Combining Oceanic And Atmospheric Carbon Data SC2016 - 28 SEP... · ICOS Open Science Conference,...

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ICOS Open Science Conference, Helsinki, Sept 2016

CombiningOceanic And

Atmospheric Carbon Datato constrain CO2 fluxes

in Europe and its surrounding oceansChristian Rodenbeck

Max Planck Institute for Biogeochemistry, Jena

D. C. E. Bakker, B. Pfeil, G. Rehder, M. Glockzin,R. Keeling, and M. Heimann

In collaboration with

C. Le Quere, S. Zaehle

N. Gruber, Y. Iida, A.R. Jacobson, S. Jones, P. Landschutzer, N. Metzl, S. Nakaoka, A. Olsen,G.-H. Park, P. Peylin, K.B. Rodgers, T.P. Sasse, U. Schuster, J.D. Shutler, V. Valsala,

R. Wanninkhof, J. Zeng,

Many thanks to:Data contributors, DKRZ, CarboChange, IMBER / SOLAS

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↓ ↓ ↓

←←←

Atmosphere

ZOT

NOAA/GMD

MLO

SPO

340

360

380

1980 1984 1988 1992 1996 2000 2004

CO2MLO

Atmosphere

◮l l l

Causality: Fluxes, Transport −→ Concentration gradientKnowledge:

∑Fluxes ←− Concentration gradient, Transport

cmeas ←→ cmod = Af + c0

“Atmospheric Inversion” = Multidimensional linear regression

Schauinsland - SCH (night time)

360

370

380

390

400

2002 2003 2004

Monte Cimone - CMN (day time)

360

370

380

390

400

2002 2003 2004

Schauinsland - SCH (night time)

360

370

380

390

400

2002 2003 2004

Monte Cimone - CMN (day time)

360

370

380

390

400

2002 2003 2004

W Europe

1990 1995 2000 2005 2010 2015year (A.D.)

-1.5-1.2-0.9-0.6-0.30.00.30.6

CO

2 Flu

x (P

gC/y

r)

s90 v3.8

L

CO2 uptake

KCO2 release

Schauinsland - SCH (night time)

360

370

380

390

400

2002 2003 2004

Monte Cimone - CMN (day time)

360

370

380

390

400

2002 2003 2004

W Europe

1990 1995 2000 2005 2010 2015year (A.D.)

-1.2

-0.9

-0.6

-0.3

0.0

CO

2 Flu

x (P

gC/y

r)

s90 v3.8 (summer only)

L

More CO2 uptake

K

More CO2 release

Schauinsland - SCH (night time)

360

370

380

390

400

2002 2003 2004

Monte Cimone - CMN (day time)

360

370

380

390

400

2002 2003 2004

W Europe

1990 1995 2000 2005 2010 2015year (A.D.)

-1.2

-0.9

-0.6

-0.3

0.0

CO

2 Flu

x (P

gC/y

r)

s90 v3.8 (summer only)

L

More CO2 uptake

K

More CO2 release

Schauinsland - SCH (night time)

360

370

380

390

400

2002 2003 2004

Monte Cimone - CMN (day time)

360

370

380

390

400

2002 2003 2004

W Europe

1990 1995 2000 2005 2010 2015year (A.D.)

-1.2

-0.9

-0.6

-0.3

0.0

CO

2 Flu

x (P

gC/y

r)

s90 v3.8 (summer only)

L

More CO2 uptake

K

More CO2 release

∆ Temperature: ∆ Precipitation: (Jul-Sep) [Ciais et al., Nature (2005)]

2003 European climate anomaly

K

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Atmosphere

CO2

Sea-air gas exchange

Carbon

CO2 fluxinferred from CO2 inversion

Pacific 15S-15N

1990 1995 2000 2005 2010year (A.D.)

-0.50

-0.25

0.00

0.25

0.50

Sea

-air

CO

2 flu

x (P

gC/y

r)

just-to-prevent-the-PDF-page-to-be-flipped

Atmosphere

CO2

Sea-air gas exchange

Carbon

CO2 fluxinferred from CO2 inversion

Pacific 15S-15N

1990 1995 2000 2005 2010year (A.D.)

