21
-- ....- Pmb\e.m S-e.J- ~ Ch~-\-er J 1. Q F, ,,~ /'F \ . <, ~e.. f / .. '--F 3 ,-\-er1 c. ~ : b \3 u-t hD. ore --\-Luo \ () ne \:l Qit- s eWl d 'St> +he if f Cl1-e \h -I--II<c ~tVo;to.-;",\ ~()~i\-ioh @ QO° ~ ~C\L-~ er+kr. \b'\)L{-h \ ~: ~ e., '3 j C e,r..-\-ru 5,/ \-(Ime:.m c. \ Wo..\- \,ne...<\r \e. "'3 N = is N :: 5 Q-to'r<' S ~. It-QhS \~+1t)Y\s -? \ -:2. ~_dI'~.dl"'" . 1.- <l i ~,--t,o..

1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

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Page 1: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

-- ....- Pmb\e.m S-e.J- ~Ch~-\-er J

1. Q F, ,,~/'F\ . <, ~e..

f / .. '--F

3,-\-er1c. ~ : b\3u-t hD.ore --\-Luo \ ()ne \:l Qit- s eWld 'St> +he if fCl1-e \h -I--II<c ~tVo;to.-;",\ ~()~i\-ioh @ QO° ~

~C\L-~ er+kr.

\b'\)L{-h\ ~: ~ e., '3 j C e,r..-\-ru 5,/ \-(Ime:.m c.\ Wo..\- \,ne...<\r

\ e. "'3 N = isN :: 5 Q-to'r<' S

~. It-QhS \~+1t)Y\s-? \ -:2.~_dI'~.dl"'" . 1.- <li~,--t,o..

Page 2: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

~o+C\-\-ionsA~no 7-"Z - ~'l.i~

A'rOfSn d .z,.~-~'t( s

--- -- ----

Page 3: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

-AdA~ -~ -~--------A l..j -\-B '.\...j *" B Cl--j .\- A~u -\- \)au -+ a'£\J

·~~-b::.9

l i, \?:e..c.0.u se. C~ s,/ rn me..-hic, J rn 0 -\-v 0,\

e.,~G\ 0 $\'1',-1

Page 4: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

-1- 1. -1 1 -1 i -1 1-1o -1 0 0 d- 0 -:1 0 0

o -J. 0 a -J. 0 ~ 0 0))( 3

r-

'V J. A1.j"' 1 1~~". .i 1~~j'. 1.. -1Q ' 1- -- 1u~J'

d-Aav·' (t 1-

~au·· 1

E~f{l-\- "5 tu"' ('d-

-

1 1. L 1. i1 -1. -1 1. 1 1ill -1 -11.. 1 -1 1-1 1. 1.. -1-

i -1 1. 1 -1 1-1 1

1 -1 -1.. -1 -1 -1 11..))(d

-1 -3-1 -3 -1 5 J 1

~e,,,,~11\b& ~~d. I-t\>. :::.2" -r.rrtl rt.{>.

~ \ . .

~ F~4h E l4 cd... -:J..c.~ '"J..c~\ i d-s,+ ~ Ju'( IlOJ

1.. 1- 'L 1. L L i 1.. 1 1 A1J

Page 5: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

FF Xe --F

l

Fd..-C r . \\.

J.. "d.- c~ L

1 -1 \.~ 54 ~ d.-cJv sr d.

-1 1. 1. - i B~

1 F~~ 'XI(r1

1- -1 1-\--t1 \3~J

-: 1..".5 q.r-r+: )J~~t~T-

~ f, tv

1 -1 1 -1 + 1\ 101 1.~

V · 'ie - fjJ. -= to 1(i l\J

'f3

Page 6: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

~ 'rfI, \Z e.e{l \ \'\ mil" d -\-\-e.. \one.. f'Q irS' ,-z..

Y •• "'-i.)'lItt'" ~<,

'J.. sh,w\a (.(:)'n s·D4- ()~ (, \ rttd\J C\bk..-\-ef3 .

