Contents...Further, name of the company has been changed from Nector Crop Sciences Private Limitedto Nichino Chemical India Limited withPrivate effect from 16-12-2017 (Annexure-M/s

i

Contents

S. No. Description Page No.

1.0 Executive Summary 1

1.1 Salient Features of the Project 2

2.0 Introduction 4 2.1 Identification of the Project and project proponent 4 2.2 Brief description of Nature of the Project 5

2.3 Need for the Project and its importance to the country and or region

6

2.4 Demand and Supply Gap 7

2.5 Imports Vs. Indigenous production, Export Possibility, Domestic/Export Markets

7

2.6 Employment Generation 7

3.0 Project Description 7

3.1 Type of the project including interlinked and interdependent projects, if any 7

3.2 Location 8 3.3 Alternate sites 8 3.4 Size or magnitude of operation 8 3.5 Project description 12 3.6 Raw materials 13 3.7 Resources optimization / recycling and reuse 13 3.8 Availability of water and Energy 14

3.9 Quantity of Wastes Generation and their Management / Disposal

14

3.9.1 Water requirement and Wastewater generation and their Management / Disposal

14

3.9.2 Hazardous / Solid Waste Generation, Handling and their Disposal

16

3.10 Schematic flow sheet for EIA procedure 18

4.0 Site Analysis 18

4.1 Connectivity 18 4.2 Land Form, Land use and Land ownership 18 4.3 Topography 18 4.4 Existing Land use pattern 18 4.5 Existing Infrastructure 19 4.6 Soil Classification 19

ii

S. No. Description Page No.

4.7 Climate data from Secondary sources 19 4.8 Social Infrastructure 20

5.0 Planning 20 5.1 Planning Concept 20 5.2 Population Projection 20 5.3 Land use planning 20 5.4 Assessment of Infrastructure Demand 21 5.5 Amenities/Facilities 21

6.0 Proposed Infrastructure 21 6.1 Industrial Area 21 6.2 Residential Area 21 6.3 Green Belt 21 6.4 Social Infrastructure 22 6.5 Connectivity 22 6.6 Drinking Water management 22 6.7 Sewerage System 22 6.8 Industrial Waste Management 22 6.8.1 Process Emissions Management 22 6.8.2 Fugitive emissions 23 6.8.3 Emissions–Utilities 23 6.8.4 Noise Environment 24 6.9 Hazardous / Solid Waste Management 25 6.10 Power Requirement & Supply / Source 25

7.0 Rehabilitation and Resettlement (R&R) Plan 25 8.0 Project Schedule & Cost Estimates 25

8.1 Time Schedule for the project construction 25 8.2 Estimated project cost 25

9.0 Analysis of proposal (Final Recommendations) 25 9.1 Budgetary allocation for Pollution Control Measures 26

iii

List of Tables

Table Title Page

1 Coordinates of all Corners of the Project Site 8

2A Permitted Products and their Capacities as per EC-2012 9

2B Permitted products and their capacities as per CFE - 2014 9

3A Proposed Products, their Capacity and End use 9

3B Products Permitted, proposed and total after expansion with its status 11

4 Existing Water Requirement, Wastewater Generation and its Treatment

15

5 Proposed Water Requirement and Waste water Generation with Segregation 15

6 Effluent Treatment Flow as per segregation 16

7 Hazardous Waste Generation from the Existing (CFO) Products 17

8 Hazardous / Solid Waste Generation from the Proposed Products 17

9 Environmental Components Shortest distance from Project Periphery 19

10 Land Break-up details 21

11 Maximum quantity of process Emissions from Existing Products

22

12 Maximum Quantity of Process emission from Proposed Products 23

13 Stack Emission Details – Proposed 24

14 Budgetary allocation for pollution Control Measures 26

iv

LIST of Annexures

Annexure No.

Title Page

I EC vide order F.no. J-11011/132/2010-IA-II (I) dated 20-07-2012 27

II CFE from KSPCB vide order no. KSPCB/HPI/189/Hyd-Chemicals/2012-13/571 dated 17-08-2012 34

III CFO vide No. KSPCB/189/Hyd-Chemicals/ 2012-13/09 dated 02-04-2013 46

IV CFE – CPM from KSPCB vide order no. PCB//189/HPI/2014-15/718 dated 09-09-2014 57

V Latest CFO vide No. AW-30313, PCB ID: 29166 dated 19-07-2017 and valid till 30-06-2021 62

VI Latest Hazardous waste authorization vide order no. PCB/HWM/ SEO/H.D. Reg.No.77665/2014-15 dated 27-8-2014 valid upto 30-06-2019

67

VII RoC of Nector Crop Sciences Private Limited 70

VIII RoC of Nichino Chemical India Private Limited 71

IX MoEF&CC Acknowledgement on submission Name Change application 72

X CA Certificate 73 XI General location of the Proposed Project 74 XII Specific Location of the Proposed Project 75 XIII Google map showing the coordinates 76 XIV Plant Layout 77 XV Typical process description & Flowchart for proposed products 78 XVI Raw Materials of Proposed products 128 XVII Hazardous Raw Materials 151 XVIII Ground water analysis report 152 XIX ETP Flow Scheme 153 XX Schematic Flow Sheet for EIA Procedure 154 XXI Topomap of 10km radius 156 XXII Soil analysis report 157

M/s Nichino Chemical India Pvt. Ltd. Pre-Feasibility Report

1

Pre-Feasibility Report for Expansion of Pesticide technical, its intermediates,

Bio Pesticides & Pesticides Formulations with R&D Facility 1.0 Executive Summary

M/s. Nichino Chemical India Pvt. Limited (Formerly known as Hyderabad Chemical Products

Limited) proposes to expand its Pesticide Technical Manufacturing and Formulation Unit to Pesticide

technical, its intermediates, Bio Pesticides & Pesticides Formulations with R&D products

manufacturing unit in the existing plant premises of 5.46 Ha i.e. 54634.5 sq.m (13.5 acres). The Unit

is located in Plot nos. 50, 82P, 83 and 84P of Karnataka Industrial Area Development Board (KIADB)

Industrial Area, Humnabad Taluk, Bidar district, Karnataka.

Background:

Industry granted Environmental Clearance (EC) by MoEF vide F.No. J-11011/132/2010-IA-II (I) dated

20-07-2012 in favor of M/s Hyderabad Chemical Products Limited (Annexure-I) for 4 pesticide and

formulation products with a production capacity of 1900 TPA wherein it is stated that Public Hearing

was exempted as per section 7(i), (iii) Stage (3), Para (i) (b) of EIA Notification, 2006. Industry was

established in the year 2012 and granted CFE by Karnataka State Pollution Control Board (KSPCB)

vide KSPCB/HPI/189/Hyd-Chemicals/2012-13/571 dated 17-08-2012 (Annexure-II) The combined

(water & Air) consent for operation as per EC granted in favor of M/s Hyderabad Chemical Products

Limited vide KSPCB/189/Hyd-Chemicals/ 2012-13/09 dated 02-04-2013 for 4 pesticide products with

a production capacity of 1900 MTPA (Annexure-III). Subsequently, consent for establishment for

expansion was granted in favor of M/s Hyderabad Chemical Products limited for 13 products mix for

manufacture of pesticide technical and formulations using existing plant and machinery by reducing

existing production capacity of 3 products and retaining one product capacity along with addition of 9

new products with a total production capacity of 1900 TPA by PCB//189/HPI/2014-15/718 dated 09-

09-2014 (Annexure-IV).

Industry granted regular renewals for consent for operation of the plant from time to time. The Latest

combined Consent for the Operation (CFO) granted in favor of M/s Nector Crop Sciences Pvt. Limited

by KSPCB vide AW-30313, PCB ID: 29166 dated 19-07-2017 and valid till 30-06-2021 (Annexure-V). Latest Hazardous waste authorization vide order no. PCB/HWM/SEO/H.D. Reg.No.77665/2014-

15 dated 27-8-2014 in the name of Hyderabad Chemical Product Limited valid upto 30-06-2019

(Annexure-VI).

The Nector Crop Sciences Limited which was originally incorporated on 05-12-2013 and

subsequently converted to Nector Crop Sciences Private Limited has been incorporated on 25-03-

2015 (Annexure-VII). Further, name of the company has been changed from Nector Crop Sciences

Private Limited to Nichino Chemical India Private Limited with effect from 16-12-2017 (Annexure-


2

The expansion proposal is to grant Environmental Clearance (EC) by the Ministry of Environment,

Forests and Climate Change (MoEF&CC) to manufacture 9 campaign products at a time out of 48

products, Bio pesticides, R&D products with a production capacity of 6251.8 TPA from existing

production capacity of 1900 TPA with additional investment of Rs.75.42 Crores, the existing

investment is Rs. 51.47 Crores and total investment after expansion will be Rs.126.89 Crores

(Annexure-X).

The proposed expansion of Pesticide Technical Grade, its intermediates, Bio pesticides, R&D

products manufacturing and formulation unit falls under Category 'A' project under 5 (b) of EIA

Notification 2006 and will be appraised by the sector specific expert appraisal committee (EAC) of the

Ministry of Environment, Forest and Climate Change, Govt. of India, New Delhi.

1.1 Salient Features of the Project

• Proposing expansion in the existing pesticides manufacturing & formulation unit premises land

area of 5.46 Ha. Total Greenbelt area is 1.87 Ha (34.4%) of 5.46 Ha.

• This proposed project site is located at an aerial distance of:

i. National Highway-65 : Machilipatnam-Hyderabad-Pune (old NH-9)-1.4 km (N)

ii. NH-218: Bidar to Hospet-0.6 km (W)

iii. Nearest town: Humnabad-2.3 km (NE)

iv. Bidar District: 42 km (NE)

v. Humnabad Railway Station-4.7 km (ENE)

vi. Kalaburag Airport-52 km (SSW)

vii. Rajiv Gandhi International Airport, Hyderabad -153 km (E)

viii. Nearest Village: Ganwanti-2 km (N)

• Total cost of the expansion is Rs.126.89 Crores including existing investment of Rs. 51.47

Crores. Total capital cost allocated towards environmental pollution control measures is Rs.

8.59 Crores including existing investment of Rs. 3.44 Crores. Recurring cost will be about Rs.

9.48 Crores per annum.

• The proposed power requirement of the plant is 1350 KVA (CMD) including existing 900 KVA

(CMD). Power will be met from Karnataka State Power Distribution Corporation Limited.

• Total water requirement will be about 527 KLD of which fresh water requirement will be

367 KLD. Treated effluent of 162 KLD from ETP will be reused in cooling tower makeup. Fresh

water will be met from bore wells & private tankers

• Diesel of about 300 lit/hr will be used in the proposed DG sets of 625 KVA, in addition to

existing 625 KVA & 250 KVA DG sets. DG sets are used as standby during power failure.


3

• About 60 TPD of coal will be used in the proposed 2 nos of 5 TPH coal / Bio fuel fired boilers

along with existing 3 & 2 TPH coal fired boilers.

• Existing Incinerator of 75 kg/hr will be dismantled, as it is not required to operate, due to

discontinuation of Monocrotophos Technical production.

• About 397 employees including existing 197 employees will be benefitted due to the proposed

project. Out of which direct 187 and indirect 210 employees.

• Industry will provide dual scrubbers based on the characteristics of process emissions. Multi-

cyclone separator & bag filter will be provided to Boilers to reduce the particulate emissions into

atmosphere.

• Wastewater generated from the plant will be about 178 KLD from process, washing, utilities,

Fresh water RO rejects, scrubber, Q.C, R&D and domestic wastewater.

• Effluent will be pumped to the above ground level RCC lined tanks for storage and

neutralization then sent to upgraded ETP-ZLD of 200 KLD capacity within the premises.

• Domestic wastewater will be sent to ETP - ZLD.

• Hazardous waste will be segregated and collected in the HDPE drums / bags as appropriate

and will be stored in the covered and raised platform with provision of leachate collection

system.

• Solid waste like boiler ash will be sent to cement brick manufacturers.

• Existing solvent recovery system consists of 3x125 lph and 250 lph distillation columns. Industry

will upgrade the existing solvent recovery system for recovery of solvents from the process by

addition of 3 nos. as required. Primary and secondary condensers will continue to be provided

with cooling water and chilled brine circulation for effective recovery of solvents thereby

reducing the solvent emissions.

• Compressors, Boilers and DG sets will be the major noise generating units in the plant. Out of

these, the generator will be functioning at the time of power failure only. Built-in acoustic

enclosures provided for DG sets unit to minimize the noise levels. However, the workers in this

area will be provided with ear muffs.

Industry has prepared Form-I application along with draft Terms of Reference (ToR) in the process of

granting ToR for preparation of EIA, in line with issue of Environmental Clearance. Hence, pre-

feasibility report highlighting the expansion project and the various operations including waste

generation and mitigation measures are prepared & submitted to the Expert Appraisal Committee

(EAC) for its consideration and appraisal.


4

2.0 Introduction

2.1 Identification of the Project and Project Proponent

The present unit was established in 2012 in the name of M/s. Hyderabad Chemical Products

Limited was granted Environmental Clearance (EC) by the Ministry of Environment and Forests

(MoEF), New Delhi in 2012 for production quantity of 1900 TPA vide F.No. J-11011/132/2010-IA-II (I)

dated 20-07-2012. Industry proposes expansion of Pesticides Technical, its intermediates, Bio

pesticide, Formulation and R&D products manufacturing unit with the production quantity of

6251.8TPA in the land extent of 5.46 Ha at Plot nos. 50, 82P, 83 and 84P, Karnataka Industrial Area

Development Board (KIADB) Industrial Area, Humnabad, Bidar district, Karnataka.

• Industry was established in the year 2012 and granted CFE by Karnataka State Pollution

Control Board (KSPCB) vide KSPCB/HPI/189/ Hyd-chemical /2012-13/571 dated 17-08-2012

(Annexure-II). The combined (water & Air) consent for operation as per EC granted in favor of

M/s. Hyderabad Chemical Products limited vide KSPCB/189/Hyd-Chemicals/2012-13/09

dated 02-04-2013 for 4 pesticide products with a production capacity of 1900 MTPA.

Subsequently, consent for establishment for expansion was granted in favor of M/s

Hyderabad Chemical Products limited for 13 products mix for manufacture of pesticide

technical and formulations using existing plant and machinery by reducing existing production

capacity of 3 products and retaining one product capacity along with addition of 9 new

products with a total production capacity of 1900 TPA by PCB//189/HPI/2014-15/718 dated

09-09-2014.

• Management have changed the Name of the company from M/s. Hyderabad Chemical

Products Limited to M/s. Nectar Crop Sciences Limited in 2014 and Nectar Crop Sciences

Private Limited in 2015 and to M/s. Nichino Chemical India Private Limited in December 2017

located at Plot No. 50, 82 83 and 84, KIADB Industrial Area, Humnabad, Bidar District,

Karnataka State in confirmation of the Board of Directors.

• Industry granted regular renewals for consent for operation of the plant from time to time. The

Latest combined Consent for Operation (CFO) granted in favor of M/s Nector Crop Sciences

Pvt. Limited by KSPCB vide AW-30313, PCB ID: 29166 dated 19-07-2017 and valid till 30-06-

2021.

• Latest Hazardous waste authorization vide order no. PCB/HWM/SEO/H.D.

Reg.No.77665/2014-15 dated 27-08-2014 in the name of Hyderabad Chemical Product

Limited valid upto 30-06-2019.

Project Proponent

Since its inception in 1954, established by Dr. Ramesh Gandhi for over 4 Decades Nichino India

(formerly Hyderabad Chemicals Limited) have been working for well-being of Farmers in India.

Nichino is one of the leading Manufacturer of Technical Grade Pesticides in India. Which engaged in


5

Agro Farm Industry to increase Agro farm Productivity, Profitability and to develop sustainable

agriculture by offering various innovative and Customer / Crop focused products by maintaining

international quality standards at affordable prices.

Nichino India has a broad portfolio of agrochemicals including insecticides, herbicides, fungicides &

growth promoters. The Crop Protection Products help farmers to prevent crop losses from the effects

of weeds, pests & diseases thereby enhancing production of food, fiber and feed. The Plants are

operated by well qualified and experienced senior professionals, Engineers and others who are well

versed with Plant Operations. Having in-built flexibility of plant and machinery is able to produce and

distribute new products in a short time.

Mr. Hideii. Hosoda- (CMD): He was nominated as Chairman & Managing Director by Nihon Nohyaku

Co., Ltd. He holds a Master Degree in Science. He has joined the parent company Nihon Nohyaku

Co., Ltd in the year 1979 and is having over 35 years of experience in the fields of Agrochemical

Regulatory, Product Development and Sales and Marketing.

Mr. Mitsuhiro Kishida - (Director): He was nominated as Director by Nihon Nohyaku Co., Ltd. He is

holding Masters in Agricultural Science. He joined Nihon Nohyaku Co., Ltd in the year 1985 and has

over 30 years of experience in the fields of Chemical, Product Development and Sales and

Marketing.

Mr. N. Sukumar- (Director): He inducted into the Board of Directors in September 1988.he is

renowned for his business acumen, innovative thinking and he has been instrumental in propelling

the Nichino India (HCL) group forward into several core industrial sectors and in the emerging of

Nichino India (HCL) group as an enterprise with commitment to society and in expanding into the

international markets and built strong relationships with powerful distributors. He plays an active role

in Crop Care Federation of India (CCFI) as a Director.

