonylAntimony2Arsenic _BerylliumCadmium _ChromiumCopperLeadlLead2ManganeseMercuryNickel^LeleniumlHfclenium2pilverThalliumZinc

Wave-length(nm)308.21206.83206.83189.04313.04226.50267.71324.75

__ 257.61

231.60

328.06190.86213.85

In1

Al

0.00000000.00000000.00000400.00000000.0000000-0.00000100.00000000.0000000'

-0.0000020

0.0000000

O.QOOOOOO-0.00001500.0000050

terelement (

Ca

0.00000000.0000000o.oOoooooo.oOooooo0.00000000.00000000.00000000.0000000

_0. 0000000

0.0000000

0.00000000.00000000.0000000

Correction ]Fe

0.00000000.00002900.00002600.00001000.00000000.00009900.00001500.0000140

_0. 0000000

0.0000220

0.0000000-0.00005200.0001130

Factors forMg

0.00000000.00000000.00000000.00000000.00000000.00000000.00000000.0000000

_0. 0000000

0.0000000

0.00000000.00000000.0000180

••

CO

0.00000000.00000000.00000000.00000000.0000000-0.00018100.00000000.0000000

_0. 0000000

-0.0004610

0.00000000.00333200.0000000

Comments:

FORM XI (PART 1) - IN ILM04.0

31AR30I*98I

U.S. EPA - CLP



Lab Code: _____ Case No. : _______ SAS No. : _____ SDG No. : AES02

ICP ID Number: __05936 __ Date: 09/19/95

Analyte

AluminumAntimonylAntimony 2ArsenicBerylliumCadmiumChromiumCopperLeadlLead2ManganeseMercuryNickelSeleniumlSelenium2SilverThalliumZinc

Wave-length(nm)

220.35220.35

196.02__ 196.02

Int

Al

0.0001270-0.0001270

0.0000000_0. 0000000

:erelement C

Ca

0.00000000.0000000

0.0000000_0. 0000000

Correction I

Fe

0.00010300.0000490

-0.0000250-0.0003900

factors for-

Mg

0.00000000.0000000

0.0000000_0. 0000000

CO

0.00046000.0000000

0.0003320-0.0011980

Comments:


32

U.S. EPA - CLP

11BICP INTERELEMENT CORRECTION FACTORS (ANNUALLY)

Lab Name: LANCASTER LABORATORIES Contract:Lab Code: _____ Case No.: ________ SAS No.: _____ SDG No.: AES02

ICP ID Number: _ 05478 __ Date: 09/19/95

AnalyteAluminum_AntimonylAntimony2Arsenic _BerylliumCadmium _Chromium_CopperLeadlLead2ManganeseMercuryNickelfcseleniumlSelenium2SilverThalliumZinc

Wave-length(nm)

308.21206.83206.83189.04313.04226.50267.71

__ 324.75

__ 257.61

231.60

328.06190.86213.85

Ini

CR

0.00000000.00900000.0019640-0.00683300.00000000.00000000.0000000

_0. 0000000

-0.0000180

0.0000000

^

0.00001200.00030200.0000000

:erelement C

CU0.00000000.00000000.00000000.00000000.00000000.00000000.0000000

_0. 0000000

_0. 0000000

0.0000000

0.00000000.00000000.0012170

:orrection I

MN

0.00000000.0000000O.OOOOOOO0.00000000.0000000'0.00000000.0001250

_0. 0000000

_0;0000000

0.0000000

-0.00010300.00016500.0000000

âctors for

MO

0.0000000-0.0026820-0.0044830-0.00477100.0000000-0.00005800.0000000

_0. 0000000

_0. 0000000

0.0000000

-0.0005270-0.00158900.0000000

t»

NI

0.0000000-0.00186100.00000000.00000000.00000000.00000000.0000000

_0. 0000000

_0. 0000000

0.0000000

0.00000000.00000000.0048470

•

Comments:


33AR30i*983

U.S. EPA - CLP





Analyte

Aluminum_AntimonylAntimony2Arsenic _BerylliumCadmium _Chromium_CopperLeadlLead2ManganeseMercuryNickelSeleniumlSelenium2SilverThalliumZinc

Wave-length(nm)

308.21206.83206.83189.04313.04226.50267.71324.75

__ 257.61

231.60

328.06190.86213.85

Ini

TI

0.00000000.00037000.00005700.00000000.00000000.00000000.00000000.0000000

_0. 0000000

0.0000000

*

0.00000000.00014500.0000000

:erelement C

V

0.0258500-0.00431300.00000000.00000000.00039000.00000000.00000000.0000000

_0. 0000000

0.0000000

0.00004800.00186000.0000000

Correction I

0.00000000.00000000.00000000.00000000.00000000.00000000.00000000.0000000

_0. 0000000

0.0000000

0.00000000.00000000.0000000

-'actors for'

0.00000000.00000000.00000000.00000000.00000000.00000000.00000000.0000000

_0. 0000000

0.0000000

0.00000000.00000000.0000000

0.00000000.00000000.00000000.00000000.00000000.00000000.00000000.0000000

_0. 0000000

0.0000000

0.00000000.00000000.0000000

Comments:


34AR30l*98l*

U.S. EPA - CLP


Lab Name: LANCASTER LABORATORIES__ Contract:


CCP ID Number: __0~5936 __ Date: 09/19/95

Analyte

AluminumAntimonylAntimony2ArsenicBerylliumCadmiumChromiumCopperLeadlLead2 _ _ManganeseMercuryickelKleniumlelenium2SilverThalliumZinc

Wave-length(nm)

220.35__ 220.35

196.02~196.02

In1CR

0.0000000_0. 0000000

0.0000710-O.Q000920

:erelement (

MN

0.0001030_0. 0000940

0.0003840_0. 0001860

:orrection ]

MO

0.0000000-0.0010160

-0.0007000_0. 0000000

factors for

TI

0.0007750-0.0008340

0.0000000_0. 0000000

»»

V

0.0000000-0.0001500

0.0001670-0.0001100

Comments:

FORM XI (PART 2) - IN , ILM04.0

35Afi30(,985

U.S. EPA - CLP

12ICP LINEAR RANGES (QUARTERLY)



ICP ID Number: __05478___ Date: 07/15/96

Analyte

AluminumAntimonyArsenicBerylliumCadmiumChromiumCopperLeadManganeseMercuryNickelSeleniumSilverThalliumZinc -

Integ .Time •(Sec.)

10.0010.0010.0010.0010.0010.0010.00

10.00

10.00

10.0010.0010.00

Concentration(ug/L)

600000.050000.020000.05000.020000.0100000.050000.0

50000.0

'50000.0

5000.010000.05000.0

M

PPPPPPPNRPNRPNRPPP

Comments:

FORM XII - IN ILM04.0

36

U.S. EPA - CLP

'12ICP LINEAR RANGES (QUARTERLY)


Lab Code: ____ Case No.: _______ SAS No.: ____ SDG No.: AES02_ICP ID Number: __05936___ Date: 07/15/96

Comments:

Analyte

AluminumAntimonyArsenicBerylliumCadmiumChromiumCopperLeadManganeseMercuryNickelSeleniumSilverThalliumZinc *

Integ.Time(Sec.)

10.00

10.00

Concentration(ug/L)

50000.0

10000.0

M

NRNRNRNRNRNRNRPNRNRNRPNRNRNR


37

Preparation and Run Logs

38

U.S. EPA - CLP

13PREPARATION LOG


Lab Code: _____ Case No.: _____' SAS No.: _____ SDG No.: AES02

Method: P

EPASampleNo.

JC206JC305JC306JC306DJC306SJCEICJCTBBLCSWPBW

PreparationDate

07/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/96

Weight(gram)

Volume(ml)

100100100100100100100100100

FORM XIII - IN. ILM04.0

33

U.S. EPA - CLP

.13PREPARATION LOG



Method: CV

EPASampleNo.

*38140*38140D*38140SJC206JC305JC306JCEICJCTBBLCSWPBW

PreparationDate

07/04/9607/04/9607/04/9607/04/9607/04/9607/04/9607/04/9607/04/9607/04/9607/04/96

Weight(gram)

Volume(ml)

8888888888

FORM XIII - IN ILM04.0

40AR30I»990

U.S. EPA - CLP

14

ANALYSIS RUN LOG


Lab Code: _____ _ Case No.: _______ SAS No.: _____ SDG No.: AES02_

Instrument ID Number: 05478_ Method: P_

Start Date: 07/15/96 ;. End Date: 07/15/96

1

EPASampleNo.

SOSsSICVICBCRIICSAICSABCCVCCBPBWkcswUC306JC306AJC306DJC306SJC306LJC206JCEICJC305CCVCCB•JCTBBCRIICSAICSABCCVCCB

D/F

1.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.005.001.001.001.001.001.001.001.001.001.001.001.00

Time

08100815082008240828083308380843084808530858090309080913,091809230928093309380943094809530958100310081013101810231028

% R AL

XX

XX

XXXXXXX

XXXXXXXXX

XXXX

sB

X

XXXXXXXXXXX

XXXXXXXXXXXXXX

AsX

X

XXXXXXXXXX

XXXXXXXXXXXXXX

BE

X

X

XXXXXXXXXX

XXXXXXXXXXXXXX

cD

X

X

XXXXXXXXXX

XXXXXXXXXXXXXX

cR

X

XXXXXXXXXXX

XXXXXXXXXXXXXX

cU

X

X

XXXXXXXXXX

XXXXXXXXXXXXXX

pBMN

X

X

XXXXXXXXXX

XXXXXXXXXXXXXX

Al

HG

aaJ

NIX

X

XXXXXXXXXX

XXXXXXXXXXXXXX

Ly1

sE

:es

AG

X

X

XXXXXXXXXX

XXXXXXXXXXXXXX

5

TL

X

X

XXXXXXXXXX

XXXXXXXXXXXXXX

zN

X

X

XXXXXXXXXX

XXXXXXXXXXXXXX

A.830W9I

U.S. EPA - CLP

14

ANALYSIS RUN LOG


Lab Code: _____ ^ Case No.: _______ SAS No.: _____ SDG No.: AES02_

Instrument ID Number: 05936_ Method: P_

Start Date: 07/17/96 End Date: 07/17/96

EPASampleNo.

SOSSSICVICBCRIICSAICSABCCVCCBPBWLCSWJC306JC306AJC306DJC306SJC306LJC206JCEICJC305CCVCCBJCTBBCRIICSAICSABCCV 'CCB

D/F

1.001.001.001.001.001.001.001.001.001.00

. 1.001.001.001.001.001.001.005.001.001.001.001.001.001.001.001.001.001.001.00

Time

18171822182618301833183718421846185018551859190419081912.191719211926193019341939194319481952195620012005200920142018

% R ALSBAS

BECDCRCUPB

X

X

XXXXXXXXXX

XXXXXXXXXXXXXX

MN

ArHG

iaJ

NI

-ytsE

X

X

XXXXXXXXXXXXXXXXXXXXXXXXX

:es

AGTLZN

-

|'

FORM XIV - IN ILM04.0

42

I 5? I

U.S. EPA - CLP

• 14

ANALYSIS RUN LOG


Lab Code: ____ . Case No.: _______ SAS No.: ____ SDG No.: AES02_Instrument ID Number: 05220_ Method: CV


EPASampleNo.

SOSO. 2SO. 5Sl.OS2.5S5.0ICVICBCRACCVCCBZZZZZZIzzzzzzZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZCCVCCBZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZ

D/F

1.001.001.001.001.001.001.001.001.001.001.001.001.0010.001.001.001.001.001.001.001.001.001.001.001.001.001.001.0010.001.001.001.00

Time

14551458150015021505150715101513151515171520152215241526.1529153115331535153815401542154515471549155215541556155916011603160.61608

% R ALSB

1

ASBECDCRCUPBMN

Ai

HG

XXXXXXXXXXX

XX

ia.

NI

Ly1

SE

;es

AG

5

TLZN


A-R30U993

U.S. EPA - CLP

14

ANALYSIS RUN LOG


Lab Code: _____ _ Case No.: _______ SAS No.: ____ SDG No.: AES02_

Instrument ID Number: 05220__ Method: CV


EPASampleNo.

ZZZZZZCCVCCBZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZPBWLCSWZZZZZZ*38140CCVCCB*38140D*38140SZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZCCVCCBZZZZZZZZZZZZZZZZZZJC306JC206

D/F

1.001.001.001.001.001.001.0010.00100.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.00

Time

16111613161516181620162216241627162916311633163616381640.164216451647164916511653165616581700170217051707170917111714171617181720

% R

Analytes

ALSBAS

BECDCRCUPBMNHG

XX

XX

XXXXX

XX

XX

NISEAGTLZN

(11


44

U.S. EPA - CLP

14

ANALYSIS RUN LOG

Name: LANCASTER LABORATORIES . • Contract:

"Lab Code: _____ Case No.: ________ SAS No.: _____ SDG No.: AES02_

Instrument ID Number: 05220_ Method: CV


EPASampleNo.

JCEICJC305JCTBBCCVCCB

D/F

1.001.001.001.001.00

Time

17231725172717291732

% R ALSBAS

BECDCRCUPBMN

Al

HG

XXXXX

laJ

NI

Ly1

SE

:es

AG

3

TLZN

FORM XIV - IN , ILM04.0

AR30l*995

Raw Data

46AR3QI+996

ICP Data

47AR 301*997

Page: 1

Lancaster Laboratories

Data Reviewed By ri

~Data-Verified By: y]/Y///jF OAJ y/

Data File Name: 19703T61.DA'

Analyst: 243 </ Run Name: 9619703T61

Instrument Parameters:

Rinse Time: 60 secIndividual Integration Time: 10 sec.Total Integration Time: 30 'sec

Element Symbol Element Name Wavelen'gth(nm)Ag • Silver . 328.06Al , • Aluminum . 308.21As Arsenic _ 189.04Ba Barium 493.40Ba ' Beryllium 313.04,Ca Calcium 317.93Cd Cadmium 226.5OCo ' Cobalt . ' 228.61

• Cr Chromium - 267.71Cu Copper 324.75Fa • • iron ' 271.44K Potassium • 766.49Mg Magnesium- 279.07Mrv Manganese 257.61Mo '- Molybdenum 2O2.O3Na ' Sodium 330.23Ni . Nickel 231.60Pb . Lead 220.35/1Pb Lead ' 220.35/2.Sb Antimony . 206.83/1Sb Antimony 206.83/2So ' Selenium 196.02/1So Selenium 196/02/2 . .3n • . Tin 189.98Ti Titanium 334.94Tl Thallium 19O.86V • Vanadium 292.40Y ' . Yttrium 371.O3Zn • • Zinc 213.85

Th'e 61E TRACE ICP uses _ a C rawf ord-Kunsalman Noise ReductionTechnique for lead, antimony, and selenium. This requires the utilizationof the first and'second order wavelengths' in the calculation of each of thesemetal determinations. The 61E TRACE ICP also utilizes Yttrium as an internalstandard 'to compensate for fluctuations iri nebulization and plasma conditions,All Yttrium readings are expressed in counts.

Page: 2 •

LANCASTER LABORATORIES

Run Name: 9619703T61 ' , INSTRUMENT ID: 054T

Tube: 1 . SO 07/15/96 08:10

AVG. • CONC INTENSITY INTEGRATIONS

ELEM (ppm) . RATIO . %RSD " #1 #2 #3

__Ag • 0.000 -0.00035 7.695 -6.00031 -0.00036 -0.00036. Al 0.000 0.00999 0.235 0.00997 0.00998 0.01001

__As O.OOO . -0.00051 5.387 _ -0.00052 -0.00052 -0.00047__Ba 0.000 0.00016 4.512 ' 0.00017 ' 0.00015 0.00015__Be O.OOO -0.07526 0.121 -0.07521 -0.07521 ' -0.07536__Ca •' 0.000 -0.00085 0.573 -0.00085 -0.00086 -0.00085__Cd O.OOO 0.00029 6.741 0.00031 0.00029 0.00027._Co. 0.000 -0.00028 14.53 -0.00030.. -0.00023 -0.00030__Cr . 0,000 0.00004 93.80 0.00005' 0.00000 ' 0.00008__Cu ' O.OOO. •« -0.00244 0.537 -0.00243 -0.00244 -0.00246__Fe Q/OOO -0.00005 '6.98l' -O.OOOO5- -0.00005 -O-. 00006__K.' . 6.000 0.00146 "11.38 0.00164 0.00142 0.00131__Mg O.OOO ' ' 0.00014 2.346 0.00014 0.00014 0.00014__Mn ' 0.000 ' 0.00036 2.227 0.00036'" 0.00036 0.00037__Mo 0.000 rO.00070 20.75 -0.00087 -0.00060 -0.00063_Na O.OOO ' -0.00045 27.01 -0.00049 - -0.00054 -0.00031__Ni .O.OOO: O.OOOO8 : 133,8 0.0002O 0.00004 0.00000__Pb O.OOO 0.00281 12.10 0.00307 0.00242 0.00293__Sb 0.000 -O.OOO17 231.9 -0.00009 0.00018 -O.OOO61_Se ' 0.000 -0.00229 11.24 -0.00256 -0.002'27 -0.00205__Sn 0.000 -0.00011 79.86 -0.00002 -0.00019 -0.00011_Ti 0.000 -0.00053 4.720 " -0.00051 ' -0.00054 -0.00056

• ' Tl 0.000 -0.00147 " 25.57 -0.00156 -0.0pl79 -0.00106V O.OOO 0.00005 45.93 O.OOO02 0.00005 O.00007

• • Y N/A 146285.67187 0.393 146894.00000 145749.00000 146214.00000Zn 0.000 -0.00007 5.ISO -0.00007 -0.00007 -0.00008

49AR30l*999

Page: 3


Run Name: 9619703T61 • INSTRUMENT ID: 054JJ

Tube: 2 SI tb 07/15/96 . 0 8 : 1 5

AVGCONC 'INTENSITY ' INTEGRATIONS

ELEM (ppm) RATIO %RSD #1 #2 #3

__Al 50.00O 0.61453 0.140 0.61393 0.61552 0.61414_'_Ca 50.000 0.38199 0.006 0.38198 0.38198 0.38202__Fe 50.000 • 0.12676 0.212 0.12645 0.12689 0.12693__K . 50.000- 1.25993 O.095 1.25864 * 1.26104 1.26012__Mg' 50.000 0.51742 0.151 0.51653 O.51797 0.51773__Na 50.000 0.10531 0.019 0.10532 ' 0.10532 0.10528__Y , N/A 145658.67187 0.210 145999.00000 145402.00000 145575.OOC

50AB30SOOO

Page: 4 -


Run Name: 9619703T61 . ' . ' "' INSTRUMENT ID: 0547

Tube': 3 S2 £> .. O7/15/96 08:20

AVG '' . CONC INTENSITY - INTEGRATIONS - -

ELEM (ppm) . RATIO %RSD SI ' #2 v* .

AQ 1.000 0.15607 0.821 0.15461 0.15658 Q.5701"AS .1.000- , 0.18375 0.898 0. 18185 *'%***—— Ba 1.000 . 0.22825 0.676 0:22647 °'22!?i ?~Be 1.000 2.35366 6.866 . 2.33027 ' 2.36308 2— Cd - 1.000 0.689S8 0.742 0.68431 0 . 6 9094 0 . 69439"Co 1.000 ' - 0.14758 0.963 • 0.14595 0.14826 0.14853—— CU 1-000 0.17499 0.817 0.17334 ° ' ?**l o—— Mn 1.000 0.61242 0.824 0.60669 0 - 6 1435 - J

=- t:S - -S:iS? S:3J S:SSS ' :.

