semspub.epa.gov · Date: Subject: From: To: UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 5 CENTRAL REGIONAL LABORATORY 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 HAY 2

CHICAGO REGIONAL LABORATORYESAT Data Checklist

Work Order SF L:(;0fp^

EPA Region 5 Records Ctr.

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Chain of Custody

O Final report from LIMS Invoice #

a TDF Completion form signed by TOPO

3 Analytical and Data Review Checklist

El Transmittal Memo w/signatures of the following:

• Analyst(s)

• Environmental Data Coordinator

Prepared/

Date:

Subject:

From:

To:

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

REGION 5 CENTRAL REGIONAL LABORATORY

536 SOUTH CLARK STREET

CHICAGO, ILLINOIS 60605

HAY 2 6 2006

Review of Region 5 Data for US Smelter and Lead Refinery, Inc.

Stephen Connet, Chemist, TechLaw Inc. / ESATContractor to Region 5 Central Regional LaboratorySubmitted to CRL on -^

Attached are the results for: US Smelter and Lead Refinery, Inc.

CRL data set numbers): E604004, E605001 (soils only)

Samples analyzed for: ICP Metals (including Cd, Pb)

Results are reported for sample designations: E604004-03 thru -68, E605001-04 thru -40

Data7 Managementôordinator and Date Received

„ ^ . , 6 ZQ06Date Transmitted: / /

Please have the U.S. EPA Project Manager/Officer call the CRL Sample Coordinator at 3-7444 forany comments or questions.

Please sign and date this form below and return it with any comments to:

Sylvia GriffinData Management CoordinatorRegion 5 Central Regional LaboratoryML- IOC

II- 14107Received by and Date

Comments:


CRL data set number(s): E604004, E605001 (soils only)


Results are reported for sample designations: £604004-03 thru -68, E605001-04 thru -40

Rev. 4/10/02

1

Method: 200.7 (ICP Metals)Site: US Smelter and Lead Refinery, Inc.Date: May 19 2006Prepared by: Stephen Connet

TDF: R5-01-004,5TechLaw Job #: 03037.1.01.02.01.053J.000.004,5Task Order #: R5-0-01Data Sets: E604004, E605001

NARRATIVE

One hundred three (103) soil samples from the US Smelter and Lead Refinery, Inc. site were collectedbetween April 26 and May 1, 2006 and were received properly preserved at CRL on April 28 and May 2,2006. The samples were submitted to ESAT for analysis of total metals including cadmium and lead by ICP.The sample point identifications are listed on the first page of the LIMS report following this narrative. Rawdata and QC forms are filed in the folder for E604004.

The soil samples were dried and ground between May 1 and 4,2006 prior to being digested followingstandard CRL 200.2 hot block digestion protocols (CRL SOP METALS025). They were batched in 5 LIMSbatches (LIMS digestion batch EE60204 thru EE60208). All batches were digested on May 4,2006. Theywere analyzed between May 8 and 17,2006 according to CRL SOP METALS004 using the Optima 4300.One batch (EE60205) was reanalyzed due to instrument QC problems in the run. Recently completed (notlisted in METALS004) U.S. EPA MDL/RL values were used for evaluation of the data per Dr. J. V. Morris.ESAT has not had an opportunity to perform MDL/RL evaluations.

The following analytes will be addressed in this case narrative:

Al, Ba, Be, Ca, Cd, Cr, Co, Cu, Fe, Mg, Mn, Ni, Pb, K, Ag, Na, V, Zn

Qualifications of results will be limited to samples within each individual digestion batch. Each was analyzedas a separate analytical run. The following lists the case pertinent out-of-control QC audit check results:

Batches: EE60204 contains samples E604004-03 thru -22 (run May 8,2006)EE60205 contains samples E604004-23 thru -42 (run May 17,2006)EE60206 contains samples E604004-43 thru -62 (run May 11, 2006)EE60207 contains samples E604004-63 thru -68 and E605001-04 thru -17 (run May 12,2006)EE60208 contains samples E605001-18 thru -40 (run May 15,2006)

Blanks:

(May 17)

(May 8)

(May 17)

(May 11)

(May 12)

(May 15)

LCM1(3):

Instrblkl:

EE60205-BLK1

Instr blk4:

EE60207-BLK1

Cr267

Ag328

Cr267

Cr267

EE60208-BLK1 Ag 328

Co 228 10.10% deviationK 766 10.28% deviation

-2.37 ug/L

-4.36 ug/L

-2.72 ug/L

-2.34 ug/L

-5.93 ug/L

000029

RL Check Soln: Presently no "control" actions are associated with the observed RL analyte valuesactually determined during the analysis run. RL check solution values currently arebeing analyzed for purposes of generating a benchmark set of values which can be usedto monitor the appropriateness of any given RL level of analyte concentration. Valuesare subject to change pending further repairs on the instrument. Since no soil RLsolution has been prepared, CRL and ESAT water (METALS003) RL solutions wereanalyzed in the analytical run.

Duplicates:EE60204-DUP1 (E604004-12):

EE60204-DUP2 (E604004-22):

EE60205-DUP1 (E604004-34):

EE60205-DUP2 (E604004-42):

EE60206-DUP1 (E604004-43):

EE60206-DUP2 (E604004-42):EE60207-DUP1 (E604004-68):

EE60207-DUP2 (E605001-15):

EE60208-DUP1 (E605001-20):

EE60208-DUP2 (E605001-32):

Gu324Ni231Zn213Ag328,Be3I3,Cr267Ni231Ag328,Be313,Mg279Pb220Ag328, Be313,Ba455Mg279Ni231Pb220Be313Ag328, Co228A1308Ba455Cd214Cu324Pb220K766V310Zn213Be313Ag328, Co228Ag328, Co228Ni231Cd214Ag328,Be313,Ba455Co228, Na589Ag328,Be313Ca315Co228Mg279Ag328,Be313,Ba455

40.54% RPD *39.38% RPD *27.45% RPD *

Co228,V310 <5X44.14% RPD*51.58% RPD*

Cd214, Co228, Na589 < 5X9.12% RPD * (ESAT limit = 8.7%)14.37% RPD * (ESAT limit = 12%)

Cd214, Co228,Na589,V310 <5X33.74% RPD *13.42% RPD * (ESAT limit = 8.7%)20.40% RPD *15.28% RPD * (ESAT limit = 12%)* (difference > MDL)<5X19.04% RPD * (ESAT limit = 12.1%)27.12% RPD*20.20% RPD *21.59% RPD*29.91% RPD*18.73% RPD * (ESAT limit = 18.3%)20.61% RPD*23.78% RPD ** (difference > MDL)<5X<5X23.10% RPD** (difference > MDL)

Co228,Na589,V310 <5X12.63% RPD * (ESAT limit = 10%)* (difference > MDL)<5X36.98% RPD *25.51% RPD*48.55% RPD *

Cd214,Na589 <5X18.72% RPD * (ESAT limit =

000030

19. 1 0% RPD * (ESAT limit = 1 5.9%)28.96% RPD *

< 5XEE60208-DUP3 (E605001-39):

Fe273Pb220Ag328, Be313, Cd214, Co228, Na589, V310Ba455 24.28% RPD*Cd214 23.77% RPD *Cr267 24.48% RPD *Fe273 36.61% RPD*Ni231 20.02% RPD*Ag328, Be313, Co228, Na589 < 5X

< 5X: Sample and/or duplicate < 5X MDL; duplicate difference acceptable (< MDL).*: Indicates out of control result (ESAT limits)

Matrix spikes:EE60204-MS1 (E604004-12):

EE60206-MS1 (E604004-43):

EE60208-MS1 (E605001-20):

Pb220Zn213Pb220Zn213Cu324

#125.8% recovery118.7% recovery (ESAT limit = 109.9%R)109.2% recovery (ESAT limit - 107.9%R)112.5% recovery (ESAT limit =111.8%R)

# Spike invalid. Sample > 2X spike concentration. Blank spike or control sample used for controlpurposes.

Control Samples:EE60205-SRM1:EE60208-SRM1:

Serial Dilutions:EE60206-SRD1:EE60207-SRD1:EE60208-SRD1:

Ag328 0% recoveryAg328 19.3% recovery

Cr267 11.8% differenceA1308 10.1% differenceK766 11.6% difference

Sample element qualifications:

Control limits are normally set according to ESAT control charts. However, not enough data points forinstrument checks have been analyzed to determine ESAT control limits. Those control limits are setaccording to EPA limits. ESAT control limits are used for matrix QC. A linearity check sample wasperformed for Ba, Cr, Cu, Mn, Ni, Pb and Zn to extend the usable range of the instrument.

For Ag, negative Ag values whose absolute values were greater than the MDL were present for the digestionblank EE60205-BLK1 indicating a possible low bias. Samples E604004-25 thru -27, -29 thru -31 and -35 areflagged "L" in LIMS indicating the possible low bias. The instrument value for non-detect samples E604004-24 and -28 were sufficiently high to be affected by the possible low bias; those samples are also flagged "L"in LIMS. In the same analytical run, Ag results for the control samples EE60205-SRM1 and EE60208-SRM1were less than the lower ESAT limit indicating a possible low bias; Ag results for samples E604004-23 thru -42, E605001-18 thru -40 and control samples EE60205-SRM1 and EE60208-SRM1 are flagged "L" in LIMSdue to possible low bias. Finally, the raw instrument value is greater than the MDL but less than the RL for

000031

the following samples: E604004-03 thru -18, -25 thru -27, -29 thru -31, -35, -43, -45, -46, -62 thru -64, -66,E605001-04 thru -07, -10, -16, -33, -36, -37, -39 and -40. Ag results for those samples are flagged "J" inLIMS.

For Al, all sample results are reported from the Al 308 line. The duplicate RPD for EE60206-DUP1 wasgreater than the upper ESAT limit indicating possible poor precision. The Al sample results for E604004-43thru -62 and duplicate EE60206-DUP1 are flagged "*" in LIMS indicting possible poor precision.Additionally, the Al serial dilution result for EE60207-SRD1 was greater than the original result indicating apossible negative interference. Al results for E604004-63 thru -68 and E605001-04 thru -17 are flagged "L"in LIMS due to the possible interference.

For Ba, the duplicate RPD for EE60205-DUP2, EE60206-DUP1, EE60207-DUP2, EE60208-DUP2 and-DUP3 were greater than the upper ESAT limit indicating possible poor precision. The Ba sample results forE604004-23 thru -68, E605001-04 thru -40 and duplicates EE60205-DUP2, EE60206-DUP1, EE60207-DUP2, EE60208-DUP2 and -DUP3 are flagged "*" in LIMS indicting possible poor precision.

For Be, the duplicates E604004-42/EE60205-DUP2 and E604004-43/EE60206-DUP1 were greater than theMDL but less than 5X the MDL. Duplicate difference was used for control purposes. The duplicatedifference was greater than the MDL indicating possible poor precision. The Be sample results for E604004-23 thru -62 and duplicates EE60206-DUP1 and EE60205-DUP2 are flagged "*" in LIMS indicting possiblepoor precision. Finally, the raw instrument value is greater than the MDL but less than the RL for thefollowing samples: E604004-07, -09, -10, -12 thru -18, -20, -22 thru -33, -36, -37, -39 thru -48, -53 thru -64,-66 thru -68, E605001-08 thru -24, -26 thru -33, -37, -39 and -40. Be results for those samples are flagged "J"in LIMS.

For Cd, the sample E604004-68 and its duplicate EE60207-DUP1 were greater than the MDL but less than5X the MDL. Duplicate difference was used for control purposes. The duplicate difference was greater thanthe MDL indicating possible poor precision. The Cd sample results for E604004-63 thru -68, E605001-04thru -17 and duplicate EE60207-DUP1 are flagged "*" in LIMS indicting possible poor precision.Additionally, the duplicate RPD for EE60206-DUP1 and EE60208-DUP3 were greater than the upper limitindicating possible poor precision. The Cd sample results for E604004-43 thru -62, E605001-18 thru -40 andduplicates EE60206-DUP1 and EE60208-DUP3 are flagged "*" in LIMS indicting possible poor precision.Finally, the raw instrument value is greater than the MDL but less than the RL for the following samples:E604004-09, -21 thru -23, -34, -38, -41, -46, -55, -57, -59,.-64, -68, E605001-11, -18 thru -25, -28 and -32.Cd results for those samples are flagged "J" in LIMS.

For Ca, the duplicate RPD for EE60208-DUP1 was greater than the upper limit indicating possible poorprecision. The Ca sample results for E605001-18 thru -40 and duplicate EE60208-DUP1 are flagged "*" inLIMS indicting possible poor precision.

For Cr, the duplicate RPD for EE60204-DUP2 and EE60208-DUP3 were greater than the upper limitindicating possible poor precision. The Cr sample results for E604004-03 thru -22, E605001-18 thru -40 andduplicates EE60204-DUP2 and EE60208-DUP3 are flagged "*" in LIMS indicting possible poor precision.Additionally, the Cr serial dilution result for EE60206-SRD1 was greater than the original result indicating apossible negative interference. Cr results for E604004-43 thru -62 are flagged "L" in LIMS due to thepossible interference.

000032

For Co, the LCM1(3) check sample had a value greater than the acceptable limit indicating a possible highbias. Samples prior to LCM1(2) are not affected by the possible high bias. The Co sample results forE604004-30 thru -42 are flagged "K" in LIMS due to the possible high bias. Additionally, the sampleE605001-15 and its duplicate EE60207-DUP2 were greater than the MDL but less than 5X the MDL.Duplicate difference was used for control purposes. The duplicate difference was greater than the MDLindicating possible poor precision. The Co sample results for E604004-63 thru -68, E605001-04 thru -17 andduplicate EE60207-DUP2 are flagged "*" in LIMS indicting possible poor precision. Also, the duplicateRPD for EE60208-DUP1 was greater than the upper limit indicating possible poor precision. The Co sampleresults for E605001-18 thru -40 and duplicate EE60208-DUP1 are flagged "*" in LIMS indicting possiblepoor precision. Finally, the raw instrument value is greater than the MDL but less than the RL for thefollowing samples: E604004-09, -20 thru -26, -30 thru -34, -36 thru -46, -54 thru -64, -66 thru -68, E605001-06, -08 thru -11, -13, -14, -16 thru -18, -27, -28, -30 thru -33 and -39. Co results for those samples is flagged"J" in LIMS.

For Cu, the duplicate RPDs for EE60204-DUP1 and EE60206-DUP1 were greater than the upper limitindicating possible poor precision. The Cu sample results for E604004-03 thru -22, -43 thru -62 andduplicates EE60204-DUP1 and EE60206-DUP1 are flagged "*" in LIMS indicting possible poor precision.Additionally, the Cu matrix spike recovery for EE60208-MS1 was greater than the upper ESAT limitindicating a possible high bias. Cu for samples E605001-18 thru -40 and matrix spike EE60208-MS1 areflagged "K" in LIMS due to the possible high bias.

For Fe, the duplicate RPDs for EE60208-DUP2 and -DUP3 were greater than the upper ESAT limit indicatingpossible poor precision. The Fe sample results for E605001-18 thru -40 and duplicates EE60208-DUP2 and-DUP3 are flagged "*" in LIMS indicting possible poor precision. Also, all Fe results except digestion blanksare reported from the Fe 273 line. Digestion blanks are reported from the Fe 259 line.

For Pb, the duplicate RPDs for EE60205-DUP1, -DUP2, EE60206-DUP1 and EE60208-DUP2 were greaterthan the upper ESAT limit indicating possible poor precision. The Pb sample results for E604004-23 thru -62,E605001-18 thru -40 and duplicates EE60205-DUP1, -DUP2, EE60206-DUP1 and EE60208-DUP2 areflagged "*" in LIMS indicting possible poor precision. Additionally, the matrix spike recovery for EE60206-MS1 was greater than the upper ESAT limit indicating a possible high bias. Pb for samples E604004-43 thru-62 and matrix spike EE60206-MS1 are flagged "K" in LIMS due to the possible high bias.

For Mg, the duplicate RPDs for EE60205-DUP1, -DUP2 and EE60208-DUP1 were greater than the upperESAT limit indicating possible poor precision. The Mg sample results for E604004-23 thru -42, E605001-18thru -40 and duplicates EE60205-DUP1, -DUP2 and EE60208-DUPlare flagged "*" in LIMS indictingpossible poor precision. All Mg results except digestion blanks are reported from the Mg 279 line. Digestionblanks are reported from the Mg 280 line.

For Ni, the duplicate RPDs for EE60204-DUP1, -DUP2, EE60205-DUP2, EE60207-DUP1 and EE60208-DUP3 were greater than the upper limit indicating possible poor precision. The Ni sample results forE604004-03 thru -42, -63 thru -68, E605001-04 thru -40 and duplicates EE60204-DUP1, -DUP2, EE60205-DUP2, EE60207-DUP1 and EE60208-DUP3 are flagged "*" in LIMS indicting possible poor precision.

For K, the LCM1(3) check sample had a value greater than the acceptable limit indicating a possible highbias. Samples prior to LCM1(2) are not affected by the possible high bias. The K sample results forE604004-30 thru -42 are flagged "K" in LIMS due to the possible high bias. Additionally, the duplicate RPD

000033

for EE60206-DUP1 was greater than the upper limit indicating possible poor precision. The K sample resultsfor E604004-43 thru -62 and duplicate EE60206-DUP1 are flagged "*" in LIMS indicting possible poorprecision. Finally, the K serial dilution result for EE60208-SRD1 was greater than the original resultindicating a possible negative interference. K results for E605001-18 thru -40 are flagged "L" in LIMS due tothe possible interference.

For Na, the sample E605001-15 and its duplicate EE60207-DUP2 were greater than the MDL but less than5X the MDL. Duplicate difference was used for control purposes. The duplicate difference was greater thanthe MDL indicating possible poor precision. The Na sample results for E604004-63 thru -68, E605001-04thru -17 and duplicate EE60207-DUP2 are flagged "*" in LIMS indicting possible poor precision. Finally,the raw instrument value is greater than the MDL but less than the RL for the following samples: E604004-17,-20, -21, -23, -24, -36, -38, -41, -46, -55, -57, -59, -64, -68, E605001-17 thru -22 and -28. Na results for thosesamples are flagged "J" in LIMS.

For V, the duplicate RPD for EE60206-DUP1 was greater than the upper limit indicating possible poorprecision. The V sample results for E604004-43 thru -62 and duplicate EE60206-DUP1 are flagged "*" inLIMS indicting possible poor precision. Finally, the raw instrument value is greater than the MDL but lessthan the RL for the following samples: E604004-23, -34, -38, -46, -64, -68, E605001-18, -28 and -32. Vresults for those samples are flagged "J" in LIMS.

For Zn, the duplicate RPD for EE60204-DUP1 and EE60206-DUP1 were greater than the upper limitindicating possible poor precision. The Zn sample results for E604004-03 thru -22, -43 thru -62 andduplicates EE60204-DUP1 and EE60206-DUP1 are flagged "*" in LIMS indicting possible poor precision.Additionally, the Zn matrix spike recovery for EE60204-MS1 and EE60206-MS1 were greater than the upperESAT limit indicating a possible high bias. Zn for samples E604004-03 thru -22, -43 thru -62 and matrixspikes EE60204-MS1 and EE60206-MS1 are flagged "K" in LIMS due to the possible high bias. The Znresult for sample E604004-48 was greater than the linearity check sample; the sample was diluted 2X andreanalyzed. The Zn result was reported from the dilution.

All flagged results except those flagged "<5X" are considered estimated.

Other commentsSamples E604004-30/-31, -44/-4S, -52/-S3, E605001-09/-10 and -39/-40 were identified as field duplicates.E604004-30/-31 showed good correlation for all elements except Pb, E604004-44/-45 showed goodcorrelation for all elements except Ag, E604004-52/-53 showed good correlation for all elements except Ni,E605001-09/-10 showed good correlation for all elements except Ca and Mg and E605001-39/40 showedgood correlation for all elements except Cu, Na and Ni. Determinations of correlation were made accordingto laboratory duplicate criteria; however, no sample results are qualified for field duplicates.

It has been observed that, due to differences in the significant figures used for calculation, RPD values andsome matrix spike recoveries calculated by LIMS are not correct. Some of these values are reported by LIMSas being outside QC requirements when they are not. The correct values are included as Excel spreadsheets inthe Analytical/Matrix QC Summary Report provided in the data package.

000034

MLaw 105 W. Madiam Strwt, Suite 900drop, 1L6M02

(312)545-3990(312) 3454979 (Fac)

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Superfund, US EPA Region 577 West Jackson BoulevardChicago IL, 60604

Project: US Smelter and Lead Refinery, Inc.Project Number: [none] Reported:

Project Manager: Warren Layne May-25-06 14:43

ANALYTICAL REPORT FOR SAMPLES

Sample ID

X03-B-0-1

X03-B-1-6

X03-B-6-12

X03-DZ

X03-F-0-1

X03-F-1-6

X03-F-6-12

X07-B-0-1

X07-B-1-6

X07-B-6-12

X07-DZ

X07-F-0-1

X07-F-1-6

X07-F-6-12

XI5-B-0-1

XI5-B-1-6

X15-B-6-12

X15-DZ

X15-F-0-1

X15-F-1-6

X15-F-6-12

X19-B-0-1

X19-B-1-6

X19-B-6-12

X19-DZ

X19-F-0-1

X19-F-1-6

X19-F-6-12

^

Laboratory ID

E604004-03

E604004-04

E604004-05

E604004-06

E604004-07

E604004-08

E604004-09

E604004-10

E604004-11

E604004-12

E604004-13

E604004-14

E604004-15

E604004-16

E604004-17

E604004-18

E604004-19

E604004-20

E604004-2I

E604004-22

E604004-23

E604004-24

E604004-25

E604004-26

E604004-27

E604004-28

E604004-29

E604004-30

; f.M «-w

Matrix

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Report Name:

Date Sampled Date Received

Apr-26-06 12:35 Apr-28-06 12:08

Apr-26-06 12:40 Apr-28-06 12:08

Apr-26-06 12:45 Apr-28-06 12:08

Apr-26-06 12:30 Apr-28-06 12:08

Apr-26-06 12:20 Apr-28-06 12:08

Apr-26-06 12:25 Apr-28-06 12:08

Apr-26-06 12:25 Apr-28-06 12:08

Apr-26-06 09:50 Apr-28-06 12:08

Apr-26-06 09:55 Apr-28-06 12:08

Apr-26-06 09:55 Apr-28-06 12:08

Apr-26-06 10:00 Apr-28-06 12:08

Apr-26-06 1 0: 1 5 Apr-28-06 1 2:08

Apr-26-06 10:40 Apr-28-06 12:08

Apr-26-06 10:45 Apr-28-06 12:08

Apr-26-06 15:25 Apr-28-06 12:08

Apr-26-06 15:45 Apr-28-06 12:08

Apr-26-06 15:35 Apr-28-06 12:08

Apr-26-06 15:20 Apr-28-06 12:08

Apr-26-06 14:40 Apr-28-06 12:08

Apr-26-06 14:45 Apr-28-06 12:08

Apr-26-06 14:50 Apr-28-06 12:08

Apr-26-06 16:50 Apr-28-06 12:08

Apr-26-06 16:55 Apr-28-06 12:08

Apr-26-06 17:00 Apr-28-06 12:08

Apr-26-06 16:15 Apr-28-06 12:08

Apr-26-06 16:00 Apr-28-06 12:08

Apr-26-06 16:05 Apr-28-06 12:08

Apr-26-06 1 6: 1 0 Apr-28-06 1 2:08

E605001.E604004 FINAL May 25 06 1443Stephenêfinet, Chemist Page 1 of74

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Project: US Smelter and Lead Refinery, Inc.Project Number: [none]Project Manager: Warren Layne

Reported:

May-25-06 14:43


Sample ID

X19-FD-6-12

X24-B-0-1

X24-B-1-6

X24-B-6-12

X24-DZ

X24-F-0-1

X24-F-1-6

X24-F-6-12

X26-B-0-1

X26-B-1-6

X26-B-6-12

X26-DZ

X26-F-0-1

X26-F-1-6

X26-FD-1-6

X26-F-6-12

X46-B-0-1

X46-B-1-6

X46-B-6-12

X46-DZ

X46-F-0-1

X46-F-1-6

X46-FD-1-6

X46-F-6-12

X48-B-0-1

X48-B-1-6

X48-B-6-12

X48-DZ

X48-F-0-1

*± '•*/*:L/><=::=^

Laboratory ID

E604004-31

E604004-32

E604004-33

E604004-34

E604004-35

E604004-36

E604004-37

E604004-38

E604004-39

E604004-40

E604004-41

E604004-42

E604004-43

E604004-44

E604004-45

E604004-46

E604004-47

E604004-48

E604004-49

E604004-50

E604004-51

E604004.52

E604004-53

E604004-54

E604004-55

E604004-56

E604004-57

E604004-58

E604004-59

000036

Matrix

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Report Name:

Date Sampled

Apr-26-06 16:15

Apr-27-06 16:00

Apr-27-06 16:05

Apr-27-06 16:10

Apr-27-06 15:55

Apr-27-06 15:25

Apr-27-06 15:45

Apr-27-06 15:50

Apr-27-06 16:45

Apr-27-06 16:50

Apr-27-06 17:00

Apr-27-06 16:40

Apr-27-06 16:25

Apr-27-06 16:30

Apr-27-06 16:30

Apr-27-06 16:35

Apr-27-06 14:45

Apr-27-06 14:50

Apr-27-06 14:55

Apr-27-06 14:05

Apr-27-06 14:10

Apr-27-06 14:15

Apr-27-06 14:20

Apr-27-06 14:25

Apr-27-06 11:00

Apr-27-06 11:05

Apr-27-06 11:10

Apr-27-06 11:15

Apr-27-06 11:30

Date Received

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

E605001.E604004 FINAL May 25 06 1443StepherrConnet, Chemist

Page 2 of74

K iKhlQua l i t y f> In


Sample ID

X48-F-1-6

X48-F-6-12

X50-B-0-1

X50-B-1-6

X50-B-6-12

X50-DZ

X50-F-0-1

X50-F-1-6

X50-F-6-12

X10-B-0-1

X10-B-1-6

X10-B-6-12

X10-DZ

X10-F-0-1

X10-F-1-6

X10-FD-1-6

X10-F-6-12

X13-B-0-1

X13-B-1-6

X13-B-6-12

X13-DZ

X13-F-0-1

X13-F-1-6

XI3-F-6-I2

X35-B-0-1

X35-B-1-6

X35-B-6-12

X35-DZ

.aw/ r / /m

• v«f *i •. 4t* n-mnmmmTfmm •WMt^wwj ^^^rwm »• »^

Obcajo, 0,60602(312)3454990

(312)345-*97J(F»)wmv f wli'fff1''1** *"om

Project: US Smelter and Lead Refinery, Inc.Project Number: [none]Project Manager: Warren

ANALYTICAL REPORT FOR

Layne

SAMPLES

Laboratory ID Matrix

E604004-60

E604004-61

E604004-62

E604004-63

E604004-64

E604004-65

E604004-66

E604004-67

E604004-68

E605001-04

E605001-05

E605001-06

E605001-07

E605001-08

E605001-09

E605001-10

E605001-11

E605001-12

E605001-13

E60500M4

E605001-15

E605001-16

E605001-17

E605001-18

E605001-19

E605001-20

E605001-21

E605001-22

- 000037*

N.

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Report Name:

Reported:

May-25-06 14:43


Apr-27-06 11:35 Apr-28-06 12:08

Apr-27-06 1 1 :40 Apr-28-06 12:08

Apr-27-06 09:40 Apr-28-06 1 2 :08

Apr-27-06 09:45 Apr-28-06 12:08

Apr-27-06 09:50 Apr-28-06 12:08

Apr-27-06 09:30 Apr-28-06 12:08

Apr-27-06 09:05 Apr-28-06 12:08

Apr-27-06 09: 10 Apr-28-06 12:08

Apr-27-06 09: 15 Apr-28-06 12:08

May-01-06 1 1 :00 May-02-06 1 1 :21

May-01-06 11:20 May-02-06 11:21

May-0 1 -06 1 1 :25 May-02-06 11:21

May-0 1 -06 1 0:50 May-02-06 11:21

May-01-06 10:35 May-02-06 11:21

May-0 1 -06 1 0:40 May-02-06 11:21

May-01-06 10:45 May-02-06 11 :21

May-01-06 10:47 May-02-06 11:21

May-01-06 09:20 May-02-06 1 1 :21

May-0 1 -06 09:25 May-02-06 11 :2 1

May-0 1 -06 09:45 May-02-06 11:21

May-01-06 09:15 May-02-06 11:21

May-01-06 09:00 May-02-06 11:21

May-01-06 09:05 May-02-06 1 1 :21

May-0 1 -06 09: 1 0 May-02-06 11:21

May-01-06 16:25 May-02-06 11:21

May-0 1 -06 1 6:30 May-02-06 11:21

May-01-06 16:35 May-02-06 11:21

May-0 1 -06 1 6:20 May-02-06 11:21

E605001.E604004 FINAL May 25 06 1443Stephen Oertnet, Chemist Page 3 of74

MLaw 105 W. Madison Stmt, Sate 900

(312)3454990(312) H54979 (F«)

Superfund, US EPA Region 5

77 West Jackson BoulevardChicago IL, 60604

•^nrarrarnu

Project: US Smelter and Lead Refinery, Inc.Project Number: [none]

Project Manager: Warren Layne

wince m

Reported:

May-25-06 14:43


Sample ID

X35-F-0-1

X35-F-1-6

X35-F-6-12

X42-B-0-1

X42-B-1-6

X42-B-6-12

X42-DZ

X42-F-0-1

X42-F-1-6

X42-F-6-12

X49-B-0-1

X49-B-1-6

X49-B-6-12

X49-DZ

X49-F-0-1

X49-F-1-6

X49-F-6-12

X49-FD-6-12

Laboratory ID

E605001-23

E605001-24

E605001-25

E605001-26

E605001-27

E605001-28

E605001-29

E605001-30

E605001-31

E605001-32

E605001-33

E605001-34

E605001-35

E605001-36

E605001-37

E605001-38

E605001-39

E605001-40

Matrix

Soil

Soil

•Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Date Sampled

May-01-06

May-01-06

May-01-06

May-01-06

May-01-06

May-01-06

May-01-06

May-01-06

May-01-06

May-01-06

May-01-06

May-01-06

May-01-06

May-01-06

May-01-06

May-01-06

May-01-06

May-01-06

16:00

16:05

16:10

15:05

15:10

15:15

15:00

15:20

15:25

15:30

12:15

12:20

12:25

12:10

11:45

11:50

11:55

12:00

Date Received

May-02-06

May-02-06

May-02-06

May-02-06

May-02-06

May-02-06

May-02-06

May-02-06

May-02-06

May-02-06

May-02-06

May-02-06

May-02-06

May-02-06

May-02-06

May-02-06

May-02-06

May-02-06

11:21

11:21

11:21

11:21

11:21

11:21

11:21

11:21

11:21

11:21

11:21

11:21

11:21

11:21

11:21

11:21

11:21

11:21

StepheirConnet, Chemist

000038Report Name: E605001,E604004 FINAL May 25 06 1443

Page 4 of74

khUwQual i t?

105 W. Madison Stint, Sate 900Oocô,IL 60602

(312)3454990(312) 345-8979 (Fax)

tta&




Reported:

May-25-06 14:43

Metals by ICPTechLaw - ESAT Contract

X03-B-0-1 (E604004-03) Soil Sampled: Apr-26-06 12:35 Received: Apr-28-06 12:08

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X03-B-1-6 (£604004-04) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

5400

520

1.0

7.3

16000

35

4.9

180

24000

2300

6100

540

24

760

13

250

21

1400

Sampled: Apr-26-06

Result

6200

670

1.8

6.4

13000

29

5.8

170

29000

1400

4600

470

Flags/Qualifiers MDL

11

0.2

0.2

0.4

18

« 0.5

1.0

* 1.3

23

3.8

13

0.09

* 0.9

21

J 0.8

26

2.3

K, * 5.3

Limit Units

94 mg/kg

0.9

0.9

1.994

1.9

3.8

3.894

9.4

38

0.5

3.894

1.994

9.4

19

Dilution Batch Prepared Analyzed Method

1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

12:40 Received: Apr-28-06 12:08


120.2

0.2

0.4

19

* 0.5

1.1

1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

StephefiOonnet, Chemist


Page 5 of74

Tech-law105\V.M*disonS«tt,Sait«900

Qtaliti

(312)5454990(312) 3454979 (F»)

com

Superfund, US EPA Region 577 West Jackson Boulevard

Chicago IL, 60604


Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX03-B-1-6 (E604004-04) Soil Sampled: Apr-26-06 12:40 Received: Apr-28-06 12:08

Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X03-B-6-12 (E604004-05) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

278901.3370

21

1400

Sampled: Apr-26-06

Result

4800

350

1.2

3J

11000

17

4.9

110

18000

710

4700

350

31

630

1.1

280

IS

920


* 1.0

22

J 0.8

28

2.4

K, * 5.6

12:45 Received:


12

0.2

0.2

0.4

19

* 0.5

1.1

* 1.4

24

3.914

0.1

* 1.0

22

J 0.8

28

2.4

K, * S.5

Limit Units

4.0 mg/kg

100

2.0

100

10

20

Apr-28-06 12:08

Limit Units

98 mg/kg

1.0

1.0

2.0

98

2.0

3.9

3.9

98

9.8

39

0.5

3.9

98

2.0

98

9.8

20

Dilution Batch Prepared Analyzed

1 EE60204 May-04-06May-08-06n n n n

n n M «

„„n n « n


1 EE60204 May-04-06May-08-06tl » W It

n M n n

,,„,,,n

"„11 n M n

H N II II

. , „ - , „

.„. . .11 II II II

„

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stephen Certnet, Chemist

000040Report Name: E605001.E604004 FINAL May 25 06 1443

Page 6 of74

TediLaw 105 W.MadisraStmt, Sate 900

o I t t t t f t t l y

(312)5454990(312)J45-*979(Fa)vntnx tftf Mawiw toan

Superfiind, US EPA Region 577 West Jackson BoulevardChicago IL, 60604


Project Manager: Warren LayneReported:

May-25-06 14:43


X03-DZ (£604004-06) Soil Sampled: Apr-26-06 12:30 Received: Apr-28-06 12:08

AnalyteAluminumBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseNickelPotassiumSilverSodiumVanadiumZinc

X03-F-0-1 (E604004-07) Soil

Analyte

AluminumBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesium

Manganese

Result

7400

340

1.1

4.5

28000

27

5.3

93

20000

1000

12000

610

23

700

1.6

370

18

1200

Sampled: Apr-26-06

Result

5700

220

0.9

3.5

57000

32

4.1

93

18000

680

11000

590


12

0.2

0.2

0.4

19

* 0.5

I .I

* 1.4

24

4.0

14

0.1

» 1.0

22

) 0.8

28

2.4

K, * 5.6

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

" " " EPA 200.7

" EPA 200.7

EPA 200.7

" " " EPA 200.711 " " " EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

12:20 Received: Apr-28-06 12:08


12

0.2

J 0.2

0.4

19

* 0.5

1.1

* 1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stephen Cerinet, Chemist


Page 7 of74

TediLawQ x a l i t j

105 W.MkKsoa Start, Suit* NOdraft), IL 60602

(312)3454990(312) 5454979 (F«)UftVW tttCnulVIQC Aftffl




Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX03-F-0-1 (E604004-07) Soil Sampled: Apr-26-06 12:20 Received: Apr-28-06 12:08

Analyle

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X03-F-1-6 (E604004-08) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

468801.2

32017

790

Sampled: Apr-26-06

Result

6000

2001.03.8

31000

42

4.1

86

23000

780

10000

940

26

900

1.6

320

20

900

Flags /Qualifiers MDL

* 1.0

22

J 0.8

28

2.4

K,* 5.6

Limit Units

4.0 tng/kg

100

2.0

100

10

20


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

12:25 Received: Apr-28-06 12:08


12

0.2

0.2

0.4

19

* 0.5

1.1

* 1.4

24

3.914

0.1

« 1.0

22

J 0.8

28

2.4

K, * 5.5

Limit Units

99 mgflcg

1.0

1.0

2.099

2.0

3.9

3.9

99

9.939

0.5

3.999

2.0

99

9.9

20


I EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

" " " " EPA 200.7

" " " " EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

" " " ' EPA 200.7

" EPA 200.7

" EPA 200.7

Stephen Connet, Chemist


Page 8 of74

TechLawQ t e l i t i $ l u l r g r i t y

105 W.Madison Start, Sofr 900Oacafo,IL 600)2

(312)3454990(312)3454979 (Fix)



Reported:

May-25-06 14:43

X03-F-6-12 (£604004-09) Soil


Sampled: Apr-26-06 12:25 Received: Apr-28-06 12:08

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X07-B-0-1 (E604004-10) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Flags/Result Qualifiers

2500

1100.4 J

1.9 J

24000

15 *

2.4 J

39 *

11000

35011000

43023 •

4000.9 J

13010

590 K, *

MDL

12

0.2

0.2

0.4

18

0.5

I.I

1.3

23

3.9

13

0.1

1.0

21

0.8

27

2.3

5.4

Limit Units

96 mg/kg

1.0

1.0

1.9

96

1.9

3.9

3.9

96

9.6

39

0.5

3.9

96

1.9

96

9.6

19


I EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.711 " " EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

" " " " EPA 200.7



5200

220

0.6 J

5.5

17000

32 *

4.9

120 *

24000

1200

6100

620

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

" " ' " EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

StephefrtJonnet, Chemist


Page 9 of74

Tedilaw105 W.MadisouStmt, Sate 900

Qnc3fo,IL60$Q2(312)3454990

Q*a(it? & vmnt



Reported:

May-25-06 14:43


X07-B-0-1 (£604004-10) Soil Sampled: Apr-26-06 09:50 Received: Apr-28-06 12:08

AnalyteNickel

Potassium

Silver

SodiumVanadium

Zinc

X07-B-1-6 (£604004-11) Soil

Analyte

Aluminum

BariumBerylliumCadmium

Calcium

Chromium

Cobalt

Copper

IronLead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc


21 *

7200.9 J

15019

1100 K,*

MDL1.0220.8282.45.7

Limit Units

4.0 mg/kg1002.01001020


1 EE60204 May-04-06May-08-06I. ii . n

n

„

„ „

• It H It

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



5300

3101.07.5

15000

29 *5.5180 *

20000

18005600

53043 *5801.5 J15019

2900 K, *

MDL120.20.20.4190.51.11.4

233.914

0.11.0210.8272.35.5

Limit Units

98 mg/kg1.01.02.0982.03.93.9989.8390.53.9982.0989.820


1 EE60204 May-04-06May-08-06"

.,

" "„n n it ti

„it M n H

II tt H M

I,ii H n n

,,„

H n n N

tl N ti M

„

",,

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stephen Crjnnet, Chemist


Page 10 of74

TediLawQsal i t i t?

105 W. Madison Sttwt,Smli 900Chkafo,IL 60002

(312)3454990(312) 3454079 (Fix)


Chicago IL, 60604



Reported:

May-25-06 14:43

X07-B-6-12 (E604004-12) Soil



Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X07-DZ (E604004-13) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

3700

2100.64.2

12000

204.3110

16000

2700

4800

34027

4901.7

16011

1300

Sampled: Apr-26-06

Result

6900

2400.89.3

15000

485.9180

32000

1800

4600

930


120.2

J 0.2

0.419

* 0.5

1.1* 1.4

244.1140.1

• 1.0

22J 0.8

292.4

K, * 5.7

Limit Units

100 mg/kg

1.01.02.01002.04.14.110010410.54.11002.0

1001020


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

10:00 Received: Apr-28-06 12:08


120.2

J 0.2

0.419

* 0.5

1.1* 1.4

244.014

0.1

Limit Units

100 mg/kg

1.01.02.01002.04.04.010010400.5


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

000045

Stephen Connet, ChemistReport Name: E605001,E604004 FINAL May 25 06 1443

Page 11 of 74

MLaw 105 W.MkKsoa Strut, Sgitt 900Chicafo.E, 60602

012J34M990(312) 3454979 (Fax)•arvns




Reported:

May-25-06 14:43



Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X07-F-0-1 (E604004-14) Soil

Analyte

AluminumBarium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

48660

1.2

130

25

1400

Sampled: Apr-26-06

Result

7300

130

0.6

4.2

11000

40

5.4

110

20000

1200

4700

670

20

1100

1.2

120

23

940


* 1.0

22

J 0.8

28

2.4

K,* 5.6

Limit Units

4.0 mg/kg

100

2.0

100

10

20


1 EE60204 May-04-06May-08-06 EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

10:15 Received: Apr-28-06 12:08


120.2

J 0.2

0.4

19

» 0.5

1.1

* 1.4

24

4.014

0.1

* 1.0

22

J 0.8

28

2.4

K, * 5.6

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

1040

0.5

4.0

100

2.0

100

10

20


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

" EPA 200.711 " " " EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7


000046Report Name: E60500I,E604004 FINAL May 25 06 1443

Page 12 of 74

TediLawt> l u l t f r i t j

105 W.M*S«m Stttit, Safe 900Oiicafo, 160602

012)3454990(312) 3454979 (Fax)

Superftind, US EPA Region 577 West Jackson BoulevardChicago IL, 60604


Reported:

May-25-06 14:43


X07-F-1-6 (£604004-15) Soil Sampled: Apr-26-06 10:40 Received: Apr-28-06 12:08

AnalyteAluminum

BariumBeryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X07-F-6-12 (£604004-16) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

7400

120

0.5

4.0

8900

37

5.4

100

19000

980

4000

530

23

1000

1.2

110

20

850

Sampled: Apr-26-06

Result

6000

100

0.5

3.2

17000

23

4.7

62

15000

440

8700

410

Flags/Qualifiers MDL Limit Units

12

0.2

j 0.2

0.4

19

* 0.5

1.1

* 1.4

24

4.0

14

0.1

* 1.0

22

J 0.8

28

2.4

K, * 5.6

10:45 Received:


12

0.2j 0.2

0.4

19

• 0.5

1.1

* 1.4

24

4.0

14

0.1

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20

Apr-28-06 12:08

Limit Units

100 mg/kg1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


I EE60204 May-04-06May-08-06n n n H

. . . .

