40
1 Numerical study on Numerical study on efficiency droop of blue efficiency droop of blue InGaN light-emitting InGaN light-emitting diodes diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De C hen Department of Physics, National Changhua Uni versity of Education, Changhua 500, Taiwan *E-mail: [email protected]

1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

Embed Size (px)

Citation preview

Page 1: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

1

Numerical study on efficiency droop Numerical study on efficiency droop

of blue InGaN light-emitting diodesof blue InGaN light-emitting diodes

Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen

Department of Physics, National Changhua University of Education, Changhua 500, Taiwan

*E-mail: [email protected]

Page 2: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

2

Introduction

Simulation results and discussion 1. InGaN barriers

2. P-doped barriers

3. P-type last barrier

4. AlGaN barriers

5. Varied barrier thicknesses

6. N-type AlGaN layer

7. Specific designs on electron blocking layer

8. Thin last barrier

Conclusion

Outline

Page 3: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

3

Introduction

In III-N LEDs, the quantum efficiency typically reaches its peak at low current density and then decreases with further increasing drive current, which is commonly referred to as “efficiency droop”. 50

60

70

80

90

100

0 20 40 60 80 100

with droopwithout droop

Nor

mal

ized

quan

tum

eff

icie

ncy

(%)

Current (mA)

Page 4: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

4

Introduction

Poor hole injection efficiency, electron current leakage, and non-uniform distribution of carriers in the active region usually play an important role for efficiency droop.

In this work, several specific configurations in the active region and electron blocking layer (EBL) of blue InGaN LEDs are investigated numerically with the APSYS simulation program.

Page 5: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

5

Study 1: InGaN barriers

Page 6: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

6

Study 1: InGaN barriers

0

1

2

3

4

5

104.5 104.6 104.7

Distance (m)

Ene

rgy

(eV

)

Quasi-Fermi level

n-side p-side

enlarged in (b)

enlarged in (c)

(a)

(c)(b)

2.8

3.2

3.6

4

104.6 104.65

Distance (m)

Ene

rgy

(eV

)

0

0.8

1.6

2.4

3.2

4

104.634

Distance (m)

Ene

rgy

(eV

)

wavefunctions

hole electron

※ Original LED (fabricated by EpiStar Inc.)• Active region: five pairs of In0.21Ga0.79N/ GaN (2 nm/15 nm) QWs• EBL: 20-nm-thick p-Al0.15Ga0.85N• Concentration: n-51018 cm–3; p-1.21018 cm–3

• Device geometry: 300300 m2

1.The sloped triangular barriers induced by the polarization effect cause conduction band edge of barriers to be higher than that of the EBL.

This results in the insufficient electron blocking efficiency and thereby serious electron current leakage.

2.The electron and hole wavefunctions separate partially.

This results in the reduction of the radiative recombination rate and IQE. Fig. 1. The energy band diagram of the original

InGaN/GaN structure at 150 mA.(Appl. Phys. Lett., vol. 95, p. 011116, 2009)

Page 7: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

7

Fig. 2. The energy band diagram of the proposed InGaN LED structure with In0.1Ga0.9N barriers at 150 mA .

Study 1: InGaN barriers

1. The effective barrier height between last barrier and EBL increases dramatically due to lower conduction band energy of the InGaN barrier.

This results in the enhanced electron blocking efficiency of EBL.

2. Owing to better match of lattice constants between the InGaN barrier and InGaN well, the band bending situation is less severe.

This results in less QCSE and better light-emitting efficiency.

0

1

2

3

4

5

104.5 104.6 104.7

Distance (m)

Ene

rgy

(eV

)

Quasi-Fermi level

n-side

p-side

enlarged in (b)

enlarged in (c)

(a)

(c)(b)

0

0.8

1.6

2.4

3.2

4

104.634

Distance (m)

Ene

rgy

(eV

)

wavefunctions

hole electron

2.8

3.2

3.6

4

104.6 104.65

Distance (m)

Ene

rgy

(eV

)

Page 8: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

8

Study 1: InGaN barriers

0

5

10

15

20

25

30

35

104.5 104.6 104.7

ElectronHole

Distance (m)

Car

rier

con

cent

ratio

n (1

018

cm

3)

(a)

0

10

20

30

40

50

60

104.5 104.6 104.7

ElectronHole

Distance (m)

Car

rier

con

cent

ratio

n (1

018

cm

-3)

(b)

0

20

40

60

80

100

0 25 50 75 100 125 150

InGaN/GaNInGaN/InGaN

Current (mA)

IQE

(%

)

(a) (b)0

50

100

150

200

250

300

0 25 50 75 100 125 150

Current (mA)

Pow

er (

mW

)

Fig. 3. Carrier concentrations of (a) original and (b) proposed structures near active region at 150 mA.