Y N/fl 14689600000 0.476 147679.00000 146678'. OOOOO. 146331.00000Zh 1.000 " '0.06390 "0.777 • 0.06334 0.06412 0.06425

5iAB30500I

page: 5


Run Name: 9619703T61 . INSTRUMENT ID: 05473

Tube: 4 S3 ^ 07/15/96 08:24

AVGCONC INTENSITY INTEGRATIONS

ELEM (ppm) RATIO %RSD #1 #2 ' #3

__Cr • 1.000 0.07780 0.936 0.07697 0.07834 0.07808__Mo 1.000 0.29246 1.672 0.28631 0.29522 0.29534__Sb 1.000 0.27394 2.035 0.26756 0.27790 '0.27636__Sn 1.000 0.06737 0.485 0.06700 0.06751 0.06760__Ti ' l.OOO 0.34240 0.921 0.33877 ' • 0.34444 0.34400__V 1.000 0.09721 0.930 0.09617 0.09783 0.09762__Y N/A 144989.00000 0.953 146579.00000 144310.00000 144078.00000

AR305002

Page: 6


Run Name: 9619703T61 " ,. ' INSTRUMENT ID: 05473

Tube: 5 ICV 07/15/96 ' O8:28

AVG ' - •- INTEGRATIONSELEM (ppm) %RS.D ttl • • #2 tt3 • REREAD REDIG

'__Ag, 0.61334 0.224 0.61176 0.61425 0.614O1__Al 30.16597 0.270 30.14219 ' 3O.09888 30.25683_As. . 0/61604 0.581 0.61815 'o.61807 0.61190_Ba 0.60351 0.134 0.60341 0.60275 0.60437__Be • . 0.59643__ 0.434 " 0.59368 0.59883 0.59677__Ca 29.82710 0.500 29.67049 ' 29..96779 29.34301__Cd 0.60115 0.341 0.59886 0.60283 0.60176__Co ' 0.59970 0.478 0.59644 ' 0.60186 0.6008O__Cr 0.61902 O.387 0.61709 "0.62171 0.61826__Cu 0.61354 0.188 O.61323- 0.61257 0.61482__Fe- ' 30.06141 0.525 29788042 30.17242 ...30.13140__K • 31.16564 0.500 31.29792 • 30.99367 31.20534_Mg ' 30.25942'0.235 30.18250 ' 30.27223 30.32354__Mn : 0.6O090 0.369 . ;0.59844. * • 0.60276 0.6O151_Mo • 0.62298 0.638 0.61920 . 0.62713 0.62262__Na 31.10393 0:375 ' 31.22286 30.98953 31.09941

•Ni 0.60129 0.206 0.60119 '0.60259 0.60010_Pb 0.60406.0.851 0.59866 0.60890 0.60462__Sb 0.62598 0.126 0.62554 ' "0.62689 0.62550._Se • 0.60062 0.246 ' 0.66033 " 0.59930 0.60222__Sn 0.59514 0.302 0.59312 ..0.59657 0.59574•_Ti ' 0.62979 0.242 ~ 0.62803 0.63063 0.63067__Tl - 0.6O109 0.207 0.59970 0.60144 0.60212__V •.. 0.59202 0.286 0.59036 0^59375 0.59194__Y 144517.32812 0.285 144962.00000 144444.00000 144146.00000

Zn 0.59919 0.324 0.59713 0.60100 0-59944

53AR305003

LANCASTER LABORATORIES .

,,,jn Name: 9619703T61 . • INSTRUMENT ID: 05473

Cube:'' 6 IC8 07/15/96 03:33

AVG INTEGRATIONS[j.EM. (ppm) , %R'SD #1 i*2 tt3 REREAD REDIG

_Ag 0.00016 201.6 -0.00015 0.. 00052 0.00013" Al 0.02547 24.48' 0.03267 0.02213 0.02161Jus 0.00044 248.9 -0.00080 0.00130 0.00082Ba -O.O0024 15.90 . 0.00026 0.00026 O.OOO19

""""Be ' ' -0.00012 65.09 -0.00012 -0.00019 -0. OOOO3•""""Ca ' O.O9098 1.068 0.09177 0.09126 0.08989"""cd 0.00032 29.33 0.00042 0.00024 0.00029""~Co - . 0.00022 167.7 -0.00012 0.00063 0.00017"~~Cr ' 0-. 00006 198.8 -0.00007 0. OOOO9 0.00013"""""CU 0'. 00005 64.40 0.00002 0.00004 0.00009~*~Fe:' . 0.03804 8.223 0.03621 0.03625" 0.04165"""""[< : ,0.06261 5.541 O.O5992 .0.06137 0.06653."""Vlg 0.03296 7.455 0.03570 0.03096 . 0.03221""~"Mn • O.OO001 248.5 0.00006 '-0.00001 0.00000""""Mo 0.00037 133.1 0.00095 -0.00002 0.00019"~~Na ' 0.16603 10.70 0.14680 0.18187 0.1694O' Ni 0.00067 75.74 0.00125 0.00028 0.00048' pb O.OO012 441.2 -0.00033 O.OOOOO ' O.OOO7O"3Isb -0.00052 274.0 -0.00033 0.00080 -0.00203'"___Se O.OO003 1831. -0.00069 0.00005 0.00076^__Sn O.O0186 147.3 0.00263 0.00411 -0.00119__Ti' . 0.00033 10.26 0.00029 0.OOQ35 0.00034~r_Tl 0.00122 163.8 -0.00070 0.00107 0.00330__V -O.OO012 131.5 -0.00038 0.00004 ' -0.00003"^\ -1 144698.67187 0.388 144144.. OOOOO 144684.OOOOO 145268.OOOOO

• Zn ' O.OO041 31.08 0.00033 0.00034 0.00055

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"C:,:i ' 0,,0894-j :. . 235 0.09054 0, 08948 0 .. 03C133"Cd 0 ,,01000 0.633 0,. 010 07 0,. 0099!:. 0 ,. 00999"Co 0,, .1.01 08 0.21:10 0.1.01.39 0,. LOO'S! 9 0,. 1.0084"cr ' o,,o:;:o5:L ;;:.:LO::I o.o;;:c.i.:. . o,.020';)9 o .o;;:o.i.<i-"Cu 0 ,. 0 !:i ]. (:!':i O.:i:!:ii:i 0.051.76 . 0 ,. 05 :i I::-). ' 0,051.52">!=. , 0 ,. 0 :;: !::,!:! 6 10 . 7 !:i 0 . 027 1 :. 0 ,. 0324 -I- 0 ,. 0 2702"(<; 0.0(:,:.22 !:,.073 0.061.49 0.05 7'=) 8 0 . 0(:,4 13" 0.03:.24 3,81.3 0.0298.7 0 .0;S:i.':)l . 0..033.9E.Vl n 0 . 0304 S 0 ., l.ii 7 0 . 0304 !:i 0 . O304 1 0 . 0 30 5 1

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-o,, ooo.i,:;: 196., 7 -o,. 00017 -o,, 00032 • 0.0001.45 ].;S. .3 1951 0.,453 51.0,.63818 5 ].-:.., 84698 :J I. 4 . 47332

",A ;;; . - 0 ,. 0 0 .3 0 0 6 8 . / 9 - 0 ,. 0 0 1. 0 :: - 0 ,. 0 0 !::' 1 7 - 0 . 0 0 2 7 9•''""l;l.-< 0,. 007(110 0,,39!!1 0.00777 0,. 007 80 0,00783•"""[•ME; 0 . 0000 7 309 . 5 0 . 0002 7 -0 . 0 OO.1.6 0 . OC 009"'""da 507 . 08 34 3 0 ,. 0 i:,::: 506 . 8907 4 506 . 9 5602 30 7 , 40356"'""Cd ' 0.009-30 1..704 0.00986 O.C0976 0.. 03.009'"'""co . -o . oo 037 2 ;;: . 54 -o . 0004 1 -o . o 002 7 - o „ 00042"'"<:: i- - o . oo :i. :.«i. 2 1 , 09 o . oo 13 6 c . oo :. o i-t o .. ooo ii:1;;1"""OU- -0.00163 1.1..23 -O.OOHiiO -0.00i::i4 --0 .. 00,1. ill 4""""fB • 203.84323 0.1.42 20!:. . 50491 206.03372' 205,,9!=!606J:""K 0.07214 7.086 0-. 07499 0.06624 0.07!:J19

•'!""V'(:| 5.1.9. 40289 0.378 5.1.7,13757 520.40142 S20 ,. 66967""")•' n ' 0 , 003 67 1 . 38 5 0 , 00373 ;) . 00 366 0 . 0 03 <:>3"'"Vo -0., 001.'!-6 10 1!:.,!:! -O., 003:i 4 -0,00021 -0.001.04"""'.NiEi 0 „ 2 2.7 85 i:l . 97 ,1. 0 „ 205 ;i:i:i 0 . 24 499 0 . 2 53 35'""wl -0.. 00358 10.42 -0-.. 00367 -0,00390 -0. 00 3.1. "''"""pto 0..00813 1':J.:.4 0..00962 0..00826 0.00651"""j:;b "'iliTii'o'iT;' 92.41. ,-0.00032 --o-,, 00.1.11. -o.oo;;:98"j-;*:! -0.00383 7!:>.47 -0.00537' -0 „ 00 1. IS -0. 00 692-""";•; n 0 .00270, 38-. 98 0.00244 0,. 001.80 0.00386"""ri. -0.000909.037 -6.00093 -0 ,. 000 81. -0.00090""r:. 0.00734 94,79 0.0109.9 -0.00064 0,0 1.3:. 9

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AVG INTEGRATIONS£LEM (ppm) %RSD #1 . . #2 ; #3 REREAD REDIG

_Ag 0.21229 0.223 0_.21176 0.21245 0.21267 ____ _____Al . 520.79779 0.567 517.66339 521-19067' . 523.53936_As. 0.10370' 3.594 "~" "0.10118 0.10192 0.1O798__Ba ' 0.52143"0.293 0.51986 0.52152 .0.52291__Be • 0.46377 0.175 O.46443 O.46402 ' 0.46286__Ca 502.05099 O.213 5O2.36483 ' 502 ..92913 500.85900

Cd ' 0.92869 0.127 0.93003 0.92777 0-92827~Co 0.4723S 0.031 0.47222 0.47238 0.47252_Cr '' 0.48596 0.297 0.48561 ' 0.48755 0.48472__Cu . 0.55943 0.696 0.55590 0.55876 . 0.56361__Fs 204,45833 0.197 203.99264 . 204.71150 .204.67103__K 0.07549 4.495 0.07539 '. 0.07894 0.07215_Mg'' ;~522.52905 0.292 -"520.76367 523.48712 -. 523.33642'_Mrv 0.47782 0.091 0.47302 0.47313 '. 0.47732__Mo • -0.00017 258.5 -0.00065 • -0 .'00010. . O.OOO23_Na ' 0.27469 9.123 0.24906 0.29914 . 0.27587__Ni 0.92722 0.241 0.92867 0.9,2835 . 0.92464__Pb . 0.05742 2.383 0.05898 0.05682 . 0.05645__Sb - 0.62176 0.828 0.61659 0.62639 0.62179_Se 0.04166 4.537 0.03951 0.04306 0.04242

Sn - 0.00232.101.9 -0.00037 0.00326' 0.OO409___TI -0.00098 7.154 -0.00091 -0.00105' -0.00099__Tl 0.09896 4.995 . 0.10108 0.10249 0.09331__V 0.48059 0.182 0.48041. 0.48154 0.47981__Y 134869.32812 0.344 134938.00000 134374.00000 135296.00000

Zn 0.96692 0.046 0.96665. O.96744 0.96668

57&S3Q50Q7

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Name: 9619703T61 » INSTRUMENT- ID: O5473

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AVG ' " : INTEGRATIONS?;LEM (ppm) %RSD , si - #2 #3 REREAD REDIG^_Ag .0.50389 0.069 0'. 50365 0.50429 0.50373 _____ _____^_A1 25.41235 0.419 25.48.513 25.46205 25.28988 _____ _______AS • 0.50233 0.053 0.50209 0.50262 0.50228'_Sa , 0.50010 0.232 - 0.50083 0.500'Tl 0.49876^ _3e ' ' 0.48159- 0.640 0.47804 0.48306 0.48366_Ca 24.75859 0.509 24.61417 . 24.84774 24.81387'_Cd . 0.48819 0.601 .0.48480 . 0.48965 . 0.49011~"CQ , • 0.49176 0.642 0.48812 0.49333 0.49382^_Cr 0.505K) 0.707 0.5O126 , 0.50571 0.50833^__Cu O.50478 0.354 " 0.5O617 • 0.50540 0.50276""""pe . . 24.31480 0.619 24.63714 24.90410 24.90314-

K . - 26.69314 0.807 26.89565 26.73073 26.4'6803- Mg 25.54262 0.279 "25.52992 25.61958 25.47836Mn 0.49233.0.431 '.0.48987- 0.49361 0.49350

* "MO''- 0.51136 0.604 .0.50801 0.51194- 0..51411-__Na' 26.38315 0.568 26.52746 26.39405 26.22795_._Ni 0.49372 0.509 0.49087 0.49466 0.49563^_Pb ' • 0.49223 0.266 0.49094 0.4.9213 0.49356'___5b 0.50656 0.196- 0.50661 0.50753 ' 0.50555__5e 0.49805 Q.45S .' 0.49681' 0.49667.' ' 0.50069_Sn . 0.49029 0.362 0..48865 0.49218 O~. 49O04__Ti .0.51401 0.236 0.51261 0.51484 ' 0.51459'f_Tl ' 0.5O033 0.954 0.49487 0.50238 ' 0.50375_M 0.43544 0.334 0.48358 0.48658 0.48615

\___Y 144292.67187 0.546 143392.00000 144623.00000 144863.00000Zn 0.48688 0.557 . 0.48376 0.48864. 0.48826

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page: 12 - . - -• -. • . - - . - . .


Run Name:. 9619703T61 - ' INSTRUMENT ID: 05478

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AVG INTEGRATIONS '£LEM (PPm) _ %RSD ttl ' 32 • #3 REREAD REDIG

Ag 0.00013 145.8 . O.00026 O.OOO41 - -O.OOO11Al ' 0.10130 13.69 0.11304 0.10487 -0.08599As 0..00178 '40.56 0.00135 • 0.00247 0.00102

__Ba 0.00020 16.44 • ' 0.00024 0.00020 0.00017_Be • -0.00070 21.03 -0.00036 -0.00069 -0.00056_Ca', . 0.14961 4.823 0.15571 0.15148 0.14165__Cd 0.00035 21.81 . 0.00034 0.OO044 O.OOO29_£0 O.OOO34 'l!9.4 0. OOOOO 0. OOO80 0.00024

Cr 0.00019, 21O.4' -0.00016 0.00010 0.00064Cu -O.OOO23 24.69 . -0.00026 -O;00016 • " -0.00026

__Pa 0.06199 6.589 0.05754 0.06286 ' 0.06557, •_K 0.06421.8.551 0.06950 ' -. 0.05854 0.06458___Mg . 0.09506 5.743 0.09817 ; 0.09825 . 0.08875'__Mn -O.OOOO4 138.9 0.00000 -'-O.OOO1O " -O.OO003_Mo ' 0.00014 866-. 6 - - 0.00077 0.00097 --0.00130__Na 0.18731 7.725 , 0.17378 0.18011 0.20455__Ni 0.00085 55.84 0.00058 0.OOO57 O.OO140__pb' O.OOO19 175.8 -0.00014 0.00019 0.00053__Sb ' 0.00050 384.4 -0.00080' -0.00040 0.00271__Se 0.00008 538.6 O.00015 O.OOO52 -O.00041_Sn • 0.00186 62.53 0.00113 0.0012-1 0.00320^_Ti O.OOO14 57.02 0.00013 0.00022. 0.OOO06_Tl 0.00025 784.:. 0.00038 0.00223 -0.00133__V 0.00000 1272. -0.00008 0.00005 0.00005

. •_y 143075.67187 0.445 142348.00000 • 143348.00000 143531.00000Zn 0.00053 10.64 0.00065 0.00054 0.00054

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AVG ' INTEGRATIONSI.-.LEM (ppm) %RSD #1 #2 #3 REREAD REDIG//>g O.OOO16 179.7 0 . OOOO4 ' 0.00049 -O.OOOO5j?Al 0.06487' 11.24 O. 07330 • 0.06074 0.0605SJ/As ' 0.00034 577.4 -0.00194 - 0.00159 0.00139tj3a- ' 0.00014 11.02 0.00015 0.00015 0^00012"/Be- . -0.00088 10.69 " " -0.00094 -0.00077 -0.00091_7ca 0.11430 3.465 O.li872 0.11313 0.11106"/Cd . 0.00019 71.62 0. 00034- O . OOOO7 , 0..00016'" Co O.'OOOIS 169.0 ' 0.00023 ' -0.00014 0.00046'"Tor' 6.0OO16 201.6 . 0.00001 0.00056 -0.00006"Tpu 0.00000 3443. -0.00023 • 0.00001 0.00024

Fa " - 0.053O2 7.810 ' , ' X>. 05753 ~ 0.05215 0.04939.* K. ' • 0.05812 5.453 ' 0.05569 0. 06171 0.05696^Mg- - 0.05990 5.384 0.06361 0.05831 0.05777**7_y(rt ' -0.00008 42.69 -O.OO'OO'6 -O.OOO12 -0 . OOOO6__Mo •• .. .-0.00008 83.30 -0.00006 -O.OO016 -0.00002" Na ' 0.21342 16.22 O. 20083 0.18685 0.25259~V[Ni 0.00097 109.1 ' 0.00155 0.00163 -0.00025__pb ' ' 0.00094 136.8 0.00239 . -0 . 00009 " 0.. 00053/.Sb -0.00067 349.7 -0.00052 -0.00313 0.001612_3e • -0.00070 95.14 . -0.00116 -0.00100 0.00006

' -0.00115 62.54 -0.00187 -0.00115 -0.00043' • -,- 0.00014 29.64 0.00015 0.00009 0.00017

' 0.00177 118.5 '-0.00065 . 0.00296 0.00300' ' -0.00004' 203.1 -0.00008 -0.00008 0.00005

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AVG ' ' INTEGRATIONSELEM • (ppm) %RSD 31 ' - #2 _ ' #3 REREAD REDIG

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~7br,~

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ftR3050lt

/As 2.01780 0.151 2.02027 2.01440 2.01874__Ba ' 2.02020 0.063 2.01897 2.02010 2.02152. _____ ____J_QB 0.04840 0.044 0.04841 0.0.4841 0.04837 ____ ____ ICa ' 4.10224 0.236 4.10031 4.11279 4.09363 ————— ———— I

0.04879 0.879' 0.04844 O.O4927 0.04866 —Co 0.49881 O.'OSO ' 0.49865 0.49910' 0.49869

0.20506 0.062 0 . 20498 0.20521 0.20499-~7cu ' • 0.25642 0.166 -0.25626 0.256O9 , 0.25690.__Fe ' ' 1.03899 0.552 1.04177 . 1.04281. 1.03239'_ K 4.03617 0.231 4.04482 4.02623. . 4.03739

Mg 2.09637 0.247 2.09090 .2.09928- . 2.10O43"7Vln ' 0.49924 0.167 0.49863 O.50O19 0.49889' __ Mo 2.07301 0.39O ' ' 2.06415 2.07999 2.07489.