". . . . .

II H « It

« « N II

,,

.

H H » M

I , "

.

"

.

I.

( i f * i f n

.n »i n «


1 EE60204 May-04-06May-08-06n M n »

-

n ti n n

II H N H

""n •* 11 n

"

n n B „

«

. .

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stephen connet, Chemist

000047Report Name: E605001 ,£604004 FINAL May 25 06 1443

Page 13 of74

ktilaw 105 W. Madison SttMt, Sate 900

(3 12) 3454979 (Fa)earn





Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractXQ7-F-6-12 (£604004-16) Soil Sampled: Apr-26-06 10:45 Received: Apr-28-06 12:08

Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X15-B-0-1 (E604004-17) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

27

790

1.0150

17

570

Sampled: Apr-26-06

Result

5600

140

0.7

2.8

13000

51

4.3

65

23000

700

3300

1000

17

740

I.I

91

30

790

Flags/Qualifiers

*

J

K '*

MDL

1.0

22

0.8

28

2.4

5.6

Limit Units

4.0 mg/Tcg

100

2.0

100

10

20


1 EE60204 May-04-06May-08-06K tt 1. tt

„ „

.

"

M tl 11 tt

MethodEPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

15:25 Received: Apr-28-06 12:08

Flags/Qualifiers

J

*

4

*

J

J

K,*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.014

0.1

1.0

22

0.8

28

2.4

5.6

Limit Units

99 mg/kg

1.0

1.0

2.0

99

2.0

4.0

4.099

9.9

40

0.5

4.0

99

2.0

99

9.9

20


1 EE60204 May-04-06May-08-06» «

"• n tl it

"„n » II m

n ti n it

..

M n n n

,.M M m i t

.« m n n

»-.. . . .

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

StepharftJonnet, Chemist


Page 14 of 74

TediLawQtia l i t i f>

105 W. Madison Strut, Sate 900Chkafo,IL 60602

012) 345-8990(312) 3454979 (Fuc)www




Reported:

May-25-06 14:43



Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X15-B-6-12 (E604004-19) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

6900

170

0.8

2.9

10000

40

4.4

71

19000

780

2400

610

22

730

IJ

140

25

750

Sampled: Apr-26-06

Result

6200

230

1.2

33

11000

27

4.5

73

22000

990

2700

360


12

0.2

J 0.2

0.4

19

* 0.5

1.1

« 1.4

24

4.0

14

0.1

« 1.0

22

J 0.8

28

2.4

K,* 5.6

15:35 Received:


12

0.2

0.2

0.4

19

* 0.5

1.1

• 1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20

Apr-28-06 12:08

Limit Units

100 mg/kg

1.01.02.01002.04.0

4.0

100

10

40

0.5


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.711 EPA 200.7

EPA 200.7

" EPA 200.7'

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.711 " " EPA 200.7

EPA 200.7

EPA 200.7

" " ' EPA 200.7


1 EE60204 May-04-06May-08-06 EPA 200.7

" EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

Stephen Conlfet, Chemist

000049Report Name: E605001 ,E604004 FINAL May 25 06 1443

Page 15 of 74

TediLaw 105 W.&iadiM&SttMt, Sate 900

012)3454990(312) 3454979 (Fax)

Superfund, US EPA Region 577 West Jackson BoulevardChicago 1L, 60604


Project Manager Warren Layne

Reported:

May-25-06 14:43



Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X15-DZ (£604004-20) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

31

780

7.9

250

22

970

Sampled: Apr-26-06

Result

6300

95

0.6

2.4

9900

28

3J

75

16000

6302900

430

21

490U

74

20

520


• 1.0

22

0.8

28

2.4

*, K 5.6

Limit Units

4.0 mg/kg

100

2.0

100

10

20


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

15:20 Received: Apr-28-06 12:08


12

0.2

J 0.2

0.4

19

* 0.5

J 1.1

* 1.4

24

4.014

0.1

* 1.0

22

0.8J 28

2.4

K, « 5.6

Limit Units

99 mg/kg

1.0

1.0

2.0

99

2.0

4.0

4.0

99

9.940

0.5

4.0

99

2.099

9.9

20


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

" EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 16 of 74

TechLawQuali ty

105 W.Ma&wmSttHt, Suite 9000«afo,IL 60602

012)345-8990(312) 5454979 (Fix)tvww taddawintcom




Reported:

May-25-06 14:43



Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X15-F-1-6 (E604004-22) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

4100

70

1.2

1.7

25000

21

2.7

64

13000

460

13000

450

11

480U

96

15

340

Sampled: Apr-26-06

Result

3900

67

0.4

1.9

24000

19

2.4

64

11000

510

13000

370

Flags/Qualifiers

J

*

J*

*

J

K,'

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.828

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0100

10

20


1 EE60204 May-04-06May-08-06 EPA 200.711 " " " EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

14:45 Received: Apr-28-06 12:08

Flags/Qualifiers

JJ

*

J*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60204 May-04-06May-08-06 EPA 200.711 " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stepherftonnet, Chemist


Page 17 of 74

MawQtati t -r 6 la tcfr r iy

105 W,MidiwnStt«t, Suit. 900

(312)3454990(312) 34^979 (Fax)ivmsfJtthhTvinc.com



Project Manager Warren LayneReported:

May-25-06 14:43


X1S-F-1-6 (E604004-22) Soil Sampled: Apr-26-06 14:45 Received: Apr-28-06 12:08

Analyte

Nickel

Potassium

SilverSodiumVanadium

Zinc

X15-F-6-12 (E604004-23) Soil

AnalyteAluminum

BariumBeryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

NickelPotassium


Zinc

Result

13360V

11012

420

Sampled: Apr-26-06

Result

2500

400.2

U22000

9.62.136

8000

2401300020011

280U

71

8.0220

Flags/Qualifiers

*

K,*

MDL1.0220.8282.45.7

14:50 Received:

Flags/Qualifiers

«

*,JJ

J

**

*

LJJ

MDL12

0.20.20.4190.51.11.4244.1140.11.0220.8282.45.7

Limit Units

4.0 mg/kg1002.01001020

Apr-28-06 12:08

Limit Units

100 mg/kg1.01.02.01002.04.14.110010410.54.11002.01001020


1 EE60204 May-04-06May-08-06 EPA 200.7n

„

II 11 N

"n II n

Dilution Batch Prepared

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Analyzed Method

1 EE60205 May-04-06May-17-06 EPA 200.7n II N

"

n

II H M

n M n

.

« "„ .I. n

„

"

"

* II M

n II 1*

M

.

W « II

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stephen Comet, Chemist

000052Report Name: E605001 .E604004 FINAL May 25 06 1443

Page 18 of 74

ktilaw!05W.Midis<m$tntt,$ofc900

012)345-8990(312) 3454979 (Fax)www tef hhwinc MM



Reported:May-25-06 14:43



AnaJyte

Aluminum

BariumBeryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

(Magnesium

Manganese

NickelPotassium

SilverSodium

Vanadium

Zinc

X19-B-1-6 (E604004-25) Soil

Analyte

Aluminum

Barium

Beryllium

CadmiumCalcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

Result

4400

110

0.5

3.9

13000

32

3.0

75

16000

810

4300

430

16

510U

91

18

910

Sampled: Apr-26-06

Result

5100

130

0.6

5.2

12000

37

3.8

97

19000

1000

4000

460


12

* 0.2

J, * 0.2

0.4

19

0.5

J 1.1

1.4

24

* 4.0

* 14

0.1

« 1.0

22

L 0.8

J 28

2.4

5.6

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0100

10

20


1 EE6020S May-04-06 May- 17-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

16:55 Received: Apr-28-06 12:08

Rags/Qualifiers MDL

12

* 0.2

*, 1 0.2

0.4

19

0.5

J 1.1

1.424

* 4.0

• 14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60205 May-04-06May-17-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

Stephen connet, Chemist


Page 19 of 74

MLawQ u a l i t i t>

Qricafo,!L 6W02(312)3454990

(312) 3454979 (Fa)WWW tftfimTyiltf EMS




Reported:

May-25-06 14:43



Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X19-B-6-12 (£604004-26) Soil

AnalyteAluminum

BariumBeryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadVlagnesium

Manganese

NickelPotassium

Silver

Sodium

Vanadium

Zinc

Result

24530

1.7

130

21

1200

Sampled: Apr-26-06

Result

3400

110

0.6

3.6

13000

16

3.9

55

23000

800

5300

370

15

400

1.8

140

13

1000


* 1.0

22

J, L 0.8

28

2.4

5.6

17:00 Received:


12* 0.2

J, * 0.2

0.4

19

0.5

J 1.1

1.4

24

* 4.0

* 14

0.1

* 1.0

22

J,L 0.8

28

2.4

5.6

Limit Units

4.0 mg/kg

100

2.0

100

10

20

Apr-28-06 12:08

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20


1 EE60205 May-04-06May-17-06H n M M

.H M II It

„ „

H l» It H


1 EE60205 May-04-06 May- 17-06

» » " «

"„

„

(I H II 11

„

,,

,

,.

„ „

"

m r i M M

II II tt H

n H « M

"„II II N H

MethodEPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stephen Gerfnet, Chemist


Page 20 of 74

Ink-Law 105 W.Madtion Strut, Sofe 900Chic3fo,IL 60602

012)3454990(312) 3454979 (Fax)vtww




Reported:

May-25-06 14:43


X19-DZ (E604004-27) Soil Sampled: Apr-26-06 16:15 Received: Apr-28-06 12:08

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X19-F-0-1 (E604004-28) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

6900

120

0.8

6.1

10000

49

5.1

150

25000

1500

3500

800

33

540

1.0

110

30

1300

Sampled: Apr-26-06

Result

6100

140

0.7

43

15000

63

4.0

120

21000

1000

4900

640


12

» 0.2

J, * 0.2

0.4

19

0.5

1.1

1.4

24

* 4.1

* 14

0.1

* 1.0

22

J, L 0.8

28

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5

4.1

100

2.0

100

10

20


1 EE60205 May-04-06 May- 17-06 EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200. 7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

16:00 Received: Apr-28-06 12:08


12

* 0.2

J, * 0.2

0.4

19

0.5

1.1

1.4

24

* 4.0

* 14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60205 May-04-06May-17-06 EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 EPA 200.7

EPA 200.7

EPA 200.7

Stephen Cermet, Chemist


Page 21 of 74

Maw105 W.MidiwnStrt*, Suit* 900

Quef i t ?

012)3454990(312) 345-8979 (F«)•promt t»fMawinf torn



Reported:

May-25-06 14:43

Metals by ICP


Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X19-F-1-6 (£604004-29) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

NickelPotassium

Silver

Sodium

Vanadium

Zinc.

Result

23

640V

130

33

1100

Sampled: Apr-26-06

Result

5700

150

0.7

4.6

14000

55

4J

110

22000

1100

4800

490

24

550

1.5

160

22

1100


* 1.0

22

L 0.8

28

2.4

5.6

Limit Units

4.0 . mg/kg

100

2.0100

10

20


1 EE60205 May-04-06May-17-06n ii . «

„i.

,,

It II II n

Method

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

16:05 Received: Apr-28-06 12:08


12

* 0.2

*,J 0.2

0.4

19

0.5

1.1

1.4

24

* 4.0

* 14

0.1

* 1.0

22

J, L 0.8

28

2.4

5.6

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

1040

0.5

4.0

100

2.0

100

10

20


1 EE60205 May-04-06May-17-06„

,.

,, i.

,,

,,

II tt H ft

n n tt •

ii ti n n

n it ti n

«n

.

-

„

,,

,.

„

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stephen Conrjp< Chemist


Page 22 of 74

MawQta tn - t

ClikaÎL 60602012)3454990

(312) 3454979 (Fax)mtrtv




Reported:

May-25-06 14:43

X19-F-6-12 (E604004-30) Soil



AnalyteAluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X19-FD-6-12 (E604004-31) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese


3000

110 *

0.5 J, *

2.4

15000

16

3J J,K

52

19000

750 *

6100 *

320

13 *

330 K

1.2 J, L

140

11

880

Sampled: Apr-26-06 16:15


3000

100 *

0.5 J, *

2.6

15000

14

3.1 J, K

50

18000

610 »

6400 *

300

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.1

14

O.I

1.0

22

0.8

28

2.4

5.7

Received:

MDL120.20.2

0.4

19

0.5

1.1

1.4

24

3.9

14

0.1

Limit Units

100 mg/kg1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5

4.1

100

2.0

100

10

20

Apr-28-06 12:08

Limit Units

98 nig/kg1.0

1.0

2.0

98

2.0

3.9

3.9

98

9.8

39

0.5


1 EE60205 May-04-06May-17-06

-n n n it

„.„«.ii it n n

,.« II H II

„ „ „ ,,

II It « II

.

„

„

tt ft tl II

M M H •


1 EE60205 May-04-06May-17-06t* n ii n

it n H n

.. ,. H »

it n n M

"n

„

.

n

M M II n

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

000057

StephelrConnet, ChemistReport Name: E605001,E604004 FINAL May 25 06 1443

Page 23 of 74

khLaw 105 W.Madisan Start, Sato 900

Qiia f i t i *>

<312)34tt990(312) 3454979 (Fat)



Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX19-FD-6-12 (£604004-31) Soil Sampled: Apr-26-06 16:15 Received: Apr-28-06 12:08

Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X24-B-0-1 (£604004-32) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

13

350

1.5

140

11

830

Sampled: Apr-27-06

Result

4700

1400.65.2

29000

32

3.4

91

18000

1000

14000

580

16

410U

180

20

1100


* 1.0

K 22

J, L 0.8

28

2.4

5.5

Limit Units

3.9 mg/kg

98

2.0

98

9.8

20


1 EE60205 May-04-06 May- 17-06 EPA 200.711 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 EPA 200.7

16:00 Received: Apr-28-06 12:08


12* 0.2

J. * 0.2

0.4

19

0.5

J ,K »- l

1.4

24

« 3.9

» 14

0.1

* 1.0

K 22

L 0.8

28

2.4

5.5

Limit Units

9« mg/kg

1.0

1.0

2.0

98

2.0

3.9

3.9

98

9.839

0.5

3.9

98

2.098

9.8

20


1 EE60205 May-04-06 May- 17-06 EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.711 EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7



Page 24 of 74

Maw 105 W. Madison $ttHt,$afc 900€hxafo,IL 60602

012)3454990(312) 3454979 (Fax)wwro



Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX24-B-1-6 (£604004-33) Soil Sampled: Apr-27-06 16:05 Received: Apr-28-06 12:08

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X24-B-6-12 (E604004-34) Soil

Analyte

Aluminum

Barium

BerylliumCadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

3200

100

0.5

3.2

27000

14

3.2

45

15000

430

13000

340

11

320U

130

13

720

Sampled: Apr-27-06

Result

1600

25U

0.8

31000

5.6

1.8

7.9

5200

54

18000

170


12

* 0.2

*, J 0.2

0.4

19

0.5

J,K LI

1.4

24

* 4.0

* 14

0.1

* 1.0

K 22

L 0.8

28

2.4

5.5

16:10 Received:


12

* 0.2

» 0.2

J 0.4

19

0.5

J.K 1-1

1.4

24

* 4.1

» 14

0.1

Limit Units

99 mg/kg

1.0

1.0

2.0

99

2.0

4.0

4.0

99

9.9

40

0.5

4.0

99

2.099

9.9

20

Apr-28-06 12:08

Limit Units

100 mg/kg

1.0

1.02.0

100

2.0

4.1

4.1

100

10

41

0.5


1 EE6020S May-04-06 May- 17-06n n « n

,1 ,.

1,

„ „ II

. . . .

H n n n

,, *

H tt n n

. . . .II II H tt

it n tt n

n w n H

„„M M I I I I

.. n

II II . H


1 EE60205 May-04-06May-17-06M M 1 1 I t

tt it it it

n n n n

.It B 11 ||

M IP m n

II H tt tl

w it it n

.

. . .N N M M

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

000059

Stephen Conm, ChemistReport Name: E605001.E604004 FINAL May 25 06 1443

Page 25 of 74

Twhlaw$*e(H} £ I t i le j i iUf

105 WNMson Strut, Srate 900

012)34H990(312) 3454979 (Fa)

rÂbuw.

Superfijnd, US EPA Region 577 West Jackson BoulevardChicago IL, 60604



Reported:

May-25-06 14:43



Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X24-DZ (£604004-35) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

ChromiumCobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

7.5

250U

100

7.5

130

Sampled: Apr-27-06

Result

7400

160

1.1

7J

21000

37

5.3

130

23000

1300

9600

750

24

540

1.5

490

28

1600

Flags/Qualifiers

*

KL

J

MDL

1.0

22

0.828

2.4

5.7

Limit Units

4.1 mg/kg

100

2.0100

10

20


1 EE60205 May-04-06 May- 17-06 EPA 200.7

EPA 200.7

» EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

15:55 Received: Apr-28-06 12:08

Flags/Qualifiers

**

K

**

*

K

J,L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.8

28

2.4

5.6

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20


1 EE60205 May-04-06May- 17-06 EPA 200.7

EPA 200.711 EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

" " " ' EPA 200.7

EPA 200.7

EPA 200.711 EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

StephenlJonnet, Chemist

000060Report Name: E60500I ,£604004 FINAL May 25 06 1443

Page 26 of 74

Maw 105 W. Madivm Strut, Sate 900ChkarML 6MQ2

(312)3454990(312) 3454979 (Fax)xvmg




Reported:

May-25-06 14:43


X24-F-0-1 (E604004-36) Soil Sampled: Apr-27-06 15:25 Received: Apr-28-06 12:08

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X24-F-1-6 (E604004-37) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

3700

82

0.4

3.1

21000

17

2.5

61

13000

620

10000

400

11

380U

95

15

750

Sampled: Apr-27-06

Result

3400

88

0.5

3.2

24000

18

3.3

55

12000

560

12000

370

Hags/Qualifiers MDL

12

* 0.2

*, J 0.2

0.4

19

0.5

J.K 1.1

1.4

24

» 4.1

* 14

0.1

* 1.0

K 22

L 0.8

J 28

2.4

5.7

Limit

100

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5

4.1

100

2.0100

10

20

Units Dilution Batch Prepared Analyzed Method

mg/kg 1 EE60205 May-04-06 May- 17-06 EPA 200.7

" " " EPA 200.7

" EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

" " EPA 200.7

" " " EPA 200.7

" EPA 200.7

EPA 200.7

" " EPA 200.7

« - EPA 200.7

" " " EPA 200.7

" EPA 200.7

EPA 200.7

15:45 Received: Apr-28-06 12:08


12

* 0.2

J, * 0.2

0.4

19

0.5

J,K 1.1

1.4

23

* 3.9

* 14

0.1

Limit

98

1.0

1.0

2.0

98

2.0

3.9

3.9

98

9.8

39

0.5


mg/kg 1 EE60205 May-04-06May-17-06 EPA 200.7

EPA 200.7

" EPA 200.7

" EPA 200.7

" EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

' EPA 200.711 " " " EPA 200.7

" EPA 200.7

EPA 200.7

000061

Stephen Connet, ChemistReport Name: E605001.E604004 FINAL May 25 06 1443

Page 27 of 74

TediLaw 105W.Mad»oaSt»itJSwii900

<> I n t e g r i t y

(312)3454990(312) 3454979 (Fat)



Reported:

May-25-06 14:43

Metals by ICP


Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X24-F-6-12 (E604004-38) Soil

Analyte

Aluminum

Barium

BerylliumCadmium

CalciumChromium

Cobalt

CopperIron

LeadMagnesium

Manganese

Nickel

PotassiumSilverSodium

Vanadium

Zinc

Result

12320

U

110

13

850

Sampled: Apr-27-06

Result

1900

35U

0.9

22000

6.4

2.0

16

8300

14012000

180

7.5

240U

79

9.4

230

Flags/Qualifiers

»

K

L

MDL

1.0

21

0.827

2.3

5.5

15:50 Received:

Flags/Qualifiers

*

*

J

), K

**

*

K

LJ

J

MDL

12

0.2

0.20.4

19

0.5

1.1

1.4

24

4.014

0.1

1.0

22

0.828

2.4

5.5

Limit Units

3.9 . ing/kg

98

2.098

9.8

20

Apr-28-06 12:08

Limit Units

99 mg/kg

1.0

1.02.099

2.0

4.0

4.0

99

9.940

0.5

4.0

99

2.099

9.9

20


1 EE60205 May-04-06May-l7-06 EPA 200.7M It II

n n it

,,.,

" " »


EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

Analyzed Method

1 EE60205 May-04-06May-17-06 EPA 200.7

",,II II M

..

«

H II M

'

.

M M M

II II ft

-•I M ||

fl 11 «

-,

„

.

.

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 28 of 74

Techlaw}*(r/rf ; i ; l a l c f f t l r

105 W, Madison Stnit, Safc 900Chicago, H 60602

(312)345-8990(312) 3454979 (Fa)



Reported:

May-25-06 14:43



Analyle

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X26-B-1-6 (E604004-40) Soil

Aiialyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

4600

130

0.7

2.8

26000

29

3.3

95

14000

630

12000

520

15

540U

210

19

700

Sampled: Apr-27-06

Result

4900

200

0.8

3.7

23000

80

3.7

83

16000

1400

11000

400

Hags/Qualifiers MDL

12

* 0.2

J, * 0.2

0.4

18

0.5

J,K 1.1

1.4

23

* 3.9

* 14

0.1

* 1.0

K 21

L 0.8

27

2.3

5.4

Limit Units

97 mg/kg

1.0

1.0

1.9

97

1.9

3.9

3.9

97

9.7

39

0.5

3.997

1.997

9.7

19


1 EE60205 May-04-06 May- 17-06 EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

16:50 Received: Apr-28-06 12:08


12

* 0.2

»,J 0.2

0.4

19

0.5

K,J 1.1

1.4

24

» 4.0

* 14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


I EE60205 May-04-06May-17-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

000063

StepheriOonnet, ChemistReport Name: E605001,E604004 FINAL May 25 06 1443

Page 29 of 74

TechLaw$*afit}

105 W.MitamStnit, Safe 900Queafo, ft. 60602

012) 345-890(312) 3454979 (Fix)WWWJ




Reported:

May-25-06 14:43



|Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X26-B-6-12 (E604004-41) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

18

570U

160

19

920

Sampled: Apr-27-06

Result

2400

63

0.3

13

24000

12

2.7

22

6900

64013000

180

17

320U

94

10

370

Flags/Qualifiers

*

K

L

MDL

1.0

22

0.828

2.4

5.7

17:00 Received:

Flags/Qualifiers

*

J, *

S

3.K.

4

*

*

K

L]

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.014

0.1

1.0

22

0.828

2.4

5.7

Limit Units

4.0 mg/kg

100

2.0100

10

20

Apr-28-06 12:08

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

1040

0.5

4.0

100

2.0100

10

20


1 EE60205 May-04-06May-17-06„ „ „ „

.

.

n n it *

n n m M


1 EE60205 May-04-06May-17-06n i. »

• M M tt

„„it n ti ii

. . . .„.. . . ...n n n w

n M w n

n K M it

N n M n

. . . .,.

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stephen'Connet, Chemist


Page 30 of 74

TedilawQua l i t y

105 W.Maduoa Strut, Sate 900Oucafo,IL 60602

012)M5-8990(312) 5454979 (Fa)

Superfimd, US EPA Region 5




Reported:

May-25-06 14:43



Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X26-F-0-1 (£604004-43) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

4900

2100.62.8

26000

32

3.7

64

13000

870

12000

450

18

530U

160

17

730

Sampled: Apr-27-06

Result

5000

120

0.7

4.1

25000

28

3.4

96

15000

880

11000

570

Flags/Qualifiers

*

*,J

K,J

*

*

*

K

L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.828

2.4

5.5

Limit Units

99 mg/kg

1.0

1.0

2.0

99

2.0

4.0

4.0

99

9.9

40

0.5

4.0

99

2.099

9.9

20


1 EE60205 May-04-06 May- 17-06 EPA 200.7

" EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

11 " " EPA 200.711 " " EPA 200.7

" " " EPA 200.7

16:25 Received: Apr-28-06 12:08

Flags/Qualifiers

**

J, **

LJ*

K,*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

3.9

14

0.1

Limit Units

98 mg/kg

1.0

1.0

2.0

98

2.0

3.9

3.9

98

9.8

39

0.5


1 EE60206 May-04-06 May- 11 -06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 31 of 74

MawQ u a l i t y

105 W. Madron Stmt, Sate 900Qricafo,lL 60602

(312)3454990(312) 3454979 (F«)tmrar ttehbwtnc com



Reported:

May-25-06 14:43


X26-F-0-1 (E604004-43) Soil Sampled: Apr-27-Ofr 16:25 Received: Apr-28-06 12:08

Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X26-F-1-6 (£604004-44) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

CobaltCopper

IronLead

Magnesium

Manganese

NickelPotassium


Zinc

Result

164901.014017

1000

Sampled: Apr-27-06

Result

3500

97

0.6

3.5

24000

14

2.7

57

12000

690

12000

370

11

330U

120

12

860

Flags/Qualifiers

t

J

*

K,'

MDL

1.0

22

0.8

27

2.4

5.5

Limit Units

3.9 mg/kg

98

2.0

98

9.8

20


1 EE60206 May-04-06May-ll-06 EPA 200,7

EPA 200.7

" " " EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

16:30 Received: Apr-28-06 12:08

Flags/Qualifiers

*

*

J,*

*

L

J4

K,*

#

*

K. *

MDL

12

0.2

0.20.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.828

2.4

5.5

Limit Units

99 mg/kg

1.0

1.0

2.0

99

2.0

4.0

4.099

9.9

40

0.5

4.0

99

2.099

9.9

20


1 EE60206 May-04-06May-l 1-06 EPA 200.7

" EPA 200.7

EPA 200.711 " " " EPA 200.7

EPA 200.7

EPA 200.711 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200. 7



Page 32 of 74

Tedilaw* I n t e g r i t y

lOSW.MxfoonStmt, Son 900Chica|o,IL 60602

(312)3454990(312) 3454979 (Fix)



Reported:

May-25-06 14:43

X26-FD-1-6 (£604004-45) Soil

Metals by ICP

TechLaw - ESAT ContractSampled: Apr-27-06 16:30 Received: Apr-28-06 12:08

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

SodiumVanadium

Zinc

X26-F-6-12 (£604004-46) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

3600

920.6

3.4

25000

14

2.9

58

11000

630

12000

390

12

330

1.5

130

12

870

Sampled: Apr-27-06

Result

2000

42

0.3

1.1

22000

5.7

1.6

17

5800

150

11000

170

Flags/Qualifiers

*

»

J, *

*

L

J*

K.,*

*

J

*

K,*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

O.I

1.0

22

0.8

28

2.4

5.6

16:35 Received:

Flags/Qualifiers

*

*

J, *

J, *

L

J*

K,*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.014

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20

Apr-28-06 12:08

Limit Units

99 mg/kg

1.0

1.0

2.099

2.0

4.0

4.0

99

9.9

40

0.5


1 EE60206 May-«4-06May-l 1-06 EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.711 * " EPA 200.7

EPA 200.711 EPA 200.7

" " " " EPA 200.7

EPA 200.71 1 1 1 " " E P A 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7


1 EE60206 May-04-06May-ll-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 " " " EPA 200.7

EPA 200.7

EPA 200.7



Page 33 of 74

Maw( f i f f / r f ; t f l u t t f n i r

105 W.MadiwnSiwtt, Safe 900OiicafD,IL 60602

(312)54^990(312) 3454*79 (F«)

Super-fund, US EPA Region 577 West Jackson BoulevardChicago IL, 60604


Reported:

May-25-06 14:43



Analylc

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X46-B-0-1 (£60400*47) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

8.4

200

1.2

80

5.8

210

Sampled: Apr-27-06

Result

12000

200

1.0

6.1

17000

51

6.1

310

31000

9006500

860

40

890V

100

30

1300

Flags/Qualifiers

*

J

J

J, *

K.*

MDL

1.0

22

0.8

28

2.4

5.6

Limit Units

4.0 mg/kg

99

2.099

9.9

20


1 EE60206 May-04-06May-l 1-06 EPA 200.7

" " »

fl ti n

U N N

.

it ii n

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

14:45 Received: Apr-28-06 12:08

Flags/Qualifiers

*

*

*,J*

L

*

K,*

4

*

*,K

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.1

14

0.1

1.0

22

0.828

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

1041

0.5

4.1

100

2.0100

10

20


1 EE60206 May-04-06May-H-06 EPA 200.7H . „

* n H

n n n

„n

.,

.

n ii n

,,ii n n

"ii « n

« ii ii

.II M It

» tl H

„

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

StepWsiTConnet, Chemist


Page 34 of 74

Tedilaw 105W.Madi«m$tntt,S«fc900drop, H. 60602

012)3454990(312) 345^79 (Fa)www.techlawmo com




May-25-06 14:43



Analyte

AluminumBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseNickelPotassiumSilverSodiumVanadiumZinc

X46-B-6-12 (E604004-49) Soil

Analyte

Aluminum

Barium

Beryllium

CadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganese

Result95004900.984

25000

60

7.7

530

88000

1300

8900

900

60

750U

170

25

4700

Sampled: Apr-27-06

Result

5600

290

1J

7.5

17000

23

6.3

1300

38000

1600

7100

470


* 12

* 0.2

J, * 0.2

» 0.4

19

L 0.5

1.1

* 1.4

24

K, « 3.9

14

O.I

1.0

• 22

0.828

* 2.4

K, * 11

14:55 Received:Flags/

Qualifiers MDL

« 12

* 0.2

* 0.2

* 0.4

19

L 0.5

1.1

* 1.4

24

*, K 4.0

14

0.1

Limit Units

98 mg/kg

1.0

1.0

2.0

98

2.0

3.9

3.9

98

9.8

39

0.5

3.9

98

2.098

9.839

Apr-28-06 12:08

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60206 May-04-06 May-1 1 -06N N n n

n ti n n

,,.II II II M

n ii

ii n N H

« II II H

II II It *

.

» II II H

M ii H n

II It W II

n n M ii

n « ti H

n «

2 " " May-ll-06


1 EE60206 May-04-06 May-1 1-06n n . .

„

« it H «

n M H n

„..II II tl M

it n ii it

* n n it

MethodEPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

StephefrConnet, Chemist


Page 35 of 74

:Z< TedilawQual i ty

105 W. Madison SfcNt,Srii 900Qnc*fD,IL{0602

012)3454990(312) 545^979 (Fa)


Project: US Smelter and Lead Refinery, Inc.

Project Number: [none]Project Manager: Warren Layne

Reported:

May-25-06 14:43



Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X46-DZ (£604004-50) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lend

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

120

540V

230

19

1500

Sampled: Apr-27-06

Result

12000

170

1.0

6.1

22000

57

7.2

290

32000

8408800

980

38

750I)

180

33

1500


1.0

» 22

0.828

* 2.4

K,* 5.7

Limit

4.0

100

2.0100

10

20

Units

mg/kg"H

"

•

"

Dilution Batch Prepared Analyzed Method |

1 EE60206May-04-06May-ll-06 EPA 200.7

" " " " EPA 200.7EPA 200. 7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

14:05 Received: Apr-28-06 12:08


* 12

* 0.2

* 0.2

* 0.4

19

L 0.5

1.1

* 1.4

24

K,' 4.0

14

0.1

1.0

* 22

0.828

* 2.4

K,* 5.6

Limit

100

1.0

1.0

2.0

100

2.0

4.0

4.0

100

1040

0.5

4.0

100

2.0100

10

20

Units

mg/kg»

»

•

•>M

-"

-

"

H

"

-

"

"

•

"

•


1 EE60206 May-04-06May-ll-06 EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " ' EPA 200.7

" " " " EPA 200.7

EPA 200.7» " I - • E P A 200.711 " " " EPA 200.7

EPA 200.7

EPA 200.7



Page 36 of 74

IkhLaw 105 W.Madisoa $!»«,$«* 900

Q t a l i t i

012)3454990(312) 3454979 (Fix)wnrw ttcbbnvinc com





Reported:

May-25-06 14:43



Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lend

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X46-F-1-6 (E604004-S2) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

11000

1601.05.4

24000

52

5.3

250

27000

690

9900

820

30

920V

140

27

1100

Sampled: Apr-27-06

Result

10000

180

1.0

5.0

24000

43

5.5

230

28000

680

9400

720


* 12

* 0.2

* 0.2

* 0.4

19

L 0.5

1.1

* 1.4

24

K, * 3.9

14

0.1

1.0

* 22

0.828

* 2.4

K,* 5.5

Limit Units

99 mg/kg

1.0

1.0

2.0

99

2.0

3.9

3.9

99

9.939

0.5

3.9

99

2.099

9.9

20


1 EE60206 May-04-06May-ll-06 EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.711 ' ' EPA 200.7

EPA 200.7

EPA 200.711 " " EPA 200.7

" EPA 200.7

EPA 200.7

" EPA 200.7

" EPA 200.7

EPA 200.7

" EPA 200.7» " • EPA 200.7

" EPA 200.7

EPA 200.7

" " " ' EPA 200.7

14:15 Received: Apr-28-06 12:08


* 12

* 02

» 0.2

* 0.4

18

L 0.5

1.1

* 1.4

23

K,* 3.9

14

0.1

Limit Units

97 mg/kg

1.0

1.0

1.9

97

1.9

3.9

3.9

97

9.7

39

0.5


1 EE60206 May-04-06May-i 1-06 EPA 200.7

EPA 200.711 " " ' EPA 200.7

EPA 200.7

EPA 200.711 " " ' EPA 200.7

" " ' " EPA 200.7

EPA 200.7

" - EPA 200.7

' " " EPA 200.7

EPA 200.7

EPA 200.7

Stephen Gennet, Chemist


Page 37 of 74

MLaw 105 \OMson Start, Safe 900ChicafD,E 60602

012)3454990

www



Reported:

May-25-06 14:43


X46-F-1-6 (E604004-52) Soil Sampled: Apr-27-06 14:15 Received: Apr-28-06 12:08> •'

Analyte

NickelPotassium

SilverSodium

Vanadium

Zinc

X46-FD-1-6 (E604004-53) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

36

760U

190

26

1200

Flags/Qualifiers

*

*

1C,'

MDL

1.0

21

0.827

2.3

5.4

Sampled: Apr-27-06 14:20 Received:

Result

9900

180

1.0

5.1

25000

44

5.8

220

32000

67010000

750

31

720U

170

25

1200

Flags/Qualifiers

*

*

J, **

L

*

K,*

4

*

K,*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.114

0.1

1.0

22

0.828

2.4

5.7

Limit Units

3.9 mg/kg

97

1.997

9.7

19

Apr-28-06 12:08

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

1041

0.5

4.1

100

2.0100

10

20


1 EE60206 May-04-06May-ll-06 EPA 200.7

" " " EPA 200.7

» EPA 200.7

" " " " EPA 200.7

" " " " EPA 200.7

EPA 200.7


1 EE60206 May-04-06May-ll-06 EPA 200.7

" EPA 200.7

" EPA 200.7

EPA 200.7

" EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 EPA 200.7

" " " " EPA 200.7

" EPA 200.7

" EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7



Page 38 of 74

Tedilaw( f i f f f f f f ; <> l u t r i f i l ?

105 W. Madison Stn*t,Soite 900CbJcap,!! 60602

(312)3454990(312) 3454979 (Fat)WUTV ttAbivinc com

Superftind, US EPA Region 5




Reported:

May-25-06 14:43

X46-F-6-12 (E604004-54) Soil



Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X48-B-0-1 (£604004-55) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

4400

930.6

2.8

32000

17

3.3

70

21000

250

13000

340

36

590V

200

13

490

Sampled: Apr-27-06

Result

6700

80

0.5

2.0

15000

38

3.5

110

13000

290

6800

400

Flags/Qualifiers

*

*

*,J*

L

J*

'.K.

*

*

*, K

MDL12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.1

14

0.1

1.0

22

0.828

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5

4.1

100

2.0100

10

20


1 EE60206 May-04-06May-ll-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" " ' " EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

11:00 Received: Apr-28-06 12:08

Flags/Qualifiers

4

*

J, *

J,*

LJ*

K,*

MDL12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.1

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

1041

0.5


1 EE60206 May-04-06May-ll-06 EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7



Page 39 of 74

<Maw 105 W.Maduo&Stntf, Suite 900,IL 60602

012)3454990(312) 3454979 (Fax)



Reported:

May-25-06 14:43


X48-B-0-1 (E604004-S5) Soil Sampled: Apr-27-06 11:00 Received: Apr-28-06 12:08

Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X48-B-1-6 (£604004-56) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lend

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

15

620U

76

16

480

Sampled: Apr-27-06

Result

740087

0.7

2.9

17000

30

3.4

150

13000

360

8400

440

23

580U

100

18

730

Flags/Qualifiers

*

J

*

K,*

MDL

1.0

22

0.829

2.4

5.7

Limit Units

4.1 mg/kg

100

2.0100

10

20


1 EE60206 May-04-06May-l 1-06 EPA 200.7

EPA 200.7

• EPA 200.7

" EPA 200.7

EPA 200. 7

EPA 200.7

11:05 Received: Apr-28-06 12:08

Flags/Qualifiers

*

*

J, **

L

J

*

K,*

*

*

K,*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.114

0.1

1.022

0.828

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

1041

0.5

4.1

100

2.0100

10

20


1 EE60206 May-04-06May-ll-06 EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.711 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stephen Comet, Chemisteport Name: E605001.E604004 FINAL May 25 06 1443

Page 40 of 74

Tedilaw !05W. Madison StrMt,$afo 900Chicago, H 60602

(312)3454990(312) 345-8979 (Fsx)WWW ctf uiAWtflC Ôd




Reported:

May-25-06 14:43

X48-B-6-12 (E604004-57) Soil

Metals by ICP


Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X48-DZ (£604004-58) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

3300

120

OJ

1.6

24000

10

2.5

45

8400

170

13000

230

16

390U

84

11

290

Sampled: Apr-27-06

Result

7300

130

0.5

3.3

24000

29

3.7

170

15000

460

11000

460

Flags/Qualifiers

*

*

J, *

J, *

L

J*

K,*

*

J*

K, *

11:15 Received

Flags/Qualifiers

*

*

J, **

L

J*

K,*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.828

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0100

10

20


1 EE60206 May-04-06May-ll-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

: Apr-28-06 12:08

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60206 May-04-06May-l 1-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

000075

Stephen Comet, ChemistReport Name: E605001,E604004 FINAL May 25 06 1443

Page 41 of 74

MUwI t t t j t n t Y

drop, K. 60602012)3454990

(312) 3454979 (F«)



Reported:

May-25-06 14:43



Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X48-F-0-1 (E604004-59) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

PotassiumSilver

Sodium

VanadiumZinc

Result

20490D

13017

720

Sampled: Apr-27-06

Result

6000

85

0.5

1.4

13000

24

3.5

98

12000

1504800

350

16

500U

62

16

300

Flags/Qualifiers

4

*

K, * .

MDL

1.0

22

0.828

2.4

5.6

Limit Units

4.0 mg/kg

100

2.0100

10

20


1 EE60206 May-04-06May-II-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 " " " EPA 200.7

EPA 200.7

1 1 :30 Received : Apr-28-06 1 2 :08

Flags/Qualifiers

*

*

*,J

*,J

L

J*

K, *

*

J*

K, *

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.114

0.1

1.0

22

0.8282.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

1041

0.5

4.1

100

2.0100

10

20


1 EE60206 May-04-06May-l 1-06 EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7


000076

Report Name: E605001JE604004 FINAL May 25 06 1443

Page 42 of 74

Maw Qnc*fo,IL 60602(312)3454990

Q u a l i t y www t*cWawinc tons



Reported:

May-25-06 14:43



Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X48-F-6-12 (E604004-61) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

6800

93

0.6

2.3

17000

22

3.3

130

14000

290

7900

430

18

450U

110

18

520

Sampled: Apr-27-06

Result

4000

61

0.4

2.5

25000

15

2.4

87

15000

280

13000

330

Flags/Qualifiers

*

*

J,**

L

J

*

K,'

*

*

K, *

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

23

3.9

14

O.I

1.0

21

0.827

2.3

5.5

11:40 Received:

Flags/Qualifiers

*

*

J, *'*

L

J*

K, *

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

Limit Units

98 mg/kg

1.0

1.0

2.0

98

2.0

3.9

3.9

98

9.8

39

0.5

3.9

98

2.098

9.8

20

Apr-28-06 12:08

Limit Units

100 mg/fcg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60206 May-04-06May-ll-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7


1 EE60206 May-04-06May-ll-06 EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 " " EPA 200.7

EPA 200.7

Stephen (fefinet, Chemist

000077Report Name: E605001,E6Q4004 FINAL May 25 % 1443

Page 43 of 74

Techlaw 105 W. Madison Strut, Sate 900Clkafo,IL 60602

012)3454990

www tecfchmnnc cam

Superfimd, US EPA Region 577 West Jackson BoulevardChicago IL, 60604



May-25-06 14:43



Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X50-B-0-1 (E604004-62) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

ManganeseNickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

15

300U

100

13

590

Flags/Qualifiers

*

*

K, *

MDL

1.0

22

0.828

2.4

5.6

Limit Units

4.0 mg/kg

100

2.0100

10

20


1 EE60206 May-04-06May-ll-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7


Result

4400

150

0.6

4.6

22000

27

3J

110

16000

9109700

560

17

470

0.9

120

17

1100

Flags/Qualifiers

*

*

J, **

L

J*

*,K

*

J

*

if t

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.014

0.1

1.0

22

0.8

28

2.4

5.6

Limit Units

100 tug/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

1040

0.5

4.0

100

2.0

100

10

20


1 EE60206 May-04-06May-ll-06 EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

" ' ' EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 44 of 74

105 \V. Madison Stew, Suite 900

l i t t t f f i l f

(312)345^990(31?) 3454979 (Fax)




May-25-06 14:43



Aiialyte

Aluminum

Bnrium

Beryllium

Cadmium

Calcium

Chromium

Cuba It

Copper

Iron

LeadMagnesiumManganese

NickelPotassium

Silver

SodiumVnnadium

Zinc

XSO-B-6-12 (£604004-64) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

CalciumChromium

CobaltCopper

IronLead

Magnesium

Manganese


3800 L

150 *

0.5 J

5.4 *

18000

20

3.0 J, *

110

16000

1500

8400

440

17 *

390

1.7 J, L

100 +

15

1500

MDL

12

0.2

0.2

0.4

18

0.5

1.1

1.4

23

3.9

14

O.I

1.0

21

0.8

27

2.3

5.4



2400 L

74 *

0.4 J

1.7 J, *

14000

8.2

2.6 J, •

29

7600

270

7200

240

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.1

14

0.1

Limit Units

97 mg/kg

1.0

1.0

1.9

97

1.9

3.9

3.9

97

9.7

39

0.5

3.9

97

1.9

97

9.7

19

Apr-28-06 12:08

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5


I EE60207 May-04-06May-12-06H ii ri tt

II II It H

ii «

,,

„

"

" " " "

H ti n n

ii ti n n

H n n M

n n n n

*

N H n n

w 11 n n

.„H II II M


1 EE60207 May-04-06 May- 12-06n

„

„

„ I.

