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Product and company identification
August 07, 2013Validation date :August 07, 2013Print date :
DELTAGREEN ACID BOWL CLEANERProduct name :
13714 ALMA AVE, GARDENACA 90249, USA
DELTAGREEN PRODUCTS, INCSupplier :
DELTAGREEN PRODUCTS, INCManufacturer :
1 .
Product type : Liquid.
In case of emergency : United StatesTelephone: (310) 532-0353
(DELTAGREEN PRODUCTS)Fax : (310) 532-0372 (DELTAGREEN PRODUCTS)
Emergency overview
Hazards identification
Severely irritating to the respiratory system.
Severely corrosive to the eyes. Causes severe burns.
Toxic if swallowed. May cause burns to mouth, throat and
stomach.Severely corrosive to the skin. Causes severe burns.
EyesSkin
InhalationIngestion
Physical state Liquid.
See toxicological information (section 11)
DANGER!FLAMMABLE LIQUID AND VAPOR. COMBUSTIBLE. CAUSES SEVERE
EYE ANDSKIN BURNS. HARMFUL IF SWALLOWED. CAUSES RESPIRATORY
TRACTIRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN
DAMAGE.Flammable liquid. Harmful if swallowed. Severely corrosive
to the eyes and skin.Causes severe burns. Severely irritating to
the respiratory system. Keep away fromheat, sparks and flame. Avoid
exposure - obtain special instructions before use. Do notbreathe
vapor or mist. Do not ingest. Do not get in eyes or on skin or
clothing.Contains material that can cause target organ damage. Use
only with adequateventilation. Keep container tightly closed and
sealed until ready for use. Washthoroughly after handling.
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Medical conditionsaggravated by over-exposure
Pre-existing disorders involving any target organs mentioned in
this MSDS as being atrisk may be aggravated by over-exposure to
this product.
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OSHA/HCS status : This material is considered hazardous by the
OSHA Hazard Communication Standard(29 CFR 1910.1200).
2 .
Potential chronic health effectsChronic effects : Contains
material that can cause target organ damage.
Over-exposure signs/symptoms
Ingestion : Adverse symptoms may include the following: -stomach
pains:nikS Adverse symptoms may include the following: -pain or
irritation -redness -blistering
may occur:seyE Adverse symptoms may include the following: -pain
-watering -redness
Inhalation : Adverse symptoms may include the following:
-respiratory tract irritation -coughing
Target organs : Contains material which causes damage to the
following organs: lungs, upper respiratorytract, skin, eye, lens or
cornea.Contains material which may cause damage to the following
organs: central nervoussystem (CNS), stomach.
Potential acute health effects
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DELTAGREEN ACID BOWL CLEANERDate of issue: August 7, 2013
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03 - 012-83-4667dica cirohpsohp03 - 010-78-67172dica
cinoflusenezneblycedod
Isopropanol 67-63-0 5 - 105 - 10-10-7467dica cirolhcordyh
Composition/information on ingredientsName CAS number %
3 .
Wash out mouth with water. Do not induce vomiting unless
directed to do so by medicalpersonnel. Never give anything by mouth
to an unconscious person. Get medicalattention immediately.
Check for and remove any contact lenses. Immediately flush eyes
with plenty of waterfor at least 15 minutes, occasionally lifting
the upper and lower eyelids. Get medicalattention immediately.In
case of contact, immediately flush skin with plenty of water for at
least 15 minuteswhile removing contaminated clothing and shoes.
Wash clothing before reuse. Cleanshoes thoroughly before reuse. Get
medical attention immediately.Move exposed person to fresh air. If
not breathing, if breathing is irregular or ifrespiratory arrest
occurs, provide artificial respiration or oxygen by trained
personnel.Loosen tight clothing such as a collar, tie, belt or
waistband. Get medical attentionimmediately.
First aid measuresEye contact
Skin contact
Inhalation
Ingestion
No specific treatment. Treat symptomatically. Contact poison
treatment specialistimmediately if large quantities have been
ingested or inhaled.
