(i) [Zr(OPri {OSi(OtBu) }] (A) 3 · (i) [Zr(OPri) 3{OSi(O tBu) 3}] (A) Electronic Supplementary...

(i) [Zr(OPri)3{OSi(OtBu)3}] (A)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

(ii) [Zr(OPri){O(CH2)2O}{OSi(OtBu)3}] (1A)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

(iii) [Zr(OPri){O(CH2)3O}{OSi(OtBu)3}] (2A)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

(iv) [Zr(OPri){O(CH2)2CH(CH3)O}{OSi(OtBu)3}] (3A)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

(v) [Zr(OPri)2{OSi(OtBu)3}2] (B)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

(vi) [Zr{O(CH2)2O}{OSi(OtBu)3}2] (1B)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

(vii) [Zr{O(CH2)3O}{OSi(OtBu)3}2] (2B)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

(viii) [Zr{O(CH2)2CH(CH3)O}{OSi(OtBu)3}2] (3B)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

(ix) [Zr(OPri)3{OSi(OtBu)3}] (A)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

(x) [Zr(OPri){O(CH2)2O}{OSi(OtBu)3}] (1A)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

(xi) [Zr(OPri){O(CH2)3O}{OSi(OtBu)3}] (2A)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

(xii) [Zr(OPri){O(CH2)2CH(CH3)O}{OSi(OtBu)3}] (3A)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

(xiii) [Zr(OPri)2{OSi(OtBu)3}2] (B)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

(xiv) [Zr{O(CH2)2O}{OSi(OtBu)3}2] (1B)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

(xv) [Zr{O(CH2)3O}{OSi(OtBu)3}2] (2B)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

(xvi) [Zr{O(CH2)2CH(CH3)O}{OSi(OtBu)3}2] (3B)

Fig. (i)-(viii) 1H NMR spectra and (ix)-(xvi) 13C{1H} NMR spectra of complexes (A, B, 1A-3A and 1B-3B)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012