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MSDS: Mepoxe A @ l/4) MATERIAL SAFETY DATA SHEET 1. Identification of the product and the company Product Name Company Name Office Address Tel. No Fax No Email Intended Use 2. Hazard and Harm Identification Classification Hazardous Harmful 3. Composition and lngredients Information 5. Fre Fightrng Measures Extinguishing Media : Water spray, Dry chemical powder, COr. Alcohol resistant foam. Hazardous decomposition, combustion products. : Carbon monoxide and poisonous gas by decomposition reaction. : Organic peroxide type D. In{Iammable liquid : Heating generates fire and explosion. : Harmful if swallowed. Skin, mucous membrane and eyes air irritated. MEPOXEA PT Kawaguchi Kimia Indonesia Jl. Hayam Wuruk no. 44 Lt II / 28, Jakarta 1l160, Indonesia. (62 - 2rJ 6498693, 6263477 (62 - 2r) 6260e73 [email protected]. id Hardening agent for the polymerization of unsaturated polyester resins. Date oflssue : 14 August 2009 Classification Chemical Name Chemical Name Methyl Ethyl Ketone Peroxide Plasticizer Methyl Ethyl Ketone Hydrogen Peroxide : Mixture : Methyl Etiyl Ketone Peroxide Chemical Formula (CJIaO)n 133 C4}I,O HrO, 4 First Aid Measures General Inhalation Skin Eye Swallow Call a physician immedrately Remove to fresh air space- If difficulty in breathing, keep warm and get medical treatrnent immediately. Immediately wash skin with water and soap. If be unusual, get medical check. Immediately wash eyes with water for at least 15 minutes. After that gets medical treatmenL In case eyes to do contact lenses, if don,t stick eyes, remove lenses then wash eyes. In case be consciousness, immediately rinses out mouth then give a cup of water. After that gets medical treatment. And don't induce vomiting. In case be unconsciousness, immediately get medical treatment. At the time if vomiting occurs, the patient should lie on their left side while vomiting to reduce the risk of aspiration. Content (wt%) r

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Page 1: 10 Msds Mepoxe A

MSDS: Mepoxe A @ l/4)

MATERIAL SAFETY DATA SHEET

1. Identification of the product and the companyProduct NameCompany NameOffice Address

Tel. NoFax NoEmail

Intended Use

2. Hazard and Harm IdentificationClassificationHazardousHarmful

3. Composition and lngredients Information

5. Fre Fightrng MeasuresExtinguishing Media : Water spray, Dry chemical powder, COr. Alcohol resistant foam.Hazardous decomposition, combustion products.

: Carbon monoxide and poisonous gas by decomposition reaction.

: Organic peroxide type D. In{Iammable liquid: Heating generates fire and explosion.: Harmful if swallowed. Skin, mucous membrane and eyes air irritated.

MEPOXEAPT Kawaguchi Kimia IndonesiaJl. Hayam Wuruk no. 44 Lt II / 28, Jakarta 1l160, Indonesia.(62 - 2rJ 6498693, 6263477(62 - 2r) [email protected]. idHardening agent for the polymerization of unsaturated polyesterresins.

Date oflssue : 14 August 2009

ClassificationChemical Name

Chemical Name

Methyl Ethyl Ketone Peroxide

Plasticizer

Methyl Ethyl Ketone

Hydrogen Peroxide

: Mixture: Methyl Etiyl Ketone Peroxide

Chemical Formula

(CJIaO)n 133

C4}I,O

HrO,

4 First Aid MeasuresGeneralInhalation

Skin

Eye

Swallow

Call a physician immedratelyRemove to fresh air space- If difficulty in breathing, keep warm andget medical treatrnent immediately.Immediately wash skin with water and soap. If be unusual, getmedical check.Immediately wash eyes with water for at least 15 minutes. After thatgets medical treatmenL In case eyes to do contact lenses, if don,t stickeyes, remove lenses then wash eyes.In case be consciousness, immediately rinses out mouth then give acup of water. After that gets medical treatment. And don't inducevomiting. In case be unconsciousness, immediately get medicaltreatment. At the time if vomiting occurs, the patient should lie ontheir left side while vomiting to reduce the risk of aspiration.

Content (wt%) r

Page 2: 10 Msds Mepoxe A

MSDS:MepoxeA@ 2/4)

Method of extinguish a fire: Extinguish a small fire wrth powder or carbon dioxide ten apply

water to cool. Extinguish a big fire with water bar or spray or foam orreinforced liquid then apply water to cool. Escape the fire wrth manywater

Protect for the fire fighter : Must wsrr proper protective equipment. Extinguish a fire from thewindward for avoids inhalation poisonous gas. Keep the safetydistance because there is an explosion hazard.

6. Accidental Release MeasuresCaution for Human : Must wear proper protective equipment and work from the windward.

Stretch rope at leaking area and keep out except person concerned.Ventilate at leaking area, if necessary

Caution for environment : Don't allow direct to enter drain or water courses.Method for cleaning up : In case small, wipe off wrth cloth then burns in safety space

immediately. In case large, stop an outflow with earth and sand theneollect. Adsorbs remainder wrth sawdust, diatomite or dry sand thendisposes of proper Soaks water if keeps for the time.

Prevention for secondaly disaster: Remove the sources of ignition in neigborhood immediately. Use the

safety tools as don't generate sparks.

