ŒUVRES REPRÉSENTATIVES ET...Oxidation Technologies Ozonisation with hydrogen peroxide (O 3 /H 2 O...

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C/ San Jaime nº12 – Burriana (Castellón) – Spain www.anoraempresas.com

ŒUVRES REPRÉSENTATIVES ET ENGINEERING AND ARCHITECTURE PROJECTS WATER HARVESTING, TREATMENT AND DISTRIBUTION PURIFIERS

ANORA ENVIRONMENTAL INDUSTRIES

THE PRODUCT

LEADING TECHNOLOGY INCREASINGLY RECOMMENDED BY THE SCIENTIFIC COMMUNITY (THE GUARANTEE countless articles)

UNIQUE

DISTINGUISHING

INOVATIVE

VERY COMPETITIVE

THE TECHNOLOGY. ADVANCED OXIDATION PROCESSES

Advanced Oxidation

Technologies

Ozonisation with hydrogen peroxide (O3/H2O2)

Ozonisation from alkaline medium (O3/OH-)

Fenton processes (Fe+2/H2O2)

Electrochemical oxidation

Radiolysis γ and treatment with electron beams

Non-thermal plasma

Electrohydraulic descharge-ultrasounds

Water photolysis in the UV vacuum

Sub and supercritical water oxidation

UV/H2O2

UV/O3

Foto-Fenton and related

Heterogeneous photocatalysis

NO PHOTOCHEMICAL PROCESSES PHOTOCHEMICAL PROCESSES

THE PRODUCT. ADVANCED OXIDATION TECHNOLOGY

TECHNICAL DEVELOPEMENT

NDUSTRIAL DESIGN

h2o.TITANIUM

TO REPRODUCE AT THE INDUSTRIAL LEVEL THE ADVANCED OXIDATION PROCESS IN A SIMPLE AND EFFCIENT WAY TO PRODUCE HYDROXYL RADICALS, IN ORDER TO OFFER A MARKET’S UNIQUE EQUIPMENT:

COMPACT, SIMPLE AND COMPETITIVE.

THE PRODUCT. OUR MAJOR CHALLENGE

It is NOT a paste

It is NOT a coating

It is NOT a granulated

THE PRODUCT. h2o.TITANIUM REACTORS

REACTORS MANUFACTURED IN A WHOLE BLOCK OF TITANIUM DIOXIDE

LIGHTNESS, ADAPTABILITY, STAINLESS, MINIMUM CONSUMPTION AND SPACE

THE PRODUCT. h2o.TITANIUM REACTORS

To disinfect and to eliminate pollutants without chemical products addition.

¿HOW?

Using hydroxyl radicals

OH •

THE PRODUCT. THE OBJECTIVE OF THE TECHNOLOGY

HIGH REACTION

SPEED

HIGH OXIDATION POTENTIAL

UV JUST FOR OH •

GENERATION

THE PRODUCT. THE OPERATION

Oxidation Agent eV

Flúor 2,87

Radical Hidroxilo 2,80

Oxígeno Ión 2,42

Ozono 2,07

Peróxido de Oxígeno 1,78

Ácido Hipocloroso 1,48

Cloro 1,36

Oxígeno 1,23

Bromo 1,07

Dióxido de Cloro 0,95

Reaction speed •OH O3

Alquenos Clorados 109 - 1011 10-1 – 103

Fenoles 109 - 1010 103

Aromáticos 108 - 1010 100 – 102

Cetonas 109 - 1010 100

Alcoholes 108 – 109 10-2 – 100

Alcanos 106 – 109 10-2

Oxidation capacity Reaction speed

THE PRODUCT. THE OPERATION

MINIMUM SPACE

MNIMUM CONSUMPT.

VERY ADAPTABLE

VERY VERSATILE

MINIMUM MAINT.

VERY ROBUST

VERY LIGHT

IT IS NOT CONSUMED

SIMPLE DESIGN

EASY USE + INSTALL.

NO TiO2 DETACHED

OH • LIFE NANO SEC.

BENEFITS

Not resistance generation Not selective Stainless (TiO2) Not by-products generation Not chemicals use. Not installations damage Do not affect people Do not affect environment Do not affect the turbidity Well tested in many areas