Fig. 4. (a) IQE and (b) L-I curve for the two LED structures under study.

1. In Fig. 3: In the proposed InGaN/InGaN structure, more electrons and holes transport int

o the active region and contribute to the radiative recombination. Both electron and hole distributions in the QWs of the proposed InGaN/InGaN

structure are more uniform than those of the original structure.2. In Fig. 4: The InGaN/InGaN LED has better light-emitting efficiency (especially at high

current) and is almost without efficiency droop.

Page 9: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

9

Study 2: P-doped barriers

Page 10: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

10

Study 2: P-doped barriers

GaN barrier

(a)

p-sideInGaN well

15 nm

Original structure

GaN barrier

InGaN well

10 nm

p = 5×1017 cm–3p = 1×1017 cm–3

p = 3×1017 cm–3

5 nm 5 nm

Mg-doping increase

(b)

Structure A

GaN barrier

InGaN well

10 nm

p = 3×1017 cm–3p = 3×1017 cm–3

p = 3×1017 cm–3

5 nm 5 nm

(c)

Structure B Fig. 5. Schematic diagrams of the InGaN/GaN active region for: (a) the original structure, (b) structure A, and (c) structure B.

1. The barriers are partially p-doped in selected regions in order to increase the hole injection and improve the carrier distribution across the MQWs.

2. The reason of “partial” p-doping in “selected regions” is to avoid the diffusion of Mg into the quantum well during crystal growth.

(IEEE Photonics Technol. Lett., vol. 22, p. 374, 2009)

Page 11: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

11

Study 2: P-doped barriers

0

20

40

60

80

100

120 Experimental dataOriginal structureStructure AStructure B

Out

put p

ower

(m

W)

0

10

20

30

40

50

60

70

0 50 100 150 200Inte

rnal

qua

ntum

eff

icie

ncy

(%)

Current density (A/cm2)

0

4

8

12

16

Growth direction

Hol

e co

ncen

trat

ion

(1018

/cm

3 )

Original structureStructure AStructure B

@ 22 A/cm2

Fig. 6. (a) L-I curves and (b) IQEs of the blue InGaN LEDs as a function of the forward current density.

Fig. 7. Hole concentration of the original structure, structure A, and structure B in the active region at 22 A/cm2 (20 mA).

1. When the partially p-doped GaN barriers are employed, the output powers and IQEs of the InGaN LEDs are all enhanced sufficiently.

2. This is because that structure A and B possess higher concentration of holes inside the QWs due to the improved hole injection efficiency.

3. When the three barriers near the p-layer are p-doped with a gradually increased doping concentration (structure A), more holes are confined within the QWs, especially the two QWs close to the p-layer, which have the most contribution to the emission power.

Page 12: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

12

Study 3: P-type last barrier

Page 13: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

13

Study 3: P-type last barrier

GaN barrier

(a)

(c)

Mg-doped region

p-sideInGaN well

15 nm

10 nm

(b)

Mg-doped region

Fig. 8. Schematic diagrams of the InGaN/GaN active regions: (a) the original structure, (b) structure with p-doping in the last barrier, and (c) structure with partial p-doping in two-thirds of the last barrier.

0

20

40

60

80

100

120

140

160 Experimental dataOriginal structure

p = 1x1017cm 3

p = 5x1017cm 3

p = 1x1018cm 3

p = 1x1017cm 3/10 nm

p = 5x1017cm 3/10 nm

p = 1x1018cm 3/10 nm

Out

put p

ower

(m

W)

(a)

0

10

20

30

40

50

60

70

80

0 25 50 75 100 125 150

Current (mA)

Inte

rnal

qua

ntum

eff

icie

ncy

(%)

(b)

The output power and IQE are both enhanced sufficiently, when the last undoped GaN barrier is replaced by a p-type GaN barrier.

Fig. 9. (a) Simulated L-I curves and the experimental data and (b) IQEs of the blue InGaN LEDs.

