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Polymer products for personal care
derypol
“We make polymers, we care for the environment“
"We make polymers, we care for the environment" "We make polymers" means that Derypol works to detect the market needs and to investigate and develop products. Our concern for the environment has become our main objective. For this reason, we only use processes and products that respect the environment. Our range of products for water treatment is the result of our commitment to innovate and to use advanced technologies for the development of specialized and progressive products. All our products are the fruit of extensive investigation and are made in accordance with the most demanding criteria and quality.
Mr. Guillem Solé General Manager
derypol
OPM504
OPM544
DER K228PF
DER K327PF
DER BCA42PF
DER K2PF
DER K6
DER K39PF
HIMOSAP GAS100
HYGEL CL1700
HYGEL LE766
HYGEL LE585
HYGEL LE305
HYGEL E375C
HYfix CX414
Contents Index
22-23 Styling Agent HYfix Series
12-21 Rheology Modifiers Himosap & HYgel Series
4-5 Opacifiers OPM Series
6-11 Conditioners DER Series
HYGEL E100FD
DER K11PF
Opacifiers OPM Series
4
The objective of an opacifier is to improve the appearance of the product, even if colouring compounds are used in its formulation.
Our OPM series guarantees a good opacifying capacity and good stability in a wide range of products formulations; however it is mandatory to check this compatibility at laboratory scale prior to progressing to industrial scale. Derypol has an equipped laboratory and expert staff for this testing in order to check formulation stabilities. These are the conditions to which the opacified formulations are submitted:
To get the most effective blend of the opacifier we recommend a previous dilution of the OPM product with water in a proportion of 1:5 or 1:10, and to dilute with between 10% and 20% in an intermediary phase of the addition of the products. The recommended doses are usually within the range of 0.2 – 1% depending on each particular case. Our OPM series are used in a wide range of products in cosmetics and detergency as Sunlight protection products, bath gels, hand soaps, face cleaning creams, shampoos, hair treatment creams and others.
OPM 504 & OPM 544
Properties
Applications
Estability
+ 0.5% OPM 544
Stability Test Control:
4 weeks of stove 45 ºC.
Centrifugation (special cases).
derypolOpacifiers OPM Series
5
OPM 504 OPM 544
Appearance White milky White milky
Solids 40% 40%
pH 2,1 – 3,5 2. – 3.5
Viscosity <100 cps < 100 cps
Density 1.10 gr/cc aprox 1.10 gr/cc aprox
Surfactants Anionic
Nonylphenol free Anionic
Nonylphenol free
Particle Size 150 - 350 nm 150 - 350 nm
INCI Styrene / Acrylates copolymer
Specifications
Conditioners DER Series
6
Compatible with most components of cosmetic formulations, as well as with most cationic, no ionic, anionic and amphoteric surfactants. Transparent and colourless cosmetic products.
Substantively properties to skin and hair. DER K228PF and DER K327PF do not contain parabens. The preservative used as an alternative is sodium
benzoate.
Compatible with most components of cosmetic formulations, as well as with most cationic, no ionic, anionic and amphoteric surfactants.
Substantively properties to skin and hair (PQ22 is mainly used in hair care formulations due to its high cationicity).
Both products are parabens free. The preservative used as an alternative is sodium benzoate.
DER K228PF & DER K327PF
Applications
In Skin Care products: - Imparts a smooth, velvety feel and reduces tightness after drying skin. - Improves foam for liquid cleansing and liquid soaps. - Provides an excellent moisturization.
In Hair Care products: - Provides a luster and a soft silky feel. Reduce static and flyaway. Increase Shine, softness and body.
- Excellent lubricity and sang-free wet compatibility. - Imparts excellent dry compatibility when the hair is dried. Improve wet and dry combability. - Helps hold curl without flaking.
Properties
DER BCA42PF
Properties
Applications
In Skin Care products: - Imparts a smooth, velvety feel and reduces tightness after drying skin. - Improves foam for liquid cleansing and liquid soaps. - Provides an excellent moisturization.
In Hair Care products: - Provides a luster and a soft silky feel. - Excellent lubricity and sang-free wet compatibility. - Imparts excellent dry compatibility when the hair is dried. - Helps hold curl without flaking.
INCI: POLYQUATERNIUM 7
INCI: POLYQUATERNIUM 22
Conditioners DER Series
7
Compatible with most components of cosmetic formulations, as well as with most cationic, no ionic, anionic and amphoteric surfactants. Transparent and colourless cosmetic products.