-0.50

-0.25

0.00

0.25

0.50

Sea

-air

CO

2 flu

x (P

gC/y

r)

[Peylin et al., RECCAP (2013)]

But:

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Mixed

layer

pCO2,

[DIC]

Sea-air gas exchange

Carbon

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Mixed

layer

pCO2,

[DIC]

Sea-air gas exchange

Carbon

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[http://www.socat.info/]

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Data density / distribution

[www.socat.info]

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Data density / distribution

[www.socat.info]

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Statistical

Interpolation

Linear

Regression

Non-linear

Regression

Model-based

Regr./Tuning

Mapping methods

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Statistical

Interpolation

Linear

Regression

Non-linear

Regression

Model-based

Regr./Tuning

Role of driver data

Modelassump-

tions

Mapping methods

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Statistical

Interpolation

Linear

Regression

Non-linear

Regression

Model-based

Regr./Tuning

Role of driver data

Modelassump-

tions

Direct data signals

Bridging data gaps

−→ Interesting complementarity−→ Extracting robust features

SOCOM: Collating 14 mapping methods

Mapping methods

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UEA-SIOceanFlux-SIJena-MLSCU-SCSEAOML-EMPUEx-MLRJMA-MLRUNSW-SOMLOETH-SOMFFNCARBONES-NNNIES-SOMNIES-NNPU-MCMCNIES-OTTM

Monthly pCO2 (uatm)

2003 2004 2005 2006320

340

360

380

400

420

Seasonality:

Most methods roughly agreeon phasing and amplitude

(also to Takahashi et al., 2009)

→ Seasonality well constrained from data

First SOCOM results [Rodenbec k et al., BG (2015)]

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UEA-SI

Jena-MLS

AOML-EMP

JMA-MLR

UNSW-SOMLO

ETH-SOMFFN

NIES-SOM

NIES-NN

Yearly CO2 flux (PgC/yr)

1990 1995 2000 2005 20100.0

0.2

0.4

0.6

0.8

Interannual Variations (IAV):– Tropical Pacific:

* Biome with largest IAV* Link to ENSO

Methods selected / weighted byrelative IAV mismatch to SOCATv2

Thicker lines:methods better matching the data

also mutually agree more closely

First SOCOM results [Rodenbec k et al., BG (2015)]

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UEA-SI

Jena-MLS

AOML-EMP

JMA-MLR

UNSW-SOMLO

ETH-SOMFFN

NIES-SOM

NIES-NN

Yearly CO2 flux (PgC/yr)

1990 1995 2000 2005 20100.0

0.2

0.4

0.6

0.8

Interannual Variations (IAV):– Tropical Pacific:

* Biome with largest IAV* Link to ENSO

UEA-SIJena-MLSAOML-EMPJMA-MLRUNSW-SOMLOETH-SOMFFNCARBONES-NNNIES-SOMNIES-NNPU-MCMC

Yearly CO2 flux (PgC/yr)

1990 1995 2000 2005 2010-3.0

-2.5

-2.0

-1.5

-1.0

-0.5

– Global Ocean:* Larger spread

due to poorly constrained areas

First SOCOM results [Rodenbec k et al., BG (2015)]

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UEA-SI

Jena-MLS

AOML-EMP

JMA-MLR

UNSW-SOMLO

ETH-SOMFFN

NIES-SOM

NIES-NN

Yearly CO2 flux (PgC/yr)

1990 1995 2000 2005 20100.0

0.2

0.4

0.6

0.8

Interannual Variations (IAV):– Tropical Pacific:

* Biome with largest IAV* Link to ENSO

UEA-SIJena-MLSAOML-EMPJMA-MLRUNSW-SOMLOETH-SOMFFNCARBONES-NNNIES-SOMNIES-NNPU-MCMC

Yearly CO2 flux (PgC/yr)

1990 1995 2000 2005 2010-3.0

-2.5

-2.0

-1.5

-1.0

-0.5

︸ ︷︷ ︸

Little decadal change

︸ ︷︷ ︸

Increasing sink

First SOCOM results [Rodenbec k et al., BG (2015)]

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Statistical

Interpolation

Linear

Regression

Non-linear

Regression

Model-based

Regr./Tuning

Role of driver data

Modelassump-

tions

Direct data signals

Bridging data gaps

−→ Interesting complementarity−→ Extracting robust features

SOCOM: Collating 14 mapping methods

Jena-MLS �

[Rodenbeck et al.]