Notes to physician
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4 .
Protection of first-aiders : No action shall be taken involving
any personal risk or without suitable training. If it issuspected
that fumes are still present, the rescuer should wear an
appropriate mask orself-contained breathing apparatus. It may be
dangerous to the person providing aid togive mouth-to-mouth
resuscitation. Wash contaminated clothing thoroughly with
waterbefore removing it, or wear gloves.
Use dry chemical, CO2, water spray (fog) or foam.
phosphoric acid: Forms a detonable mixture with
nitromethane.Isopropanol: Vapor may travel considerable distance to
source of ignition and flashback.
Fire-fighting measures
Extinguishing media
Special remarks on firehazards
Promptly isolate the scene by removing all persons from the
vicinity of the incident ifthere is a fire. No action shall be
taken involving any personal risk or without suitabletraining. Move
containers from fire area if this can be done without risk. Use
waterspray to keep fire-exposed containers cool.
Flammable liquid. In a fire or if heated, a pressure increase
will occur and the containermay burst, with the risk of a
subsequent explosion. Runoff to sewer may create fire orexplosion
hazard.
Special protectiveequipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and
self-contained breathingapparatus (SCBA) with a full face-piece
operated in positive pressure mode.
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5 .
Special exposure hazards :Do not use water jet.
Suitable :Not suitable :
Hazardous thermaldecomposition products
: Decomposition products may include the following
materials:carbon dioxidecarbon monoxidesulfur oxidesphosphorus
oxideshalogenated compounds
Flammability of the product ::Flash point Closed cup: 41°C
(105.8°F).
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No action shall be taken involving any personal risk or without
suitable training.Evacuate surrounding areas. Keep unnecessary and
unprotected personnel fromentering. Do not touch or walk through
spilled material. Shut off all ignition sources. Noflares, smoking
or flames in hazard area. Avoid breathing vapor or mist.
Provideadequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Puton appropriate personal protective
equipment (see section 8).
Stop leak if without risk. Move containers from spill area.
Approach release fromupwind. Prevent entry into sewers, water
courses, basements or confined areas. Washspillages into an
effluent treatment plant or proceed as follows. Contain and
collectspillage with non-combustible, absorbent material e.g. sand,
earth, vermiculite ordiatomaceous earth and place in container for
disposal according to local regulations(see section 13). The
spilled material may be neutralized with sodium carbonate,sodium
bicarbonate or sodium hydroxide. Use spark-proof tools and
explosion-proofequipment. Dispose of via a licensed waste disposal
contractor. Contaminatedabsorbent material may pose the same hazard
as the spilled product. Note: see section1 for emergency contact
information and section 13 for waste disposal.
Environmental precautions
Accidental release measures
: Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drainsand sewers. Inform the relevant
authorities if the product has caused environmentalpollution
(sewers, waterways, soil or air).
Personal precautions :
Large spill :
6 .
Stop leak if without risk. Move containers from spill area.
Dilute with water and mop upif water-soluble or absorb with an
inert dry material and place in an appropriate wastedisposal
container. Use spark-proof tools and explosion-proof equipment.
Dispose ofvia a licensed waste disposal contractor.
Small spill :Methods for cleaning up
Store in accordance with local regulations. Store in a
segregated and approved area.Store in original container protected
from direct sunlight in a dry, cool and well-ventilatedarea, away
from incompatible materials (see section 10) and food and drink.
Eliminateall ignition sources. Separate from alkalis. Separate from
oxidizing materials. Keepcontainer tightly closed and sealed until
ready for use. Containers that have beenopened must be carefully
resealed and kept upright to prevent leakage. Do not store
inunlabeled containers. Use appropriate containment to avoid
environmentalcontamination.