Substantively properties to skin and hair. DER K228PF and DER K327PF do not contain parabens. The preservative used as an alternative is sodium
benzoate.
Compatible with most components of cosmetic formulations, as well as with most cationic, no ionic, anionic and amphoteric surfactants.
Substantively properties to skin and hair (PQ22 is mainly used in hair care formulations due to its high cationicity).
Both products are parabens free. The preservative used as an alternative is sodium benzoate.
100% cationic. High substantive power. Full compatibility with non-ionic and amphoteric ingredients. It imparts a smooth and velvety touch on the skin contributing greatly to maintain a maximum degree of hydration. Easy to dosage due to its solubility in water. DER K6 is a very high molecular weigh polymer.
Easy incorporation in formulations due to complete water solubility.
Compatible with a wide range of surfactants, including anionic and amphoteric ones.
Compatibility with ethanol for hair formulations (musses and sprays).
Acts as an antistatic agent, film former and hair fixative.
DER K2PF & DER K6
Properties
Applications
In Skin Care products: - Provides a luster and a soft silky feel. - Give to the skin a soft, velvety and non greasy after feel. - Improves the spreadability and the application of the final product.
In Hair Care products:
- Conditioning shampoos, blow-dry lotions, leave on or rinse off conditioners, hair relaxer creams. - Provides a luster and a soft silky feel. - Reduce Static and flyaway effect. - Increase Shine, softness and body. - Improving wet and dry combability. - Improves the spread ability and the application of the final product. - Strong conditioning effect, both products are mainly used in Afro-American products, damaged hair products and tightly curly hair.
DER K11PF
Properties Applications
Conditioner for styling gels. Hair Care; It can be formulated into styling mousses,
lotions and gels, conditioners, transparent shampoos and treatment products.
Improve wet and dry combability. Increase Shine, soft-ness and body.
Good curl retention. Form a non-tacky and continuous film. Suitable for Skin care products; liquid soaps, shower
gels, body lotions and shaving products.
INCI: POLYQUATERNIUM 6
INCI: POLYQUATERNIUM 11
Conditioners DER Series
8
Amphoteric terpolymer suited for liquid cleansing products. Compatible with anionic and amphoteric surfactants. For hair care products, it provides really good dry and wet combing properties. Preserved with Sodium Benzoate as an alternative to parabens.
Properties
DER K39PF
Applications
In Hair care products: - Excellent lubricity and slip, excellent wet combability without too much build-up. - Provides sheen to dry hair. - Excellent dry combability. - Superior conditioning properties for products with extreme pH ranges.
In Skin care products: - Contributes lubricity, which makes their application easier. - Reduces tightness of drying skin, and provides a smooth feel. - Excellent moisturization - Helps to reduce irritation resulting from liquid cleansers. - Liquid cleansers obtain a richer, thicker foam with better stability.
INCI: POLYQUATERNIUM 39
Conditioners DER Series
9
pH Viscosity Solids Components INCI
DER K228PF 3 - 4.5 7.500 - 15.000 8 - 10% AAM
DADMAC Polyquaternium - 7
DER K327PF 3.3 - 4.5 7.500 - 15.000 17 - 20%
DER BCA42PF 4 - 5.5 3.000 - 6.000 39 - 43% AAC
DADMAC Polyquaternium - 22
DER K2PF 5 - 7 5.000 - 12.000 40%
DADMAC Polyquaternium - 6
DER K6 4 - 7 4.000 - 12.000 19 - 21%
DER K11PF 3 - 5 10.000 - 60.000 19 - 22% DMAEMA Polyquaternium - 11
DER K39PF 3.3 - 4.5 1000 - 6000 9 - 11% AAC AAM
DADMAC Polyquaternium - 39
Specifications
DADMAC: Diallyldimethylammonium Chloride AAC: Acrylic Acid AAM: Acrylamide
10
Himosap Series (Exclusive Derypol´s Technology)
Are well known polymers but in aqueous presentation form. Water dispersion polymers are not known in the cosmetic market thereby Himosap are special products and they work in a different way than others solids, emulsions or latex products. Advantages of Himosap products: Aqueous dispersion free of oils, solvents and surfactants. Water based polymers that permits a very easy preparation. Immediately dissolutions. Excellent salt tolerant, even better than other products in the market. Provides aqueous transparent solutions. Viscosity recovered after boiling it. Stable with polar solvents (glycolic acid, sorbitol, glycerine, propylenglicol…). pH independent.
Water based Himosap GAS100
Aqueous emulsion HYgel CL1700
Emulsion
HYgel LE585
HYgel LE766
HYgel LE305
HYgel LE375C
Powder HYgelE100FD
Rheology Modifiers Himosap Series (Exclusive Deryol´s Technology)
Classification
HIMOSAP GAS 100
Description: ACRYLAMIDE/SODIUM ACRYLOYLDIMETHYLTAURATE/ACRYLIC ACID COPOLYMER in aqueous dispersion with ammonium and sodium sulphate
11
100
1000
10000
100000
1000000
0 2 4 6 8 10
pH
Vis
co
sid
ad
(c
ps
), 4
@0
.6 r
pm
Cross-linked copolymer with anionic content at 20% of actives. pH independent. Doesn’t need neutralization before using it. High molecular weight. The polymer thickens in all the pH range, even acid pH. Compatible with non-ionic surfactants.
Rheology Modifiers Himosap Series (Exclusive Deryol´s Technology)
HIMOSAP GAS 100
Properties
Applications
GAS100 is recommended for transparent gel formulations as: Aloe Vera, anti-cellulite gels, hot and cold effect gels, depilatories, peelings, water hairstyle, etc…
Thickening ability at different pH
1
10
100
1000
10000
100000
1000000
0 0,2 0,4 0,6 0,8 1 1,2
Viscosity (cps) Brookfield LVT
spindle 4@1.5 rpm
% NaCl
Emulsion product, 4,4%
commercial product
HIMOSAP GAS 100, 10%
commercial product
Thickening ability at different concentrations of NaCl
12
Water
Sorbitol 50% : Water 50%
Glycerine 50% : Water 50%
Propylene glycol 50% : Water 50%
Ethanol 10% : Water 90%
Sodium Chloride
Compatibilities
Cationic Surfactant
Hydrogen peroxide
Incompatibilities
Specifications
GAS 100
Appearance White milky Liquid
Actives 20%
Density 1.2
Product Viscosity < 3.000 cps
Ionic character Anionic
INCI ACRYLAMIDE/SODIUM ACRYLOYLDIMETHYLTAURATE/ACRYLIC ACID COPOLYMER
Compatibilities and Incompatibilities
Rheology Modifiers HYgel Series
Non-ionic surfactants
Glicolic acid
13
Rheology Modifiers HYgel Series
Hygel Series
HYgel CL1700
Polymer of acrylic monomers in aqueous emulsion with a high suspending ability. Anionic rheology modifier which provides clear formulations which contains high level of surfactants Compatible with electrolytes and surfactants (non-ionic, anionic and amphoteric surfactants). Solutions are pseudoplastic and non thixotropic. Neutralization at pH7. Wide pH range, pH can be reduced with Citric Acid. It is compatible with most of the more common surfactants used in personal care:
- Sodium Lauryl Sulfate - Sodium Laureth Sulfate - Cocamidopropyl Betaine - Sodium lauroyl sarcosinate - Disodium Laureth Sulfosuccinate
Properties
Aqueous Emulsion
Applications
It is usually used on clear shampoos, bath gels and 2 in 1 conditioning shampoos. Antidandruff shampoos. Baby shampoos. Facial Cleanesers. Conditioning body washes. Sanitizing gels. Low pH formulations. Pearlized Cleanising Products.
INCI: ACRYLATES COPOLYMER
14
HYgel CL 1700
Nature White milky Liquid
Viscosity (in solution) 1%: 4000-7000
Viscosity (commercial product)
< 100 cps
Acitve Content 30%
Shelf Life 6 months
pH 2.1 – 4* (Solution 1%)
INCI Acrylates Copolymer
Specifications
Rheology Modifiers HYgel Series
Factor When factor is… Suspending and viscosity
properties…
Polymer concentration Added/Increased Increase
Surfactant concentration: Sodium Lauryl Sulfate
Sodium Laureth Sulfate Cocamidopropyl Betaine
Sodium lauroyl sarcosinate Disodium Laureth Sulfosuccinate
Increased Increase
Salt Added / Increased Increase
15
Rheology Modifiers HYgel Series
Anionic acrylic copolymer dispersed in medicinal grade white oil. Those polymers are tipically used to thicken aqueous solutions and to formulate stable O/W emulsions. The polymers swell immediately in water without any neutralisation, and at room temperature. Solutions are pseudoplastic and non thixotropic. Suspension of solid particles (only the LE585) Compatible with surfactants.
Properties
HYgel LE585
Make up and sun screen formulations with a non greasy and non sticky after feel. Rub-in and spreadability of highly thick and compact creams are easier and more uniform. Cream-like gels (light textures white glossy products) Serums. Sensitive creams and baby care. Cleansing lotions and creams (compatibility with surfactants) Nail varnish remover. High pH formulations: depilatory creams, perm lotions… Hydroalcoholic gels.
Applications
INCI LE585: Acrylamide/Sodium Acrylate Copolymer Mineral Oil, Trideceth - 6
It is an anionic acrylic copolymer dispersed in Hidrogenated Polydecene as an alternative to mineral oil, and does not contain acrylamide.
It is normally used to thicken aqueous solutions and to stabilize O/W emulsions. It is pseudoplastic and non thixotropic. Its solutions do not show significant changes in viscosity and stability at high temperature. LE766 helps to stabilise suspensions. It is supplied in ready to use form, so it is no necessary neutralization. The addition can be made at any stage of
the manufacturing process (at room temperature). Compatible with surfactants.
Emulsion
HYgel LE766
Properties
INCI: Sodium Polyacrylate, Hydrogenate Polydecene, Trideceth - 6
Rheology Modifiers HYgel Series
16
Properties
It is a cationic acrylic copolymer dispersed in medicinal grade white oil. Normally used to thicken cationic aqueous solutions and to stabilize O/W emulsions. It is supplied in ready to use form, so neutralization is no necessary. It swells immediately in water at
room temperature. Solutions are pseudoplastic and non thixotropic. LE375C helps to stabilise suspensions.
Applications
Formulations that contain cationic ingredients. Make up and sun screen formulations with a non greasy and non sticky after feel. Self-tanning emulsions. Sunscreen. Skin care with AHA, acid fruits, DHA… Hair care: after-shampoos (conditioning effect)
INCI: Polyquaternium 37 Mineral Oil, Trideceth - 6
HYgel LE375C
Properties
LE305 is An anionic thickening and stabilizing agent ready to use as a fluid inverse emulsion. It has emulsifying properties with oil phases, providing gel-cream texture. HYGEL LE305 thickens extreme media (highly acidic, highly alkaline or oxidizing) and stabilizes mineral addi-
tives. This is a ready to use polymer which swells immediately in water at room temperature and without any
neutralization. LE305 allows allows the formulation of highly stable suspensions under a wide range of pH (from 2 to 11).
Applications
In Hair care products: - Creams, lotions, - Sun Care (sunscreens, self-tanning creams, …) - Hair Care - Make up
INCI: Polyacrilamide & C13-14 Isoparaffin & Laureth-7
HYgel LE305
Rheology Modifiers HYgel Series
17
HYgel LE 766 HYgel LE305 HYgel LE 585 HYgel LE 375C
Character Anionic Anionic Anionic Cationic
Nature White milky Translucent Emulsion White milky White milky
Odor Slightly acetic Slyghtly acrylic Slightly acetic Slightly acetic
Viscosity (in solution)
1%: 15000- 25000 cps
2%: 18000—32000 cps
1%: 20000-32000 cps
2%: 25000-45000 cps
Viscosity (prod. Cial.)
400 – 2000 cps 1500—5500 cps <1500 cps 200-3000 cps
Acitve Con-tent
55 - 58 %* 45 –55 % 57.5%* 53 %*
Shelf Life 12 months 12 months 12 months 12 months
pH 5 -7
(Solution 1%) 5-7
(Solution 1%) 5 – 7
(Solution 1%) 3.5 – 5
(Solution 2%)
INCI
Sodium Polyacrylate, Hydrogenate Polyde-
cene, Trideceth - 6
Polyacrilamide & C13-14 Isoparaffin &
Laureth-7
Acrylamide/Sodium Acry-late Copolymer
Polyquaternium 37
Mineral Oil (Paraffinum Liquidum), Trideceth - 6
Specifications
18
Rheology Modifiers HYgel Series
Powder
Applications
Acrylic-based polymer in powder form, typically used to formulate transparent gels. HYgel E100FD is an optimized grade of Carbomer with better clarity, handling and less foam. Thickening agent for aqueous solutions. Solutions are pseudoplastic and non thixotropic. It has a high yield value. So it is an effective agent for emulsion stabilization and stable suspen-
sion of solid particles.
HYgel E100FD (Fast Dispersion Version)
Properties
Has a very high yield value, so it is an effective agent for emulsion stabilization and stable. It used in hair care and skin care products, for gel, lotion and cream formulation. Hidro-alcoholic gels.
INCI: Carbomer
19
Hygel E100 FD
Nature
White granulated powder
Odor Slightly acetic
Water content 5 % max
Viscosity (in solution) 0.2%: 20000-30000 cps 0.5%: 45000-65000 cps
Solvent residual 1000 ppm max
Shelf Life 24 months
pH 2,7 – 3,5
(0,5% solution)
INCI Carbomer
Rheology Modifiers HYgel Series
Specifications
20
Styling Agents HYfix Series
HYfix CX414
Anionic copolymers in aqueous solution for applications in hair and skin products. Easy incorporation into formulations without heating and without neutralization. Is recommended a previous dilution to obtain better results. It provides transparent forumlations.
Properties
In Hair Care Products: - Adapted for styling gels, waxes, Creams,.. - Helps to provide high curl retention in a high humidity environment. - Contributes to a silky, dry hair feel. - Washes out easily. - Curl retantion. - It does not leave White particles once dryed - Suggested strarting concentration in Styling: 5% as supplied. - Suggested strarting concentration in Shampoos: 1.5% as supplied. In skin Care Products: - Lotions, Liquid cleanising Products, Shaving, moisturing creams. - Enhances skin smoothness. - Improve spreadibility of lotions and creams. - Suggested strarting concentration in Skin Care: 1.5% as supplied.
Applications
INCI: Methacrylic Acid/Sodium Acrylamidomethyl Propane Sulfonate Copolymer
21
Styling Agents HYfix Series
Specifications
HYfix CX414
Appearance Liquid, viscous, colorless, hazy
Odor Without scent
Colour, APHA ≤ 50
Ionic character Anionic
Solids % 10.5 – 13.1
pH 5 - 7
Viscosity 7.500 – 25.000 cps
Intrinsec Viscosity 3,5 – 4,5
INCI Methacrylic Acid/Sodium Acrylamidomethyl Propane Sulfonate
Copolymer
Product Type
Product Name
INCI
Opacifier OPM504
Styrene / acrylates copolymer
Opacifier OPM544
Conditioner DER K228PF
Polyquaternium - 7
Conditioner DER K327PF
Conditioner DER BCA42PF Polyquaternium - 22
Conditioner DER K2PF
Polyquaternium - 6
Conditioner DER K6
Conditioner DER K11PF Polyquaternium - 11
Conditioner DER K39PF Polyquaternium - 39
Rheology modifier GAS100 ACRYLAMIDE/SODIUM ACRYLOYLDIMETHYLTAURATE/
ACRYLIC ACID COPOLYMER
Rheology modifier HYgel CL1700 Acrylates Copolymer
Rheology modifier HYgel LE766 Sodium Polyacrylate / Hydrogenate Polydecene / Tri-
deceth-6
Rheology modifier HYgel LE585 Acrylamide / Sodium Acrylate Copolymer / Mineral Oil
(Paraffinum Liquidum), Trideceth - 6
Rheology modifier HYgel LE305 Polyacrylamide &
C13-14 Isoparaffin & Laureth-7
Rheology modifier HYgel LE375 C Polyquaternium 37/ Mineral Oil (Paraffinum
Liquidum), Trideceth - 6
Rheology modifier HYgel E100FD Carbomer
Styling Agent HYfix CX414 Methacrylic Acid/Sodium Acrylamidomethyl Propane
Sulfonate Copolymer.
PRODUCT APPLICATIONS / INCI NAME
PRODUCT APPLICATIONS / INCI NAME
We are working hard everyday to be able to offer new discoveries so that may:
- Improve our customers’ water quality. - Reach more profitable and sustainable treatments. - Adapt ourselves to the new government demands. - Contribute to the effort of keeping our planet blue.
Our range of products, reflective of our beliefs, is continuously evolving, because we focus our efforts specially on finding new chemicals. Our success is due to our partners, colleagues and customers, and to their spirit of innovation. We understand that our strength is in our research and development of practical application, as well as our focus on meeting the needs of our clients. To discover means that we have a great ability to adapt to the needs of the market and customers, thanks to an organization that works with dynamism, creativity, effort, and overall with illusion.
We make polymers, we care for the environment.
derypol
derypol
Derypol, S.A.
Offices: C/ Plató, Nº 6 Entlo. 5º Tel. +34 93 238 90 90, Fax +34 93238 90 91 08021 Barcelona (Spain) mail: info@derypol.com Factory and Laboratories: C/de Cal Gabatx, s/n. Tel. +34 93 849 61 88 – Fax +34 93 846 41 93 08520 Les Franqueses del Vallès Barcelona - Spain
www.derypol.com
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