Mr. Mahendra Uday Bhalerao- (Executive Director): He holds a graduation Degree in Engineering

from Osmania University. He is having over 26 years of rich experience in Chemical &

Pharmaceutical Industry. Over 11 years association with the Nichino India (HCL) as Technical

Consultant for Synthetic Chemistry, Process Development, and Engineering. Mr. Mahendra Uday

Bhalerao was nominated as Executive Director by Nihon Nohyaku Co., Ltd. On 16th May, 2017.

2.2 Brief Description of the Nature of the Project

This is an expansion of existing Pesticides technical and formulations manufacturing unit to

Pesticide technical, its intermediates, Bio Pesticides & Pesticides Formulations with R&D facility. The


6

products manufactured are used as insecticide, fungicide, herbicide, pesticide, etc., which are

applicable for agricultural activity.

The manufacturing process of Pesticides consists of chemical synthesis and multiple stage of

processing extending to maximum of 4 stages involving different types of chemical reactions. The

entire process operations are operated by various technical, skilled and unskilled persons with due

care to be met various standards prescribed by authorities.

Technology for manufacturing the products listed under proposed expansion is available from

in-house R&D & private consultants and proposes to adopt new technologies and techniques that are

continuously refined in every stage of manufacturing to meet global standards. Industry will adopt the

state of art technologies and dedicated team of environmental professionals for treatment and

recycling of effluents, operation and monitoring of all pollution control equipment. Industry has a

defined EHS policy and robust environmental management system supported by a well-defined

organizational structure to ensure the prevention of pollution and to protect the environment.

2.3 Need for the Project and its Importance to the Country and or Region

Pesticides have been recognized as an essential tool in India to increase agricultural

production by preventing crop losses before and after harvesting. Pesticides comprise of a large

group of chemicals that are used in agriculture to control plants and animals infestation. Pesticides,

being the last input in agricultural operation, are used for preventing the destruction of crops from

pests like insects, weeds, etc., thereby increasing the agricultural production. On the production front,

pesticides are first manufactured as technical grade product (85% or more of the active chemical

ingredients), which has a higher commercial purity. The active ingredients are then mixed with inert

ingredients (solvents, adjuvant and fillers) to achieve the desired formulation. The active ingredient

kills the pest whereas the inert ingredient facilitates ease of handling, spraying and coating on plants.

In India, the pesticides are broadly divided into five types and in the market share Insecticides

cover the major part i.e. 60% of the market share, whereas Fungicides 18%, Herbicides 16% and the

rest 6% by others. Bio-pesticides are an emerging category and are currently a small proportion of

the market but have a huge growth potential considering its non-toxic nature.

Currently, India is the fourth largest global producer of pesticides with an estimated market

size of around $4.9 billion in FY-2017 after United States, Japan and China. The Indian pesticide

industry is predominated with generic version products and has a substantial opportunity to explore

the drugs going off-patent during FY2017-2020 and through acquisitions and strategic partnerships of

global giants with domestic players.

www.careratings.com : Outlook of Indian Pesticide Industry

India being, an Agriculture based Economy it has become one of the strategically important

countries for Agro related Businesses, In Purview of this on March 11th 2015, a Japanese Company

Nihon Nohyaku Co. Ltd., had acquired the stakes of Hyderabad Chemicals Pvt. Ltd., Which now

http://www.careratings.com/


7

transformed into commencement of the manufacturing and sales of their proprietary active

ingredients in India, and the sales of finished products in the country through “Nichino India”.

2.4 Demand and Supply Gap

The Indian pesticides industry is characterized by low capacity utilization. The total installed

capacity in 2011 is 146,000 tonnes and has a low capacity utilization of <60%. The industry suffers

from high inventory owing to seasonal and irregular demand on account of monsoons. The

consumption of pesticides in India is low in comparison to other countries. There is a marked

difference in the consumption pattern of pesticides in India vis-à-vis the rest of the world. Insecticides

account for 76% of the total domestic market. On the other hand, herbicides and fungicides have a

significantly higher share in the global market. Crops like cotton, wheat and rice together account for

70% of total agrochemical consumption.

2.5 Imports vs. Indigenous production, Export Possibility, Domestic/Export Markets

The Indian crop protection industry was estimated to be USD 4.25 billion in FY14 and is

expected to grow at a CAGR of 12% to reach USD 7.5 billion by FY19. Exports currently constitute

almost 50% of Indian crop protection industry and are expected to grow at a CAGR of 16% to reach

USD 4.2 billion by FY19, resulting in 60% share in Indian crop protection industry. Domestic market

on the other hand would grow at 8% CAGR, as it is predominantly monsoon dependent, to reach

USD 3.3 billion by FY19. Globally, India is fourth largest producer of crop protection chemicals, after

United States, Japan and China. The crop protection companies in India can be categorized into

three types –Multi-National, Indian including public sector companies and small sector units.

Source: A Report on Indian Agrochemical Industry

2.6 Employment Generation

The expansion facility will generate direct and indirect employment. At present the company

has over 197 employees. About 397 employees including existing 197 employees will be benefitted

due to the proposed project, in that 187 nos. direct employment and 210 nos. of indirect employment.

3.0 Project Description

3.1 Type of the project including interlinked and interdependent projects, if any:

The proposed expansion of Pesticide technical, its intermediates, Bio Pesticides & Pesticides

Formulations with R&D products manufacturing unit falls under Category 'A' project under 5 (b) of EIA

Notification 2006 and its subsequent amendments. The proposed unit is located in KIADB Industrial

area, Humnabad, Bidar District, Karnataka. There is no interlink and interdependent project for this

expansion project.


8

3.2 Location

The Unit is located in Plot nos. 50, 82P, 83 and 84P, KIADB Industrial Area, Humnabad Taluk,

Bidar district, Karnataka. Project site co-ordinates of all corners are presented in Table 1. The project

site is well connected by the State High Way.

Table 1: Co-ordinates of all corners of the Project site

Sl. No. Latitude Longitude Sl. No. Latitude Longitude 1 17°45'24"N 77° 5'39"E 5 17°45'28"N 77° 5'54"E 2 17°45'28"N 77° 5'44"E 6 17°45'21"N 77° 5'47"E 3 17°45'25"N 77° 5'48"E 7 17°45'17"N 77° 5'46"E 4 17°45'29"N 77° 5'53"E 8 17°45'19"N 77° 5'44"E

The map showing general location, specific location, Google map showing the Co-ordinates

and Plant layout of the project showing existing and proposed facilities are presented at Annexures- XI, XII, XIII and XIV respectively.

3.3 Alternate Sites

This proposed expansion project is in the existing plant premises in KIADB Industrial Area,

Humnabad Taluk, Bidar district, Karnataka. Hence, Alternate sites are not considered for the present

expansion project.

Environmental considerations of this expansion project site.

• 2.3 km away from human habitation i.e. Humnabad-2.3 km (NE)

• Water Bodies

a) Pond Near Dhumansur Tanda at 6.1 km (NE)

b) Pond Near Hallikhed at 7.6 km (S)

c) Mullamari Reservoir at 9.1 km (SW)

d) Chandri Halla at 2 Km (N)

• Reserved forests:

RF near Kallur Tanda (open scrub)-3.1 km (S)

RF near Pandaragera (Dense scrub)-5.8 km (SW)

• Exist Transportation and Communication network

• There are no rare or endangered or endemic or threatened (REET) species of animals or birds.

3.4 Size or Magnitude of Operation Project Area: 5.46 Ha.

Production Capacity: 6251.8TPA from Pesticide Technical products & Bio pesticides along

with R&D products (permitted production capacity: 1900 TPA). The permitted (EC, CFO) and

proposed products with its production capacities are presented in Tables 2A, 2B & 3A respectively.


9

Table 2A: Permitted Products and their Capacities as per EC-2012

Sl. No. Name of the product Quantity

(MTPA) 1. Cartap Hydrochloride technical 1000 2. Indoxacarb technical 50 3. Acephate technical 250 4. Monochrotophos technical 600

Total Production Quantity 1900

Table 2B: Permitted Products and their Capacities as per CFE-2014

Sl. No. Name of the product

Consented Capacity

(TPA)

Additional Capacity

(TPA) 1. Profenofos -- 150 2. Imidachlopride -- 50 3. Acetamipride -- 30 4. Buprofugin -- 50 5. Fipronil -- 25 6. Chloropyrofos -- 100 7 Dichlorvos -- 100 8. Tricyclazole -- 50 9 Chlodinofop -- 25

Revises (Reduced) Capacity TPA 10. Cartap Hydrochloride technical 1000 800 11. Indoxacarb technical 50 50 12. Acephate technical 250 220 13 Monochrotophos technical 600 250

Total 1900 1900

Table 3A: Proposed Products, their Capacity and End Use Sl. No. Products Quantity

kg/day Quantity

(TPA) CAS No. End Use

1. Acephate 66.67 24 30560-19-1 Insecticide 2. Acetamiprid 166.67 60 160430-64-8 Insecticide 3. Azoxystrobin 100 36 131860-33-8 Fungicide

4 5-Amino-3-cyano-1-(2,6-dichloro-4-trifluoromethyl phenyl)pyrazole (Phenyl Pyrazole)

333.33 120 120068-79-3 Intermediate

5 Benzpyrimoxan (NNI-1501) 666.67 240 1449021-97-9 Insecticide 6 Bifenthrin 166.67 60 82657-04-3 Insecticide 7 Bispyribac sodium 33.33 12 125401-92-5 Herbicide 8 Bufrofezin 666.67 240 69327-76-0 Insecticide 9 Cartap Hydrochloride 50 18 15263-52-2 Insecticide

10 Chloropyrifos 66.67 24 2921-88-2 Pesticide 11 Clodinafop Propargyl 83.33 30 105512-06-9 Herbicide 12 Cloquintocet Mexyl 250 90 99607-70-2 Herbicide

13 (R)-(+)-2-(4-Hydroxyphenoxy) Propionic acid (DHPPA) 166.67 60 94050-90-5 Intermediate

14 Diafenthiuron 1000 360 80060-09-9 Insecticide


10

Sl. No. Products Quantity

kg/day Quantity

(TPA) CAS No. End Use

15 Ethiprole 166.67 60 181587-01-9 Insecticide 16 Fenoxanil 166.67 60 115852-48-7 Fungicide 17 Fenpyroximate 333.33 120 134098-61-6 Insecticide 18 Fipronil 500 180 120068-37-3 Insecticide 19 Flubendiamide 333.33 120 272451-65-7 Pesticide 20 Flutolanil 1333.33 480 66332-96-5 Fungicide 21 Imidacloprid 2000 720 138261-41-3 Insecticide 22 Indoxacarb 100 36 144171-61-9 Insecticide 23 Isoprothiolane 3333.33 1200 50512-35-1 Fungicide 24 Meta isopropoxy aniline [MIPA] 3000 1080 41406-00-2 Intermediate 25 Metaflumizone 33.33 12 139968-49-3 Insecticide 26 Orthosulfamuron 66.67 24 213464-77-8 Herbicide 27 Profenofos 166.67 60 41198-08-7 Insecticide 28 Pyflubumide 50 18 926914-55-8 Insecticide 29 Pymetrozine 333.33 120 123312-89-0 Insecticide 30 Pyraflufen-ethyl 66.67 24 129630-19-9 Herbicide 31 Pyrafluprole 66.67 24 315208-17-4 Insecticide 32 Pyrifluquinazon 66.67 24 337458-27-2 Insecticide 33 Pyriprole 33.33 12 394730-71-3 Insecticide 34 Quizalofop ethyl 33.33 12 76578-14-8 Herbicide 35 Sodium Trifluoromethane Sulfinate 500 180 2926-29-6 Intermediate 36 Tebufenpyrad 66.67 24 119168-77-3 Insecticide 37 Thiodicarb 722.34 260 59669-26-0 Insecticide 38 Tiadinil 666.67 240 223580-51-6 Fungicide 39 Tolfenpyrad 100 36 129558-76-5 Insecticide 40 Tricyclazole 1166.67 420 41814-78-2 Fungicide 41 Chlorantraniliprole 166.67 60 500008-45-7 Insecticide 42 Dimethoate 33.33 12 60-51-5 Insecticide 43 Ethion 33.33 12 563-12-2 Insecticide 44 Hexaconazole 33.33 12 79983-71-4 Fungicide 45 Penoxsulam 66.67 24 219714-96-2 Herbicide 46 Pretilachlor 333.33 120 51218-49-6 Herbicide 47 Sulfosulfuron 33.33 12 141776-32-1 Herbicide 48 Thiamethoxam 333.33 120 153719-23-4 Insecticide

Total 9 products to be manufactured from the total 48 products 13889.01 5000

Bio-Pesticides 1 Bio Pesticides 3472.2 1250

R & D Products 1 R&D Products 5 1.8

Total Production 9 campaign Pesticides Technical products, Bio-Pesticide products & R&D products

17366.21 6251.8

Source: Nichino Chemical India Pvt. Ltd.


11

List of By-Products

Sl. No

Name of the By-Product

Quantity Kg/day

Quantity (TPA) Name of the Product

1 Ammonium Sulphate 29.48 10.6 Acephate 2 Acetic acid 26.8 9.6 3 Potassium Bisulphate 50 18.0 Azoxystrobin

4 Potassium Chloride 891.91 321

Azoxystrobin, Bifenthrin, Cloquintocet Mexyl, Fenpyroximate, Imidacloprid, Quizalofop Ethyl, Thiamethoxam,

5 Hydrogen Chloride 592.15 213.2 Benzpyrimoxan 6 Phosphoric acid 794.95 286.2 Benzpyrimoxan 7 Ammonia 48 17.3 Diafenthiuron

8 Potassium Bromide 2804.68 1009.7 Fenpyroximate, Metaisopropoxy Aniline

9 Trimethylamine Bromoethane 82.3 29.6 Profenofos

10 Potassium bicarbonate 944.55 340 Imidacloprid, Quizalofop Ethyl, Thiamethoxam

11 Sodium Bromide 17.82 6.4 Ethion Source: Nichino Chemical India Pvt. Ltd.,

Table 3B: Products Permitted, Proposed and Total After expansion with its Status

Sl. No. Products Permitted

(TPA)

Proposed / Additional / (Reduced)

(TPA)

Total After Expansion

(TPA) Status after Expansion

1 Acephate 220 (-196) 24 Reduced 2 Acetamiprid 30 30 60 Increased 3 Azoxystrobin -- 36 36 New

4

5-Amino-3-cyano-1-(2,6-dichloro-4-trifluoromethyl phenyl)pyrazole (Phenyl Pyrazole)

-- 120 120 New

5 Benzpyrimoxan (NNI-1501) -- 240 240 New 6 Bifenthrin -- 60 60 New 7 Bispyribac sodium -- 12 12 New 8 Bufrofezin 50 190 240 Increased 9 Cartap Hydrochloride 800 (-782) 18 Reduced 10 Chloropyrifos 100 (-76) 24 Reduced 11 Clodinafop Propargyl 25 5 30 Increased 12 Cloquintocet Mexyl -- 90 90 New

13 (R)-(+)-2-(4-Hydroxyphenoxy) Propionic acid (DHPPA) -- 60 60 New

14 Diafenthiuron -- 360 360 New 15 Ethiprole -- 60 60 New 16 Fenoxanil -- 60 60 New


12

Sl. No. Products Permitted

(TPA)

Proposed / Additional / (Reduced)

(TPA)

Total After Expansion

(TPA) Status after Expansion

17 Fenpyroximate -- 120 120 New 18 Fipronil 25 155 180 Increased 19 Flubendiamide -- 120 120 New 20 Flutolanil -- 480 480 New 21 Imidacloprid 50 670 720 Increased 22 Indoxacarb 50 (-14) 36 Reduced 23 Isoprothiolane -- 1200 1200 New

24 Meta isopropoxy aniline [MIPA] -- 1080 1080 New

25 Metaflumizone -- 12 12 New 26 Orthosulfamuron -- 24 24 New 27 Profenofos 150 (-90) 60 Reduced 28 Pyflubumide -- 18 18 New 29 Pymetrozine -- 120 120 New 30 Pyraflufen-ethyl -- 24 24 New 31 Pyrafluprole -- 24 24 New 32 Pyrifluquinazon -- 24 24 New 33 Pyriprole -- 12 12 New 34 Quizalofop ethyl -- 12 12 New

35 Sodium Trifluoromethane Sulfinate

-- 180 180 New

36 Tebufenpyrad -- 24 24 New 37 Thiodicarb -- 260 260 New 38 Tiadinil -- 240 240 New 39 Tolfenpyrad -- 36 36 New 40 Tricyclazole 50 370 420 Increased 41 Chlorantraniliprole -- 60 60 New 42 Dimethoate -- 12 12 New 43 Ethion -- 12 12 New 44 Hexaconazole -- 12 12 New 45 Penoxsulam -- 24 24 New 46 Pretilachlor -- 120 120 New 47 Sulfosulfuron -- 12 12 New 48 Thiamethoxam -- 120 120 New 49 Dichlorvos 100 - -- Dropped

50 Monochrotophos technical

250 - -- Dropped

3.5 Project Description

The manufacturing process of Pesticides consists of chemical synthesis and multiple stages

of processing extending to maximum of 4 stages involving different types of chemical reactions.