»

N M n ii

H H (I II

I.

II H H H

n ii ii n

ii H n H

Method

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

000079


Page 45 of 74

TechLawQteDt} <v Ig tegr t t ?

105 W. Madison $ttwt,Soxit 900

012)3454990(312) 545^979 (Fix)

com





Reported:

May-25-06 14:43


X50-B-6-12 (£604004-64) Soil Sampled: Apr-27-C>6 09:50 Received: Apr-28-06 12:08

Ajialyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X50-DZ (E604004-6S) Soil

Aiialyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lend

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc


12 *

280

0.9 J, L

90 J, *

10 J

730

MDL

1.0

22

0.8

28

2.4

5.7

Limit Units

4.1 mg/kg

100

2.0

100

10

20


1 EE60207 May-04-06 May- 12-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7



6500 L

240 *

1.6

9.0 *

19000

26

5.2 *

150

22000

2300

8700

61029 *

600

4.4 L

240 *

28

2600

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.014

0.1

1.0

22

0.8

28

2.4

5.6

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

1040

0.5

4.0

100

2.0

100

10

20


1 EE60207 May-04-06 May- 12-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

" EPA 200.7

" EPA 200.711 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

" EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7



Page 46 of 74

r<Tedilaw105 W Madison Stntt,Soiti 900

l i t t t f r i l y

(312)3454990(312) 3454979 (Fa)www ttddminc com




Reported:

May-25-06 14:43



Aiialyte

Aluminum

Barium

Beryllium

Cadmium

Cnlcium

Chromium

Cobalt

CopperIron

Lend

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X50-F-1-6 (E604004-67) Soil

Analyte

Aluminum

Barium

BerylliumCiidmium

Calcium

Chromium

CobaltCopper

Iron

Lend

Magnesium

Manganese


4900 L

110 *

0.6 J

3.6 *

26000

303.7 J, *

9814000

83011000

59015 *

510

1.0 J, L

110 *

171200

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

O.I1.0

22

0.8

28

2.4

5.5

Limit Units

99 mg/kg

1.0

1.02.0

99

2.0

4.0

4.0

99

9.9

40

0.5

4.0

99

2.099

9.9

20


1 EE60207 May-04-06 May- 12-06 EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.711 " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Sampled: Apr-27-06 09: 10 Received: Apr-28-06 12:08


3200 L

63 *

0.4 J

2.7 *

26000

14

2.4 J, *

65

11000

520

13000

370

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60207 May-04-06 May- 12-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

" EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

000081


Page 47 of 74

Techlaw 105 W. Madtwa Strwt, Sort* 900Qucato. IL 60602

Qta t i t i(312) 345̂ 979 (Fix)\vufiv



Reported:

May-25-06 14:43


X50-F-1-6 (E604004-67) Soil Sampled: Apr-27-06p9:10 Received: Apr-28-06 12:08

Analyte

Nickel

Potassium


Zinc

X50-F-6-12 (£604004-68) Soil

Analyte

Aluminum

Barium

Beryllium

Cndmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

13

320V

110

13

1000

Flags/Qualifiers

*

L*

MDL

1.0

22

0.828

2.4

5.6


Result

1800

23

0.2

1.0

29000

5.7

2.1

12

5400

8815000

180

7.0

260U

89

6.9

250

Flags/Qualifiers

L*

J

J,*

J, *

*

L '

J, *

J

MDL

12

0.2

0.2

0.4

19

0.5

l.l

1.4

24

4.014

0.1

1.0

22

0.828

2.4

5.7

Limit Units

4.0 rng/kg

100

2.0100

10

20

Apr-28-06 12:08

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0100

10

20


1 EE60207 May-04-06 May- 12-06n n H M

»„„

" " " "


1 EE60207 May-04-06 May- 12-06„

«„

„ ,.

n n n n

n M n n

« ft H It

. i n . .M H n n

n • n ii

H H 11 H

II II 1* M

,.

n M M n

.„. . . . .

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 48 of 74

MLawQ u a l i t y

,IL 60602012)3454990

(312) 3454979 (F«)www




May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX10-B-0-1 (E605001-04) Soil Sampled: May-01-06 11:00 Received: May-02-06 11:21

Analyte


X10-B-1-6 (£605001-05) Soil

Aiialyte

AluminumBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLendMagnesiumManganese

Result

7400

320

1.7

3.9

24000

35

5.5

120

25000

1300

7400

630

22

830

1.0

360

24

970

Sampled: May-01-06

Result

7600

380

2.0

4.1

24000

34

5J

100

24000

1100

7100

620


L 12

* 0.2

0.2

* 0.4

19

0.5

* 1.1

1.4

24

4.1

14

O.I

* 1.0

22

J, L 0.8

» 28

2.4

5.7

11:20 Received:

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5

4.1

100

2.0

100

10

20

May-02-06 11:21

Hags/Qualifiers MDL Limit Units

L 12

* 0.2

0.2* 0.4

19

0.5

• 1.1

1.4

24

4.1

14

0.1

100 mg/kg1.01.02.0100

2.0

4.1

4.1

100

10

41

0.5

Dilution Batch Prepared Analyzed Mediod

1 EE60207 May-04-06May-12-06 EPA 200.7

" " " " EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7


1 EE60207 May-04-06May-12-06 EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7


000083

Report Name: E605001.E604004 FINAL May 25 06 1443

Page 49 of 74

MLaw 105 W. Madison Sttnt, Safe 900

I g t t g r i t f

012)3454990(312) 3454979 (F«)




May-25-06 14:43


X10-B-1-6 (£605001-05) Soil Sampled: May-01-06 11:20 Received: May-02-06 11:21

Aiialyte

NickelPotassiumSilverSodiumVanadiumZinc

XlO-B-6-12 (£605001-06) Soil

Analyte

AluminumBariumBerylliumCadmiumCnlciumChromiumCobaltCopperIronLendMagnesiumManganeseNickelPotassiumSilverSodiumVanadiumZinc


24 *

760

1.0 L, J

430 *

24

970

MDL

1.0

22

0.8

28

2.4

5.7

Sampled: May-01-06 11:25 Received:


5100 L

240 *

1.4

2.4 *

18000

13

3.6 J, *

53

12000

890

7400

240

18 *

460

0.9 J, L

320 *

16

600

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

3.914

0.1

1.0

22

0.8

28

2.4

5.5

Limit Units

4.1 mg/kg

100

2.0

100

10

20

May-02-06 11:21

Limit Units

98 mg/kg

1.0

1.0

2.0

98

2.0

3.9

3.9

98

9.839

0.5

3.9

98

2.0

98

9.8

20


1 EE60207 May-04-06 May- 12-06 EPA 200.7ti it n

It It N

ft w n

H n H

m m m


EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

Analyzed Method

1 EE60207 May-04-06 May- 12-06 EPA 200.7H n n

„II II N

"

„

„

" " «

" " »

"

n

n n n

n n n

.,

.

n n ii

it n n

.

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7


000084

Report Name: E605001,E604004 FINAL May 25 06 1443Page 50 of 74

lediLaw 105 W.MadisoDStmt, Soil 900Oucafo,IL 60602

012)3454990(312) 3454979 (Fax)wnro taAbninnc cam




Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX10-DZ (E605001-07) Soil Sampled: May-01-06 10:50 Received: May-02-06 11:21

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X10-F-0-1 (£605001-08) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

11000

410

2.8

5.1

35000

37

5.3

140

25000

1500

8900

880

28

990

1.0

460

29

1200

Sampled: May-01-06

Result

4700

130

0.7

3J

23000

25

3.3

64

13000

840

9400

440


L 12

* 0.2

0.2

• 0.4

19

0.5

* 1.1

1.4

24

4.1

14

0.1

« 1.0

22

J, L 0.8

* 28

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5

4.1

100

2.0

100

10

20


1 EE60207 May-04-06May-12-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 " " ' EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " ' EPA 200.711 EPA 200.7

10:35 Received: May-02-06 11:21


L 12

* 0.2

J 0.2

* 0.4

18

0.5

J,« 1.1

1.4

23

3.9

14

O.I

Limit Units

97 mg/kg

1.0

1.0

1.997

1.9

3.9

3.9

97

9.7

39

0.5


1 EE60207 May-04-06May-12-06 EPA 200.7

" EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

000085


Page 51 of 74

Maw105W.Madis«Sl»t, Suite 900

(jtalit?

(312)545^90(312) 3454979 (Fa)

Superftmd, US EPA Region 577 West Jackson BoulevardChicago IL, 60604



Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX10-F-0-1 (£605001-08) Soil Sampled: May-01-06 10:35 Received: May-02-06 11:21

Analyte

Nickel

Potassium


Zinc

X10-F-1-6 (£605001-09) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

12

620U

130

15

780

Sampled: May-01-06

Result

3800

110

0.6

3.5

16000

17

2.9

57

11000

7507400

390

15

410U

130

13

760

Flags/Qualifiers

*

L*

MDL

1.0

21

0.827

2.3

5.4

Limit Units

3.9 mg/kg

97

1.997

9.7

19


1 EE60207 May-04-06May-12-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

10:40 Received: May-02-06 11:21

Flags/Qualifiers

L*

J4

J , »

*

L*

MDL

12

0.2

0.2

0.4

19

o.s1.11.4

24

4.114

0.1

1.0

22

0.828

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

1041

0.5

4.1

100

2.0100

10

20


1 EE60207 May-04-06 May- 12-06 EPA 200.7

" " " EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

Stephen'connet, Chemist


Page 52 of 74

Maw 105 W.Madisott Strut, Sufr 900

$*afil}

(312)3454990(312) 3454979 (Fix)




May-25-06 14:43

X10-FD-1-6 (E60500MO) Soil


Sampled: May-01-06 10:45 Received: May-02-06 11:21

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

PotassiumSilver

Sodium

Vanadium

Zinc

X10-F-6-12 (E6050G1-11) Soil

Aiialytc

Aluminum

BariumBeryllium

Cadmium

Calcium

ChromiumCobaltCopper

IronLead

Magnesium

Manganese


4100 L

120 *

0.6 J

4-3 »

24000

19

3.1 J, *

64

11000

870

11000

380

12 *

440

1.2 J, L

130 *

13

840

MDL

12

0.2

0.2

0.4

18

0.5

1.1

1.4

23

3.9

140.1

1.0

21

0.8

27

2.3

5.4



3100 L

110 *

0.7 J '

2.0 J, *

17000

10

2.6 J, *

31

10000

310

7300

220

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.1

14

0.1

Limit Units

97 mg/kg

1.0

1.0

1.9

97

1.9

3.9

3.9

97

9.7

39

0.5

3.997

1.997

9.7

19

May-02-06 11:21

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5


1 EE60207 May-04-06 May- 12-061, M 1.

n H n .

.

N n n n

.H M tt II

» I..

n M

n n

n n it «

H n n n

.„

•-II II 1* N


1 EE60207 May-04-06 May- 12-06n n H II

„ ,.

II II n m

H II II H

M O H n

N M n n

• • • i n

* M m n

tt n « n

II H N |,

N ft N It

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 53 of 74

Maw 105 W.Midiwm Strut, Suite 900

Q t e l i t j

<312)S4M990(312) 3454979 (Fa)TOTCTP




May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX10-F-6-12 (£60500]-]])Soil Sampled: May-01-06 10:47 Received: May-02-06 11:21

Analyte

NickelPotassium

SilverSodium

Vanadium

Zinc

X13-B-0-1 (E605001-12) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

CalciumCliromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

12

290U

150

12

420

Flags/Qualifiers

*

L*

MDL

1.0

22

0.828

2.4

5.7

Limit Units

4.1 rag/kg

100

2.0100

10

20


1 EE60207 May-04-06May-12-06 EPA 200.7

",,n n li

it H n

H N m

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Sampled: May-01-06 09:20 Received: May-02-06 1 1:21

Result

4200

130

0.6

3.5

20000

32

5.0

75

29000

940

8000

480

19

480V

170

16

760

Flags/Qualifiers

L*

J*

*

*

L*

MDL

12

0.2

0.2

0.4

18

0.5

1.1

1.4

23

3.914

O.I

(.0

21

0.827

2.3

5.4

Limit Units

97 mg/kg

1.0

1.0

1.9

97

1.9

3.9

3.9

97

9.739

0.5

3.9

97

1.997

9.7

19


1 EE60207 May-G4-06May-12-06 EPA 200.7ir ii M

H n M

m m n

n n n

H H m

It N M

H fl II

n ti H

,,

n M n

n n H

,

H M h

tl N II

,

M

«

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7


000088Report Name: E605001,E604004FINALMay2506 1443

Page 54 of 74

MLawQua/Hi

105W.Madi«m$ttietl$<ifo900Chicafo,E 60602

(312)3454990(312) 345-8979 (Fat)www ttfhhminf COBS



Reported:

May-25-06 14:43


X13-B-1-6 (E605001-13) Soil Sampled: May-01-06 09:25 Received: May-02-06 11:21

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X13-B-6-12 (E605001-14) Soil

Ajialyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese


3800 L

130 *

0.6 J

3.4 *

16000

19

3.9 J, *

68

ISOOO

690

6600

340

16 *

410

U L140 *

20

810

MDL12

0.2

0.2

0.4

20

0.5

I.I

1.4

25

4.1

14

0.1

1.023

0.829

2.5

5.8



2500 L

67 *

0.4 J

2.2 *

19000

8.6

3.2 J, *

28

10000

260

9100

220

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.1

14

O.I

Limit Units

100 mg/kg

1.0

1.0

2.1

100

2.1

4.1

4.1

100

1041

0.5

4.1

100

2.1100

10

21

May-02-06 11:21

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5


1 EE60207 May-04-06May-12-06 EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.711 EPA 200.7

EPA 200.7

" " " " EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.711 EPA 200.7


1 EE60207 May-04-06May-12-06 EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7


OOOOS9Report Name: E605001,E604004 FINAL May 25 06 1443

Page 55 of 74

TediLawQaat i t? i>

105 W. Madison SttMt,Sqi* 900Chicago, H, 60602

012) 3454990(312) 3454979 (Fa)

Superfiind, US EPA Region 5

77 West Jackson Boulevard

Chicago IL, 60604



Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX13-B-6-12 (E605001-14) Soil Sampled: May-01-06 09:45 Received: M»y-02-06 11:21

Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X13-DZ (E605001-15) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

13

33011

100

12

390

Sampled: May-01-06 09

Result

4100

200

0.5

3.0

23000

44

6.0

61

14000

1000

9900

400

14

530U

260

15

750

Flags/Qualifiers

*

L*

MDL

1.0

22

0.828

2.4

5.7

Limit Units

4.1 mg/kg

100

2.0100

10

20


1 EE60207 May-04-06May-12-06 EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

:1S Received: Mty-02-06 11:21

Flags/Qualifiers

L*

J*

*

*

L*

MDL

12

0.2

0.2

0.4

20

0.5

1.1

1.4

25

4.114

0.1

1.0

23

0.829

2.5

5.7

Limit Units

100 mg/kg

1.0

1.0

2.1

100

2.1

4.1

4.1

100

1041

0.5

4.1

100

2.1100

10

21


1 EE60207 May-04-06 May- 12-06 EPA 200.711 " " " EPA 200.7

" " " " EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

" " " ' EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7- " - EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7



Page 56 of 74

MawQuality

105 W. Madison Start, Sate 900Oiicaf^H 60602

(312)3454990(312) 3454979 (Fat)

com




Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX13-F-0-1 (E60S001-16) Soil Sampled: May-01-06 09:00 Received: May-02-06 11:21

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X13-F-1-6 (£605001-17) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

5100

170

0.7

5.0

20000

97

4.0

100

15000

1500

7500

560

18

500

1.7

130

IS

1200

Sampled: May-01-06

Result

3100

66

0.5

2.7

14000

11

2.2

57

10000

530

6500

300


L 12

* 0.2

J 0.2

* 0.4

19

0.5

J,* 1-1

1.4

24

4.0

14

0.1

* 1.0

22

J, L 0.8

« 28

2.4

5.7

Limit Units

100 mg/lcg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20


1 EE60207 May-04-06 May- 12-06 EPA 200. 7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.711 " " ' EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

" " " " EPA 200.7

" " " EPA 200.7

09:05 Received: May-02-06 11:21


L 12

* 0.2

J 0.2

* 0.4

19

0.5

J,* 1.1

1.4

24

4.1

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5


1 EE60207 May-04-06May-12-06 EPA 200.7

" EPA 200.7

" " " EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.711 " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7



Page 57 of 74

MawQ u a l i t y $

!05W. Madison Stwt,Suta 900Obc3fo,H 60602

012)34tt990(312) 3454979 (Fa)




Project Number: [none]


Reported:

May-25-06 14:43


X13-F-1-6 (£605001-17) Soil Sampled: May-01-06 09:05 Received: May-02-06 11:21

Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X13-F-6-12 (E605001-18) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

9J

310U

98

10

750

Flags/Qualifiers

*

LJ, *

MDL

1.0

22

0.829

2.4

5.7

Sampled: May-01-06 09: 10 Received:

Result

1900

35

0.2

0.9

15000

5.4

2.0

33

6100

1507000

160

8.1

230U

65

7.5

240

Flags/Qualifiers

»

J

*,J*

t

*,J

K*

**

*

L

LJ

J

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

23

3.914

0.1

1.0

21

0.827

2.3

5.5

Limit Units

4.1 mg/kg

100

2.0100

10

20

May-02-06 11:21

Limit Units

98 mg/kg

1.0

1.0

2.0

98

2.0

3.9

3.9

98

9.839

0.5

3.9

98

2.098

9.8

20


1 EE60207 May-04-06May-12-06 EPA 200.711 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7


1 EE60208 May-04-06May-15-06 EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

" EPA 200.7

" " " " EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.711 " " " EPA 200.7

" EPA 200.7

" EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 58 of 74

MLaw(iir/ 'f;

Chicafo,IL 60602012)3454990

(312) 5454979 (Fn)www techiawinc.com




May-25-06 14:43



Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

NickelPotassium

SilverSodium

Vanadium

Zinc

X35-B-1-4 (E605001-20) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

CalciumChromium

CobaltCopper

Iron

LeadMagnesium

Manganese

Result

6000

75

0.5

0.8

15000

17

6.2

34

13000

120

5500

460

13

1000U

54

15

160

Sampled: May-01-06

Result

9400

930.50.7

13000

19

8.5

36

18000

120

5500

530

Flags/Qualifiers

*

J

J, *4

*

*

K*

*

*

*

L

LJ

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.1

14

0.1

1.0

220.8

28

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5

4.1

100

2.0100

10

20


1 EE60208 May-04-06May-I5-06M K H H

n n n n

„„„it ti n n

„N n n n

„„H U M I t

ii •( M n

f it m jv

M M H I I

• n ti ii

„

U N i i n

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

16:30 Received: May-02-06 11:21

Flags/Qualifiers

*

J

*,J4

*

*

K*

4

*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60208 May-04-06 May- 15-06ti H n H

H H n M

n ii H n

ii H « N

„

n x H n

n

. . . .

. . .

« . . n

« n n n

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

000093


Page 59 of 74

Tedilaw , Said 900

Qaal i t?

(312)3454990(312) 545^979 (Fax)WWW




May-25-06 14:43



Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X35-B-6-12 (E605001-21) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc


19

1300

U

78

21

160

Sampled: May-01-06

*

L

LJ

MDL

1.0

22

0.828

2.4

5.6

16:35 Received:


6100

75

0.5

1.2

25000

24

4.9

42

15000

17012000

530

22

740U

9117

190

4

JJ, *

**4

K

*

*

*

*

L

LJ

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.014

O.I

1.0

22

0.828

2.4

5.6

Limit Units

4.0 mg/kg

100

2.0100

10

20

May-02-06 11:21

Limit Units

99 mg/kg

1.0

1.0

2.0

99

2.0

4.0

4.0

99

9.940

0.5

4.0

99

2.099

9.9

20


1 EE60208 May-04-06May-15-06 EPA 200.7

" " " EPA 200.7

EPA 200.7

" EPA 200.711 " " EPA 200.7

EPA 200.7


1 EE60208 May-04-06May-15-06 EPA 200.711 " " " EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

" " " " EPA 200.7

" EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

" " " EPA 200.7

" - » EPA 200.7

EPA 200.711 " " EPA 200.7

EPA 200.7



Page 60 of 74

TedilawQ t a l i t ?

105 W. Madison Sttttt, Safe 900Chica|o,IL 60602

(312)3454990(312) 5454979 (Fix)

com




Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX3S-DZ (E605001-22) Soil Sampled: May-01-06 16:20 Received: May-02-06 11:21

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X35-F-0-1 (E605001-23) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

6400

82

0.4

0.6

15000

14

6.6

26

13000

69

5600

450

17

920U

54

15

130

Sampled: May-01-06

Result

6000

74

0.6

1.0

32000

17

4.1

36

14000

92

9800

450

Flags/Qualifiers

4

J

*,J

*

*

*

K

*

*4

4

L

LJ

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.1

14

0.1

1.0

22

0.828

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5

4.1

100

2.0100

10

20


1 EE60208 May-04-06May-15-06 EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

» " • EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

1 6:00 Received: May-02-06 11:21

Flags/Qualifiers

4

J

J,*

4

4

4

K4

4

4

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

3.9

14

0.1

Limit Units

99 mg/kg

1.0

1.0

2.099

2.0

3.9

3.999

9.9

39

0.5


1 EE60208 May-04-06 May- 15-06 EPA 200. 7

" EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 61 of 74

TediLawQxsf i t?

105 W.Mxfcon Start, So* 900Oric3|otIL 60602

(312)3454990(312) 3454979 (F«)

tefMarvinr com


Chicago IL, 60604




Reported:

May-25-06 14:43


X3S-F-0-1 (E605001-23) Soil Sampled: May-01-06. 16:00 Received: May-02-06 11:21

Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X3S-F-1-6 (E60S001-24) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

12

770V

110

14

180

Sampled: May-0 1-06

Result

8200

96

0.8

1.1

25000

20

5J

52

18000

130

8300

590

22

900U

130

19

250

Flags/Qualifiers

*

L

L

MDL

1.0

22

0.828

2.4

5.5

Limit Units

3.9 nig/kg

99

2.099

9.9

20


1 EE60208 May-04-06May-15-06 EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.71 1 1 1 • " E P A 200.7

16:05 Received: May-02-06 1 1:21

Flags/Qualifiers

*

JJ, *

*

*

*

K*

*

*

*

L

L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.828

2.4

5.6

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0100

10

20


1 EE60208 May-04-06 May- 15-06 EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

" EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7" " « EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7



Page 62 of 74

TediLawf> l u l t g r i l ?

105 W.MidisonSttMt, $aj*90001X310,1160602

(312)3454990(312) 345̂ 979 (Fn)warn r•fMan'tng NMB




Reported:

May-25-06 14:43

X35-F-6-12 (E60500I-25) Soil



Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X42-B-0-1 (E605001-26) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

8700

120

1.0

1.5

39000

16

4.1

SO

15000

140

11000

820

22

810U

190

16

260

Sampled: May-01-06

Result

5600

180

0.7

5.5

29000

48

5.4

120

23000

1400

13000

810

Flags/Qualifiers

*

*,J*

*

*

K*

*

t

»

L

L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.828

2.4

5.6

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0100

10

20

Dilution Batch

1 EE60208M H

"i,

.

„

M f>

-,

n n

ii n

n n

« ti

n n

,,....M

II M

Prepared Analyzed Method

May-04-06May-15-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

15:05 Received: May-02-06 11:21

Flags/Qualifiers

*

J*

*

*

*

K*

*

*

MDL

12

0.2

0.2

0.4

18

0.5

1.1

1.4

23

3.9

14

0.1

Limit Units

97 mg/kg

1.0

1.0

1.9

97

1.9

3.9

3.9

97

9.7

39

0.5

Dilution Batch

1 EE60208M N

".

.

,,

» n

«

„

n

H II

H N


May-04-06May-15-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

000097Stephen Connet, Chemist

Report Name: E605001 ,E604004 FINAL May 25 06 1443

Page 63 of 74

MawQttt i t?

105 W. Madison Stmt, SaiH 90001)090,0.60602

(312)3454990(312) 345-8979 (Ftt)




May-25-06 14:43



Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X42-B-1-6 (E605001-27) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

23

710U

150

25

1400

Sampled: May-01-06

Result

3800

150

0.6

3.9

27000

23

3.9

73

17000

76013000

440

14

450V

150

16

1000

Flags/Qualifiers

*

L

L

MDL

1.0

21

0.827

2.3

5.4

Limit Units

3.9 mg/kg

97

1.997

9.7

19


1 EE60208 May-04-06May-15-06N « n n

.„ii M n n

•i n M n

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

15:10 Received: May-02-06 11:21

Flags/Qualifiers

*

J***

J,*K4

*

*

4

L

L '

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.014

0.1

1.0

22

0.828

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

1040

0.5

4.0

100

2.0100

10

20


1 EE60208 May-04-06May-15-06m n

U N n H

it N n n

n ti n n

„..H M II ||

i. « n

..

H ft M H

I.

n n n n

n H • H

»

H N II It

H

« n « it

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 64 of 74

Maw105 W. Madison Stmt, Safe 900

dik3|o,IL 60602012)J4M990




May-25-06 14:43

X42-B-6-12 (E605001-28) Soil



Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X42-DZ (E605001-29) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

2200

45

0.2

1.0

24000

6.9

2.8

18

11000

100

13000

250

9.7

290U

859.4

190

Sampled: May-01-06

Result

3600

120

0.5

3.8

30000

23

4.2

64

15000

760

14000

420

Flags/Qualifiers '

*

J

*,J*

*

*,J

K

*

*4

*

L

LJ

J

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.022

0.828

2.4

5.5

Limit Units

99 mg/kg

1.0

1.0

2.099

2.0

4.0

4.099

9.9

40

0.5

4.0

99

2.0

99

9.9

20


1 EE60208 May-04-06May-15-06 EPA 200.7

EPA 200.7

" EPA 200.7

" EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.711 " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

•• - " EPA 200.71 1 1 1 " " E P A 200.7

" EPA 200.7

EPA 200.7

15:00 Received: May-02-06 11:21

Flags /Qualifiers

•

J*

**

*

K*

*

*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60208 May-04-06May-15-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

Stepheif Connet, Chemist


Page 65 of 74

Maw105 W. Madium Stmt, Suit* 900

Chk*fo,!L 60602(312)3454990


Chicago IL, 60604




Reported:

May-25-06 14:43


X42-DZ (£605001-29) Soil Sampled: May-01-06 J5:00 Received: May-02-06 11:21

Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X42-F-0-1 (£605001-30) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

14

410U

120

14

950

Sampled: May-01-06

Result

5300

97

0.5

3.4

19000

35

3.9

110

18000

740

8000

660

18

530U

250

24

850

Flags/Qualifiers

*

L

L

MDL

1.0

22

0.828

2.4

5.6

Limit Units

4.0 mg/kg

100

2.0100

10

20


1 EE60208 May-04-06May-l5-06 EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

15:20 Received: May-02-06 11:21

Flags/Qualifiers

*

J

*

*

t

J, *

K

*

*

*

*

L

L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

244.1

14

O.I

1.0

22

0.829

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5

4.1

100

2.0100

10

20


1 EE60208 May-04-06 May- 15-06 EPA 200.7

" EPA 200.711 " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

" EPA 200.7

" " " " EPA 200.7

Stephen Q^nnet, Chemist

oooiooReport Name: E605001 .E604004 FINAL May 25 06 1443

Page 66 of 74

TediLawQtal i t )

105 W. Madison Strut, Sob 900Chica|o,IL 60602

012)3454990(312) 545-8979 (Fix)wnmr fechbwmc torn

Superilind, US EPA Region 577 West Jackson BoulevardChicago IL, 60604



Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT Contract

X42-F-1-6 (E605001-31) Soil Sampled: May-01-06 15:25 Received: May-02-06 11:21

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X42-F-6-12 (E6050G1-32) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese


4300

86

0.5

3.4

22000

22

3.3

70

16000

560

10000

480

14

340U

170

17

920

Sampled: May-01-06

*

J

*

*

*

J ,»

K*

*

*

*

LL

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

O.I

1.022

0.828

2.4

5.7

15:30 Received:

Flags/Result Qualifiers1900

44

0.2

1.1

24000

6.9

2.6

16

7100

180

13000

210

*

JJ,«

**

*,JK*

*

*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0100

10

20

May-02-06 11:21

Limit Units

100 mg/kg

1.01.02.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60208 May-04-06 May- 15-06 EPA 200.7

EPA 200.7

EPA 200.711 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.71 1 1 1 " " E P A 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

" " " " EPA 200.7

" " " EPA 200.7

EPA 200.7


1 EE60208 May-04-06May-15-06 EPA 200.711 EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

" " " EPA 200.7

EPA 200.7

" EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7



Page 67 of 74

TechLaw105 W.Maduon Strut, Safe 900

ChJcafo,IL 60602012)3454990

(312) 3454979 (F«)



Reported:

May-25-06 14:43


X42-F-6-12 (E60500U2) Soil Sampled: May-OI-06 15:30 Received: May-02-06 11:21

Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X49-B-0-1 (£605001-33) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

7.S

240U

120

7.4

260

Sampled: May-01-06

Result

7500

180

0.8

2.8

38000

35

3.8

130

22000

1100

7200

53021

880

1.0

110

23

740

Flags/Qualifiers

*

L

L

J

MDL

1.0

22

0.828

2.4

5.7

Limit Units

4.0 mg/kg

100

2.0100

10

20


1 EE60208 May-04-06May-15-06II It H H

ii m m H

„«n u n n

MethodEPA 200.7EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

12:15 Received: May-02-06 11:21

Flags/Qualifiers

4

J

*

*

4

J, *

K

*

*

4

»L

J,L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.11.0

22

0.8

282.4

5.6

Limit Units

99 mg/kg

1.0

1.0

2.0

99

2.0

4.0

4.099

9.9

40

0.5

4.0

99

2.0

99

9.9

20


1 EE60208 May-04-06May-15-06* « H «

M ii n n

•i « n n

* M M *

n n it H

n ii * t,

H • n h

» it n n

H ti n *

11 It H N

n it n n

"

« M it «

ft H it ir

H n N H

.

N n n n

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7


000102Report Name: E605001JE604004 FINAL May 25 06 1443

Page 68 of 74

ledilawK>5W.Madi«mS»tt,Sqfr900

012)3454990(312) 3454979 (Fix)

com




Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX49-B-1-6 (£605001-34) Soil Sampled: May-01-06 12:20 Received: May-02-06 11:21

AnalyteAluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

NickelPotassium

Silver

Sodium

Vanadium

Zinc

X49-B-6-12 (E605001-35) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese


9700

180 *

1J

2.8 *

24000 *

28 *

5.0 *

120 K

24000 *

2800 *

4400 *

440

27 *

790 L

3.4 L

180

25

890

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.8

28

2.4

5.7



5500

220 *

13

3.1 *

29000 *

21 *

4.8 *

110 K

21000 *

1100 *

9600 *

340

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

23

3.9

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20

May-02-06 11:21

Limit Units

97 mg/kg

1.0

1.0

1.9

97

1.9

3.9

3.9

97

9.7

39

0.5


1 EE60208 May-04-06May-15-06 EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.711 " " " EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

" EPA 200.7

EPA 200.7


1 EE60208 May-04-06 May- 15-06 EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

000103

Stephen COB&CT, ChemistReport Name: E605001.E604004 FINAL May 25 06 1443

Page 69 of 74

Maw105 W.Mjdiam Strut, Sato 900

QuufD, IL 60602012)345-8990

(312) 545^79 (Fa)


Chicago IL, 60604



Reported:

May-25-06 14:43


X49-B-6-12 (£605001-35) Soil Sampled: May-01-Q6 12:25 Received: May-02-06 11:21

Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X49-DZ (£605001-36) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

30

660

2.2

230

20

1100

Sampled: May-01-06

Result

9600

330

1.2

5.5

18000

68

7.5

270

31000

3000

7800

880

41

580

1.4

160

44

2500

Flags/Qualifiers

*

L

L

MDL

1.0

21

0.8

27

2.3

S.5

Limit Units

3.9 mg/kg

97

1.9

97

9.7

19


1 EE60208 May-04-06May-15-06 EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

" EPA 200.7

" " " EPA 200.7

12:10 Received: May-02-06 11:21

Flags/Qualifiers

4

*

4

4

*

K

*

*

*

*

L

J.L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

23

3.914

0.1

1.0

21

0.8

27

2.3

5.5

Limit Units

98 mg/kg

1.0

1.0

2.0

98

2.0

3.9

3.9

98

9.839

0.5

3.9

98

2.0

98

9.8

20


1 EE60208 May-04-06May-15-06 EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

" EPA 200.7

" EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

Stephen CoMet, Chemist


Page 70 of 74

TechUwQ x e l H j $ l i i t e g t t t r

(312)5454990(312) 3454979 (Fa)

.com




May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX49-F-0-1 (E605001-37) Soil Sampled: May-01-0£ 11:45 Received: May-02-06 11:21

Analyte


X49-F-1-6 (£605001-38) Soil

Analyte

Aluminum

Barium

BerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganese

Result100002100.95.4

25000

67

5.9

250

26000

980

11000

890

36

890

1.1

150

31

2400

Sampled: May-01-06

Result

10000

230

1.0

6J

19000

46

6.6

220

26000

1000

8900

700

Flags/Qualifiers

*

J*

*

*

*

K**

4

*

L

J, L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.1

14

O.I

1.0

22

0.8

29

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5

4.1

100

2.0

100

10

20


1 EE60208 May-04-06May-15-06 EPA 200.7

" EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

" EPA 200.7

" EPA 200.7

" EPA 200.711 EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.711 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

1 1 :50 Received: May-02-06 11:21

Flags/Qualifiers

*

*

*

*

*

K

*

*

*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

O.I

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60208 May-04-06May-l 5-06 EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

000105


Page 71 of 74

Maw 105 W. Madison Stmt, Safe 900

Q*eti t] i

012)3454990(312) 345-W9 (Fa)trortp



Reported:

May-25-06 14:43


X49-F-1-6 (E60S001-38) Soil Sampled: May-01-06 11:50 Received: May-02-06 11:21

JAnalvte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X49-F-6-12 (E605001-39) Soil

|AnalyteAluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

NickelPotassium

Silver

SodiumVanadium

Zinc


35

830U

150

33

2200

Sampled: May-01-06

*

L

L

MDL

1.0

22

0.828

2.4

5.6

11:55 Received:


4300

150

0.6

2.5

26000

26

3.5

60

15000

58014000

370

14

440

1.0

150

15

920

*

J*

*

*

J, *

K*

4

*

*

L

J,L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.8

28

2.4

5.6

Limit Units

4.0 mg/kg

100

2.0100

10

20

May-02-06 11:21

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

1040

0.5

4.0

100

2.0

100

10

20


1 EE60208 May-04-06May-15-06n ti n H

I,n

,H n H n


1 EE60208 May-04-06May-I5-06n n H H

n H n n

N M II *

W tl N H

II II M It

,,

n n n n

w n n n

II H H II

..

.n it tt n

« M n M

.-. . .» n H M

Method

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stephen Connet, ISfiemist


Page 72 of 74

Mlaw 105 W. Madison Stmt, Safe 900Chxafo,IL 60602

(312)345^990

Qsali l? com



Reported:

May-25-06 14:43

X49-FD-6-12 (E605001-40) Soil



Analyte

AluminumBarium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

4800

130

0.7

2.6

26000

27

4.4

74

15000

640

13000

400

18

490

1.1

230

16

1000

Flags/Qualifiers

*

J4

*

*

*

K*

*

*

*

L

J.L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.8

28

2.4

5.6

Limit

100

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20


mg/kg 1 EE60208 May-04-06May-15-06 EPA 200.7ii n tt n

H M H n

N M II H

„

it ii n n

,H N II It

II H II N

„

.

.

M

.

.

N • H N

„

„

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7


000107

Report Name: E605001.E604004 FINAL May 25 06 1443Page 73 of 74

TediLawQ t a t i t j r f l i t t t f f i t y

105 W.MidUa&Smtt, Sate 900ChkafD,IL 60602

(312)3454990(312} 3454979 (Fn)wmr te toet




Reported:

May-25-06 14:43

Notes and Definitions

X U

L The identification of the analyte is acceptable; the reported value may be biased low. The actual value is expected to be greaterthan the reported value.

K The identification of the analyte is acceptable; the reported value may be biased high. The actual value is expected to be less thanthe reported value.

J The identification of the analyte is acceptable; the reported value is an estimate.

< 5X One or both concentration values for the duplicate analysis audit were less than 5 times the MDL value AND the differencebetween the two values was less than the MDL value. The duplicate audit is acceptable. No qualification made for this QC audit

* The duplicate analysis precision is not within control limits The reported value is estimated.

# Spike audit not valid. The sample concentration exceeds twice the concentration of the spike added No qualification made for thisQC audit.

U Not Detected

NR Not Reported

000108

Stephen Cermet, ChemistReport Name: E605001,E604004 FINAL May 25 06 1443

Page 74 of 74


Work Order SF ^feo^f- US u

Chain-of-Custody on file

LIMS Invoice #

Q TDF Completion form signed by TOPO

Of Analytical and Data Review Checklist

Of Transmittal Memo w/signatures of the following:

• Analyst(s)


Prepared byEnvironmeinalTData Coordinator

Date:

Subject:

From:

To:





MAY 2 6 2006


Stephen Connet, Chemist, TechLaw Inc. / ESATContractor to Region 5 Central Regional LaboratorySubmitted to CRL on


CRL data set number(s): E604004, E605001 (waters only)

Samples analyzed for: ICP Metals (including Sb, As, Cd, Pb, Se, Tl)

Results are reported for sample designations: E604004-01, -02, E605001-01 thru -03

2 6/?oas7 I

Data/ManagementtGoordinator and Date Received

^ * T •« A MAY. 2 6 200SDate Transmitted: / /



Sylvia GriffinData Management CoordinatorRegion 5 Central Regional LaboratoryML-10C

07Received by and Date

Comments:




Results are reported for sample designations: £604004-01, -02, E605001-01 thru -03

Rev. 4/10/02

Method: 200.7 (ICP Metals)Site: US Smelter and Lead Refinery, Inc.Date: May 9,2006Prepared by: Stephen Connet

Io f3TDF: R5-01-004,5TechLaw Job #: 03037.1.01.02.01.053J.000.004,5Task Order #: R5-0-01Data Sets: E604004, £605001

NARRATIVE

Five (5) water samples from the US Smelter and Lead Refinery, Inc. site were collected between April 26 andMay 1,2006 and were received properly preserved at CRL on April 28 and May 2,2006. The samples weresubmitted to ESAT for analysis of total metals by ICP. The sample point identifications are listed on the firstpage of the LIMS report following this narrative.

The water samples were digested following standard CRL 200.2 hot block digestion protocols (CRL SOPMETALS025) on May 3, 2006 (LIMS digestion batch EE60203). The samples were analyzed on May 5, 2006according to CRL SOP METALS003 using the Optima 4300. Recently reevaluated (not listed inMETALS003) U.S. EPA MDL/RL values were used for evaluation of the data per Dr. J. V. Morris becausechanges were made to the instrument and ESAT has not had an opportunity to perform new MDL/RLevaluations.


Sb, Al, As, Ba, Be, Ca, Cd, Cr, Co, Cu, Fe, Pb, Mg, Mn, Ni, K, Se, Ag, Na, Tl, V, Zn

The following lists the case pertinent out-of-control QC audit check results based on ESAT QA/QC limits:

Blanks: Instr. Blank 1

Instr. Blank 2

Co 228Ni231V292

Ni231V292

0.36 ug/L0.71 ug/L0.60 ug/L

0.54 ug/L0.69 ug/L

RL Check Soln: Presently no "control" actions are associated with the observed RL analyte valuesactually determined during the analysis run. RL check solution values currently arebeing analyzed for purposes of generating a benchmark set of values which can be usedto monitor the appropriateness of any given RL level of analyte concentration. Valuesare subject to change pending further repairs on the instrument. U.S. EPA and ESATRL solutions were analyzed in the April 25, 2006 analytical run.

Duplicate:EE60203-DUP1 (E604004-01): Ag328, A1396, Asl93, Be313, Cd226, Co228, Cr267 <5X

Cu327, Fe259, Mn257, Pb220, Sb206, Se 196, Tl 190 <5XBa455, V292, Zn213 * (difference > MDL)Na589 * (RPD > ESAT limit)

<5X: Sample and/or duplicate <5X MDL; duplicate difference acceptable (<MDL).*: Indicates out of control result (ESAT limits)

2 of 3Note: Although the duplicate difference is greater than the MDL for Be313, Cd226, Cu327 and Sb206, bothsample and duplicate values are less than the MDL and the difference is considered acceptable.


Control limits are normally set according to ESAT control charts. However, not enough data points forinstrument checks have been analyzed to determine ESAT control limits. Those control limits are setaccording to EPA limits. ESAT control limits are used for matrix QC.