7. Handling and StorageHandling

Storage

: Handle well in ventilated area. Wear proper protective equipment forguard eyes and skin. Avoid strong rubbing and shock. Eliminate allsources of ignition, and don't generate flames or sparks. Keep awayfrom reducing agents, amines, acrds, alkalies and heavy metalcompounds.Use materials of equipment stainless steel, glass lining, polyethylene.Don't use irons, copper compounds, leads, and rubbers. Takemeasures for static electricity as ground. Use explosion protectedequipment. Wash empty container with water at once, after then putthe cap and avoid the direct sunlight.

: Store in accordance with local and national regulations. Keep in thecool dark place of less than 30'C. Don't use fire. Keep away fromfood, drink and other chemicals, especially amines, acids, alkalies,heavy metal compounds and reduction agents. Take measures for thefall and the fall prevention. Must not put the horizontal and thereverse.

: Use materials stainless steel, glass lining, polyethylene for avoidsdecomposition.

8 Exposure Controls and Human ProtectionEquipment : Set the local exhaust ventilation when gas and mist are generated. Set

the washing tool for eyes and body. Use explosion protectedequipments. Take measures the static electricity.

Allowable ConcentrationShot Term Exposure Limit (STEL)

: Methyl Ethyl Ketone Peroxide 0.2 ppm (Ceiling): Methyl Ethyl Ketone 300 ppm

Container

Page 3: 10 Msds Mepoxe A

MSDS: Mepoxe A @ 3/4)

Trme Weighted Average (TWA): Methyl Ethyl Ketone 200 ppm: Dimethyl Phthalate 5 mg / ml: Hydrogen Peroxide I ppm

Human ProtectionRespiration Organs : Wear the organic gas proof mask.Hand : Wear the unpermeation gloves.Eyes . Wear the glasses or goggles.Skin and body : Wear the shirt with long sleeves and safety shoes.

9 Physical and Chemical PropeniesAppearance : Clear liquidColor : ColorlessOdor : Characteristic odorMelting pornt : No dataCoagulating point : No dataBoiling point : Irnpossible to measure because generates decomposition

10. Stability and ReactivityStability : Instability to heat. SADT : 65"C

Avoid the direct sunlight and strong rubbing and shock.Keep away fire and heat.

Reactivity : Self reactiveness. Promoted decomposition with amines, acid,alkalies, heavy metal compounds and reduction agents. Avoid usingmaterials of iron, copper compound and rubber.

I l. Toicological lnfomationAcute toxicity : The following data are the diluted to 609/0 solution with dimethyl

phthalate.Oral : Rat LD50 1051mg/I(g 1)

Human TDLo 480mg/I(g 2)Mouse LD50 4TOmglKg 3)

Inhalation : Mouse LC50 l7oppm/4hours exposure time 4)Abdominal cavity : Rat LD50 65mg,iKg 4)

Mouse LD50 200mg/Kg 5)Localized InJluenceSkin : Rabbit Conosive I )

Rabbit the highest density doesn't stimulates I.57o 4)Eyes : Strong corrosive and stimulative. 6)

Rabbit the highest density doesn't stimulates 0.60lo 4)Carcinogenic : Not mention of NTP, IARC, OSHA. 7)Mutation field of the generative cell

: Gloomy 8)

12. Ecological InformationToxicity to ecology : No dataRemain / Decomposition : No dataAccumulation : No data

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MSDS: Mepoxe A@4/4)

13. Disposal C onsiderationGeneral : It disposes properly according to the law in each country and the

regron.Incinerate : Use proper incinerator. When the incineration is done,it incinerates

little by little mixing it with an inert high boiling point solvent. Or,the diatom soil and the vermiculite, etc. are made to absorb it and itburns. If there is no proper rncinerator, the consignment disposal isdone to the industrial waste trader who obtains permission.

Contaminated packing : Removed contents completely after then incinerated.

I 4. Transport InformationGeneral : It disposes properly according to the law in each country and the

regron.Classification : 5.2 Organic PeroxideUN Number : 3105 Organic Peroxide type D liquidSea transport : Follow method of transport, be provided in IMDGAir transport : Follow method of transport, be provided in IATA.Safety measures : Thke measures for the fall and the fall prevention, for prevent

leakage. The top of container tumed upward, must not put thehorizontal and the reverse. When transport, keep out inflammable.Avoid direct sunlight and heat.

15. Application of RegulationsFire Defense Law : Classification 5 2 self reactivenessIndustrial Safety and Health Law : Dangerous substancesSafety ofVessel law : Oxidized material. Organic peroxideAviation law : Organic Peroxide. (It is forbidden to air transportation)

16. Other InformationReferences

I. Data of Company2. National Clearinghouse for Poison Control Centers, Bulletin., Jan/F3. J.Am.Med.Assoc., 165.201.574. Floyd, Ep and H.E.Stokinger : Amer.Ind Hyg.Assoc.J., 19.205.585. Hygiene and Sanitation 29.103 (January 1964)6. Report of International Research and Development Corporation, Mattawan,

Michigan IRDC 328-0047 The Nippon Chemical Industrial Co., Ltd. Safe material and United States OHSA..

Dangerous, harmful, well-known, standard rule and clearinghouse edit (issue on July2, 2OOl).. list of a dangerous harmful chemical. (the fifth edition)

8. Rdport of Central Institute voor Voedingsonderzoek TNO (CNO), Zeist, Holland