13

Process description with flow chart details for all 48 products and Typical Bio-Pesticide product are

enclosed at Annexure-XV. These pesticides & Biopesicides are mainly used in agricultural

production by preventing crop losses before and after harvesting. Industry will implement the proven

technologies in the R&D for the cost effective & environment friendly practices. The plant layout

showing existing and proposed components of the project is enclosed at Annexure-XIV.

3.6 Raw Materials

The raw materials required for the manufacture of proposed products are the

chemicals/solvents and the fuel. The chemicals required for the process are mostly secured from the

local (indigenous) markets. Some of these raw materials will be imported from various countries.

Mode of transportation of all raw materials and finished products from the project site is by road to

local markets and by road / rail / sea if exported.

• The Pesticides manufacturing involve the use of various chemicals and organic solvents either

directly as reactant or for extraction of a product of interest from the reaction mixture.

• About 60 TPD of coal will be used in the proposed 2 nos. of 5 TPH coal / bio fuel fired boilers

along with existing 3 and 2 TPH coal fired boilers.

• Diesel of about 300 lit/hr will be used in the proposed DG sets of 625 KVA, in addition to

existing 625 KVA & 250 KVA DG sets. DG sets are used as standby during power failure.

• The proposed power requirement of the plant is 1350 KVA (CMD) including existing 900 KVA

(CMD). Power will be met from Karnataka State Power Distribution Corporation Limited.

• The chemicals (raw materials) required for the manufacture of proposed products is presented

at Annexure -XVI and Hazardous chemicals list is presented at Annexure-XVII.

3.7 Resources Optimization / Recycling and Reuse

R&D facility in the unit is making all efforts to recycle the wastes / reuse wherever possible.

However, R&D is a continuous process, where improvements in the processes adopted by the

industry, waste minimization etc. will be worked out as the project progresses. Following are some of

the recycle options proposed by the Proponent.

Improvement of yield of the products so as to reduce the waste generation during

manufacturing.

Industry uses zero liquid discharge plant to reuse all treated effluents as makeup water for

utilities like Cooling Tower. This will reduce the fresh water consumption.

All solvents are recovered to the extent possible and reused in the process.

Organic residue, spent carbon, distillation residue will be sent to Authorized Cement Industries

to burn in Cement Kiln as an alternate fuel or TSDF in case of shut down of Cement

industries.

Boiler ash will be sent to Brick manufacturing units.


14

ETP sludge / Evaporation salts will be sent to TSDF or Authorized Cement Industries based

on the calorific value of the waste.

Container & container liners of hazardous chemicals, Polythene / HDPE Bags, broken plastic

drums will be disposed off to outside agencies after complete detoxification.

Spent catalyst will be sent back to suppliers

Waste Lead acid batteries will be sent back to suppliers on buy back basis.

Optimum utilization of solar energy.

There is tremendous potential for implementation of clean technologies, recovery and reuse

techniques in this proposed APIs unit which will be explored and implemented after R&D process.

3.8 Availability of Water and Energy

Fresh water requirement is about 367 KLD which will be met from bore wells and private

tankers. The proposal is to minimize the effect on the level of water table by practicing reuse /

recycling of the treated water wherever possible thereby reducing the fresh water requirement.

Characteristics of Ground water are enclosed at Annexure–XVIII.

The proposed power requirement (Contract Power Demand) of the plant is 1350 KVA

including existing 900 KVA and it is sourced from the Karnataka State Power Distribution Corporation

Limited. Coal and Diesel will be procured from the distribution sources closer to the project site.

3.9 Quantity of Wastes Generation and their Management /Disposal

3.9.1 Water requirement and Wastewater Generation and their Management / Disposal

The permitted water requirement and waste water generation with treatment is presented in

Table 4. The proposed gross water requirement after expansion will be 527 KLD of which total fresh

water requirement will be 367 KLD. Treated effluent from ETP-ZLD of about 162 KLD will be reused

in utilities. Fresh water will be met from bore wells and private tankers. Proposed Water Requirement

and Waste water Generation with Segregation is presented in Table 5. The sources of wastewater

generation are from the process, floor & reactor washings, utilities, Q.C, R&D, scrubber and plant

domestic waste. Total proposed wastewater will be 178 KLD, which will be segregated into

HTDS/HCOD & LTDS/LCOD and collected by gravity into a collection tank separately. This individual

effluent will be pumped to the above ground level RCC lined tanks for storage and neutralization then

sent to ETP-ZLD. The effluents segregated quantity, characteristics and treatment flow is briefly

presented in Table 6.


15

Table 4 : Existing Water Requirement, Wastewater Generation and its Treatment

(Water consumption & Effluent details for EC / CTE 2010-2012)

Sl. No. Description

Input (KLD)

Output (KLD)

Fresh Water

Evaporation loss /

(Generation) Total

Wastewater Treatment as per Consent Order

1. Process 7.6 (-1) 8.6

( HTDS: 5 KLD LTDS: 3.6 KLD )

Shall be treated and evaporated in MEE and condensate shall be treated in biological treatment plant to the standards (on land for irrigation) and treated effluents shall be used for cooling and gardening.

2. Washings (Reactors, floor washing, etc.)

6.4 -- 6.4 (LTDS)

3. Boiler & Cooling tower Make up 33 25 8

(LTDS) 4. Gardening 2 2 0

5. Domestic (Sewage) 2 -- 2

(LTDS)

Sewage shall be treated in septic tank with soak pit. No overflow from soak pit allowed.

Total 51 26 25

Table 5: Proposed Water Requirement and Waste water Generation with Segregation

Description Input (KLD) Output (KLD)

Fresh Water

Recycled Water

Evaporation / Handling

Loss Total

Wastewater Segregation type of

Wastewater

Process (9 products at a time) 91 -- (-5) 96

(105) HTDS/HCOD

Washings (reactor, centrifuges, nutch filters, dryers, floor, etc.,)

10 -- -- 10 LTDS/LCOD

Boiler (5, 5, 3 & 2 TPH boilers)

108 -- 96 12

(Blow down) Utilities (LTDS/LCOD)

(makeup) Cooling Tower 4200 TR 92 160 231 21

(Bleed) Fresh water RO rejects 10 -- -- 10 LTDS / LCOD

Scrubber 10 -- -- 10 HTDS / LCOD Q.C, R&D & formulation 3 -- -- 3 LTDS/LCOD

Domestic (397 nos @50 lpcd) 20 -- 4 16 LTDS/LCOD Greenbelt (4 acres @ 5KL/acre) 20 -- 20 -- -- Formulation 3 -- 3 --

Total

367 162 349 178 Stripper condensate 0.5 KLD; Moisture in salt & ETP sludge is 1 KLD, Water loss in ETP 16.5 KLD (Total water loss is 18 KLD = 10 %) Reuse: 162 KLD

527 527


16

Table 6: Effluent Treatment Flow as per Segregation

Effluent Characteristics

Quantity (KLD) Treatment Flow

Stream -1 (Process & scrubber)

TDS > 5000 mg/l COD > 5000 mg/l

106

Collection Equalization cum Neutralization Settling Holding Steam stripper MEE along with HTDS effluent Condensate to ETP (biological treatment) Concentrate to ATFD MEE & ATFD Condensate to ETP (Biological Treatment) along with domestic wastewater holding tank Pressure Sand Filter Activated Carbon Filter ETP RO system RO permeate water reuse in Cooling towers. ETP RO rejects to MEE. ATFD Salts to TSDF and stripped solvents to SPCB authorized cement industries

Stream- 2 (Washings, Utilities, QC, R&D, Formulation and

Domestic) TDS / COD < 5000 mg/l

62 Collection Equalization cum Neutralization ETP (Biological Treatment) along with MEE & ATFD Condensate

Stream 3 (Fresh water RO rejects) 10 Collection Tank ETP RO system

Existing treatment system will be enhanced to meet the proposed effluent quantities. All the

proposed additional tanks in the ETP will be constructed / installed above the ground with water proof

lining. These individual effluents will be pumped to the RCC lined tanks for storage and neutralization

and then sent to upgraded ETP-ZLD of 200 KLD capacity within the plant premises. Effluent

Treatment Plant flow chart is enclosed as Annexure-XIX.

ETP – ZLD facility consists of primary treatment (equalization and neutralization), thermal

treatment (stripper with MEE, ATFD), secondary treatment (biological) and tertiary treatment

(Pressure sand filter, Activated carbon filter & Reverse Osmosis) will be provided. Domestic

wastewater will be sent to ETP (biological treatment). Concentrate from MEE system will be sent to

ATFD and the salts from the evaporation system will be collected and sent to TSDF or Authorized

Cement industries for safe disposal based on calorific value of the waste.

3.9.2 Hazardous / Solid Waste Generation, Handling and their Disposal

Hazardous / Solid waste will be segregated, detoxified and collected in the HDPE drums /

bags and will be stored in the covered and raised platform with Leachate collection system. The

existing and proposed solid waste and other waste generated, handling and disposal method from

the various stages of Pesticides manufacturing plant is presented in the Tables 7 & 8 respectively. Spillages such as wastewater / solid wastes / raw materials are possible and the risk of this would be

limited to within the premises of the manufacturing facility. A precautionary measure like spillage

control management is practiced in the industry.


17

Table 7: Hazardous Waste Generation from the Existing (CFO) Products

Description Waste Category

Quantity Disposal method as per CFO

Used Oil 5.1 0.3 KL/A

Shall be collected in leak proof containers & disposed to KSPCB registered authorized re-processors provided the oil meets the standards as per Schedule-5 Part-A of the Rules.

Organic Residue 29.1 213 MT/A

Shall be stored in a secured manner and handed over to KSPCB authorized incinerator/ co-processing in cement kiln.

Discarded containers 33.3 1000 No’s/A Shall be stored in secured manner and handed over to authorized recycler after wash only

Sludge from MEE 34.3 5.4 MT/A Shall be stored in secured manner and handed over to TSDF

Table 8: Hazardous / Solid Waste Generation from the Proposed Products

Sl. No. Description

Proposed Quantity

(TPD) HW Stream Handling

Method Disposal

1. Organic residue from Process 2.1 28.1 of Schedule -I

HDPE Drums

Sent to SPCB Authorized Cement

industries or to TSDF for Incineration

2. Distillation Bottom Residue (1% of spent solvents) 0.5 36.1 of

Schedule -I

3. Spent carbon 0.01 28.3 of Schedule -I

4. Inorganic & Evaporation salt (Process) (10% moisture) 10.4 28.1 of

Schedule -I HDPE Bags



(based on Calorific value)

5. Evaporation salt with moisture (Non-Process) 0.5 35.3 of

Schedule -I

6. ETP Sludge with moisture 0.5 35.3 of Schedule -I

7. Boiler ash 24 -- HDPE Bags

Sent to Brick Manufacturers

Other Hazardous Waste generation from the Plant

8.

a) Detoxified Container / Liners drums, HDPE Carboys, Fiber Drums,

100 nos./month

33.1 of Schedule-I Designated

covered area

Disposed to SPCB Authorized agencies

after complete detoxification b) PP Bags 0.3 TPM --

9. Spent solvents (49.4 KLD + 1.6 KLD water) 51 KLD 28.6 of

Schedule -I Tanks / Drums

Recovered within the premises

10.

Recovered Solvents from Spent solvents (85% recovery from spent solvents)

42 KLD 28.6 of

Schedule -I

Tanks / Drums

Reuse or sold to Recyclers

11. Spent Mixed solvents (unrecovered solvents) 9 KLD 28.6 of

Schedule -I Tanks/ Drums

Sent to SPCB Authorized agencies


18

Sl. No. Description

Proposed Quantity

(TPD) HW Stream Handling

Method Disposal

12. Waste oils & Grease 2 KL/ Annum

5.1 of Schedule -I MS Drums

Sent to SPCB Authorized agencies for

reprocessing

13. Used Lead acid Batteries 30 nos. / annum

A1160 of Schedule-III

Stored in Covered

shed

Sent to suppliers on buy-back basis.

14. Misc. Waste (spill control waste) L.S. -- Stored in

Drums TSDF 15. Rejects L.S. --

16. E- waste L.S. -- Designated covered

area

Authorized reprocessor or

TSDF

17. Waste papers & other types of packing scrap L.S. -- Sold to scrap venders

18. Canteen waste L.S. -- HDPE bags

Composted on site and reused for green belt

19 Bio Medical Waste LS. -- Color coded

containers

Sent to SPCB authorized Biomedical

waste incinerator

20 Off-spec / Shelf Life expired chemicals / Products etc., L.S 28.5 of

Schedule -I HDPE Bags



(based on Calorific value) Note: Hazardous / Solid waste quantities maximum on various combinations i.e., 9 products on campaign products at a point of time & Bio pesticides, formulations R&D products.

3.10 Schematic Flow Sheet for EIA Procedure

The schematic flow sheet for EIA procedure is depicted as Annexure -XX.

4.0 Site Analysis 4.1 Connectivity

This proposed expansion project site is located at a distance (aerial) of 1.4 km (N) from

National Highway No. 65 (Machilipatnam-Hyderabad-Pune); about 0.6 km (W) from NH-218 (Bidar-

Hospet); 52 km (SSW) to Kalaburagi Airport.

4.2 Land Form, Land use and Land Ownership

The proposed expansion is in the existing manufacturing unit. Total land is 5.46 Ha plain land

and is in possession of Project Proponent.

4.3 Topography

The Topography map with a 10 km radius is enclosed as Annexure-XXI.

4.4 Existing Land Use Pattern

The existing and proposed land use pattern of project area (core area) of 5.46 Ha is Industrial

land and shortest aerial distance environmental components in buffer area from the project periphery

are given in Table 9.


19

Table 9: Environmental Components shortest distance from Project periphery S. No. Description Distance & Direction w.r.t. site

1. Water bodies • Pond Near Dhumansur Tanda at 6.1 km (NE) • Pond Near Hallikhed at 7.6 km (S) • Mullamari Reservoir at 9.1 km (SW)

2. Reserved Forests • RF near Kallur Tanda (open scrub)-3.1 km (S) • RF near Pandaragera(Dense scrub)-5.8 km (SW)

3. National Parks/ Wild Life Sanctuaries/ Eco sensitive areas

Nil

4. Industries 1. Satya Deeptha Pharmaceutical 2. Lakshmi Durga Chemicals 3. GPR Sciences Pvt. Ltd. 4. Venkata Sai Chemicals (Pharmaceuticals)

5. R K Chemicals 6. Sahiti Organics 7. Kshatriya Organics 8. Skents Chemicals

5. Habitation Humnabad -2.3 km (NE) 4.5 Existing Infrastructure

Internal CC / Black top roads, Transportation facilities, water supply, In-house ETP facility,

Power supply, Primary Health Centre, Conference halls, Fire hydrant system, Telecommunication

facility, canteen etc., are available.

4.6 Soil Classification

The soil in the study area is Laterite soil with brownish in colour and sandy clay texture. Soil

analysis report is enclosed as Annexure-XXII.

4.7 Climate Data from Secondary Sources

The district experiences semi-arid climate with extreme summer. The dust storms and severe

heat waves are common in the district between April and May. The temperature begins to rise

towards the end of February till the end of May, which is the hottest month of the year. Coldest

months are December and January. The temperature varies in the district between 20 ºC and 42 ºC

The year in the district may be divided into summer season from March to May, southwest monsoon

season from June to September, post-monsoon season from October to November and winter

season from December to February. Generally, the monsoon sets in the month of June and reaches

its peak in the month of September. The rainfall generally is spread over 45 to 55 days. Nearly 75%

to 80% of the annual rainfall is during the period of southwest monsoon. A few showers are also

received during the Northeast monsoon period, generally in the month of December. Bidar district

receives an average normal rainfall of 886 mm. The normal rainfall over the district ranges from 821

mm to 998 mm.


20

4.8 Social Infrastructure

This proposed expansion project site is located at a distance (aerial) of 1.4 km (N) from

National Highway No. 65 (Machilipatnam-Hyderabad-Pune); about 0.6 km (W) from NH-218 (Bidar-

Hospet); Road network, Transportation facilities, Private water supply, Power supply, Fire station,

Hospitals, Telecommunication facility, Schools, Community centers etc., are available at Humnabad,

Bidar district located at a distance of 2.3 km (aerial distance) and also available in nearby villages.

5.0 Planning

5.1 Planning Concept

Type of Industry: Pesticide technical, its intermediates, Bio Pesticides & Pesticides Formulations

with R&D products manufacturing unit.

Facilities: Industry proposed for expansion at existing land and facilities required for the proposed

project will be provided as per requirement.

Transportation: Transportation of raw materials and final products is done via roads as the proposed

expansion project is well connected to Road, Rail and Airways.

Town and Country Planning Classification: This is industrial area and allotted to Proponent and is

in possession of project proponent.

5.2 Population Projection

Proposal is for expansion of the existing industry and there is a scope for increase in the

population in the vicinity as most of the skilled workers prefers to stay in the nearby locations to avoid

travelling from long distances. However semi skilled and indirect employment potential is from local

villages. Hence, there is a possibility of increase in population of the skilled and semi skilled. The

local unskilled villagers will be preferred for the unskilled jobs such as gardening, movement of

materials, etc. Educated youth will be employed as semi-skilled workers and training will be provided.

However, on the whole there is a possibility of little increase in population of the area.