• ~~ine.. +he. rtduc. iblB- \'e.{>\t~-\-~<;,n.,• \) 92- 'Ie. e:\&"s ,to', rod. <e;\e. 0- i'rI~ L-\-iov,S -4- \one. \l C\ \ \- s '

ltLt CJ.. ~c~ lC~ 1 d,Stt ~ J.OV :lOJ~ d... d- ooo4t1d-

rlkJ : ~A'Lj ~ BLj '\- A'J,u +- s.,b -\0+'\ t ~ ~r:-set'+,,-hat'lS

~A'l.j·'

~'Lj "Aav r.

Eu '.

'3, dzd-d~d-_~~

~z-

V){ ) v~

t~ 3a s~~1\'Kes sense hie.Od-llhe.lrt\\ ~\ex\nt<;\:r~

Page 7: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

,. f'e/ f'f/L -J/

2. Assign the follo . ," v' ~are chilal and ifth:mg mol~ules tg their appro iate .y have a dipole moment. pr pomt groups and identify if they

oII

H/P\JI"CICI

c 5

11111"" s·· ~.\{P\~/~ Cts ~C\S

v"<\o n'W-r-r-\

a ,FISL"

F/ \"IF "\F J

FF_~·,\\\\\F

.,

I'F f>3hFF

F// I F1/, \\\ 6","Co'\\

F~I'FF

Page 8: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

F F""N=N/

Fe \J 5d~ 4-

3. What are the symmetries of the normal modes of vibration ofthese molecules? .er~i/ll--~iI

,ff"# fli/"'''''

I f iJ. '}.(Hy

'\ It

4. Unlikethewater molecule, carbon dioxide has no dipole moment. How isitpossible for it to have any of its vibrational modes to be infrared active?

\ 5.Why isit that theO-H band in the IRbroadenswith H-bonding?

?", 6. In an sp'd hybridized phosphorus atom in a trigonal bipyramidal molecule, will theatom have a greater electronegativity when bonding through equatorial or axial orbitals?Explain. .

Page 9: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

J. ..~N

/II I

F t> 't:F

"3 \'J -=- 1~ ~~r-ees J .2~ ~~h"

oN- b: 6 " ibru.t- \oh S

C~y E J- C3 Jay... ~UI\~O~ Jf 1- ~

Co~b ~ D 11.Q.

~rrtJ~- "