Na ' 4.26626 1.073 4.31795 4.25014 4.23069Ni . 0.50297 0.282 0.50265 0.50453 . 0.50174

_ pb 0.49906 0.564 0.49769 0.50230 0.49718-/Sb 0.52081 0.549 0.51894 ' -0.51939 0.52411__ Se 2.02075 0.301 2.01464 2.02684 2.02073__ Sn 3.95702 0.112 3.95360- 3.96203 3.95542__ Ti 1.05814 0.167 1.05621 . 1.05971' 1.05851/Tl 2.02666 0.389. 2.01794 2.02376 ' 2.03328V 0.49476 0.104 0.49469 ' 0.49530 0.49423Y 142345.67137 0.117 142839.00000 142681.00000 143017.00000

0.49181 0.183 '0.49121 O. 49234 0.49137

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Name: 9619703T61 ' . INSTRUMENT ID: 0547S

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' 0.00004 235.2 0.00002 0.00019 -0.00007 ____ ____1 0.03428 11.41 0.03369 0.03070 0.03846

0.00058 568. O O.OO391 -0.00273 0.00057' 0.07T97 0.131 0. 07195 - 0.07189 0.07208

%,Be' -0.00088 24,93 -0.00069 -0.00084 -0.00113_Ca ' 72.65198 0.219 72,50428 72.63098 . ' 72,82069*XCd .- • 0.00046 16.76 . 0.00040 0.00054 0.00042

CO. .. 0,00114 60.90 0.00100 0.00189 0.00052' O.OOOOr 1833. ' -0. 00025 0. 00019 ' O..OOO10

- 0.00518 4.226 ' 0.00508 • '0.00543 ' 0.00502Fe--' 0.04051 19.13 0.04946 ' 0.03601 0.03605

• 0.91370 0.550 -0.9148O :. 0.90820 0.91809_ ' 33.04850 6.4.04 . 32.92282 33.03377 33.18891\/Mn ' 0.00214 1.431 .0.00217 0.00215 . . 0.00211MO 0.00197 58.55 0.00306 0.00211 0.00075Na 32.14779 0.556 32.01739- 32.0742O 32.35178

- 0100135 20.41 ' 0.00167 0.00119 0.00119-0.00018 343.3 0.00003 0.00030 ' -0.00089-0.00069 151.1 "" -0.00188 ' 0.00010 -0 . OOQ30O.OO140 69.95 0.00029 , 0.00176 0.00214

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AVG , INTEGRATIONS ,ELEM ' '(ppm) %RSD ttl ' #2 . S3 REREAD REDIG

i _ Ag . 0.02053 1.315 0.02080 0.02026 ' 0.02053__ Al • ' 0.46203 0.246 0.46075 0.46242 0.46293__ As 0.02208 10.76 6.01997 0.02162 '0.02465_ Ba ' 0.48029 0.121 0.47982 • 0". 4.3094 0.48011'_ Be 0.00869 2.280 0.00864 0.00853 ' 0.00891_ Ca 71.61141 0.067 71.66624 71.59373 . 71.57419__ Cd .'. 0.01027 1.180 0.01013 0.01030 0.01037__ C o ' - - 0.10146 0.333 0.1O181 '. ' 0.. 10143 0.10114__ Cr - 0.02041 2.666 ' 0:01984 0.02047 , 0.02093

•• _ cu 0.05725 0.621 0.05691 0.05723 .- 0.05762__ Fe 0.23901 7.369 - ' 0.25616 0.22097. 0.23992

, _ K 3.02771 0.239 3.01956 - 3.03348 • 3.03007._ Mg 33.56727 0.272' 33.46336 33.60293, 33.63553_ Mn 0.03235 0.193 . ' 0.03229 0.03242 0.03235'.__ Mo 0.20333 1.001 ' 0.2O661 0. 20771 0.21065_ Na 34.01937 0.511 33.82649 34.06726 34.16437__Ni 0.08210 1.459 6.08325- 0.08220 0,. 03086

1 Pb O.O0962 5.787 , 0 . OO906 0.00961 ' 0.01018_ Sb 0.12332 2.868 0.11923 .0.-12589 0.12479_ Se 0.01054 6.945 0.01052 0.00982 0.01129_ Sn 0.59393 1.323 0.58578 0.59452 0.60147__ Ti 0.10535 0.226 0.10527 O. 10562 0.10516__ Tl , 0.02016 8.455 0.01935 0.01863 0.02200__ V 0.09921 0.261 0.09915 0.09950 0.09899_ Y 142053.00000 0.005 142046.00000 142052.00000 142061.00000

Zn ' 0.07379 0.522 0.07415 0.07382 0.07338

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AVG INTEGRATIONSELEM (ppm) %RSD SI . S2- ' • S3 REREAD REDIG

_Ag 0 .'21194 0.452 0.21134 ' 0.213O4 0.21143 ———— ————__A1, 530-. 23681 0.267 529.45642' ' 531.87164 ' 529.38233.__As 0.09864 2.327 0.10039 0.09949 0.09604__Ba 0.52301 0.182 . • 0.52269 0.52408 0.52225

. Be • O.46624 0.239 0.46503 0.46722' 0.46648__Ca 505.49736 0.257 5O4.04757 .506.57235' 505.87368_Cd 0.92500 0.115 0.924O9' .0.92618 0.92472__Co 0.48623 0.450 0.48393 0.48829 0.48646__Cr> ' 0.48596 0.278 O.4844O- '' 0'. 48662 0.48685__Cu 0.56840 0.329 • - 0,56766 . • 6.57052 . 0.5670O-__Fa ; 211". 60238 0.301 ' 210.92312 212.19131 . -. 211.69273__K\. ' O.'08137 4.520 " 0.08523 . 0.0779O - 0.08098

Mg "" 530.05895~6.248 529:09289 531.55645 -529152752'.__Mn . 0.47870 0.129 . Cf. 47800 0.47919 0.47891.__Mo -0.00123 195.0 0.00144' -O.00323 -0.00191__Na 0.30329 20.10 0.37812 0.25976 - 0.28701• Ni 0.9,2423 0.293 0.92459 0.92683 0.92143__Pb 0.05656 3.446 0.05484 0.05615 0.05868_Sb 0.62960 0.653 ' 0.62849 . 0.63415 0.62615__Se 0.05023 4.035 O.04802 0.05199 0.05069__Sn O.OO390 50.67 '. O.OO619 O.OO266 , 0.OO287' Ti -0.00106 9.635 _ -O.OO116 0.00095 -0.00107__Tl - 0.10355 3.778 0.09903 0.'10597 0.10564__V 0.48335 0.119 • O.48268 0.48369 0.48368__Y 134041.32812 0.271 134320.00000 133630.00000 134174.00000

Zn , 0.96247 0.173 - 0.96074 0.96407 0.96260

AR30502575

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LANCASTER LABORATORIES* - '

Run Name: 96197O3T61 •' INSTRUMENT ID: 05478

Tube: 28 CCV 07/15/96 10:23 • ,

AVG • ' INTEGRATIONSELEM (ppm) %RSD. SI S2 S3 REREAD REDIG

__Ag 0.49725 O.33O - 0.49538 0.49849- 0.49787 _____ ________Al ' 25.415OO 0.306 • 25.38171 25.35926 ' 25.50401 ____.______As . 0.47001 0.663 0.47320 0.46989 0.46696__Ba 0.50847 0.056 ' 0.50833 0.50826 0.5O880_Be ' • 0.47023 0.485 0.46913 . • 0.47286 0.46870__Ca 24 ..25473 0.467 24.202.12 ' 24.38475 24.17731__Cd 0.48039 0-.261 • 0.48084 0.48136 0.47897__Co • O.49874 O.296 0.49718 0.5O012' 0.49893.__Cr . 0.50863 0.29O 0.50738 0.51026 0.50825___Cu 0.52195 0.386 0.52137 0.52029 0.52420__pe ' 25.22879 0.267 25.18280:' 25.30638 25..19717__K . 26 .'41926 0.662 26.53219- ' 26.21776 26.50785-__Mg ' 24.80265 0.036 24.80328 '_ 24.31123 ' 24.79339__Mn 0.49523 0.377 0.49396 '." 0.49738 0.49436__Mo 0.50915 0.305 0.50374 0.51087 0.50783__Na 26.02737 0.654 25.9219O 25.93634 26.22387__Ni ' 0.48622 0.191 0.48676 0.48676 0.48515__Pb ' 0.48(533 0.697 0.47711 0.48379 0.48010,__Sb - 0.49900 0.198' 0.50013. 0.49855 0.49832-__Se . 0.41783 1.016 - 0.4130O 0.42101 0.41947

' Sn "0.490 0 0.648 0.48733 .0..49366 0.49001__Ti 0.52397 0.238 0.52303 0.52539 0.52350__Tl ' 0.47295 0.509 ' 0.4740O 0.47020 0.47466

. __V x 0.49144 0.315 0.49057 0.49323 0.49053_Y- 139521.67187 0.577 133599.00000 '139884.OOOOO 140082.00000

Zn " ' 0.46613 0.378 0.46487 0.46815 0.46537

76W30502S

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Run Name: 9619703T61 ' INSTRUMENT ID: 05478

Tube:' 29 CCB 07/15/96 -10:28

AVG • INTEGRATIONSELEM (ppm) %RSD SI. S2 S3 REREAD REDIG

_Ag ' 0.00009 66.40 0.00002 0.00011 0.00014__Al O.03990 13.26 0.04539 0.03948 0.03484__AS 0.00013 1187. -0.00050 0.00261 -O.OO156. Ba 0.00012 17.05 0.00011 0.00011 . 0.00014__Be • -O.OOO48 30.15 -0.00037 -0.00043 -0.00065__Ca 0.12521 3.906 0.12924 0.12662 0.11977__Cd 0..00032 68.67 0.00021 0.00013 ' 0.00058__Co 0.00000 16259 -Q.00031 -0.00031 0.00061

;"__Cr ' '' -0.00016.337.5 0.00027 -0.00079 0.00001__Cu . 0.00140 12-.12 0.00157 • 0.00123 . 0.00140"__Fa - 0.04593 9.068 0.04953 0.04689 0.04137•_K '. 0-. 06037 3.042 '0.06249 . 0.05924 ' 0.05938,_Mg- 0.06792 7'.366 0.07117 0.07044- 0.06216

• Mn ' -O.OOO10 13.64 -6.00009 -0.00012 -O.OOO09'__Mo' • 0.00029 336.6:- 0.00131- 0.00022 -0.00065_L_Na - 0.21013'-7.216 0.22676' ' 0.19707 ' 0.20656_Ni 0.00087 49.49 0.00077 0.00049. 0.00134__Pb • 0.00037 191.7 -0.00019 O.OO013 0.00119__Sb -O.OOO65 130.1 -O.00152 . -O.O0114. 0.00069

. _Se -O.OOO16 479.0 , -0.00014 -0.00095 0.00060' _Sn . O.OO128 130.3 ' 0.00093 -0.00019 0.00310__Ti O.OOO1O 39.20 0.'00012 0.00013 0.00005_Tl . 0.00205 41.42 0.00236 0.00109 0.00271

' _V -0.00009 397.2 0.00019 -0.00052 0.00004__Y 143621.67187 0.433 143915.00000 144051.OQOOO 142399.OOOOO__Zn O.OOO14 45.59 0.00011 ' 0.00022 , 0.00010

Data Reviewed by:

Data Verified by:

AR30502777

Verified :3y: .

(_J Data File .s'ame: ! 9 9 04T5 2 . 0

Analyst: o Vi '". "~ " '. Run Name: ?S 1 99G4T52' .

!-apamet3PS: - ~ "

Rinse Time: .30 secIndividual In.-sgrati on Time: 10 secTotal Integration Time: 30 "sec".

Element Symbol Element Name Wavsl engtnAg _ . . _ _ _ _ Silver 323.0.6Al Aluminum ' 308.21As Arsern'c .' 139.045 Sopon 249.573a ; Ban" urn 493.40Be Bepylllum . .313.04Ca Calcium 317.93 •Cd ' • ---Cadmium ' 226.50Co Cobalt 223.51Cr ' Chromium 257.71Cu • Copper " 324.75Fs - Ipon " ' • 27 1 .44-:< Potassium. " 755.49Mg . . Magnesium 279.07i^n Manganese 257. -51Mo - Mol ybasnurr.Na • roc 1 urnNi NickelPb . Laad ~" " " Z 20. 3 5, -"IPb . . Lead 220. 35/2'5b- - . Antimony . 206.33/1

Selenium- . 1 95 . 02/2-3 e 1 en 1 um '< v 5.02 / 1Tin ~ '

Titanium 3 3 4 . 9 <^Thai 1 lum : 90 . 35Vanadi um 292.40Yttplum 37 i . 03Zinc T D 5 . 2 0

The O IE.TRACE ICP 'js-as = . C'rswfc-rd-X.unsal man Mo";* r.eciuc- - <?i"echniaus TOP leaa and selenium. This reauirss tne utilization of

78

7 •=• ~, T\ n " c"j =• TOP ! s- 5 o a "! c. ' ~ •=• I e !~i ~.. u rti. Th "i s" r —• c! u "!"=•£ t. n e u t'. "i " ~ =: t i or. 7- —' - ~i ~-•'rst =r.a s>~conc! CPCSP.. wavelengths in "he calculation of aaon or" -rS^rji •VJ'detertril n-at i ons . Tne 5 11 TRACE ICv also utili-is: Yttrium r.r .-.n T r-t5-pns":•jtandapd to compensate rc-r fluctuations In neou 1 -, zatl on sna o 1 ssr.ia ccnaiAll Yttrium reacinas ar~ exD'-^ssea in counti.

•-1 s a e : i.

'_ A N C A S T E R L ABO P. A TORIES

Run Name: 9519904T52 . INSTRUMENT ID:

I S O . 07/17/95 18:!7.

A-/C--CONC INTENSITY - INTEGRATIONS

EL Eh (ppm) RATIO %'RSD It! 1*2 #3

_Ag 0.000 -0.00239 9.113 -0.00214 -0.00243. -0.00255_Al 0.000 0.05449 "0.301 0.05460 0.05430 O.G5456_As 0.000 0.00032 359.4 0.00156 0.00027 -0.00085_B 0.000 0.00009 89.10 - d. 00011 0.00015 0.0 CO 00_3a 0.000 "' 0.00117 5.449 0.00124 0.00115 0.00112_Be 0.000 '-0.06317 0.542 -0.06353 -0.06314 -0.06235_Ca . 0.000 -0.00450 1.262 . -0.00448 -0.00446 -0.00456_Cd .0.000 0.00022 274.4 0.0007S 0.00031 -0.00042_Co O'. 000 -3.00035 2.334 -0.00085 . -0.00085 -0.00089_Cr 0.000. 0.00003' 514.5. -0.00011 -0.00007 O.GOO;_Cu 0.000 . -0.02799 0.333- -0.02790 -0.02795 -0.023'_re - 0.000 -0.00141 5.773 -0.00144 -0.00131 -0.00147_K O.QOQ 0.00698 24.59 0.00499 . 0.007-99 0.00797_Mg 0.000 - 0.00165 12.36 0.00133 0.00170 0.00143_fin 0.000 0.00333 25.09 0.00312 0.00492 0.00344_Mo O.OOO . -0.00340 24.82 -0.00433 -0.0032V -0.00267_Na O.OQQ O.OOQ05 1357. 0.00035 u. 00112 -0.00127_Ni O.QOQ . JL00073 89.95 0.00003 0.00135 0.00031_Pb '0.000 ~Q.QQ514 14.19 - 0 ."Q~Q"577 ' 0.00434 0.00530_Sb 0.000. 0.00421 32.43 0.00370 0.0031? 0.00577_Se • 0.000 -0.04127 2.923 -0.04148 -0.04235 -0.03996_S.n 0.000 -0.00557 23.02 -0.00718- -0.00500 -O.C0434_SP 0.000 O.OOI72 54.35 - - 0.00241 0.00209 0.00065_Ti 0.000 -0.00801 3.302 -0.. 0077 2 -0.00805 -0.00824_n o.ooo -o.coiss 9.^79 -0.00171 -0.00135 -0.00209_V .0.000 0.00019 261.2 , 0.00074 O . O O 0 1 1 -0.00027_Y r-!/A 25741.56601 0.409 25622.00000 25732.00000 2532'i. OOOOO

In 0.000 0.0002-4 ..114,0 -0.00039 0.00042 -•!_. 0

79AR305029

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Run Name: 9b'l99Q4T62 INSTRUMENT ID: 05936

Tube: 2 S1 "^ -' 07/17/95

AVoCONC' INTENSITY " . INTEGRATIONS

ELEM (pom) RATIO. . • %RSD tfl '#2 ' ??3

_Al 50.000 . , 5.25326 0.863 5.21043 5.28896- - 5.29034__Ca 50.000 ,_,„ 6.30360 0.514 6.27046 6.33525 5.30509_Fs 50..000,- ..: .- 7".""Q384Q 0.594 -5.99323 7.07537 7.0^505_K 50.000 . . .5.94549 1_. 013 ' '6.85490 5.97642 5.99516_Mg 50.000 - 5.12043 0.523 "5107513 5.14574 6.13942_Na- 50.000 . .. 0..89610 1.052 0.88533 0.89952 0.90344_Y N/A 25539.56601 0.697 25745.OQGOO 25449.00000 25425.00000

AR305030


Run Name: 9619904T52 ' INSTRUMENT ID: 05936

Tube: 3 S2 ^ - 07/17/96

AVGCONC INTENSITY INTEGRATIONS

ELEM (ppm) RATIO %RSO -31 #2 ft?

•_Ag 1.000 1.20036 0.765 1.19132 1.21010 1.19917_As 1.000 0.55832 0.893 0.65355 0.66522 0.65758_3 .1.000 0.15475 0.304 0.16332 0.15593 0.15503_Ba 1.000 'i.96295 0.972 1.94784 1.98440 . ..1.95659_3e 1.000 2.96257 0.958 -2.93445 2.99130 2.95177_Cd 1.000 -7.65708 0.828 7.59133 7.71790 7.66202_Co 1.000 0.74240 0'. 370 0.73653 0.74941 0.74111_Cu 1.000 . 1.05644 1.005 - 1.05525 1.07763 1.06543_Mn l.OGO 15.30315 0.935 16.15113 15.45530 16.30201__Ni 1.000 1.69147 1.040 1.67598 1.71051 1.6878:_Pb 1.000 1.30228 0.945 1.23309 • 1.31027 1.308'_Se 1.000 v,2.42042 0.068 2.41872 2.42052 2.4220^_SP 1.000 58.13090 ..0.953 57.71575 53.80306 ' 58.02389_Tl 1.000 0.17649 0.784 0.17656 0.17784 0.17508_Y N./.A 25653.00000 0.477 25752.00000 25515.00000 25691.00000_Zn 1.000 0.38521 0.920 0.33148 0.38354 " 0.38562

815830503 I

L A N C A S T £ R L ABO R A T u R I E S - "_

R u n Name: 9519904T52 . " . . " " " " ' ; . - - . INSTRUMENT I D : 05y3i

""•jbe:' -4 S3 -S 07/17/96 18:30

AVGC'ONC . INTENSITY INTEGRATIONS

ELEM (P.pm) .. RATIO . . XRSD , *M .. tt'2 ' ' 43

_CP 1.000 1.39387 0.433 . 1.40064 1.39194 1.38903_Ho ".000 - - : ~2V3902T:- 0.440 2.40130 2.38904 2.38033_Sb 1.000 1.10282 0.499 1.10372 1.09781 1.1019?_SIT 1.000 "-"2.34164 "07319 : ~ 2.35501 . 2.33372 2.3-312C-_Ti 1.000 . 7.24245 0:3"3o" 7.27330 7.23533 7.21871_V 1.000 2.33"095 0".479.; 2.34385 ' 2.32397 2.32505_Y N./A 25310.00000 0.239 . 25725.00000 25835.00000 25359. OQOQQ

OO

A8305032

I'' •:! O K1 : C

•-ANC ASTER LABORATORIES


Tube: 5 ,ICV 07/17/96 18:33

AV6 INTEGRATIONSfLEM (ppm) SRSO #1 #2 S3 REREAD REDIG

Ag 0.50929 2.298 0.59316 . 0.51831 • 0.61641 ________—Al 29.'62094 2.55.7 28.74390 30.09739, 30.02154 '____ ____

, fi.s 0.60810 1.879 . 0.59298 0.61215- 0.51319 ____ _____3 0.60347 2.391 0.59167 " 0.61702 0.51672

B~ 0.59443 2.41&- 0.57736 0.60341 0.50202_Re - 0.59Q01 2.-130 0.57346 0.59815 ' 0.59844

Ca 29.30155 2.508 28.45347 29.69592 29.75527Cd 0.59102 2.302 0.57532' 0.59345 0.59930Co 0.59901 2.501 0.53TQ3 0'.60756 0.60844Cr 0-.S9569 2.520 0.57836 0.60378 0.60492

__j*u ' 0. S0184 2.223 0.58547 0.61038 0.60819F* 29.51503 2.578 23.53668 29.93153 29.97598K 30.76266*2.236 29.96953 31.19602 31.12242

_Mg 29.3.8459 2.421 23.56411 29.82855 29.76141Mn 0.59767 2.546 0.58010 • 0.60630 0.60661'Mo 0.59291 2.905 0.57302 0.60284 0.60289Na 30.27381 1.S96 .29.61208 30.56804 30.64130

_ivH 0.59949 2.559 0.58193 0.60624 0.61029_Pb 0.59238 2.180 ' 0.57755 0.59843 0.60117_^b 0.60735 2.755 " 0.58805 0.61781 0.61622_Se 0.58788 2.205 0.57305 0.59706 0.59354_-;n 0.56599 1.834 0.55545 " 0.57565 0.58987_1,- ' 0.58915 2.455 '0.57240 0.59331 0.59676_Ti 0.50300 2.513 0.59032 0.51667 0.61702_Tl 0.55250 1.890 0.57979 0.59579 0.60093_/ 0.57369 2.451 0.55746 0.53195 0.53167_f 75537.00000 2.241 25249.00000 25240.00000 25272.OOOGO

Zn 0.58545" 2.495 . . 0.56865 0.59253 0.59517

83ftR305033

\- age: / - -~ - - . ; -7 4 ' ; - .