(IEEE J. Quantum Electron., vol. 22, p. 374, 2009)

Page 14: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

14

Study 3: P-type last barrier

0

4

8

12

16

Original strucutreStructure AStructure B

@ 20 mA

Hol

e co

nent

ratio

n (1

018/c

m3 )

(a)

0

5

10

15

20

25

30

35

40

104.57 104.58 104.59 104.60 104.61 104.62 104.63

@ 150 mA

Distance (m)

Hol

e co

nent

ratio

n (1

018/c

m3 )

(b)

Fig. 10. Hole concentrations of the original structure, structure A, and structure B in the active regions at (a) 20 mA and (b) 150 mA.

As indicated in Fig. 10, both structure A and structure B possess relatively high hole concentration inside the QWs because the hole injection efficiency is effectively improved.

Page 15: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

15

Study 3: P-type last barrier

0

0.5

1

1.5

2

2.5

3

3.5

4

104.57 104.58 104.59 104.60 104.61 104.62 104.63

Original structureStructure AStructure B

Distance (m)

Rad

iati

ve r

ecom

bina

tion

rate

(10

28/c

m3 -s

)

@ 150 mA

0

0.2

0.4

0.6

0.8

1

104.57 104.58 104.59 104.60 104.61 104.62 104.63

Rad

iativ

e re

com

bina

tion

rate

(10

28/c

m3 -s

)

Distance (m)

@ 20 mA

Fig. 11. Radiative recombination rate of the original structure, structure A, and structure B in the active region at 150 mA. The inset shows the radiative recombination rates at 20 mA.

1. The total radiative recombination rates inside the QWs of structure A and B at 20 (150) mA are improved by a factor of 1.35 (2.15) and 1.33 (2.06), respectively, as compared to that of original one.

2. Therefore, at high current, the optical performance of the blue InGaN LEDs under study can be markedly enhanced when the last barrier is fully or partially p-doped.

Page 16: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

16

Study 4: AlGaN barriers

Page 17: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

17

Study 4: AlGaN barriers

1. The use of an AlGaN barrier instead of a GaN barrier can diminish the polarization charges accumulating in the last-barrier/EBL interface, which accordingly can relax the band-bending of the EBL. Due to this phenomenon, the effective potential barrier height for holes in the valence band decreases and hence the transportation of holes into the active region becomes easier.

2. In the meantime, the ability of electron confinement in the last-barrier/EBL interface does not degrade under this variation.

3. As a result, it is expected that the efficiency of hole injection can be enhanced for the structure with AlGaN barriers without the cost of reduction of electron confinement.

Table 1. Surface Charge Density Between Well Layer and Barrier Layer

Table 2. Surface Charge Density Between (last) Barrier Layer and EBL

(Opt. Lett., vol. 35, p. 1368, 2010 )

Page 18: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

18

Study 4: AlGaN barriers

0

1

2

3

4

104.58 104.65

Distance (m)

Ene

rgy

(eV

)

quasi-Fermi level

p-side

enlarged in (c)

enlarged in (e)

(a) (b)

104.62 104.65

effectivepotentialheight

(for electrons)(f)

effectivepotential

height(for holes)

(d)

3

3.5

104.62 104.65

effectivepotentialheight

(for electrons)(e)

0

0.5effectivepotential

height(for holes)

(c)

104.58 104.65

enlarged in (d)

enlarged in (f)

quasi-Fermi level

p-side

Fig. 12. Energy band diagrams of InGaN/GaN and InGaN/AlGaN structures at 150 mA.

1. The effective potential height for holes in the valence band of the InGaN/AlGaN structure is lower than that of the InGaN/GaN one due to slighter polarization effect in the last-barrier/EBL interface.

Better hole injection efficiency is anticipated.

2. Besides, the effective potential height for the electrons in the conduction band of the InGaN/AlGaN structure becomes higher than the other structure, which demonstrates the enhancement of electron confinement.

Page 19: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

19

Study 4: AlGaN barriers

0

50

100

150

200

250

300

3.5

4

4.5

5

0 50 100 150

Pow

er (

mW

) Voltage (V

)

Current (mA)

(a)(b)

0

20

40

60

80

100

0 50 100 150

GaN barrierAl

0.05Ga

0.95N barrier

IQE

(%

)

Current (mA)

Fig. 14. (a) L-I-V (b) IQE performance curves of the InGaN/GaN and InGaN/AlGaN structures.