Put on appropriate personal protective equipment (see section
8). Eating, drinking andsmoking should be prohibited in areas where
this material is handled, stored andprocessed. Workers should wash
hands and face before eating, drinking and smoking.Do not get in
eyes or on skin or clothing. Do not breathe vapor or mist. Do not
ingest.Use only with adequate ventilation. Wear appropriate
respirator when ventilation isinadequate. Do not enter storage
areas and confined spaces unless adequatelyventilated. Keep in the
original container or an approved alternative made from acompatible
material, kept tightly closed when not in use. Store and use away
from heat,sparks, open flame or any other ignition source. Use
explosion-proof electrical(ventilating, lighting and material
handling) equipment. Use non-sparking tools. Takeprecautionary
measures against electrostatic discharges. To avoid fire or
explosion,dissipate static electricity during transfer by grounding
and bonding containers andequipment before transferring material.
Keep away from alkalis. Empty containersretain product residue and
can be hazardous. Do not reuse container.
Handling and storageHandling
Storage
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7 .
Exposure controls/personal protectionProduct name Exposure
limits
8 .
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DELTAGREEN ACID BOWL CLEANERDate of issue: August 7, 2013
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Exposure controls/personal protection8 .phosphoric acid ACGIH
TLV (United States, 1/2008).
TWA: 1 mg/m³ 8 hour(s). STEL: 3 mg/m³ 15 minute(s).OSHA PEL 1989
(United States, 3/1989). TWA: 1 mg/m³ 8 hour(s). STEL: 3 mg/m³ 15
minute(s).NIOSH REL (United States, 6/2008). TWA: 1 mg/m³ 10
hour(s). STEL: 3 mg/m³ 15 minute(s).OSHA PEL (United States,
11/2006). TWA: 1 mg/m³ 8 hour(s).
Isopropanol ACGIH TLV (United States, 1/2008). TWA: 200 ppm 8
hour(s). STEL: 400 ppm 15 minute(s).OSHA PEL 1989 (United States,
3/1989). TWA: 400 ppm 8 hour(s). TWA: 980 mg/m³ 8 hour(s). STEL:
500 ppm 15 minute(s). STEL: 1225 mg/m³ 15 minute(s).NIOSH REL
(United States, 6/2008). TWA: 400 ppm 10 hour(s). TWA: 980 mg/m³ 10
hour(s). STEL: 500 ppm 15 minute(s). STEL: 1225 mg/m³ 15
minute(s).OSHA PEL (United States, 11/2006). TWA: 400 ppm 8
hour(s). TWA: 980 mg/m³ 8 hour(s).
hydrochloric acid ACGIH TLV (United States, 1/2008). C: 2
ppmOSHA PEL 1989 (United States, 3/1989). CEIL: 5 ppm CEIL: 7
mg/m³NIOSH REL (United States, 6/2008). CEIL: 5 ppm CEIL: 7
mg/m³OSHA PEL (United States, 11/2006). CEIL: 5 ppm CEIL: 7
mg/m³
Use a properly fitted, air-purifying or air-fed respirator
complying with an approvedstandard if a risk assessment indicates
this is necessary. Respirator selection must bebased on known or
anticipated exposure levels, the hazards of the product and the
safeworking limits of the selected respirator.
Personal protectionRespiratory :
Chemical-resistant, impervious gloves complying with an approved
standard should beworn at all times when handling chemical products
if a risk assessment indicates this isnecessary.
:sdnaH
Engineering measures : Use only with adequate ventilation. Use
process enclosures, local exhaust ventilation orother engineering
controls to keep worker exposure to airborne contaminants below
anyrecommended or statutory limits. The engineering controls also
need to keep gas, vaporor dust concentrations below any lower
explosive limits. Use explosion-proof ventilationequipment.
Hygiene measures : Wash hands, forearms and face thoroughly
after handling chemical products, beforeeating, smoking and using
the lavatory and at the end of the working period.
Appropriatetechniques should be used to remove potentially
contaminated clothing. Washcontaminated clothing before reusing.