For Ba, the sample and laboratory duplicate were less than 5X the MDL; duplicate difference is used for thecontrol criteria. The matrix duplicate difference is greater than the MDL indicating possible poor precision; allBa sample results and EE60203-DUP1 are flagged "*" in LIMS due to possible poor precision. Also, thesample results for E604004-01 and E605001-01 are greater than the MDL but less than the RL; Ba for thosesamples are flagged "J" in LIMS.

For Ca, the sample results for E604004-02, E605001-02 and -03 are greater than the MDL but less than theRL; Ca for those samples are flagged "J" in LIMS.

For Co, one of the instrument blanks had a value greater than the MDL indicating possible contamination.Sample results for E604004-02 and E605001-01 are flagged "K" in LIMS due to the possible contamination.Additionally, sample results for E604004-02 and E605001-01 are greater than the MDL but less than the RL;Co for those samples are also flagged "J" in LIMS.

For Cr, the sample result for E605001-02 is greater than the MDL but less than the RL; Cr for that sample isflagged "J" in LIMS.

For Cu, the sample results for E605001-01 thru -03 are greater than the MDL but less than the RL; Cu forthose samples are flagged "J" in LIMS.

For Fe, all Fe results were reported from the Fe 259 line. The sample results for E604004-02 and E605001-01are greater than the MDL but less than the RL; Fe for those samples are flagged "J" in LIMS.

For Mg, all results are reported from the Mg 280 line.

For Mn, the sample results for E604004-01 and E605001-02 are greater than the MDL but less than the RL;Mn for those samples are flagged "J" in LIMS.

For Na, the duplicate RPD was greater than the ESAT limit indicating possible poor precision; all Na sampleresults and EE60203-DUP1 are flagged "*" in LIMS due to possible poor precision.

For Se, the sample result for E604004-02 is greater than the MDL but less than the RL; Se for that sample isflagged "J" in LIMS.

For V, both of the instrument blanks had values greater than the MDL indicating possible contamination. Thesample results for E604004-02, E605001-01, and -02 are flagged "K" in LIMS due to the possiblecontamination. Also, the sample was less than the MDL and laboratory duplicate were less than 5X the MDL;duplicate difference is used for the control criteria. The matrix duplicate difference is greater than the MDL (fa

" ,rf'

3 of 3indicating possible poor precision; all V sample results and EB60101-DUP1 are also flagged "*" in LIMS dueto possible poor precision. Finally, the sample results for E604004-02, E605001-01, and -02 are greater thanthe MDL but less than the RL; V for those samples are also flagged "J" in LIMS.

For Zn, the laboratory duplicate was less than 5X the MDL; duplicate difference is used for the controlcriteria. The matrix duplicate difference is greater than the MDL indicating possible poor precision; all Znsample results and EE60203-DUP1 are flagged "*" in LIMS due to possible poor precision. Also, all sampleresults are greater than the MDL but less than the RL; all Zn sample results are flagged "J" in LIMS.


Other comments

No samples were identified as field duplicates or field blanks.

It has been observed that, due to differences in the significant figures used for calculation, RPD values andsome matrix spike recoveries calculated by LIMS are not correct. The correct values are included as Excelspreadsheets in the Analytical/Matrix QC Summary Report provided in the data package.

TediLaw 105 W, Madison Sw^Sai* 900

l u t r f r i l y

(312)3454990(312) 3454979 (Fax)

com




Reported:

May-19-06 11:21


Sample ID Laboratory ID Matrix Date Sampled Date Received

Auger 1

Auger 2

Auger 3

Auger 4

Auger 5

E604004-01

E604004-02

E605001-01

E605001-02

E605001-03

Water

Water

Water

Water

Water

Apr-26-06 12:45 Apr-28-06 12:08

Apr-27-06 13:55 Apr-28-06 12:08

May-01-06 12:05 May-02-06 11:21

May-01-06 14:55 May-02-06 11:21

May-01-06 16:40 May-02-06 11:21

000011

Stephen <£piuiet, ChemistReport Name: E605001,E604004 FINAL May 19 06 1121

Page 1 of6

lediLawQte l i t j

10$ W. Madison S&Mt,Soiti 900Qucaco,!L 60(02

<312)34M990(312) 3454979 ffa)




Reported:

May-19-06 11:21


Auger 1 (E604004-01) Water Sampled: Apr-26-06.12:45 Received: Apr-28-06 12:08

Analyte

Aluminum

Antimony

Arsenic

Barium

Beryllium

Cadmium

Calcium

Chromium

CobaltCopper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Selenium

Silver

Sodium

ThalliumVanadium

Zinc

Auger 2 (£604004-02) Water

Analyte

AluminumAntimony

Arsenic

Barium

Beryllium

CadmiumCalcium

Chromium

Cobalt

Result

VVu1.0uu

4150Uuu

52.2U

341

0.9

81.1

5230UU

820UU

19.5

Sampled: Apr-27-06

ResultUUuVuV

72.0

U

OJ


25.4

3.03.3

i, * 0.4

0.1

0.357.9

0.40.20.916.3

2.55.9

J 0.4

0.5

92.3

7.00.7

* 4S.9

6.7• 0.3

J, * 3.9

Limit Units

100 ug/L

20.0

20.0

3.0

1.02.0200

5.03.05.050.0

15.0

100

1.0

3.0

800

30.0

5.0400

20.0

5.030.0


1 EE60203 May-03-06May-05-06 EPA 200.7« •• " EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

» » • EPA 200.7

EPA 200.7

EPA 200.7•• » " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

" " ' " EPA 200.7« " • EPA 200.7

EPA 200.7

EPA 200.7

13:55 Received: Apr-28-06 12:08


25.4

3.03.3

* 0.4

0.1

0.3J 57.9

0.4

J, K 0.2

Limit Units

100 ug/L

20.0

20.0

3.01.02.0200

5.03.0


1 EE60203 May-03-06May-05-06 EPA 200.7EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stephen Carmet, Chemist


Page 2 of6

Tediaw 105 W.KdduonStsNt, Sate 900

012)3454990(312) 3454979 (Fa)


Project: US Smelter and Lead Refinery, Inc.Project Number [none]


Reported:

May-19-06 11:21

Metals by ICP

TechLaw - ESAT ContractAuger 2 (£604004-02) Water Sampled: Apr-27-06,13:55 Received: Apr-28-06 12:08

Analyte

CopperIron

LeadMagnesiumManganeseNickel

PotassiumSelenium

SilverSodiumThalliumVanadium

Zinc

Auger 3 (E605001-01) Water

Analyte

AluminumAntimonyArsenicBarium

BerylliumCadmiumCalciumChromiumCobalt

Copper

Iron

LeadMagnesiumManganeseNickel

PotassiumSeleniumSilver

ResultU

24.7UU

U

48.9

U

8.5UUU

0.5

8.1

Sampled: May-01-06

ResultUUU

0.5VUUU

0.2

1.7

43.0

VUU

34.8

UUU


0.9J 16.3

2.55.90.40.5

92.3

J 7.0

0.7* 45.9

6.7

J, K, • 0.3

J, * 3.9

12:05 Received:

Limit Units

5.0 ug/L

50.0

15.0

1001.03.0

80030.0

5.040020.0

5.0

30.0

May-02-06 11:21


25.4

3.03.3

J, * 0.4

O.I0.3

57.9

0.4

J, K 0.2

J 0.9

J 16.3

2.55.90.40.5

92.3

7.00.7

100 ug/L

20.0

20.0

3.0

1.02.02005.03.0

5.0

50.0

15.0

1001.03.0

80030.0

5.0


1 EE60203 May-03-06May-05-06 EPA 200.7n n it

„„n

"

n

„

„

n it w

H n n

"n


EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Analyzed Method

1 EE60203 May-03-06May-05-06 EPA 200.7,,„

•H I * n

„,,*„„„„.» m W

m m n

„,,• H H

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stephen/ponnet, Chemist


Page 3 of6

TediLaw 105 WMidiymStrttt, Sort. 900000210,1160602

(312)3454990(312) 345-8979 (Fat)




Reported:

May-19-06 11:21


Auger 3 (£605001-01) Water Sampled: May-01-06,12:05 Received: May-02-06 11:21

Analyte

Sodium

ThalliumVanadium

Zinc

Auger 4 (E605001-02) Water

Analyte

Aluminum

Antimony

ArsenicBarium

Beryllium

CadmiumCalcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

Nickel

PotassiumSelenium

Silver

Sodium

Thallium

Vanadium

Zinc

Result

UU

0.6

4.6

Sampled: May-01-06

Result

UUUUUU

87.1

0.8U

3.4

288UU

1.0

36.9UU

UUU

0.8

7.9

Flags/Qualifiers

*

J.K.*

J,*

MDL

45.9

6.70.3

3.9

14:55 Received:

Flags/Qualifiers

*

J

J

J

J

*

J ,K ,*

J, *

MDL

25.4

3.03.30.4O.I

0.357.9

0.4

0.2

0.9

16.3

2.55.90.4

0.5

92.3

7.00.7

45.9

6.70.3

3.9

Limit Units

400 ug/L

20.0

5.0

30.0

May-02-06 11:21

Limit Units

100 ug/L

20.0

20.0

3.01.02.0200

5.0

3.05.0

50.0

15.0

1001.0

3.0

80030.0

5.040020.0

5.0

30.0


1 EE60203 May-03-06May-05-06n

. . . . .

.1 .1 H H


1 EE60203 May-03-06May-05-06H II H N

„

„

M

. . . . . n

„

„

„ „

„

,.

„

i. t. « n

,. „ .

,,

,,

ii H n H

,,.n N n n

n n ti M

.

MethodEPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 4 of6

TwhLaw lOSW.MidisaiStiHt, Suite 900Chicafo,IL 60602

(312)545^990(312) 345^979 (Fix)

MfMinviiw* Mum




May-19-06 11:21


Auger 5 (£605001-03) Water Sampled: May-01-06 16:40 Received: May-02-06 11:21

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalcium


IronLeadMagnesiumManganeseNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZinc

Result

UVVU

UU

79.3

UU

3.1UUUU

10.7

UUUUVV

5.2


25.4

3.03.3

* 0.4

O.I

0.3J 57.9

0.40.2

J 0.9

16.3

2.55.90.40.5

92.3

7.00.7

* 45.9

6.7• 0.3

J, * 3-9

Limit

10020.0

20.0

3.01.02.0200

5.03.05.0

50.0

15.0

1001.03.0

80030.0

5.040020.0

5.030.0


ug/L 1 EE60203 May-03-06May-05-06 EPA 200.7EPA 200.7

>• » - EPA 200.7

' EPA 200.7

>• - - EPA 200.7

» - • EPA 200.7

EPA 200.7

EPA 200.7

" " - EPA 200.7

" EPA 200.7

" EPA 200.7

EPA 200.7

• - - EPA 200.7

• EPA 200.7

" EPA 200.7

'• EPA 200.7

EPA 200.7

- " " EPA 200.7

„ . n EPA 200.7

•• EPA 200.7

• EPA 200.7

" EPA 200.7


000015


Page 5 of6

TediLawQiatit]

!05W.Madi«mSttiit,Sufc900

(312)345-8990(312) 3454979 (Fa)



Reported:

May-19-06 11:21


x

K

J

<5X

*

U

NR

U

The identification of the analyte is acceptable; the reported value may be biased high. The actual value is expected to be less thanthe reported value.

The identification of the analyte is acceptable; the reported value is an estimate.

One or both concentration values for the duplicate analysis audit were less than 5 times the MDL value AND the differencebetween the two values was less than the MDL value. The duplicate audit is acceptable. No qualification made for this QC audit

The duplicate analysis precision is not within control limits The reported value is estimated.

Not Detected

Not Reported

000016

Stephen Cofoet, ChemistReport Name: E605001.E604004 FINAL May 19 06 1121

Page 6 of6


Work Order SF £frP*/Jfl4 tl-S

Chain of Custody

Final report from LIMS Invoice # £ 6 £ t f f l f l f J:t>7:<&>

TDF Completion form signed by TOPO

Analytical and Data Review Checklist

Transmittal Memo ^/signatures of the following:

• Analyst(s)


£6 05to I Prepared bvU f\ Enviônm^liAl Data Coordinator

Date:

Subject:

From:

To:





M4Y 2 6 2006


Stephen Connet, Chemist, TechLaw Inc. / ESATContractor to Region 5 Central Regional LaborSubmitted to CRL on



Samples analyzed for: GFAA Antimony, Arsenic, Selenium, Thallium


2 ^ 2006Data Management7 (Coordinator and Date Received

r» * T •« j MAY 2 6/2006Date Transmitted: / /




Received by and Date

Comments:



Samples analyzed for: GFAA Antimony, Arsenic, Selenium, Thallium


Rev. 4/10/02

Method: 200.9 (GFAA Metals) TDF: R5-01-004,5Site: US Smelter and Lead Refinery, Inc. TechLaw Job #: 03037.1.01.02.01.053J.000.004, 5Date: May 23,2006 Task Order #: R5-0-01Prepared by: Stephen Connet Data Sets: E604004, E605001

NARRATIVE

One hundred three (103) soil samples from the US Smelter and Lead Refinery, Inc. site were collectedbetween April 26 and May 1, 2006 and were received properly preserved at CRL on April 28 and May 2,2006. The samples were submitted to ESAT for analysis of antimony, arsenic, selenium, and thallium byGFAA. The sample point identifications are on the first pages of the LIMS report following this narrative.Raw data and QC forms are filed in the folder for E604004.

The soil samples were dried and ground between May 1 and 4, 2006 prior to being digested followingstandard CRL 200.2 hot block digestion protocols (CRL SOP METALS025). They were batched in 5LIMS batches (LIMS digestion batches EE60204 containing samples E604004-03 thru -22, EE60205containing samples E604004-23 thru -42, EE60206 containing samples E604004-43 thru -62, EE60207containing samples E604004-63 thru -68 and E605001-04 thru -17 and EE60208 containing samplesE605001-18 thru -40). All batches were digested on May 4,2006. They were analyzed between May 5 and22, 2006 using 200.9 methods (CRL SOP's MET ALSO 17/019). Antimony and thallium were analyzed onthe SimAA 6000 using the single element programs (CRL SOP MET ALSO 17). Arsenic and selenium wereanalyzed on the AAnalyst 800 (CRL SOP METALS019). QC limits are based on ESAT control limits; CRLdefault limits are used if ESAT limits are greater than CRL limits.

Because reported QC values are less than 5 times the MDL for all selenium and thallium samples, duplicatedifference criteria are used for control purposes for all selenium and thallium QC samples; all selenium andthallium matrix duplicates (EE60204-DUP1, -DUP2, EE60205-DUP1, -DUP2, EE60206-DUP1, -DUP2,EE60207-DUP1, -DUP2, EE60208-DUP1, -DUP2, -DUP3) are flagged "<5X" in LIMS. Duplicate RPDwas used for control purposes for antimony and arsenic. Antimony duplicates EE60207-DUP2 andEE60208-DUP1 and arsenic duplicate EE60206-DUP2 did not meet QC requirements indicating possiblepoor precision. No redigestion/reanalysis were performed due to time constraints. Antimony for samplesE604004-63 thru -68 and E605001-04 thru -40 and duplicates EE60207-DUP2 and EE60208-DUP1 andarsenic for samples E604004-43 thru -62 and duplicate EE60206-DUP2 are flagged "*" in LIMS andconsidered estimated. All other QC values were within limits. All samples were analyzed within theholding time limit.

The following results between the method detection limit (MDL) and the RL are reported as the instrumentvalue with a "J" flag and are considered estimated: E604004-03, -05, -07, -08, -10, -12 thru -17, -21 thru -23,-26, -30, -32, -33, -36 thru -39, -41, -42, -44 thru -48, -50 thru -53, -64, -67, E605001-06, -09, -11, -14, -15, -17thru -25, -27, -29, -31 thru -33, -37, -39 and -40 for selenium; E604004-03 thru -05, -30, -31, -39, -44, -53,E605001-29, -34, -38 and -40 for thallium. The following reported values are adjusted for dilution: allantimony results except digestion blanks and E604004-59 and E605001-19 thru -24; all arsenic results exceptdigestion blanks; all control samples, blank spikes and matrix spikes plus samples E604004-06, -08, -13, -15,-53, E605001-25, -33 and -37 for selenium; all thallium samples except digestion blanks. All other sampleresults are acceptable. Where appropriate, reported values are dilution corrected.

Samples E604004-30/-31, -44/-4S, -527-53, E605001-09/-10 and -39/-40 were identified as field duplicates.All show good correlation for all elements except E604004-52/-53 arsenic and selenium. Determinations ./.

"- s~*

of correlation were made using laboratory duplicate criteria. No sample results are qualified for fieldduplicates. No samples were identified as field blanks.

QC reports which include analytical QC are provided as Excel spreadsheets. Logbook entries for thismetals analysis can be found in an ESAT Laboratory Notebook. It has been observed that, due todifferences in the significant figures used for calculation and rounding of reported values, RPD values andsome matrix spike recoveries calculated by LIMS are not correct. The correct values are included in theExcel spreadsheets in the Analytical/Matrix QC Summary Report provided in the data package.

TfdiLaw105 W. Madison StrHt,Safc 900

Chicago, IL 60602(312)3454990

(312) 3454979 (Fac)vnvm

Superfund, US EPA Region 5 Project: US Smelter and Lead Refinery, Inc.77 West Jackson Boulevard Project Number: [none] Reported:Chicago IL, 60604 Project Manager: Warren Layne May-24-06 16:48


Sample ID

X03-B-0-1

X03-B-1-6

X03-B-6-12

X03-DZ

X03-F-0-1

X03-F-1-6

X03-F-6-12

X07-B-0-1

X07-B-I-6

X07-B-6-12

X07-DZ

X07-F-0-1

X07-F-1-6

X07-F-6-I2

X15-B-0-1

X15-B-1-6

X15-B-6-12

X15-DZ

X15-F-0-1

X15-F-1-6

X15-F-6-12

X19-B-0-1

X19-B-1-6

X19-B-6-12

X19-DZ

X19-F-0-1

X19-F-1-6

X19-F-6-12

^-

Laboratory ID

E604004-03

E604004-04

E604004-05

E604004-06

E604004-07

E604004-08

E604004-09

E604004-10

E604004-11

E604004-12

E604004-13

E604004-14

E604004-15

E604004-16

E604004-17

E604004-18

E604004-19

E604004-20

E604004-21

E604004-22

E604004-23

E604004-24

E604004-25

E604004-26

E604004-27

E604004-28

E604004-29

E604004-30

000031

Matrix

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

/vX^* -^ Report Name:


Apr-26-06 12:35 Apr-28-06 12:08

Apr-26-06 12:40 Apr-28-06 12:08

Apr-26-06 12:45 Apr-28-06 12:08

Apr-26-06 12:30 Apr-28-06 12:08

Apr-26-06 12:20 Apr-28-06 12:08

Apr-26-06 12:25 Apr-28-06 12:08

Apr-26-06 12:25 Apr-28-06 1 2 :08

Apr-26-06 09:50 Apr-28-06 12:08

Apr-26-06 09:55 Apr-28-06 12:08

Apr-26-06 09:55 Apr-28-06 12:08

Apr-26-06 10:00 Apr-28-06 12:08

Apr-26-06 10:15 Apr-28-06 12:08

Apr-26-06 10:40 Apr-28-06 12:08

Apr-26-06 10:45 Apr-28-06 12:08

Apr-26-06 15:25 Apr-28-06 12:08

Apr-26-06 15:45 Apr-28-06 12.08

Apr-26-06 15:35 Apr-28-06 12:08

Apr-26-06 15:20 Apr-28-06 12:08

Apr-26-06 14:40 Apr-28-06 12:08

Apr-26-06 14:45 Apr-28-06 12:08

Apr-26-06 14:50 Apr-28-06 12:08

Apr-26-06 16:50 Apr-28-06 12:08

Apr-26-06 16:55 Apr-28-06 12:08

Apr-26-06 17:00 Apr-28-06 12:08

Apr-26-06 16:15 Apr-28-06 1 2:08

Apr-26-06 16:00 Apr-28-06 12:08

Apr-26-06 16:05 Apr-28-06 12:08

Apr-26-06 16:10 Apr-28-06 12:08

E605001.E604004 FINAL May 24 06 1648onnet, Chemist Page 1 of29

khlawJ l i f f / f f ; <!• I f t e ^ r i f t

105 W.Madwon Strwt, State 900Qicap, H&m

012)3454990(312) 5454979 (Fa)www t*fUawiae com





Sample ID

XI9-FD-6-12

X24-B-0-1

X24-B-1-6

X24-B-6-12

X24-DZ

X24-F-0-1

X24-F-1-6

X24-F-6-I2

X26-B-0-1

X26-B-1-6

X26-B-6-12

X26-DZ

X26-F-0-1

X26-F-I-6

X26-FD-I-6

X26-F-6-12

X46-B-0-1

X46-B-1-6

X46-B-6-12

X46-DZ

X46-F-0-1

X46-F-1-6

X46-FD-1-6

X46-F-6-12

X48-B-0-I

X48-B-1-6

X48-B-6-12

X48-DZ

X48-F-0-1

Laboratory ID

E604004-31

E604004-32

E604004-33

E604004-34

E604004-35

E604004-36

E604004-37

E604004-38

E604004-39

E604004-40

E604004-41

E604004-42

E604004-43

E604004-44

E604004-45

E604004-46

E604004-47

E604004-48

E604004-49

E604004-50

E604004-51

E604004-52

E604004-53

E604004-54

E604004-55

E604004-56

E604004-57

E604004-58

E604004-59

Matrix

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

/£>^ *'i*'°' 000032 M6/ Report Name:


Apr-26-06 16:15 Apr-28-06 1 2:08

Apr-27-06 16:00 Apr-28-06 12:08

Apr-27-06 16:05 Apr-28-06 12:08

Apr-27-06 16: 10 Apr-28-06 12:08

Apr-27-06 15:55 Apr-28-06 12:08

Apr-27-06 15:25 Apr-28-06 12:08

Apr-27-06 15:45 Apr-28-06 12:08

Apr-27-06 15:50 Apr-28-06 12:08

Apr-27-06 16:45 Apr-28-06 12:08

Apr-27-06 16:50 Apr-28-06 12:08

Apr-27-06 17:00 Apr-28-06 12:08

Apr-27-06 16:40 Apr-28-06 12:08

Apr-27-06 16:25 Apr-28-06 12:08

Apr-27-06 16:30 Apr-28-06 12:08

Apr-27-06 16:30 Apr-28-06 12:08

Apr-27-06 16:35 Apr-28-06 12:08

Apr-27-06 14:45 Apr-28-06 12:08

Apr-27-06 14:50 Apr-28-06 12:08

Apr-27-06 14:55 Apr-28-06 12:08

Apr-27-06 14:05 Apr-28-06 12:08

Apr-27-06 14:10 Apr-28-06 12:08

Apr-27-06 14:15 Apr-28-06 12:08

Apr-27-06 14:20 Apr-28-06 12:08

Apr-27-06 14:25 Apr-28-06 12:08

Apr-27-06 1 1 :00 Apr-28-06 12:08

Apr-27-06 1 1 :05 Apr-28-06 1 2:08

Apr-27-06 11:10 Apr-28-06 1 2:08

Apr-27-06 11:15 Apr-28-06 12:08

Apr-27-06 1 1 :30 Apr-28-06 12:08

E605001,E604004 FINAL May 24 06 1648Stephen Connet, Chemist Page 2 of29

TediLawQual i ty c

105 W. Madison Sttwt,Stiiti 900dnca jo, IL 60602

(312)3454990(312) 345^979 (Fax)wane


Project: US Smelter and Lead Refinery, Inc.Project Number: [none] Reported:Project Manager: Warren Layne May-24-06 16:48


Sample ID

X48-F-1-6

X48-F-6-12

X50-B-0-1

X50-B-1-6

X50-B-6-12

X50-DZ

X50-F-0-1

X50-F-1-6

X50-F-6-12

X10-B-0-1

X10-B-1-6

X10-B-6-12

X10-DZ

X10-F-0-1

X10-F-1-6

X10-FD-1-6

XIO-F-6-12

X13-B-0-1

X13-B-1-6

X13-B-6-12

X13-DZ

X13-F-0-1

X13-F-1-6

X13-F-6-12

X35-B-0-1

X35-B-1-6

X35-B-6-12

X35-DZ

e^*~-

Laboratory ID

E604004-60

E604004-61

E604004-62

E604004-63

E604004-64

E604004-65

E604004-66

E604004-67

E604004-68

E605001-04

E60500I-05

E605001-06

E605001-07

E605001-08

E605001-09

E605001-10

E605001-11

E605001-12

E605001-13

E605001-14

E605001-15

E605001-16

E605001-17

E605001-I8

E605001-19

E605001-20

E605001-21

E605001-22

* 000033

Matrix

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Report Name:

Date Sampled

Apr-27-06 11:35

Apr-27-06 11:40

Apr-27-06 09:40

Apr-27-06 09:45

Apr-27-06 09: 50

Apr-27-06 09:30

Apr-27-06 09:05

Apr-27-06 09: 10

Apr-27-06 09: 15

May-0 1-06 11:00

May-01-06 11:20

May-01-06 11:25

May-01-06 10:50

May-01-06 10:35

May-01-06 10:40

May-01-06 10:45

May-01-06 10:47

May-01-06 09:20

May-01-06 09:25

May-0 1-06 09:45

May-01-06 09:15

May-01-06 09:00

May-0 1-06 09:05

May-0 1-06 09: 10

May-01-06 16:25

May-01-06 16:30

May-01-06 16:35

May-01-06 16:20

Date Received

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

E605001,E604004 FINAL May 24 06 1648Stephen Connet, Chemist Page 3 of29

Tedilaw 10SW.M*lU<mStn*t, Safe 900Chicago, IL 60602

012)3454990(312) 3454979 (F«)www ttfhlawinc.com




Sample ID

X35-F-0-1

X35-F-1-6

X35-F-6-12

X42-B-0-1

X42-B-1-6

X42-B-6-12

X42-DZ

X42-F-0-1

X42-F-1-6

X42-F-6-12

X49-B-0-I

X49-B-1-6

X49-B-6-12

X49-DZ

X49-F-0-1

X49-F-1-6

X49-F-6-12

X49-FD-6-12

Laboratory ID

E605001-23

E605001-24

E605001-25

E605001-26

E605001-27

E605001-28

E605001-29

E605001-30

E605001-31

E605001-32

E605001-33

E605001-34

E605001-35

E605001-36

E605001-37

E605001-38

E605001-39

E605001-40

Matrix

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Date Sampled

May-01-06 16:00

May-01-06 16:05

May-01-06 16:10

May-01-06 15:05

May-01-06 15: 10

May-01-06 15:15

May-01-06 15:00

May-01-06 15:20

May-01-06 15:25

May-01-06 15:30

May-01-06 12:15

May-01-06 12:20

May-01-06 12:25

May-01-06 12:10

May-01-06 11:45

May-01-06 11:50

May-01-06 11:55

May-01-06 12:00

Date Received

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21



Page 4 of29

TediLawQta l i i i

105 W. Madison Strwt,$ofo 900OucaCofIL«0602

(312)3454990(312) 3454979 (Fix)www ttfUiwinc con





Metals by GFAATechLaw - ESAT Contract

X03-B-0-1 (£604004-03) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X03-B-1-6 (E604004-04) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X03-B-6-12 (£604004-05) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

Sampled: Apr-26-Ofr 12:35 Received: Apr-28-06 12:08

Result

54

35.0

0.7

0.53

Sampled: Apr-26-06

Result

42

36.4

0.8

0.73

Flags/Qualifiers

JJ

MDL Limit Units

3.8 15 nig/kg

0.94 3.77

0.2 0.8

0.47 1.89

Dilution

20

101

5

Batch Prepared Analyzed Method

EE60204 May-04-06May-09-061ETALS GFA

May-08-06IETALS OFA

May- 1 1 -06 IETALS GFA

May- 1 6-06 IETALS GFA

12:40 Received: Apr-28-06 12:08

Flags /Qualifiers

J

MDL Limit Units

4.0 16 mg/kg

1.00 3.98

0.2 0.8

0.50 1.99

Dilution

20

10

1

5


EE60204 May-04-06May-09-061ETALSGFA

May-08-06ffiTALS GFA

May-ll-06ffiTALSGFA

May-16-061ETALSGFA


Result

31

29.2

0.70.37

Flags/Qualifiers

JJ

MDL Limit Units

2.0 7.9 mg/kg

0.98 3.93

0.2 0.8

0.29 1.18

Dilution

10"

1

3



May-08-06IETALS GFA

May- 11 -06 IETALS OF A

May- 16-06 IETALS GFA


Analyte

Antimony

Arsenic

Selenium

Thallium

X03-F-0-1 (£604004-07) Soil

Analyte

Antimony

Arsenic

Result

39

33.9U

U

Sampled: Apr-26-06

Result

1717.9

Flags /Qualifiers MDL Limit Units

2.0 8.0 mg/kg

1.00 4.01

0.4 1.6

0.50 2.00

Dilution

10»

25



May-08-06iETALS GFA

May-12-06lETALSGFAMay-l7-06lETALS GFA

12:20 Received: Apr-28-06 12:08


1-0 4.0 mg/kg

0.50 2.01

Dilution

5

"


EE60204 May-04-06May-09-06IETALS GFA

May-08-061ETALS GFA

000035


Page 5 of29

Maw 105W.Madi«mSttHt,Sd*900

Q u a l i t y

(312)3454990(312) 345-8979 (Fa)




Reported:

May-24-06 16:48


X03-F-0-1 (£604004-07) Soil Sampled: Apr-26-0612:20 Received: Apr-28-06 12:08

Analyte

Selenium

Thallium

Result

0.5

U

Flags/Qualifiers

J

MDL

0.2

0.50

Limit

0.8

2.01

Units

mg/kg


1 EE60204 May-04-06May-12-061ETALSGFA

5 " " May-17-06*ETALSGFA.


Analyte

Antimony

Arsenic

Selenium

Thallium

X03-F-6-12 (£604004-09) Soil Sampled

Analyte

Antimony

Arsenic

Selenium

Thallium

X07-B-0-1 (£604004-10) Soil Sampled:

Analyte

Antimony

Arsenic

Selenium

Thallium

X07-B-1-6 (£604004-11) Soil Sampled:

Analyte

Antimony

Arsenic

Selenium

Thallium

/fy&> „ '̂1^-0

Result

2524.2

0.7U

: Apr-26-06

Result

26

19.7UU

Flags/Qualifiers MDL Limit

2.0 7.9

0.99 3.95

J 0.4 1.6

0.49 1.97


mg/kg 10 EE60204 May-04-06May-09-061ETALS GFA

" May-08-061ETALS GFA

2 " " May-22-061ETALS GFA

5 " ' May-17-06lETALSGFA

12:25 Received: Apr-28-06 12:08


1.9 7.7

0.48 1.93

0.2 0.8

0.29 1.16

Apr-26-06 09:50 Received: Apr-28-06 12

Result

30

22.6

0.7U


2.0 8.1

0.50 2.02

J 0.2 0.8

0.30 1.21

Apr-26-06 09:55 Received: Apr-28-06 12

Result

4334.0

0.8U

<f


2.0 7.8

0.98 3.90

0.2 0.8

0.29 1.17

000036


mg/kg 10 EE60204 May-04-06May-09-061ETALS GFA

5 " " May-08-06ffiTALS GFA

1 " " May-12-06lETALSGFA3 May-17-06reTALSGFA

:08


mg/kg 10 EE60204 May-04-06May-09-06ffiTALS GFA

5 May-08-06ffiTALS GFA

1 May-12-06ffiTALS GFA

3 " " May-17-06lETALSGFA

:08


mg/kg 10 EE60204 May-04-06May-09-06tETALS GFA


1 " " May- 1 2-06 1ETALS GFA

3 May-17-06lETALSGFA

Report Name: E60500 1 .E604004 FINAL May 24 06 1648StefJnen Connet, Chemist Page 6 of29

SB IfdiLawQ x a l i t i i ; l i t t t f t i t y

!05W Madison $tr**,$«» 900Chicago, IL 60602

(312)3454990(312) 345^979 (Fax)

Superfund, US EPA Region77 West Jackson BoulevardChicago IL, 60604

5 Project: US Smelter and Lead Refinery, Inc.Project Number: [none] Reported:


Metals by GFAA



Analyte

Antimony

Arsenic

Selenium

Thallium

X07-DZ (E604004-13) Soil

AnalyteAntimony

ArsenicSelenium

Thallium

X07-F-0-1 (£604004-14) Soil

AnalyteAntimony

Arsenic

SeleniumThallium

X07-F-1-6 (£604004-15) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

Result

42

33.5

0.7U

Sampled: Apr-26-06 10:

Result

36

33.4

0.9U

Flags/Qualifiers

J

MDL Limit Units

2.0 8.1 mg/kg

1.02 4.07

0.2 0.8

0.51 2.04

Dilution

10"

1

5



May-05-06 IETALS GFA

May-l 1-061ETALS GFA

May-l 5-06 1ETALS GFA

00 Received: Apr-28-06 12:08

Flags/Qualifiers

J

MDL Limit Units

2.0 8.0 mg/kg

1.00 3.99

0.4 1.6

0.50 2.00

Dilution

10«

2

5



May-08-061ETALS GFA

May-l2-06IETALSGFA

May- 17-06 IETALS GFA


Result

2018.5

0.7U

Flags/Qualifiers

J

MDL Limit Units

1.0 4.0 mg/kg

0.50 2.00

0.2 0.8

0.30 1.20

Dilution

5"

1

3


EE60204 May-04-06May-09-06ffiTALS GFA

May-08-06IETALS GFA

May-l I-061ETALS GFAMay- 17-06 IETALS GFA


Result

2320.4

0.7U

X07-F-6-12 (£604004-16) Soil Sampled: Apr-26-06

Analyte

Antimony

Arsenic

Result

1617.8

Flags/Qualifiers

J

MDL Limit Units

2.0 8.0 mg/kg

0.50 1.99

0.4 1.6

0.30 1.20

Dilution

10

5

2

3



May-08-061ETALS GFA

May-l2-061ETALSGFA

May-l7-061ETALS GFA

10:45 Received: Apr-28-06 12:08


1.0 4.0 mg/kg

0.50 2.01

Dilution

5M



May-08-06tETALS GFA

O00037

StepljjfrTConnet, ChemistReport Name: E605001,E604004FINALMay2406 1648

Page 7 of29

TediLaw 105 W. Madison Strut, Sofc 900

Q t e l i t i

(312)3454990(312) 3454979 (Fat)




Reported:

May-24-06 16:48



AnaJyte

Selenium

Thallium

Result

0.5U

Flags/Qualifiers

J

MDL

0.2

0.30

Limit

0.8

1.21

Units

mg/kgit


1 EE60204 May-04-06May-ll-06IETALSGFA3 " " May-17-06lETALSGFA


Analyte

Antimony

Arsenic

Selenium

Thallium

X15-B-1-6 (£604004-18) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

Result

17

20.9

0.8U


1.0 4.0

0.50 1.99

J 0.2 0.8

0.30 1.19

Units Dilution Batch

mg/kg 5 EE60204„

1

3


May-04-06May-09-061ETALS GFA


May-ll-06IETALSGFA.May-l7-06lETALSGFA


Result

21

23.5

0.9U

X15-B-6-12 (£604004-19) Soil Sampled: Apr-26-06

Analyte

Antimony

Arsenic

Selenium

Thallium

X15-DZ (£604004-20) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

Jg?~

Result

41

34.4

0.9U


Result

21

20.6

0.9U


1.0 4.0

1.00 4.01

0.2 0.8

0.30 1.20

15:35 Received: Apr-28-06


2.0 8.0

1.01 4.02

0.2 0.8

0.30 1.21

20 Received: Apr-28-06 12:


1.0 4.0

0.50 1.99

0.2 0.8

0.30 1.19

00003S


mg/kg 5 EE60204

10U |

3

12:08


mg/kg 10 EE60204II II H

1

3

08


mg/kg 5 EE60204.

U | .

" 3 "


May-04-06May-09-06ffiTALS GFA

May-08-061ETALS GFA

May-ll-06(ETALSGFAMay-17-06lETALSGFA


May-04-06May-09-06tETALS GFA

May-08-06tETALS GFA.