0

20

40

60 ElectronHole

104.58 104.61 104.64

Car

rier

con

cent

rati

on (

1018

cm

-3)

150 mA

GaN barrier

Distance (m)

(a)

104.58 104.61 104.64

Distance (m)

Al0.05

Ga0.95

N barrier

(b)

Fig. 13. Carrier concentrations of (a) InGaN/GaN and (b) InGaN/AlGaN structures near active region at 150 mA.

1. Ascribing to the enhancement of hole injection and electron confinement, for the InGaN/AlGaN structure, there are more carriers in the active region

2. Thus, the InGaN/AlGaN structure has higher IQE and output power in the whole range of current injection under study.

3. The efficiency droop is markedly improved when the traditional GaN barriers are replaced by AlGaN.

Page 20: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

20

Study 5: Varied barrier

thicknesses

Page 21: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

21

Study 5: Varied barrier thicknesses

1. For this study: The original structure of the blue LED used in the simulation is with equal

barrier thickness of 15 nm. In structure A, the thicknesses of all the three barriers next to the n-side

layers are 15 nm, which is identical to the barrier thickness of the original structure. The thickness of the three barriers next to the p-side layer are reduced to 10 nm.

In structure B, the thicknesses of the barriers from the n-side to p-side layers decrease linearly from 15 nm to 5 nm with a step of 2 nm.

2. In the two redesigned structures, the thicker barriers located close to the n-side layers are used for increasing the electron transport distance while the thinner barriers located close to the p-side layers are used for reducing the hole transport distance.

Based on this rationale, it is expected that the electrons leaking out of the active region will reduce and the holes injecting into the active region will increase. (To be published in IEEE Photonics Technol. Lett.)

Page 22: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

22

Study 5: Varied barrier thicknesses

0

10

20

30

40

50

60

70

80

0 20 40 60 80 100 120

IQE

(%

)

Current (mA)

0

40

80

120

160

Original structureStructure AStructure BExperimental data

Out

put p

ower

(m

W) 1x10 34cm6/s

(a)

0

10

20

30

40

50

601x10 30cm6/s

0

10

20

30

40

50

0 20 40 60 80 100 120

Current (mA)

(c)

(b) (d)

Fig. 15. (a) L-I curves and (b) IQEs of the original structure, structure A, and structure B under an Auger coefficient of 1×10–34 cm6/s; (c) L-I curves and (d) IQEs of the original structure, structure A, and structure B under an Auger coefficient of 1×10–30 cm6/s.

1. The output powers of structures A and B are enhanced greatly as compared with the original structure for the both cases with 1×10–34 cm6/s and 1×10–30 cm6/s Auger coefficients.

2. However, the efficiency droop for the original structure under an Auger coefficient of 1×10–30 cm6/s is 72.9%, which is much larger than the value obtained experimentally (in a range of 23–53%).

Therefore, an Auger coefficient of 1×10–34 cm6/s is utilized for subsequent investigations on the optical properties of the blue LEDs under study.

Page 23: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

23

Study 5: Varied barrier thicknesses

0

4

8

12

16

20

104.57 104.58 104.59 104.60 104.61 104.62 104.63

HoleElectron

@ 20 mA

Car

rier

con

cent

ratio

n (1

018

/cm

3 )

(a)

0

4

8

12

16

20

104.57 104.58 104.60 104.62

HoleElectron

(b)

0

4

8

12

16

20

104.57 104.58 104.60 104.61

HoleElectron

Distance (m)

@ 20 mA

(c)

Fig. 16. Electron and hole concentrations of (a) original structure, (b) structure A, and (c) structure B at 20 mA.

1. Decrease in thickness of barriers next to the p-side layers is beneficial for enhancing the injection of holes into the active region and hole transportation in the active region, which would allow more holes to reach the QWs near the n-side layers.

2. Among the two redesigned structures, structure B possesses the largest amounts of carriers and the most uniform distribution of carriers inside the active region.