5.3 Land use Planning

The expansion unit has been proposed in existing area of about 5.46 Ha i.e., (54634.5 sq.m).

Total land is in the procession of the Proponent. The Break-up of the Land in procession of the

proponent is presented in Table 10.


21

Table 10: Land Break-up Details

S. No. Description

Existing Area

Additional Area

Total Area

(SQ.M) (SQ.M) (SQ.M) Percent (%)

1. Built-up area 10883 13843 24726 45.2 2. Roads 9990 1120 11110 20.3 3. Greenbelt 18798 Same 18798 34.4 4. Open Area 14963 Reduced 0 0

Total 54634 54634 100

5.4 Assessment of Infrastructure Demand

On assessment of infrastructure demand near the project area; Hospital with Ambulance

facility and Fire station requirement for the nearby villages of project area. Project site located in

Karnataka Industrial Area Development Board (KIADB) Industrial Area, Humnabad, Bidar district,

Karnataka.

5.5 Amenities/Facilities

Industry will continue to provide and upgrade the following amenities / facilities in the

proposed expansion project.

• Canteen • Potable drinking water • Training block • Laying of Concrete internal roads • Fire hydrant facility • Eye/body wash showers • First Aid kits at all prominent places. • Head nurse for emergency medication. • Rest Room for employees • Seating facilities for those employees who do their work standing and ergonomically designed

seating facilities for those who do their work seating • Pre-employment and routine medical examinations and the necessary follow up actions • Communication systems like Phone, Internet with safety measures, etc. • Security system at the entrance etc.

6.0 Proposed Infrastructure

6.1 Industrial Area

Additional Production Blocks, Utilities area, ETP up-gradation has been proposed in the

existing area of 5.46 Ha.

6.2 Residential Area

There will be no residential area within the project site.

6.3 Greenbelt

• The existing Greenbelt area is 1.88 Ha (34.4%) of 5.46 Ha.


22

6.4 Social Infrastructure

As Enterprise Social Commitment (ESC), Industry will contribute for development of village

social infrastructure.

6.5 Connectivity

There is no change in connectivity compare to existing facility.

6.6 Drinking Water Management

Potable drinking water will be provided to additional employees. The source of drinking water

is packaged drinking water.

6.7 Sewerage System

Sewage will be generated from the Canteen and Toilets, which will be collected into sewage

collection tank through pipelines and will be sent to ETP – ZLD system which needs to be upgraded

to meet the project demand.

6.8 Industrial Waste Management

Existing storage system needs to be enhanced to meet the expansion project demand. The

management of these wastes is to be handled very sensitively and by adopting proper segregation

techniques.

6.8.1 Process Emissions Management

Manufacturing of Pesticides technical, its intermediates, Bio pesticides, formulation & R&D

products manufacturing unit will result in gaseous emissions. Maximum process emissions for

existing and proposed products are given in Tables 11 & 12 respectively. Proposed gaseous

emissions will be scrubbed in two stages with water and caustic solution based on the characteristics

of gases. Proposed additional 4 scrubbers for the expansion project in addition to the existing 5

scrubbers to scrub the additional process emissions.

Table 11: Maximum Quantity of Process Emissions from Existing Products

Sl. No.

Process Emission

Maximum Quantity on various

combinations (kg/day)

Treatment

1. CO2 208.05 • Scrubbed using Caustic Lye

2. SO2 77.29 • Scrubbed by using CS lye solution

3 CH3Cl 227.09 • Connected to Incinerator with Scrubbing system (Discontinued the Monochrotophos Tech Production)


23

Table 12: Maximum Quantity of Process Emissions from Proposed Products

Sl. No.

Process Emission

Maximum Quantity on various combinations

(kg/day) Treatment

1. HCl 693.2 • Scrubbed by using water & CS lye sol.

2. SO2 817.94 • Scrubbed by using CS lye solution

3. CO2 542.68 • Scrubbed using Caustic Lye

4. H2 3.29 • Diffused with Flame Arrestor

6.8.2 Fugitive emissions

Solvents used in the Pesticides technical, its intermediates, Bio Pesticides & Pesticides

Formulations with R&D products manufacturing process unit will be stored in drums and bulk

quantities will be stored in above ground storage tanks.

Solvents are handled in closed conditions thereby reducing the losses in the form of

evaporation.

Proper earthing will be provided to all the electrical equipment and the joints / connections

wherever solvent handling is done.

Reactor and solvent handling pump will have mechanical seals to prevent leakage.

The industry will take measures for reduction of fugitive emissions and for further reduction

industry will provide vent condensers to the tanks.

Chilled brine circulation will be carried out to condensate the solvent vapour and to the

receivers of the solvent vapors which ensures the maximum recovery.

Solvent vapours from the Centrifuge and Catch pots will be connect to vent condensers.

The height of the solvent receiver tank vent is above production block roof level and the

diameter is 20 mm.

Flame proof fitting / equipments / pumps / lighting will be used wherever solvents are used.

The solvent storage tanks will be provided with breather valve to prevent losses

Solvent Input Solvent in

Solvent in Product

Solvent Recovery Effluent Org. residue Handling loss

51.6 0.4 0.17 1.43 0.2 49.4 (95.7%)

6.8.3 Emissions–Utilities

Boilers and DG sets are the main sources contributing to emissions from the plant. Proposed

2 nos. of 5 TPH coal / bio-fuel fired boilers in addition to the existing 3 & 2 TPH coal fired boilers.

Coal of about 60 TPD will be used in the boilers.


24

Diesel about 300 lit / hr will be used at full operation load in the DG sets. Proposed DG set of

625 KVA, in addition to existing 625 KVA & 250 KVA DG sets. DG sets will be used as standby

during power failure. The stack emissions from the boiler and DG sets are given in Table 13.

Table 13: Stack Emission Details – Proposed

Source Stack Height

(m)

Diameter (m)

Temperature (oC)

Flue Gas Flow rate

(m3/hr)

Exit Gas

Velocity (m/sec)

PM SO2 NOx

kg/hr

Coal Fired Boilers 5 TPH

(Proposed) 30 0.6 150 13308 13.1 0.675 7.08 4.05

5 TPH (Proposed) 30 0.6 150 13308 13.1 0.675 7.08 4.05

3 TPH (Existing) 30 0.5 150 7985 11.3 0.405 4.25 2.43

2 TPH (Existing) 30 0.5 150 5322 7.5 0.27 2.83 1.62

Diesel Generator (DG) sets Proposed 625 KVA 10 0.3 150 3528 13.9 0.0396 0.782 0.84

Existing 625 KVA 10 0.3 150 3528 13.9 0.0396 0.782 0.84 250 KVA 8 0.2 150 1411 12.5 0.016 0.31 0.34

The various measures proposed to minimize the pollution from the boiler are as follows:

Multi-cyclone separator followed by Bag filter will be installed to control the particulate (PM)

emissions within statutory limit of 115 mg/Nm3. To facilitate wider dispersion of pollutants,

30m height stack each will be installed.

The NOx emissions from the boilers will be controlled by controlling combustion measures,

which will be approached by way of low NOx burners or by air stagging in boiler.

Stack height will be based on Sulphur content in fuel as per CPCB guidelines

Stacks will be provided to proposed DG sets as per CPCB / SPCB Guidelines.

Fugitive dust will be controlled by adopting dust extraction and dust suppression measures

and development of greenbelt along the periphery of the proposed Boiler area.

6.8.4 Noise Environment

• Compressors, Boilers and DG sets will be the major noise generating units in the plant.

• The noise levels of the DG sets will be well within the limits as these will be installed with acoustic enclosures. Workers will always be provided with ear muffs.

• All the equipment in the plant would be designed to have a total noise level not exceeding 85-

90 dB(A) as per the requirement of OSHA (Occupational Safety and Health Administration)

standards.


25

6.9 Hazardous / Solid Waste Management

• Solid waste mainly segregated into process organic residues, inorganic salts, distillation

residue, boiler ash, spent mixed unrecoverable solvents and spent carbon.

• The organic residues, Spent carbon & Spent mixed unrecoverable solvents, distillation residue

can be disposed off to Cement plants as recommended by CPCB for use as alternate fuels

either in the solid or liquid form.

• Boiler ash will be sold to brick manufacturers.

• Inorganic salts are to be sent for landfill at TSDF.

Solid waste will be segregated, stored and disposed as mentioned in the Table 8

6.10 Power Requirement & Supply / Source

The proposed power requirement (Contract Power Demand) of the plant is 1350 KVA

including existing 450 KVA. Proposed DG sets are 625 KVA, in addition to existing 625 & 250 KVA

DG set. DG set which will be used as standby during power failure.

7.0 Rehabilitation and Resettlement (R&R) Plan

The proposed project is in the existing area and is in possession of project proponent.

Therefore Rehabilitation and Resettlement plan is not applicable to this expansion project. The

nearest town is away from 2.3 km away from the project site.

8.0 Project Schedule & Cost Estimates

8.1 Time Schedule for the project construction

The timelines for commencement of proposed construction activity will be from April 2019 as it

is expected that the expansion project will be in a position to obtain Environmental Clearance for the

project and Consent to Establish from the State Pollution Control Board. In end of 2019 the

commercial production is expected to be commenced.

8.2 Estimated Project Cost

Overall estimated cost involved in the total project (existing and proposed) like land, building,

plant & machinery is Rs. 126.89 Crores. Total capital cost allocated towards environmental pollution

control measures is Rs. 8.59 Crores including the existing Rs. 3.44 Cr. Recurring cost will be about

Rs. 9.48 Crores per annum.

9.0 Analysis of proposal (Final Recommendations)

• The proposed expansion project will result in growth of surrounding area by generating direct

and indirect employment to local people. Around 397 members will be benefitted due to the

expansion project (including existing 197 nos.).

• Under the Enterprise Social Commitment, Industry will continue to develop a policy of

developing the surrounding villages in the vicinity by identifying the requirements.


26

• No adverse effect on environment is envisaged as proper mitigation measures will be taken up.

• Industry will strengthen the existing Safety, Health & Environment Department and also

continue to engage recognized laboratories to carry out all necessary monitoring parameters for

its activities.

• The segregated (HTDS / LTDS) wastewater will regularly analyzed before and after treatment in

ETP-ZLD.

• Qualified staff will be appointed for the purpose of Operation and Maintenance of the pollution

control facilities.

• Stand-by facilities will be provided to all the pumps so as to ensure fail proof treatment, handling

and disposal

9.1 Budgetary allocation for Pollution Control Measures

The management will set aside adequate funds in its budget to fully meet the stated objectives

of the environmental policy. The proposed and existing capital equipment for environmental

management include up-gradation of effluent treatment plant, pipelines and channels for wastewater

discharge, greenbelt development, air pollution control equipments and the environment laboratory.

The Estimated break-up of budgetary allocation for various control measures is presented in Table 14.

Table 14: Budgetary allocation for Pollution Control Measures

S. No. Description

Existing cost (in lakhs)

Proposed cost (in lakhs)

Capital *Recurring Capital *Recurring

1. Air Pollution Control

97 19 85 30 a. Multi-cyclone / Bag filter with Stacks b. Scrubbers

2. Water Pollution Control

100 45 250 450 a. ETP Civil works, Steam stripper, MEE, ATFD, RO and mechanical equipment

3. Noise Pollution Control 15 1 10 2 a. Silencers / acoustic enclosures

4. Solid Waste Management

14 16 10 350** a. Covered Platform with leachate collection system

5. Greenbelt Development 4 3 5 6 6. Occupation Health and Safety 20 20 30 30 7. Fire Management 20 5 20 5 8. Dyke walls and Storm water drains 5 5 5 5 9. Environmental Laboratory 9 4 20 10 10 Miscellaneous 60 30 80 60

Total 344 148 515 948 *Recurring cost includes manpower, consumables, maintenance, energy charges per annum

** includes transportation, stabilization and handling charges to Cement industries / TSDF

Annexures

ANNEXURE - I

27

ANNEXURE - I

28

ANNEXURE - I

29

ANNEXURE - I

30

ANNEXURE - I

31

ANNEXURE - I

32

ANNEXURE - I

33

ANNEXURE - II

34

ANNEXURE - II

35

ANNEXURE - II

36

ANNEXURE - III

46

ANNEXURE - III

47

ANNEXURE - III

48

ANNEXURE - IV

57

ANNEXURE - IV

58

ANNEXURE - V

62

ANNEXURE - V

63

ANNEXURE - V

64

ANNEXURE - V

65

ANNEXURE - V

66

ANNEXURE - VI

67

ANNEXURE - VI

68

ANNEXURE - VI

69

GOVERNMENT OF INDIA

MINISTRY OF CORPORATE AFFAIRS

Certificate of Incorporation Consequent upon Conversion to

Private Limited Company

Corporate Identity Number : U24100TG2013PTC091503.

IN THE MATTER OF NECTAR CROP SCIENCES LIMITED

I hereby certify that NECTAR CROP SCIENCES LIMITED which was originally incorporated on Fifth day ofDecember Two Thousand Thirteen under any previous company law as NECTAR CROP SCIENCES LIMITED andupon an intimation made for conversion into Private limited by shares Company under Section 18 of theCompanies Act, 2013; and approval of Central Government signified in writing having been accorded thereto by theAndhra Pradesh vide SRN C46286373 dated 25/03/2015 the name of the said company is this day changed toNECTAR CROP SCIENCES Private Limited.

Given under my hand at Hyderabad this Twenty Fifth day of March Two Thousand Fifteen.

Hyderabad

2nd Floor , CPWD Building , Kendriya Sadan , Sultan Bazar, Koti Hyderabad - 500195,

Telangana, INDIA

Fresh Certificate of Incorporation Consequent upon Conversion from Public Company to Private Company .

Mailing Address as per record available in Registrar of Companies office:

NECTAR CROP SCIENCES Private LimitedA-24/25, APIE, BALANAGAR,HYDERABAD - 500037,Telangana, INDIA

Registrar of Companies

Hyderabad

Varaha Santoshi Jagirdar

Assistant Registrar of Companies

Digitally signed by NKRISHNA MURTHYDate: 2015.03.2516:09:40 GMT+05:30

Signature Not Verified

ANNEXURE - VII

70

Certificate of Incorporation pursuant to change of name

[Pursuant to rule 29 of the Companies (Incorporation) Rules, 2014]

GOVERNMENT OF INDIA MINISTRY OF CORPORATE AFFAIRS

Registrar of Companies

Mailing Address as per record available in Registrar of Companies office:

Corporate Identification Number (CIN):

Office of the Registrar of Companies

I hereby certify that the name of the company has been changed from NECTAR CROP SCIENCES PRIVATE LIMITED to NICHINO CHEMICAL INDIA PRIVATE LIMITED with effect from the date of this certificate and that the company is limited by shares. Company was originally incorporated with the name NECTAR CROP SCIENCES PRIVATE LIMITED. Given under my hand at Hyderabad this Sixteenth day of December two thousand seventeen.

DS MINISTRY OF CORPORATE AFFAIRS 24

Digitally signed by DS MINISTRY OF CORPORATE AFFAIRS 24 DN: c=IN, o=MINISTRY OF CORPORATE AFFAIRS, postalCode=500068, st=Telangana, street=NAGOLE BANDKAGUDA HYDERABAD, 2.5.4.51=2 ND FLOOR CORPORATE BHAWAN, cn=DS MINISTRY OF CORPORATE AFFAIRS 24 Reason: I attest to the accuracy and integrity of this document Date: 2017.12.16 14:00:11 +05'30'

2nd Floor, CPWD Building Kendriya Sadan, Hyderabad, Telangana, India, 500195

RoC - Hyderabad

RAMESH CHANDRA MISHRA

NICHINO CHEMICAL INDIA PRIVATE LIMITED

A-24/25, APIE, BALANAGAR, HYDERABAD, Hyderabad, Telangana, India, 500037

U24100TG2013PTC091503

ANNEUXRE - VIII

71

3/17/2018 Gmail - Acknowledgement Slip for EC application

https://mail.google.com/mail/?ui=2&ik=e2c370d4b0&jsver=7NKBhY4B7p8.en.&view=pt&search=inbox&th=1622f08ab89d41e6&siml=1622f08ab8… 1/1

Nichino Chemical India Pvt Ltd <[email protected]>

Acknowledgement Slip for EC application 1 message

[email protected] <[email protected]> Fri, Mar 16, 2018 at 7:08 PMTo: [email protected], [email protected]: [email protected], [email protected]

Acknowledgement Slip for amendment in EC

This is to acknowledge that the proposal for amendment in EC has been successfullyuploaded on the portal of the Ministry. The proposal shall be examined in the Ministryto ensure that required information has been submitted. An email will be sent forseeking additional information , if any, within 20 working days. Once verified, anacceptance letter shall be issued to the project proponent.

Following should be mentioned in further correspondence

1. Proposal No. : IA/KA/IND2/73539/20122. Category of the Proposal : Industrial Projects - 23. Name of the proposal : Nichino Chemical India Private Limited4. Date of submission : 16 Mar 20185. Name of the Project proponent along with contact details

a) Name of the proponent : NICHINO CHEMICAL INDIA PVT LTDb) Mobile No. : 9848443076c) State : Karnatakad) District : Bidare) Pincode : 585330

ANNEUXRE - IX

72

ANNEUXRE - X

73

General Location Map

Bidar District

Project Site

India

Karnataka State

Humnabad Tehsil

ANNEXURE - XI

74

Specific Location (Route map)

M/s. Nichino Chemical India Pvt. Limited

M/s. Nichino Chemical India Pvt. Limited

ANNEUXRE - XII

75

Google Image of the Proposed Project with Site Coordinates

Sl. No. Latitude Longitude Sl.