May-12-061ETALSGFAMay-l7-06ffiTALSGFA



May-08-061ETALS GFA

May-1 1 -061ETALS GFA

May- 1 7-06 fETALS GFA

/tS-̂ *^* Report Name. £60500 1 .E604004 FINAL May 24 06 1 648Stepfien Connet, Chemist Page 8 of29

MLiwI ft (fir;

105W.MadiwmS«mt,$ahi900Qricafo, EL 60602

(312)3454990(312) 345-8979 (Fax)





X15-F-0-1 (E604004-21) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X15-F-1-6 (£604004-22) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X15-F-6-12 (E604004-23) Soil

AnalyteAntimony

Arsenic

SeleniumThallium

X19-B-0-1 (E604004-24) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X19-B-1-6 (£604004-25) Soil

Analyte

AntimonyArsenic

J^



18

23.3

0.5 J

U

MDL Limit Units

1.0 4.0 mg/kg

1.01 4.05

0.2 0.8

0.30 1.21


5 EE60204 May-04-06May-09-061ETALS GFA


1 " " May-ll-06IETALSGFA

3 ' ' May-17-06lETALSGFA


Flags /Result Qualifiers

26

24.9

0.5 J

V

MDL Limit Units

2.0 8.1 mg/kg

1.01 4.04

0.2 0.8

0.51 2.02


10 EE60204 May-04-06May-05-06tETALS GFA

May-05-061ETALS GFA

1 " " May-ll-06IETALSGFA




24

19.0

0.2 JU

MDL Limit Units

2.0 8.1 mg/kg

0.51 2.03

0.2 0.8

0.30 1.22




1 " " May- 1 2-06 1ETALS GFA




29

24J

0.9U

MDL Limit Units

2.0 8.0 mg/kg

1.00 4.01

0.2 0.8

0.30 1.20


10 EE60205 May-04-06May-09-06IETALSGFA

May-08-06IETALS GFA

1 " " May-ll-06fETALSGFA

3 " " May-17-06<ETALSGFA



41

35.9

MDL Limit Units

2.0 8.0 mg/kg

1.01 4.02

000039


10 EE60205 May-04-06May-09-06CETALS GFA

May-08-061ETALS GFA

/^ ^^ Report Name: E60500 1 ,E604004 FINAL May 24 06 1 648Stephen bonnet, Chemist Page 9 of29

TediLawQ u a l i t y

105 W. Madison Stntt, Suit* 900ducafo,IL 60602

012)3454990(312) 3454979 (Fix)



Reported:

May-24-06 16:48


X19-B-1-6 (£604004-25) Soil Sampled: Apr-26-06.16:55 Received: Apr-28-06 12:08

Analyte

SeleniumThallium

Result

1.1U


0.2

0.30

Limit

0.8

1.21

Units

mg/kgn


1 EE60205 May-04-06 May- 1 1 -06 1ETALS OF A.

3 " ' May-17-06lETALSGFA


Analyte

AntimonyArsenicSeleniumThallium

X19-DZ (E604004-27) Soil

Analyte

Antimony

ArsenicSeleniumThallium

X19-F-0-1 (£604004-28) Soil

AnalyteAntimonyArsenicSeleniumThallium

X19-F-1-6 (E604004-29) Soil

Analyte


X

Result

60

42.0

0.8U


4.0

1.00

J 0.2

0.30

Limit

16

3.99

0.8

1.20


mg/kg 20 EE60205

10

1

3


May-04-06 May-09-061ETALS GFA

May-08-061ETALS GFA

May-ll-061ETALSGFAMay-17-06lETALSGFA


Result

42

36.5

1.0V

Sampled: Apr-26-06

Result

32

31.8

1.0V

Sampled: Apr-26-06

Result

42

39.6

1.1U


2.0

1.01

0.2

0.30

Limit

8.1

4.06

0.8

1.22

16:00 Received: Apr-28-06 12


2.0

1.00

0.2

0.50

Limit

8.0

4.01

0.8

2.00

16:05 Received: Apr-28-06 12


2.0

1.00

0.2

0.30

Limit

8.0

4.01

0.8

1.20


mg/kg 10 EE60205

"

1

3

:08


mg/kg 10 EE60205«

1

5

:08


mg/kg 10 EE60205n . „

1

3



May-08-061ETALS GFA

May- 1 2-06 1ETALS GFA

May-17-06tETALSGFA


May-04-06 May-09-06fETALS GFA

May-08-061ETALS GFA

May-12-061ETALS GFA



May-04-06 May-09-06ffiTALS GFA

May-08-061ETALS GFA


May-17-06lETALSGFA

r-z^c 000040/ ^^-^^^ Report Name: E605001,E604004 FINAL May 24 06 1648

StephclfConnet, Chemist Page 10 of29

Techlaw 105W.Kiadu<mSttMt, Sate 900

Quality

(312)3454990(312) 3454979 (Fax)wnnsr t*chlawinc com



Chicago IL, 60604

X19-F-6-12 (£604004-30) Soil

Analyte


Project Number: [none] Reported:




Flags/Result Qualifiers MDL Limit Units Dilution

Antimony 63 4.1 16 mg/kg 20

Arsenic 51.6 203 8.11

Selenium 0.7 J 0.2 0.8 - 1

Thallium 0.31 J 0.30 1.22 " 3

X19-FD-6-12 (E604004-31) Soil Sampled: Apr-26-06 16:15 Received: Apr-28-06 12:08

Analyte

Antimony

Arsenic

Selenium

Thallium

X24-B-0-1 (£604004-32) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X24-B-1-6 (£604004-33) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X24-B-6-12 (£604004-34) Soil

Analyte

Antimony


59 3.9 16 mg/kg 20

46.1 0.98 3.93 " 10

0.8 0.2 0.8 " |

0.43 J 0.29 1.18 " 3



20 1.0 3.9 mg/kg 5

17.4 0.49 1.97

0.8 J 0.2 0.8 " 1

U 0.49 1.97 " 5



24 1.0 4.0 mg/kg 5

20.9 0.49 1.98

0.5 J 0.2 0.8 " 1

W 0.49 1.98 " 5



5.7 0.4 1.6 mg/kg 2



May-08-061ETALS GFA

May-12-061ETALS GFA

May-17-061ETALSGFA




May-12-061ETALS GFA

May-17-061ETALSGFA




May-12-061ETALS GFAMay- 1 8-06 1ETALS GFA


EE60205 May-04-06May-09-06tETALSGFA

May-08-061ETALS GFA

May-I2-061ETALSGFA

May-l8-06lETALSGFA



_^ 000041S ^^^ ~:=:::^ Report Name: E60500 1 .E604004 FINAL May 24 06 1 648

Steptten Connet, Chemist Page 11 of29

TedilawQ x a i t t i C-

Oaca|o,IL 60602(312)3454990

(312)345-«979(Fa)


X24-B-6-12 (E604004-34) Soil

Analyte

Arsenic

SeleniumThallium



Sampled: Apr-27-06

Result

7.49VU

X24-DZ (E604004-35) Soil Sampled: Apr-27-06 15:

Analyte

Antimony

Arsenic

Selenium

Thallium

X24-F-0-1 (£604004-36) Soil

AnalyteAntimony

ArsenicSelenium

Thallium

X24-F-I-6 (E604004-37) Soil

Analyte

Antimony

ArsenicSelenium

Thallium

X24-F-6-12 (£604004-38) Soil

AnalyteAntimony

Arsenic

Selenium

Result

44

42.4

0.9U


16:10 Received: Apr-28-06 12:08


0.20 0.81 mg/kg

0.2 0.8

0.20 0.81

55 Received: Apr-28-06 12:08

Flags /Qualifiers MDL Limit Units

2.0 8.0 mg/kg

1.00 3.99

0.2 0.8

0.50 1.99

Dilution Batch

2 EE60205

12

Dilution Batch

10 EE60205

"

1

5




May-1 1-061ETALS GFA

May-1 5-06*ETALS GFA



May-08-06IETALS GFA

May- 12-06 lETALS GFA

May-1 8-06 lETALS GFA


Result

21

20.1

0.7U


1-0 4.1 mg/kg

0.51 2.03

J 0.2 0.8

0.30 1.22

Dilution Batch

5 EE60205fl t»

1

3



May-08-061ETALS GFA

May- 12-06 lETALS OF A

May- 1 7-06 lETALS GFA


Result

30

24.5

0.7U

Sampled: Apr-27-06

Result

14

15.5

OJ

^~~\ '** "7 C* ***,


2.0 7.8 mg/kg

0.98 3.90

J 0.2 0.8

0.49 1.95

15:50 Received: Apr-28-06 12:08


1.0 4.0 mg/kg

0.50 1.98

J 0.2 0.8

000042

Dilution Batch

10 EE60205,

1

5

Dilution Batch

5 EE60205.

1


May-04-06May-IO-061ETALS GFA

May-08-061ETALS GFA

May- 1 2-06 lETALS GFA



May-04-06 May-1 1-061ETALS GFA

May-08-06 lETALS GFA

May- 12-06 lETALS GFA

/^^^^ " Report Name: E605001,E604004 FINAL May 24 06 1648Stephen^^mnet, Chemist Page 12 of 29

TfdiLawQ t a t i t i \-

(312)3454990(312) 345-8979 (Fa)




Reported:

May-24-06 16:48



AnalyteThallium

X26-B-0-1 (E604004-39) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X26-B-1-6 (E604004-40) Soil

AnalyteAntimony

Arsenic

Selenium

Thallium

ResultV

Sampled: Apr-27-06

Result

13

12.1

0.7

0.60

Sampled: Apr-27-06

Result

23

19_J

0.9U


0.30 1.19 mg/kg

Dilution Batch

3 EE60205


May-04-06 May- 1 7-06 1ETALS GFA

16:45 Received: Apr-28-06 12:08

Flags/Qualifiers

J

J

MDL Limit Units

1.0 3.9 mg/kg

0.49 1.94

0.2 0.8

0.49 1.94

Dilution Batch

5 EE60205II II

1

5



May-08-061ETALS GFA

May-1 2-06 1ETALS GFA

May-18-061ETALSGFA

16:50 Received: Apr-28-06 12:08


2.0 8.1 mg/kg

0.51 2.02

0.2 0.8

0.30 1.21

Dilution Batch

10 EE60205

5

I

3


May-04-06 May-1 0-06 1ETALS GFA

May-08-061ETALS GFA

May- 1 2-061ETALS GFA

May-17-06lETALSGFA


AnalyteAntimony

Arsenic

Selenium

Thallium

X26-DZ (E60400442) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

^^

Result

11

10.8

0.3U

Sampled: Apr-27-06 16

Result

15

16.5

0.6U

f~^ t l^/ S**"^? ^ £ i *~^2s*

Flags/Qualifiers

J

MDL Limit Units

0.6 2.4 mg/kg

0.51 2.02

0.2 0.8

0.30 1.21

Dilution Batch

3 EE60205

5

1

3



May-08-06IETALS GFA


May-17-06lETALSGFA

:40 Received: Apr-28-06 12:08

Flags/Qualifiers

J

MDL Limit Units

0.8 3.2 mg/kg

0.49 1.98

0.2 0.8

0.49 1.98

000043

Dilution Batch

4 EE60205

5

1

5


May-04-06 May-05-061ETALS GFA

May-05-061ETALS GFA


May_l5.06lETALSGFA

//^ "̂"" Report Name: E605001.E604004 FINAL May 24 06 1648Stephen Connet, Chemist Page 13 of29


105 W.MadaonSttwt, Suite 900Oricafo,IL 60602

(312)3454990(312) 3454979 (Fax)WIMP f*A1»TBtlM» MUM



X26-F-0-1 (E604004-43) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X26-F-1-6 (£604004-44) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X26-FD-1-6 (£604004-45) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X26-F-6-12 (E604004-46) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X46-B-0-1 (E604004-47) Soil

Analyte

Antimony

Arsenic





27

22.5 *

0.9t

MDL Limit Units

2.0 7.9 mg/kg

0.49 1.96

0.2 0.8

0.29 1.18



5 " " May-05-061ETALSGFA

1 " " May-12-06fETALSGFA




29

26.5 *

0.5 J

0.43 J

MDL Limit Units

2.0 7.9 mg/kg

0.99 3.96

0.2 0.8

0.30 1.19


10 EE60206 May-04-06May-10-06IETALS GFA

May-08-061ETALS GFA


3 " " May-l8-061ETALSGFA



32

27.2 *

0.6 JV

MDL Limit Units

2.0 8.0 mg/kg

1.00 4.01

0.2 0.8

0.30 1.20


1 0 EE60206 May-04-06 May- 1 0-06 1ETALS GFA

May-09-061ETALS GFA

1 " " May-l2-061ETALSGFA3 " " May-18-06lETALSGFA.



16

13.0 *

0.6 JU

MDL Limit Units

1.0 4.0 mg/kg

0.50 1.98

0.2 0.8

0.30 1.19


5 EE60206 May-04-06 May- 1 1 -06 ffiTALS GFA

May-09-061ETALS GFA


3 " " Mav-18-06lETALSGFA



12

14.7 *

MDL Limit Units

0.6 2.4 mg/kg

0.51 2.03


3 EE60206 May-04-06May-ll-061ETALSGFA


000044

Stephgx/connet, ChemistReport Name: E605001.E604004 FINAL May 24 06 1648

Page 14 of 29

TedilawQ u a l i t y

!05W. Madi«m State, Sofc 900Oucafo,IL 60602

(312)3454990(312) 3454979 (Fix)

nvm





Reported:

May-24-06 16:48

Metals by GFAA


X46-B-0-1 (£604004-17) Soil Sampled: Apr-27-0614:45 Received: Apr-28-06 12:08

Analyte

Selenium

Thallium

Result

0.5U

Flags/Qualifiers

J

MDL

0.2

0.51

Limit

0.8

2.03

Units

mg/kg


1 EE60206 May-04-06May-12-061ETALSGFA5 " " May-18-06lETALSGFA


Analyte

Antimony

Arsenic

Selenium

Thallium

Result

25

21.7

0.5U

X46-B-6-12 (£604004-49) Soil Sampled: Apr-27-06

Analyte

Antimony

Arsenic

SeleniumThallium

X46-DZ (£604004-50) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X46-F-0-1 (£604004-51) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

Result

31

16.5UV


Result

10

21.2

0.4U

Flags/Qualifiers

*

J

MDL Limit Units

2.0 7.9 mg/kg

0.49 1.97

0.2 0.8

0.98 3.93






14:55 Received: Apr-28-06 12:08

Flags/Qualifiers

*

MDL Limit Units

2.0 8.1 mg/kg

0.51 2.02

0.2 0.8

0.51 2.02


1 0 EE60206 May-04-06 May- 1 0-061ETALS GFA

5 " " May-09-06ffiTALS GFA

I " " May-l2-06ffiTALSGFA-5 " " May-18-06lETALSGFA

05 Received: Apr-28-06 12:08

Flags/Qualifiers

*

J

MDL Limit Units

0.6 2.4 mg/kg

0.50 2.01

0.2 0.8

0.50 2.01


3 EE60206 May-04-06May-l 1-061ETALS GFA


1 " " May-12-061ETALSGFA5 • " May-18-06lETALSGFA


Result

9.5

13J

0.4U

*£: ?-£r^—^ '

Flags/Qualifiers

*

J

zy~t

MDL Limit Units

0.6 2.4 mg/kg

0.49 1.97

0.2 0.8

0.49 1.97

000045


3 EE60206 May-04-06 May- 11 -06 1ETALS OF A.

5 " " May-09-06IETALS GFA

1 " " May-l2-061ETALSGFA.5 " " May-l8-06lETALSGFA.

, /^^ ""^ Report Name: E60500 1 .E604004 FINAL May 24 06 1 648Stephen Connet, Chenflst Page 15 of29

khlaw !05W.Madi«mSttHt, Suite WOChicafo,lL 60602

(312)5454990(312) 3454*79 (F«)

Superfimd, US EPA Region 577 West Jackson Boulevard

Chicago 1L, 60604




X46-F-1-6 (E604004-52) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X46-FD-1-6 (E604004-53) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X46-F-6-12 (£604004-54) Soil

Analyte

Antimony

Arsenic

SeleniumThallium

X48-B-0-1 (E604004-55) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X48-B-1-6 (E604004-56) Soil

Analyte

Antimony

Arsenic



1215.8 *

03 JU

MDL Limit Units

0.6 2.3 mg/kg

0.48 1.94

0.2 0.8

0.48 1.94


3 EE60206 May-04-06May-l 1-06IETALS GFA


1 " " May-l2-061ETALSGFA5 ' " May-l8-06lETALSGFA



1221.4 *

0.8 J

0.40 J

MDL Limit Units

1.0 4.1 mg/kg

0.51 2.03

0.4 1.6

0.30 1.22



May-08-06ffiTALSGFA





7.511.6 *U11

MDL Limit Units

0.4 1.6 mg/kg

0.51 2.03

0.2 0.80.51 2.03


2 EE60206 May-04-06 May- 1 1 -06 ffiTALS GFA

5 " " May-09-061ETALS GFA1 " " May- 12-06 PETALS OF A5 " ' May-I8-06lETALSGFA



5.89.75 *

UU

MDL Limit Units

0.4 1 .6 mg/kg

0.41 1.63

0.2 0.8

0.31 1.22



4 " " May-09-06ffiTALS GFA1 " " May-12-06lETALSGFA




8.510.5 *

MDL Limit Units

0.4 1.6 mg/kg

0.51 2.03


2 EE60206 May-04-06May-ll-06tETALSGFA

5 ' " May-09-06IETALS GFA

000046


Page 16 of29

TediLawlOSW.NMsou Strut, Sm* 900

,IL 60602

Quality <<

(312)3454990(312) 3454979 (Fu)


X48-B-1-6 (£604004-56) Soil

Analyte

Selenium

Thallium

Sampled: Apr-27-06

ResultUU



Metals by GFAA

TechLaw - ESAT Contract11:05 Received: Apr-28-06 12:08


0.2 0.8 mg/kg

0.30 1.22


1 EE60206 May-04-06 May- 1 2-06 1ETALS GFA

3 » " May-lS-06'ETALSGFA


Analyte

Antimony

Arsenic

Selenium

Thallium

X48-DZ (£604004-58) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X48-F-0-1 (£604004-59) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X48-F-1-6 (£604004-60) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

Result

6.18.65

UU


Result

7.5

9.45UU

Sampled: Apr-27-06

Result

3.6

8.20U

U

Sampled: Apr-27-06

Result

8.0

11.4UU


0.4 1 .6 mg/kg

* 0.40 1.61

0.2 0.8

0.30 1.21

:15 Received: Apr-28-06 12:08


0.4 1.6 mg/kg

• 0.40 1.61

0.2 0.80.30 1.21

11:30 Received: Apr-28-06 12:08


0.2 0.8 mg/kg

• 0.20 0.81

0.2 0.80.30 1.22

11:35 Received: Apr-28-06 12:08


0.4 1 .6 mg/kg

* 0.49 1.95

0.2 0.8

0.29 1.17


2 EE60206 May-04-06May-ll-061ETALS GFA

4 " " May-09-06IETALS GFA1 " " May-12-06lETALS GFA

3 " " May-1 8-06 1ETALS GFA



4 " " May-09-061ETALS GFA1 " " May-1 2-061ETALS GFA

3 " " May-1 8-061ETALS GFA


1 EE60206 May-04-06May-ll-06tETALSGFA

2 " " May-09-061ETALS GFA1 " " May-12-06tETALS GFA

3 " " May-1 8-06 1ETALS GFA





3 " " May-18-06<ETALSGFA

JP£T ^-t-y-os/ /P^ ^>- 0 30047 Report Name: E605001 ,E604004 FINAL May 24 06 1648

Stephen Corffift, Chemist Page 17 of 29

Maw105 lOMumSttHt, Safe 900

Quali ty

012)3454990(312) 345-8979 (Fix)



X48-F-6-12 (E604004-61) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X50-B-0-1 (E604004-62) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X50-B-1-6 (E604004-63) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X50-B-6-12 (E604004-64) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium


Project Manager. Warren Layne May-24-06 16:48



Result

11

15.1UU

Flags/Qualifiers

*

MDL Limit Units

0.6 2.4 mg/kg

0.50 2.00

0.2 0.8

0.30 1.20

Dilution

3

5

13

1Batch Prepared Analyzed Method |

EE60206 May-04-06May-U-06tETALSGFA

May-09-061ETALS GFAMay-12-06lETALS GFA

May-18-06lETALSGFA


Result

22

16.9UU

Sampled: Apr-27-06

Result

28

22.6

1.1U

Flags/Qualifiers

*

MDL Limit Units

t.O 4.0 mg/kg

0.50 2.01

0.2 0.8

0.30 1.20

Dilution

5»

13

EE60206 May-04-06May-ll-06IETALSGFA

May-09-061ETALS GFAMav-12-06*ETALSGFA

May-18-06lETALS GFA

09:45 Received: Apr-28-06 12:08

Flags/Qualifiers

*MDL Limit Units

1.9 7.7 mg/kg

0.97 3.87

0.2 0.8

0.29 1.16

Dilution

10H

1

3



May-10-061ETALS GFA

May-12-06ffiTALS GFAMay-18-06lETALSGFA


Result

13

14.5

0.4U

X50-DZ (E604004-65) Soil Sampled: Apr-27-06 09

Analyte

Antimony

Arsenic

Result

56

34.3

Flags/Qualifiers

*

J

MDL Limit Units

0.6 2.4 mg/kg

0.51 2.03

0.2 0.8

0.30 1.22

Dilution

3

5

1

3

EE60207 May-04-06May-ll-061ETALSGFA

May-10-061ETALSGFA

May-l2-061ETALSGFA

May-18-06lETALSGFA

:30 Received: Apr-28-06 12:08

Flags/Qualifiers

*MDL Limit Units

4.0 16 mg/kg

1.00 4.01

Dilution

20

10


EE60207 May-04-06May-IO-06tETALSGFA

May-10-061ETALS GFA

000048

Steph6rt:onnet, ChemistReport Name: E605001.E604004 FINAL May 24 06 1648

Page 18 of 29

Tedilaw 105 W.MadiwaSttwt, Sate 900Chicago, IL 60602

(312)3454990(312) 3454979 (F«>




Reported:

May-24-06 16:48

Metals by GFAA

TechLaw - ESAT ContractXSO-DZ (£604004-65) Soil Sampled: Apr-27-06 09:30 Received: Apr-28-06 12:08

Analyte

Selenium

Thallium

Result

1.4

U


0.2

0.50

Limit

0.8

2.00

Units

mg/kg

Dilution Batch Prepared Analyzed Method ]

1 EE60207 May-04-06May-15-061ETALSGFA5 " " May-19-06lETALSGFA


AnalyteAntimony

ArsenicSelenium

Thallium

X50-F-1-6 (£604004-67) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X50-F-6-12 (£604004-68) Soil

Analyte

Antimony


X10-B-0-1 (£605001-04) Soil

Analyte

AntimonyArsenic

Selenium

Thallium

~&^-

Result

20

18.3

1.1U

Flags/Qualifiers

*MDL Limit Units

2.0 7.9 mg/kg

0.49 1.98

0.2 0.8

0.30 1.19

Dilution Batch

10 EE60207

5 "

1 "

3



May-10-061ETALS GFA

May-12-061ETALS GFA

May-18-06lETALSGFA


Result

21

21.1

0.7U

Flags/Qualifiers

4

J

MDL Limit Units

2.0 8.1 mg/kg

0.50 2.02

0.2 0.8

0.30 1.21

Dilution Batch

10 EE60207

5

1

3


May-04-06May-10-06IETALS GFA

May-09-061ETALS GFA

May-12-061ETALSGFA

May-l8-06lETALSGFA


Result

6.8

8.06VU

Sampled: May-01-06

Result

27

28.4

1.2I)

, — ' -,11 S'

Flags/Qualifiers

*MDL Limit Units

0.4 1.6 mg/kg

0.20 0.81

0.2 0.8

0.20 0.81

Dilution Batch

2 EE60207ii

12



May-09-061ETALS GFA

May-ll-06lETALSGFA

May- 1 5-061ETALS GFA

1 1 :00 Received: May-02-06 11:21

Flags/Qualifiers

*MDL Limit Units

2.0 8.1 mg/kg

1.02 4.07

0.2 0.8

0.51 2.03

000049

Dilution Batch

10 EE60207H It

1

5


May-04-06 May- 1 0-06 1ETALS GFA

May-09-061ETALS GFA

May-12-061ETALSGFA

May-19-06lETALS GFA

J&^^ -7^7-**/ ^-^ Report Name: E60500 1 ,E604004 FINAL Mav 24 06 1 648

Stephen Gdhnet, ChemistPage 19 of29

Maw 105 W. Madison Strwt, Sate 900Chkafo,]L 60(02

012)3454990(312) 345-8979 (F«)wwro t*rUawfnf com





X10-B-1-6 (£605001-05) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X10-B-6-12 (E605001-06) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

Sampled: May-01-06

Result

4032.7

1.0U

11:20 Received: May-02-06 11:21

Flags/Qualifiers

*MDL Limit Units

2.0 8.1 mg/kg

1.02 4.07

0.2 0.8

0.51 2.03

Dilution

10"

1

5


EE60207 May-04-06May-10-06IETALSGFA

May-09-061ETALS GFA

May-12-061ETALS OF A.May- 1 9-06 1ETALS GFA


Result

27

26.2

0.6D

X10-DZ (£605001-07) Soil Sampled: May-01-06 10

Analyte

Antimony

Arsenic

Selenium

Thallium

XlO-F-0-1 (£605001-08) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X10-F-1-6 (E605001-09) Soil

Analyte

Antimony

Arsenic

Result

31

35.4

1.1U

Sampled: May-01-06

Result

26

26.4

0.9U

Sampled: May-01-06

Result

3030.7

Flags/Qualifiers

*

J

MDL Limit Units

2.0 7.9 mg/kg

0.98 3.93

0.2 0.8

0.29 1.18

Dilution

10••

L

3



May-09-061ETALS GFA

May-12-061ETALS GFAMay-19-06lETALSGFA

:50 Received: May-02-06 11:21

Flags/Qualifiers

*MDL Limit Units

2.0 8.1 mg/kg

1.01 4.05

0.2 0.8

0.51 2.03

Dilution

10"

1

5



May-09-061ETALS GFA

May-15-06IETALS GFAMay-19-06lETALS GFA

10:35 Received: May-02-06 11:21

Flags/Qualifiers

*MDL Limit Units

1.9 7.8 mg/kg

0.97 3.89

0.2 0.8

0.29 1.17

Dilution

10»

1

3


EE60207 May-04-06May-IO-06IETALSGFA

May-09-061ETALS GFA

May- 1 2-06 JETALS GFAMay-19-06<ETALSGFA

10:40 Received: May-02-06 11:21

Flags/Qualifiers

*MDL Limit Units

2.0 8.1 mg/kg

1.01 4.06

Dilution

10M


EE60207 May-04-06May-IO-06!ETALSGFA

May-09-061ETALS GFA

Stephen (Bonnet, Chemist


Page 20 of 29

ktilawQ u a l i t y

105 W. Madison Stint, Striit 900Cbicafo,IL 60602

(312)545-8990(312) 3454979 (F«)www ttchlawinc com



Chicago IL, 60604




Reported:

May-24-06 16:48



Analyte

Selenium

Thallium

Result

0.7

V

Flags/Qualifiers

J

MDL

0.2

0.30

Limit

0.8

1.22

Units

mg/kg


1 EE60207 May-04-06May-l2-061ETALSGFA

3 " " May-19-06lETALS GFA

X10-FD-1-6 (£605001-10) Soil Sampled: May-01-06 10:45 Received: May-02-06 11:21

Analyte

Antimony

Arsenic

Selenium

Thallium

X10-F-6-12 (E605001-11) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X13-B-0-1 (£605001-12) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X13-B-1-6 (E605001-13) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

/^

Result

32

34.4

0.8U

Flags/Qualifiers

*MDL Limit Units

1.9 7.8 mg/kg

0.97 3.88

0.2 0.8

0.29 1.16


10 EE60207 May-04-06May-IO-061ETALSGFA

May-09-061ETALS GFA




Result

31

33.3

0.6U

Flags/Qualifiers

*

J

MDL Limit Units

2.0 8.1 mg/kg

1.01 4.06

0.2 0.8

0.30 1.22


10 EE60207 May-04-06May-IO-061ETALSGFA

May-09-061ETALS GFA

I " " May-12-061ETALSGFA

3 " ' May-l9-06lETALSGFA


Result

28

30.1

0.9U

Flags/Qualifiers

*MDL Limit Units

1.9 7.8 mg/kg

0.97 3.88

0.2 0.8

0.29 1.17




1 " • May-12-061ETALSGFA

3 • • May-19-06lETALSGFA


Result

31

36.8

0.9U

f^^t

Flags/Qualifiers

*

9

MDL Limit Units

2.1 8.2 mg/kg

1.03 4.12

0.2 0.8

0.31 1.24

000051


10 EE60207 May-04-06May-10-06IETALS GFA

May-09-06IETALS GFA



{/ Report Name: E605001 ,E604004 FINAL Mav 24 06 1648Stephen Connet, Chemist Page 21 of 29

TwhUw !05W. Madison Stmt, Sate 90000010,1160602

(312)3454990(312) 3454979 (Fax)wwwtfcdilATeffic.com

Superftjnd, US EPA Region 577 West Jackson Boulevard

Chicago IL, 60604

Project: US Smelter and Lead Refinery, Inc.Project Number: [none] Rtported:



X13-B-6-12 (E605001-14) Soil Sampled: May-01-06 09:45 Received: May-02-06 1 1 :21

Analyte

Antimony

Arsenic

Selenium

Thallium

X13-DZ(E605001-15)Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X13-F-0-1 (E605001-16) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X13-F-1-6 (E60500M7) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

Result

21

24.5

0.4U

Flags/Qualifiers

*

J

MDL Limit Units

2.0 8.1 mg/kg

1.01 4.05

0.2 ' 0.8

0.30 1.22


10 EE60207 May-04-06May-10-06tETALSGFA


1 " " May-12-061ETALSGFA3 " " May-19-06tETALS GFA


Result

31

24.9

0.4U

Flags/Qualifiers

*

J

MDL Limit Units

2.1 8.2 mg/kg

1.03 4.11

0.2 0.8

0.51 2.05




1 ' " May-12-06IETALS GFA5 " " May-l5-06lETALSGFA


Result

47

36.3

1.1U

Flags/Qualifiers

*MDL Limit Units

2.0 8.1 mg/kg

1.01 4.05

0.2 0.8

0.30 1.21


10 EE60207 May-04-06May-10-06tETALSGFA


1 " " May-12-061ETALSGFA3 " " May-19-06lETALS GFA


Result

31

32.6

0.7U

Flags/Qualifiers

*

J

MDL Limit Units

2.0 8.1 mg/kg

1.02 4.07

0.2 0.8

0.31 1.22

Dilution Batch Prepared Analyzed Method (

1 0 EE60207 May-04-06 May- 1 0-06tETALS GFA

May-10-061ETALS GFA

1 " " May-l2-061ETALSGFA3 ' " May-19-06lETALSGFA


Analyte

Antimony

Arsenic

Result

20

20.7

Flags/Qualifiers

*MDL Limit Units

2.0 7.8 mg/kg

0.98 3.91


10 EE60208 May-04-06 May- 1 0-06 tETALS GFA

May-10-065ETALS GFA

Stephen'Connet, Chemist


Page 22 of 29

khLawQitalH) i* I t l t f u l j e

105 W. Madison Stmt, Sate 900

(312)345-8990(312) 3454979 (Fa)




Reported:

May-24-06 16:48


X13-F-6-12 (£605001-18) Soil Sampled: May-01-06 09:10 Received: May-02-06 11:21

Analyte

Selenium

Thallium

Result

OJ

U

Flags/Qualifiers

J

MDL

0.2

0.29

Limit

0.8

1.17

Units

mg/kg


1 EE60208 May-04-06 May- 1 2-06 ffiTALS GFA



Analyte

Antimony

Arsenic

Selenium

Thallium

X35-B-1-6 (£605001-20) Soil Sampled:

Analyte

Antimony

Arsenic

Selenium

Thallium

X35-B-6-12 (£605001-21) Soil Sampled

Analyte

Antimony

Arsenic

Selenium

Thallium

Result

1.6

5.92

0.4U

May-01-06

Result

2.6

8.06

0.6U

Flags/Qualifiers

*

J

MDL Limit

0.2 0.8

0.20 0.81

0.2 0.8

0.30 1.22

Units Dilution

mg/kg 1

2

" 1

3



May-10-06IETALSGFA

May- 1 2-06 ffiTALS GFA

May-19-06lETALS GFA

16:30 Received: May-02-06 11:21

Flags/Qualifiers

*

J

MDL Limit

0.2 0.8

0.20 0.80

0.2 0.8

0.30 1.20

: May-01-06 16:35 Received: May-02-06

Result

2.2

6.93

0.4U

X35-DZ (£605001-22) Soil Sampled: May-01-06 16

Analyte

Antimony


^-~*&? <^ 7 <•

Result

1.0

SM

0.4V

/~~,<£

Flags/Qualifiers

*

J

MDL Limit

0.2 0.8

0.20 0.79

0.2 0.8

0.30 1.19

:20 Received: May-02-06 11:

Flags/Qualifiers

*

J

MDL Limit

0.2 0.8

0.20 0.81

02 0.8

0.30 1.22

000053

Units Dilution

mg/kg 1

2

1

3

11:21

Units Dilution

mg/kg 1

2

1

3

21

Units Dilution

mg/kg 1

2

1

3


EE60208 May-04-06 May-08-061ETALS GFA

May-09-061ETALSGFA

May-ll-06ffiTALSGFA

May-l5-06ffiTALSGFA


EE60208 May-04-06May-l 1-061ETALS GFA

May-10-061ETALS GFA

May-12-061ETALSGFAMay-19-06ffiTALS GFA


EE60208 May-04-06May-ll-06ffiTALS GFA

May-10-061ETALS GFA

May-12-061ETALS GFAMay-19-06fETALS GFA

^^^^ ^-^ Report Name: E60500 1 ,£604004 FINAL May 24 06 1 648StephertTJonnet, Chemist Page 23 of 29

TediLaw !05W. Madison SttNt, Sate 900CbkafOvIL 60602

012)3454990

* *


X35-F-0-1 (£605001-23) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X35-F-1-6 (£605001-24) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X35-F-6-12 (£605001-25) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X42-B-0-1 (£605001-26) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X42-B-1-6 (£605001-27) Soil

Analyte

Antimony

Arsenic

/£^

WWTO rwniM.incco™






3.6 *

11.0

0.5 JU

MDL Limit Units

0.2 0.8 mg/kg

0.30 1.18

0.2 0.8

0.30 1.18

Dilution

1

31

3



May-IO-061ETALS GFA

May-l2-061ETALS GFAMay-19-06lETALSGFA



4.1 *

10.5

0.6 J

U

MDL Limit Units

0.2 0.8 mg/kg

0.30 1.21

0.2 0.8

0.30 1.21

Dilution

1

3

1

3


EE60208 May-04-06May-ll-06ffiTALSGFA


May- 1 2-06 ffiTALS GFAMay-19-06lETALSGFA



5.8 *

lU

0.6 JU

MDL Limit Units

0.4 1.6 mg/kg

OJO 1.20

0.4 1.6

0.30 1.20

Dilution

2

3

23




May-15-061ETALSGFAMay-19-06lETALSGFA



20 *

24.2

0.9U

MDL Limit Units

1-9 7.8 mg/kg

0.97 3.89

0.2 0.8

0.49 1.94

Dilution

10"

1

5


EE60208 May-04-06May-10-06tETALSGFA

May-10-06fETALSGFA

May-12-06ffiTALS GFAMay-22-06ffiTALS GFA



20 *

25.6

5 ~*i tJ f"•""*"* * V ~ f) J&1

MDL Limit Units

1.0 4.0 mg/kg

1.01 4.05

000054

Dilution

510



May-IO-061ETALS GFA

s / Report Name: E60500 1 ,£604004 FINAL Mav 24 06 1 648Stephenêonnet, Chemist Page 24 of 29

Maw (312)345-8990(312) 345^79 (Fax)




Reported:

May-24-06 16:48



Analyte

Selenium

Thallium

Result

0.6U

Flags/Qualifiers

J

MDL

0.2

0.30

Limit

0.8

1.21

Units

mg/kg


1 EE60208 May-04-06May-12-061ETALSGFA3 " " May-19-06'ETALSGFA


Analyte

Antimony

Arsenic

SeleniumThallium

X42-DZ (£605001-29) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X42-F-0-1 (£605001-30) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X42-F-1-6 (£605001-31) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

Result

14

20.3U

U


Result

18

24.4

0.6

0.30

Sampled: May-01-06

Result

15

21.6

0.9U

Sampled: May-01-06

Result

20

30.1

0.7U

Flags/Qualifiers

*MDL

1.2

0.99

0.2

0.30

Limit Units

4.8 mg/kg

3.96

0.8

1.19

Dilution

6

10

1

3



May-10-06IETALS GFAMay-12-06lETALSGFA.

Mav-19-06lETALS GFA

:00 Received: May-02-06 11:21

Flags/Qualifiers

*

J

J

MDL

1.0

1.00

0.2

0.30

Limit Units

4.0 mg/kg

4.00

0.8

1.20

Dilution

5

10

1

3


EE60208 May-04-06May-l 1-061ETALS GFA

May-10-061ETALS GFA

May-l5-06IETALSGFA

May-19-06IETALSGFA

15:20 Received: May-02-06 11:21

Flags/Qualifiers

*MDL

1.0

1.02

0.2

0.31

Limit Units

4.1 mg/kg

4.01

0.8

1.22

Dilution

5

10

1

3




May-15-061ETALSGFA

May-19-06lETALS GFA

15:25 Received: May-02-06 11:21

Flags/Qualifiers

*

J

MDL

1.0

1.01

0.2

0.30

Limit Units

4.0 mg/kg

4.05

0.8

1.21

Dilution

5

10

1

3


EE60208 May-04-06May-ll-06ffiTALSGFA

May-IO-061ETALS GFA

May-l5-06ffiTALSGFAMay-19-06lETALSGFA

<&^ f,z ^ 000055xx^£^<~:;i^

/ Report Name: E60500 1 ,E604004 FINAL May 24 06 1 648StepheivCbnnet, Chemist Page 25 of 29

MawQ u a l i t i <? l i t t t f in - :

105 W.Madaon Strut, Sqfc 900Qncafo,IL 60602

(312)3454990(312) 3454979 (Fit)1MOTP

Superfiind, US EPA Region 5 Project: US Smelter and Lead Refinery, Inc.77 West Jackson Boulevard Project Number: [none] Reported:Chicago IL, 60604 Project Manager: Warren Layne May-24-06 16:48


X42-F-6-I2 (£605001-32) Soil Sampled: May-Ol-O^ 15:30 Received: May-02-06 11:21

Analyte


X49-B-0-1 (£605001-33) Soil


X49-B-1-6 (£605001-34) Soil



10 *

17.2

0.2 J

U

MDL Limit Units

1.0 4.0 mg/kg

0.50 2.02

0.2 0.8

0.30 1.21


5 EE60208 May-04-06 May-08-06 IETALS GFA

May-08-06 IETALS GFA

1 " " May-ll-061ETALSGFA




21 *

16.0

1.0 J

U

MDL Limit Units

2.0 7.9 mg/kg

0.50 1.99

0.4 1.6

0.50 1.99




2 " " May- 15-06 IETALS GFA

5 " " May-22-06fETALS GFA



110 *

25.5

1.1

0.65 J

MDL Limit Units

8.1 32 mg/kg

1.01 4.04

0.2 0.8

0.30 1.21


40 EE60208 May-04-06 May- 10-06 IETALS GFA

10 ' ' May- 10-06 IETALS GFA


3 " " May-19-06IETALS GFA



X49-DZ (£605001-36) Soil

AnalyteAntimony

^

>g> .̂


32 *

23.4

1.1U

MDL Limit Units

1.9 7.8 mg/kg

0.97 3.90

0.2 0.8

0.49 1.95



May-10-06IETALSGFA

1 " " May-15-06IETALSGFA

5 " " May-22-06 IETALS GFA



48 *

y^^

MDL Limit Units

3.9 16 mg/kg

000056


20 EE60208 May-04-06 May- 10-06 IETALS GFA

/^ ^^ Report Name: E60500 1 .E604004 FINAL Mav 24 06 1 648StephojJ-Connet, Chemist Page 26 of 29

Tedilaw105W.Madi«mStmt,$mii900

Q u a l i t y

(312)345-8990(312) 345-8979 (F«)




X49-DZ (E605001-36) Soil Sampled: May-01-06 12:10 Received: May-02-06 11:21

Analyte

Arsenic

Selenium

Thallium

X49-F-0-1 (E605001-37) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X49-F-1-6 (E605001-38) Soil

Analyte

Antimony

Arsenic

Selenium

Thallium

X49-F-6-12 (E605001-39) Soil

Analyte

Flags/Result Qualifiers MDL Limit Units

26.0 0.98 3.90 mg/kg

1.4 0.2 0.8

U 0.49 1.95



30 * 2.0 8.1 mg/kg

20.5 0.51 2.04

1.5 J 0.4 1.6

U 0.31 1.22



28 * 2.0 8.0 mg/kg

23.9 1.00 4.02

1.1 0.2 0.8

0.33 J 0.30 1.20



Antimony 21 *

Arsenic 20.3

Selenium 0.7 J

Thallium U

X49-FD-6-12 (E605001-40) Soil Sampled: May-01-06 12:00

Analyte

Antimony

Arsenic

Selenium


23 *

19.9

0.7 J

MDL Limit Units

1.0 4.0 mg/kg

0.50 2.01

0.2 0.8

0.30 1.20

Received: May-02-06 11:21

MDL Limit Units

2.0 8.1 mg/kg

0.50 2.02

0.2 0.8


10 EE60208 May-04-06May-10-06ffiTALS GFA

1 " " May- 15-06 ffiTALS GFA






3 " " May-l9-06*ETALS GFA


10 EE60208 May-04-06May-10-06ffiTALSGFA

May- 10-06 ffiTALS GFA

1 " " May- 15-06 ffiTALS GFA




May-08-061ETALS GFA

1 " " May-ll-06ffiTALSGFA

3 " " May-15-06*ETALSGFA


1 0 EE60208 May-04-06 May- 1 0-06 ffiTALS GFA

5 " ' May-10-061ETALS GFA

1 ' " May-15-061ETALSGFA

^jf~ <^'i<i^& 000057/£/^ ^^ Report Name: E605001,E604004 FINAL May 24 06 1648

Stephe&CTonnet, Chemist Page 27 of 29

TediLawQta l i t i

lOSW.MadiamStiwt.SufcWOQricafo,IL 60602

012J34W990(312) 345-S979 £«)www tefhlaninc com




Reported:

May-24-06 16:48

Metals by GFAA

TechLaw - ESAT ContractX49-FD-6-12 (E60500I-40) Soil Sampled: May-01-06 12:00 Received: May-02-06 11:21

Analyte ResultFlags/

Qualifiers MDL Limit Units Dilution Batch Prepared Analyzed Method

Thallium 0.37 0.30 1.21 trig/kg EE60208 May-04-06May-19-061ETALSGFA

000058

Stephe^ônnet, ChemistReport Name: E605001.E604004 FINAL May 24 06 1648

Page 28 of 29

Mlaw 105 W. Madison Stwtt, Sate 900Qucafo,IL 60602

(312)3454990(312) 3454979 (F«)




Reported:

May-24-06 16:48


X

J

<5X

*

uMR

U



The duplicate analysis precision is not within control limits The reported value is estimated.

Not Detected

Not Reported



Page 29 of 29


Work Order SF E f r Q ^ f l l _ ^£ SW/fc r j l&lA

Chain-of-Custody on file

LIMS Invoice # g^£0^f JMt&o fm. SQ



Transmittal Memo w/signatures of the following:

• Analyst(s)


Prepared by

nen

4FA-A

Envi/onntfnfal Data Coordinator





Date: MAY 2 6 2006

Subject: Review of Region 5 Data for US Smelter and Lead Refinery, Inc.

From: Stephen Connet, Chemist, TechLaw Inc. / ESATContractor to Region 5 Central Regional LaboratorySubmitted to CRL on

To:





Data ManagemenrGoordinator and Date Received

TA * T •« j HAY 2 6 Z006Date Transmitted: " /



Sylvia GriffinData Management CoordinatorRegion 5 Central Regional LaboratoryML-IOC

Received by and Date

Comments:





Rev. 4/10/02

I o f 3Method: 200.7 (ICP Metals) TDF: R5-01-004, 5Site: US Smelter and Lead Refinery, Inc. TechLaw Job #: 03037.1.01.02.01.053J.000.004,5Date: May 9,2006 Task Order #: R5-0-01Prepared by: Stephen Connet Data Sets: £604004, E605001

NARRATIVE

Five (5) water samples from the US Smelter and Lead Refinery, Inc. site were collected between April 26 andMay 1,2006 and were received properly preserved at CRL on April 28 and May 2,2006. The samples weresubmitted to ESAT for analysis of total metals by ICP. The sample point identifications are listed on the firstpage of the LIMS report following this narrative.

The water samples were digested following standard CRL 200.2 hot block digestion protocols (CRL SOPMETALS025) on May 3,2006 (LIMS digestion batch EE60203). The samples were analyzed on May 5,2006according to CRL SOP METALS003 using the Optima 4300. Recently Devaluated (not listed inMETALS003) U.S. EPA MDL/RL values were used for evaluation of the data per Dr. J. V. Morris becausechanges were made to the instrument and ESAT has not had an opportunity to perform new MDL/RLevaluations.


Sb, Al, As, Ba, Be, Ca, Cd, Cr, Co, Cu, Fe, Pb, Mg, Mn, Ni, K, Se, Ag, Na, Tl, V, Zn

The following lists the case pertinent out-of-control QC audit check results based on ESAT QA/QC limits:

Blanks: Instr. Blank 1 Co 228 0.36 ug/LNi231 0.71 ug/LV 292 0.60 ug/L

Instr. Blank 2 Ni 231 0.54 ug/LV 292 0.69 ug/L

RL Check Soln: Presently no "control" actions are associated with the observed RL analyte valuesactually determined during the analysis run. RL check solution values currently arebeing analyzed for purposes of generating a benchmark set of values which can be usedto monitor the appropriateness of any given RL level of analyte concentration. Valuesare subject to change pending further repairs on the instrument. U.S. EPA and ESATRL solutions were analyzed in the April 25,2006 analytical run.

Duplicate:EE60203-DUP1 (E604004-01): Ag328, A1396, Asl93, Be313, Cd226, Co228, Cr267 <5X

Cu327, Fe259, Mn257, Pb220, Sb206, Sel96, T1190 <5XBa455, V292, Zn213 * (difference > MDL)Na589 * (RPD > ESAT limit)

<5X: Sample and/or duplicate <5X MDL; duplicate difference acceptable (<MDL).*: Indicates out of control result (ESAT limits)

2 of 3Note: Although the duplicate difference is greater than the MDL for Be313, Cd226, Cu327 and Sb206, bothsample and duplicate values are less than the MDL and the difference is considered acceptable.


Control limits are normally set according to ESAT control charts. However, not enough data points forinstrument checks have been analyzed to determine ESAT control limits. Those control limits are setaccording to EPA limits. ESAT control limits are used for matrix QC.

For Ba, the sample and laboratory duplicate were less than 5X the MDL; duplicate difference is used for thecontrol criteria. The matrix duplicate difference is greater than the MDL indicating possible poor precision; allBa sample results and EE60203-DUP1 are flagged "*" in LIMS due to possible poor precision. Also, thesample results for E604004-01 and E605001-01 are greater than the MDL but less than the RL; Ba for thosesamples are flagged "J" in LIMS.