� ETH-SOMFFN[Landschutzer et al.]

� UEx-MLR[Talk Ute Schuster]

Mapping methods

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Mixed

layer

pCO2,

[DIC]

Sea-air gas exchange

Carbon

CO2 fluxinferred from pCO2 interpolation

Pacific 15S-15N

1990 1995 2000 2005 2010year (A.D.)

-0.50

-0.25

0.00

0.25

0.50

Sea

-air

CO

2 flu

x (P

gC/y

r)

just-to-prevent-the-PDF-page-to-be-flipped

Atmosphere

CO2

Mixed

layer

pCO2,

[DIC]

Sea-air gas exchange

Carbon

CO2 fluxinferred from CO2 inversion

Pacific 15S-15N

1990 1995 2000 2005 2010year (A.D.)

-0.50

-0.25

0.00

0.25

0.50

Sea

-air

CO

2 flu

x (P

gC/y

r)

inferred from pCO2 interpolation

just-to-prevent-the-PDF-page-to-be-flipped

Atmosphere

CO2

Mixed

layer

pCO2,

[DIC]

Sea-air gas exchange

Carbon

Pacific 15S-15N

1990 1995 2000 2005 2010 2015year (A.D.)

-0.50

-0.25

0.00

0.25

0.50

CO

2 Flu

x (P

gC/y

r)

CO2 fluxinferred from CO2 inversion

Pacific 15S-15N

1990 1995 2000 2005 2010 2015year (A.D.)

-0.50

-0.25

0.00

0.25

0.50

CO

2 Flu

x (P

gC/y

r)

inferred from pCO2 interpolation

just-to-prevent-the-PDF-page-to-be-flipped

Atmosphere

CO2

Mixed

layer

pCO2,

[DIC]

Sea-air gas exchange

Carbon

Pacific 15S-15N

1990 1995 2000 2005 2010 2015year (A.D.)

-0.50

-0.25

0.00

0.25

0.50

CO

2 Flu

x (P

gC/y

r)

CO2 fluxinferred from CO2 inversion

Pacific 15S-15N

1990 1995 2000 2005 2010 2015year (A.D.)

-0.50

-0.25

0.00

0.25

0.50

CO

2 Flu

x (P

gC/y

r)

inferred from pCO2 interpolation

South American Trop.

1990 1995 2000 2005 2010 2015year (A.D.)

-1.5-1.0

-0.5

0.0

0.5

1.01.5

CO

2 Flu

x (P

gC/y

r)

just-to-prevent-the-PDF-page-to-be-flipped

Atmosphere

CO2

Mixed

layer

pCO2,

[DIC]

Sea-air gas exchange

Carbon

North Atlantic Temp.

1990 1995 2000 2005 2010 2015year (A.D.)

-0.50

-0.25

0.00

0.25

0.50

CO

2 Flu

x (P

gC/y

r)

CO2 fluxinferred from CO2 inversion

North Atlantic Temp.

1990 1995 2000 2005 2010 2015year (A.D.)

-0.50

-0.25

0.00

0.25

0.50

CO

2 Flu

x (P

gC/y

r)

inferred from pCO2 interpolation

just-to-prevent-the-PDF-page-to-be-flipped

Atmosphere

CO2

Mixed

layer

pCO2,

[DIC]

Sea-air gas exchange

Carbon

North Atlantic Temp.

1990 1995 2000 2005 2010 2015year (A.D.)

-0.50

-0.25

0.00

0.25

0.50

CO

2 Flu

x (P

gC/y

r)

CO2 fluxinferred from CO2 inversion

North Atlantic Temp.

1990 1995 2000 2005 2010 2015year (A.D.)

-0.50

-0.25

0.00

0.25

0.50

CO

2 Flu

x (P

gC/y

r)

inferred from pCO2 interpolation

Europe

1990 1995 2000 2005 2010 2015year (A.D.)

-0.50

-0.25

0.00

0.25

0.50

CO

2 Flu

x (P

gC/y

r)

just-to-prevent-the-PDF-page-to-be-flipped

Atmosphere

CO2

Mixed

layer

pCO2,

[DIC]

Sea-air gas exchange

Carbon

Southern Ocean

1990 1995 2000 2005 2010 2015year (A.D.)