LANCASTER LABORATORIES .

Pun Name: 96T9904T52 'INSTRUMENT ID: v5?3-f:

Tube: 5 . IC3 .... .."--,- ". ,07/17/96 13:37

AVG - INTEGRATIONSELEM (ppm) %RSD SI , 32 S3 REREAD REDIG

_Ag 0.00008 258.2 -0.00016 0.00015 0.00025 _________Al 0 . CC063 ,755'.7 0.00103 0.00521 . -0.00441 ____ ______As -0.00199 89-. 94 " -0.00019 -0.00378 , -0.00201__3 0.00406.21-97 0.00503 ' ' •' 0.00344 - 0.00355_Ba 0.00010 33.32 Q.OOOQS 0.00014 0.00008_3s • .'.- 0.-0-0045 24.07 "" " 0.00041 0.00037 0.00053_Ca - - -"0.05170 1.375 -0.05065 -0.05192 -0.05255_Cd • ' 0.00014 125.5 0.00.034' ' 0.00000 0.00007_Co -0.00002 552.0 -0.00018 -0.00003 0.00013_CP 0.00012 139.3 0.00030 -0.00005" 0.00013_Cu -0.00022 145.8 -0.00060 -0.00007 . 0.00000_Fe Q.01885_40.27 0.01430 ' 0.02762 0.01464-_K 0.11523 1.611 0.11731 . 0.11452 0.11374_fig 0.00380 47.11' 0.00628 - 0-. 01359 0.00653_Mn 0.00014 39.50 0.00021 0.00009 0.00014_Mo 0.00122 71.54 - 0.00210 0.00122 0.00034_Na 0.1828644.37 0.27545 ' 0.13195 0.14020_Ni O.OOG14 '543.9 • 0.00077 -0.00077 0.00045_Pb -0.00041 271.0 -0.00170 0.00003 0.00041_3b 0.00.321 13.31 0.00317 0.00367 0.00278_Se 0.00210 '22.71 Q.00236 0.00240 0.00155_Sn . -0.00015 462.0 -0.00090 -0.00007 0.00051_SP 0 ._Q_001019.95 0.00012 0.00011 0.00008_Ti 0". 00020 20.92 0.00013 0.00017" • 0.00025_TI • "0.00388' 47.87 0.00551 0.00191 0.00413._V . 0.00059 42.12 0.00086 0.00052 0.00033_Y 25396.66501 0.375 25351.00000 25822.00000 26007.00000

Zn -0.00010 359.2 0.00005 0..00016 . -0.00054

p a g e : 8


Run Name: 9619904T52 ' •_ INSTRUMENT ID: 0593-f

Tube: 7 CRI 07/17/95 13:42

AVG INTEGRATIONSELEM (pom) %RSD SI S2 S3 REREAD REDIG

_Ag 0.02102 2.890 0.02170 0.02053 0.02083_Al ' 0.00723 125.9 0.01711 -0.00031 0..00539_As 0.01751 9.567 0.01653 0.01651 0.01945_3 0.00362 3.650 . jD. 00385 ' 0.00325 0.00373_6 a -0.0000530.53 0.00010 0.00000 0.00005_8a 0.01059 1.802 0.01037 0.01072 0.01063_Ca - . -0.05155 1.797 • -0.05229 -0.05208 -0.05059__Cd 0.01079 2.925 0-01113 0.01050 0.01075_Co 0.10434 1.947 0.10663 0.10306 ' 0.10327_Cr 0.02026 1.309 0.02054 0:02001 0.02024_Cu 0.05050 0.842 0.05099 0.05030 0.05021_Fe 0.02181 -23.47 ' 0.02530 0.01464 0.02549_K 0.11242 2.832 0.11563 0.10915 0.11247_Mg 0.00516 33.53 . 0.00627 0.00373 ' 0.00848_Mn 0.03139 2.230 0.03220 0.03092 ' 0.03107_Mo 0.00125 37.41 0.00167 0.00135 0.00074_Na . 0.18404 52.79 • 0.20217 0.07909 0.27085_Ni 0.03373 2.090 0.08568 ' 0.08222 0.08344_Pb 0.00532 19.14 0.00645 0.00443 0.00503_Sb 0.12539 0.515 0.12667 0.12512 0.12537_Se 0.01050 5.892 0.00979 0.01093 0.01079_Sn 0.00085 31.93 Q.QQ032 0.00164 0.00059_SP 0.00005 23.15 . 0.00005 0.00004 0.00007_Ti 0.00014 66.53 0.00014 0.00005 ' . 0.00024_Tl 0.02421 16.53 0.02396 o! 02834 0.0203-4_-•! 0.10155 2.119 0.10404 0.10040- 0.10023_Y 25655.00000 1.540 25179.00000 25915.00000 25900.00000

In 0.04315 1.S03 0.04380 0.04223 Q.nd.3<iS

flR305035

p 5 C1 •=a " r5 • i - . 4


Run Name: 951990-4T52 . INSTRUMENT ID: 0593:

Tube: 3 ICSA 07/17/95

AVG - . INTEGRATION?ELEM (ppm) _._._.%RSO S1 S2 S3 REREAD REDIG

_Ag 0.00024 70.23 0.00004 - 0.00034 0.00034 _________Al 536.29962 4/551 565.10556 " 522.01141 " 521.73032;_As- -0.00271 139.0 : -0.00087 "' -0.00555 ""-0.00235_S "" " ," O.Q09JD4 2-296 O.Q092~3 O.QQ392 0.00392__Sa ". 0.00"8?3~'"3"..S17 .0.-. 00933 0.00877 G. 00863_3e -0.00228 37.90 -0.00323 -O.QO"180 -0.00177_Ca ' 522.70996 4.917 552.36735 503.89764 505.35431_Cd ' -0.00696 2.120 ' "."-0.00713 -0.00590 -0.00585_Co 0.00122-12.93 .0.00141 0.00116 0.00111_CP -0.00055*81.68 ""-0.00005 ' -0.00093 -0.00065_Cu - -0.003025*33. i'Y "-0.004T3 -0.00220 -0.00272_Fe 211.466444.539" '" 222.55868 206.15277 205.57733_;_K 0.10983 5.184 0.11604 0.10485 0.10360_Mg 549.54748 4.372 577.29010 536.13280 535.15961'_Mn "" 0.00533 7.532 0.-00587 • 0.00599 0.00612_Mo ' -0.00046 253.7 ' O.""0005_5 -0/00035 -0.00167_Na 0.20537 35.70~ _ 0.26369 0.22936 0.12305_Ni 0.00175 13.90 ""0.00'l-&9 0.00203' 0.00156_Pb 0.00464 38.78 0.00505 0.00257. 0.00620._Sb. 0.01130 16.47 0.01021 0.01345 ' 0.01024_Se 0.00533 57.53 0.00824 0.00555 0.00212_Sn 0.00558 64.94 0.01162 0.00502 0.00342_SP 'oV02097 4.345 0.02203 " '0.02045 " " 0.02044_Ti -O.OQ107 11.29 '' -0.00120 -0."00096 -0.00107_Tl -0 .00352 n 55. 8 "" -0.00464 0.00245" -C. 00858_V 0.00188 65.37 _ 0.00333 ' 0.00106 0.00125_Y 23207.00000 3.694 22217^.00000 23694.00000 ' 23710.00000

Zn 0.00368 16.10" 0^00388 0.00415 0.00301

AR30503686

10 ' •


Run Name: 9519904T52 . . INSTRUMENT ID: 0593f

Tube: 9 ICSAB . ._ .. 07/17/96 13:50

AVG INTEGRATIONSELEM f.ppm) %RSD S1 S2 *3 REREAD REDIG

_Aa 0.22244 0.535 0.22147 0.22392 0.22193_Al 530.05273 0.565 527.66'833 533.41516 529.07470_As 0.10453 1.505 0.10335 0.10390 0.10631_5 0.03350 2.233 0.'03265 0.03330 0.03406_Ba 0.54076 0.421 0.53894 0.54332 . O.b4002_Be ' 0.49952 0.544 0.49742 ' Of. 50323 0.49791_Ca 509.02105 0.759 506.58523 513.47717 507.00079_Cd 0.35609 0.743 0.96110 0.97432 0.962-35_Co '0.50597 0.495 0.50374 0.50869 0.50549_CP 0.50617 0.784 0.50367 0.51075 0.50409_Cu -0.56206 0.387 • 0.559'97 0.56431 0.56183_Fe 207.25120*0.558 205.33244 208.31375 206.60243_K ' 0.13800 0.784 0.13872 0.13351 0.13675_Mg 540.06097 0.652 537.32537 544.04003 538.31756_Mn 0.51811 0.618' 0.51599 0.52180 - 0.51553_Mo 0.00153 43.25 0.00077 0.00199 0.00183_Na 0.20369 24.07 0.15022 0.21426' 0.24658.__Ni " 0.98729 0.320 0.98195 0.99661 • 0.93331_Pb ' 0.05735 3.118 0.05863 0.05806 0.05532_Sb 0.55011.0.906 0.54456 0.65637 ' 0.64929_Se ' ' 0.05388 4.300 0.05255 0.05254 ' 0.05656_Sn 0.00275 40.42 0.00253 0.00177 0.00398_SP ' O.G-2072 Q..453 - 0.02065 0.02033 0.02070_Ti -0.00097 3.433 -0.00094 -0.00100 -0.00098_TI 0.38935 3.344 .. 0.08994 0.08580 0.09280_V 0.50562 0.590 0,50491 0.51008 0.50433_Y 23621. OOO'OQ 0.573 23739.00000 23473.00000 23651.00000

Zn Q.94546 "0.755" "" "_0\ 94157 0.95370 0.94110

87AR305Q37


Run Name: 9519904T52 ' " T" INSTRUMENT ID: 05936

Tube: 10 CCV 07/17/96

A'v'G . ' _ INTEGRATION;-ELEM .OppmV" %RSD S1 . S2 ' .. S3 REREAD REDIG

_Ag 0.51206 0.549 '" 0.51511 0.50957 0.5115:_Al 25.12159 0.552 25.25843 ' 24.99229 25.10405_As 0.51419 0.235 0.5"1553 0.51355 0.513-43_3 0'.5S1655 0.475 0.51943 0.51530 0.51516_Ba • - 0".50336""0.505 0.50612 " 0.50112 0.502S4_Be . 0.50542 0.785 0.51000 0.50330 0.50297_Ca 25.04249 0.741 25.25487 24.91164 24.95097_Cd 0/50357 O."76'0 0.50801 0.50075 0.5Q224_Co 0.50777 0'.704 ""0.51191 / 0.50563 0.50578_Cr 0.50615 0.825 0.51091 0.50311 0.50443__Cu 0.50440 0.379 0.50650 • 0.50311 0.50349•_Fe 25.15302.0.769 25.37596 25.02313 25.05496_K 25.50997 0.506 25.73560 25.47635 25.51796_Mg ' 25.06646 0.633 25.25373 24.94386 24.99179_Mn 0.50936 0.691 0.51337" ' 0/50676 0.50794_Mo 0.50734 0.755 0.51175 0.50490 ' 0.50535

- Na 25.71 16~8 0.595 ' 25.88845 25.52537 25.62022_Ni - 0.51042 0.880 . 0.51541 0.50667. 0.50919_Pb 0.50129 0.488 0.50398 0.49920 0.50069_Sb 0.50758 0.371 0.50976 0.50650- 0.50649_Se • 0.50694 1.129 0.51078 0.5003-6 0.50957_Sn 0.49500 1.025 0.49936 0.48943 0.49621_SP 0.49595 0.508 . 0.49370 0.49375 0.4954-1_Ti " 0.51097 0.503 " 0,51445 0.50857 0.50989_Tl " "0.510010.505 0.51177 " . 0.51121 . 0.50706_V 0.4S631 0.715 0.49083 0.43480 0.48480

Y 25459.33398 CL492 25369.00000 "25510.00000 25429.00000Zn 0.50570 0.983 .-0.51141 0.50334 0.50234

AR3Q5038

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Tube: 11 CC3 07/17/96 13:59

AVG ' INTEGRATIONS.ELEM (ppm) %RSD S1 S2 *3 REREAD REDIG

_Ag 0.00007 51.19 0.00003 Q. 00010 0.00010 _____ ______41 0.03361 14.37 • 0.03917 0.03113 0.03051_As -0.00070 220.2 -0.00154 -0.00166 0.00108_3 0.01497 3.365 0.01516 0.01535 0.01440_Ba 0.00017 24.15 0.00020 0.00012 0.00013_Be 0.00031 33.99 0.00044 0; 00027 0.00.023_Ca • -0.02880 11.25 -0.02509 -0.03021 -0.03110_Cd 0.00027 18.37 ' 0.00024 0.00024 0.00033_Co ' 0.00009 440.6 0.00002 -0.00028 0.00054_Cr 0.00037 22.25 0.00030 0.00046 0.00035_Cu -0.00051 18.11 -0.00043 -0.00050 -0.0006V_^F~ 0.02725-6.720 0.02581 0.02928 0.02570'_K 0.11661 3.697 0.12020 0.11183 0.11781_Mg 0.03138 10.12 0.03504 0.02925 0.02935_Mn ' ' 0.00021 9.938 0.00019 ' 0.00023 0.00019_Mo 0.00133 35.04 0.00194 ' 0.00111 0.00108_Na -0.22117 21.50 0.21340 0.27215 0.17797_Ni 0.00006 419.2 '0.00020 . 0.00024 -0.00025_Pb -0.00015 524.5 0.00059 -0.00099 -0.00006_3b -0.00006 1573. -0.00108 0.00005 0.00034_Se 0.00016 501.4 -0.00019 0,00114 -0.00043_Sn 0.00115 135.0 0.00253 -0.00048 0.00133_SP 0.00009 11.32 0.00010 0.00009- 0.00008•_Ti 0.00010 28.50 0.00013 ' 0.00003 0.00009_Tl ' 0.00239 23.97 0.00215 0.00304 0.00195_V 0.00047 12.24 0.00053 . 0.00043 0.00043_Y 25943.56501 0.137 25890.00000 25956.00000 25935.00000

Zn ' 0.00009 333.9 "-Q". 00024 0.00015 0.00035

AR30503989

Page: 1 3 " - " . ' - Y " Y = ^ - - . " - - . . ' - „ . ' .

L A N C A S T E P. L A S 0 R A T 0 R I E S

Run Name: 9519204T62. . _ . . . , INSTRUMENT ID: 05935

Tube: 12 PSW 07/17/96 .19:04_ 100-1 00. DP 1 .9o1905720002. 3. .

AVG -INTEGRATIONSELEM (ppm) %RSD ... SI . S2 S3 REREAD REDIG

_ Aa 0_. 00052 '30. "05"""~ O.QO'0-63 : 0.00034 0.00059 ____ _____ Al 0.02208 11.50 ? O.QZ458 - ' 0.01950. ' - 0.02217 ____ _____ As -0.00169 52.25 -O.QO:267 : -0.00095 -0.00144^ B ' 0.01055 3.974 0.01007 : 0.01077 0.01082_ Ba 0 .00012' 24.33 • 0.00015 : 0.00009 0.00013_ Be 0. 00010 93.13 0.00.004 0.00022 ' 0.00005_ Ca ' -0.04130 3..139 -0.04014 - -0.04105 -0.04270_ Cd 0.00007^709.1 0.00017 -0/00010 0.00016_ Co ' 0.00003 1420. -0.00040 -0.00003 0.00053_ CP - 0.00043 151.7 0.00055 -0.00027 0.00103_ Cu ' -0.00048. 14.15 -0.00055" -0.00043 -0.00044_ F-e . ' 0.02176 8.397 0.02189 0.02351 0.01987_ K 0.11424 3.506 -0.11480 0.10999 0.11794_ Mg "0.01713 6."596 ' 0.01779. 0.01588 . 0.0'1788_ Mn 0.00012 44. 07 0.00006 ' 0.00016 0.00014_ Mo 0.00067 120.0 0.00031 ""0.00160 0.00010_ Na 0.20207 44.34 0.2'0700 0.11010 0.28910

Ml O.OOQ89 59.52" 0.00052" 0.00064 0.00150~7pb 0.00032 394.3 0.00122 -0.00115 0.00090_ Sb 0.00369 44.15 0.00209 0.00534 0.00353

• 0.00155 57:59 0.00161 0.00063" ~ 0.. 00242Sn • 0.00052. 227.5 0.00038 -0.00059 , 0.00180SP 0.000 05 16. 98 0.00005 O.QQ005 " 0.00007T1 Q/OQOT5 13.33 "0~. 00018 0.00013 0.00015Tl 0.00493 59.33 0.00166 0.00531 0.00731V 0.00023 1 1 1 . 5 0.00032 -0.00005 0.00044Y 25699.33398 0.231 25727.00000 25740.00000 25631.00000Zn 0.00286 11.05 0.00259 0.00278 0.00321

90

I

R =tge : 1 4


Run Name: 9619904T62 INSTRUMENT ID: 0593&

Tube: 13 LCSW -^w 07/17/96 "" 19:03. 1-1 , OF 1 .951905720002,8.. ,

AVG INTEGRATIONS'ELEM C.ppm) %RSD S1 S2 S3 REREAD P.EDI3

_ Ag 0.05127 1.073 0.05134 0.05068 0.05173_ Al 2. .17945 0.747 2.19285 2.16130 2.13421_ As 2.07336 0.551 . 2.08862 2.06301 2.08345_ B 2.14933 0.727 ' 2.16293 2.13250 2.15407_ 3a 2.01012 0.6-95 2.02188 1.99467 2.01332_ Be . 0.05062 0.449 - 0.05074 0.05036 0.05075_ Ca 4.09344 0.809 4.10985 4.05530 4,11515_ Cd 0.05047 0.879 Q'. 05075 0.04996 0.05071_ Co 0.51003 0.893 0.51367 0.50492 0.51150_ Cr 0.20480 0.910 0.20545 0.20270 0,20625_ Cu 0.25369*0.557 0.25495 0.25130 0.25432_ Fe ' 1.05010 1.105 1.05349 1.03716 1.05965_ K ' 3.34141 0.665 3.35040 3.31235 3.35149_ Mg 2.03355 0.807 2.04599 2.01494 2.03973_ Mn 0.51290 0.780 0.51495 0.50828 0.51546_ Mo 2.04568 0.706 2.05448 2.03000 2.05555__Na ' 4.01443 1.434 3.95227 4.06601 4.02503'_ Ni 0.51486 0.585 0.51603 0.51089 0.51756i/Pb 0.50605 0.369 0.50666 0.50137 0.51011_ Sb 0.52932 1.059 0.53385 0.52297 0.53114

2.02322 0.552 . 2.03627 2.01294 2.03545Sn 3.91664 0.754 3.93427 3.88254 3 . S33 1 2SP 1.02502 0.703 1.03193 1.01791 1.02815Tl 1.04727 0.732 1.05250 1.03847 ' 1.05035Tl 2.02450 0.599 2.03315 2.01063 2.029T3V 0.49292 0.731 0.49544 .0.48849 0.49433Y 25534.00000 O.S25 25507.00000 25314.00000 25531.00000Zn 0.50849 .1.026 0.51189 0.50248 0.51110

UR3050U

1 5 ' . - . " ' " ; ; - - T " "


Run Name: 9619904TS2 INSTRUMENT IQ: 05935

Tube: 14 2538238 C5>$(, 07/17/95 -19:121 00-100 , DP'1 .. 961905720002.. 8 , ..' ._.__..