No. Latitude Longitude

1 17°45'24"N 77° 5'39"E 5 17°45'28"N 77° 5'54"E 2 17°45'28"N 77° 5'44"E 6 17°45'21"N 77° 5'47"E 3 17°45'25"N 77° 5'48"E 7 17°45'17"N 77° 5'46"E 4 17°45'29"N 77° 5'53"E 8 17°45'19"N 77° 5'44"E

ANNEXUER - XIII

76

ANNEXURE - XIV

77

Administrator

Text Box

Flow Chart

Dichloromethane Stage-1 MassDimethyl Sulfate

Stage-1 Mass By-Product Ammonia (21%) Sol.RecoveryAcetic Anhydride Evaporation LossSulfuric Acid EffluentEthyl Acetate Organic ResidueWater

Acephate

Stage-1 : Dimethyl Phosphoryl Amide is dissolved in the Dichloro methane to get Dimethyl Phosphoryl Amidesolution. To this solution, Dimethyl Sulfate is added to get Isomerised product called Methamidophos.

Stage-2 : Methamidophos is reacted with Acetic Anhydride in the presence of Sulfuric Acid to get Acetylationproduct. The Acetylation product is hydrolised with Ammonia, then the organic layer and aqueous layers areseparated. Organic layer is distilled for recovery of the solvent and Acephate.

PRODUCT : Acephate

Description :

O,O-Dimethyl Phosphoramidothionate

Stage I

Stage II

ANNEXURE - XV

78

Flow Chart

Sol.RecoveryEvaporation Loss

Sodium Hydroxide (98%)

Stage-1 Mass Sol.RecoveryEthyl-N-Cyano Acetaimidate Evaporation LossWater Effluent

Organic Residue

Acetamiprid

Stage-1 : 2-Chloro-5-Chloromethyl Pyridine is reacted with Monomethyl Amine and Sodium Hydroxide inMonomethyl Amine with Methanol to get Stage-1.

Stage-2 : Stage-1 is reacted with Methyl-N-Cyano acetoimidate to get Acetamiprid.

PRODUCT : Acetamiprid

Description :

2-Chloro-5-Chloromethyl PyridineMonomethyl Amine (30% in Methanol)

Stage I

Stage II

ANNEXURE - XV

79

Flow Chart


EffluentPotassium BisulphateTolueneDimethyl formamideWater


2-Cyanophenol EffluentPotassium carbonate Organic ResidueMethanol Process EmissionsWater

Azoxystrobin

Methyl 2-[2-(6-chloropyrimidin-4-yloxy)phenyl]-3,3- dimethoxy propanoate

Stage-1 Mass in Dimethyl formamide

PRODUCT : Azoxystrobin

Description :

Stage-1 : Stage 1 involves the reaction of Methyl 2-[2-(6-chloropyrimidin-4-yloxy)phenyl]-3,3-dimethoxypropanoate (MDCPP) with Potassium bisulphate in toluene. Water is added to dissolve salts. Tolueneis distilled and DMF added to the mass.

Stage-2 : This mass is taken to stage-2 where the reaction of stage-1 intermediate with 2-cyanophenol inpresence of potassium carbonate. DMF is distilled and water added to dissolve the salts and filtered the crudeproduct. The crude product which is crystallized with Methanol to give pure Azoxystrobin technical.

Stage I

Stage II

ANNEXURE - XV

80

Flow Chart

Sol.RecoverySodium Nitrite Evaporation LossHydrochloric acid (32%) EffluentEthyl 2,3-dicyano propionate Organic ResidueAmmonia (25%) Process EmissionsMethanolEthylene dichlorideWater

PRODUCT : 5-Amino-3-cyano-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]pyrazole (Phenyl Pyrazole)

Description :

Stage-1 : 2,6-dichloro4-trifluoromethyl aniline reacts with sodium nitrite and HCl(32%) to form diazonium saltwhich further reacts with Ethyl-2,3-dicyanopropionate to give a intermediate. This intermediate cyclize inpresence of ammonia to give Phenyl pyrazole product.

5-Amino-3-cyano-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]pyrazole (Phenyl Pyrazole)

2,6-dichloro-4-trifluoromethyl aniline

Stage I

ANNEXURE - XV

81

Flow Chart

4,6-DihydroxypyrimidinePhosphrous oxychloride1,3-propanediol EffluentDimethyl formamide Process EmissionsTolueneWater

4-Trifluromethyl benzyl alcohol EffluentSodium carbonate (25%) Organic ResidueWater Process Emissions

Stage-2 intermediate in Toluene Sol.RecoveryCatalyst Evaporation LossHydrogen EffluentWater Organic ResidueMethanol Process Emissions

Benzpyrimoxan

Stage-1 intermediate in Toluene

Stage-1 : 4,6-dihydroxy pyrimidine, phosphorous oxychloride, and 1,3-propanediol reacted in solvent dimethylformamide and toluene to give the stage -1 intermediate, 4,6-dichloro-5-(1,3-dioxan-2-yl) pyrimidine.

Stage-2 : The stage-1 intermediate is reacted with 4-trifluromethyl benzyl alcohol in presence of a base sodiumcarbonate to give the stage-2 intermediate 6-chloro-5-(1,3-dioxan-2-yl)-[4-(-4-trifluromethyl) benzyloxy)]pyrimidine.

Stage-3 : The stage-2 intermediate is reacted with hydrogen in presence of catalyst to give the final productBenzpyrimoxan technical.

PRODUCT : Benzpyrimoxan

Description :

Stage I

Stage II

Stage III

ANNEXURE - XV

82

Flow Chart


Thionyl chloride EffluentDimethylformamide Organic Residue

Process Emissions


EffluentOrganic Residue

DimethylformamidePotassium carbonateTetrabutyl ammonium bromideWater

Stage-1

Lamda Cyhalothric acid (MTH Acid)

Bifenthrin

Stage-1 : Stage 1 involves reaction of 2-methyl-3-biphenyl methyl alcohol with thionyl chloride to prepare BPC.

Stage-2 : Then this intermediate reacts with Lamda cyhalothric acid in stage-2 in presence of potassiumcarbonate to form the product. The solvent is distilled and crude is crystallized with methanol to get Bifenthrintechnical.

PRODUCT : Bifenthrin

Description :

2-methyl-3-biphenyl methyl alcohol (BPA)

Stage I

Stage II

ANNEXURE - XV

83

Flow Chart


2,6-dihydroxy benzoic acid EffluentSodium hydroxide (48%) Organic ResidueTetrabutyl ammonium bromideToluenen-ButanolEthyl acetateWater

Bispyribac Sodium

4,6-dimethoxy-2-methyl sulfonyl pyrimidine

Stage-1 : This process is involving reaction of 2,6-dihydoxy benzoic acid with 2-methyl sulfonyl 4,6-dimethoxypyrimidine in presence of sodium hydroxide to form the product. Then toluene is distilled and the crude iscrystallized with mixture of butanol and ethyl acetate to get Bispyribac sodium technical.

PRODUCT : Bispyribac Sodium

Description :

Stage I

ANNEXURE - XV

84

Flow Chart


EffluentAmmonium bicarbonate Organic ResidueEthylene dichloride Process EmissionsMethanolWater

Buprofezin

N-Tertiary butyl N-isopropyl thio urea

Stage-1 : N-Tertiary butyl N-isopropyl thio urea, N-Chloro methyl N-phenyl Carbamoyl chloride, Ammoniumbicarbonate and Ethylene dichloride were charged to the reactor to get the reaction to form Buprofezin. Wateradded and layer separated to get Buprofezin in EDC. EDC distilled out and methanol added to crystallize andfiltered to get Buprofezin technical.

PRODUCT : Buprofezin

Description :

N-Chloro methyl N-phenyl Carbamoyl chloride

Stage I

ANNEXURE - XV

85

Flow Chart

Dimethylamine (40% in water)Allyl ChlorideEthylene dichloride EffluentSodium Hydroxide (48%)Water

Stage- 1 mass Sol.RecoverySulfuryl Chloride Evaporation LossToluene Process Emissions

Stage 2 massSodium thiocyanateWater Effluent

Stage- 3 mass Sol.RecoveryHydrogen chloride gas Evaporation LossMethanol Organic ResidueWater

Cartap Hydrochloride

Stage-1 : Allyl chloride (liquid), dimethylamine (40% solution in water) and sodium hydroxide (30%) solution arereacted to give stage-1 intermediate.

Stage-2 : .stage-1 intermediate reaction with sulfuryl chloride to give stage-2 intermediate.

Stage-3 : Stage-2 intermediate reacted with sodium thiocyanate to give Stage-3 intermediate.

Stage-4 : Stage-3 intermediate reacted with hydrochloride gas passing gives the final product, CartapHydrochloride.

PRODUCT : Cartap Hydrochloride

Description :

Stage I

Stage II

Stage III

Stage IV

ANNEXURE - XV

86

Flow Chart

2,3,5,6-Tetrachloro PyridineCaustic lye (48%) Stage-1 MassWater

Stage -1 Mass Sol.RecoveryEvaporation Loss

EffluentEthylene dichloride Organic Residue

Chlorpyrifos

Diethoxy thiophosphoryl chloride

PRODUCT : Chlorpyrifos

Description :

Stage-1 : ,3,5,6-tetrachloropyridine reacted with sodium hydroxide in water to give sodium salt of 3,5,6-trichloro-2-hydroxy pyridine.

Stage-2 : This stage 1 material is then reacted with DETCl (diethoxy thiophosphoryl chloride) in presenceEthylene dichloride as solvent to give the product chlorpyrifos. Ethylene dichloride layer is distilled to givechlorpyrifos technical.

Stage I

Stage II

ANNEXURE - XV

87

Flow Chart

Stage -1 MassProcess Emissions

5-Chloro-2,3-difluoropyridinePotassium carbonateToluene

Stage-1 Mass Sol.RecoveryPropargyl chloride Evaporation LossMethanol EffluentCarbon Organic ResidueWater Spent Carbon

R-(+)-2-[4-5(-chloro-3-fluoropyridin-2-yloxy)phenoxy]propionic acid

PRODUCT : Clodinafop Propargyl

Clodinafop Propargyl

Stage-1 : This process is involving two stages. Stage 1 involves preparation of potassium salt of R-(+)-2-[4-5(-chloro-3-fluoropyridin-2-yloxy)phenoxy]propionic acid by reacting 5-Chloro-2,3-difluoropyridine with R(+)-2-(4-hydroxy phenoxy)propionic acid in presence of base and solvent.

Stage-2 : Stage 2 involves reaction of potassium salt of R-(+)-2-[4-(5-chloro-3-fluoropyridin-2-yloxy)phenoxy]propionic acid resulted from Stage 1 with propargyl chloride in solvent to give crude product andfollowed by crystallization with methanol to give Clodinafop Propargyl.

Description :

Stage I

Stage II

ANNEXURE - XV

88

Flow Chart

2-HeptanolChloro acetic acid Stage-1 massn-Hexane EffluentWater

Stage-1 Mass Sol.Recovery8-Hydroxy-5-chloroquinoline Evaporation LossPotassium Carbonate EffluentToluene Organic ResidueMethanolWater

PRODUCT : Cloquintocet Mexyl

Description :

Stage-1 : Chloroacetic acid and 2-heptanol reacted to give 2-heptyl chloracetyl ester in presence of n-Hexaneas solvent. Stage 1,

Stage-2 : Stage 1 is reacted with 8-hydroxy quinoline in presence of potassium carbonate and toluene to givethe product Cloquintocet mexyl. Water is added and layer separation done., Toluene layer is distilled, methanoladded to crystallize the product and filtered to get the product.

Cloquintocet Mexyl

Stage I

Stage II

ANNEXURE - XV

89

Flow Chart

D-methyl lactate Stage 1 MassThionyl chloride EffluentWater Process Emissions

Stage 1 Mass Sol.RecoveryHydroquinone Evaporation LossSodium hydroxide (48%) EffluentMethylisobutyl ketone Organic ResidueSulfuric acidHydrochloric acid(33%)Water

PRODUCT : (R) 2-(4-Hydroxyphenoxy) Propionic Acid [DHPPA]

Description :

Stage-1 : This process is involving the reaction of D-methyl lactate and thionyl chloride to prepare theintermediate.

Stage-2 : Methyl-2-chloro propionate which further reacts with hydroquinone in the presence of a base, sodiumhydroxide to give the product (R) 2-(4-Hydroxyphenoxy) Propionic Acid [DHPPA]). This is one of a raw materialfor the production of Clodinafop propargyl.

(R) 2-(4-Hydroxyphenoxy) Propionic Acid [DHPPA]

Stage I

Stage II

ANNEXURE - XV

90

Flow Chart


O-xylene Process Emissions

Stage-1 Sol.Recoveryt-butyl amine Evaporation LossDichloromethane EffluentMethanol Organic ResidueWater

Stage-1 : This process is involving two stages. Stage 1 involves the heating of 2,6-diisopropyl-4-phenoxy phenyl thiourea to give the intermediate, -isothiocynate.

Stage-2 : This intermediate reacts with tert-butyl amine to give the product. After the solvent is distilled, thecrude mass is crystallized in methanol to get the product Diafenthiuron technical.

Diafenthiuron

PRODUCT : Diafenthiuron

Description :

2,6-diisopropyl-4-phenoxy phenyl thiourea Stage I

Stage II

ANNEXURE - XV

91

Flow Chart



Hydrogen Peroxide (30%)DichloromethaneMethanolWater

PRODUCT : Ethiprole

Description :

Stage-1 : This process is involving the reaction between 5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-3-(ethylthio)-1H-pyrazole-4-carbonitrile (sulfide) and hydrogen peroxide in DCM as solvent to obtain Ethiprole.

Ethiprole

5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-3-(ethylthio)-1H-pyrazole-4-carbonitrile (Sulfide)

Stage I

ANNEXURE - XV

92

Flow Chart

D-Methyl Lactate EffluentThionyl chloride Process EmissionsWater

Stage-12,4-DichlorophenolSodium Hydroxide (48%) EffluentTolueneWater

Stage-2 in Toluene Sol.RecoveryEvaporation Loss


Hydrochloric acid(32%)MethanolWater

Stage-3 : The stage-2 intermediate is reacted with 2-amno-2,3,-dimethylbutyronirtrile in presence of base,sodium methoxide to give the final product Fenoxanil technical.

2-amino-2,3-dimethyl butyronitrileSodium methoxide (28%) in Methanol

Fenoxanil

Stage-1 : D-methyllactate and thionyl chloride reacted to give the stage -1 intermediate, methyl 2-chloropropionate.

Stage-2 : The stage-1 intermediate is reacted with 2,4-dichlorophenol in presence of a base sodium hydroxideto give the stage-2 intermediate methyl (2,4-dichlorophenoxy)propionate.

PRODUCT : Fenoxanil

Description :

Stage I

Stage II

Stage III

ANNEXURE - XV

93

Flow Chart

Phenol EffluentSodium Hydroxide (48%)TolueneCuprous chloride [CuCl]Water

Stage 1 in Toluene layer Sol.RecoveryHydroxylamine hydrochloride Evaporation Loss


Potassium hydroxide (50%)MethanolWater

Fenpyroximate

Stage-1 : This process is involving the reaction between Pyrazole 1,3-dimethyl-5-chloro-4-carbaldehyde andPhenol in presence of CuCl to give Stage 1 intermediate.

Stage-2 : Stage 1 intermediate reacts with hydroxylamine hydrochloride and t-butyl 4-(bromomethyl)benzoate inpresence of a base, potassium hydroxide, in a solvent. After the completion of reaction, the inorganic salt isdissolved in water and layer separated. The organic toluene layer distilled and crude mass crystallized inMethanol to get Fenpyroximate technical.

PRODUCT : Fenpyroximate

Description :

Pyrazole 1,3-dimethyl-5-chloro-4-carbaldehyde

t-butyl 4-(bromomethyl)benzoate

Stage I

Stage II

ANNEXURE - XV

94

Flow Chart

Dimethyl amine (40%) EffluentEthylene dichlorideWater

Stage 1 Mass



Process EmissionsThionyl chlorideAcetonitrileWater

Fipronil

Stage-1 : Dimethyl amine is added to p-toluene sulfonic acid at low temperature. Then water is distilled out andethylene dichloride added to make solution of p-toluenesulfonyl-dimethylamine complex in EDC.

Stage-2 : Trifluoromethane sulfinyl sodium salt is dissolved in ethyl acetate and filter the inorganic salt. Thenethyl acetate distilled out and added stage 1, p-toluenesulfonyl-dimethylamine complex in EDC. The mass iscooled and added pyrazole and thionyl chloride. Then again raised the temperature to RT and maintained for 10hrs to get fipronil product.