Page 24: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

24

Study 5: Varied barrier thicknesses

0

0.4

0.8

1.2

1.6

104.57 104.58 104.59 104.60 104.61 104.62 104.63

@ 20 mA@ 120 mA

Rad

iati

ve r

ecom

bina

tion

rate

(10

28 c

m3

/s)

(a)

0

0.4

0.8

1.2

1.6

104.57 104.58 104.60 104.62

@ 20 mA@ 120 mA

(b)

0

0.4

0.8

1.2

1.6

104.57 104.58 104.60 104.61

@ 20 mA@ 120 mA

Distance (m)

(c)

Fig. 17. Radiative recombination rates of (a) the original structure, (b) structure A, and (c) structure B at 20 mA and 120 mA.

1. As the thickness of barriers close to the p-side layers decreases, more QWs contribute to radiative recombination due to the marked improvement in hole injection efficiency.

2. For the original structure, the total radiative recombination rate is enhanced by a factor of 3.77 when the injection current increases from 20 mA to 120 mA. On the other hand, for structures A and B, the total radiative recombination rates are enhanced by a factor of 4.15 and 5.67, respectively, when the injection current increases from 20 mA to 120 mA.

The improvement is because that more QWs, especially the three QWs close to the p-side layers, can contribute to radiative recombination.

Page 25: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

25

Study 6: N-type AlGaN layer

Page 26: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

26

Study 6: N-type AlGaN layer

0

20

40

60

80

100

0 20 40 60 80 100 120

P-EBLN-EBL

Inte

rnal

qua

ntum

eff

icie

ncy

(%)

Current (mA)

15 mA

Fig. 18. L-I curves of the LEDs with P and N-AlGaNs. Experimental data are shown by green solid dots.

Fig. 19. IQE of the LEDs with P and N-AlGaNs.

0

50

100

150

200

250

0 20 40 60 80 100 120

ExperimentP-AlGaNN-AlGaN

Current (mA)

Pow

er (

mW

)

0

5

10

15

20

0 4 8 12 16

P-AlGaNN-AlGaN

6 mA

1. The output power of the LED with N-AlGaN at 120 mA is improved by a factor of 2.37 as compared with that with P-AlGaN.

2. The efficiency droop of the LED with N-AlGaN at 120 mA is markedly improved as compared to that with P-AlGaN.

(IEEE Photonics Technol. Lett., vol. 21, p. 975, 2009)

Page 27: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

27

Study 6: N-type AlGaN layer

0

5

10

15

20

25

30

P-AlGaNN-AlGaN

Hol

e co

ncen

trat

ion

(1018

/cm

3 )

(a)

p-side@120 mA

0

5

10

15

20

25

30P-AlGaNN-AlGaN

Growth direction

Ele

ctro

n co

ncen

trat

ion

(1018

/cm

3 )

(b)

p-side

For the N-AlGaN LED:1. More holes transport to the QWs next

to the n-side layer due to the absence of P-AlGaN.

2. The amount of electrons in the active region also increases, despite that the concentration of electrons in the last QW is reduced.

As a result, the radiative recombination rates are more uniform in QWs and almost all QWs can contribute to output power. Thus, the IQE droop at high current may be improved due to the enhanced electron and hole injection efficiencies.

Fig. 20. (a) Hole and (b) electron concentrations of the LEDs with P-AlGaN and N-AlGaN at 120 mA.

Page 28: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

28

0

1

2

3

4

Ene

rgy

(eV

)

(a)

Quasi-Fermi levelN-AlGaN

0

1

2

3

4

104.55 104.58 104.61 104.64 104.66

Distance (m)

Ene

rgy

(eV

)

Quasi-Fermi levelP-AlGaN

(b)

Fig. 21. Band diagrams and quasi-Fermi levels of the LEDs with (a) N-AlGaN and (b) P-AlGaN layers at 120 mA.

For the N-AlGaN LED:• The electron distribution in the QWs is m

ore uniform, as indicated in the relative position of the quasi-Fermi levels.

For the P-AlGaN LED:• The strong electric field, caused by the po

larization effect, lowers the conduction band energy in the last barrier.

This is a negative effect for the confinement of electrons at high carrier density.

The percentages of electron leakage current for the LEDs with P-AlGaN and N-AlGaN are 46.1% and 4.5%, respectively, at 120 mA.

Study 6: N-type AlGaN layer

Page 29: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

29

Study 7: Specific designs on

electron blocking layer

Page 30: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

30

Study 7: Specific designs on electron blocking layer

1. There is a side effect of the usage of EBL the EBL also acts as a potential barrier for holes in the valence band and impedes the transportation of holes into the active region.