AVG INTEGRATIONSELEM (ppm)' %RSD S1 ' S2 S3 REREAD REDIG

_ Ag " 0.00033 1.23.2 '_ -0.00009 0.00071 0.00033Al 0.03084 30.70 0.04122 ''. 0'. 02257 0.02865As -0.00099 107.2 -0.00201 -0.00107 0.00011

_ B , 28.65845 1.746 '29. 23025 23.29908 28.44602_ 3a 0.07263 1 /95~1 0.07430 0.07158 " 0.07205_ 3e -0.0-0039 31.64 -0.00076 -0.00018 . " -0.00023_ Ca '. 75 . 08985 1 .895 76.73095 74.18225. 74.35536_ Cd 0.0006 6 51. 94. 0.00072 .0.00098 0.00029.Co ' 0.00055 54._93 0.00023 0.00084 0.00058

_ CP - 0/00056. "14". 04 "0/00052 . " 0.00050 0.00065_ Cu 0.00455^3.355 0/00425 0.00504 0.00468_ Fe -0.04443 37.94 -0.05877 -0.02586 . -0.04865_ K" -0/93172 1.723 "~"0. 95020 0.92123 0.92372_ Mg 33.19788 1.911 33.92617 32.75452 32.90295_ Mn • 0.00252 3.226 -0.00256 0.00257 0.00243_ Mo 0.00331 56.39 0.00527 0.00314 0.00153. _ Na 31.66853 1 . 9 1 0 '. 32.35788 31.22542 . 31.42230_ N1 • 0.00230 28.-11 0/00150 0.00242 0.00233V_Pb 0.00019 1156. -0.00052 - -0.00164" 0.00276

Sb 0.00135 160.9 0.00359 -0.00075 0.001220.00131 144.4 0.00349 0.00000 0.000440.00290^48". 70 Q.QT369" " 0.00375" 0.00127

Sr 4.54770 1.924 4/74997- 4.53398 . 4.60916yt 0.00000 3090. -0.00001 0.00007 . -0.00004T1 "O.Q0628 8.041 ' 0:00582 '0.00519 0.00682V 0. 00063" 40V38 " 0.00052 0.00093 0.00045y 25137.00000 1.706 -24648.00000 25450.00000 25313.00000Zn -- 0/01>50 2.341 0.01799 ' 0". 01751 0.01700

AB3050i»2

P a g e : 1 6

LANCASTER LABORATORIES '

Run Name: 9619904T62 . . INSTRUMENT ID: 05936

Tube: 15 2533233 -J^-J^r* 07/17/96 19:17UP**. 100-1 00. DF1 .. 961905720002,8.. . ''

AVG INTEGRATIONSELEM' (ppm) %RSD S1 S2 S3 REREAD REDIG

_Ag 0.02030 2-. 104 0.01988 0.02030 0.02074_Al 0.44295 0.351 0.44115 0.44395 0.44375_As 0.01901 11.17 0.02048 0.01658 0.01999_B 27.36323'0.103 27.83085 27.38650 27.87233_Sa 0.47401 0.210 0.47332 Q.47515' 0.47355_Be . 0.01033 0.349 ' O."01037 - 0.01033 0.01030_Ca 73.24332 0.301 73.04470 " 73.20462 73.43063_Cd 0.010'52 1.544 0.01049 0.01038 0.01070_Co 0.10175 0.120 0,10164 0.10173 0.10183_CP 0.02012 2.164 0:02012 0.01969 0.02055_Cu 0.05607"0.788 0.05590 0.05574 0.05657_Fe 0.14955 5.555 0.13998 0.15488 0.'15380_K 2.83732 0.362 2.37542' • 2.39149 2.39505_Mg 33.04239 0.139 32.98999 33.06119 33.07598_Mn 0.03353 0.163 0.03354 0.03348 0.03359_Mo 0.20707 0.513 - 0.20616 0.20654 0.20852_Na . 32.79742 0.223 ' 32.77262 32.73990 32.87974_N1 0.08319 1.232 0.08289 0.08235 0.03433_Pb 0.01027 1.2.50 0.00927 0.00982' 0.01172_Sb 0.12753 1.260 0.12609 ' 0.12750- 0.12930_Ss ' O.Q1165 11.07 0.01310 0.01121 0.01063_Sn 0.54995 0.061 0.55022 0/54957 0.55008_SP 4.50885 0.207 4.49871" 4.51719 4.51066_Tl 0.10285 0.087 0.10280 0.10279 0.10295_Tl • 0.02409 ' 10. 15 0.02526- 0.02123 0.02574_V 0.09751 0.445 . 0.09783' O.Q9701 0.09763_-f 25363.33393-0.131 25374.00000 25390.00000 25326.00000

Zn 0.06552 0.554 "' '""0.06505 0.0"S562 0.06589

Page: 1 7 " . _ _ " . , " . ' . "


Run Name: 9519904T62 Y . . "INSTRUMENT ID: 05936'-/

Tube: 16 2538233" JCÔ D 07/17/96 19:210***. 100-100..DF1 . 961905720002. 3. ; ' :

AVG • -INTEGRATIONSELEM (pom) .%RSD. SI . -. S2 . ... . S3 REREAD REDIG

_Ag 0.00008 .396'.-4" . 0.00043 -0.00017 -0.00001_Al 0".00787 90:08- 0.01'242 0.01150 . -0.00029__As -0.00314 63.59 -0'. 00114 . -0.00314 -0.00515_B ' 28.17375 0.737 ' 23.28365 ' 28.30355 " 2.7.93404_8s ' 0.07123 0.706 0.07154 0.07160 0.07070_Be 0.00017 127.5 0.00002 "~ 0.00007 0.00042_Ca ' 74. 3295"8_ 0.553" 74.60099 "'" 74.61898 73.75879_Cd 0.00045 22.34 0.00051 ~ 0.00052 0.00034_Co 0.00041 8.265 0.00037" " 0.00043 0.00044_CP 0.00012 438.2 0.00011 0.00057 -0.00041_Cu " 0.00515-4.625 0.00490 0.00517 0.00533

Fe - -0.05194 15.27 -0.'04325 ; -0.05376 -0.058803j< -- 0.90923 1.531 0.92386 ' 0.90768 ' 0.89515_Ma 32.65649 0.311 32.80990 32.80899 32.35056_Mn 0.00241 2.940 0.00234 ' 0.00243 0.00241_Mo 0-.00154 31.55 0.00098 ""0.00187 0.00176_Na 31.03284 0.687 - 31.17214 . .31.13903 30.73734

Ni ( 0.00071 63.30" 0.00113 0.00023 0.00079"Tpb 0.00128 108.2 " . -0.00002 ' 0.00275 0.00114_Sb 0.00062 '30.09 0.00069 0.00041 0.00075_/_Se • 0.00117 66.54 -0.00032 . 0.00131 0.00136_on o 00184 50.44 0.00153 ' 0.00110 0.00289_SP 4.56852 0.720 '4.58526- 4.58939 4.53070_Tl -0.00011 17.34 -0.00010 -0.000*10 -0..00013_Tl ' 0.00508 22.51 0.00534 """"0700383 0.00507_V 0.00017 35.76 0.00010 0.00019 0.00022_Y 25795.66601 0.335 25635100000 25697.00000 26058.00000

Zn 0.01594 1.256 ' 0.01708 0/01704 '.. 0.01669

94AB30501»l»

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Run Name: 9519904T62 . INSTRUMENT-. ID : 05935

Tube: 17 2533238 JC"bC > 07/17/96 19:26R***. 100- 100. OF 1 ..96 1905720002, 8r ,

AVG INTEGRATIONSELEM (ppm) - %RSD . . S1 - S2 S3 REREAD REDIC-

_ Ag 0.0511V 0.423 0.05135 0.05093 0.05106_ Al 2.25783 1.389 2.28575 2.22446 2.26229_ As ' -0-04045 4.439 0.03357 0.04215 0.04062_ B 3'0. 15939 1.184 30.46112 29.77095 30.27610_ 3a 2.03436 1.219 2.05536 2.00693 2.04074_ Be '•- - 0.05168 0.746 0.05193 0.05.124 0.05187_ Ca 78.86052 1.063 79.54109 77.92330 79.11719_ Cd ' 0.05084 1.124 0.0.5131 0.05021 0.05102._ Co 0.51113 1 ..1 1 1 0.51519 0.50498 0.51221_ CP ' 0.20495 0.880 0.20633 0.20291 0.20561_ Cu 0.25659 '1 . 160 ' 0.25929 0.25340 0.25710_ Fe ' ' 0.98766 0.080 0.98849 0.98690 0.98758_ K 4.89549 0.998 4.93533 4.84096 4.91014_ Mg 34.58027 1.135 35.03877 34.23165 34.77038

, _ Mn 0.51545 1.169 0.52034 -0.50872 0.51729: _ Mo 2.04232 0.954 2.05740 • 2.02031 2.04925_ Na 35.19176 0.843' 35.41680 34.85525 35.30322_ N1 0.50936 1.213 0.51275 0.50223 0.51311S'Pb 0.02186 2.203 0.02149 0.02167 0.02240

Sb 0.52704 0.552 0.53013 0.52423 0.5257*0.01280 12.37 0.0'1373 0.01369 0.01097

Sn 4.08819 1.145 • 4.13220 4.03392 ' 4.09345Sr 5.70766 1.154 5.762'12 5. .53356 5.72723Tl 1.03998 1.132 1,04974 1.02691 1.04330Tl 0.05275 1.784 0.05340 0.05167 0.05313V 0.49025 1.120 0.49485 0.48417 0.49173Y 25310.33393 1.054 25534.00000 26073.00000 25819.00000Zn 0.52701 1. 029 0.53260 0.52176 0.52857


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Tube: 18 2538238 ? — 07/17/96 19:30UL*X, 100-100, DF5. 96.1905720002,8, ,

' AVG . INTEGRATIONSELEM (ppm) %RSD . . S1 . _ S2 S3 REREAD REDIG

__Ag -0.00007 185.1 -O.OOOQ7 -0.00023 0.00006 ____ _____ Al -0.00354 20.09 " -0.00412 ' -0.00374 " -0.00274 ____ _____ As -0.00132 133.0 -0.00036 -0.00025 -0.00336_ B . 5.74841 0.634 - 5.78_680 5.74421 5.71423_ Ba 0.01439 0.536 0.01443 0.01435 0.01433_ Be 0.00048 15.59 0.00040 0.00050 - 0.00055_ Ca ' 15.07599 0 /3~96 15/14435 ' ' 15.05062 15.03301_ Cd 0.00032 38.86 'o/QOOSl 0.00045 0.00020_ Co ' 0.00016 271.4 0.00038- 0.00043 -0.00034_ CP . 0.00029 51.63 0.00013 0.00044 0.00030___Cu 0.00134 "13'.82 .0.00125 0.00122 0.00156_ Fe -0.00027 822.5 0.00004 " -0/00267 0.00180.._ K . 0.26650 1.058 0.26463" 0.26974 0.26513'._ Mg 6.52387 0.488 ' 6.55458 ' 6.52605 6.49098_ Mn 0.00066 1.106 ' 0.00065 " 0.00065 . 0.00067._ Mo 0.00220 38.14 0.00309 0.00208 0.00142_ Na 5.98303 1.544 6.07295 5.98777 5.88836 ._ Ml 0.00038 106.5 0.00029 0.00002 0.00082_ Rb 0.00055 18.51 0/00044 ' 0,00053 0.00063; _ Sb 0.00036 73.52 • 0.00017 0.00067 0.00024_ Se -0.00050 59.52 -0-. 00052 -0.0.0078 -0.00019_ Sn 0.00102 120.3 0.00230 .0.00094 -0.00016_ SP 0.87500 0.346 ' 0.37821 0.37462 0.87218_ Tl 0.0001 6 14. 52' 0.00018 ' 0.00016 " 0.00013_ Tl 0.00355 26.06 O.QQ'403 0.00256 0.00431_ V- ' 0.00 03 9 40. 12 .0.00051 0.00021 0.00044_ Y 25329.00000 0.134 25309.00000 25809.00000 25369.00000

Zn O.OQ592 3.491 0.00609 0.00559 0.00598

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Run Name: 9519904T62 - . INSTRUMENT ID: 05935

Tube:. 19 2538239 3 C 7_(E>Cx 07/17/95 19:34. 100-100. DF1. 96190 57 20002. 3, .-

AVG INTEGRATIONSELEM (ppm) %RSD S1 S2 S3 REREAD REDIC-

_ Ag . 0.00005 196.1 0.00015 -0^00005 0.00006_ Al 0/04413 7.222 0.04419 0.04729 0.04091_ As -0.00237 75.56 -0.00541 -0.00165 -0.00154_ B ' 72.42857 0.2Z9 72.23865 72.50081 72.54625_ 3a 0.01735 0.281 0.01783 0.01791 0.01782_ Be . 0.00052 29.77 0.00035 ' 0.00055 0.00066_ Ca . 16.19250 0.583 16.10000 16.13753- . 16.29027_ Cd 0.00059 38.70 0.00077 0.00066 0.00033_ Co 0..00095 40-.85 0.00059 0.00137 0.00090_ Cr ' 0.00041,64.23 0.00065 0.00012 0.00048_ Cu 0.00269*8.344 0.00255 0.00255 - 0.00296_ Fe 0.09326 9.465 0.09440 0.10147 0.08392_ K 0.81576 0.871 0.82374 " 0.81344 0.81011_ Mg 3.51139 0'.150 3.50717 3.50968 3.51733_ Mn 0.21866 0.505 0-. 21760 0.21857 0.21930_ Mo . - 0.02837 0.349 0.02847 0.02838 0.02827_ Na 112.43845 0.260 112.53718' 112.66926 112.10890_ N1 O.Q0107 43.91 0.00116 0.00056 0.00150.XPb . -0.00015 813/8 -0.00153 •' 0.00090 ' 0.00016_ Sb. 0.00-075 110.0 0.00159 -0.00005 0.00071Jk_Se 0.00193 19.23 0.00150 0.00217 0.00212_ Sn 0.. 00381 31.81 ' 0.00323 0.00299 0'. 00520_ SP 0.04912 0.205 0.04915 0.04919 0.04900_ Tl 0.00075 5.722 0.00071 0.00074 0.00079'_ Tl 0.00511 63.47 0.00384 "" "0.00345 0.00302_ V 0. 0009236.17 0.00120 0.00100 0.00055_ Y - 25960.00000 0,161 25912.00000 25989.00000 25979.00000_ Zn 0.01311 3.479 0.01304 ' . 0.01270 0.01350

97AR3050l*7

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Tube: 20 2538240 -3"C6"E-C_ 07/17/96.. 19:391 o 0 - 1 0 0 , D F 1 .. 9 6 1 9 0 5 72 0 0 0 2 , 3 ; ,

AVG INTEGRATIONSELEM (ppm) %'RSD ' S1 S2 S3 REREAD REDIG

_ Ag 0.00008 338.1 0.00045 -0.00011 -0.00008_ A.I -0.00512 165.4 0.00412 -0.01255 -0.00695_ As -0.00430" 51 .30 . -0.00280 -0.00323 -0.00686__8 10.06327 1/179 fO."l9974" 10.00624 9.98384_ Ba '0.05938 1.037. 0.06!0'09 0.05909 0.05897_ 3e 0.00047 58.21 0.00016 . 0.00070 0.00055_ Ca '"" 61.85872 1.035 62.59402 51.42151 51.56063_ Cd * 0.00033 82.51 _ 0.00058 0.00004 0.00037__Co 0.00022 104.8 "" "0/00015 * 0.00049 0.00002_ CP 0.00039 50.59 0.00050 '0.00016 0.00052_ _Cu 0. 00180* 8.957 ' "" 0/OOT52 " 0.00190 0.00190_ Fe -0.04263 28.02 -0.03256 -0.03949 -0.05583__K 0.90170 0.769 0.90971 0.89753 0.89788_ Mg 26. 43287 0.991 2617353.7 26.27172 26.29153_ Mn 0.0b~081 8.688 " . O.OQ'OSS " 0/00074 " 0.00082_ Mo ' 0.00147 39/62 0.00214 " 0.00105 0.00123

Na ' 33.17147 0.927 38.56024 38.08616' , 37.86300N1 0.00132 42.53 ' 0.00192" 0.00081 0.00122Pb 0.00062 140.8 0.00129 0^00096' -0.00037Sb ' 0.00242 93.86 0.00504" " 0.0.0112 ' 0.00109

0.00043 190.'0 0.00134 -0.00023 • 0.00018Sn 0.00098 40.87 - 0.00059 - 0.00140 0.00095Sr 5.08675 1.055 5.14873 5.05774 "• 5.05380Tl 0.00014 53. 50 0.00018 0.00018 0.00005Tl 0 .00285 21 .31 0.00356" 0.00261 0.0.0239V 0.00035 38.26 0.00051 0.00024 0.00031Y 25331 .33398 " 1.056 ' 25514/00000 26011.00000 25969.00000Zn 0.01256 0.888 0.01268 ' 0.01253 0.01275

H~

98flR3050l»8

p a g e : 2 2



Tube: 21 2538241 Tjc.fc 07/17/96 19.: 43100-100 fOF1 .. 961905720002, 8f.