-0.50

-0.25

0.00

0.25

0.50

CO

2 Flu

x (P

gC/y

r)

CO2 fluxinferred from CO2 inversion

Southern Ocean

1990 1995 2000 2005 2010 2015year (A.D.)

-0.50

-0.25

0.00

0.25

0.50

CO

2 Flu

x (P

gC/y

r)

inferred from pCO2 interpolation

just-to-prevent-the-PDF-page-to-be-flipped

Mixed

layer

pCO2,

[DIC]

Ocean-internal sources/sinks

Sea-air gas exchange

Carbon

CO2 fluxinferred from pCO2 interpolation

Pacific 15S-15N

1990 1995 2000 2005 2010year (A.D.)

-0.50

-0.25

0.00

0.25

0.50

Sea

-air

CO

2 flu

x (P

gC/y

r)

[www.socat.info]

But:

just-to-prevent-the-PDF-page-to-be-flipped

Mixed

layer

pCO2,

[DIC]

Ocean-internal sources/sinks

Sea-air gas exchange

Carbon

CO2 fluxinferred from pCO2 interpolation

Pacific 15S-15N

1990 1995 2000 2005 2010year (A.D.)

-0.50

-0.25

0.00

0.25

0.50

Sea

-air

CO

2 flu

x (P

gC/y

r)

0

1

“Reduction of Uncertainty” of flux IAV

But:

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Mixed

layer

pCO2,

[DIC]

Sea-air gas exchange

Carbon

just-to-prevent-the-PDF-page-to-be-flipped

Mixed

layer

pCO2,

[DIC]

Sea-air gas exchange

Ocean-internal sources/sinks

Carbon

just-to-prevent-the-PDF-page-to-be-flipped

Mixed

layer

pCO2,

[DIC]

Ocean-internal sources/sinks

, MLD, wind speed, XCO2, SLP,

Alk, SSS

Sea-air gas exchange

hd

dtC = fma(C) + finth

d

dtC = fma(C) + fint

Using parameterizations of– Solubility– Sea–air gas exchange– Carbonate chemistry– Mixed-layer tracer budget

Carbon

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Mixed

layer

pCO2,

[DIC]

Sea-air gas exchange

Ocean-internal sources/sinks

Carbon Oxygen

• Biology:Redfield stoichiometry

RO:C ≈ −1.4

• Transport+Mixing:Common pathways

just-to-prevent-the-PDF-page-to-be-flipped

Mixed

layer

pCO2,

[DIC][O2]

Ocean-in

Sea-air gas exchange

Carbon Oxygen

• Biology:Redfield stoichiometry

RO:C ≈ −1.4

• Transport+Mixing:Common pathways

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Mixed

layer

pCO2,

[DIC][O2]

Ocean-in

Sea-air gas exchange

Carbon Oxygen

• Biology:Redfield stoichiometry

RO:C ≈ −1.4

• Transport+Mixing:Common pathways

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Atmosphere

O2

Mixed

layer

pCO2,

[DIC][O2]

Ocean-internal sources/sinks

Sea-air gas exchange

Carbon Oxygen

• Biology:Redfield stoichiometry

RO:C ≈ −1.4

• Transport+Mixing:Common pathways

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Atmosphere

O2

Mixed

layer

pCO2,

[DIC][O2]

Ocean-internal sources/sinks

Sea-air gas exchange

Carbon Oxygen

CO2 fluxinferred from O2/N2

Pacific 15S-15N

1990 1995 2000 2005 2010year (A.D.)

-0.50

-0.25

0.00

0.25

0.50

Sea

-air

CO

2 flu

x (P

gC/y

r)

? �

just-to-prevent-the-PDF-page-to-be-flipped

Atmosphere

O2

Sea-air gas exchange

Carbon Oxygen

Pacific 15S-15N

1990 1995 2000 2005 2010year (A.D.)