Ensure that eyewash stations and safety showersare close to the
workstation location.
Recommended monitoringprocedures
: If this product contains ingredients with exposure limits,
personal, workplace atmosphereor biological monitoring may be
required to determine the effectiveness of the ventilationor other
control measures and/or the necessity to use respiratory protective
equipment.
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DELTAGREEN ACID BOWL CLEANERDate of issue: August 7, 2013
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Exposure controls/personal protection8 .Safety eyewear complying
with an approved standard should be used when a riskassessment
indicates this is necessary to avoid exposure to liquid splashes,
mists,gases or dusts.Personal protective equipment for the body
should be selected based on the task beingperformed and the risks
involved and should be approved by a specialist before handlingthis
product.
Eyes
Skin
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Environmental exposurecontrols
: Emissions from ventilation or work process equipment should be
checked to ensure theycomply with the requirements of environmental
protection legislation. In some cases,fume scrubbers, filters or
engineering modifications to the process equipment will benecessary
to reduce emissions to acceptable levels.
Physical and chemical properties9 .Liquid.
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DELTAGREEN ACID BOWL CLEANERDate of issue: August 7, 2013
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Toxicological information11 .Conclusion/Summary : Isopropanol:
Exposure can cause nausea, headache and vomiting.
CarcinogenicityClassification
--.enoN---dica cirohpsohpdodecylbenzenesulfonic acid - - - None.
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--.enoN-34AlonaporposI34Adica cirolhcordyh - - - -
Product/ingredient name ACGIH EPA NIOSH NTP AHSOCRAI
Sensitizer
:nikS Isopropanol: Prolonged or repeated contact can defat the
skin and lead to irritation,cracking and/or dermatitis.
Ecological informationEnvironmental effects : No known
significant effects or critical hazards.
12 .
Aquatic ecotoxicity
sruoh 84hsiFL/gm 00001 05CE etucA-lonaporposIsruoh 69hsiFL/gm
00401 05CL etucA-sruoh 69hsiFL/gm 03111 05CL etucA-sruoh 69hsiFL/gm
0469 05CL etucA-sruoh 69hsiFL/gm 0556 05CL etucA-sruoh 69hsiFL/gm
0041> 05CL etucA-
seicepStseTeman tneidergni/tcudorP erusopxEtluseR
The generation of waste should be avoided or minimized wherever
possible. Emptycontainers or liners may retain some product
residues. This material and its containermust be disposed of in a
safe way. Dispose of surplus and non-recyclable products viaa
licensed waste disposal contractor. Disposal of this product,
solutions and any by-products should at all times comply with the
requirements of environmental protectionand waste disposal
legislation and any regional local authority requirements.
Avoiddispersal of spilled material and runoff and contact with
soil, waterways, drains andsewers.
Waste disposal
Disposal considerations:
13 .
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE
CONTROLS/PERSONAL PROTECTIONfor additional handling information and
protection of employees.
Transport information
-8
8
CORROSIVE
DOT Classification Corrosive liquid,acidic, inorganic,n.o.s.
(PhosphoricAcid, HydrochloricAcid)
II
IMDG Class Corrosive liquid,acidic, inorganic,n.o.s.
(PhosphoricAcid, HydrochloricAcid)
8 II
8
Corrosive liquid,acidic, inorganic,n.o.s. (PhosphoricAcid,
HydrochloricAcid)
3264IATA-DGR Class
8
8
Regulatoryinformation
UN number Proper shippingname
Classes PG* Label Additionalinformation
II
3264 -
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3264
14 .