AVG' ' INTEGRATIONSELEM (ppm) %RSD SI S2 . »3 REREAD REDIG

_Ag 0.00032 14.80 0.00037 0.00027 0.00031 ____ _____Al -0.00056 423.9 0.00145 -0.00328 0.00011

A-* -0.00018 366.3 -0.00024 0.00051 -0.00082~3~ 3.33752 0'.265 3.34769 3.33334 3.33152

Ba 0.17456 0.126 0.17480 0.17437 0.17451_B* - 0.00067 15.96 0.00056 0.00077 0.00067_Ca 33.12519 0.129 33.08900 33.1.1378 33.17279_Cd ' 0.00038 '27.86 0.00028 0.00050 0.00037_Co 0.00032 35.35 0.00034 0.00060 0.00004_Cr ' 0.00349 6.529 0.00331 0.00375 0.00341'_Cu 0.00370 "5.053 0.00356 0.00396 0.00358_Fe 0.02003 4.973 0.01930 0.02-117 0.01962_K • ' 67.52342 0.135 67.42530 67.53888 67.60610_Mg 0.43178 0.735 0.43433 ' 0.43278 0.42822_Mn 0.00059 16.66 0./00043 0.00063 0.00061_Mo 0.00292 7.668 0.00317 0.00274 0.00285_Ma 84.61407 0.038 34.58073 84.64627 34.61515

Nl 0.00173 18.96 '0.00200 0.00182 0.00136Pb 0.00114 19.62' 0.00095 0.00109 0.0013-9~Sb - 0.00219 131.8 ' -0.00082 0.00493 0.00246~Se 0.00064 399.3 -0.00023 -0.00133 0.00355~Sn 0.00192 90.27 0.00005 0.00222 0.00350"Sr- 4.78855 0.162 4.73752' 4.73136 4..79681"fi 0.00021 19.57 0.00025 0.00017 0.00019~T1 0.00190 62.23 0.00182 0.00076 0.00313~V 0.00022150.2 0.00000 0.00061 0.00007~Y 26217.33398 0.132 26139.00000' 26207.00000 25256.00000"Zn 0.01038 2.836 0.01045 0.01005 0.01063

A83050U999

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Run Name: 9619904T52 . . /.' INSTRUMENT ID: 05936

Tube:' 22 CCV 07/17/95 19:43

.AVG INTEGRATIONSELEM. (ppm) %RSD S1 ^ S2 S3 REREAD REDIG

_Ag 0.51238.0.102 0.51344 0.51239 \ 0.51281_Al 24.74525 0. 1 1'4 "24.75073" 24.71446 24.77057_As 0.5T801" 0/097 """"0.51755" 0.51855 0/51793_B ' 0.56605 1..192 0.57237 . ,0.56685 0.55395_Ba 0.49261 '0. 141 0.49251 0.49191 0.49331_Be 0.52378 0.345- " 0.52532 0.52424 0.52179_Ca ' 25.08230 0.407 , 25.14757 26.13965 25.95966_Cd ' 0.52093 0.485 0.52328 0.52128 0.51825_Co ' ' 0.52057 0'. 157 0.52121 0.52084 • 0.51965._Cr - 0.51935 0.293 0.52039 0.52008 0.51761_Cu • 0.49923 0.256 0.49938 0.49788 0.50042_Fe ' 25.35173 0.285 25.89773 25.89088 ' 25.76672•_K • ' 24.98751 0.187 24.99.198" 24.93869 . 25.03186_Ma 25.33372 0.019 25.33928 ' 25.33088 25.33099_Mn 0.51877 0.198 0.51936 . 0.51938 0.51759_Mo 0.51802 0 . 1 1 1 . 0.51835 0.51334 0.51735_Na ' ' '- 25.29555 0.378 25.19722 25.30097 25.38845_Ni 0.52224 0.231 0/52135 , 0.5'2362 '0.52176_Pb 0.51038 0.348 0.51238 0.5.0898 0.50979_Sb 0.51261 0.246 " 0.51144 ' 0.51395 " 0.51245_Se 0.50977 0.228 0.50878 0.51105 0.50948

. Sn ' 0.50522 0.290 0.50585 0.50401 0150480_Sr 0.48938 ~"b/T2Q 0.48913 0.48891 Q. 49004_Tl 0.51481 0.059 0.515 15 0.51433 0.5 1443' Tl 0.50839 0.899 0.50445 0.50733 0.51340_V 0.49414 0.056 "0.49390 0.49451 0.49400_Y 26039.00000 0.498 26099 ..OOOO'O 25128.00000- 25590100000

Zn 0.53577 0.627 0.53389 0.53621 0.53221

Ai3Q5Q5QJOO

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Run Name: 9619904T62 " ~~ " INSTRUMENT ID: 05935

Tube: 23 CCB - 07/17/96 19:52

AVG INTEGRATIONSELEM (ppm) %RSD S1 . H S2 S3 REREAD REDIG

_Ag 0.00018 83.55 0.00004 0.00035 0.00015_Al -0.02396 7.388 -0.02224 -0.02387 -0.02578_As' -0.00024 417.1 . -0.00025. 0.00077 -0.00124_B 0.04123 6.156 ' 0.04397 0.04077 0.03396_Ba 0.00017 22.56 0.00020 .0.00013 0.00017_Be 0.00114 6.311 0.00121 • 0.00107 0.00113_Ca -0.04297 9.606 -0.03821 -0.04535 -0.04537_Cd "0.00038 23.32 0.00032 0.00033 0.00048_Co 0.00036 89.58 0.00070 0.00035 0.00004_Cr 0.00003 13'4.3 0.00018 0.00008 -0.00002_Cu ' 0.00128. J8.70 . 0.00105 0.00'l53 0.00124_Fe 0.01764 25.38 0.01248 0.02048 0.01996_K -0.11759 4.436 0.12177 0.11927 0.11175_Mg 0.01170 27.46 0.01531 0.00912 0.01068_Mn 0.00018 43.94 0.00028 ' 0.00014 0.00013_Mo 0.00143 54.08 0.00216 0.00153 0.00061_Na 0.20500 37.75 9-16812 0.15294 0.29393_Ni 0.00028 248.7 -0.00052 0.00070 0.00066l_Pb 0.00033 508.2 0.00211 • 0.00015 -0.00125_Sb . 0.00250 33.75 0.00281 0.00155 0.00315_Se 0.00034 312.4 0.00118 0.00070 -0.00085_Sn 0.00031 .74.53 ' 0.00116 0.00116 0.00011_Sr 0.00054 30.95 0/00073 0.00045 0.00042_Tl 0.00013 93.71 0.00027 0.00008 0.00003_Tl 0.00350 32.65 0.00382 0,. 00233 0.00456_V 0.00034 60.37 0.00029 0.00016 0.00057_Y 26446.33398 0.043 26457.00000 25448.00000 2'6434. OOOOO_Zn -0.00008 293.5 -0.00034 ' 0.00014 -0.00004

ioiAB30505I

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Tube: 24 2538242 3"C.T<2>& 07/17/96 19:56xxxx; 1QO-1QO,DF1,961905720002,8, ; . . . ' '

AVG INTEGRATIONSELEM (ppm) %RSD S1 S2. S3 REREAD REDIG

_Ag 0.00015 179.8 0.00020 0.00039 -0.00014_Al --0.01953. 8. 160 -0.02135 -0.01879 -0.0184.5_As -0.00086 "1 19 .7 -0.00136 -0.00153 0.00032_B 0.03134 8.674' 0.03434 0.03066 0.-02903_Ba ' 0.00.0-12 27.44 0.00014 0.00014 0.00008__Be ' 0.00073 9.737 0.00057 ' 0.00070 0.00031_Ca ' -0.04173 1.869 -0.040"95 .-0.04190 -0.04250_Cd 0.00033 51.07 0/00015 " -0.00050 0.00035_Co -0.00013 313.6 -0.00058 0/00028 -0.00012_CP -' 0.00040 117.4 ' 0.00024 0.00093 0.00002_Cu "0/00102 22.29 "" O". 00080" "" 0.00100 0.00125_Fe 0.02181 41.44 . 0.02122 0.03113 0.01308_K 0.12170 1.683 0.11939 0'.12331 0.12239_Mg 0.00639 2.981 ' 0.0051.7 ' 0.00651 0.00650_Mn 0.00017 7.549 . 0.00016 0.00016 0.00018_Mo 0.00069 88.14 0.00014 0.00059 0.00135__Na 0.15511 -68.54 . 0.19147 ' 0.24097 0.03590

N1 0.00072 128.3 0.00024 0.00013 ' 0.00178-O.OJD001 5013. _ 0.00070 -0.00079 0.00005

Sb 0/00293 47.34 0.00134 '0.00392 0.00353Se 0.00037 191 .2 . 0.00111 0.00035 -0.00033'Sn 0/00053 174.7 0.00147 -0.00039 0.00052SP' 0.00033 7.965 0..00034 0.00034 0.00030Tl 0.00013 51.50 0.00012 0.00023 ' 0.00005Tl . 0.00107 240.2 0.00286 -0/00187 0.00221V 0.00027 55/72 0.00035 0.00040 0.00006Y 26081.66601 0.084 26107.00000 26058.. OOOOO' - 25070.00000Zn 0.00321 9.982 0 ."00334 0.00344 0.00284

102ftB305052

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Run Mame: 9619904T52 " INSTRUMENT ID: 05935

Tube: 25 CRI 07/17/96 20:01

AVG - INTEGRATIONSELEM . (ppm) . %RS.D S1 S2 . #3 REREAD REDIG

_Ag 0.02110 2.104 0.02134 0.02137 0.02059_Al -0.01933 7.341 -0.01814 -0.01906 -0.02093_As 0.02174 12.47 0.02152 • 0.02455 0.01914_B 0.03442 4.306 0.03536 0.03519 0.03271_Ba 0.00004 150.1 .0.00008 0.00009 -0.00003_3S ' 0.01155 0.996 0.01142 ' 0.01163 0.01161_Ca -0.04813 1.617 -0.04761. - -0.04775 -0.04902_Cd 0.01090 1.520 ' 0.01105 " 0.01093 0.01072_Co 0.10720 0.592 0.10720 • 0.10783 0.10555_CP 0.02132 1.233 0.02101 0.02151 ' 0.02145_Cu 0.05221 0.135 0.05223 0/05222 0.05214_Fe . 0.01137*6/942 0/01220 0.01247 0.01093_K ' 0.11695 0.508 0.11752 . ' 0.11648 0.11675_Mg 0.00636 9.937 0.00618 0.00707 0.00584_Mn 0.03201 0.045 ' 0.03202 0.03200 - 0.03200_Mo 0.00039 75.37 0.00108 0.00145 0.00014

Na 0.17632 41/57 0.09214 0.22619 0.21062_N1 0.08553 0.906 ' 0.08530 . 0.08569 0.08476_Pb 0.00589 9.540 0.00587 0.00646 ' 0.00534_Sb 0.12539 1.050 0.12649 0.12501 0.12766_Se 0.01173 15.33 0.009.68 0.01244 0.01305_Sn - 0.00112 50.25 8.00132 0.00167. 0.00036_SP 0.00014 6.789 0.00015 0.00015 0.00013_Tl 0,00009 74.51 0.00015 0.00007 0.00003_Tl Q 02380 10.54 0.02543 0.02341 0.02151_V 0.10285 0.181 0.10305 _- 0.10269 0.10232_Y 26147 .00000 ""0.235 26083 . O O O O O ' " "2"6206/OOOOO 25152.00000

Zn 0.04615. 1.555 G.04594 0.04602 0.0^552

103

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Tube: 26 . ICSA . . . 07/17/96. 20:05

AVG ' . INTEGRATIONSELEM (ppm) %RSD S1 S2 S3 REREAD REDIG

Ag -0.00031 231.0. -0.00131 0.00033 0.00003_Al 509/361 -M 3.763 520.30731 487.20028 '' 520.07574_As -0 .00394/24.40 "-0". 00'29~5" ' -0.00487 -0.00401_B 0.03114 3/333 0-03165 ' 0.02976 " 0.03201_Ba 0.008.15 3.562 0.00826 : 0.00782 0.00839_Be . -0.00073 89.04 -0.00129 0.0.0001 -0.00107-

Ca 519.01373 31458 526.94139 498.46478 531.63458~Cd -0.00733 2.374 _ -0.0073-1 /. -0.00726 -0.00758_Co- 0.00017 359.0 Y" -0.00044 ' .0.00080 " 0.00016_Cr -0100053 42.23 -0.00079 -0.00033 -0.00042_Cu -0.00007' 1470. -0.00132 0.00094 0.00014

Fe 205.80809 3.484 210.57258 198.49946 211.35221_K 0.11402 1.959 0.11338 0/112-18 0.11651_Mg 533.82452 3.280 543.85034 513.60113 544.02203_Mn 0.00608 3.474 " 0.00628 ". 0.00586 0.00611_Mo -0.00057 216."9 -0.00037 0.00056 ' -0.00190_Na 0.22683 19.31 0.21597 " 0.18948 0.27505_Ml 0.00144 14.11 0.00162" " 0.00150 0.00122_Pb 0.00265142.1 " -0.00016 ' 0.00118 0.00695_Sb O.Q0641 66.64 0.00385 0.00404 0.01135_Se _0 . 00462 - 34. 06 ~ " 0.00504 0.00594 0.00288_Sn 0.00353 105/5 0.00781 0.00037 0.00257_Sr ' 0.02000 3.441 ' 0.02044 0.01920 . 0.02035_Tl -0.00115 21 .51 -0,00139 -0.00090 -0.00116_Tl -0.00924 "54.14 -0.01501 -0.00605 -0.00666_y 0.GO 255 29.51 0.00301 0.00168 0.00297_Y '24671.33398 3.403 24135.00000 "25639.00000 24240.00000

Zn 0.00357 32.90 ~0~.00243 0/00342 0.00482

104A830505I*

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Run Name: 9619904T62 ._ ~ - - - INSTRUMENT ID: 05935

Tube: 27 ICSAB ' 07/17/96 20:09

AVG INTEGRATIONSELEM (ppm) ... %RSD S.1 . .#2 S3 REREAD REDIG

_Ag 0.22358 0.313 0.22330 0.22305 0.22437 _________Al 525.23840 0.533 524.01855 524.92285. 529.77374_________As' 0.10685 1.134. -0.10550 0.10722 0.10784'____ _____B 0.04659 1.489 0.04640 ' 0.04601 0.04736 ____•_____Ba -0.53150 0.627 0.52350 0.53102 0.53519 ____ •_____Be 0.51626 0.460 0.51637 0.51353 0.51326 _________Ca • 526.07531 0.614 527.57922 522.36230 528.28442 ________._Cd ' 0.93381 0.435 0,99167 0.93326 0.99151 _________Co 0.51375 0.363 0.51407 0.51176 0.51546 _________CP 0.51525 0.607 0.51533 - 0:51210 . 0.51835_Cu 0.56329 0.698' 0.55927 0.56347 0.56713_Fe 210.98617-0.535 211.09193 209,80622 212.06034_K 0.13544 3.575 0.14091 0.13169 0113371_Mg 546.17248 0.535 545.12011' 543.91760 549.47967_Mn 0.52498 0.454 0.52516 '0.52251 ' 0.52727_Mo ' 0.00126 183.6 -0.00099 ' 0.00364 0.00114_Na 0.23"195 6-3.73 0.39133 0.09928 0.20528_Ni 0.99655 0.440 1.00097 0.99219. 0.99650_Pb 0.05563 3.201 0.05395 ~~ 0.05545 0.05749_Sb O.Q5006 0.691 0.65423 0.64533 0.65056_Se -0.05714 2.325 0.05844 0.05721 0.05578-_Sn 0.00359 27.72 0.00300 - 0-.00303 0.00474_SP 0.02059 0.584 . 0.02049 0.02055 0.02072_Tl -0.00126 6.311 -0.00117 -0,00125 -0.00135_Tl 0.13863 53.35 0.08930 0.10206 0.22452_V 0.51252 0.429 0.51272 .0.51037 0.51476_Y 23965.33398 0.644 24015.00000 24088.00000 23792.00000_Zn - 0.98756 0.707 0.99299 0.97975 0.9'9023

flfi30S05S105

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Run Name: 9619904T62 " - INSTRUMENT ID: 05936

Tube: 28 CCV 07/17/96 20:14

AVG ' INTEGRATIONSELEM (ppm) ' %RSD S1 ' • #2 -S3 REREAD. REDIG

_Ag. 0.51456 0.038 0.51468 0.51486 0.51433 • _ _ _ __Al 24.79538 0.038 24.73683 24.30549 24.79380 ____ ______A.s 0.52146 0.557 0.52469 0.52054 0.51905 ____ _____3 - 0.52933 0.068 0.52914 0.52974 0.52910_Ba 0.49181 0.063 ' 0.49,154 0.49215 0.49173_8e 0.52925 0.324 0.53109 0.52899 0.52770_Ca 25.23450 0.422 2"6.34890 26.22750 25.12732_Cd ' 0.52"338""OY33'5 0/52534" 0.52284 0.52195_Co 0-5235-6 0.250 0-52519 0.52257 0.52321._CP 0.52141 0.398 0.52346 0.52147 0.51931_Cu - 0.50423 0.118 0.50370 " 0.50410 ""0.50488_Fe '25.92364 0.234 26.00367 25.90898 25.85825_K 24.83121* 0. 148 24.80279 24.81781 24.87303_Mg 25.41539 0.099 25.44416 25.40545 " 25.39655-_Mn 0.52026-0.362 0/52222 0.52009 0.51847__Mo ' 0.52095 0/330. 0.51893 ' 0.52214 0.52174_Na 25.24886 0.285 25.16647 25.27922 25.30090.__N1 ' 0.52243 0.232 "0.52380 0.52149 0.52200'_Pb 0..50993 0.322 0.51183 0.50396 • 0.50901_Sb 0.51493 0.221 0.51511 0.51597 0.51371_Se 0.50776 0.565 0.51000 0.50875 0.50452_Sn 0.50634 0.273 0.50655 0.50834 0.50562_SP 0.49064 0.040 - 0.49079 0.49071 . 0.49041_Tl 0.51577 0.178 0.51737 0.51723 0.51571_Tl ~"~0". 51215 0.216 0.51039 0.51297 • 0.51259'_V ' 0.49434 "0/332 "0.49650" .0.49352 0.49299_Y 26171.33398 0.051 26188.00000 25170.00000 26156.00000

Zn 0.53977 0.448 0.54251 0.53791 0.53389

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107AH3050S7

Mercury Data

10848305058

L A M C H S T E R L A B R i"i T 0 R HI S

MERCURY ANALYZER

DATA REVIEWED BY:

•9 DATA VERIFIED BY:

DATA FILE NAME: 9&18701.PRN INSTRUMENT NO: 05SS0RUN NAME: 96187011103

ANALYST: 6S3 ELEMENT: HG

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rn ro en(X;

r

UIO

C-i .

:r

1<jO

CO

CDLQCDCOcc

Chain-of-Custody Record

124

AB-305075

Data PackageContract Lab Program Data Package

forAlliance Environmental Svcs.

TYPE IV INORGANICS DATA PACKAGE

Jack's Creek/Sitkin SiteWater Samples

Collected on 06/26/96 - 06/28/96Sample No. 2537155-2437161, 2538139-2538147,

2538234-2538237

PA Cert. # 36-037NY Cert. # 10670NJ Cert. # 77011

Prepared by U XXx>K- *~/ ( y UQ ^ - U iL J

Quality Assurance Rev i ew /' ik** -- -*-*-, £—*— -j.

Date gfaft,_______________________Delivery Date

Lancaster LaboratoriesA Thermo Analytical Laboratory

Lancaster Laboratories • 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 • 717-656-2300 Fax- 717-656-2681 £&

+m$

AR305076 2262 Rev 7/i i/9s

Lancaster LaboratoriesA division of Thermo Analytical Inc.

Sample Reference List for SDG # AES01with a Package Type of iv-l

LabSample SampleNumber Code Client Sample Description2537155 W-204 GMW-204 Filtered Grab Water Sample2537156 W-203 GMW-203 Filtered Grab Water Sample2537157 W-303 GMW-303 Filtered Grab Water Sample2537158 W-200 GMW-200S Filtered Grab Water Sample2537159 . W-400 GMW-400S Filtered Grab water Sample2537160 W201S GMW-201S Filtered Grab Water Sample2537161 W-201 GMW-201 Filtered Grab Water Sample2538139 JCFBA Field Blank A Filtered Grab Water Sample2538140 JC302 GMW-302 Filtered Grab Water Sample2538141 JC202 GMW-202 Filtered Grab Water Sample2538142 JC205 GMW-205 Filtered Grab Water Sample2538143 JCR02 GWR-02 Filtered Grab Water Sample2538144 JC209 * GMW-209 Filtered Grab Water Sample2538145 JC309 GMW-309 Filtered Grab Water Sample2538146 JC212 GMW-212 Filtered Grab Water Sample2538147 JCTRI Trip Blank A Filtered Grab Water Sample2538234 JCFBB Field Blank B Filtered Grab Water Sample2538235 JC210 GMW-210 Filtered Grab Water Sample2538236 JC211 GMW-211 Filtered Grab Water Sample2538237 JC406 GMW-406 Filtered Grab Water Sample

I.IMI.I-.II i l.ihi'i.ilniu". ShippingM."i (Iru Mnll.llill I'll.i- l,)iH.I'.tl'rl.lhi)l,il(.|ii", ' ;_ . MISMUCH

n'"'" '•'•'''''' .M.r.NmllMll.MKlP,!,- Environmental- Foods- Pharmaceutical, ISIQ1I.IMI.I.IIM. PA l7GOr,-.M.''? l.,iiiur>U'r, PA l/fi()ln,' >'-.v, ?!(in r.c 71 '-'-'-'-. /'iwi 7i7-fir-fi-;>ino r.i» 7ir nr-i. ;i.",i * D O'Cljtt"<if'iiiT7of7"heriMO lerraTeth Inc., a Ihomio Flrction compntiy* D O'Cfljtt"<if'i[iiT7of7"heri

TABLE OF CONTENTS

A. Case Narrative-Conformance/Nonconformance Summary............1

B. Sample Data..................................................4

C. Quality Control Data........................................24

D. Verification of Instrument Parameters.......................47

E. Preparation and Run Logs.................................... 58

F. Raw Data.................................................... 72

1. ICP Data............................................73

2. Mercury Data....................................... 208

3. Extraction/Distillation/Digestion Logs.............228

G. Chain-of-Custody Record....................................232

AB305078

Case NarrativeConformance/Nonconformance Summary

A83Q5Q79

Lancaster LaboratoriesA Thermo Analytical LaboratoryWhere quality is a science.