PRODUCT : Fipronil

Description :

P-toluene sulfonic acid mono hydrate

5-Amino-3-cyano-1-(2,6-dichloro-4-trifluoromethylphenyl)pyrazole

Sodium trifluoromethanesulfinate (65%)

Stage I

Stage II

ANNEXURE - XV

95

Flow Chart

6-iodo ortho phthaloyl chloride

EffluentProcess Emissions

Ethylene Dichloride

Stage-1[dicarboxamide] Sol.RecoveryHydrogen Peroxide (30%) Evaporation LossMethanol EffluentWater Organic Residue

Stage-2 : 1-N-[4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-2-methylphenyl]-3-iodo-2-N-[2-methyl-1-methylthio)propan-2-yl]benzene-1,2-dicarboxamide which is further oxidized with Hydrogen peroxide in Ethylene dichloride to give the product Flubendiamide.

Flubendiamide

2-methyl-1-methylthio propan-2-amine

2-methyl-[4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)- aniline

PRODUCT : Flubendiamide

Description :

Stage-1 : 6-iodo ortho phthaloyl chloride reacts with 2-methyl-1-methylthio propan-2-amine and 2-methyl-[4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)- aniline to give the intermediate 1-N-[4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-2-methylphenyl]-3-iodo-2-N-[2-methyl-1-methylthio)propan-2-yl]benzene-1,2-dicarboxamide

Stage I

Stage II

ANNEXURE - XV

96

Flow Chart

2-Trifluromethyl benzoic acid Sol.RecoveryThionyl chloride Process EmissionsToluene

Stage-1 Mass in Toluene layer Sol.Recovery3-Isopropoxy aniline Evaporation LossMethanol EffluentWater Organic ResidueSodium carbonate Process Emissions

Flutolanil

PRODUCT : Flutolanil

Description :

Stage-1 : Stage 1 involves preparation of 2-trifluromethyl benzoyl chloride by reacting 2-trifluromethyl benzoicacid with thionyl chloride in a solvent.

Stage-2 : Stage 2 involves reaction of 2-trifluromethyl benzoyl chloride with 3-isopropxy aniline in a solvent togive crude product and followed by crystallization with methanol to give Flutolanil product.

Stage I

Stage II

ANNEXURE - XV

97

Flow Chart

2-Chloro-5-Chloro Methyl Pyridine Sol.RecoveryN-Nitro Imino Imidazolidine Evaporation LossPotassium Carbonate EffluentDimethyl formamide Organic ResidueMethanolWater

PRODUCT : Imidacloprid

Description :

Stage-1 : 2-Chloro-5-Chloro Methyl Pyridine, N-Nitro imino imidazolidine, Potassium Carbonate and DimethylFormamide will be charged in reactor and mixed to get Imidacloprid.

Imidacloprid

Stage I

ANNEXURE - XV

98

Flow Chart

Stage-1 MassSol.Recovery

Methyl acetateHydrogenPd/C catalyst

Stage-1 Mass Sol.RecoveryEvaporation Loss


Sodium citrate solution Inorgainc Solid Wasten-HexaneSilicaWater

Indoxacarb

Phenyl methyl ( 5-chloro-2,3-dihydro-2-hydroxy-2-

(methoxycarbonyl)-1H-inden-1-ylidne hydrazine carboxylate

PRODUCT : Indoxacarb

Description :

Stage-1 : Phenyl Methyl [5-Chloro-2,3-dihydro -2-hydroxy-2-(methoxycarbonyl)-1H-inden-1-ylidene hydrazinecarboxylate (solid), methyl acetate (liquid), and Palladium/Carbon catalyst are charged to the reactor.Hydrogenation is done by giving Hydrogen pressure to the reactor. The catalyst is filtered through filter. Filteredcatalyst is reused in the next batch. Total mass, which is liquid, this stage-1 Intermidiate.

Stage-2 : Stage-1 Intermidiate is reacted with Methyl (Chlorocarbonyl)[ 4-(trifluoromethoxy) phenyl] Carbamate (solid) and sodium citrate solution are added and stirred. Methyl acetate layer is taken for distillation to recover the methyl acetate. Recovered methyl acetate will be reused in the next batch. To the residue, n-hexane is added to crystallize the material.Crystallized material is filtered to get the wet product and dried. Hexane mother liquor is taken for recovery of hexane

Methyl (chlorocarbonyl)- [4-(trifluromethoxy) phenyl] carbamate

Stage I

Stage II

ANNEXURE - XV

99

Flow Chart

Diisopropyl malonate Sol.RecoveryCarbondisulfide Evaporation LossSodium Hydroxide (48%) EffluentEthylene dichloride as reactant Organic ResidueEthylene dichlorideMethanolHydrochlorid acid (32%)Water

Stage-1 : This process is involving the reaction of Diisopropyl malonate with Carbon disulphide to form aintermediate salt which further reacts with ethylene dichloride to give the product. After workup, the product iscrystallized with methanol to get Isoprothiolane technical.

Isoprothiolane

PRODUCT : Isoprothiolane

Description :

Stage I

ANNEXURE - XV

100

Stage-2 : Stage-1 intermediate reacted with isopropyl bromide to give the stage-2 intermediate.

Stage-3 : stage-2 is deprotected with methanolic hydrochloride to give the product Meta isopropoxy aniline.

PRODUCT : Metaisopropoxy Aniline

Description :

Stage-1 : Stage 1 involves protection of meta amino phenol with acetic acid to get stage -1 intermediate.

ANNEXURE - XV

101

Flow Chart

Meta amino phenol Sol.RecoveryAcetic acid as reactant Evaporation LossAcetic acid EffluentWater

Stage-1 Sol.RecoveryIsopropyl bromide Evaporation LossPotassium carbonate EffluentDimethyl formamideWater

Stage-2 Sol.RecoveryEvaporation Loss

EffluentSodium Hydroxide Organic ResidueWater

PRODUCT : Metaisopropoxy Aniline

Hydrochloric acid in Methanol (25%)

Metaisopropoxy Aniline

Stage I

Stage II

Stage III

ANNEXURE - XV

102

Flow Chart



4-cyanobenzyl-3-trifluoromethyl-phenylketone hydrazone

4-trifluoromethoxyphenyl isocyanate

Metaflumizone

PRODUCT : Metaflumizone

Description :

Stage-1 : 4-cyanobenzyl-3-trifluoromethyl-phenylketone hydrazone is reacted with 4-trifluoromethoxyphenylisocyanate in presence of ethylene dichloride to obtain Metaflumizone.

Stage I

ANNEXURE - XV

103

Flow Chart


chlorosulfonylisocyanate EffluentOrganic Residue

Methylene DichlorideMethanolWaterSodium Hydroxide (48%)

2-amino-N,N'-dimethylbenzamide

4,6-dimethoxy-2-aminopyrimidine

PRODUCT : Orthosulfamuron

Description :

Stage-1 : 2-amino-N,N'-dimethylbenzamide is condensed with chlorosulfonyl isocyanate and 4,6-dimethoxy-2-aminopyrimidine in presence of DCM at room temperature to obtain Orthosulfamuron.

Stage I

ANNEXURE - XV

104

Flow Chart

Effluent

Sodium Hydroxide (26%)Water

Stage-1 Stage-2 MassTrimethylamine(30%)

Stage-2 Mass(Q-Salt) Sol.Recoveryn-Propyl Bromide EffluentWater Organic Residue

Profenofos

4-Bromo-2-Chloro Phenol (BCP)Diethyl Thiophosphoryl Chloride (DTC)

PRODUCT : Profenofos

Description :

Stage-1 : 4-Bromo-2-Chloro Phenol is reacted with diethyl thio phosphoryl Chloride and Sodium Hydroxide toget Triester (stage-1) compound.

Stage-2 : tage1 Compound is reacted with Trimethylamine to get (Stage-2) Compund.

Stage-3 : Stage 2 compound is reacted with Propyl Bromide and to get Profenofos.

Stage I

Stage II

Stage III

ANNEXURE - XV

105

Flow Chart



Process Emissions

2-methyl propionyl chlorideSodium Hydride [NaH] (60%)TetrahydrafuronMethanolWater

N-[4-(1,1,1,3,3,3-hexafluoro-2-methoxypropan-2-yl)-3-(2-methylpropyl)phenyl]-1,3,5-

trimethyl-N-(2-methylpropanoyl)-1H-pyrazole-

4-carboxamide

Pyflubumide

PRODUCT : Pyflubumide

Description :

Stage-1 : N-[4-(1,1,1,3,3,3-hexafluoro-2-methoxypropan-2yl)-3-(2-methylpropyl)phenyl]-1,3,5-trimethyl-1H-pyrazole-4-carboxamide is reacted with 2-methyl propionyl chloride inpresence of alkali sodium metal at room temperature to obtain N-[4-(1,1,1,3,3,3-hexafluoro-2-methoxypropan-2-yl)-3-(2-methylpropyl)phenyl]-1,3,5-trimethyl-N-(2-methylpropanoyl)-1H-pyrazole-4-carboxamide.

Stage I

ANNEXURE - XV

106

Flow Chart

Stage-1 intermediate

Hydrochloric acid(32%)Methanol

Stage-1 intermediate Sol.Recovery3-cyanopyridine Evaporation LossSodium hydroxide (48%) EffluentRaney Nickel Organic ResidueHydrogen Process EmissionsWater

Description :

Stage-1 : This process is involving de acetylation of the reaction of 4-Acetylamino-6-methyl-3-oxo-2,3,4,5-tetrahydro-1,2,4-triazine with Hydrochloric acid to get stage 1 intermediate.

Stage-2 : Then stage 2 intermediate is reacted with 3-Cyano Pyridine in methanol solvent under hydrogenationto give the product. The product then cooled and filtered to get pure Pymetrozine technical.

4-Acetylamino-6-methyl-3-oxo-2,3,4,5-tetrahydro-1,2,4-triazine

Pymetrozine

PRODUCT : Pymetrozine

Stage I

Stage II

ANNEXURE - XV

107

Flow Chart



3-[(3-hydroxy-4-chloro-5-fluoro)phenyl]-4-chloro-5-difluoromethoxy-1-methyl pyrazole

Pyraflufen-ethyl

PRODUCT : Pyraflufen-ethyl

Description :

Stage-1 : 3-[(3-hydroxy-4-chloro-5-fluoro)phenyl]-4-chloro-5-difluoromethoxy-1-methyl pyrazole is reacted withethylchloroacetate in presence of alkali potassium salt and dimethyl formamide as solvent to obtain Pyraflufen-ethyl.

Stage I

ANNEXURE - XV

108

Flow Chart



Process Emissions

Dimethylamine hydrochlorideEthylene dichlorideMethanolWaterSodium Carbonate

1-(2,6-dichloro-α,α,α-trifluoro-p-tolyl)-5-[(2-pyrazinylmethyl)amino]-1H-pyrazole-3-carbonitrile Monofluoromethyl sulfenyl chloride

Pyrafluprole

PRODUCT : Pyrafluprole

Description :

Stage-1 : 1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-5-[(2-pyrazinylmethyl)amino]-1H-pyrazole-3-carbonitrile isreacted with Monofluoromethyl sulfenyl chloride in presence of a catalyst and Ethylene dichloride as solvent toobtain Pyrafluprole.

Stage I

ANNEXURE - XV

109

Flow Chart


Acetic anhydride EffluentSodium hydride (60%), NaH Organic ResidueDimethylformamide Process EmissionsEthylacetateMethanolWater

3-[(3-pyridylmethyl)amino]-3,4-dihydro-6-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl] quinazolin-2-one

Pyrifluquinazone

PRODUCT : Pyrifluquinazone

Description :

Stage-1 : 3-[(3-pyridylmethyl)amino]-3,4-dihydro-6-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl] quinazolin-2-oneis reaction with acetic anhydride in presence of a strong alkali metal in dimethyl formamide as a solvent to obtainPyrifluquinazon.

Stage I

ANNEXURE - XV

110

Flow Chart


Difluoromethyl sulfenyl chloride EffluentDimethylamine hydrochloride Organic ResidueEthylene dichloride Process EmissionsMethanolWaterSodium carbonate

1-(2,6-dichloro-α,α,α-trifluoro-p-tolyl)-5-[(2-pyridylmethyl)amino]-1H-pyrazole-3-carbonitrile

Pyriprole

PRODUCT : Pyriprole

Description :

Stage-1 : 1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-5-[(2-pyrazinylmethyl)amino]-1H-pyrazole-3-carbonitrile isreacted with Monofluoromethyl sulfenyl chloride in presence of a catalyst and Ethylene dichloride as solvent toobtain Pyrafluprole.

Stage I

ANNEXURE - XV

111

Flow Chart

2,6-dichloro quinoxaline Sol.RecoveryHydroquinone Evaporation LossSodium hydroxide (98%) EffluentDimethyl formamideWater

6-chloro quinoxaline Sol.RecoveryEthyl-2-chloropropionate Evaporation LossPotassium carbonate EffluentDimethyl formamide Organic ResidueWaterMethanol

Quizalofop Ethyl

PRODUCT : Quizalofop Ethyl

Description :

Stage-1 : Stage 1 involves the reaction of 2,6-dichloro quinoxaline with hydroquionone in presence of sodiumhydroxide in a solvent dimethyl formamide to get the Stage-1 intermediate.

Stage-2 : Stage-1 intermediate reacts with ethyl 2-chloro propionate in stage-2 to give Quizalofop ethyltechnical.

Stage I

Stage II

ANNEXURE - XV

112

Flow Chart

Bromotrifluoromethane (gas) Sol.RecoverySodium phosphate Evaporation LossSodiumdithionite (85%) EffluentSodium hydroxide (98%)AcetonitrileWater

Stage-1 : Sodiumdithionite, Sodium phosphate and Bromotrifluoromethane reacted in the presence of sodiumhydroxide under pressure conditions in Acetonitrile and Water as mixture solvent to give the product of Sodiumtrifluoromethane sulfinate.

Sodium Trifluoromethane Sulfinate

PRODUCT : Sodium Trifluoromethane Sulfinate

Description :

Stage I

ANNEXURE - XV

113

Flow Chart

Methyl ethyl ketoneDiethyl oxalate


Toluene EffluentHydrazine hydrate (80%) Organic ResidueDimethyl sulphate Process EmissionsSodium hydroxide(30%)Sulfuryl chlorideDichloromethaneWater

EMCA Thionyl chloride Sol.RecoveryToluene Evaporation Loss4-tertiarybutyl benzyl amine EffluentMethanol Organic ResidueSodium Hydroxide (25%) Process EmissionsWater

Tolfenpyrad

Sodium ethoxide (21%) in ethanol

PRODUCT : Tolfenpyrad

Description :

Stage-1 : Intermediate EMCA: Methylethyl ketone and Diethyl oxalate reacts to give an intermediate whichreacts with hydrazine to get cyclized intermediate. It is reacted with dimethyl sulphate and sodium hydroxide togive an intermediate which on reaction with sulfuryl chloride gives the intermediate EMCA [4-chloro-3-ethyl-1-methyl-1H-pyrazole-5-carboxylic acid].

Stage-2 : 4-chloro-3-ethyl-1-methyl-1H-pyrazole-5-carboxylic acid [EMCA] is reacted with thionyl chloride toform acid chloride and further reacted with 4-tertiarybutyl benzyl amine in presence of sodium hydroxide basein Toluene solvent to obtain Tebufenpyrad.

Stage I

Stage II

ANNEXURE - XV

114

Flow Chart

Methomyl Oxime Sol.RecoveryN-methyl carbamoyl chloride Evaporation LossDichloromethane EffluentCaustic Lye (48%) Organic ResidueWater

Sol.RecoveryStage -1 (Methomyl) Evaporation LossSulfur dichloride EffluentPyridine Organic ResidueMixed XyleneMethanolWater

Stage-2 : This intermediate and Sulfur dichloride reacted in the presence of Pyridine and mixed Xylene solventto give Thiodicarb. . After the reaction, water added to dissolve pyridine hydrochloride and the solid materialfiltered. The wet cake is crystallized in methanol to get Thiodicarb technical. Filtrate is basified to get pyridineand recycled.

Thiodicarb

PRODUCT : Thiodicarb

Description :

Stage-1 : In stage 1, methomyl oxime and N-methyl carbamoyl chloride reacted to give Methomyl asintermediate.

Stage I

Stage II

ANNEXURE - XV

115

Flow Chart

Ethyl acetateHydrazine hydrate (82%) Stage-1 Mass

Stage-1 Mass Sol.RecoveryMethylacetoacetate Evaporation LossDichloromethane Effluent

Stage-2 Mass Sol.RecoveryThionyl chloride Evaporation LossSodium Hydroxide (48 %) EffluentWater Process Emissions

Stage-3 Sol.Recovery3-chloro-4-toluidine Evaporation Loss


Hydrochloric acid (32%)Water

Tiadinil

Stage-1 : Stage 1 involves reaction of ethylacetate and hydrazine hydrate to prepare intermediate 1

Stage-2 : This intermediate reacts with methyl acetoacetate to give intermediate 2 in stage 2.

Stage-3 : Stage 3 involves reaction of thionyl chloride with intermediate 2 to yield the intermediate 3.

Stage-4 : Finally intermediate 3 reacts with 3-chloro-4-toluidine to give Tiadinil technical.