1-~ 0 d- - 3Al +- A;;. l-4E.-.- A1 ~t:\h-.5--E

fV)~ : ~ Ai. +~E _A~-'t- \m+

~~~+;Ot>5 ~"fA 1...\-~f-

Cd-\[tJ r \JnY'1\O\ft.. J

ct.Y\+·

Page 10: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

4-. \je..nc\ S l.\nJ ~S'lmme...+nc.

~e.- ~~po\e.. h\()r<\V'\-l.

\. 5, 'v4 i}.-h "- bOh J Ih~ .\-he bjth .o~ ~Il.c..h

0- \..\ bo1'\d C,h 0."JeJ, -n.e... 'J Ib~"" .\--hos

Q,~ /11\ je " rt"SL'l \~n j ,l\ non hllh'lO~V\DU sh ctuQ.-u

c...•ts

4- a bn:>t!.J ]:\1. sjJeL-huro S)~ 0'1\,

\)

1'"A

. ~

~

<:-A/'B ~ t'I ci,1"\ con\n bu\'cn,: 5) h1~'l

'>l'>J 'd '3 f "3 bu.\- ~ rtct,l·e.r, S C~o,y-t\c..-kr IY\ e..£tUO;hh'\ I~~q ne. A Ctork,n -to p.l!',-r •.\-1 S ruIe) rtlbr€.-

e..\eck,,~,\o,-h'l,i-hf ~ ~ ctvo,-kh"' .. ~\qne . '\he.. moree-\e.t..\=,,'i,J Oi\1~ SJbst-H'v ti'I\- ",. II b~ "I' ~e,

Q-j,\o.\ ~os;\1'uV',

Page 11: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

Ch~~5

flJ1 q. 0

\-\L ~\-\

c~" \: c,~Q d- O

Ai 1-

~Cf- i -1

~0

®~o bond~ ~ \uJ() 5~hiY\

'VI b ~4-1on s ~

D

~">\~ \--\

'-\J 1- ~a.-L~" E cd- e; (~~ (J'" ("1"2-1lIli

4\ 4' 'J. Yl~.. l\l1

LV (~1):: i IjJ i +- 1. tiJ~ -t 1Yl;). -t 1~1

~ Q... 1jJ1. ..\-~ '-Pel-: ~ (l\J i -I-~J I ,,_phq5e (C()\XII:;'hq\-i'~Yl

Page 12: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

~ (Qg) ~ 0

~ ('o1-):- 0

~ ( b;>-):: 1)(' tpl + (- i ~~~(-ll\Ja)-l- ( 1,,411): :1YJL -tJ-%.-:.-h. (t\J 1. - 4J9-) Do-\- J ~k)Q (0'" 6ih~-\1aY\

c . 3ee i t;jl-- c\ c,'SS '(Ibks

-rne h\~\;er E 0. i (l\l~ 4- \-\.-- 'oonbb"J-\ f\jbi ( "-\'If) ~ oUS~ -\-k \ Q~ P c.\ 1'-5 -

J. .eo

···N~\.\

l)1" ~

H

c.3'J \ \: ~C3 ,,"3 CJy

0 1\rtJ -:3Ai 1 1- 1..

:yr ~-t 0-

:) 0 i

Page 13: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

~ (qJ: 1.tPl -I- L*~-\-i ~3 i- t ~l -\-i ~3~ 1..'"f'J--:: ~ t/li -I-l~;}-...\-a. ~3 A No hOck.s

I\'(Qil: ~ (ljJ1- \- ~~-i- Yl3) ~

~ (~J: d- tfl ~ t IxI\IJ.) ~ (- i~LJl3).\. 0

: ll!J T 4J - LP"\1 ~:. V

:: --k- (d- t.Pl - ~'J-- 43),.

- - -~--~-

Page 14: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

e. Fo'r c e n'~\ ,\.-k rn®

r Q r '3 ~7 ~L'

J, )

e. '. ?-,:.) ~'j )

s.'"ro '0l~~ VYl ~.\-c:..h in.J~l

Page 15: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify
Page 16: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

~, ('-0:='"'-- - ®'-= -8 --7 2 -o.."/.. \ S

'3i~rr.G i~d.QhS c.en\h><;'f m~t.

'J.s ~~"l-

C'· @ CfkJC\.~m(Co"rb'\\-c\\ S' J LJ

l~O :~OO

U

- -~--- --

Page 17: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

\ ~i ih-\-€J-e. "'-\;Qh!'-z.

y

C0.40"", -,~ o I-- ~ - ~

~~j. )Q~.~bD+h ,,~ uYl 3t~ k

lG-os

)('\H lln~~.k --~iH ~v-".k

\h~ 9&-D>Ae~ m

~l' ~ ~~

~ ~j~lahO

'3,/ r<\~ rM-k..'-' .

Page 18: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

@

0*\J

lone pair++,----_e 0

2s

carbon oxygen

Page 19: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

3.

~ ~ Al -+ 'Cd-'--yr- --"

~ '\ r- H..~. re..ps .

N Q-+ahl; c, G t-b~~\s \.;..Ii~ +he.~ ~~ mhle:he.S

o 1.... S 0.hd ~ 7: ~

b~·. ?~

Page 20: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

z

,he... "e.t.-~~s pO\Y"\4 ',h 0.d\re. c-\;on P q r- ~ \' e.,\ -h> -\-h~

'i.. - O'(\C) .

o 0 -d.-

Ad- -\- B 1-N ,,-\-"W"'I i c, b ,...b .,t..\ s V-> -.+6· +he. se. s~rn me...-hJe. s .

~;;L'. ~

b L: ~)< )

+he... -\\, \ \t>win J '1\ i,,+-e..r-q c.+;"n3:

hi -

Page 21: 1. Q F, ,,~/'F - Weebly · 2018. 8. 17. · ,. f'e/ f'f/L-J/ 2.Assign the follo . ," v' ~ arechilal andifth:mgyhavemoal~uldipolees tmoment.gtheirappropriatepomt. groupsandidentify

~"" l\~ t'n Ul'~ ~\.rilt() __b',"\-- \

aL(~ '. O~(~~')

~ d.l'i -d-1'1

~ :l?z. -\-'J\>z.

n d.-Pz. - d.-yZ

~h -;}?")( --\-d.p"

h 'd.-y", - ~r"

yoss;'o\t

THe o4L .\\,,\~(4\~n

cr