CASE NARRATIVE FOR INORGANICS

Laboratory Name: Lancaster Laboratories

SDG Number: AES01

Date Received: 06/28/96

Calibration Standards;Instrument calibration standards are prepared monthly from stock

solutions purchased from Spex Industries Inc., JT Baker, AldrichChemical, VWR Scientific, EM Science, or VHG Laboratories.

Lancaster Laboratories « 2425 New Holland Pike, PO Box 12425. Lancaster, PA 17605-2425 • 717-656-2300 Fax: 717-656-2681A subsidiary of Thermo Process Systems Inc., a Thermo Electron company

U.S. EPA - CLP

COVER PAGE - INORGANIC ANALYSES DATA PACKAGE

b Name: LANCASTER LABORATORIES Contract:


SOW No.: ILM04.0

EPA SAMPLE No. Lab Sample ID._JC202____ _2538141___JC205___ _2538142_JC209___ " " ' " " _2538144~_JC210____; ; _2538235___JC211____ ._' _25382J36___JC212____ _2538146___JC302___ _2538140__JC309___ _2538145__

' _JC406___ _2538237__JCFBA____ - - . - . . . _2538139__JCFBB _2538234___JCR02___ _2538143__JCTRI___ _2538147___W-200____ _2537158___W-201____ _2537161___W-203____ _ _2537156___W-204____ " _2537155___W-303___ _2537157__W-400____ ' _2537159___W201S____ _2537160__

jre ICP interelement corrections applied ? Yes/No YES*

Were ICP background corrections applied ? Yes/No YESIf yes - were raw data generated beforeapplication of background corrections ? Yes/No NO_

Comments:

I certify that this data package is in compliance with the terms andconditions of the contract, both technically and for completeness, for otherthan the conditions detailed above. Release of the data contained in thishardcopy data paclcage- and in the compujfcer-readable data submitted ondiskette has bjken authorized/by t /Jraboratory Manager or the Manager'sdesignee, as yerififed by/tee foj wona signature.

Signature: // s?J'Y •—-/\ / \S-7//l/ Name: _Debora K. Gifford_

Date: ' I J/Jd/lL..- / / Title: Chemist IIIInorganic Analysis

COVER PAGE - IN ILM04.0

3

AH30508I

Sample Data

4AB305082

U.S. EPA - CLP


JC202ib Name: LANCASTER LABORATORIES Contract:

Lab Code: _____ Case No.: _______ SAS No.: _____ SDG No. : AES01



% Solids: 0.0

Concentration Units (ug/L or mg/kg dry weight): UG/L__ '

CAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-07440-66-S

Analyte


Concentration

42.92.82.9

0.990.500.860.981.2

69.70.0211.62.3

0.503.47.0

C

BUUUUUUU

UUUBUB

Q M

PPPPPPPPPCVPPPPP



Comments:

FORM I - IN ILM04.0

AB305083

U.S. EPA - CLP



Lab Code: _____ Case No.: __________ SAS No.: _____ SDG No.: AES01

Matrix (soil/water-) : WATER Lab Sample ID: 2538142


% Solids: 0.0


GAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28--07440-66-6

Analyte


Concentration

41.13.42.90.990.505.70.981.20.27

0.0211.65.20.353.410.5

C

BBUUUBUUBUU

BUB

Q M

PPPPPPPPPCVPPPPP


color After: COLORLESS_ Clarity After: CLEAR____ Artifacts:Comments:

FORM I - IN ILM04.0

6

AH3050814

U.S. EPA - CLP


JC209ab Name: LANCASTER LABORATORIES Contract:


Matrix (soil/water-) : WATER Lab Sample ID: 2538144


% Solids: 0.0


GAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-.07440-66-6

Analyte


Concentration

55.22.82.90.990.500.860.981.250.1

0'. 0211.62.30.303.48.7

C

BUUUUUUU

UUUUUB

Q M

PPPPPPPPPCVPPPPP



Comments:

FORM I - IN ILM04.0

7

Ai305085

U.S. EPA - CLP



Lab Code: _____ Case No.: _________ SAS No.: _____ SDG No.: AES01


Level (low/med): < LOW Date Received: 06/28/96

% Solids: 0.0


CAS NO.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-07440-66-16

Analyte


Concentration

58.82.819.90.990.503.53.31.23.8

0.0212372.30.303.48.0

C

BU

UUBBUBU

UUUB

Q M

PPPPPPPPPCVPPPPP

Color Before: YELLOW___ Clarity Before: CLEAR____ Texture:

Color After: YELLOW___ Clarity After: CLEAR____ Artifacts:Comments:

FORM I - IN ILM04.0

8

A8305086

U.S. EPA - CLP


JC211fab Name: LANCASTER LABORATORIES Contract:




% Solids: 0.0


CAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-3

. 7440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-07440-66-"6

Analyte


Concentration

93.42.84770.990.507.41.51.33.9

0.021684

15.1-0.303.411.0

C

BU

UUBBBBB

UUB

Q M

PPPPPPPPPCVPPPPP

Color Before: YELLOW___ Clarity Before: CLOUDY___ Texture:

Color After: YELLOW___ Clarity After: CLEAR____ Artifacts:

Comments:

FORM I - IN ILM04.0

AR305087

U.S. EPA - CLP






% Solids: 0.0

Concentration Units (ug/L or mg/kg dry weight): UG/L__ •

GAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-07440-66-6

Analyte

AluminumAntimonyArsenicBerylliumCadmium .ChromiumCopperLeadManganeseMercuryNickelSeleniumSilverThalliumZinc

Concentration

38.02.82.90.990.500.860.981.216.00.0211.62.30.303.416.5

C

BUUUUUUU

UUUUUB

Q M

PPPPPPPPPCVPPPPP



Comments:

FORM I - IN ILM04.0

fAR305088

t

U.S. EPA - CLP

1 'EPA SAMPLE NO.INORGANIC ANALYSIS DATA SHEET

JC302b Name: LANCASTER LABORATORIES Contract:



Level (low/med): LOW Date Received: 06/28/96% Solids: 0.0


GAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-07440-66-6

Analyte


Concentration

61.42.82.90.990.500.860.981.24.2

0.0291.62.30.303.45.5

C

BUUUUUUUBBUUUUB

Q M

PPPPPPPPPCVPPPPP



Comments:

FORM I - IN ILM04.0

flR305089

U.S. EPA - CLP



Lab Code: _____ Case No.: ________ SAS No. : _____ SDG No.: AES01



% Solids: 0.0


GAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-07440-66-6

Analyte


Concentration

55.42.82.90.990.500.861.11.25.0

0.. 0211.62.3

0.303.416.4

C

BUUUUUBUBUUUUUB

Q M

PPPPPPPPPCVPPPPP



Comments:

FORM I - IN ILM04.0

flB305090

U.S. EPA - CLP


JC406!b Name: LANCASTER LABORATORIES Contract:




% Solids: 0.0

Concentration Units (ug/L or mg/kg dry weight): UG/L___

CAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-0

"~7782-49-27440-22-47440-28-07440-66-6

AnalyteAluminumAntimonyArsenicBerylliumCadmiumChromiumCopper •LeadManganeseMercuryNickelSeleniumSilverThalliumZinc

Concentration33.82.82.9

0.990.500.863.31.21.7

0,0211.6

. 2.30.303.418.2

C

BUUUUUBUBUUUUUB

Q M

PPPPPPPPPCVPPPPP



Comments:

FORM I - IN ILM04.0

13flR30S09l

U.S. EPA - CLP


JCFBALab Name: LANCASTER LABORATORIES Contract:




% Solids: 0.0


CAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-3

- 7440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-07440-66-6

Analyte


Concentration

52.42.82.90.990.500.860.981.20.170.0291.62.3.0.303.44.1

C

BUUUUUUUUBUUUUU

Q M

PPPPPPPPPCVPPPPP



Comments:

FORM I - IN ILM04.0

14

AR305092

U.S. EPA - CLP


JCFBB.b Name: LANCASTER LABORATORIES Contract:

Lab Code: _____ , Case No.: _______ SAS No.: _____ SDG No.: AES01



% Solids: 0.0


CAS NO.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-07440-66-6

AnalyteAluminumAntimonyArsenicBerylliumCadmiumChromiumCopperLead -ManganeseMercuryNickelSeleniumSilverThalliumZinc

Concentration35.02.82.90.990.500.860.981.20.170.0211.62.30.303.44.1

C

BUUUUUUUUUUuuuu

Q M

PPPPPPPPPcvppppp

Color Before: COLORLESS_ - Clarity Before: CLEAR____ Texture:


Comments:

FORM I - IN ILM04.0

15AR305093

U.S. EPA - CLP


JCR02Lab Name: LANCASTER LABORATORIES Contract:

Lab Code: _____ Case No.: _________ SAS.No.: _____ SDG No.: AES01



% Solids: 0.0


CAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-07440-66-6

Analyte


Concentration

61.02.82.90.990.500.8611.41.20.170.0342.82.30.323.416.4

C

BUUUUUBUUBBUBUB

Q M

PPPPPPPPPCVPPPPP

Color Before: COLORLESS_ Clarity Before: CLEAR_____ Texture:


Comments:

FORM I - IN ' ILM04.0

U.S. EPA - CLP


, JCTRIlib Name: LANCASTER LABORATORIES Contract:

Lab Code: _____ Case No. ; SAS No.: _____ SDG No.: AES01



% Solids: 0.0


CAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-8.7439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-07440-66-6


Concentration31.52.82.90.990.500.860.981.20.170.0211.62.30.303.44.1

C

BUUUUUUUUUUUUUU

Q M

PPPPPPPPPCVPPPPP



Comments:

FORM I - IN ILM04.0

AB305095

U.S. EPA - CLP


W-200Lab Name: LANCASTER LABORATORIES Contract:



Level (low/med): LOW • Date Received: 06/27/96

% Solids: 0.0


GAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-07440-66-6

Analyte


Concentration

88.72.82.90.990.500.860.981.2

0.290.0691.62.3

0.303.4

11.0

C

BUUuuuuuBBUUUUB

Q M

PPPPPPPPPCVPPPPP

Color Before: COLORLESS

Color After: COLORLESS

Clarity Before: CLEAR Texture:

Clarity After: CLEAR Artifacts:

Comments :

FORM I - IN ILM04.0

AR305096

U.S. EPA - CLP


W-201b Name: LANCASTER LABORATORIES Contract:



Level (low/med): LOW Date Received: 06/27/96% Solids: 0.0


CAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-3.7440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-07440-66-6

Analyte


Concentration

63.02.82.90.990.500.860.981.2

0.380.0901.62.3

0.303.415.9

C

BUUUUUUUBBUUUUB

Q M

PPPPPPPPPCVPPPPP



Comments:

FORM I - IN ILM04.0

19AR305097

U.S. EPA - CLP




Matrix (soil/waterj: WATER Lab Sample ID: 2537156


% Solids: 0.0

Concentration Units (ug/L or mg/kg dry weight): UG/L__ '

CAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-07440-66-6


Concentration

64.22.92.9

0.990.500.860.981.2

0.170.0661.62.3

0.303.47.7

C

BBUUUUUUUBUUUUB

Q M

PPPPPPPPPCVPPPPP


Color After: COLORLESS_ Clarity After: CLEAR____ Artifacts:Comments:

FORM I - IN ILM04.0

AR305098"

U.S. EPA - CLP


W-204ib Name: LANCASTER LABORATORIES Contract:

Lab Code: _____ Case_No_.: ________ SAS No.: _____ SDG No.: AES01

Matrix (soil/water): WATER Lab Sample ID: 2537155Level (low/med): LOW Date Received: 06/27/96

% Solids: 0.0

Concentration Units (ug/L or rag/kg dry weight): UG/L__

CAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-07440-66-"6

Analyte


Concentration

51.63.02.9

0.990.500.860.981.2

' 0.170.0721.62.7

0.308.56.0

C

BBUUUUUUUBUBUBB

Q M

PPPPPPPPPCVPPPPP


Color After: COLORLESS_ Clarity After: CLEAR_____ Artifacts:

Comments:

FORM I - IN ILM04.0

21

AR305099

U.S. EPA - CLP






% Solids: 0.0


GAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-07440-66-6


Concentration49.53.42.90.990.500.860.981.2

0.170.0791.62.3

0.633.44.1

C

BBUUUUUUBBUUBUU

Q M

PPPPPPPPPCVPPPpp

Color Before: COLORLESS

Color After: COLORLESS

Comments :

Clarity Before: CLEAR Texture:

Clarity After: CLEAR Artifacts:

FORM I - IN ILM04.0

W30SIOO

U.S. EPA - CLP

1 . EPA SAMPLE NO.INORGANIC ANALYSIS DATA SHEET

W-400.b Name: LANCASTER LABORATORIES__ Contract:




% Solids: 0.0


CAS No .

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-07440-66-6

Analyte


Concentration

79.63.92.9

0.990.500.860.981.20.170.0721.62.3

0.303.44.9

C

BBUUUUUUUBUUUUB

Q M

PPPPPPPPPCVPPPPP

Color Before: COLORLESS_ Clarity Before: CLEAR_____ Texture:


Comments:

FORM I - IN ILM04.0

AR305IOI

U.S. EPA - CLP


f W 2 0 1 Sb Name: LANCASTER LABORATORIES Contract:




% Solids: 0.0

Concentration Units (ug/L of mg/kg dry weight): UG/L__

GAS No.

7429-90-57440-36-07440-38-27440-41-77440-43-97440-47-37440-50-87439-92-17439-96-57439-97-67440-02-07782-49-27440-22-47440-28-07440-66-6

Analyte


Concentration

62.52.82.90.990.500.860.981.20.270.0751.62.30.303.45.6

C

BUUUUUUUBBUUUUB

Q M

PPPPPPPPPCVPPPPP



Comments:

FORM I - IN ILM04.0

23

AR305I02

Quality Control Data

•4

4R305I03

U.S. EPA - CLP


*ab Name: LANCASTER LABORATORIES Contract:


Initial Calibration Source: LLI_______



AnalyteAluminum_AntimonyArsenicBerylliumCadmiumChromiumCopperLeadManganeseMercuryNickel[Selenium•SilverFCha IliumZinc


30000.0600.0600.0600.0600.0600.0600.0600.0600.02.0

600.0600.0600.0600.0600.0

30014.82638.31622.86617.45617.08631.08624.13587.64623.111.87

622.94611.92628.015.87.67607.71

100.0106.4103.8102.9102.8105.2104.097.9103.993.5103.8102.0104.797.9101.3


25000.0500.0500.0500.0500.0500.0500.0500.0500.01.0

500.0500.0500.0500.0500.0

25248.84521.94512.69510.30512.49522.40520.16506.52520.370.92

521.89512.07517.93517.28505.89

101.0104.4102.5102.1102.5104.5104.0101.3104.192.0104.4102.4103.6103.5101.2

25395.14522.77513.44509.12513.85525.09518.23499.66522.480.90

523.08513.53519.55503.88503.67

101.6104.6102.7101.8102.8105.0103.699.9104.590.0104.6102.7103.9100.8100.7

M

PPPPPPPPPCVPPPPP

«



25

U.S. EPA - CLP



Lab Code: _____ Case No.: ____' SAS No.: _____ SDG No.: AES01

Initial Calibration Source: LLI________



AnalyteAluminumAntimony_ArsenicBerylliumCadmium _ChromiumCopperLeadManganeseMercuryNickelSelenium_SilverThallium_Zinc


*


25000.0500.0500.0500.0500.0500.0500.0500.0500.01.0

500.0500.0

, 500.0500.0500.0

25281.69519.77512.27506.08510.56522.39516.04506.69519.340.88

520.40511.12515.76503.30501.91

101.1104.0102.5101.2102.1104.5103.2101.3103.988.0104.1102.2103.2100.7100.4

25264.24526.59521.83519.05521.07530.44519.86518.93525.78

524.91516.65521.69516.22521.72

101.1105.3104.4103.8104.2106.1104.0103.8105.2

105.0103.3104.3103.2104.3

M

PPPPPPPPPCVPPP (PPf



26

AR305I05

U.S. EPA - CLP

i , -T- 2A YY: ;INITIAL AND CONTINUING CALIBRATION VERIFICATION

ib Name: LANCASTER LABORATORIES Contract:


Initial Calibration Source: LLI____.



AnalyteAluminum_AntimonyArsenicBerylliumCadmiumChromiumCopperLeadManganeseMercuryNickelSeleniumfcilverthalliumZinc


2 .0 1.99

*

99.5


25000.0500.0500.0500.0500.0500.0500.0

500.01.0

500.0500.0500.0500.0500.0

25498.84526.83517.43514.94514.78525.67526.80

521.911.04

520.28515.83522.19548.68510.72

102.0105.4103.5103.0103.0105.1105.4

104.4104.0104.1103.2104.4109.7102.1

1.04 104.0

M

PPPPPPPNRPCVPPPPP

«



2

AR305I06

U.S. EPA - CLP




Initial Calibration Source: LLI_____,



Analyte

AluminumAntimony_ArsenicBerylliumCadmium _Chromium_CopperLeadManganeseMercuryNickelSelenium_SilverThalliumZinc


600.0

600.0

617.61

*

613.51

102.9

102.3


500.0

1.0

500.0

506.51

1.03

505.21

101.3

103.0

101.0

501.26

1.01

495.38

100.3

101.0

99.1

1

M

NRNRNRNRNRNRNRPNRCVNRNRNRPNR



AR305I07 38

Eab

U.S. EPA - CLP


ab Name: LANCASTER LABORATORIES Contract:


Initial Calibration Source: LLI_____'

Continuing Calibration Source: LLI_________


«Analyte

AluminumAntiraony_Arsenic _BerylliumCadmium _ChromiumCopperLeadManganeseMercuryNickelêleniumBlilverT?hallium_Zinc

Initial CalibrationTrue Found %R ( 1 )

,


500.0

1.0

500.0

502.02

1.02

500.61

100.4

102.0

100.1

1.03 103.0

M




29

W305I08

U.S. EPA - CLP




AA CRDL Standard Source: LLI_______

ICP CRDL Standard Source: LLI________



CRDL St

True

0.2

:andard foiFound

0.23

A

: AA

%R

115.0

True

120.020.010.010.020.050.06.030.0

80.010.020.020.040.0


124.6618.179.959.9619.2449.516.5230.25

. 80.559.5320.4019.0740.73

idard 1

%R

103.990.899.599.696.299.0108.7100.8

100.795.3102.095.4101.8

:or ICPFinal

Found

127.3018.5510.349.8919.1348.206.6830.38

80.5311.0220.8020.0541.60

%R

106.192.8103.498.995.696.4111.3101.3

100.7110.2104.0100.2104.0


AI305I09

U.S. EPA - CLP



Lab Code: _____ __Case No.: _______ SAS No.: _____ SDG No.: AES01

AA CRDL Standard Source: LLI____._ -.- • \

ICP CRDL Standard Source: LLI ,


•Analyte

AluminumAntimonyArsenicBerylliumCadmiumChromiumCopperLeadManganeseMercury|TickelpeleniumSilverThalliumZinc

CRDL St

True

0.2

:andard fbi

Found

0.17

*

~ AA

%R

85.0

True

120.020.010..010.020.050,0

30.0

80.010.020.020.040.0


idard i

%R

:or ICPFinal

Found

125.7818.4610.2910.1119.4749.23

30.43

81.969.5220.6219.9742.13

%R

314.446.225.725.348.7123.1

76.1

204.923.851.649.9105.3


31

A8305I10

U.S. EPA - CLP




AA CRDL Standard Source: LLI_______

ICP CRDL Standard Source: LLI_______


Analyte


CRDL St

True

:andard foi

Found

: AA

%R True

6.0

20.0


6.44

19.23

idard i

%R

•

107.3

96.2

:or ICPFinal

Found

5.31

21.48

%R

88.5

—— 1107.4


"R30SI//

U.S. EPA - CLP

3BLANKS

b Name: LANCASTER LABORATORIES ! Contract:

Lab Code: ____=_ Case No.: _______ SAS No.: _____ SDG No.: AES01


Preparation Blank Concentration Units (ug/L or mg/kg): UG/L_

Analyte

AluminumAntimonyArsenicBerylliumCadmiumChromiumCopperLeadManganeseMercuryNickelkelenium"liverThalliumZinc