PRODUCT : Tiadinil

Description :

Sodium methoxide (28% in Methanol)

Stage I

Stage II

Stage III

Stage IV

ANNEXURE - XV

116

Flow Chart

Methyl ethyl ketoneDiethyl oxalateSodium ethoxide (21%) in ethanol Sol.RecoveryToluene Evaporation LossHydrazine hydrate (80%) EffluentDimethyl sulphate Organic ResidueSodium hydroxide(30%) Process EmissionsSulfuryl chlorideDichloromethaneWater

p-Cresolp-Chlorobenzonitrile Sol.RecoverySodium hydroxide (48%) Evaporation LossToluene EffluentHydrogen gas Process EmissionsPalladium carbonMethanolWater

EMCA Sol.RecoveryThionyl chloride Evaporation LossToluene EffluentTOBA crude Organic ResidueMethanol Process EmissionsSodium Hydroxide (25%)Water

Tolfenpyrad

PRODUCT : Tolfenpyrad

Description :

Stage-1 : Intermediate EMCA: Methylethyl ketone and Diethyl oxalate reacts to give an intermediate whichreacts with hydrazine to get cyclised intermediate. It is reacted with dimethyl sulphate and sodium hydroxide togive an intermediate which on reaction with sulfuryl chloride gives the intermediate EMCA [4-chloro-3-ethyl-1-methyl-1H-pyrazole-5-carboxylic acid].Stage-2 : Intermdiate TOBA: This involves the reaction of p-Cresol and p-chlorobenzonitrile in presence of a base to give an intermediatewhich on hydrogenation gives the intermediate TOBA [4-(p-tolyloxy) benzylamine].

Stage-3 : Tolfenpyrad: EMCA reacts with thionyl chloride in stage-1 and the intermediate further reacts withTOBA to give the product Tolfenpyrad.

Stage I

Stage II

Stage III

ANNEXURE - XV

117

Flow Chart


Formic Acid EffluentWater

Tricyclazole

PRODUCT : Tricyclazole

Description :

Stage-1 : 2-Hydrazine-4-methyl Benzothiazole and Formic acid will be charged in reactor and mixed to getTricyclazole. Recovered Formic Acid to be reused and aqueous layer is sent to effluent treatment plant forfurther treatment purpose.

2-Hydrazino-4-Methyl Benzothiazole

Stage I

ANNEXURE - XV

118

Flow Chart

Sol.RecoveryMethane sulfonylchloride Evaporation Loss3-Picoline EffluentAcetonitrile Organic ResidueDichloromethaneMethanolSodium Hydroxide(30%)Water

Stage-1 : Chlorantraniliprole is prepared by reaction of 3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid with 2-methyl-4-chloro-N-methylcarbamoyl)aniline in presence of methanesulfonyl chloride andpicoline in acetonitrile.

PRODUCT : Chlorantraniliprole

Description :

Chlorantraniliprole

3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid2-methyl-4-chloro-N-methylcarbamoyl)aniline

Stage I

ANNEXURE - XV

119

Flow Chart



PRODUCT : Dimethoate

Description :

Dimethoate

O,O-dimethyl S-[methylaceto] dithiophosphate

Stage-1 : O,O-dimethyl S-[methylaceto] dithiophosphate is reacted with Monomethyl Amine solution (40%) toget Dimethoate. Ethylene dichloride is used to extract the product and distilled to get Dimethoate technical.

Stage I

ANNEXURE - XV

120

Flow Chart

Diethyl Thiophosphoric Acid Sol.RecoverySodium Hydroxide (35%) Evaporation LossTolueneWater

Stage-1 Mass By-ProductMethylene Dibromide EffluentWater Organic Residue

Description :

Ethion

Stage-1 : Diethyl Thiophosphoric Acid is neutralized with 35% Sodium Hydroxide to get Sodium DiethylThiophosphoric Acid.

Stage-2 : Sodium Diethyl thiophosphoric Acid is reacted with Methylene Dibromide to get Ethion and Sodiumbromide organic layer contains Ethion and Aqueous layer contains sodium bromide, aqueous layer (sodiumBromide layer) selling as a bi product. Organic layer to be purified.Crude Ethion steam spurging to be done to get pure Ehion, Technical. Recovery organic residue sent toincinerator and aqueous layer is sent to ETP for further treatment.

PRODUCT : Ethion

Stage I

Stage II

ANNEXURE - XV

121

Flow Chart

2,4-Dichloro Valerophenone Sol.RecoveryDimethyl Sulfate Evaporation LossDimethyl Sulfide EffluentPotassium HydroxideEthylacetateWater

Stage-1 Mass Sol.Recovery1,2,4-Triazole Evaporation LossDimethyl Formamide EffluentPotassium Carbonate Organic ResidueWater

Hexaconazole

Stage-1 : Valerophenone, Dimethyl Sulfide, Dimethyl sulfate and Potassium Hydroxide will be charged in to thereactor and mixed to get 2-Butyl-2-(2,4-dichloro phenyl) oxirane product.

Stage-2 : 2-Butyl-2-(2,4-dichloro phenyl) oxirane, 1,2,4-Trizole, Dimethyl Formamide and water will be chargedinto the reactor and mixed to get final product Hexaconzole. Aqueous layer is sent to effluent treatment plant forfurther treatment purpose.

PRODUCT : HEXACONAZOLE

Description :

Stage I

Stage II

ANNEXURE - XV

122

Flow Chart


Pyridine EffluentAcetonitrile Organic ResidueDichloromethaneSodium Hydroxide (30%)MethanolWater

2-amino-5,8-dimethoxy-[1,2,4]triazolo[1,5-c] pyrimidine

2-(2,2-Difluoroethoxy)-6-(trifluoromethyl) benzene-1-sulfonylchloride

Stage-1 : Penoxsulam is prepared by reaction of 2-(2,2-Difluoroethoxy)-6-(trifluoromethyl) benzene-1-sulfonylchloride with 2-amino-5,8-dimethoxy-[1,2,4]triazolo[1,5-c]pyrimidine in presence of dry pyridine andacetonitrile.

PRODUCT : Penoxsulam

Description :

Stage I

ANNEXURE - XV

123

Flow Chart

2,6-Diethyl Anilinen-Propoxy Ethylchloride EffluentSodium Hydroxide (25%) Organic ResidueWater

Stage-1 Sol.RecoveryChloro Acetyl Chloride Evaporation LossSodium Bicarbonate EffluentHexane Organic ResidueHydrochloric acid (32%) Process EmissionsWater

Pretilachlor

Stage-1 : 2,6-Diethyl Aniline is reacted with n-Propoxy Ethyl Chloride and Sodium Hydroxide to get (Stage-1)Compound.

Stage-2 : Stage 1 compound is reacted with Chloro Acetyl Chloride in n-Hexane and quenched tosodiumbicarbonate solution to get the product. The solvent , n-Hexane is distilled to Pretilachlor technical.

PRODUCT : Pretilachlor

Description :

Stage I

Stage II

ANNEXURE - XV

124

Flow Chart


EffluentC S Lye (30%) Organic ResidueAcetoneHydrochloric acid(32%)Water Inorgainc Solid Waste

PRODUCT : Sulfosulfuron

Description :

Stage-1 : Sulfonamide, carbamate and Acetone are charged to the reactor. Addition of caustic lye solution at<100C gives the product of sulfosulfuron. Then the mass is neutralized with HCl and centrifuged to getSulfosulfuron technical. Acetone is distilled to recover and reused.

Sulfosulfuron

[4,6-Dimethoxy-2-(phenoxycarbonylamino)-pyrimidine]

[2-Ethylsulfonyl imidazo [1,2-a] pyridine-3-sulfonamide]

Stage I

ANNEXURE - XV

125

Flow Chart



Potassium carbonateTolueneMethanolWater

3-methyl-4-nitroiminoperhydro-1,3,5-oxadiazine

2-Chloro-(5-chloromethyl)thiazole

Description :

Stage-1 : 2-Chloro-(5-chloromethyl)thiazole reacts with 3-methyl-4-nitroiminoperhydro-1,3,5-oxadiazine inpresence of base and solvent. After filtration of potassium salts, the solvent is distilled off and the crude mass iscrystallized from methanol to give Thiamethoxam technical.

Thiamethoxam

PRODUCT : Thiamethoxam

Stage I

ANNEXURE - XV

126

BLOCK FLOW DIAGRAM for AZADIRECTIN BIO PESTICIDE

Cold Press Method Water Spent Kernels as fertilizer

Neem Seed Kernels

Neem Oil

Extraction of Azadirectin

Formulation of

Azadirectin (0.1%) as Bio pesticide

Kernels

ANNEXURE - XV

127

Raw Material

Consumption of Raw Material /

Batch of Product

Daily Consumption of

Raw Material

Kg KgAcetic Anhydride = 660 44.0Ammonia (21%) = 938 62.5Dichloromethane = 1000 66.7Dimethyl Sulfate = 127 8.5Ethyl Acetate = 1000 66.7O,O-Dimethyl Phosphoramidothionate = 900 60.0Sulfuric Acid = 320 21.3

Raw Material


Batch of Product


Raw Material

Kg Kg2-Chloro-5-Chloromethyl Pyridine = 800 133.3Ethyl-N-Cyano Acetaimidate = 600 100.0Monomethyl Amine (30% in Methanol) = 2000 333.3Sodium Hydroxide (98%) = 202 33.7

Raw Material


Batch of Product


Raw Material

Kg Kg2-Cyanophenol = 360 36.0Dimethyl formamide = 2120 212.0Methanol = 2000 200.0

Potassium Bisulphate = 500 50.0Potassium Carbonate = 225 22.5Toluene = 2650 265.0

Methyl 2-[2-(6-chloropyrimidin-4-yloxy)phenyl]-3,3- dimethoxy propanoate = 1056 200.0

PRODUCT : AcephateLIST OF RAW MATERIALS

PRODUCT : AcetamipridLIST OF RAW MATERIALS

PRODUCT : AzoxystrobinLIST OF RAW MATERIALS

ANNEXURE - XVI

128

Raw Material


Batch of Product


Raw Material

Kg Kg2,6-dichloro-4-trifluoromethyl aniline = 800 266.7Ammonia (25%) = 710 236.7Ethyl 2,3-dicyano propionate = 550 183.3Ethylene dichloride = 2400 800.0Hydrochloric acid (32%) = 875 291.7Methanol = 1600 533.3Sodium Nitrite = 264 88.0

Raw Material


Batch of Product


Raw Material

Kg Kg1,3-propanediol = 310 206.74,6-Dihydroxypyrimidine = 452 301.34-Trifluromethyl benzyl alcohol = 710 473.3Catalyst = 20 13.3Dimethyl formamide = 300 200.0Hydrogen = 10 6.7Methanol = 1000 666.7Phosphrous oxychloride = 1860 1240.0Sodium carbonate (25%) = 1536 1024.0Toluene = 2800 1866.7

PRODUCT : 5-Amino-3-cyano-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]pyrazole (Phenyl Pyrazole)

LIST OF RAW MATERIALS

PRODUCT : BenzpyrimoxanLIST OF RAW MATERIALS

ANNEXURE - XVI

129

Raw Material


Batch of Product


Raw Material

Kg Kg2-methyl-3-biphenyl methyl alcohol (BPA) = 544 90.7Dimethylformamide = 1360 226.7Lamda Cyhalothric acid (MTH Acid) = 666 111.0Methanol = 1500 250.0n-Hexane = 2000 333.3Potassium carbonate = 400 66.7Tetrabutyl ammonium bromide = 32 5.3Thionyl chloride = 330 55.0

Raw Material


Batch of Product


Raw Material

Kg Kg2,6-dihydroxy benzoic acid = 380 12.7

4,6-dimethoxy-2-methyl sulfonyl pyrimidine = 1150 38.3Ethyl acetate = 500 16.7n-Butanol = 5000 166.7Sodium hydroxide (48%) = 640 21.3Tetrabutyl ammonium bromide = 20 0.7Toluene = 1500 50.0

PRODUCT : BifenthrinLIST OF RAW MATERIALS

PRODUCT : Bispyribac SodiumLIST OF RAW MATERIALS

ANNEXURE - XVI

130

Raw Material


Batch of Product


Raw Material

Kg KgAmmonium bicarbonate = 542 361.3Ethylene dichloride = 2100 1400.0Methanol = 2000 1333.3N-Chloro methyl N-phenyl Carbamoyl chlori = 700 466.7N-Tertiary butyl N-isopropyl thio urea = 597 398.0

Raw Material


Batch of Product


Raw Material

Kg KgAllyl Chloride = 316 15.8Dimethylamine (40% in water) = 466 23.3Ethylene dichloride = 1270 63.5Hydrogen chloride gas = 150 7.5Methanol = 1269 63.5Sodium Hydroxide (48%) = 350 17.5Sodium thiocyanate = 670 33.5Sulfuryl Chloride = 558 27.9Toluene = 1270 63.5

PRODUCT : BuprofezinLIST OF RAW MATERIALS

PRODUCT : Cartap HydrochlorideLIST OF RAW MATERIALS

ANNEXURE - XVI

131

Raw Material


Batch of Product


Raw Material

Kg KgEthylene dichloride = 1700 113.3Diethoxy thiophosphoryl chloride = 598 39.9Caustic lye (48%) = 582 38.82,3,5,6-Tetrachloro Pyridine = 688 45.9

Raw Material


Batch of Product


Raw Material

Kg Kg5-Chloro-2,3-difluoropyridine = 480 40.0Carbon = 20 1.7Methanol = 1500 125.0Potassium carbonate = 816 68.0Propargyl chloride = 245 20.4R-(+)-2-[4-5(-chloro-3-fluoropyridin-2-yloxy)phenoxy]propionic acid = 567 47.3

Toluene = 1700 141.7

PRODUCT : ChlorpyrifosLIST OF RAW MATERIALS

PRODUCT : Clodinafop PropargylLIST OF RAW MATERIALS

ANNEXURE - XVI

132

Raw Material


Batch of Product


Raw Material

Kg KgToluene = 1200 300Potassium Carbonate = 440 110n-Hexane = 900 225Methanol = 1500 375Chloro acetic acid = 300 758-Hydroxy-5-chloroquinoline = 546 1372-Heptanol = 353 88

Raw Material


Batch of Product


Raw Material

Kg KgD-methyl lactate = 675 112.5Hydrochloric acid(33%) = 1427 237.8Hydroquinone = 714 119.0Methylisobutyl ketone = 1000 166.7Sodium hydroxide (48%) = 2168 361.3Sulfuric acid = 650 108.3Thionyl chloride = 772 128.7

PRODUCT : Cloquintocet MexylLIST OF RAW MATERIALS

PRODUCT : (R) 2-(4-Hydroxyphenoxy) Propionic Acid [DHPPA]

LIST OF RAW MATERIALS

ANNEXURE - XVI

133

Raw Material


Batch of Product


Raw Material

Kg Kgt-butyl amine = 210 210.0O-xylene = 1730 1730.0Methanol = 2000 2000.0Dichloromethane = 300 300.02,6-diisopropyl-4-phenoxy phenyl thiourea = 935 935.0

Raw Material


Batch of Product


Raw Material

Kg Kg5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-3-(ethylthio)-1H-pyrazole-4-carbonitrile (Sulfide)

= 1050 175.0

Dichloromethane = 2100 350.0Hydrogen Peroxide (30%) = 375 62.5Methanol = 2000 333.3

PRODUCT : DiafenthiuronLIST OF RAW MATERIALS

PRODUCT : EthiproleLIST OF RAW MATERIALS

ANNEXURE - XVI

134

Raw Material


Batch of Product


Raw Material

Kg Kg2,4-Dichlorophenol = 580 96.72-amino-2,3-dimethyl butyronitrile = 400 66.7D-Methyl Lactate = 370 61.7Hydrochloric acid(32%) = 385 64.2Methanol = 1200 200.0Sodium Hydroxide (48%) = 320 53.3Sodium methoxide (28%) in Methanol = 650 108.3Thionyl chloride = 423 70.5Toluene = 1000 166.7

Raw Material


Batch of Product


Raw Material

Kg KgToluene = 1920 320.0t-butyl 4-(bromomethyl)benzoate = 825 137.5Sodium Hydroxide (48%) = 256 42.7Pyrazole 1,3-dimethyl-5-chloro-4-carbaldehyde = 480 80.0

Potassium hydroxide (50%) = 680 113.3Phenol = 285 47.5Methanol = 2000 333.3Hydroxylamine hydrochloride = 215 35.8Cuprous chloride [CuCl] = 24 4.0

PRODUCT : FenoxanilLIST OF RAW MATERIALS

PRODUCT : FenpyroximateLIST OF RAW MATERIALS

ANNEXURE - XVI

135

Raw Material


Batch of Product


Raw Material

Kg Kg5-Amino-3-cyano-1-(2,6-dichloro-4-trifluoromethylphenyl)pyrazole = 929 464.5

Acetonitrile = 2085 1042.5Dimethyl amine (40%) = 550 275.0Ethylene dichloride = 2800 1400.0P-toluene sulfonic acid mono hydrate = 550 275.0Sodium trifluoromethanesulfinate (65%) = 695 347.5Thionyl chloride = 345 172.5

Raw Material


Batch of Product


Raw Material

Kg Kg2-methyl-[4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)- aniline = 490 163.3

2-methyl-1-methylthio propan-2-amine = 215 71.76-iodo ortho phthaloyl chloride = 585 195.0Ethylene Dichloride = 1755 585.0Hydrogen Peroxide (30%) = 410 136.7Methanol = 2000 666.7Sodium Bicarbonate = 300 100.0