2. The downward band-bending in the last barrier/EBL interface induced by electrostatic polarization makes this problem even more serious.

0

1

2

3

4

104.56 104.6 104.64 104.68

Distance (m)

Ene

rgy

(eV

)

n-side p-side

quasi-Fermi level

@ 150 mA

EBL

0

0.5

104.64 104.68

Distance (m)

Ene

rgy

(eV

)

Effective potential heightfor holes

◎ Without polarization

0

1

2

3

4

104.56 104.6 104.64 104.68

Distance (m)

Ene

rgy

(eV

)

n-side p-side

quasi-Fermi level

EBL

@ 150 mA

0

0.5

104.64 104.68

Distance (m)

Ene

rgy

(eV

)

Effective potential heightfor holes

enlarged enlarged

◎ With polarization

(Opt. Lett., vol. 35, p. 3285, 2010)

Page 31: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

31

Study 7: Specific designs on electron blocking layer

Main goal of this study: Main goal of this study: To increase the efficiency of hole injection without losing the blocking capability for electrons.

PlanPlan:: Reduce the polarization charge density in the last barrier/EBL interface in order to mitigate downward band-bending of this interface.

Method:Method: Some specific designs on EBL of blue InGaN LEDs are proposed.

Fig. 22. Schematic diagrams of the original structure and the structures with redesigned EBLs.

1. Structure A is the original structure.

2. The structures of structure B, C, and D are identical except for the EBLs.

Page 32: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

32

Study 7: Specific designs on electron blocking layer

Table 3. Surface Charge Density in the “Last-Barrier/EBL” and “Front-EBL/Rear-EBL” Interfaces

-4

-3

-2

-1

0

1

2

3

104.62 104.64 104.66 104.68

ABCD

Distance (m)

Ele

ctro

stat

ic f

ield

(10

5 V/c

m)

150 mA

EBL

Fig. 23. Electric fields of various InGaN/GaN structures near the EBLs at 150 mA.

The original structure (structure A) possesses much stronger electrostatic field in the last-barrier/EBL interface than the redesigned structures because of high surface charge density.

Page 33: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

33

Study 7: Specific designs on electron blocking layer

3.2

3.3

3.4

3.5

3.6

104.64 104.66 104.68

Distance (m)

Ene

rgy

(eV

)

EBL

conduction band

150 mA

-0.3

-0.2

-0.1

0

0.1

104.64 104.66 104.68

ABCD

Distance (m)

Ene

rgy

(eV

)

valence band

EBL

150 mA

(a) (b)0

10

20

30

40

50

60

104.56 104.6 104.64

AB

CD

Distance (m)

Hol

e co

ncen

trat

ion

(10

18 c

m-3

)

12

14

16

18

20

104.56 104.6 104.64

0

10

20

30

40

50

60

104.56 104.6 104.64

Distance (m)

Ele

ctro

n co

ncen

trat

ion

(10

18 c

m-3

)

150 mA

8

10

12

14

16

18

20

104.56 104.6 104.64

(a) (b)

Fig. 25. (a) Hole and (b) electron concentrations in the active regions of various InGaN/GaN structures at 150 mA. The insets show the comparison of cases A and D in LOG scale.

Fig. 24. Enlarged energy band diagrams near the EBLs of various InGaN/GaN structures in (a) conduction band and (b) valence band at 150 mA.

1. The situation of downward band-bending at the interfaces near the EBL of all the three redesigned structures are slighter than that of the original one, which will lead to the enhancement of hole injection efficiency.

2. The hole concentrations of the redesigned structures increase obviously, which demonstrates the improvement of hole injection efficiency. Besides, the redesigned structures also have higher electron concentrations, which indicates that the capability of electron confinement does not suffer from the modifications of EBL.

Page 34: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

34

Study 7: Specific designs on electron blocking layer

0

50

100

150

200

250

0 25 50 75 100 125 150

ABCD

Current (mA)

Pow

er (

mW

)

0

20

40

60

80

100

0 25 50 75 100 125 150

Current (mA)

IQE

(%

)

(a) (b)

Fig. 26. (a) L-I curves and (b) IQE as a function of current for various InGaN/GaN structures.

1. The overall performances of the redesigned structures show significant enhancement as compared with that of the original structure.