THE PRODUCT. BENEFITS

HARMLESS

WRAS APPROVED

EFECTIVENESS 99,99%

1. 4,5 < pH < 10,5

2. 1ºC < T (ºC) < 55ºC

3. P< 10 bar

OPTIMAL WORKING CONDITIONS

Positioning Minimum flow Maximum flow

Online 0.2 m3/h 1.000 m3/h

Recirculating 0.2 m3/h 2.500 m3/h

FLOW RATES TREATED BY ONE REACTOR

THE PRODUCT. LIMITATIONS

PRODUCT MADE IN SPAIN

EQUIPMENT SUITABLE TO BE USED FOR

DRINKING WATER DISINFECTION

ÖNORM UNDER DEVELOPMENT

THE PRODUCT. CERTIFICATIONS

MODELS AND TECHNICAL BASIC CHARACTERISTICS MODELS Flow

(m3/h) Drop pressure

(bar) Installed power

(W) Lamp 80/105 W

(nº) Diameter

(mm) Lenght

(mm) AOP 05 0.5 < 0.1 20 1 45 222 AOP 1 1 < 0.1 30 1 76 472 AOP 3 3 < 0.1 110/130 1 60 883 AOP 5 5 < 0.1 110/130 1/1 76 894 AOP 10 10 < 0.1 200/250 2/2 120 891 AOP 20 20 < 0.1 385/490 4/4 160 956 AOP 50 MULTI 50 < 0.2 765/720 8/6 224 954 AOP 100 MULTI 100 < 0.2 1.320/1.200 14/10 304 954 AOP 200 MULTI 200 < 0.2 ---/2.140 ----/18 405 1.070 AOP 300 MULTI 300 < 0.2 ---/3.320 ----/28 455 1.132 AOP 400 MULTI 400 < 0.2 ---/4.500 ----/38 505 1.138 AOP 500 MULTI 500 < 0.2 ---/5.680 ----/48 605 1.163 AOP 700 MULTI 600-700 < 0.2 ---/7.820 ----/66 706 1.246 AOP 900 MULTI 800-900 < 0.2 ---/9.980 ----/84 756 1.316 AOP 1.000 MULTI 1.000 < 0.2 ---/11.120 ----/94 806 1.327

THE PRODUCT. CHARACTERISTICS

APPLICATION FIELDS

10 YEARS SALT, BRACKISH AND FRESH WATERS MUDDY AND TRANSPARENT WATERS WITH OR WITHOUT POLLUTANTS PRESENCE WITH OR WITHOUT SOLIDS PRESENCE CLEAR AND COLOUR WATERS WITH OR WITHOUT ODOR

MICROORGANISMS REDUCTION 3-4 LOGARITHMIC UNITS

H2o.TITANIUM. DISINFECTION EXPERIENCE

h2o.TITANIUM. APPLICATION FIELDS

LA FE UNIVERSITY HOSPITAL VALENCIA (SPAIN)

GOAL: To disinfect the water of cooling circuit corresponding to 6 cooling towers for legionela prevention.

h2o.TITANIUM AOP 50 V circuit=40 m3 F recirculation=625 m3/h

APPLICATION FIELDS. DISINFECTION

RESULTS: Reduction of 3 logarithmic units continuously

LA FE UNIVERSITY HOSPITAL VALENCIA (SPAIN)

APPLICATION FIELDS. DISINFECTION

GOAL: To improve the water quality switching the chlorine dioxide unit for a h2o.TITANIUM reactor.

COMMUNITY HOSPITAL OF LONDON (UK)

h2o.TITANIUM AOP 5 F recirculation=5 m3/h

APPLICATION FIELDS. DISINFECTION

RESULTS: Bacterial contamination and maintenance costs reduction

COMMUNITY HOSPITAL OF LONDON (UK)

The reduction in the bacteria colony counts at 22 y 37 ºC has been de 99.8% y del 100% respectively.

APPLICATION FIELDS. DISINFECTION

GOAL: To reduce the existing phosphatizing process bacteria contamination to prevent damages during the catophoresis process.

NISSAN MOTORS BARCELONA (SPAIN)

h2o.TITANIUM AOP 20 V pond=10 m3 F recirculation=163 m3/h F intake=4.5 m3/h.

APPLICATION FIELDS. DISINFECTION

NISSAN MOTORS BARCELONA (SPAIN)

RESULTS: Reduction of 3 logarithmic units continuously overtime.

APPLICATION FIELDS. DISINFECTION

NUCLEAR WASTE PLANT OF SELLAFIELD LTD KENT (UK)

GOAL: To disinfect the water of cooling circuit using the h2o.TITANIUM as a gamma irradiation supporting technology to prevent legionela

h2o.TITANIUM 2 X AOP 100 V circuito=880 m3 F recirculación=200 m3/h

APPLICATIONS FIELDS. DISINFECTION

RESULTS: Water completely disinfected without using chemical products.

Tailor made solution installed on a container

NUCLEAR WASTE PLANT OF SELLAFIELD LTD KENT (UK)

APPLICATIONS FIELDS. DISINFECTION

GOAL: h2o.TITANIUM water disinfection as a tertiary treatment for the chlorine elimination as a disinfection chemical agent.

WASTE WATER PLANT MURCIA (SPAIN)

h2o.TITANIUM AOP 100 F recirculation= 50 m3/h

APPLICATION FIELDS. DISINFECTION

RESULTS: Reduction never lower to 90% in all the cases

2 logarithmic units reduction in all the cases.

WASTE WATER PLANT MURCIA (SPAIN)

APPLICATION FIELDS. DISINFECTION

GOAL: Water disinfection using the h2o.TITANIUM as a tertiary treatment to reuse the water for irrigation.

WATER WASTE PLANTVALENCIA (SPAIN)

h2o.TITANIUM AOP 50 F online= 49 m3/h

APPLICATION FIELDS. REUSE

RESULTS: 2-3 logarithmic units reduction continuously, with a single pass through the reactor.