For Ca, the sample results for E604004-02, E605001-02 and -03 are greater than the MDL but less than theRL; Ca for those samples are flagged "J" in LIMS.

For Co, one of the instrument blanks had a value greater than the MDL indicating possible contamination.Sample results for E604004-02 and E605001-01 are flagged "K" in LIMS due to the possible contamination.Additionally, sample results for E604004-02 and E605001-01 are greater than the MDL but less than the RL;Co for those samples are also flagged "J" in LIMS.

For Cr, the sample result for E605001-02 is greater than the MDL but less than the RL; Cr for that sample isflagged "J" in LIMS.

For Cu, the sample results for E605001-01 thru -03 are greater than the MDL but less than the RL; Cu forthose samples are flagged "J" in LIMS.

For Fe, all Fe results were reported from the Fe 259 line. The sample results for E604004-02 and E605001-01are greater than the MDL but less than the RL; Fe for those samples are flagged "J" in LIMS.

For Mg, all results are reported from the Mg 280 line.

For Mn, the sample results for E604004-01 and E605001-02 are greater than the MDL but less than the RL;Mn for those samples are flagged "J" in LIMS.

For Na, the duplicate RPD was greater than the ESAT limit indicating possible poor precision; all Na sampleresults and EE60203-DUP1 are flagged "*" in LIMS due to possible poor precision.

For Se, the sample result for E604004-02 is greater than the MDL but less than the RL; Se for that sample isflagged "J" in LIMS.

For V, both of the instrument blanks had values greater than the MDL indicating possible contamination. Thesample results for E604004-02, E605001-01, and -02 are flagged "K" in LIMS due to the possiblecontamination. Also, the sample was less than the MDL and laboratory duplicate were less than 5X the MDL;duplicate difference is used for the control criteria. The matrix duplicate difference is greater than the MDL

3 of 3indicating possible poor precision; all V sample results and EB60101-DUP1 are also flagged "*" in LIMS dueto possible poor precision. Finally, the sample results for E604004-02, E605001-01, and -02 are greater thanthe MDL but less than the RL; V for those samples are also flagged "J" in LIMS.

For Zn, the laboratory duplicate was less than 5X the MDL; duplicate difference is used for the controlcriteria. The matrix duplicate difference is greater than the MDL indicating possible poor precision; all Znsample results and EE60203-DUP1 are flagged "*" in LIMS due to possible poor precision. Also, all sampleresults are greater than the MDL but less than the RL; all Zn sample results are flagged "J" in LIMS.


Other comments

No samples were identified as field duplicates or field blanks.

It has been observed that, due to differences in the significant figures used for calculation, RPD values andsome matrix spike recoveries calculated by LIMS are not correct. The correct values are included as Excelspreadsheets in the Analytical/Matrix QC Summary Report provided in the data package.

TwhLaw Chic*fo,IL 60602(312)34W990

(312) 3454979 (F«)




Reported:

May-19-06 11:21


I Sample ID Laboratory ID Matrix Date Sampled Date Received

Auger 1

Auger 1

Auger 3

Auger 4

Auger 5

E604004-01

E604004-02

E605001-01

E605001-02

E605001-03

Water

Water

Water

Water

Water

Apr-26-06 12:45 Apr-28-06 12:08

Apr-27-06 13:55 Apr-28-06 12:08

May-01-06 12:05 May-02-06 11:21

May-01-06 14:55 May-02-06 11:21

May-01 -06 16:40 May-02-06 11:21

000011

Stephen (£piffiet, ChemistReport Name: E605001.E604004 FINAL May 19 06 1121

Page 1 of 6

TechLawQtalit} £ l i t t cx t i ly

105 W. Madison Strut, So*900Qnca|o,IL 60602

(312)34M990(312) 3454979 (Fn)vmno



Reported:

May-19-06 11:21


Auger 1 (£604004-01) Water Sampled: Apr-26-06 12:45 Received: Apr-28-06 12:08

AnaJyte

AluminumAntimonyArsenicBarium

BerylliumCadmiumCalcium

ChromiumCobaltCopperIron

LeadMagnesium

Manganese

Nickel

Potassium

SeleniumSilverSodium

ThalliumVanadiumZinc

Auger 2 (£604004-02) Water

Analyte


ChromiumCobalt

ResultUUU

1.0UU

4150UUU

52.2U

341

0.9

81.1

5230UV

820UU

19.5

Sampled: Apr-27-06

Result

UU

VUUU

72.0

UOJ


25.4

3.03.3

J, * 0.4

0.10.357.9

0.40.20.916.3

2.55.9

j 0.4

0.5

92.3

7.00.7

» 45.9

6.7* 0.3

J, * 3.9

Limit Units

100 ug/L

20.0

20.0

3.0

1.02.0200

5.03.05.050.0

15.0

100

1.0

3.0

800

30.0

5.0400

20.0

5.030.0


1 EE60203 May-03-06May-05-06 EPA 200.7" EPA 200.7

» " • EPA 200.7

EPA 200.7

» " • EPA 200.7

- - • EPA 200.711 " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

" EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.711 EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

13:55 Received: Apr-28-06 12:08


25.4

3.03.3

* 0.4

0.10.3

J 57.9

0.4

J, K 0.2

Limit Units

100 ug/L

20.0

20.0

3.01.02.0200

5.03.0


1 EE60203 May-03-06May-05-06 EPA 200.7" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

» EPA 200.7

" " • " EPA 200.7

EPA 200.7

EPA 200.7



Page 2 of6

TechLaw 105 W.MidisonStmt, Safe 900Qucafo,IL 60602

012)3454990




Reported:

May-19-06 11:21


Auger 2 (£604004-02) Water Sampled: Apr-27-06'13:55 Received: Apr-28-06 12:08

Analyte

CopperIron

LeadMagnesium

Manganese

Nickel

Potassium

Selenium

Silver

SodiumThalliumVanadium

Zinc

ResultU

24.7UUV

48.9

U

8.5UUU

0.5

8.1


0.9J 16.3

2.55.90.40.5

92.3

J 7.0

0.7* 45.9

6.7

J, K, » 0.3

J, * 3.9

Limit

5.050.0

15.0

1001.03.0

80030.0

5.040020.0

5.0

30.0

Units Dilution Batch Prepared Analyzed

ug/L 1 EE60203 May-03-06May-05-06" M M « .

„n ii n ti n

n n ii n n

n M n I •

„

„

I,

,,

"

ti M it n M

" "

Method

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Auger 3 (E605001-01) Water Sampled: May-01-06 12:05 Received: May-02-06 11:21

Analyte

Aluminum

Antimony

Arsenic

Barium

Beryllium

Cadmium

CalciumChromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

Nickel

Potassium

Selenium

Silver

Result

UUU

0.5UVUU

0.2

1.7

43.0

UU

U

34.8

UUU


25.4

3.03.3

J, * 0.4

O.I0.357.9

0.4J, K 0.2

J 0.9

J 16.3

2.55.90.40.5

92.3

7.00.7

Limit

10020.0

20.0

3.0

1.02.02005.03.0

5.0

50.0

15,0

too1.03.0

80030.0

5.0


ug/L 1 EE60203 May-03-06May-05-06 EPA 200.7

» EPA 200.7

• EPA 200.7

" EPA 200.7

• EPA 200.7

" EPA 200.7

EPA 200.7

• " EPA 200.7

" " " " EPA 200.7

EPA 200.7

" " " EPA 200.7

" " EPA 200.7

" EPA 200.7

EPA200.7

EPA 200.7" EPA 200.7

" EPA 200.7

" EPA 200.7

Stephen£S6nnet, Chemist


Page 3 of6

khLawQ x a l i t j

105 W. Madison Stnrt, Suite 900Ouca|o,IL 60602

(312)3454990(312) 3454979 (Fa)




Reported:

May-19-06 11:21

Metals by ICP

TechLaw - ESAT ContractAuger 3 (£605001-01) Water Sampled: May-01-06 12:05 Received: May-02-06 11:21

Analyte

SodiumThalliumVanadium

Zinc

Auger 4 (£605001-02) Water

Analyte


Chromium

CobaltCopper

Iron


Nickel

PotassiumSeleniumSilverSodiumThalliumVanadium

Zinc

Result

UU

0.6

4.6

Sampled: May-01-06

Result

UUUUU

U

87.1

0.8U

3.4

288UU

1.0

36.9

UUUUU

0.8

7.9


» 45.9

6.7

J, K, * 0.3

J, • 3.9

14:55 Received:


25.4

3.03.3

* 0.4

0.10.3

J 57.9

J 0.4

0.2J 0.9

16.3

2.55.9

J 0.4

0.5

92.3

7.00.7

« 45.9

6.7

J, K, * 0.3

J, * 3.9

400 ug/L

20.0

5.0

30.0

May-02-06 11:21

Limit Units

100 ug/L

20.0

20.0

3.01.02.0200

5.0

3.05.0

50.0

15.0

1001.0

3.0

80030.0

5.040020.0

5.0

30.0


1 EE60203 May-03-06May-05-06 EPA 200.7|| n

„

it n n


EPA 200.7

EPA 200.7

EPA 200.7

Analyzed Method

1 EE60203 May-03-06May-05-06 EPA 200.7,.II H N

„

II II H

II «

„

„

„

„

"

II II •

„

II II •

„

I,

II H It

„

„

„

it H n

„

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 4 of6

TechLaw 105 W. Madison SttHtSofc 900Chkafo,IL 60602

012)3454990(312) 3454979 (Fa)




Reported:

May-19-06 11:21


Auger 5 (£605001-03) Water Sampled: May-01-06 16:40 Received: May-02-06 11:21

Analyte



IronLeadMagnesiumManganeseNickel

PotassiumSeleniumSilverSodiumThalliumVanadiumZinc

Result

UUUUUU

79.3

UU

3.1UUUU

10.7

UUUUUU

5.2


25.4

3.03.3

* 0.4

0.10.3

J 57.9

0.40.2

J 0.9

16.3

2.55.90.40.5

92.3

7.00.7

• 45.9

6.7* 0.3

J, * 3.9

Limit

10020.0

20.0

3.01.02.0200

5.03.05.0

50.0

15.0

1001.03.0

80030.0

5.040020.0

5.030.0

Units Dilution Batch Prepared Analyzed

. ug/L 1 EE60203 May-03-06May-05-06II H II N H

n

„..

it n M H n

••.

ti tt n n w

n it H « n

.n

„u . i. i, n

„

„

„

,,

.

"

n n n it H

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7


000015

Report Name: E605001,E604004 FINAL May 19 06 1121

Page 5 of6

MLaw 105 W. Madison Stout, Sate 900

(312)3454990(312) 3454979 (Fa)

.ttdda wine .com





x

K

J

<5X

*

U

NR

U

The identification of the analyte is acceptable; the reported value may be biased high. The actual value is expected to be less thanthe reported value.



The duplicate analysis precision is not within control limits. The reported value is estimated.

Not Detected

Not Reported

000016

Stephen Comet, ChemistReport Name: E605001,E604004 FINAL May 19 06 1121

Page 6 of6


Work Order SF £ 6 &S0Q) U s Srvigffgr g Uad P<rf?n e,

Chain of Custody

Final report from LIMS Invoice #



Transmittal Memo w/signatures of the following:

• Analyst(s)


Prepared bj

Date:

Subject:

From:

To:





HAY 2 6 2006


Stephen Connet, Chemist, TechLaw Inc. / ESATContractor to Region 5 Central Regional LaboratorySubmitted to CRL on i£- ff





aG/ 2006

Daî Management Coordinator and Date Received

MAY 2 6 2DOEDate Transmitted: / /




/07_Received by and Dale

Comments:





Rev. 4/10/02

1

Method: 200.7 (ICP Metals)Site: US Smelter and Lead Refinery, Inc.Date: May 19 2006Prepared by: Stephen Connet

TDF: R5-01-004,5TechLaw Job #: 03037.1.01.02.01.053J.000.004,5Task Order #: R5-0-01Data Sets: E604004, E605001

NARRATIVE

One hundred three (103) soil samples from the US Smelter and Lead Refinery, Inc. site were collectedbetween April 26 and May 1, 2006 and were received properly preserved at CRL on April 28 and May 2,2006. The samples were submitted to ESAT for analysis of total metals including cadmium and lead by ICP.The sample point identifications are listed on the first page of the LIMS report following this narrative. Rawdata and QC forms are filed in the folder for E604004.

The soil samples were dried and ground between May 1 and 4,2006 prior to being digested followingstandard CRL 200.2 hot block digestion protocols (CRL SOP METALS025). They were batched in 5 LIMSbatches (LIMS digestion batch EE60204 thru EE60208). All batches were digested on May 4,2006. Theywere analyzed between May 8 and 17, 2006 according to CRL SOP METALS004 using the Optima 4300.One batch (EE60205) was reanalyzed due to instrument QC problems in the run. Recently completed (notlisted in METALS004) U.S. EPA MDL/RL values were used for evaluation of the data per Dr. J. V. Morris.ESAT has not had an opportunity to perform MDL/RL evaluations.


Al, Ba, Be, Ca, Cd, Cr, Co, Cu, Fe, Mg, Mn, Ni, Pb, K, Ag, Na, V, Zn

Qualifications of results will be limited to samples within each individual digestion batch. Each was analyzedas a separate analytical run. The following lists the case pertinent out-of-control QC audit check results:

Batches: EE60204 contains samples E604004-03 thru -22 (run May 8, 2006)EE60205 contains samples E604004-23 thru -42 (run May 17, 2006)EE60206 contains samples E604004-43 thru -62 (run May 11, 2006)EE60207 contains samples E604004-63 thru -68 and E605001-04 thru -17 (run May 12, 2006)EE60208 contains samples E605001-18 thru -40 (run May 15, 2006)

Blanks: (May 8)

(May 17)

(May 11)

(May 12)

(May 15)

(May 17) LCM1(3):

Instrblkl:

EE60205-BLK1

Instr blk4:

EE60207-BLK1

EE60208-BLK1

Cr267

Ag328

Cr267

Cr267

Ag328

-2.37 ug/L

-4.36 ug/L

-2.72 ug/L

-2.34 ug/L

-5.93 ug/L

Co 228 10.10% deviationK 766 10.28% deviation

000029

RL Check Soln: Presently no "control" actions are associated with the observed RL analyte valuesactually determined during the analysis run. RL check solution values currently arebeing analyzed for purposes of generating a benchmark set of values which can be usedto monitor the appropriateness of any given RL level of analyte concentration. Valuesare subject to change pending further repairs on the instrument. Since no soil RLsolution has been prepared, CRL and ESAT water (METALS003) RL solutions wereanalyzed in the analytical run.

Duplicates:EE60204-DUP1 (E604004-12):

EE60204-DUP2 (E604004-22):

EE60205-DUP1 (E604004-34):

EE60205-DUP2 (E604004-42):

EE60206-DUP1 (E604004-43):

EE60206-DUP2 (E604004-42):EE60207-DUP1 (E604004-68):

EE60207-DUP2 (E605001-15):

EE60208-DUP1 (E605001-20):

EE60208-DUP2 (E605001-32):

Cu324Ni231Zn213Ag328,Cr267Ni231Ag328,Mg279Pb220Ag328,Ba455Mg279Ni231Pb220Be313Ag328,A1308Ba455Cd214Cu324Pb220K766V310Zn213Be313Ag328,Ag328,Ni231Cd214Ag328,Ba455Co228,Ag328,Ca315Co228Mg279Ag328,Ba455

Be313,Co228,

Be313,Cd214,

Be313,Cd214,

Co228

Co228Co228

Be313,Co228,

Na589Be313

Be313,Cd214,

40.54% RPD *39.38% RPD *27.45% RPD *

V310 <5X44.14% RPD*51.5 8% RPD*

Co228, Na589 < 5X9.12% RPD * (ESAT limit = 8.7%)14.37% RPD * (ESAT limit = 12%)

Co228,Na589,V310 < 5X3 3.74% RPD*13.42% RPD * (ESAT limit = 8.7%)20.40% RPD *15.28% RPD * (ESAT limit = 12%)* (difference > MDL)<5X19.04% RPD * (ESAT limit = 12.1%)27.12% RPD*20.20% RPD *21.59% RPD*29.91% RPD*18.73% RPD * (ESAT limit = 18.3%)20.61% RPD*23.78% RPD ** (difference > MDL)<5X<5X23.10% RPD** (difference > MDL)

Na589,V310 <5X12.63% RPD * (ESAT limit =* (difference > MDL)<5X36.98% RPD *25.51% RPD*48.55% RPD *

Na589 < 5X18.72% RPD * (ESAT limit = 10%

000030

19.10% RPD * (ESAT limit = 15.9%)28.96% RPD *

< 5XEE60208-DUP3(E605001-39):

Fe273Pb220Ag328, Be313, Cd214, Co228, Na589, V310Ba455 24.28% RPD*Cd214 23.77% RPD*Cr267 24.48% RPD *Fe273 36.61% RPD*Ni231 20.02% RPD*Ag328,Be313,Co228,Na589 <5X

< 5X: Sample and/or duplicate < 5X MDL; duplicate difference acceptable (< MDL).* : Indicates out of control result (ESAT limits)

Matrix spikes:EE60204-MS1 (E604004-12):

EE60206-MS1 (E604004-43):

EE60208-MS1 (E605001-20):

Pb220Zn213Pb220Zn213Cu324

#125.8% recovery118.7% recovery (ESAT limit = 109.9%R)109.2% recovery (ESAT limit = 107.9%R)112.5% recovery (ESAT limit =111.8%R)

# Spike invalid. Sample > 2X spike concentration. Blank spike or control sample used for controlpurposes.

Control Samples:EE60205-SRM1: Ag328EE60208-SRM1: Ag328

Serial Dilutions:EE60206-SRD1: Cr267EE60207-SRD1: A1308EE60208-SRD1: K766


0% recovery19.3% recovery

11.8% difference10.1% difference11.6% difference

Control limits are normally set according to ESAT control charts. However, not enough data points forinstrument checks have been analyzed to determine ESAT control limits. Those control limits are setaccording to EPA limits. ESAT control limits are used for matrix QC. A linearity check sample wasperformed for Ba, Cr, Cu, Mn, Ni, Pb and Zn to extend the usable range of the instrument.

For Ag, negative Ag values whose absolute values were greater than the MDL were present for the digestionblank EE60205-BLK1 indicating a possible low bias. Samples E604004-25 thru -27, -29 thru -31 and -35 areflagged "L" in LIMS indicating the possible low bias. The instrument value for non-detect samples E604004-24 and -28 were sufficiently high to be affected by the possible low bias; those samples are also flagged "L"in LIMS. In the same analytical run, Ag results for the control samples EE60205-SRM1 and EE60208-SRM1were less than the lower ESAT limit indicating a possible low bias; Ag results for samples E604004-23 thru -42, E605001-18 thru -40 and control samples EE60205-SRM1 and EE60208-SRM1 are flagged "L" in LIMSdue to possible low bias. Finally, the raw instrument value is greater than the MDL but less than the RL for

000031•̂ '15'

heLCMl(3)chinples prior to LI-30 thru -42 are-15 and itsduple difference wasg possible poor; EE60207-DUPEE60208-DUP1>rE605001-18tlvision. Finally, ig samples: E604ton-11,-13,-14MS.

he duplicate RPg possible poor ]* EE60204-DU1tally, the Cu matg a possible higl'K" in LIMS dvu

he duplicate RP1poor precision,ire flagged "*" it•ted from the Fe

he duplicate RPupper ESAT lirr-18thru-40anc'*" in LIMS inds greater than th<matrix spike EE(

the duplicate RPmit indicating poand duplicates Epoor precision,re reported from

he duplicate RPI'ere greater than i1-03 thru -42, -63JE60207-DUP1 \

iieLCMl(3)cheimples prior to LI1-30 thru -42 are

the following samples: E604004-03 thru -18, -25 thru -27, -29 thru -31, -35, -43, -45, -46, -62 thru -6E605001-04 thru -07, -10, -16, -33, -36, -37, -39 and -40. Ag results for those samples are flagged "JLIMS.

For Al, all sample results are reported from the Al 308 line. The duplicate RPD for EE60206-DUP11greater than the upper ESAT limit indicating possible poor precision. The Al sample results for E60'thru -62 and duplicate EE60206-DUP1 are flagged "*" in LIMS indicting possible poor precision.Additionally, the Al serial dilution result for EE60207-SRD1 was greater than the original result indipossible negative interference. Al results for E604004-63 thru -68 and E605001-04 thru -17 are flag]in LIMS due to the possible interference.

For Ba, the duplicate RPD for EE60205-DUP2, EE60206-DUP1, EE60207-DUP2, EE60208-DUP2 i-DUP3 were greater than the upper ESAT limit indicating possible poor precision. The Ba sample reE604004-23 thru -68, E605001-04 thru -40 and duplicates EE60205-DUP2, EE60206-DUP1, EE602DUP2, EE60208-DUP2 and -DUP3 are flagged "*" in LIMS indicting possible poor precision.

For Be, the duplicates E604004-42/EE60205-DUP2 and E604004-43/EE60206-DUP1 were greater tMDL but less than 5X the MDL. Duplicate difference was used for control purposes. The duplicatedifference was greater than the MDL indicating possible poor precision. The Be sample results for E23 thru -62 and duplicates EE60206-DUP1 and EE60205-DUP2 are flagged "*" in LIMS indicting ppoor precision. Finally, the raw instrument value is greater than the MDL but less than the RL for thfollowing samples: E604004-07, -09, -10, -12 thru -18, -20, -22 thru -33, -36, -37, -39 thru -48, -53 i-66 thru -68, E605001-08 thru -24, -26 thru -33, -37, -39 and -40. Be results for those samples are fl.in LIMS.

For Cd, the sample E604004-68 and its duplicate EE60207-DUP1 were greater than the MDL but les5X the MDL. Duplicate difference was used for control purposes. The duplicate difference was grethe MDL indicating possible poor precision. The Cd sample results for E604004-63 thru -68, E6050thru -17 and duplicate EE60207-DUP1 are flagged "*" in LIMS indicting possible poor precision.Additionally, the duplicate RPD for EE60206-DUP1 and EE60208-DUP3 were greater than the upp<indicating possible poor precision. The Cd sample results for E604004-43 thru -62, E605001-18 thrduplicates EE60206-DUP1 and EE60208-DUP3 are flagged "*" in LIMS indicting possible poor preFinally, the raw instrument value is greater than the MDL but less than the RL for the following samE604004-09, -21 thru -23, -34, -38, -41, -46, -55, -57, -59, .-64, -68, E605001-11, -18 thru -25, -28 aiCd results for those samples are flagged "J" in LIMS.

For Ca, the duplicate RPD for EE60208-DUP1 was greater than the upper limit indicating possible pprecision. The Ca sample results for E605001-18 thru -40 and duplicate EE60208-DUP1 are flagge<LIMS indicting possible poor precision.

For Cr, the duplicate RPD for EE60204-DUP2 and EE60208-DUP3 were greater than the upper lim:indicating possible poor precision. The Cr sample results for E604004-03 thru -22, E605001-18 thnduplicates EE60204-DUP2 and EE60208-DUP3 are flagged "*" in LIMS indicting possible poor pr<Additionally, the Cr serial dilution result for EE60206-SRD1 was greater than the original result indpossible negative interference. Cr results for E604004-43 thru -62 are flagged "L" in LIMS due to tpossible interference.

000032

for EE60206-DUP1 was greater than the upper limit indicating possible poor precision. The K sample resultsfor E604004-43 thru -62 and duplicate EE60206-DUP1 are flagged "*" in LIMS indicting possible poorprecision. Finally, the K serial dilution result for EE60208-SRD1 was greater than the original resultindicating a possible negative interference. K results for E605001-18 thru -40 are flagged "L" in LIMS due tothe possible interference.

For Na, the sample E605001-15 and its duplicate EE60207-DUP2 were greater than the MDL but less than5X the MDL. Duplicate difference was used for control purposes. The duplicate difference was greater thanthe MDL indicating possible poor precision. The Na sample results for E604004-63 thru -68, E605001-04thru -17 and duplicate EE60207-DUP2 are flagged "*" in LIMS indicting possible poor precision. Finally,the raw instrument value is greater than the MDL but less than the RL for the following samples: E604004-17,-20, -21, -23, -24, -36, -38, -41, -46, -55, -57, -59, -64, -68, E605001-17 thru -22 and -28. Na results for thosesamples are flagged "J" in LIMS.

For V, the duplicate RPD for EE60206-DUP1 was greater than the upper limit indicating possible poorprecision. The V sample results for E604004-43 thru -62 and duplicate EE60206-DUP1 are flagged "*" inLIMS indicting possible poor precision. Finally, the raw instrument value is greater than the MDL but lessthan the RL for the following samples: E604004-23, -34, -38, -46, -64, -68, E605001-18, -28 and -32. Vresults for those samples are flagged "J" in LIMS.

For Zn, the duplicate RPD for EE60204-DUP1 and EE60206-DUP1 were greater than the upper limitindicating possible poor precision. The Zn sample results for E604004-03 thru -22, -43 thru -62 andduplicates EE60204-DUP1 and EE60206-DUP1 are flagged "*" in LIMS indicting possible poor precision.Additionally, the Zn matrix spike recovery for EE60204-MS1 and EE60206-MS1 were greater than the upperESAT limit indicating a possible high bias. Zn for samples E604004-03 thru -22, -43 thru -62 and matrixspikes EE60204-MS1 and EE60206-MS1 are flagged "K" in LIMS due to the possible high bias. The Znresult for sample E604004-48 was greater than the linearity check sample; the sample was diluted 2X andreanalyzed. The Zn result was reported from the dilution.


Other commentsSamples E604004-30/-31, -44/-4S, -527-53, E605001-09/-10 and -39/-40 were identified as field duplicates.E604004-30/-31 showed good correlation for all elements except Pb, E604004-44/-45 showed goodcorrelation for all elements except Ag, E604004-52/-53 showed good correlation for all elements except Ni,E605001-09/-10 showed good correlation for all elements except Ca and Mg and E605001-39/40 showedgood correlation for all elements except Cu, Na and Ni. Determinations of correlation were made accordingto laboratory duplicate criteria; however, no sample results are qualified for field duplicates.

It has been observed that, due to differences in the significant figures used for calculation, RPD values andsome matrix spike recoveries calculated by LIMS are not correct. Some of these values are reported by LIMSas being outside QC requirements when they are not. The correct values are included as Excel spreadsheets inthe Analytical/Matrix QC Summary Report provided in the data package.

000034

MawQ u a l i t y <,>

105 W. Madison Str*, Sate 900Cbicafo, 160602

(312)3454990(312) 3454979 (Fa)




Sample ID

X03-B-0-1

X03-B-1-6

X03-B-6-12

X03-DZ

X03-F-0-1

X03-F-1-6

X03-F-6-12

X07-B-0-1

X07-B-1-6

X07-B-6-12

X07-DZ

X07-F-0-1

X07-F-1-6

X07-F-6-12

XI5-B-0-1

X15-B-1-6

XI5-B-6-12

X15-DZ

XI5-F-0-1

X15-F-1-6

X15-F-6-12

X19-B-0-1

X19-B-1-6

X19-B-6-12

X19-DZ

X19-F-0-1

X19-F-1-6

X19-F-6-12

*£*JL>^

Laboratory ID

E604004-03

E604004-04

E604004-05

E604004-06

E604004-07

E604004-08

E604004-09

E604004-10

E604004-11

E604004-12

E604004-13

E604004-14

E604004-15

E604004-16

E604004-17

E604004-18

E604004-19

E604004-20

E604004-21

E604004-22

E604004-23

E604004-24

E604004-25

E604004-26

E604004-27

E604004-28

E604004-29

E604004-30

000035S. Z6>-<s><b>

Matrix

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Report Name:

Date Sampled

Apr-26-06 12:35

Apr-26-06 12:40

Apr-26-06 12:45

Apr-26-06 12:30

Apr-26-06 12:20

Apr-26-06 12:25

Apr-26-06 12:25

Apr-26-06 09:50

Apr-26-06 09:55

Apr-26-06 09:55

Apr-26-06 10:00

Apr-26-06 10: 15

Apr-26-06 10:40

Apr-26-06 10:45

Apr-26-06 15:25

Apr-26-06 15:45

Apr-26-06 15:35

Apr-26-06 15:20

Apr-26-06 14:40

Apr-26-06 14:45

Apr-26-06 14:50

Apr-26-06 16:50

Apr-26-06 16:55

Apr-26-06 17:00

Apr-26-06 16:15

Apr-26-06 16:00

Apr-26-06 16:05

Apr-26-06 16: 10

Date Received

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

E605001,E604004 FINAL May 25 06 1443Stephenêfinet, Chemist Page 1 of74

Maw 105 W. Madison Stn*t,Safo 900

(312)3454990(312) 3454979 (Fat)\vww tecUawinc com




Sample ID

X19-FD-6-12

X24-B-0-1

X24-B-1-6

X24-B-6-12

X24-DZ

X24-F-0-1

X24-F-1-6

X24-F-6-12

X26-B-0-1

X26-B-1-6

X26-B-6-12

X26-DZ

X26-F-0-1

X26-F-1-6

X26-FD-1-6

X26-F-6-12

X46-B-0-1

X46-B-1-6

X46-B-6-12

X46-DZ

X46-F-0-1

X46-F-1-6

X46-FD-1-6

X46-F-6-12

X48-B-0-1

X48-B-1-6

X48-B-6-12

X48-DZ

X48-F-0-1

*Z± ~^^>^=^ ' &

Laboratory ID

E604004-31

E604004-32

E604004-33

E604004-34

E604004-35

E604004-36

E604004-37

E604004-38

E604004-39

E604004-40

E604004-41

E604004-42

E604004-43

E604004-44

E604004-45

E604004-46

E604004-47

E604004-48

E604004-49

E604004-50

E604004-51

E604004-52

E604004-53

E604004-54

E604004-55

E604004-56

E604004-57

E604004-58

E604004-59

000036

Matrix

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Report Name:

Date Sampled

Apr-26-06 16:15

Apr-27-06 16:00

Apr-27-06 16:05

Apr-27-06 16:10

Apr-27-06 15:55

Apr-27-06 15:25

Apr-27-06 15:45

Apr-27-06 15:50

Apr-27-06 16:45

Apr-27-06 16:50

Apr-27-06 17:00

Apr-27-06 16:40

Apr-27-06 16:25

Apr-27-06 16:30

Apr-27-06 16:30

Apr-27-06 16:35

Apr-27-06 14:45

Apr-27-06 14:50

Apr-27-06 14:55

Apr-27-06 14:05

Apr-27-06 14:10

Apr-27-06 14: 15

Apr-27-06 14:20

Apr-27-06 14:25

Apr-27-06 11:00

Apr-27-06 11:05

Apr-27-06 11:10

Apr-27-06 11:15

Apr-27-06 11:30

Date Received j

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

E605001,E604004 FINAL May 25 06 1443StepherfConnet, Chemist Page 2 of74

TediLaw 105 W. Madison SttHt, Sri* 900

012)3454990(312) 3454979 (Fn)wwitmiawmcrcm



Sample ID

X48-F-1-6

X48-F-6-12

X50-B-0-1

X50-B-1-6

X50-B-6-12

X50-DZ

X50-F-0-I

X50-F-1-6

X50-F-6-12

X10-B-0-1

X10-B-1-6

X10-B-6-12

X10-DZ

X10-F-0-1

X10-F-1-6

X10-FD-1-6

X10-F-6-12

X13-B-0-1

X13-B-1-6

X13-B-6-12

X13-DZ

X13-F-0-1

X13-F-1-6

X13-F-6-I2

X35-B-0-1

X35-B-1-6

X35-B-6-12

X35-DZ

^«~

Laboratory ID

E604004-60

E604004-61

E604004-62

E604004-63

E604004-64

E604004-65

E604004-66

E604004-67

E604004-68

E605001-04

E605001-05

E605001-06

E605001-07

E605001-08

E605001-09

E605001-10

E605001-11

E605001-12

E605001-13

E605001-14

E605001-15

E605001-16

E605001-17

E605001-18

E605001-19

E605001-20

E605001-21

E605001-22

000037

Matrix

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Report Name:

Date Sampled

Apr-27-06 11:35

Apr-27-06 11:40

Apr-27-06 09:40

Apr-27-06 09:45

Apr-27-06 09:50

Apr-27-06 09:30

Apr-27-06 09:05

Apr-27-06 09: 10

Apr-27-06 09: 15

May-01 -06 11:00

May-0 1-06 11:20

May-01-06 11:25

May-01-06 10:50

May-01-06 10:35

May-01-06 10:40

May-01-06 10:45

May-01-06 10:47

May-0 1-06 09:20

May-0 1-06 09:25

May-0 1-06 09:45

May-0 1-06 09: 15

MayX)l-06 09:00

May-01-06 09:05

May-0 1-06 09: 10

May-01-06 16:25

May-01-06 16:30

May-01-06 16:35

May-01-06 16:20

Date Received

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

Apr-28-06 12:08

May-02-06 11. 21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11 :21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11. -21

May-02-06 11:21

E605001,E604004 FINAL May 25 06 1443Stephen Oermet, Chemist Page 3 of74

khlaw i05 W.^Mson Stmt, Saite 900Chicafo,IL 60602

Hi f l i t t t g t t l r(3 12) 345^979 (Fu)



Sample ID

X35-F-0-1

X35-F-1-6

X35-F-6-12

X42-B-0-1

X42-B-1-6

X42-B-6-12

X42-DZ

X42-F-0-1

X42-F-1-6

X42-F-6-12

X49-B-0-1

X49-B-1-6

X49-B-6-12

X49-DZ

X49-F-0-I

X49-F-1-6

X49-F-6-12

X49-FD-6-12

Laboratory ID

E60500I-23

E605001-24

E605001-25

E605001-26

E605001-27

E605001-28

E60500I-29

E605001-30

E605001-31

E605001-32

E605001-33

E605001-34

E605001-35

E605001-36

E605001-37

E605001-38

E605001-39

E60500I-40

Matrix

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Date Sampled

May-01-06 16:00

May-01-06 16:05

May-01-06 16:10

May-01-06 15:05

May-01-06 15:10

May-01-06 15:15

May-01-06 15:00

May-01-06 15:20

May-01-06 15:25

May-01-06 15:30

May-01-06 12:15

May-01-06 12:20

May-01-06 12:25

May-01-06 12: 10

May-01-06 11:45

May-01-06 11:50

May-01-06 11:55

May-01-06 12:00

Date Received

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:2 1

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

May-02-06 11:21

StepheirConnet, Chemist


Page 4 of74

khlaw i05W.&{aduoBStmt, Said 900Oneafo.IL 60(02

(312)3454990(312) 3454979 (F«)

fop h ijnvtttf . MMB




Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX03-B-0-1 (E604004-03) Soil Sampled: Apr-26-06,12:35 Received: Apr-28-06 12:08

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X03-B-1-6 (£604004-04) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

5400

5201.07.3

16000

354.9180

24000

2300

6100

540247601.325021

1400

Sampled: Apr-26-06

Result

6200

6701.86.4

13000

295.8170

29000

1400

4600

470


110.20.20.4

18* 0.5

1.0* 1.3

233.813

0.09

* 0.9

211 0.8

262.3

K, * 5.3

Limit Units

94 mg/kg

0.90.91.9941.93.83.8949.4380.53.8941.9949.419


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " ' EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.711 " ' EPA 200.7

EPA 200.711 EPA 200.7

" EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

12:40 Received: Apr-28-06 12:08


120.20.20.419

* 0.5

1.1* 1.4

244.014

0.1

Limit Units

100 mg/kg

1.01.02.01002.04.04.01001040

0.5


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

" " " EPA 200.7

" " " EPA 200.7

7,

StepherrConnet, Chemist

000039Report Name: E605001 .E604004 FINAL May 25 06 ] 443

Page 5 of74

JechLaw 105 W.Nia&onStntt, Sate 900

(312)3454990(312) 345-S979 (Fat)wmv t»r Uawintccm





Reported:

May-25-06 14:43

Metals by ICP


Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X03-B-6-12 (£604004-05) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

27890

U370

21

1400

Sampled: Apr-26-06

Result

4800

350

1.2

3.3

11000

17

4.9

110

18000

710

4700

350

31

630

1.1

280

15

920


* 1.0

22

J 0.8

28

2.4

K,» 5.6

12:45 Received:


12

0.2

0.2

0.4

19

* 0.5

1.1

* 1.4

24

3.9

14

0.1

* 1.0

22

J 0.8

28

2.4

K,* 5.S

Limit Units

4.0 mg/kg

100

2.0

100

10

20

Apr-28-06 12:08

Limit Units

98 mg/kg

1.0

1.0

2.0

98

2.0

3.9

3.9

98

9.8

39

0.5

3.9

98

2.0

98

9.8

20


1 EE60204 May-04-06May-08-06,. . n

"

,.

,.

n ii . n


1 EE60204 May-04-06May-08-06» H n n

11 n H F

n n it n

„„H n n m

n

-„n N n n

.

.„„„..

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stephen dorfnet, Chemist


Page 6 of 74

TechLaw 105W.Midi«m$»«,&riti900

(312)3454990(312)3454979 (Fax)www tfctMsivinc com




Reported:

May-25-06 14:43


X03-DZ (E604004-06) Soil Sampled: Apr-26-06 1?:30 Received: Apr-28-06 12:08

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X03-F-0-1 (E604004-07) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

7400

3401.14.5

28000

27S.393

20000

1000

12000

610237001.637018

1200

Sampled: Apr-26-06

Result

5700

2200.93.5

57000

324.193

18000

68011000

590


120.20.20.4

19* . 0.5

1.1* 1.4

244.014

0.1» 1.0

22

J 0.8

282.4

K, * 5.6

Limit Units

100 mg/kg

1.01.02.01002.04.04.010010400.54.01002.0100

1020


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 " " " EPA 200.7

EPA 200.7

EPA 200.711 " " " EPA 200.711 " ' " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.711 EPA 200.7

EPA 200.7

EPA 200.7

12:20 Received: Apr-28-06 12:08


120.2

J 0.2

0.419

* 0.5

1.1* 1.4

244.014

0.1

Limit Units

100 mg/kg

1.01.02.01002.04.04.01001040

0.5


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

" EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

Stephen Cermet, Chemist


Page 7 of74

MawQ u a l i t y

105 W. Madison SttMt, Sate 900Chkafo,IL 60602

(312)3454990(312) 3454979 (Fa)


Chicago IL, 60604



Reported:

May-25-06 14:43


X03-F-0-1 (£604004-07) Soil Sampled: Apr-26-06,12:20 Received: Apr-28-06 12:08

Analytc

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X03-F-1-6 (£604004-08) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

46

880

1.2

320

17

790

Sampled: Apr-26-06

Result

6000

200

1.0

3.8

31000

42

4.1

86

23000

780

10000

940

26

900

1.6

320

20

900


* 1.0

22

J 0.8

28

2.4

K,* 5.6

Limit Units

4.0 mg/kg

100

2.0

100

10

20


1 EE60204 May-04-06May-08-06n ti n n

n n n n

*.n H H n

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

12:25 Received: Apr-28-06 12:08


12

0.2

0.2

0.4

19

* 0.5

1.1

* 1.4

24

3.914

0.1

« 1.0

22

J 0.8

28

2.4

K, * 5.5

Limit Units

99 mg/kg

1.0

1.0

2.0

99

2.0

3.9

3.9

99

9.9

39

0.5

3.9

99

2.0

99

9.9

20


1 EE60204 May-04-06May-08-06H II II H

» n ft n

M M M I I

it M n it

n H n n

„„m tt n m

„II II H It

n it ft n

it n » m

n

„

.,

m n H it

„

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 8 of74

MawQ u a l i t y <>

(312)3454990(312) 3454*79 (Fat)




May-25-06 14:43

X03-F-6-12 (E604004-09) Soil

Metals by ICP


Analyte


X07-B-0-1 (E604004-10) Soil

Analyte

AluminumBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesium

Manganese


2500

110

0.4 J

1.9 J

24000

15 *

2.4 J

39 *

11000

350

11000

430

23 *

400

0.9 J

130

10

590 K, *

MDL

12

0.2

0.2

0.4

18

0.5

1.1

1.3

23

3.9

13

0.1

1.0

21

0.8

27

2.3

5.4

Limit Units

96 mg/kg

1.0

1.0

1.9

96

1.9

3.9

3.9

96

9.639

O.S

3.9

96

1.9

96

9.6

19


I EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

" " " EPA 200.7

EPA 200.7

" " " " EPA 200.7

" " " EPA 200.7

EPA 200.711 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7



5200

220

0.6 J

5.5

17000

32 *

4.9

120 *

24000

1200

6100

620

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60204 May-04-06May-08-06 EPA 200.711 " " " EPA 200.7

" " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7



Page 9 of74

ledilaw 105 W.MadUottSttHt, So* 900

Q a a l i t ?

(312)5454990(312)J45-8979(Fa)

Super-fund, US EPA Region 5



Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX07-B-0-1 (E604004-10) Soil Sampled: Apr-26-Q6 09:50 Received: Apr-28-06 12:08

Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X07-B-1-6 (£604004-11) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc


21 *

720

0.9 J

150

19

1100 K, *

MDL

1.0

22

0.8

28

2.4

5.7

Limit Units

4.0 mg/kg

100

2.0

100

10

20


1 EE60204 May-04-06May-08-06it n n n

n H N n

N n ti n

.n it • n

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



5300

310

1.0

7.5

15000

29 •

5.5

180 *

20000

1800

5600

530

43 *

580

1.5 J

150

19

2900 K,*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

23

3.9

14

0.1

1.0

21

0.8

27

2.3

5.5

Limit Units

98 mg/kg

1.0

1.0

2.0

98

2.0

3.9

3.9

98

9.8

39

0.5

3.9

98

2.0

98

9.8

20


I EE60204 May-04-06May-08-06"

"

"„

II M II It

.