2. Structure D seems to be the most superior one among these redesigned structures due to the reduced efficiency droop and higher light output power at elevated level of current injection.

Page 35: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

35

Study 8: Thin last barrier

Page 36: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

36

Study 8: Thin last barrier

(IEEE Photonics Technol. Lett., vol. 22, p. 1787, 2010)

0

5

10

15

20

25

103.10 103.15 103.20 103.25

Last barrier = 12 nm

Hol

e co

ncen

trat

ion

(1018

cm

3)

Distance (m)

(a)

0

5

10

15

20

25

103.10 103.15 103.20 103.25

Last barrier = 9 nm

Hol

e co

ncen

trat

ion

(1018

cm

3)

Distance (m)

(b)

14

15

16

17

18

19

103.14 103.18 103.23 103.28

12 nm 9 nm

Ele

ctro

n co

ncen

trat

ion,

log

(cm

3)

Distance (m)

Electron leakage

Fig. 27. Distribution of hole concentrations of the LEDs with (a) 12-nm and (b) 9-nm last barriers at 55 A/cm2.

Fig. 28. Distribution of electron concentrations of the LEDs with 12-nm and 9-nm last barriers at 55 A/cm2.

※ Original structure:• Active region: ten pairs of In0.21Ga0.79N/ GaN (2 nm/12 nm) QWs• EBL: 10-nm-thick p-Al0.10Ga0.90N• Concentration: n-41018 cm–3; p-51017 cm–3

• Device geometry: 245560 m2

• A thinner last-barrier could be beneficial for increasing the hole injection efficiency so that holes can inject into more QWs within the active region.

2.With better hole injection efficiency, electron leakage can be depressed correspondingly.

3.The radiative recombination and optical power are enhanced accordingly when thinner last-barrier is adopted.

Page 37: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

37

Study 8: Thin last barrier

0

4

8

12

16

103.10 103.15 103.20 103.25

L.B. = 12 nm

L.B. = 9 nm

Rad

iati

ve r

ecom

bina

tion

rate

(1026

cm3

/s)

Distance (m)

0

0.5

1

1.5

2

103.12 103.14 103.16 103.18 103.20Distance (m)

0

10

20

30

40

50

60

70

0 20 40 60 80 100

Last barrier = 12 nmLast barrier = 9 nm

Inte

rnal

qua

ntum

eff

icie

ncy

(%)

Current density (A/cm2)

Fig. 30. IQE as a function of current density of the LEDs with 12-nm and 9-nm last barriers.

Fig. 29. Radiative recombination rates of the LEDs with 12-nm and 9-nm last barriers at 55 A/cm2.

1. The radiative recombination rates in the QWs next to the n-side layers greatly enhances when the last barrier is 9 nm because more holes can transport to the QWs.

2. At high current density, the IQE of the LED with 9-nm last barrier is improved sufficiently due to higher hole injection efficiency and more uniform hole distribution.

Page 38: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

38

Study 8: Thin last barrier

0

100

200

300

400

500

600

0

1

2

3

4

5

6

7

8

0 20 40 60 80 100

Last barrier = 12 nmLast barrier = 9.6 nm

Current density (A/cm2)

Pow

er (

a.u.

)

Vol

tage

(V

)

Fig. 31. (experimental data) Optical power and forward voltage as a function of current density for InGaN LED with the last barrier thicknesses of 12 nm and 9.6 nm.

The experimental results show that, when the thickness of the last barrier decreases from 12 to 9.6 nm, the optical power is markedly enhanced, especially at high current density.

Page 39: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

39

Some specific designs on band structure near the active region,

including the modifications of barrier material or thickness, th

e redesigns of the electron blocking layer (EBL), etc., in the bl

ue InGaN LEDs are investigated numerically with the APSY

S simulation program. Simulation results show that, with ap

propriate designs, the efficiency droop may be effectively i

mproved due to the increase of hole injection efficiency, en

hancement of blocking capability for electrons, or uniform

distribution of carriers in the active region. The methods pr

oposed in this paper are advantageous especially for high curr

ent injection.

Conclusion

Page 40: 1 Numerical study on efficiency droop of blue InGaN light-emitting diodes Yen-Kuang Kuo*, Jih-Yuan Chang, and Jen-De Chen Department of Physics, National

Thank you for your attention !!