Initialcalib.Blank(ug/L) C

27.22.82.9

0.990.50-1.2-1.81.2

-0.220.0551.62.3

0.303.44.1

UUUUUBBUBBUUUUU


1 C 2 C 3 C

63.12.82.9

0.990.500.86-2.71.2

-0.260.0601.62.3

0.303.44.1

BUUUUUBUBBUUUUU

45.73.82.9

0.990.500.86-2.91.2

-0.270.0581.62.3

0.303.44.1

BBUUUUBUBBUUUUU

75.82.8

-3.70.990.50-1.5-2.71.2

-0.260.057-1.62.3

0.303.44.1

BUBUUBBUBBBUUUU

Prepa-rationBlank C

43.7402.8002.9000.9900.500-0.960-2.5601.200-0.2000.0671.6202.3000.3003.4004.100

BUUUUBBUBBBUUUU

M

PPPPPPPPPCVPPPPPIIt


A.B305I 12

U.S. EPA - CLP

3BLANKS




Preparation Blank Concentration Units (ug/L or rug/kg) : UG/L_

Analyte

AluminumAntimonyArsenic _BerylliumCadmiumChromiumCopperLeadManganeseMercuryNickelSeleniumSilverThalliumZinc


__ _0.021 U


1 C 2 C 3 C

29.63.22.90.990.500.86-2.31.2

-0.170.0211.62.3

____ 0.63* 3 . 4

4.1

BBUUUUBUBUUUBUU

57.22.82.90.990.500.86-1.9

0.170.0211.62.30.305.04.1

BUUUUUB

UUUUUBU

0.021

—

—

U

—

Prepa-rationBlank C

0.025

—

—

B

M

P~PPPPPPPPCVPPPPP


AR305II3

•£j£l ID

U.S. EPA - CLP

3BLANKS


Lab Code: _____ Case No.: _______ SAS No.: _____ SDG No.: AESOl

Preparation Blank Matrix (soil/water): ________

Preparation Blank Concentration Units (ug/L or rag/kg):

11

Analyte

Aluminum_AntimonyArsenicBerylliumCadmium _ChromiumCopperLeadManganeseMercuryickelBeleniumSilverThalliumZinc


1.2

3.4

—

U

U


1 C 2 C 3 C

1.2

0.021

3.4

U

U

U

1.2

0.021

3.4

U

U

U

1.2

0.021

3.4

U

U

U

Prepa-rationBlank C

—

—

—

M



U.S. EPA - CLP




ICP ID Number: 05936______ ICS Source: LLI________


AnalyteAluminum_AntimonyArsenicBerylliumCadmiumCalcium _ChromiumCopperIronLeadMagnesiumManganeseMercuryNickelSeleniumSilverThalliumZinc

TrueSol. Sol.A AB

5000000000

50000000

200000

5000000

000

0

5000006001005001000

500000500500

200000

500000500

100050200

1000


5173209-2-50

515206-2-5

210065

5463156

030

5

514066.9658.8101.6502.9994.2

513126.8525.0580.2

209671.6

543237.8528.1

1023.655.0224.4

959.1

102.8109.8101.6100.699.4102.6105.0116.0104.8

108.6105.6

102.4110.0112.2

95.9

Final FoundSol. Sol.A AB %R

51365113» -)

-3-1

511349-2-6

_ 208970

5409166

1— 1

0

6

513089.0657.8105.1500.1993.3

513255.4525.2573.3

209734.4

540508.6528.8

1023.152.9223.7

962.8

102.6109.6105.1100.099.3102.7105.0114.7104.9

108.1105.8

102.3105.8111.8

96.3


AR305II5

U.S. EPA - CLP



Lab Code: _____ _Case No.: _______ SAS No.: _____ SDG No.: AES01



'

Analyte

AluminumAntimonyArsenicBerylliumCadmiumCalciumChromiumCopperIronLeadMagnesiumManganeseMercuryTickel•eleniumSilverThalliumZinc

TrueSol. Sol.A AB

5000000000

50000000

200000

5000000

000

0

500000600100500

1000500000

500500

200000

500000500

100050200

1000

Initial FoundSol. Sol.A . AB %R


5161258-4-40

__ 518549— "1

-5210951

5469846

040

5

513832.7657.3105.0507.61000.2

518317.7528.8579.8

210891.4

544527.6530.4

1024.452.7225.3

982.5

102.8109.6105.0101.5100.0103.7.105.8116.0105.4

108.9106.1

102.4105.4112.6

98.2


37

AR3Q5I 16

U.S. EPA - CLP


Lab Name; LANCASTER LABORATORIES Contract:


ICP ID Number: 05478______ , ICS Source: LLI________


Analyte

Aluminum_AntimonyArsenicBerylliumCadmiumCalcium _Chromium_CopperIronLeadMagnesiumManganeseMercury _NickelSeleniumSilverThalliumZinc

TrueSol. Sol.A AB

500000

500000

2000000

500000

0

__ 500000

__ 5000,00

20000050

__ 500000

100

Initial FoundSol. Sol.A . AB %R

_ 500577

__ 493663

1989621

__ 506307

1

499660.6

498319.2

199561.951.9

507733.7

103.1

_99.9

_99.7

99.8103.8101.5

103.1


__ 469069

__ 500440

1914492

__ 488474

3

479373.2

504798.0

192614.453.4

496810.4

103.4

_95.9

101.0

96.3106.8_99.4

103.4


*

AR305I17

U.S. EPA - CLP






•Analyte

AluminumAntimonyArsenicBerylliumCadmiumCalcium _ChromiumCopperIronLeadMagnesiumManganeseMercury^Tickel•eleniumSilverThalliumZinc...„. ...... — _____

TrueSol. Sol.A AB

500000

500000

200000

500000

0

__ 500000

__ 500000

200000

500000

100



__ 499057

__ 549814

205831

__ 523700

1

511299.3

560863.3

209231.9

535150.9

110.2

102.3

112.2

104. .6

107.0

110.2


AR305//8

U.S. EPA - CLP




ICP ID Number: 05478________ ICS Source: LLI________


Analyte

Aluminum_Antimony_ArsenicBerylliumCadmiumCalcium _Chromium_CopperIron ______LeadMagnesiumManganeseMercuryNickelSelenium_SilverThalliumZinc

TrueSol. Sol.A AB

500000

500000

2000000

500000

0

__ 500000

__ 500000

20000050

__ 500000

100


_ 535402

__ 529483

2195191

__ 552354

3

524951.6

521927.1

216239.849.4

543070.1

108.6

105.0

104.4

108.198.8108.6

108.6


__ 544767

__ 557789

__ 243625-~T

__ 569851

15

559292.2

566202.9

247336.048.2

581043.2

115.2

111.9

113.2

123. .796.4

116.2

115.2


AR305I19

*U.S. EPA - CLP


W-204Sab Name: LANCASTER LABORATORIES Contract:


Matrix (soil/water): WATER_____._ Level (low/med) : LOW



•Analyte

AluminumAntimonyArsenicBerylliumCadmiumChromiumCopperLeadManganeseMercuryNickelêleniumKilverT?ha IliumZinc

ControlLimit%R

75-12575-12575-12575-12575-12575-12575-12575-12575-12575-12575-12575-12575-12575-12575-125


2119.1000535.620041.950049.460049.6100208.5300255.590020.7300511.19000.9470

512.270013.500051.690047.2800495.9900

CSample

Result (SR)

51.60002.95002.90000.99000.50000.86000.98001.20000.17000.07201.60002.66000.30008.52006.0500

C

BBUUUUUUUBUBUBB

SpikeAdded (SA)

2000.00500.0040.0050.0050.00200.00250.0020.00500.001.00

500.0010.0050.0050.00500.00

%R

103.4106.5104.998.999.2104.3102.2103.6102.287.5102.5108.4103.477.598.0

Q M

PPPPPPPPPCVPPPPP

Comments:


41

&R305I2Q

U.S. EPA - CLP


W-204DLab Name: LANCASTER LABORATORIES Contract:


Matrix (soil/water) : WATER_____ Level (low/med) : LOW



Analyte


ControlLimit

*

Sample (S)

51.60002.95002.90000.99000.50000.86000.98001.20000.17000.07201.60002.66000.30008.52006.0500

C

BBUUUUUUUBUBUBB

Duplicate (D)

55.63002.80002.90000.99000.50000.86000.98001.20000.17000.07101.60002.30000.30003.40004.7200

C

BUUUUUUUUBUUUUB

RPD

7.5200.0

1.4

200.0

200.024.7

Q M

PPPPPPPPPCVPPPPP


AR305I2I

U.S. EPA - CLP



Lab Code: _____ Case No. : ________ SAS No. : _____ SDG No. : AES01

Solid LCS Source: - - - - - -

Aqueous LCS Source: LLI_

Analyte

AluminumAntimonyArsenic _BerylliumCadmiumChromiumCopperLeadManganeseMercuryNickelSelenium_•SilverPhallium_Zinc


2000.0500.02000.0

50.050.0200.0250.0500.0500.01.0

500.02000.0

50.02000.0500.0

2106.39531.542049.0149.2949.75206.17251.57506.48508.73

0.92512.462017.9050.68

2045.78498.37

105.3106.3102.598.699.5103 d100.6101.3101.792.0

102.5100.9101.4102.399.7


—

—


O

A.R305I22

U.S. EPA - CLP




Solid LCS Source: __________

Aqueous LCS Source: LLI_______

Analyte

Aluminum_Antimony_Arsenic _BerylliumCadmium ___Chromium_CopperLeadManganeseMercuryNickelSeleniumSilverThalliumZinc


1.0 1.03

•t

103.0


—


fAR3G5I23

U.S. EPA - CLP

8STANDARD ADDITION RESULTS


Lab Code

1EPA

SampleNo.

*=

! Case No. : SAS No. : SDG No. : P


An

•— •••

—

—

—

—

—

—

—

—

—

— —

0 ADDABS

1 ADDCON ABS

A

2 ADDCON ABS

3 ADDCON ABS

FinalCone.

.

r Q

—

—

—

—

—

—

—

—

—

FORM VIII - IN ILM04.0

AB305I2I*

U.S. EPA - CLP

9 EPA SAMPLE NO.ICP SERIAL DILUTIONS

W-204 LLab Name: LANCASTER LABORATORIES Contract:Lab Code: _____ Case No.: ________ SAS No.: _____ SDG No.: AES01

Matrix (soil/water) : WATER________ Level (low/med) : LOW_


Analyte


Initial SampleResult (I)

51.602.952.900.990.500.860.98

. 1.200.17

1.602.660.308.526.05

^

C

BBUUUUUUU

UBUBB

SerialDilutionResult (S)

280.9014.0014.504.952.504.304.906.000.85

8.0011.502.55

17.0032.85

C

BUUUUUUUU

UUBUB

%Differ-ence

444.4100.0

100.0

100.0443.0

Q M

PPPPPPPPP

PPPPP

FORM IX - IN ILM04.0

-6

AR305I25

Verification of Instrument Parameters

AS3Q5/26

U.S. EPA - CLP




ICP ID Number: __________ Date: 04/15/96

Flame AA ID Number: __05220___

Furnace AA' ID Number:

Comments:

Analyte

AluminumAntimonyArsenic _BerylliumCadmiumChromiumCopperLeadManganeseMercuryNickelSeleniumSilverThalliumZinc

Wave- •length(nm)

254.00 _

Back-ground

CRDL(ug/L)

0.2

IDL(ug/L)

__ 0.021

M


FORM X - IN ILM04.0

AH305I27

TO

U.S. EPA - CLP


Name: LANCASTER LABORATORIES ! Contract:

Lab Code: ____ Case No.: ______ SAS No.: ____ SDG NO.: AESOIICP ID Number: __05478___ Date: 07/15/96



Comments:

Analyte


Wave-length(nm)

220.35

190.86

Back-ground

CRDL(ug/L)

-

3

10

IDL(ug/L)

1.2

3.4

M

NRNRNRNRNRNRNRPNRNRNRNRNRPNR

FORM X - IN ILM04.0

AR305I28

U.S. EPA - CLP




ICP ID Number: . __05936___ Date: 07/15/96



Analyte


Wave-length(nm)

308.21206.83189.04313.04226.50267.71324.75

257.61

231.60196.02328.06

206.20

Back-ground

CRDL(ug/L)

2006010551025

15

-40510

20

IDL(ug/L)

27.22.82.9

0.990.500.860.98

0.17

1.62.3

0.30

4.1

M

PPPPPPPNRPNRPPPNRP

Comments:

FORM X - IN ILM04.0

50'

AR305I29

U.S. EPA - CLP. i ' - - - ct* *« f -

•I 11AICP INTERELEMENT CORRECTION FACTORS (ANNUALLY)



ICP ID Number: __05478 __ . Date: 09/19/95

Analyte

AluminumAntimonylAntimony2ArsenicBerylliumCadmiumChromiumCopperLeadlLead2ManganeseMercuryNickelêleniumlKelenium2"silverThallium_Zinc

Wave-length(nm)

220.35220.35

__ 190.86

In1

Al

0.0003010-0.0001510

-0.0000150

terelement (

Ca

0.00000000.0000000

_0. 0000000

Correction 1

Fe

0.00006900.0000430

-0.0000520

factors for

Mg

0.00000000.0000000

_0. 0000000

•»

CO.

0.00032600.0000000

_0. 0033320€

Comments:


' HR305I30 31

U.S. EPA - CLP



Lab Code: ______ Case No.: ________ SAS No.: _____ SDG No.: AES01


Analyte

Aluminum_AntimonylAntimony 2Arsenic _BerylliumCadmium _Chromium_CopperLeadlLead2ManganeseMercuryNickelSeleniumlSelenium2SilverThalliumZinc

Wave-length(nm)

308.21206.83206.83189.04313.04226.50267.71324.75

__ 257.61

231.60196.02196.02328.06

206.20

Int

Al

0.00000000.00000000.00000000.0000000-0.00000200.00000200.00000000.0000060

_0. 0000000

0.00000000.00000000.0000000o.-ooooooo0.0000000

:erelement C

Ca

0.00000000.00000000.00000000.00000000.00000000.00000000.00000000.0000000

_0. 0000000

0.00000000.00000000.00000000.0000000

0.0000000

:orrection I

Fe

0.00000000.00000000.00000000.00000000.00000000.00012300.00001000.0000000

_0. 0000000

0.0000000-0.0000250-0.00039000.0000000

-0.0000860

''actors for

Mg

0.00000000.00000000.00000000.00000000.00000000.00000000.00000000.0000000

_0. 0000000

0.00000000.00000000.00000000.0000000

0.0000000

co-o.ooooooo0.00000000.00000000.00000000.0000000-0.00024600.00000000.0000000

_0. 0000000

-0.00068200.0003320-0.00119800.0000000

0.0000000

Comments:


HR305131

U.S. EPA - CLP- .? j,*-':? . T , - -f4 -^. \a :

11B """*' 'ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY)



ICP ID Number: __05478 __ , Date: 09/19/95

Analyte

AluminumAntimonylAntimony 2ArsenicBerylliumCadmiumChromiumCopperLeadlLead2 ___ManganeseMercuryNickelSeleniumltf>elenium2Rilver[ThalliumZinc

Wave-length(nm)

220.35__ 220.35

__ 190.86

InlCR

0.0000000_0. 0000000

_O.JD003020

terelement <

CU

0.0000000_0. 0000000

_0. 0000000

Correction 1

MN

0.0000000_0. 0001920

_0. 0001650

âctors for

MO

-0.0006330-0.0008320

-0.0015890

•t>

NI

0.0002370_0. 0001740

_0. 0000000«

Comments:


53

AR305I32

U.S. EPA - CLP



Lab Code: _______ " Case No.: _______ SAS No.: _____ SDG No.: AES01


Analyte

AluminumAntimonylAntimony 2ArsenicBerylliumCadmiumChromiumCopperLeadlLead2ManganeseMercuryNickelSeleniumlSelenium2SilverThalliumZinc

Wave-length(nm)

220.35220.35

__ 190.86

Int

Tl

0.0000490-0.0005970

*

_0. 0001450

:erelement C

V

0.0000000-0.0004950

_0. 0018600

-orrection I

0.00000000.0000000

_0. 0000000

"•actors for:

0.00000000.0000000

_0. 0000000

0.00000000.0000000

_0. 0000000

Comments:


AR305I33

, U.S. EPA - CLP




ICP ID Number: __05936 __^ Date: 09/19/95

Analyte

Aluminum_AntimonylAntimony2ArsenicBerylliumCadmium _Chromium_CopperLeadlLead2ManganeseMercuryNickel^Seleniuml•elenium2^silverThalliumZinc

Wave-length(nm)

308.21206.83206.83189.04313.04226.50267.71324.75

__ 257.61

231.60196.02196.02328.06

206.20

In1

CR

0.00000000.0000000O.OOOOOOO-0.00336900.00000000.00000000.00000000.0000000.

_0. 0000000

0.00000000.0000710-0.00009200.0000130

0.0010140

_erelement (

MN

0.00000000.00000000.00000000.00000000.00000000.00000000.00006200.0000000

_0. 0000000

0.00000000.00038400.0001860-0.0001030

0.0000000

Correction 1MO

0.00000000.00000000.0000000-0.00417100.00000000.00000000.00000000.0000000

_0. 0000000

0.0000000-0.00070000.00000000.0000000

0.0020190

?actors forTl

0.00300000.00000000.00000000.00000000.00000000.00000000.00000000.0000000

_0. 0000000

0.00000000.00000000.00000000.0000000

0.0020000

9t

V

0.02646000.00000000.00000000.00000000.00165100.00000000.0000000-0.0001130

_0. 0000000

0.00000000.0001670-0.00011000.0000000

0.0000000

Comments:

FORM XI (PART 2) - IN ILM04 . 0

AR305I3U

U.S. EPA - CLP




ICP ID Number: __05478___ Date: 07/15/96

Comments:

Analyte


Integ.Time(Sec.)

10.00

10.00

Concentration(ug/L)

50000.0

10000.0

M

NRNRNRNRNRNRNRPNRNRNRNRNRPNR


AR305I35

Wi

U.S. EPA - CLP



Lab Code: _____ Case No.: _______ SAS No.: _____ SDG No.: AESOlICP ID Number: __05936___ Date: 07/15/96

Analyte


Integ.Time(Sec.) .

10.0010.0010.0010.0010.0010.0010.00

10.00

10.0010.0010.00

10.00

Concentration(ug/L)

600000.050000.020000.05000.020000.0100000.050000.0

50000.0

50000.010000.02000.0

5000.0

M

PPPPPPPNRPNRPPPNRP

Comments:


57

A/?305I36

Preparation and Run Logs

AR305I37

cai

U.S. EPA - CLP

13PREPARATION LOG



Method: P

EPASampleNo.

JC202JC205JC209JC210JC211JC212JC302JC309JC406JCFBAJCFBBJCR02JCTRILCSWPBWW-200W-201W-203W-204W-204DW-204SW-303W-400W201S

PreparationDate

07/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/9607/08/96

Weight(gram)

Volume(ml)

100100100100100100100100100100100100100100100100100100100100100100100100


AR305I38

U.S. EPA - CLP

13PREPARATION LOG


Lab Code: _____ Case No. : ________ SAS No. : _____ SDG No. : AES01

Method: CV .

EPASampleNo.

LCSWPBWW-200W-201W-203W-204W-204DW-204SW-303W-400W201S

PreparationDate

07/03/9607/03/9607/03/9607/03/9607/03/9607/03/9607/03/9607/03/9607/03/9607/03/9607/03/96

Weight(gram)

Volume(ml)

88888888888


f,AR305I39

Documents

10X121- · Lab Code: _____ Case No.: _____ SAS No.: _____ SDG No.: AES02 Matrix (soil/water)-: WATER Lab Sample ID: 2538242 Level (low/med): LOW Date Received: 06/28/96 % Solids:

10X121- · Lab Code: ___ Case No.: _ SAS No.: ___ SDG No.: AES02 Matrix (soil/water)-: WATER Lab Sample ID: 2538242 Level (low/med): LOW Date Received: 06/28/96 % Solids: