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Oil Chem SurfacOil Chem TECHNOLOGIES
Our CoOur Co
ctants Bringing Chemical IORg gTO THE NEXT GENERATION
mpanympany
Oil ChemGlobal BusGlobal Bus
Raw MatSupp
Oil CInternationalTechno
InternationalMarketing & sales
OProdu
m Network –siness Strategysiness Strategy
terial ply
hem Local Partners /ologies
Local Partners / Toll Manufactures
Oil ucers
State-of-the-art PatentedDescription
New Anionic Surfactants for Large QuaAnionic ASP CompositionAnionic ASP Composition
Sulfonated Phenolic Resins for Low Ad
Viscoelastic Surfactants for EOR
Alcohol Ether Sulfonates for Hi Temp/H
Organic Alkali for Hard Waters
Amphoteric Surfactants for High TempAmphoteric Surfactants for High Temp
High MW Anionic Surfactants
I t l Ol fi Eth S lf t f Hi TInternal Olefin Ether Sulfonates for Hi T
d Technology for EORPatent No.
antity 6,043,3916 022 8346,022,834
dsorb 6,736,211
7,373,977
Hi TDS 7,427,588
11/811,786
p/Hi TDS 7,556,098p/Hi TDS 7,556,098
11/895,497
T /Hi TDS 12/009 429Temp/Hi TDS 12/009,429
Oil Chem SurfaOil Chem TECHNOLOGIES
Field ExpField Exp
actants Bringing Chemical IORg gTO THE NEXT GENERATION
perienceperience
ASP, SP Field FWarner
Instow
Crowsnest Gull Lake
Ad
Tanner
MellottRange
Pelican Lake (4)
CountessAdena
Sho-VelTum CypressBridgeport
Countess
Suffield
Diadema
ASP-othersASP, SP- Oil Chem
lood Since 1995
KaramayDaqing
Gudong
ShengliShengli
Viraj
Surtek. Chemical Enhanced Oil Recovery
ASP PROJECTASP PROJECTIN DAQ
20y
1015
cove
rys/
Day
T/D
ay
05
10
Oil R
eTo
nsMT
01 2
Well NWell N
T USING ORS 41TMT USING ORS-41TM
ING, CHINA
BEFORE ASPAFTER ASP
3 4NumberNumber SPE 36748 (1996)
Husky Tab
12
10 4/20082087 bbls/day
6
8
il C
ut
Begin ASP 6/2006
4
% O
i
300
0
2
1.7% oil cut
ber ASP Project
2500
2000
4/200810.2% oil cut
1500 bbls oil/day
00
1000
0
500
Oil Cut
Oil Production
Sho‐Vel‐Tum Fi
• On production > 40 yrs• On production > 40 yrsproduced 4 bbl/day
• ASP started on 2/98 usASP started on 2/98, us
• Total incremental oil > 1
25
30
35
5
10
15
20
So % PV
0
0 5 10 15 20 25 30 35(Surfactant Concentration %)(ASP Slug Size)
ield ASP Projectj
extensive water flood, extensive water flood,
sing Na2CO3 and ORS‐62sing Na2CO3 and ORS 62
10,444 bbl in 1.3 years
SPE 84904
North Americ
H il fi ld• Heavy oil field• Under polymer flood • Added 0.1% surfactant• ~ 3 months later, the wto 58%
a SP Project
t with polymerwater cut reduced from 97%
Big SinkingBig Sinking
Chemical injected: 0.8% NProblems overcome:• IFT lowered from 23.6 to 0• Poor water injectivity• High water cuts• 220% increase in injectivity
g, Kentuckyg, Kentucky
NaOH + 0.1% ORS‐162HF
0.001 mN/m
y
SPE 89384
Surfactant Flood For
• BHT ~ 56C• Produced brine is used to re‐i• TDS ~ 195,000 ppm, Ca,Mg ~2pp gcontain
• Had trouble injecting water• Using 0.1% SS‐780 since 2003increased the oil production
Note: Producer is not revealed d
r Low Perm Formation
inject2500 ppm, sour, high Fe pp g
3 in 2 fields – successfully
due to customer confidentially
South America
AGUA DEL CAJON AREA (CAPEX)
2005 03 04 1139.dwg
a SP Project
DIADEMA and SINDICATO (CAPSA)
KM20 y OTROS (CAPSA)
Offshore A
Sea water is softened
Single well test succe
using SS 6-72LV injec
AS Project
on the platform
essfully performed
cted with NaOH
SPE 100943, 109033
Oil Chem SurfacOil Chem TECHNOLOGIES
ProducProduc
ctants Bringing Chemical IORg gTO THE NEXT GENERATION
ct Linesct Lines
Oil Chem IOR
New Generation of IOR Surfactants:New Generation of IOR Surfactants: GreenSurfTM - Bio-Based low adsorpsurfactant
ORS Series - Pioneer ASP surfactants > 60 Millionssurfactants. > 60 Millions pounds at ≤ 0.2% successfully implemented
“Cold” Heavy Oil Recovery –No steam or solvent is neededneeded
Product Lines
Visco-elastic Smart Surfactant to provide low IFT and viscosity tion
NanoSurf 969 – 100% “Green” based micro emulsion for gas shale
“Green” aromatic solvent replacement
ORS Surfact
• > 60 million pounds were injec> 60 million pounds were injecsuccess
• Low concentration requiredq
• No co‐surfactant, solvent, salt
• Field proven successField proven success
tants for ASP
cted since 1995 with totalcted since 1995 with total
t optimization required
GreenSurfTM foGreenSurf fo
• State‐of‐the‐Art Bio‐baseState of the Art, Bio base
• Tolerant to high TDS, Ca, M
i h bl• High temperature stable
• Low adsorption
3
4
5
6
7ed
/g berea
san
d
0
1
2
3
0surfactant adsorbe
mg
or SP and ASPor SP and ASP
ed surfactantsed surfactants
Mg
GreenSurf™ Adsorption
0.05 0.1 0.15 0.2 0.25 0.3
Green Surf
Control
Surfactant wt%
“Cold” Heavyy
Heavy oil recoverythe apparent viscoppsmall amount of th
No steam or solve
y Oil Recoveryy y
y by modifyingsity of the oil with ye surfactant
ent is required
NanoSurf 969 – MUnconventiona
• 100% “Green” – environm100% Green environm
• Reduce Phase trapping
• Improve water recovery
• Increase gas regained per
• Low pour point <‐ 20⁰F
Micro Emulsion for lal Gas Reservoir
mental friendlymental friendly
meability
Nanosurf 969 for S
40
Regained Permeability Increase
20
25
30
35
40
d Pe
rmeability, %
0 1
0.15
0.2
0.25
Perm
eability, m
D0
5
10
15
0 1 2 3 4
Regained
0
0.05
0.1
30P
0 1 2 3 4Gas Drive Pressure, MPa
Shale Gas Recovery
Relative Permeability vs Residual Fluid Saturation
0.3% Nanosurf 969
Without Nanosurf 969
35 40 45 50 55 60 65
Residual Fluid Saturation, %
“Green” Aromatic So
• GreenSolv Wellbore Cle• GreenSolv Rig Wash• GreenSolv Rig Wash• GreenSolv Aromatic Re
90
100
y
GreenSolv™ Aromatic Rep
40
50
60
70
80
spha
lten
e Solven
cyue
ne=100
%)
0
10
20
30
40
Relative As
(tolu
Toluene Xy
olvent Replacement
eaner
eplacement
placement Solvency
1
lene GreenSolv Aromatic Replacement
Oil Chem SurfacOil Chem TECHNOLOGIES
ServicesServices
ctants Bringing Chemical IORg gTO THE NEXT GENERATION
AvailableAvailable
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