.,

n n w H

n rt H H

n n H n

II II M II

n n n H

n n n n

.M M m n

It M II H

M II H N

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stephen Sonnet, Chemist


Page 10 of74

Maw 105W.Madis«S<n«,$ufc900Orxato,IL 60602

(312)3454990

Q u a l i t y


Chicago IL, 60604



Reported:

May-25-06 14:43

X07-B-6-12 (£604004-12) Soil



Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X07-DZ (£604004-13) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

3700

2100.64.2

12000

20

4.3110

16000

2700

4800

34027

4901.7

16011

1300

Sampled: Apr-26-06

Result

6900

240

0.89.3

15000

485.9180

32000

1800

4600

930


120.2

J 0.2

0.4

19* . 0.5

1.1* 1.4

244.1140.1

* 1.0

22J 0.8

292.4

K,* 5.7

Limit Units

100 mg/kg

1.01.02.01002.04.14.110010410.54.11002.01001020

Dilution Batch

1 EE60204„„H H

H n

n it

„„

-„

n

„n M

„„P n

»

" "


May-04-06May-08-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

10:00 Received: Apr-28-06 12:08


120.2

J 0.2

0.419

* 0.5

l.l* 1.4

244.014

0.1

Limit Units

100 mg/kg

1.01.02.01002.04.04.01001040

0.5

Dilution Batch

1 EE60204.

N II

„

„

.

„

„

P N

„

n ii

W N


May-04-06May-08-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

000045


Page 11 of 74

TediLawQxaiil?

105 W. Madison Sttwt, Sort* 900Chicifo,! 60602

(312)3454990(312) 3454979 (F«)




Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX07-DZ (E604004-13) Soil Sampled: Apr-26-06 10:00 Received: Apr-28-06 12:08

Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X07-F-0-1 (E604004-14) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lend

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

48

660

1.2

130

25

1400

Sampled: Apr-26-06

Result

7300

130

0.6

4.2

11000

40

5.4

110

20000

1200

4700

670

20

1100

1.2

120

23

940


* 1.0

22

J 0.8

28

2.4

1C,* 5.6

Limit Units

4.0 mg/kg

100

2.0

100

10

20


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.711 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

10:15 Received: Apr-28-06 12:08


120.2

J 0.2

0.4

19

* 0.5

1.1

* 1.4

24

4.014

0.1

* 1.0

22

J 0.8

28

2.4

K, * 5.6

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

" " " " EPA 200.7

" EPA 200.7

" " " EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" ' " EPA 200.7

EPA 200.7

EPA 200.7

Stephen Cfonnet, Chemist


Page 12 of74

MawQtalit}

)05W.Ma&aaStmt,SQitaftOQuca|D,lL6M02

(312)545^990(312) 3454979 (Fa)





Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX07-F-1-6 (£604004-15) Soil Sampled: Apr-26-06,10:40 Received: Apr-28-06 12:08

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X07-F-6-12 (£604004-16) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

7400

120

0.5

4.0

8900

37

5.4

100

19000

980

4000

530

23

1000

1.2

110

20

850

Sampled: Apr-26-06

Result

6000

100

0.5

3.2

17000

23

4.7

62

15000

440

8700

410


12

0.2

j 0.2

0.4

19

* 0.5

1.1

* 1.4

24

4.0

14

O.I

* 1.0

22

J 0.8

28

2.4

K,* 5.6

10:45 Received:


12

0.2

J 0.2

0.4

19

* 0.5

1.1

* 1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20

Apr-28-06 12:08

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60204 May-04-06May-08-06„

M

M „

II II n n

ft

„

» H II II

M U M M

H N M H

.1

" "

II I.

I. „

II II It II

tl II V II

n ii n n

M ii n it


1 EE60204 May-04-06May-08-06n i, „

n - „

M

n ii M ii

.n n n n

.

.n ti n H

n n n n

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stephen C6hnet, Chemist


Page 13 of 74

TediLawQ x a l i t i i{ l a t t f n i r

105W.MaduaaStw*,$mti900

(312)3454990(312) 3454979 (Fa)mnv terlilawinc com




Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX07-F-6-12 (E604004-16) Soil Sampled: Apr-26-0£ 10:45 Received: Apr-28-06 12:08

Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X15-B-0-1 (E604004-17) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

27

790

1.0

150

17

570

Sampled: Apr-26-06

Result

5600

140

0.7

2.8

13000

51

4J

65

23000

700

3300

1000

17

740

1.1

91

30

790

Flags/Qualifiers

*

J

K,*

MDL

1.0

22

0.8

28

2.4

5.6

Limit Units

4.0 mg/kg

100

2.0

100

10

20


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

15:25 Received: Apr-28-06 12:08

Flags/Qualifiers

J

*

4

*

JJ

K, *

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.8

28

2.4

5.6

Limit Units

99 mg/kg

1.0

1.0

2.0

99

2.0

4.0

4.0

99

9.9

40

0.5

4.0

99

2.0

99

9.9

20


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

StephenConnet, Chemist


Page 14 of74

MawQ x t l i t ?

105 W. Madison Sat*, Sate 900Chicago, E. 60602

(312)3454990(312) 3454979 (Fa)




Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX15-B-1-6 (£604004-18) Soil Sampled: Apr-26-06,15:45 Received: Apr-28-06 12:08

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X15-B-6-12 (£604004-19) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

6900

170

0.8

2.9

10000

40

4.4

71

19000

780

2400

610

22

730

1.3

140

25

750

Sampled: Apr-26-06

Result

6200

230

1.2

3J

11000

27

4.5

73

22000

990

2700

360


12

0.2

J 0.2

0.4

19

« . 0.5

1.1

« 1.4

24

4.0

14

0.1

* 1.0

22

J 0.8

28

2.4

K. * 5.6

15:35 Received:


12

0.2

0.2

0.4

19

* 0.5

1.1

» 1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20

Apr-28-06 12:08

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60204 May-04-06May-08-06n n N n

n tt n n

tt a it it

„„n II ii n

M

H n n ii

M N ft II

tt tl It It

n tt ti tt

rt H n tt

M M 1 1 I t

ii ii n M

„„II H w II


1 EE60204 May-04-06May-08-06n N H H

„

N n n H

„„n n n M

.

.

.

.

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 15 of 74

TediLaw 105 W.MadiwmSttHt, Sate 900

l u t c f t t t y

012)3454990(312) 3454979 (Fn)wwai t»f Matfiw MHB




Reported:

May-25-06 14:43


X1S-B-6-12 (£604004-19) Soil Sampled: Apr-26-06 15:35 Received: Apr-28-06 12:08

Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X15-DZ (£604004-20) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

31

780

7.9

250

22

970

Sampled: Apr-26-06

Result

6300

95

0.6

2.4

9900

28

3J

75

16000

630

2900

430

21

490U

74

20

520


* 1.0

22

0.8

28

2.4

*,K 5.6

Limit Units

4.0 mg/kg

100

2.0

100

10

20


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200. 7

EPA 200.7

EPA 200.7

15:20 Received: Apr-28-06 12:08


12

0.2

J 0.2

0.4

19

* 0.5

J 1.1

* 1.4

24

4.0

14

0.1

* 1.0

22

0.8J 28

2.4

K, * 5.6

Limit Units

99 mg/kg

1.0

1.0

2.0

99

2.0

4.0

4.0

99

9.9

40

0.5

4.099

2.099

9.9

20


1 EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

" EPA 200.7

" " " " EPA 200.7

EPA 200.7

" " " EPA 200.711 " " " EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.711 " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 16 of 74

Maw 105 W.Midiwn Strut, Sofc900Oacafo, H6WQ2

(312)3454990(312) 3454979 (Fa)




Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX15-F-0-1 (E604004-21) Soil Sampled: Apr-26-06,14:40 Received: Apr-28-06 12:08

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X1S-F-1-6 (E604004-22) Soil

AnalyteAluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

Result

4100

701.21.7

25000

21

2.7

64

13000

460

13000

450

11

480U

96

15

340

Sampled: Apr-26-06

Result

3900

67

0.4

1.9

24000

19

2.4

64

11000

510

13000

370


12

0.2

0.2

J 0.4

19

* 0.5

J 1.1

* 1.4

24

4.0

14

0.1

« 1.0

22

0.8

J 28

2.4

K, * 5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0100

10

20


I EE60204 May-04-06May-08-06 EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

" " " EPA 200. 7

EPA 200.7

" " " " EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.711 " " EPA 200.7

" " » EPA 200.7

EPA 200.7

" EPA 200.711 " " EPA 200.7

14:45 Received: Apr-28-06 12:08


12

0.2

J 0.2

J 0.4

19

* 0.5

J 1.1

* 1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60204 May-04-06May-08-06 EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

StepheifConnet, Chemist


Page 17 of74

Tedilaw iOSW.KiadiumSttMt, Sato 9000x110,1160602

(312)545^990(312) 3454*79 (Fa)



Reported:

May-25-06 14:43

Metals by ICP


Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X15-F-6-12 (£604004-23) Soil

AnaJyle

Aluminum

BariumBeryllium

Cadmium

Calcium

Chromium

CobaltCopper

IronLead

Magnesium

Manganese

NickelPotassium

SilverSodium

Vanadium

Zinc

Result

13360U

11012

420

Sampled: Apr-26-06

Result

2500

400.21.3

22000

9.62.136

8000240

13000

20011

280U

71

8.0220

Flags/Qualifiers

*

K,*

MDL1.0220.8282.45.7

14:50 Received:

Flags/Qualifiers

*

*,JJ

J

**

*

LJJ

MDL120.20.20.4190.51.11.4244.1140.11.0220.8282.45.7

Limit Units

4.0 mg/kg1002.01001020

Apr-28-06 12:08

Limit Units100 mg/kg1.01.02.01002.04.14.110010410.54.11002.01001020


1 EE60204 May-04-06May-08-06 EPA 200.711 " " " EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7


1 EE60205 May-04-06May-17-06 EPA 200.7

EPA 200.7EPA 200.7

" " " ' EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

" EPA 200.7

EPA 200.7" " " " EPA 200.7

" EPA 200.7

EPA 200.7

" " " " EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

Stephen Cornlet, Chemist


Page 18 of74

Techlaw 105 W.Midisaa Start, Sate 900Oucafo,IL 60602

012)345-8990(312)3454979 (F«)tvtvtv tteMawtnf con

Supertund, US EPA Region 577 West Jackson BoulevardChicago IL, 60604



Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX19-B-0-1 (£604004-24) Soil Sampled: Apr-26-06.16:50 Received: Apr-28-06 12:08

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X19-B-1-6 (E604004-2S) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

4400

1100.53.9

13000

32

3.0

75

16000

810

4300

430

16

510U

91

18

910

Sampled: Apr-26-06

Result

5100

130

0.6

5.2

12000

37

3.8

97

19000

1000

4000

460


12

* 0.2

J, * 0.2

0.4

19

0.5

J 1.1

1.4

24

* 4.0

* 14

0.1

* 1.0

22

L 0.8

J 28

2.4

5.6

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0100

10

20

Dilution Batch

1 EE60205,,

«m m

,.„

•.,„n n

N n

n n

ti n

M «

« n

n n

M n


May-04-06 May- 17-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

16:55 Received: Apr-28-06 12:08


12

• 0.2

*, J 0.2

0.4

19

0.5

J 1.1

1.4

24

* 4.0

* 14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

Dilution Batch

1 EE60205ii

„

•

M M

.

"

.

.

.

M 11

"


May-04-06May-17-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 19 of74

MawQ u a l i t y o

105 W. Madison SbMt, Safe 900Qncafo,IL 60602

(312)3454990(312) 345-8979 (F«»





Metals by ICP


Anaiyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X19-B-6-12 (£604004-26) Soil

AnaiyteAluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

24S301.713021

1200

Sampled: Apr-26-06

Result

3400

110

0.6

3.6

13000

16

3.9

55

23000

800

5300

370

15

400

1.8

140

13

1000


* 1.0

22

J, L 0.8

28

2.4

5.6

17:00 Received:


12

* 0.2

J, • 0.2

0.4

19

0.5

J 1.1

1.4

24

* 4.0

* 14

0.1

» 1.0

22

J, L 0.8

28

2.4

5.6

Limit Units

4.0 mg/kg

100

2.0

100

10

20

Apr-28-06 12:08

Limit Units

100 mg/kg1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20


1 EE6020S May-04-06May-17-06 EPA 200.7« tt n

II 11 it

„

• M H

H H n


EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Analyzed Method

1 EE60205 May-04-06 May- 17-06 EPA 200.7H n *

H It II

"

„

„

„

n

n II It

I.

.,

.

.,

H It W

.

n

n

n H H

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stephen Qbrfhet, Chemist


Page 20 of 74

>T< Techlaw 105 WMiduonSttHt, Sort 900

(312)3454990(312) 3454979 (Fa)



Chicago IL, 60604




Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX19-DZ (E604004-27) Soil Sampled: Apr-26-06 16:15 Received: Apr-28-06 12:08

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X19-F-0-1 (E604004-28) Soil

Aiialyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

6900

120

0.8

6.1

10000

49

5.1

ISO

25000

1500

3500

800

33

540

1.0

110

30

1300

Sampled: Apr-26-06

Result

6100

140

0.7

4.3

15000

63

4.0

120

21000

1000

4900

640


12

* 0.2

J, * 0.2

0.4

19

0.5

1.1

1.4

24

» 4.1

* 14

0.1

* 1.0

22

}, L 0.8

28

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5

4.1

100

2.0

100

10

20


1 EE60205 May-04-06 May- 17-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

" EPA 200.7

EPA 200.7

" " " " EPA 200.7

16:00 Received: Apr-28-06 12:08


12

* 0.2

J, * 0.2

0.4

19

0.5

1.1

1.4

24

* 4.0

* 14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


I EE60205 May-04-06 May- 17-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

000055


Page 21 of 74

Maw 105 W Madiwn Stmt, Sate 9000x010,160602

(312)3454990(312) 3454979 (Fa)wttftu

Superfund, US EPA Region 577 West Jackson BoulevardChicago \L, 60604



Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX19-F-0-1 (E604004-28) Soil Sampled: Apr-26-0616:00 Received: Apr-28-06 12:08

Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X19-F-1-6 (E604004-29) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

NickelPotassium

Silver

Sodium

Vanadium

Zinc

Result

23

640V

130

33

1100

Sampled: Apr-26-06

Result

5700

150

0.7

4.6

14000

55

4.3

110

22000

1100

4800

490

24

550

1.5

160

22

1100


* 1.0

22

L 0.8

28

2.4

5.6

Limit Units

4.0 mg/kg

100

2.0100

10

20


1 EE60205 May-04-06May-17-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

16:05 Received: Apr-28-06 12:08


12* 0.2

*, J 0.2

0.4

19

0.5

1.1

1.4

24

* 4.0

* 14

0.1

» 1.0

22

J, L 0.8

28

2.4

5.6

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20


1 EE60205 May-04-06 May- 17-06 EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.711 EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

Stephen Congetf Chemist


Page 22 of 74

MLawQ u a l i t y

105 W. Madison Stmt, Suih 900Oixafo,]L 60602

(312)3454990(312) 345̂ 979 (Fax)vrvmt t*fMauinc com




May-25-06 14:43

X19-F-6-12 (E604004-30) Soil


Sampled: Apr-26,06 16:10 Received: Apr-28-06 12:08

AnalyteAluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

VanadiumZinc

X19-FD-6-12 (£604004-31) Soil

Analyte

Aluminum

Barium

BerylliumCadmium

Calcium

ChromiumCobalt

Copper

Iron

Lead

Magnesium

Manganese


3000

110 *

0.5 J, *

2.415000

163.3 J, K

5219000

750 *

6100 *

32013 *

330 K

1.2 J,L

140

11

880

Sampled: Apr-26-06 16:15


3000

100 *

0.5 J, *

2.615000

143.1 J, K

5018000

610 *

6400 *

300

MDL120.20.20.4190.51.11.4244.1

140.1

1.0220.8282.45.7

Received:

MDL

120.20.20.419

0.51.11.4243.914

0.1

Limit Units

100 mg/kg1.01.02.01002.04.14.11001041

0.54.11002.01001020

Apr-28-06 12:08

Limit Units

98 mg/kg1.01.02.0

982.03.93.9989.839

0.5


1 EE60205 May-04-06 May- 17-06n K n w

.

.

.,„„

»

•"n .. .. . . .„, , „ , , „„ „

„„

" " "


1 EE60205 May-04-06 May- 17-06it K n n

H U N K

« H II ft

* n n H

«

ti n p H

,.n H n N

it n n n

H H N H

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

000057

StephelfConnet, ChemistReport Name: E605001.E604004 FINAL May 25 06 1443

Page 23 of 74

TediUw (312)3454990(312) 3454979 (F«)wwn t*fMawinc .com




Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX19-FD-6-12 (E604004-31) Soil Sampled: Apr-26-06 16:15 Received: Apr-28-06 12:08

Analyte

Nickel

PotassiumSilver

Sodium

Vanadium

Zinc

X24-B-0-1 (£604004.32) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

IronLead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

13

350

1.5

140

11

830

Sampled: Apr-27-06

Result

4700

140

0.6

5.2

29000

32

3.4

91

180001000

14000

580

16

410U

180

20

1100

Flags/Qualifiers

*

K

J, L

MDL

1.0

22

0.8

28

2.4

5.5

Limit Units

3.9 mg/kg

98

2.0

98

9.8

20


1 EE60205 May-04-06 May- 17-06n ..

n

H m m M

„ M

II If • If

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

16:00 Received: Apr-28-06 12:08

Flags/Qualifiers

*

J,*

J.K

**

4

K

L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

3.9

14

0.1

1.0

22

0.828

2.4

5.5

Limit Units

98 mg/kg

1.0

1.0

2.0

98

2.0

3.9

3.9

989.8

39

0.5

3.9

98

2.098

9.8

20


1 EE60205 May-04-06 May- 17-06„

H N H n

,,H N n n

-, .II H W tl

n

"

n n n H

H n H n

n « w n

n H n |t

1. ..n n H n

." « It M

,,

Method |

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stephen C<iHhet, Chemist


Page 24 of 74

TediLaw !05W. Madison Sttut, Sri* 900Oricafo,IL 60602

(312)3454990

Q u a l i t y www tfcdjlatttnc.com




Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX24-B-1-6 (£604004-33) Soil Sampled: Apr-27-06,16:05 Received: Apr-28-06 12:08

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X24-B-6-12 (E604004-34) Soil

Analyte

Aluminum

Barium

BerylliumCadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

3200

100

0.5

3.2

27000

14

3.2

45

15000

430

13000

340

11

320U

130

13

720

Sampled: Apr-27-06

Result

1600

25U

0.8

31000

5.6

1.8

7.9

5200

54

18000

170


12

* 0.2

*, J 0.2

0.4

19

0.5

J,K LI1.4

24

* 4.0

* 14

0.1

• 1.0

K 22

L 0.8

28

2.4

5.5

16:10 Received:


12

* 0.2

* 0.2

J 0.4

19

0.5

J,K 1.11.4

24

* 4.1

* 14

0.1

Limit Units

99 mgdcg

1.0

1.0

2.0

99

2.0

4.0

4.099

9.9

40

0.5

4.0

99

2.099

9.9

20

Apr-28-06 12:08

Limit Units

100 nig/kg

1.0

1.02.0

100

2.0

4.1

4.1

100

10

41

0.5


1 EE60205 May-04-06 May- 17-06 EPA 200. 7H It n

„

„

It II H

„

„

n

n n «

.„n « n

.

„

„.

„1 1 " •


EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Analyzed Method

1 EE60205 May-04-06May-17-06 EPA 200.7.

.»

.

.

II II H

H It tt

m m n

„U N n

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

000059

Stephen Connfe£ ChemistReport Name: E605001 ,£604004 FINAL May 25 06 1443

Page 25 of 74

Maw lOSW.MadiuaStmt, Sate 900Onca|o,IL 60602

012)3454990(312) 3454979 (Fn)



Reported:

May-25-06 14:43


X24-B-6-12 (£604004-34) Soil Sampled: Apr-27-Of 16:10 Received: Apr-28-06 12:08

Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X24-DZ (E604004-35) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

7.5

250U

100

7.5

130

Sampled: Apr-27-06

Result

7400

160

1.1

7.3

21000

37

53

130

23000

1300

9600

750

24

540

1.5

490

28

1600

Flags/Qualifiers

*

K

L

J

MDL

1.0

22

0.828

2.4

5.7

Limit Units

4.1 mg/kg

100

2.0100

10

20


1 EE60205 May-04-06May-17-06 EPA 200.7

" " " " EPA 200.7

- - " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

15:55 Received: Apr-28-06 12:08

Flags/Qualifiers

*

*

K

*

*

*

K

J,L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.014

0.1

1.0

22

0.8

28

2.4

5.6

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20


1 EE60205 May-04-06May-17-06 EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200,7

EPA 200.7

EPA 200.7

EPA 200.7

Stephentonnet, Chemist


Page 26 of 74

TediLaw 105 W.MidisonStwt, Sato 900

l i t t r f t t r

(312)3454990(312) 3454979 (Fa)




Reported:

May-25-06 14:43

Metals by ICP


Analyte

Aluminum

BariumBeryllium

Cadmium

Calcium

Chromium

CobaltCopper

Iron


NickelPotassium


Zinc

X24-F-1-6 (E604004-37) Soil

AnalyteAluminum

BariumBeryllium

CadmiumCalcium

ChromiumCobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

3700

82

0.4

3.1

21000

17

2.5

61

13000

620

10000

400

11

380U

95

15

750

Sampled: Apr-27-06

Result

3400

88

0.5

3.2

24000

18

3.3

55

12000

560

12000

370

Flags/1

Qualifiers MDL

12

* 0.2

*, J 0.2

0.4

19

0.5

J,K 1.1

1.4

24

* 4.1

* 14

0.1

* 1.0

K 22

L 0.8

J 28

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

JOO

2.0

4.1

4.1

100

10

414

0.5

4.1

100

2.0100

10

20


1 EE60205 May-04-06May-17-06

-,.

» « « i.

tt n n H

.

II II K »

"

W tt II M

„

tt N n n

n n H m

,,

.

H n n m

n n H M

it n tt n

M fl M H

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

15:45 Received: Apr-28-06 12:08


12

» 0.2

J, * 0.2

0.4

19

0.5

J,K 1.1

1.4

23

* 3.9

* 14

O.I

Limit Units

98 mg/kg

1.0

1.0

2.0

98

2.0

3.9

3.9

98

9.839

0.5


1 EE60205 May-04-06May-17-06H H n N

,.tl H It II

n H H H

. . . .

11 M M II

.

,

n n m n

M n II n

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

000061


Page 27 of 74

SB MawQaal i l i

Qacafo,IL£Oti02012)54M990

(312) 3454979 (F«)




Reported:

May-25-06 14:43


X24-F-1-6 (£604004-37) Soil Sampled: Apr-27-06,15:45 Received: Apr-28-06 12:08

Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X24-F-6-12 (E604004-38) Soil

Analyte

Aluminum

Barium

BerylliumCadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

12320U

110

13

850

Sampled: Apr-27-06

Result

1900

35U

0.9

22000

6.4

2.0

16

8300

140

12000

180

7.S

240U

79

9.4

230

Flags/Qualifiers

*

K.

L

MDL

1.0

21

0.827

2.3

5.5

15:50 Received:

Flags/Qualifiers

*

*

)

J,K

*

*

*

K

LJ

J

MDL

12

0.2

0.20.4

19

0.5

1.1

1.4

24

4.0

14

O.I

1.0

22

0.828

2.4

5.5

Limit Units

3.9 mg/kg

98

2.098

9.8

20

Apr-28-06 12:08

Limit Units

99 mg/kg

1.0

1.02.099

2.0

4.0

4.0

99

9.9

40

0.5

4.0

99

2.099

9.9

20


/ EE60205 May-04-06 May- 17-06 EPA 200. 7n

ii n n

.„ii n n


EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Analyzed Method

1 EE60205 May-04-06May-17-06 EPA 200.7

"„H n n

„„.„n

.

,,

"

„

*

.

,.

„

„

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 28 of 74

khUwQ*al i t r

105 W.MwfaoaSttttt, Sate 900Cbkafo,IL 60002

(312)545-8990(312) 3454979 (Fax)wnmr w hkrai'tv torn



Reported:

May-25-06 14:43



Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X26-B-1-6 (£604004-40) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

4600

130

0.7

2.8

26000

29

3.3

95

14000

630

12000

520

15

540V

210

19

700

Sampled: Apr-27-06

Result

4900

200

0.8

3.7

23000

80

3.7

83

16000

1400

11000

400


12

* 0.2

J, * 0.2

0.4

18

0.5

J,K 1.1

1.4

23

» 3.9

• 14

0.1

« 1.0

K 21

L 0.8

27

2.3

5.4

Limit Units

97 mg/kg

1.0

1.0

1.9

97

1.9

3.9

3.9

97

9.7

39

0.5

3.9

97

1.997

9.7

19

Dilution Batch

1 EE60205n

It X

n

,,

H 1*

N tt

II

"

I.

„

K ft

.

,,

I,

n

n

H n


May-04-06 May- 17-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

16:50 Received: Apr-28-06 12:08


12

* 0.2

*, J 0.2

0.4

19

0.5

K.J 1.11.4

24

* 4.0

* 14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

Dilution Batch

1 EE60205II n

*

* n

.,,.n rt

..tt H

«t tt

„


May-04-06 May- 1 7-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

000063

Stephen-Cermet, ChemistReport Name: E605001 .E604004 FINAL May 25 06 1443

Page 29 of 74

TechlawQ u a l i t y

105 W.MadiunStiNt, Sate 900Chicafo,IL 60602

(312)3454990(312) 3454979 (F«)wttftg




Reported:

May-25-06 14:43


X26-B-1-6 (E604004-40) Soil Sampled: Apr-27-06,16:50 Received: Apr-28-06 12:08

Ajialyle

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X26-B-6-12 (E604004-41) Soil

AnalyteAluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

18

570U

160

19

920

Sampled: Apr-27-06

Result

2400

63

0.3

1.324000

12

2.7

22

6900

640

13000

180

17

320U

94

10

370

Flags/Qualifiers

*

KL

MDL

1.0

22

0.828

2.4

5.7

17:00 Received:

Flags/Qualifiers

*

J, *

}

J.K

*

*

*

K

LJ

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.828

2.4

5.7

Limit Units

4.0 mg/kg

100

2.0100

10

20

Apr-28-06 12:08

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0100

10

20


1 EE60205 May-04-06May-17-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7


1 EE60205 May-04-06May-17-06 EPA 200.7

EPA 200.7

" " " • EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stephen "Cbrinet, Chemist


Page 30 of 74

TechLaw 105 W. Madison Stmt, Sato WO

(312)5454990(312) 3454979 (Fax)W\WV t^P hil'iJL'it hi* .





Reported:

May-25-06 14:43



Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X26-F-0-1 (£604004-43) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

4900

210

0.6

2.8

26000

32

3.7

64

13000

870

12000

450

18

530U

160

17

730

Sampled: Apr-27-06

Result

5000

120

0.7

4.1

25000

28

3.4

96

15000

880

11000

570

Flags/Qualifiers

*

*,J

K..J

*

*

*

K

L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.828

2.4

5.5

Limit Units

99 mg/kg

1.0

1.0

2.0

99

2.0

4.0

4.0

99

9.9

40

0.5

4.0

99

2.099

9.9

20


1 EE60205 May-04-06May-17-06 EPA 200.7„

„

,,

n n it

n t» m

„

„

n it n

n 11 n

n n n

.„.,.„

"ii n n

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

16:25 Received: Apr-28-06 12:08

Flags/Qualifiers

*

*

J, **

L

J

*

K,*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

3.9

14

0.1

Limit Units

98 mg/kg

1.0

1.0

2.0

98

2.0

3.9

3.9

98

9.8

39

0.5


1 EE60206 May-04-06May-ll-06 EPA 200.7n ,.

it w n

,,

it M n

K M 1 1

-N n n

II M H

H M H

H « II

II n M

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 31 of 74

MawQ x t t t i t i * t i t t r f i l l j

105 WNWiwnStmt, Suit* 900Oncafo,IL 60602

012)3454990(312) 3454979 (F«)



Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX26-F-0-1 (E604004-43) Soil Sampled: Apr-27-06,16:25 Received: Apr-28-06 12:08

AnalyteNickel

Potassium

Silver

Sodium

VanadiumZinc

X26-F-1-6 (E604004-44) Soil

Analyle

Aluminum

Barium

BerylliumCadmium

Calcium

Chromium

CobaltCopper

IronLeadMagnesium

Manganese

Nickel

PotassiumSilverSodiumVanadium

Zinc

Result

16

490

1.0

14017

1000

Sampled: Apr-27-06

Result

3500

97

0.6

3.5

24000

14

2.7

57

12000

690

12000

37011

330U

120

12

860

Flags/Qualifiers

*

J

4

K,*

MDL

1.0

22

0.8

27

2.4

5.5

Limit Units

3.9 mg/kg

98

2.0

98

9.8

20


1 EE60206 May-04-06 May- 11-06 EPA 200.7II It N

m m i i

H II N

M M •

N i l H

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

16:30 Received: Apr-28-06 12:08

Flags/Qualifiers

*

*

J, •t

LJ*

K,*

*

*

K,*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.828

2.4

5.5

Limit Units

99 mg/kg

1.0

1.0

2.099

2.0

4.0

4.0

99

9.9

40

0.5

4.0

99

2.099

9.9

20


1 EE60206 May-04-06May-l 1-06 EPA 200.7

"„

.

.

n ii N

it n «

tl n II

n u n

»-•n n i*

M M H

m m n

ii n n

II II M

M n n

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 32 of 74

MawQ t t t l i t l

IQSW.MidixmStiwL, Safe 900Qucafo,IL 60602

(312)3454990(312) 3454979 (Fax)




May-25-06 14:43

X26-FD-1-6 (E604004-45) Soil

Metals by ICP


Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

ChromiumCobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

PotassiumSilver

Sodium

VanadiumZinc

X26-F-6-12 (£604004-46) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

ChromiumCobalt

CopperIron

Lead

Magnesium

Manganese

Result

3600

92

0.6

3.4

25000

14

2.9

58

11000

630

12000

390

12

330

1.5

130

12

870

Sampled: Apr-27-06

Result

2000

42

0.3

1.1

22000

5.7

1.617

5800

150

11000

170

Flags/Qualifiers

*

*

J,*

*

L

J*

K,*

*

J

*

K,*

MDL

12

0.2

0.2

0.4

19

0.5

I . I

1.4

24

4.0

14

0.1

1.0

22

0.8

28

2.4

5.6

16:35 Received:

Flags/Qualifiers

*

*

J, *

J,*

L

J*

K, *

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20

Apr-28-06 12:08

Limit Units

99 mg/kg

1.0

1.0

2.099

2.0

4.0

4.0

99

9.9

40

0.5


1 EE60206 May-04-06May-ll-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" ' " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " ' " EPA 200.7

EPA 200.7

EPA 200.7


I EE60206 May-04-06May-ll-06 EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.711 EPA 200.7



Page 33 of 74

MawQ t a t i t i

105 W.MxtwmSttHt, Suite 900Oucafo,IL 60602

(312)545^990(312) 5454979 (Fa)





Reported:

May-25-06 14:43



Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X46-B-0-1 (E604004-47) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

8.42001.2805.8210

Sampled: Apr-27-06

Result

12000

2001.06.1

17000

516.1310

31000

9006500

86040890

U

10030

1300

Flags/Qualifiers

*

J

JJ ,*

K,*

MDL1.0220.8282.45.6

Limit Units

4.0 mg/kg

992.099

9.920


1 EE60206 May-04-06May-ll-06M l * H N

M n H it

n M M n

n

II H H •

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

14:45 Received: Apr-28-06 12:08

Flags/Qualifiers

*

*

*,J•

L

*

K,*

4

4

*,K.

MDL120.20.20.4190.51.11.4244.1

140.11.0220.8282.45.7

Limit Units

100 mg/kg

1.01.02.01002.04.14.110010410.54.11002.01001020


1 EE60206 May-04-06May-ll-06it tt n n

"tt * « H

p n n H

n n tt tt

n It II it

« n it »

n tt it n

.M n n n

.U N M M

.

„

. . . .

it tt » it

„ ,,

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

StepHen Connet, Chemist


Page 34 of 74

ktilawQ u a l i t y

105 W.KMumStmt, Sate 900Qacafo,IL 60602

012)3454990(312) 3454979 (Fat)




Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX46-B-1-6 (£604004-48) Soil Sampled: Apr-27-Ofr 14:50 Received: Apr-28-06 12:08

AnalyteAluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X46-B-6-12 (£604004-49) Soil

AnalyteAluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

9500

4900.984

25000

60

7.7

530

88000

1300

8900

900

60

750U

170

25

4700

Sampled: Apr-27-06

Result

5600

290

13

7.5

17000

23

6.3

1300

38000

1600

7100

470

Flags/Qualifiers

*

*

J, **

L

*

K, *

*

*

K,*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

3.9

14

0.1

1.0

22

0.828

2.4

11

14:55 Received:

Flags/Qualifiers

*

**

*

L

*

*,K

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

Limit Units

98 mg/kg

1.0

1.0

2.0

98

2.0

3.9

3.9

98

9.8

39

0.5

3.9

98

2.098

9.8

39

Apr-28-06 12:08

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60206 May-04-06 May- 1 1 -06„

fl ft H ft

ii ii H n

n H ft ft

H n H ft

„» (• IP H

„

u ft M N

., ,. ft t,

ft

ft

n N M n

ft H H ft

n n n H

n n ft ft

2 " " May-11-06


1 EE60206 May-04-06 May- 1 1 -06H H tt ft

• tt n ft

„

M ft ft ft

n n n n

n n n it

ft

„

H ft II ft

II II ft II

ft ft ft ft

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 35 of 74

Tediaw 10SW.Madi«mSttMt,Suiii900Chicap,IL 60602

Qtt t l i t ] o(312) 3454979 (Fa)



Reported:

May-25-06 14:43


X46-B-6-12 (£604004-49) Soil Sampled: Apr-27-0614:55 Received: Apr-28-06 12:08

Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X46-DZ (£604004-50) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

120

540U

230

19

1500

Sampled: Apr-27-06

Result

12000

170

1.0

6.1

22000

57

7.2

290

32000

840

8800

980

38

750U

180

33

1500


1.0

* 22

0.828

* 2.4

K, * . 5.7

Limit Units

4.0 mg/kg

100

2.0100

10

20


1 EE60206 May-04-06May-lI-06 EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

14:05 Received: Apr-28-06 12:08


* 12

* 0.2

* 0.2

• 0.4

19

L 0.5

1.1

• 1.4

24

K,* 4.0

14

0.1

1.0

* 22

0.828

• 2.4

K, * 5.6

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0100

10

20


1 EE60206 May-04-06 May- 1 1-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.711 " " EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

" " " " EPA 200.7

" EPA 200.7

EPA 200.7EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7



Page 36 of 74

MawQ u a l i t y

105 W. Madison Stmt, Sate 900ChicafD,IL 60602

012)3454990(312) 345^979 (Fix)wmvttthlatvinc.com



Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX4G-F-0-1 (£604004-51) Soil Sampled: Apr-27-06J4:10 Received: Apr-28-06 12:08

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X46-F-1-6 (£604004-52) Soil

Analyte

A l u m i n u m

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

11000

160

1.0

5.4

24000

52

5.3

250

27000

690

9900

820

30

920U

140

27

1100

Sampled: Apr-27-06

Result

10000

180

1.0

5.0

24000

43

5.5

230

28000

680

9400

720


» 12

* 0.2

* 0.2

• 0.4

19

L 0.5

1.1

» 1.4

24

K, * 3.9

14

O.I

1.0

* 22

0.828

* 2.4

K,* 5.5

Limit Units

99 mg/kg

1.0

1.0

2.0

99

2.0

3.9

3.999

9.9

39

0.5

3.999

2.099

9.9

20


1 EE60206 May-04-06May-l 1-06 EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

" " " EPA 200.7

" EPA 200.7

EPA 200.711 " " EPA 200.7

EPA 200.7

EPA 200.7

" - » EPA 200.7

EPA 200.7

EPA 200.711 EPA 200.7

14:15 Received: Apr-28-06 12:08


* 12

* 0.2

* 0.2

* 0.4

18

L 0.5

1.1

« 1.4

23

K, » 3.9

14

0.1

Limit Units

97 mg/kg

1.0

1.0

1.9

97

1.9

3.9

3.9

97

9.739

0.5


1 EE60206 May-04-06May-ll-06 EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 " " EPA 200.7

Stephen Omnet, Chemist


Page 37 of 74

TwhLawQ»at i ( i <• l u l t f r t l y

105 W. Madison Stmt, So* 900Qoca|D,IL606Q2

0U) 3454990(312) 3454979 (Fax)




Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX46-F-1-6 (£604004-52) Soil Sampled: Apr-27-06.14:15 Received: Apr-28-06 12:08

Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X46-FD-1-6 (E604004-53) Soil

AnalyteAluminum

Barium

Beryllium

Cadmium

Ciilcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc


36

760 *U

190

26 *

1200 K, •

MDL

1.0

21

0.827

2.3

5.4



9900 *

ISO *

1.0 J, *

5.1 *

25000

44 L

5.8

220 *

32000

670 K, *

10000

750

31

720 *

U

170

25 *

1200 K, *

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.1

14

0.1

1.0

22

0.828

2.4

5.7

Limit Units

3.9 mg/kg

97

1.997

9.7

19

Apr-28-06 12:08

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5

4.1

100

2.0100

10

20


1 EE60206 May-04-06 May- 1 1 -06 EPA 200.7

" EPA 200.7

EPA 200.711 EPA 200.7

EPA 200.7

EPA 200.7


1 EE60206 May-04-06May-ll-06 EPA200.7

EPA 200.7

EPA 200.711 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7


000072Report Name: E605001,E604004FINALMay2506 1443

Page 38 of 74

TediLaw 105W.MaduouStntt>Saiti900

/ » f r / ; f / y

012)345-8990(312) 345-S979 (Fax)www f *cWanTnc com





Reported:

May-25-06 14:43

X46-F-6-12 (£604004-54) Soil

Metals by ICP


Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X48-B-0-1 (E604004-55) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Ciilcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

4400

930.62.8

32000

173.370

21000

25013000

34036590V

20013

490

Sampled: Apr-27-06

Result

6700

800.52.0

15000

383.5110

13000

2906800

400


* 12

« 0.2

*, J 0.2

« 0.4

19L 0.5

J 1.1

* 1.4

24

*, K 4.1

14

0.1

1.0

* 22

0.828

« 2.4

*, K. 5.7

Limit Units

100 mg/kg

1.01.02.01002.04.14.110010410.54.11002.01001020


1 EE60206 May-04-06May-l 1-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

" " " " EPA 200.7

" " " " EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

11:00 Received: Apr-28-06 12:08


• 12

« 0.2

J, • 0.2

J. * 0.4

19L 0.5

J 1.1

* 1.4

24

K,* 4.1

140.1

Limit Units

100 mg/kg

1.01.0

2.01002.04.14.110010410.5


1 EE60206 May-04-06May-ll-06 EPA 200.7

EPA 200.7

" " ' ' EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

" " " " EPA 200.7

" " " " EPA 200.7

EPA 200.7



Page 39 of 74

Q u a f i l r e

105 W.Madis<a Strut, Soht 900Cbicap,IL 60602

(312)3454990(312) 3454979 (F«)




May-25-06 14:43


X48-B-0-1 (E604004-55) Soil Sampled: Apr-27-06,11:00 Received: Apr-28-06 12:08

Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X48-B-1-6 (E604004-S6) Soil

AnaJyte

Aluminum

Barium

Beryllium

Ciidmium

Calcium

Chromium

Cobalt

Copper

IronLoud

Magnesium

Manganese

NickelPotassium

SilverSodium

Vanadium

Zinc

Result

15

620U

76

16

480

Sampled: Apr-27-06

Result

7400

87

0.7

2.9

17000

30

3.4

ISO

13000

360

8400

440

23

580V

100

18

730

Flags/Qualifiers

*

J*

K.'