The efficiency in the 90% of the samples has been the 100%

WASTE WATER PLANT VALENCIA (SPAIN)

APPLICATION FIELDS. REUSE

FOOD INDUSTRY SEVILLA (SPAIN)

GOAL: Water regeneration coming from the brine of the processed vegetables for it reuse on the same industrial process.

h2o.TITANIUM AOP 50 V total= 10m3/día F recirculation= 200 m3/h

APPLICATION FIELDS. REGENERATION

RESULTS: After the industrial process proposed, the water coming from the brine reachs the law to be reused on the same process.

The proposed solution and customer are confidential. The results have been achieved due the synergies between the h2o.TITANIUM and other technologies.

FOOD INDUSTRY SEVILLA (SPAIN)

APPLICATION FIELDS. REGENERATION

EELS FISH FARM VALENCIA (SPAIN)

GOAL: To reduce the water orange in colour due the humic acids presence.

APPLICATION FIELDS. COLOUR REDUCTION

h2o.TITANIUM AOP 1 F recirculation= 1 m3/h V= 2’5 m3

RESULTS: 92% colour reduction without any change to water physicochemical properties.

One unit pH reduction and the NH4 and the NO3 remain the same.

EELS FISH FARM VALENCIA (SPAIN)

APPLICATION FIELDS. COLOUR REDUCTION

BASS FISH FARM VALENCIA (SPAIN)

GOAL: Turbidity reduction and water quality growth comparing the h2o.TITANIUM effect with traditional UV equipments.

h2o.TITANIUM AOP 100 V total= 540 m3 F recirculation= 250 m3/h

APPLICATION FIELDS. TURBIDITY REDUCTION

RESULT: 95% turbidity and microbial load remaining constant over time.

BASS FISH FARM VALENCIA (SPAIN)

APPLICATION FIELDS. TURBIDITY REDUCTION

TILE INDUSTRY CASTELLÓN (SPAIN)

OBJETIVO: Flocculants consumption reduction for the atomizers sludge's, using h2o.TITANIUM, to avoid the mills stop caused by clogging.

h2o.TITANIUM AOP 100 V total= 400 m3 F recirculation= 90 m3/h

APPLICATION FIELDS. DECONTAMINATION

TILE INDUSTRY CASTELLÓN (SPAIN)

RESULTS: 30% of reduction of flocculants consumption using h2o.TITANIUM in a continuous way, representing a significant savings in the use of chemical products.

APPLICATION FIELDS. DECONTAMINATION

PAPER INDUSTRY VILLABA (SPAIN)

GOAL: Odor and water micro-organisms concentration reduction coming from the casting process.

h2o.TITANIUM AOP 100 V total= 400 m3 F recirculación= 200 m3/h

APPLICATION FIELDS. DEODORIZING

RESULT: Significant ambience odor reduction that has been appreciated for both: Employees and area residents.

In just three (3) working days the reactor achieves going from and maintain over time:

• From a penetrating odor to a slightly perceptible. • From a opaque colour to an almost transparent. • From bacteria >8MM ufc/ml to 0 ufc/ml.

PAPER INDUSTRY VILLABA (SPAIN)

APPLICATION FIELDS. DEODORIZING

HOTELS AND PUBLIC SUPPLY POINTS (SPAIN)

To disinfect the water for supply.

h2o.TITANIUM AOP 300 V circuit=12,500 m3 F recirculation=625 m3/h

APPLICATION FIELDS. DISINFECTION

APPLICATION FIELDS. HOUSING and CAMS

Compact units for housing, camps, etc. 500-5,000 litres/hour

W 7 kg. M 72 x 26 x 48 cm 500 litres/hour 24 h/day 365 days/year of purified water

Stage 1 Basic filter It reduces dirt, mud, rust, suspended solids Fiber cartridge PP 1, 5, 20 and 50 m

Stage 2 Multistage filter Reduce and / or remove hundreds of contaminants from water

Stage 3 Solid carbon filter. Reduces and / or eliminates volatile organic compounds (VOCs), insecticides, pesticides and industrial solvents.

Stage 4 Advanced oxidation process. Reduces and / or eliminates microbiological contaminants without using chemicals.

Compact units for housing, camps, etc. 500-5,000 litres/hour

APPLICATION FIELDS. HOUSING and CAMPS

APPLICATION FIELDS. HOUSING and CAMPS

Compact units for housing, camps, etc. 500-5,000 litres/hour

1. Simple and effective OH solution 2. Low maintenance cost 3. Enduring in time 4. High processing capacity 5. Versatile and adaptable 6. Economically competitive 7. Unchecked by qualified personnel 8. No generation of byproducts

APPLICATION FIELDS. HOUSING and CAMPS

Containers taylored for camps and neighborhood

APPLICATION FIELDS. HOUSING and CAMPS

Compact units for housing, camps, etc. 500-5,000 litres/hour

ANORA ENVIRONMENTAL INDUSTRIES C/ San Jaime 12-B 12530 Burriana - Tel 964 51 63 92

SPAIN www.anoraempresas.com vmonsonis@anoraempresas.com

The problem of water and our solution

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