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DELTAGREEN ACID BOWL CLEANERDate of issue: August 7, 2013
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Transport information14 .PG* : Packing group
Combustible liquidToxic materialCorrosive materialTarget organ
effects
HCS Classification
Regulatory information
U.S. Federal regulations
Connecticut Carcinogen Reporting: None of the components are
listed.Connecticut Hazardous Material Survey: None of the
components are listed.Florida substances: None of the components
are listed.Illinois Chemical Safety Act: None of the components are
listed.Illinois Toxic Substances Disclosure to Employee Act: None
of the components arelisted.Louisiana Reporting: None of the
components are listed.Louisiana Spill: None of the components are
listed.Massachusetts Spill: None of the components are
listed.Massachusetts Substances: The following components are
listed: phosphoric acid;dodecylbenzenesulfonic acid;
Isopropanol;hydrochloric acidMichigan Critical Material: None of
the components are listed.Minnesota Hazardous Substances: None of
the components are listed.New Jersey Hazardous Substances: The
following components are listed: phosphoricacid;
dodecylbenzenesulfonic acid; Isopropanol;hydrochloric acidNew
Jersey Spill: None of the components are listed.New Jersey Toxic
Catastrophe Prevention Act: None of the components are listed.New
York Acutely Hazardous Substances: The following components are
listed:Phosphoric acid; Dodecylbenzenesulfonic acid;Hydrochloric
acidNew York Toxic Chemical Release Reporting: None of the
components are listed.Pennsylvania RTK Hazardous Substances: The
following components are listed:phosphoric acid;
dodecylbenzenesulfonic acid; Isopropanol;hydrochloric acidRhode
Island Hazardous Substances: None of the components are listed.
TSCA 4(a) final test rules: IsopropanolUnited States inventory
(TSCA 8b): All components are listed or exempted.TSCA 8(d) H and S
data reporting: Isopropanol: 1986TSCA 12(b) one-time export:
Isopropanol
Clean Water Act (CWA) 307: No products were found.Clean Water
Act (CWA) 311: phosphoric acid; dodecylbenzenesulfonic
acid;hydrochloric acidClean Air Act (CAA) 112 accidental release
prevention: hydrochloric acidClean Air Act (CAA) 112 regulated
flammable substances: hydrochloric acidClean Air Act (CAA) 112
regulated toxic substances: hydrochloric acid
State regulations
SARA 302/304/311/312 extremely hazardous substances:
hydrochloric acidSARA 302/304 emergency planning and notification:
hydrochloric acidSARA 302/304/311/312 hazardous chemicals:
phosphoric acid;dodecylbenzenesulfonic acid; Isopropanol;
hydrochloric acidSARA 311/312 MSDS distribution - chemical
inventory - hazard identification:phosphoric acid: Immediate
(acute) health hazard; dodecylbenzenesulfonic acid:Immediate
(acute) health hazard; Isopropanol: Fire hazard, Immediate (acute)
healthhazard, Delayed (chronic) health hazard; hydrochloric acid:
Sudden release of pressure,Immediate (acute) health hazard, Delayed
(chronic) health hazard
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SARA 313
:
Product name CAS number Concentration
SARA 313 notifications must not be detached from the MSDS and
any copying and redistribution of the MSDS shallinclude copying and
redistribution of the notice attached to copies of the MSDS
subsequently redistributed.
15 .
01 - 50-36-76lonaporposI5 - 10-10-7467dica cirolhcordyh01 -
50-36-76lonaporposI
5 - 10-10-7467dica cirolhcordyh
Form R - ReportingrequirementsSupplier notification
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DELTAGREEN ACID BOWL CLEANERDate of issue: August 7, 2013
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Regulatory information15 .
United States inventory(TSCA 8b)
: United States inventory (TSCA 8b): All components are listed
or exempted.
Other information
02
3
National Fire ProtectionAssociation (U.S.A.)
Health
Special
Instability
Flammability
Notice to readerTo the best of our knowledge, the information
contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability
whatsoever for theaccuracy or completeness of the information
contained herein.Final determination of suitability of any material
is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain
hazardsare described herein, we cannot guarantee that these are the
only hazards that exist.
Date of printingDate of issue
August 7, 2013August 7, 2013
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16 .
Indicates information that has changed from previously issued
version.
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