PRODUCT : FipronilLIST OF RAW MATERIALS

PRODUCT : FlubendiamideLIST OF RAW MATERIALS

ANNEXURE - XVI

136

Raw Material


Batch of Product


Raw Material

Kg Kg2-Trifluromethyl benzoic acid = 692 922.73-Isopropoxy aniline = 551 734.7Methanol = 1500 2000.0Sodium carbonate = 193 257.3Thionyl chloride = 434 578.7Toluene = 1385 1846.7

Raw Material


Batch of Product


Raw Material

Kg Kg2-Chloro-5-Chloro Methyl Pyridine = 661 1322.0Dimethyl formamide = 1980 3960.0Methanol = 2000 4000.0N-Nitro Imino Imidazolidine = 636 1272.0Potassium Carbonate = 570 1140.0

PRODUCT : FlutolanilLIST OF RAW MATERIALS

PRODUCT : ImidaclopridLIST OF RAW MATERIALS

ANNEXURE - XVI

137

Raw Material


Batch of Product


Raw Material

Kg KgHydrogen = 4 0.4Methyl (chlorocarbonyl)- [4- = 595 59.5Methyl acetate = 1576 157.6n-Hexane = 1500 150.0Pd/C catalyst = 10 1.0Phenyl methyl ( 5-chloro-2,3-dihydro-2-hydroxy-2-(methoxycarbonyl)-1H-inden-1-ylidne hydrazine carboxylate

= 80080.0

Silica = 260 26.0Sodium citrate solution = 1017 101.7

Raw Material


Batch of Product


Raw Material

Kg KgCarbondisulfide = 284 947Diisopropyl malonate = 695 2317Ethylene dichloride = 2550 8500Ethylene dichloride as reactant = 370 1233Hydrochlorid acid (32%) = 50 167Methanol = 1200 4000Sodium Hydroxide (48%) = 650 2167

PRODUCT : IndoxacarbLIST OF RAW MATERIALS

PRODUCT : IsoprothiolaneLIST OF RAW MATERIALS

ANNEXURE - XVI

138

Raw Material


Batch of Product


Raw Material

Kg KgAcetic acid = 550 1650.0Acetic acid as reactant = 452 1356.0Dimethyl formamide = 2000 6000.0Hydrochloric acid in Methanol (25%) = 1100 3300.0Isopropyl bromide = 930 2790.0Meta amino phenol = 820 2460.0Potassium carbonate = 1038 3114.0Sodium Hydroxide = 602 1806.0

Raw Material


Batch of Product


Raw Material

Kg Kg4-cyanobenzyl-3-trifluoromethyl-phenylketone hydrazone = 665 22.2

4-trifluoromethoxyphenyl isocyanate = 450 15.0Ethylene dichloride = 1330 44.3Methanol = 1200 40.0Triethylamine = 10 0.3

PRODUCT : Metaisopropoxy AnilineLIST OF RAW MATERIALS

PRODUCT : MetaflumizoneLIST OF RAW MATERIALS

ANNEXURE - XVI

139

Raw Material


Batch of Product


Raw Material

Kg Kg2-amino-N,N'-dimethylbenzamide = 430 28.74,6-dimethoxy-2-aminopyrimidine = 406 27.1chlorosulfonylisocyanate = 380 25.3Methanol = 1500 100.0Methylene Dichloride = 1200 80.0Sodium Hydroxide (48%) = 225 15.0

Raw Material


Batch of Product


Raw Material

Kg Kg4-Bromo-2-Chloro Phenol (BCP) = 598 99.7Diethyl Thiophosphoryl Chloride (DTC) = 543 90.5n-Propyl Bromide = 380 63.3Sodium Hydroxide (26%) = 462 77.0Trimethylamine(30%) = 567 94.5

PRODUCT : OrthosulfamuronLIST OF RAW MATERIALS

PRODUCT : ProfenofosLIST OF RAW MATERIALS

ANNEXURE - XVI

140

Raw Material


Batch of Product


Raw Material

Kg KgTetrahydrafuron = 1932 96.6Sodium Hydride [NaH] (60%) = 83 4.2N-[4-(1,1,1,3,3,3-hexafluoro-2-methoxypropan-2-yl)-3-(2-methylpropyl)phenyl]-1,3,5-trimethyl-N-(2-methylpropanoyl)-1H-pyrazole-4-carboxamide

= 966 48.3

Methanol = 1500 75.02-methyl propionyl chloride = 230 11.5

Raw Material


Batch of Product


Raw Material

Kg Kg3-cyanopyridine = 591 197.04-Acetylamino-6-methyl-3-oxo-2,3,4,5- = 967 322.3Hydrochloric acid(32%) = 1050 350.0Hydrogen = 15 5.0Methanol = 2901 967.0Raney Nickel = 10 3.3Sodium hydroxide (48%) = 767 255.7

PRODUCT : PyflubumideLIST OF RAW MATERIALS

PRODUCT : PymetrozineLIST OF RAW MATERIALS

ANNEXURE - XVI

141

Raw Material


Batch of Product


Raw Material

Kg Kg3-[(3-hydroxy-4-chloro-5-fluoro)phenyl]-4-chloro-5-difluoromethoxy-1-methyl pyrazole

= 880 58.7

Dimethylformamide = 1760 117.3Ethylchloroacetate = 340 22.7Methanol = 1500 100.0Potassium carbonate = 400 26.7

Raw Material


Batch of Product


Raw Material

Kg Kg1-(2,6-dichloro-α,α,α-trifluoro-p-tolyl)-5-[(2-pyrazinylmethyl)amino]-1H-pyrazole-3-carbonitrile

= 960 64.0

Dimethylamine hydrochloride = 195 13.0Ethylene dichloride = 2800 186.7Methanol = 1200 80.0Monofluoromethyl sulfenyl chloride = 240 16.0Sodium Carbonate = 125 8.3

PRODUCT : Pyraflufen-EthylLIST OF RAW MATERIALS

PRODUCT : PyrafluproleLIST OF RAW MATERIALS

ANNEXURE - XVI

142

Raw Material


Batch of Product


Raw Material

Kg Kg3-[(3-pyridylmethyl)amino]-3,4-dihydro-6-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl] quinazolin-2-one

= 1011 67.4

Acetic anhydride = 243 16.2Dimethylformamide = 2022 134.8Ethylacetate = 2100 140.0Methanol = 1500 100.0Sodium hydride (60%), NaH = 95 6.3

Raw Material


Batch of Product


Raw Material

Kg Kg1-(2,6-dichloro-α,α,α-trifluoro-p-tolyl)-5-[(2-pyridylmethyl)amino]-1H-pyrazole-3-carbonitrile

= 927 30.9

Difluoromethyl sulfenyl chloride = 275 9.2Dimethylamine hydrochloride = 195 6.5Ethylene dichloride = 2800 93.3Methanol = 1200 40.0Sodium carbonate = 125 4.2

PRODUCT : PyrifluquinazoneLIST OF RAW MATERIALS

PRODUCT : PyriproleLIST OF RAW MATERIALS

ANNEXURE - XVI

143

Raw Material


Batch of Product


Raw Material

Kg Kg2,6-dichloro quinoxaline = 630 21.06-chloro quinoxaline = 862 28.7Dimethyl formamide = 1250 41.7Dimethyl formamide = 2300 76.7Ethyl-2-chloropropionate = 432 14.4Hydroquinone = 350 11.7Methanol = 1200 40.0Potassium carbonate = 470 15.7Sodium hydroxide (98%) = 154 5.1

Raw Material


Batch of Product


Raw Material

Kg KgAcetonitrile = 1200 600.0Bromotrifluoromethane (gas) = 960 480.0Sodium hydroxide (98%) = 265 132.5Sodium phosphate = 375 187.5Sodiumdithionite (85%) = 1320 660.0

PRODUCT : Quizalofop EthylLIST OF RAW MATERIALS

PRODUCT : Sodium Trifluoromethane SulfinateLIST OF RAW MATERIALS

ANNEXURE - XVI

144

Raw Material


Batch of Product


Raw Material

Kg Kg4-tertiarybutyl benzyl amine = 545 36.3Dichloromethane = 844 56.3Diethyl oxalate = 620 41.3Dimethyl sulphate = 525 35.0Hydrazine hydrate (80%) = 248 16.5Methanol = 1500 100.0Methyl ethyl ketone = 300 20.0Sodium ethoxide (21%) in ethanol = 276 18.4Sodium Hydroxide (25%) = 540 36.0Sodium hydroxide(30%) = 1110 74.0Sulfuryl chloride = 570 38.0Thionyl chloride = 396 26.4Toluene = 2126 141.7

Raw Material


Batch of Product


Raw Material

Kg KgCaustic Lye (48%) = 1125 812.6Dichloromethane = 1450 1047.4Methanol = 2000 1444.7Methomyl Oxime = 725 523.7Mixed Xylene = 3100 2239.3N-methyl carbamoyl chloride = 660 476.7Pyridine = 500 361.2Sulfur dichloride = 330 238.4

PRODUCT : TebufenpyradLIST OF RAW MATERIALS

PRODUCT : ThiodicarbLIST OF RAW MATERIALS

ANNEXURE - XVI

145

Raw Material


Batch of Product


Raw Material

Kg Kg3-chloro-4-toluidine = 616 410.7Dichloromethane = 2556 1704.0Ethyl acetate = 394 262.7Hydrazine hydrate (82%) = 275 183.3Hydrochloric acid (32%) = 547 364.7Methylacetoacetate = 518 345.3Sodium Hydroxide (48 %) = 585 390.0Sodium methoxide (28% in Methanol) = 926 617.3Thionyl chloride = 1060 706.7

Raw Material


Batch of Product


Raw Material

Kg KgDichloromethane = 750 75.0Diethyl oxalate = 550 55.0Dimethyl sulphate = 475 47.5Hydrazine hydrate (80%) = 220 22.0Hydrogen gas = 14 1.4Methanol = 2500 250.0Methyl ethyl ketone = 270 27.0Palladium carbon = 10 1.0p-Chlorobenzonitrile = 461 46.1p-Cresol = 362 36.2Sodium ethoxide (21%) in ethanol = 245 24.5Sodium Hydroxide (25%) = 550 55.0Sodium hydroxide (48%) = 335 33.5Sodium hydroxide(30%) = 1000 100.0Sulfuryl chloride = 507 50.7Thionyl chloride = 352 35.2TOBA crude = 713 71.3Toluene = 2750 275.0

PRODUCT : TiadinilLIST OF RAW MATERIALS

PRODUCT : TolfenpyradLIST OF RAW MATERIALS

ANNEXURE - XVI

146

Raw Material


Batch of Product


Raw Material

Kg Kg2-Hydrazino-4-Methyl Benzothiazole = 1000 1166.7Formic Acid = 2400 2800.0

Raw Material


Batch of Product


Raw Material

Kg Kg2-methyl-4-chloro-N- = 460 76.73-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid = 700 116.7

3-Picoline = 215 35.8Acetonitrile = 1400 233.3Dichloromethane = 1000 166.7Methane sulfonylchloride = 263 43.8Methanol = 1200 200.0Sodium Hydroxide(30%) = 615 102.5

PRODUCT : TricyclazoleLIST OF RAW MATERIALS

PRODUCT : ChlorantraniliproleLIST OF RAW MATERIALS

ANNEXURE - XVI

147

Raw Material


Batch of Product


Raw Material

Kg KgEthylene Dichloride = 1000 33.3Methyl Amine (40%) = 376 12.5O,O-dimethyl S-[methylaceto] dithiophosphate = 1116 37.2

Raw Material


Batch of Product


Raw Material

Kg KgDiethyl Thiophosphoric Acid = 1073 35.8Methylene Dibromide = 502 16.7Sodium Hydroxide (35%) = 660 22.0Toluene = 700 23.3

Raw Material


Batch of Product


Raw Material

Kg Kg1,2,4-Triazole = 246 8.22,4-Dichloro Valerophenone = 825 27.5Dimethyl Formamide = 1400 46.7Dimethyl Sulfate = 1050 35.0Ethylacetate = 1000 33.3Potassium Carbonate = 83 2.8Potassium Hydroxide = 220 7.3

PRODUCT : DimethoateLIST OF RAW MATERIALS

PRODUCT : EthionLIST OF RAW MATERIALS

PRODUCT : HEXACONAZOLELIST OF RAW MATERIALS

ANNEXURE - XVI

148

Raw Material


Batch of Product


Raw Material

Kg Kg2-(2,2-Difluoroethoxy)-6-(trifluoromethyl) benzene-1-sulfonylchloride = 750 50

2-amino-5,8-dimethoxy-[1,2,4]triazolo[1,5-c] pyrimidine = 450 30

Acetonitrile = 1500 100Dichloromethane = 1000 67Methanol = 1200 80Pyridine = 182 12Sodium Hydroxide (30%) = 308 21

Raw Material


Batch of Product


Raw Material

Kg Kg2,6-Diethyl Aniline = 560 186.7Chloro Acetyl Chloride = 390 130.0Hexane = 1000 333.3Hydrochloric acid (32%) = 375 125.0n-Propoxy Ethylchloride = 460 153.3Sodium Bicarbonate = 290 96.7Sodium Hydroxide (25%) = 600 200.0

PRODUCT : PenoxsulamLIST OF RAW MATERIALS

PRODUCT : PretilachlorLIST OF RAW MATERIALS

ANNEXURE - XVI

149

Raw Material


Batch of Product


Raw Material

Kg Kg[2-Ethylsulfonyl imidazo [1,2-a] pyridine-3-sulfonamide] 1 641 21.4

[4,6-Dimethoxy-2-(phenoxycarbonylamino)-pyrimidine] 1 610 20.3

Acetone = 2564 85.5C S Lye (30%) = 300 10.0Hydrochloric acid(32%) = 256 8.5

Raw Material


Batch of Product


Raw Material

Kg Kg2-Chloro-(5-chloromethyl)thiazole = 606 202.03-methyl-4-nitroiminoperhydro-1,3,5-oxadiazine = 577.5 192.5

Methanol = 1250 416.7Potassium carbonate = 497.8 165.9Toluene = 750 250.0

PRODUCT : SulfosulfuronLIST OF RAW MATERIALS

PRODUCT : ThiamethoxamLIST OF RAW MATERIALS

ANNEXURE - XVI

150

LIST OF HAZARDOUS RAW MATERIALS

Raw Material

Acetic acid Acetic AnhydrideAcetoneAcetonitrileAmmonia (25%)Chloro acetic acidChloro Acetyl ChlorideDichloromethaneDiethyl oxalateDimethyl amine (40%)Dimethyl formamideDimethyl SulfateEthyl AcetateEthylene dichlorideFormic Acid Hydrazine hydrate (82%)Hydrochloric acid (32%)Hydrogen chloride gasHydrogen gasHydrogen Peroxide (30%)Isopropyl bromideMethane sulfonylchlorideMethanolMethyl Amine (40%)Methyl ethyl ketoneMethylene DibromideMethylene DichlorideMethylisobutyl ketoneMixed Xylenen-Butanoln-HexaneO-xylenePhenolPhosphrous oxychloridePotassium BisulphatePotassium CarbonatePyridineSodium BicarbonateSodium NitriteSulfuric AcidSulfuryl Chloridet-butyl amineTetrahydrafuronThionyl chlorideTolueneTriethylamine

ANNEXURE - XVII

151

ANNEXURE - XVIII

152

Effluent Treatment Flow Scheme - ZLD

ANNEXURE - XIX

153

Schematic flow Sheet for EIA Procedure

Time schedule for obtaining the EC from MOEF

Submission of application by proponent (Form 1, Pre-feasilibility report and Draft Terms of Reference)

Scrutiny by EAC

Scoping an communication of Terms of Reference for EIA Studies to the Proponent for EIA preparation

Submission of proceedings of the public hearing by the SPCB / PCC to EAC

Conducting public hearing by SPCB / PCC or any other public Agency / authority engaged by regulatory authority

Submission of Draft EIA / Summary EIA / Application for Public consultation

Appraisal by EAC

Submission of final EIA by the proponent after improving EIA / EMP

Decision of MoEF

Decision of MoEF

Specific Concerns

Yes NO Rejection

Issuing clearance to project proponent

60 days

45 days

60 days

Scop

ing

Publ

ic C

onsu

ltanc

y De

cisio

n M

akin

g Ap

prai

sal

Reservation on the proposal conveyed to EAC

EAC views on reservations sent to MoEF

45 days

60 days

30 days

Category A Project

Preparation of FORM I Application & Prefeasibility report

30 days on obtaining information from industry

as per check list

Preparation of Draft EIA report 120 days minimum other than monsoon period of 120 days

30 days for preparation of Final REIA Maximum

ANNEXURE - XX

154

Environmental Baseline Monitoring (To Establish quality of the

Environment)

Application of Impact Prediction Tools (Quantitative Significance Analysis)

Identification of Likely Impacts (Quantitative Significance Analysis

(Ref: Impact Matrix)

EIA Team

Social Impact Assessment

Risk Assessment

Project Features (Pre-feasibility Report,

Form1)

Valued Environment Components

Mitigation Measures

Environmental Management Plan

Reporting

Approach of EIA Study – 4 months other than monsoon period after obtaining TOR copy from MOEF

ANNEXURE - XX

155

ANNEXURE - XXI

156

ANNEXURE - XXII

157

Documents

Contents...Further, name of the company has been changed from Nector Crop Sciences Private Limitedto Nichino Chemical India Limited withPrivate effect from 16-12-2017 (Annexure-M/s