MDL

1.0

22

0.829

2.4

5.7

Limit Units

4.1 mg/kg

100

2.0100

10

20


1 EE60206 May-04-06May-ll-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 " " " EPA 200.7

11:05 Received: Apr-28-06 12:08

Flags/Qualifiers

*4

J, *

*

LJ*

K.,*

t

*

K,*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.1

14

0.1

1.0

22

0.828

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5

4.1

100

2.0100

10

20


1 EE60206 May-04-06May-ll-06 EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 " " " EPA 200.7

EPA 200.711 " ' EPA 200.7

Stephen Cortnet, Chemist

000074,,eport Name: E605001 .E604004 FINAL May 25 06 1443

Page 40 of 74

'<TediLaw!05\VNMwDStrt*t,Sorti900

012)3454990(312)5454979 (Fix)





Reported:

May-25-06 14:43

X48-B-6-12 (E604004-57) Soil

Metals by ICP


Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Cliromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

NickeJ

Potassium

Silver

Sodium

Vanadium

Zinc

X48-DZ (£604004-58) Soil

Analyte

Aluminum

B.i ri urn

Beryllium

Cadmium

Calcium

Cliromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

3300

120

03

1.6

24000

10

2.5

45

8400

170

13000

230

16

390t

84

11

290

Sampled: Apr-27-06

Result

7300

130

0.5

3.3

24000

29

3.7

170

15000

460

11000

460

Flags/Qualifiers

*

*

J, *

J, *

L

J*

K,*

*

J

#

K, *

MDL

12

0.2

0.2

0.4

19

0.5

I . I

1.4

24

4.0

14

0.1

1.0

22

0.828

2.4

5.7

Limit Units

100 mg/kg

1.01.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0100

10

20


1 EE60206 May-04-06May-tl-06 EPA 200.7

" " " EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

• " " EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

11:15 Received: Apr-28-06 12:08

Flags/Qualifiers

«

*

J, *

*

L

J*

K,*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60206 May-04-06May-ll-06 EPA 200.7

EPA 200.711 " " " EPA 200. 7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

" " " " EPA 200.7

000075

Stephen Corfltet, ChemistReport Name: E605001 .E604004 FINAL May 25 06 1443

Page 41 of 74

TediLaw 105 W.MxfamS&wt, Sate 900

012)345-8990(312)345-*979(Fac)




Reported:

May-25-06 14:43



Analyte

Nickel

Potassium


Zinc

X48-F-0-1 (E604004-59) Soil

Analyte

Aluminum

BariumBeryllium

Cndmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

NickelPotassium


Zinc

Result

20

490U

13017

720

Sampled: Apr-27-06

Result

6000

85

0.5

1.4

13000

24

3.5

98

12000

ISO

4800

350

16

500U

62

16

300

Flags/Qualifiers

*

*

K, *

MDL

1.0

22

0.828

2.4

5.6

Limit Units

4.0 mg/kg

100

2.0100

10

20


1 EE60206 May-04-06May-ll-06 EPA 200.7

EPA 200.7

» •• » EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

11:30 Received: Apr-28-06 12:08

Flags/Qualifiers

*

*

*,J

*, J

L

J+

K, *

*

J*

K,*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.1

14

O.I

1.0

22

0.8282.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5

4.1

100

2.0100

10

20

Dilution Batch Prepared Analyzed Method ]

1 EE60206 May-04-06May-ll-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

« EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7


000076

Report Name: E605001 .E604004 FINAL May 25 06 1443

Page 42 of 74

TediLaw 105 W. Madison SttMt,$ofc 900Chicafo,IL 60602

(312)3454990(312) 3454979 (Fax)




May-25-06 14:43


X48-F-1-6 (E604004-60) Soil Sampled: Apr-27-Ofr11:35 Received: Apr-28-06 12:08

AnalyteAluminum

BariumBeryllium

Cadmium

CalciumChromium

Cobalt

CopperIron

LeadMagnesium

Manganese

NickelPotassium

SilverSodiumVanadiumZinc

X48-F-6-12 (£604004-61) Soil

Aualyte

Aluminum

Barium

Beryllium

Cadmium

CalciumChromium

Cobalt

CopperIron

LeadMagnesium

Manganese

Result

6800

93

0.6

2.3

17000

22

3.3

130

14000

290

7900

430

18

450U

110

18

520

Sampled: Apr-27-06

Result

4000

61

0.4

2.5

25000

15

2.4

87

15000

280

13000

330

Flags/Qualifiers

*

*

J, **

L

J

*

K, *

*

*

K, *

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

23

3.9

14

0.1

1.0

21

0.827

2.3

5.5

11:40 Received:

Flags/Qualifiers

*

*

J, **

L

J

*

K, *

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

O.I

Limit Units

98 mg/kg

1.0

1.0

2.0

98

2.0

3.9

3.9

98

9.8

39

0.5

3.9

98

2.098

9.8

20

Apr-28-06 12:08

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60206 May-04-06May-ll-06" " »

» » •

,,

it ft n H

it It it tt

„

I.

M tt II tt

I,

I, I, .

t. ,, n

" «

„

,.

n t» H H

H M n n

n n H n


1 EE60206 May-(M-06May-ll-06H n n m

it tt « n

n H n N

.»tt it n n

n

„

„

.

H II H H

Method

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

Stephen (Sonnet, Chemist


Page 43 of 74

35 TediLawQ u a l i t y

105 W. Madison S<mt,Safc 900Chicago, IL 60602

(312)345^990(312)345-879 (Fax)vmns t»fMan-mp corn

Superftmd, US EPA Region 577 West Jackson BoulevardChicago 1L, 60604



May-25-06 14:43

Metals by ICP



Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X50-B-0-1 (E604004-6.2) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

IronLead

Magnesium

Manganese

Nickel

PotassiumSilver

Sodium

Vanadium

Zinc


15

300 *U

100

13 *

590 K, *

MDL

1.0

22

0.828

2.4

5.6

Limit Units

4.0 mg/kg100

2.0100

10

20


1 EE60206 May-04-06May-lI-06n n N n

.

.„M H H n

Method

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



4400 *

150 *

0.6 J, *

4.6 *

22000

27 L

3J J

110 *

16000

910 *,K

9700

560

17

470 *

0.9 ;120

17 *

1100 K, •

MDL

12

0.2

0.2

0.4

19

0.5

LI

1.4

24

4.0

14

0.1

1.0

22

0.8

28

2.4

5.6

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

10010

40

0.5

4.0

100

2.0

100

10

20


1 EE60206 May-04-06May-ll-06»

n

N M N rl

n

n n n tt

,,tt * « n

ft " M W

.

„

m n n n

.n H it tt

n n n „

•.n

Method

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7



Page 44 of 74

TediLaw 105 W. Madison Stntt,Smti 900

Q u a l i t ?

(312)345-8990(312) 345-3979 (Fa)

ro-m




May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX50-B-1-6 (E604004-63) Soil Sampled: Apr-27-Od09:45 Received: Apr-28-06 12:08

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

CopperIron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

VanadiumZinc

X50-B-6-12 (E604004-64) Soil

Aiialyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

CopperIron

Lead

Magnesium

Manganese


3800 L

150 *

0.5 J

5.4 •

18000

20

3.0 J, *

110

16000

1500

8400

440

17 *

390

1.7 J, L

100 *

15

1500

MDL

12

0.2

0.2

0.4

18

0.5

1.1

1.4

23

3.9

14

0.1

1.0

21

O.g

27

2.3

5.4



2400 L

74 *

0.4 J

1.7 J, *

14000

8.2

2.6 J, *

29

7600

270

7200

240

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.1

14

0.1

Limit Units

97 mg/kg

1.0

1.0

1.9

97

1.9

3.9

3.997

9.7

39

0.5

3.9

97

1.9

97

9.7

19

Apr-28-06 12:08

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5


1 EE60207 May-04-06May-12-06ii n ii «

„»„,,„„„.M M n H

• n n n

.,

'

"

.

M M H M

M n II M


1 EE60207 May-04-06 May- 12-06II . II M

II

"

n

„

"

n ii M n

.„,.« n H n

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 45 of 74

lediLaw 105 W.MatxmStwit, Suite 900

(312)3454990(312) 3454979 (Fa)




Reported:

May-25-06 14:43



Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X50-DZ (£604004-65) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

[runLead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

12

280

0.9

90

10

730


Result

6500

240

1.6

9.0

19000

26

5.2

150

220002300

8700

610

29

600

4.4

240

28

2600


* 1.0

22

J, L 0.8

J, * 28

J 2.4

5.7

Limit Units

4.1 mg/kg

100

2.0

100

10

20

Dilution Batch

1 EE60207,,

„

•H N

ii n


May-04-06 May- 1 2-06 EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

30 Received: Apr-28-06 12:08


L 12

• 0.2

0.2

* 0.4

19

0.5

* 1.1

1.4

24

4.014

0.1

* 1.0

22

L 0.8

* 28

2.4

5.6

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20

Dilution Batch

1 EE60207.1

n i.

n w

n ft

„»n n

i,„ntl H

,,

II H

*

„

.,

„


May-04-06May-12-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 46 of 74

khLaw 105 W. Madison Strut, Safe 900

Q u a l i t y

(312)545-8990(312) 3454979 (Fat)




Reported:

May-25-06 14:43



Aiialyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X5U-F-1-6 (E604004-67) Soil

An;ilyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese


4900 L

110 *

0.6 J

3.6 *

26000

30

3.7 J, »

98

14000

830

11000

590

15 *

510

1.0 J,L

110 *

17

1200

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.8

28

2.4

5.5

Limit Units

99 mg/kg

1.0

1.0

2.0

99

2.0

4.0

4.0

99

9.9

40

0.5

4.0

99

2.099

9.9

20


1 EE60207 May-04-06 May- 12-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7



3200 L

63 '

0.4 J

2.7 *

26000

14

2.4 J, *

65

11000

520

13000

370

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60207 May-04-06 May-1 2-06 EPA 200.7

" " " " EPA 200.7

" " " EPA 200.7

EPA 200.711 EPA 200.7

EPA 200.7

" " ' EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

" EPA 200.7

EPA 200.7

000081


Page 47 of 74

Tedilaw ,! 60602(312)3454990

(312) 3454979 (Fix)



Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX50-F-1-6 (E604004-67) Soil Sampled: Apr-27-06.09:10 Received: Apr-28-06 12:08

Analyte

Nickel


Vanadium

Zinc

X50-F-6-12 (E604004-68) Soil

AnalyteAluminumB;niumBeryllium

Cadmium

Calcium

Chromium

Cobalt

CopperI run

Lead

Magnesium

Manganese

NickelPotassium

SilverSodium

Vanadium

Zinc

Result

13

320U

110

13

1000

Flags/Qualifiers

*

L*

MDL

1.0

22

0.828

2.4

5.6


Result

1800

23

0.2

1.0

29000

5.7

2.1

12

5400

88

15000

ISO

7.0

260U

89

6.9

250

Flags/Qualifiers

L*

J

J,*

J,*

*

LJ,*

J

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.014

0.1

1.0

22

0.828

2.4

5.7

Limit Units

4.0 mg/kg

100

2.0100

10

20

Apr-28-06 12:08

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

1040

0.5

4.0

100

2.0100

10

20


1 EE60207 May-04-06May-12-06 EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7


1 EE60207 May-04-06 May- 12-06 EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

" " " EPA 200.7

" " " " EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

" " " " EPA 200.7

EPA 200.7



Page 48 of 74

TediLaw( f n a f i f r o t a t f f r t t y

!OSW.MadiumSttMt, Sate 900Cbk*fo,lL 60602

(312)3454990(312) 3454979 pa)www tttklaisiM.com



Reported:

May-25-06 14:43

Metals by ICP


Aiialyte

Aluminum

BnriumBeryllium

Cadmium

Cnlcium

ChromiumCobalt

Copper

Iron

Lend

MagnesiumManganese

Nickel

Potassium

Silver

Sodium

VanadiumZinc

X10-B-1-6 (E605001-OS) Soil

Annlyte

A l u m i n u mBnrium

BerylliumCadmium

Cnlcium

Chromium

CobaltCopper

Iron

Lend

Magnesium

Manganese

Result

7400

320

1.7

3.9

24000

35

5.5

120

25000

1300

7400

630

22

830

1.0

360

24

970

Sampled: May-01-06

Result

7600

380

2.0

4.1

24000

34

53

100

24000

1100

7100

620


L 12

* 0.2

0.2

» 0.4

19

0.5

* 1.1

1.4

24

4.1

14

O.I

* 1.0

22

J, L 0.8

* 28

2.4

5.7

11:20 Received:

Limit Units

100 nig/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5

4.1

100

2.0

100

10

20

May-02-06 11:21


L 12

* 0.2

0.2

» 0.4

19

0.5

* 1.1

1.4

24

4.1

14

0.1

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5


1 EE60207 May-04-06 May- 12-06 EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

" EPA 200.7

EPA 200. 7

" " ' EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7


1 EE60207 May-04-06May-12-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7


000083


Page 49 of 74

105 W.MKbonStmt, Sate 900

(312)3454990(312) 3454979 pat)




Reported:

May-25-06 14:43


X10-B-1-6 (E605001-05) Soil Sampled: May-01-0611:20 Received: May-02-06 11:21

Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X10-B-6-12 (£605001-06) Soil

Aiialyte

Aluminum

Bnrium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

Nickel

Potassium

Silver

SodiumVanadium

Zinc


24 *

760

1.0 L, J

430 *

24

970

MDL

1.0

22

0.8

28

2.4

5.7

Sampled: May-0 1-06 11:25 Received:


5100 L

240 *

1.4

2.4 •

18000

13

3.6 J, *

S3

12000

890

7400

240

18 »

460

0.9 J, L

320 *

16

600

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

3.914

0.1

1.0

22

0.8

28

2.4

5.5

Limit Units

4. 1 mg/kg

100

2.0

100

10

20

May-02-06 11:21

Limit Units

98 mg/kg

1.0

1.0

2.0

98

2.0

3.9

3.9

98

9.8

39

0.5

3.9

98

2.0

98

9.8

20


1 EE60207 May-04-06May-12-06 EPA 200.7n

.

M H II

If tf ff

M H ft


EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

Analyzed Method

1 EE60207 May-04-06 May- 12-06 EPA 200.7H n n

,.n

..

„

tl H It

H H m

m m n

n

„

"

II

.,

.

r,

I.

.

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7


000084


Page 50 of 74

Qtal i l i i ' - l u t t f t i t y

] 05 WMidiwn Strut, Surti 900Chkafo,IL{0602

(312)3454990(312) 345*979 (Fax)


Chicago IL, 60604



May-25-06 14:43


X10-DZ (£605001-07) Soil Sampled: May-01-06 10:50 Received: May-02-06 11:21

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X10-F-0-1 (£605001-08) Soil

Ajialyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

11000

410

2.8

5.1

35000

37

5.3

140

25000

1500

8900

880

28

990

1.0

460

29

1200

Sampled: May-01-06

Result

4700

130

0.7

3J

23000

25

33

64

13000

840

9400

440


L 12

* 0.2

0.2

* 0.4

19

0.5

» I.I

1.4

24

4.1

14

0.1

* 1.0

22

J, L 0.8

* 28

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5

4.1

100

2.0

100

10

20


1 EE60207 May-04-06 May- 12-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

10:35 Received: May-02-06 11:21

Rags/Qualifiers MDL

L 12

» 0.2

J 0.2

* 0.4

18

0.5

J,* 1.11.4

23

3.9

14

0.1

Limit Units

97 mg/kg

1.0

1.0

1.9

97

1.9

3.9

3.9

97

9.7

39

0.5


1 EE60207 May-04-06 May- 12-06 EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

000085


Page 51 of 74

TediLaw 103 W.MadijonSftttt, Salt 900000310,0160602

(312)3454990(312) 3454979 (F«)



Reported:

May-25-06 14:43


X10-F-0-1 (£605001-08) Soil Sampled: May-01-06,10:35 Received: May-02-06 11:21

Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X10-F-1-6 (E605001-09) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadVlagnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

12620

U

130IS

780

Sampled: May-01-06

Result

3800

110

0.6

3.5

16000

17

2.9

57

11000

750

7400

390

15

410U

130

13

760

Flags/Qualifiers

*

L4

MDL1.0

21

0.827

2.3

5.4

Limit Units

3.9 mg/kg

97

1.997

9.7

19


1 EE60207 May-04-06 May- 12-06 EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

" " " EPA 200.7

EPA 200.7

10:40 Received: May-02-06 11:21

Flags/Qualifiers

L

*

J*

J, *

*

L*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

244.1

14

0.1

1.0

22

0.828

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5

4.1

100

2.0100

10

20


1 EE60207 May-04-06May-12-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 EPA 200.7

EPA 200.7

" " " " EPA 200.7

" " " ' EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

Stephen'connet, Chemist


Page 52 of 74

MawQ u a l i t y K> l e l t ( ' t i \ -

105 W.MafcottSttHt, Sate 900Chicafo, 1160602

(312)3454990(312) 5454979 (Fat)





Reported:

May-25-06 14:43

X10-FD-1-6 (£605001-10) Soil

Metals by ICP

TechLaw - ESAT ContractSampled: May-01-06 10:45 Received: May-02-06 11:21

Analytc

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X10-F-6-12 (£605001-11) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

MagnesiumManganese


4100 L

120 *

0.6 J

4J *

24000

19

3.1 J, *

64

11000

870

1 1000

380

12 »

440

1.2 J, L

130 *

13

840

MDL

12

0.2

0.2

0.4

18

0.5

1.1

1.4

23

3.9

14

O.I

1.0

21

0.8

27

2.3

5.4



3100 L

110 *

0.7 J

2.0 J, *

17000

10

2.6 J, »

31

10000

310

7300

220

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.1

14

0.1

Limit Units

97 mg/kg

1.0

1.0

1.9

97

1.9

3.9

3.9

97

9.7

39

0.5

3.9

97

1.9

97

9.7

19

May-02-06 11:21

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5


1 EE60207 May-04-06 May- 12-06„

. n .,

„

„

„ „

n

It « II H

"

,,

„

.

n

„

«

"

• n u n

w n II it


1 EE60207 May-04-06May-12-06n n n n

„M M n H

N N II H

n

„

11 II M H

.U N n H

H n it n

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 53 of 74

Maw 103 W.MadiumStntt, Sato 900Oiicafo.IL 60602

Q u a l i t y(312) 345-879 (Fa)

cam





Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX10-F-6-12 (E605001-11) Soil Sampled: May-01-06 10:47 Received: May-02-06 11:21

Analyte

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X13-B-0-1 (£605001-12) Soil

AnaJyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

12

290U

ISO

12

420

Sampled: May-01-06

Result

4200

130

0.6

3.5

20000

32

S.O

75

29000

940

8000

480

19

480U

170

16

760

Flags/Qualifiers

*

L*

MDL

1.0

22

0.828

2.4

5.7

Limit Units

4.1 mg/kg

100

2.0100

10

20


1 EE60207 May-04-06 May- 12-06 EPA 200.7

" " " " EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

09:20 Received: May-02-06 11:21

Flags/Qualifiers

L*

J*

4

*

L*

MDL

12

0.2

0.2

0.4

18

0.5

1.1

1.4

23

3.9

14

0.1

1.0

21

0.827

2.3

5.4

Limit Units

97 mg/kg

1.0

1.0

1.9

97

1.9

3.9

3.9

97

9.7

39

0.5

3.9

97

1.997

9.7

19


1 EE60207 May-04-06 May- 12-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 54 of 74

TediLaw 105W.Madis<mSttut,Sufc900

Q u a l i t y

(312)3454990(312)3454979 (Fa)www.ttddatiinc.com



Reported:

May-25-06 14:43



Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X13-B-6-12 (E605001-14) Soil

Aualyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese


3800 L

130 *

0.6 J

3.4 *

16000

193.9 J, *

6815000

6906600

34016 «

410V L

140 *

20

810

MDL

12

0.2

0.2

0.4

20

0.5

1.1

1.4

254.1

14

0.1

1.0

23

0.829

2.5

5.8



2500 L

67 *

0.4 J

2.2 *

19000

8.6

3.2 J, •

28

10000

260

9100

220

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.1

14

O.I

Limit Units

100 mg/kg

1.0

1.0

2.1

100

2.1

4.1

4.1

100

10

41

0.5

4.1

100

2.1100

10

21

May-02-06 11:21

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5


1 EE60207 May-04-06May-I2-06 EPA 200.711 " " " EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.711 " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

•• " •• EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7


1 EE60207 May-04-06May-12-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

" " " " EPA 200.7



Page 55 of 74

TediUw 105 W. Madison Stxtrt, Suite 900

Q u a l i t y

(312)3454990(312) 3454979 (Fa)www teddatnno HUB




May-25-06 14:43


X13-B-6-12 (E60500M4) Soil Sampled: May-01-Qfi 09:45 Received: May-02-06 11:21

Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X13-DZ (E605001-15) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

13

330U

100

12

390


Result

4100

200

0.5

3.0

23000

44

6.0

61

14000

1000

9900

400

14

530U

260

15

750


* 1.0

22

L 0.8

* 28

2.4

5.7

Limit Units

4.1 mg/kg

100

2.0100

10

20


1 EE60207 May-04-06 May- 12-06M H M II

H n it n

I.

I,

n H M II

MethodEPA 200.7

EPA 200.7

EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7

: 15 Received: May-02-06 1 1 :21


L 12

* 0.2

J 0.2

* 0.4

20

0.5

* 1.1

1.4

25

4.1

14

0.1

« 1.0

23

L 0.8

* 29

2.5

5.7

Limit Units

100 mg/kg

1.0

1.0

2.1

100

2.1

4.1

4.1

100

1041

0.5

4.1

100

2.1100

10

21


1 EE60207 May-04-06 May- 12-06ri n H H

n n n n

„n

• H n it

»ii n H n

.

.N N n n

.n n n n

tt N H II

.

-M n it n

.

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 56 of 74

TechLawQ*al! t i o t t l t f t t i j

105 W.NMwa Strut, Suite 900

(312)3454990(312) 3454979 (Fa)wivrc tedila nine .coa




May-25-06 14:43



AnalyteAluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X13-F-1-6 (E605001-17) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese


5100 L

170 *

0.7 J

5.0 *

20000

97

4.0 J, *

100

15000

1500

7500

560

IS *

500

1.7 J,L

130 *

18

1200

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.8

28

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20


1 EE60207 May-04-06 May- 12-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



3100 L

66 *

0.5 J

2.7 *

14000

11

2.2 J, *

57

10000

530

6500

300

MDL

12

0.2

0.2

0.4

19

0.5

1.11.4

24

4.1

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5


1 EE60207 May-04-06May-12-06 EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.711 " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 57 of 74

MawQ t a l i l j c^ i K l t f t i l v

105 W. Madison Stmt, Suite 900

(312)3454990(312) 3454979 (Fat)




Reported:

May-25-06 14:43


X13-F-I-6 (E605001-17) Soil Sampled: May-01-06 09:05 Received: May-02-06 11:21

Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X13-F-6-12 (E605001-18) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

9.3

310V

98

10

750

Flags/Qualifiers

*

LJ, *

MDL

1.0

22

0.829

2.4

5.7


Result

1900

35

0.2

0.9

15000

5.4

2.0

33

6100

ISO

7000

160

8.1

230U

65

7.5

240

Flags/Qualifiers

*

J

*, J*

*

*,J

K*

**

*

L

LJ

J

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

23

3.914

0.1

1.0

21

0.827

2.3

5.5

Limit Units

4.1 mg/kg

100

2.0100

10

20

May-02-06 11:21

Limit Units

98 mg/kg

1.0

1.0

2.0

98

2.0

3.9

3.9

98

9.839

0.5

3.9

98

2.098

9.8

20


1 EE60207 May-04-06 May- 12-06 EPA 200.7

EPA 200.7

- EPA 200. 7

EPA 200.7

EPA 200.7

EPA 200.7


1 EE60208 May-04-06May-15-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

" EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.711 " " " EPA 200.7

" EPA 200.7

" " " " EPA 200.7•• " • EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 58 of 74

MLaw 105W.NM«mStrHt>$afc900Chicap, DL 60602

(312)3454990(312) 5454979 (Fix)xvww t*thlaivinr com




Reported:

May-25-06 14:43


X3S-B-0-1 (E605001-19) Soil Sampled: May-01-06 16:25 Received: May-02-06 11:21

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X35-B-1-6 (E605001-20) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

ChromiumCobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

6000

75

0.5

0.8

15000

17

6.2

34

13000

120

5500

460

13

1000

U

54

15

160

Sampled: May-01-06

Result

9400

93

0.5

0.7

13000

19

8.5

36

18000

120

5500

530

Flags/Qualifiers

*

J

J ,*

*

*

4

K**

4

4

L

L

J

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.1

14

O.I

1.0

22

0.828

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5

4.1

100

2.0100

10

20


1 EE60208 May-04-06 May- 15-06 EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

• " » EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

16:30 Received: May-02-06 11:21

Flags/Qualifiers

*

J

*,J*

*

*

K*

*

*

MDL

12

0.2

0.2

0.4

19

0.5

I.I

1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60208 May-04-06 May- 15-06 EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.711 EPA 200.7

EPA 200.7

EPA 200.711 " " " EPA 200.711 EPA 200.7

EPA 200.7

EPA 200.7

" ' " EPA 200.7


000093


Page 59 of 74

MawQ u a l i t y

105 W.Madison Strut, Sri* 900Chicago, IL 60602

(312)3454990(312)345-3979 (fa)www twUawiiie com



Reported:

May-25-06 14:43

Metals by ICP


Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X35-B-6-12 (E605001-21) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

LeadMagnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc


19

1300

U

78

21

160

Sampled: May-01-06

*

L

LJ

MDL

1.0

22

0.828

2.4

5.6

16:35 Received:


6100

75

0.5

1.2

25000

24

4.9

42

15000

17012000

530

22

740U

91

17

190

*J

J, ****

K*

*

*

*

L

LJ

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.014

0.1

1.0

22

0.828

2.4

5.6

Limit Units

4.0 mg/kg

100

2.0100

10

20

May-02-06 11:21

Limit Units

99 mg/kg

1.0

1.0

2.0

99

2.0

4.0

4.0

99

9.940

0.5

4.0

99

2.099

9.9

20


1 EE60208 May-04-06 May- 15-06 EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7


1 EE60208 May-04-06 May- 15-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

- " - EPA 200.7

" " " " EPA 200.7

" EPA 200.7

EPA 200.7



Page 60 of 74

TedilawQ x a l i t i IT I t t t f t n r

105 W. Madison Stntt, Sri* 900

(312)3454990(312) 3454979 (Fa)



Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX35-DZ (E605001-22) Soil Sampled: May-01-06 16:20 Received: May-02-06 11:21

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X3S-F-0-1 (E605001-23) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

6400

82

0.4

0.6

15000

14

6.6

26

13000

69

5600

450

17

920V

54

15

130

Sampled: May-01-06

Result

6000

74

0.6

1.0

32000

17

4.1

36

14000

92

9800

450

Flags/Qualifiers

*

J

*,J*

*

*

K*

*

*

*

L

LJ

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

244.1

14

0.1

1.0

22

0.828

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

1041

0.5

4.1

100

2.0100

10

20


1 EE60208 May-04-06 May- 15-06 EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

'• EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

16:00 Received: May-02-06 11:21

Flags/Qualifiers

*

J

J, **

*

»

K*

*

*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

3.9

14

0.1

Limit Units

99 ing/kg

1.0

1.0

2.099

2.0

3.9

3.9

99

9.9

39

0.5


1 EE60208 May-04-06 May- 15-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 61 of 74

khLaw 105 W.MjdiwnStntt, Sate 900

l u t t f t i l y

(312)3454990(312) 3454979 (F«)



Reported:

May-25-06 14:43



Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X35-F-1-6 (E605001-24) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

12

770U

110

14

180

Sampled: May-01-06

Result

8200

96

0.8

1.1

25000

20

5J

52

18000

130

8300

590

22

900U

130

19

250

Flags/Qualifiers

4

L

L

MDL

1.0

22

0.828

2.4

5.5

Limit Units

3.9 mg/kg

99

2.099

9.9

20


1 EE60208 May-04-06May-l 5-06 EPA 200.7

" " " ' EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.711 " " EPA 200.7

16:05 Received: May-02-06 11:21

Flags/Qualifiers

»

J

J, *

4

*

*

K

*

*

*

4

L

L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.014

0.1

1.0

22

0.828

2.4

5.6

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

1040

0.5

4.0

100

2.0100

10

20


1 EE60208 May-04-06 May- 15-06 EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

" EPA 200.7

" " " " EPA 200.7

" " " EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7



Page 62 of 74

TediLawQ u a l i t y i ' I x t t f r i l y

105 W.Midiso&Stntt, Sate 900

(312)3454990(312) 3454979 (Fix)www ttchliwinc con




Reported:

May-25-06 14:43

X35-F-6-12 (E605001-25) Soil



Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X42-B-0-1 (E605001-26) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

8700

120

1.0

1.5

39000

16

4.1

50

15000

140

11000

820

22

810U

190

16

260

Sampled: May-01-06

Result

5600

180

0.7

5.5

29000

48

5.4

120

23000

1400

13000

810

Flags/Qualifiers

*

*, J

**

*

K4

*

*

*

L

L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.828

2.4

5.6

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0100

10

20


1 EE60208 May-04-06 May- 15-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

" EPA 200.7

" EPA 200.7

15:05 Received: May-02-06 11:21

Flags/Qualifiers

*

J**

**

K*

*

*

MDL12

0.2

0.2

0.4

18

0.5

1.1

1.4

23

3.9

14

0.1

Limit Units

97 ing/kg

1.0

1.0

1.9

97

1.9

3.9

3.9

97

9.7

39

0.5


1 EE60208 May-04-06 May-1 5-06 EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7



Page 63 of 74

khlawQuality j l u t c f r t l ?

105 W. Madison Stwtt,Suilt 900

(312)3454990(312) 3454979 (F«)vawve f *e MMftiw



Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX42-B-0-1 (£605001-26) Soil Sampled: May-01-06 15:05 Received: May-02-06 11:21

Analyte

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X42-B-1-6 (E605001-27) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

IronLead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

23710U

150

25

1400

Sampled: May-01-06

Result

3800

ISO

0.6

3.9

27000

23

3.9

73

17000

760

13000

440

14

450U

150

16

1000

Flags/Qualifiers

*

L

L

MDL

1.0

21O.g

27

2.3

5.4

Limit Units

3.9 mg/kg

97

1.997

9.7

19


1 EE60208 May-04-06May-I5-06 EPA 200.711 EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

" " " ' EPA 200.7

15:10 Received: May-02-06 11:21

Flags/Qualifiers

*

J*

*

*

J, •

K*

*

*

*

L

L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

O.I

1.0

22

O.g28

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0100

10

20


1 EE60208 May-04-06May-15-06 EPA 200.711 " ' EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.71 1 1 1 " " E P A 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" » - EPA 200.7

" " " EPA 200.7

" " " EPA 200.7

" " " EPA 200.7



Page 64 of 74

Maw 105 W.&MwaStmt, Sate 900

Qitlit?

(312)3454990(312) J454979 ffa)

t»f Uawinc




Reported:

May-25-06 14:43

X42-B-6-12 (E60S001-28) Soil



Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

SilverSodium

Vanadium

Zinc

X42-DZ (£605001-29) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

2200

45

0.2

1.0

24000

6.9

2.8

18

11000

100

13000

250

9.7

290U

85

9.4

190

Sampled: May-01-06

Result

3600

120

0.5

3.8

30000

23

4.2

64

15000

760

14000

420

Flags/Qualifiers

*

J

*,J

*

*

*,J

K*

*

*

*

L

LJ

J

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.828

2.4

5.5

Limit Units

99 mg/kg

1.0

1.0

2.0

99

2.0

4.0

4.0

99

9.9

40

0.5

4.0

99

2.099

9.9

20


I EE60208 May-04-06 May- 15-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

15:00 Received: May-02-06 11:21

Flags/Qualifiers

*

J

*

*

*

*

K*

*

*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

r.o1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60208 May-04-06 May- 15-06 EPA 200.7

" EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.711 " " ' EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

StepherTConnet, Chemist


Page 65 of 74

TtthUwQ u a l i t y * IsKfif ;

105 \VMidiKmStmt.Smti900

(312)3454990(312) 3454979 (Fa)TOTOTP




Reported:

May-25-06 14:43


X42-OZ (E605001-29) Soil Sampled: May-01-06 15:00 Received: May-02-06 11:21

AnalyteNickel

Potassium

SilverSodium

Vanadium

Zinc

X42-F-0-1 (£605001-30) Soil

AnalyteAluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron


Nickel

Potassium

SilverSodium

Vanadium

Zinc

Result

14410

U

12014

950

Sampled: May-01-06

Result

530097

0.53.4

19000

353.9110

18000

7408000

66018

530U

25024850

Flags/Qualifiers

*

LL

MDL1.0220.8282.45.6

Limit Units

4.0 mg/kg1002.01001020


1 EE60208 May-04-06May-15-06n ii H M

it n n it

„,,n n « i*

Method

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7EPA 200.7

EPA 200. 7

15:20 Received: May-02-06 1 1:21

Flags /Qualifiers

*

J4

*

*

J,*

K***

*

LL

MDL120.20.20.4190.51.11.4244.1

140.1

1.0220.8292.45.7

Limit Units

100 mg/kg1.01.02.01002.04.14.1

1001041

0.5

4.1

1002.01001020


1 EE60208 May-04-06May-15-06It 1* II H

I,

"

it n n n

"n

n

,1 ,1

.,

,.

.

„ .

,.

" » n »

„,.„ .

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

Stephen Q^nfiet, Chemist

000100_ Report Name: E605001 ,£604004 FINAL May 25 06 1443

Page 66 of 74

TechLaw 105 W. Madison StrHt, Sri* 900

(312)3454990(312)345-3979 (Fax)


Chicago IL, 60604



Reported:

May-25-06 14:43



Analytc

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X42-F-6-12 (£605001-32) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese


4300

86

O.S

3.4

22000

22

3.3

70

16000

560

10000

480

14

340t

170

17

920

Sampled: May-01-06

*

J

*

*

*

J, *

K*

*

4

4

L

L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.828

2.4

5.7

15:30 Received:


1900

44

0.2

1.1

24000

6.9

2.6

16

7100

180

13000

210

*

J

J, *

*

*

*,J

K

*

*

*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1,4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0100

10

20

May-02-06 11:21

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60208 May-04-06May-15-06 EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" ' " EPA 200.7

EPA 200.7EPA 200.7

" " " EPA 200.7

EPA 200.7

" " " EPA 200.7


1 EE60208 May-04-06May-15-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7



Page 67 of 74

MawI t t t jmj

105 W.MidiKmStxttt, Sate 90001X310,1160602

(312)3454990(312) 3454979 <?*)•anmv t»thbtrittf Mm




May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX42-F-6-12 (£605001-32) Soil Sampled: May-01-Q6 15:30 Received: May-02-06 11:21

Analyte

Nickel


Vanadium

Zinc

X49-B-0-1 (E605001-33) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

CobaltCopper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

7.5

240U

120

7.4

260

Sampled: May-01-06

Result

7500

180

0.8

2.8

38000

35

3.8

130

22000

1100

7200

530

21

880

1.0

11023

740

Flags/Qualifiers

*

L

L

J

MDL

1.0

22

0.828

2.4

5.7

Limit Units

4.0 mg/kg

100

2.0100

10

20


1 EE60208 May-04-06May-15-06n M H H

.n n n n

. . . .» * H It

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200. 7

12:15 Received: May-02-06 11 :21

Flags/Qualifiers

*

J**

*

J, *

K*

*

*

*

L

J, L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.8

28

2.4

5.6

Limit Units

99 mg/kg

1.0

1.0

2.0

99

2.0

4.0

4.0

99

9.9

40

0.5

4.0

99

2.0

99

9.9

20


1 EE60208 May-04-06 May- 15-06II II It ft

.

«

i n n M

.t* it it n

.« . . ..M „

M M . II

.

H n n n

. « N H

II » H .

.

..

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 68 of 74

SB TdiLaw105W.M*U*»SttMt,$ahi900

Quality

(312)3454990(312) 345-8979 (Fa)www t*chlawinc com




Reported:

May-25-06 14:43



Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X49-B-6-12 (E605001-35) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese


9700

180

1.3

2.8

24000

28

5.0

120

24000

2800

4400

440

27

790

3.4

180

25

890

Sampled: May-0 1-06

*

*

*

*

*

K*

*

4

*

L

L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.8

28

2.4

5.7

12:25 Received:


5500

220

1.3

3.1

29000

21

4.8

110

21000

1100

9600

340

*

*

*

*

*

K**

*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

23

3.9

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20

May-02-06 11:21

Limit Units

97 mg/kg

1.0

1.0

1.9

97

1.9

3.9

3.9

97

9.7

39

0.5


1 EE60208 May-04-06May- 15-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

" " " " EPA 200.7


1 EE60208 May-04-06 May- 15-06 EPA 200.711 " " EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

000103

Stephen Cornel, ChemistReport Name: E605001 ,£604004 FINAL May 25 06 1443

Paee69of74

TediLaw Onea|o,IL 60602012)3454990

Quality www taehlawinc eons




May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX49-B-6-12 (E605001-3S) Soil Sampled: May-01-06 12:25 Received: May-02-06 11:21

Analyte

Nickel

Potassium

Silver

SodiumVanadium

Zinc

X49-DZ (E60S001-36) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

Result

30

660

2.2

230

20

MOO

Sampled: May-01-06

Result

9600

330

1.2

5.5

18000

68

7.5

270

31000

3000

7800

880

41

580

1.4

160

44

2500

Flags/Qualifiers

*

L

L

MDL

1.0

21

0.8

27

2.3

5.5

Limit Units

3.9 mg/lcg

97

1.9

97

9.7

19


1 EE60208 May-04-06May-l5-06

"«

,,

•» n tt n

ii n n n

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

12:10 Received: May-02-06 11:21

Flags/Qualifiers

*

*

*

*

*

K**

*

*

L

J, L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

23

3.9

14

0.1

1.0

21

0.8

27

2.3

5.5

Limit Units

98 mg/kg

1.0

1.0

2.0

98

2.0

3.9

3.9

98

9.839

0.5

3.9

98

2.0

98

9.8

20


1 EE60208 May-04-06May-l5-06n n n •

m n m n

M n n *

M II K M

»

N II N M

.-

tt H tt n

H » H m

H

H tt n n

H n n ti

n n M H

n H ti H

i. n« N H H

M tl H K

Method

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7



Page 70 of 74

Techlaw 105 W.MadiwaStmt, Suht 900

Q u a l i t y

(312)3454990(312) 3454979 (Fat)vntns ttfnnvnnf MHB



Chicago IL, 60604




Reported:

May-25-06 14:43

Metals by ICP

TechLaw - ESAT ContractX49-F-0-1 (E605001-37) Soil Sampled: May-01-06 11:45 Received: May-02-06 11:21

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Silver

Sodium

Vanadium

Zinc

X49-F-1-6 (E60S001-38) Soil

Analyte

Aluminum

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Result

10000

210

0.9

5.4

25000

67

5.9

250

26000

980

11000

890

36

890

1.1

150

31

2400

Sampled: May-0 1-06

Result

10000

230

1.0

6.3

19000

46

6.6

220

26000

1000

8900

700

Flags/Qualifiers

*

J*

*

*

*

Kt

+

*

«

L

J ,L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

244.1

140.1

1.0

22

O.g

29

2.4

5.7

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.1

4.1

100

10

41

0.5

4.1

100

2.0

100

10

20


1 EE60208 May-04-06May-15-06 EPA 200.7

EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " " " EPA 200.7

EPA 200.7

" " " EPA 200.7

11:50 Received: May-02-06 11:21

Flags /Qualifiers

*

**

*

*

K*

*

*

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

Limit Units

100 mg/kg

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5


1 EE60208 May-04-06 May- 15-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

000105


Page 71 of 74

MawQ t e f i t i i ;

105 W. Madison Sttwt, Suite 900Oncafo,IL 60602

(312)3454990(312)5454979 (Fa)wnrw f»fMawing com




May-25-06 14:43


X49-F-1-6 (E605001-38) Soil Sampled: May-01-0611:50 Received: May-02-06 11:21

Analyte

Nickel

PotassiumSilverSodiumVanadium

Zinc

X49-F-6-12 (E605001-39) Soil

AnalyteAluminum

BariumBeryllium

Cadmium

CalciumChromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

NickelPotassium

SilverSodium

Vanadium

Zinc


35 *

830 L

U L

ISO

33

2200

MDL

1.0

22

0.828

2.4

5.6

Sampled: May-0 1-06 11:55 Received:


4300

150 *

0.6 J

2.5 *

26000 *

26 *

3.5 J, *

60 K

15000 *

580 *

14000 *

370

14 *

440 L

1.0 J,L

150

15

920

MDL12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.022

0.8

28

2.4

5.6

Limit Units

4.0 mg/kg

100

2.0100

10

20

May-02-06 11:21

Limit Units

100 mg/kg1.01.02.0

100

2.0

4.0

4.0

100

1040

0.5

4.0

100

2.0

100

10

20


1 EE60208 May-04-06 May- 15-06 EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7


1 EE60208 May-04-06 May- 15-06 EPA 200.7

EPA 200.7

" " ' " EPA 200.7

EPA 200.7

EPA 200.7

EPA 200.7

" " ' " EPA 200.7

EPA 200.7

EPA 200.711 " " EPA 200.7

EPA 200.7

EPA 200.711 EPA 200.7

EPA 200.7

EPA 200.7

" " " EPA 200.7

EPA 200.7

EPA 200. 7

Stephen Connet, cnemist


Page 72 of 74

lediLawQ u a / i t ? *

(312)3454990(312) 3454979 (Fax)

torn

Superrund, US EPA Region 577 West Jackson BoulevardChicago IL, 60604


Reported:

May-25-06 14:43

X49-FD-6-12 (£605001-40) Soil


Sampled: May-OK06 12:00 Received: May-02-06 11:21

AnalyteAluminum

BariumBeryllium

Cadmium

Calcium

Chromium

Cobalt

CopperIron

LeadMagnesium

Manganese

NickelPotassium

Silver

SodiumVanadium

Zinc

Result

4800

130

0.7

2.6

26000

27

4.4

74

15000

640

13000

400

18

490

1.1

230

16

1000

Flags/Qualifiers

*

J

*

*

*

*

K*

*

*

*

L

J, L

MDL

12

0.2

0.2

0.4

19

0.5

1.1

1.4

24

4.0

14

0.1

1.0

22

0.8

28

2.4

5.6

Limit

100

1.0

1.0

2.0

100

2.0

4.0

4.0

100

10

40

0.5

4.0

100

2.0

100

10

20


mg/kg 1 EE60208 May-04-06May-15-06 EPA 200.7

" EPA 200.7

" EPA 200.7

EPA 200.7

" EPA 200.7

" " " • EPA 200.7

" " EPA 200.7

" EPA 200.7

" " " " EPA 200.7

EPA 200.7

• EPA 200.7

" " EPA 200.7

" " " EPA 200.7

" EPA 200.7

EPA 200.7

EPA 200.7

" EPA 200.7

. . . . „ „ E P A 200.7


000107


Page 73 of 74


(312)345-8990(312) 345-8979 (F«c)UrtOTV PfcrtllSKTITtltf £MB



Reported:

May-25-06 14:43


X U

L The identification of the analyte is acceptable; the reported value may be biased low. The actual value is expected to be greaterthan the reported value.

K The identification of the analyte is acceptable; the reported value may be biased high. The actual value is expected to be less thanthe reported value.

J The identification of the analyte is acceptable; the reported value is an estimate.

< 5X One or both concentration values for the duplicate analysis audit were less than 5 times the MDL value AND the differencebetween the two values was less than the MDL value. The duplicate audit is acceptable. No qualification made for this QC audit

* The duplicate analysis precision is not within control limits. The reported value is estimated.

# Spike audit not valid. The sample concentration exceeds twice the concentration of the spike added. No qualification made for thisQC audit.

U Not Detected

NR Not Reported

000108

fhernktReport Name: E605001.E604004 FINAL May 25 06 1443

Documents

semspub.epa.gov · Date: Subject: From: To: UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 5 CENTRAL REGIONAL LABORATORY 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 HAY 2