-100

-50

0

50

100

Sea

-air

AP

O fl

ux (

Tm

ol/y

r)

APO fluxinferred from APO inversion

just-to-prevent-the-PDF-page-to-be-flipped

Atmosphere

O2

Mixed

layer

pCO2,

[DIC][O2]

Ocean-internal sources/sinks

Sea-air gas exchange

inferred from pCO2

Assumption: Linked a la Redfield

Carbon Oxygen

Pacific 15S-15N

1990 1995 2000 2005 2010year (A.D.)

-100

-50

0

50

100

Sea

-air

AP

O fl

ux (

Tm

ol/y

r)

APO fluxinferred from APO inversion

just-to-prevent-the-PDF-page-to-be-flipped

Atmosphere

O2

Mixed

layer

pCO2,

[DIC][O2]

Ocean-internal sources/sinks

Sea-air gas exchange

inferred from pCO2

Assumption: Linked a la Redfield

Carbon Oxygen

Pacific 15S-15N

1990 1995 2000 2005 2010year (A.D.)

-100

-50

0

50

100

Sea

-air

AP

O fl

ux (

Tm

ol/y

r)

APO fluxinferred from APO inversion

just-to-prevent-the-PDF-page-to-be-flipped

Atmosphere

O2

Mixed

layer

pCO2,

[DIC][O2]

Ocean-internal sources/sinks

Sea-air gas exchange

inferred from pCO2

Assumption: Linked a la Redfield

Carbon Oxygen

Pacific 15S-15N

1990 1995 2000 2005 2010year (A.D.)

-100

-50

0

50

100

Sea

-air

AP

O fl

ux (

Tm

ol/y

r)

APO fluxinferred from APO inversion

Ocean 15N-90N

-2000

-1000

0

1000

2000

Ocean 15S-15N

-2000

-1000

0

1000

2000

Sea

-air

AP

O fl

ux (

Tm

ol/y

r)

Ocean 90S-15S

Jan Jul Jan Jul

-2000

-1000

0

1000

2000

just-to-prevent-the-PDF-page-to-be-flipped

Atmosphere

O2

Mixed

layer

pCO2,

[DIC][O2]

Ocean-internal sources/sinks

Sea-air gas exchange

inferred from pCO2

Assumption: Linked a la Redfield

Carbon Oxygen

Pacific 15S-15N

1990 1995 2000 2005 2010year (A.D.)

-100

-50

0

50

100

Sea

-air

AP

O fl

ux (

Tm

ol/y

r)

APO fluxinferred from APO inversion

Ocean 15N-90N

-2000

-1000

0

1000

2000

Ocean 15S-15N

-2000

-1000

0

1000

2000

Sea

-air

AP

O fl

ux (

Tm

ol/y

r)

Ocean 90S-15S

Jan Jul Jan Jul

-2000

-1000

0

1000

2000

!

!

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What do the atmospheric stations “see”?Testing existing and potential CO2 observations (RINGO)

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W Europe

2012 2013 2014 2015year (A.D.)

-0.6

-0.3

0.0

0.3

0.6

CO

2 Flu

x (P

gC/y

r)

– “Known truth”(OCN, Zaehle et al., 2010)

– Retrieved from “synthetic data”

(s04 v3.8 sites)

(3-monthly anomalies)

What do the atmospheric stations “see”?Testing existing and potential CO2 observations (RINGO)

just-to-prevent-the-PDF-page-to-be-flipped

W Europe

2012 2013 2014 2015year (A.D.)

-0.6

-0.3

0.0

0.3

0.6

CO

2 Flu

x (P

gC/y

r)

– “Known truth”(OCN, Zaehle et al., 2010)

– Retrieved from “synthetic data”

(s04 v3.8 sites)

(3-monthly anomalies)

Northern Europe

2012 2013 2014 2015year (A.D.)

-0.3

-0.2

-0.1

0.0

CO

2 Flu

x (P

gC/y

r)

What do the atmospheric stations “see”?Testing existing and potential CO2 observations (RINGO)

just-to-prevent-the-PDF-page-to-be-flipped

W Europe

2012 2013 2014 2015year (A.D.)

-0.6

-0.3

0.0

0.3

0.6

CO

2 Flu

x (P

gC/y

r)

– “Known truth”(OCN, Zaehle et al., 2010)

– Retrieved from “synthetic data”

(s04 v3.8 sites)

(3-monthly anomalies)

Northern Europe

2012 2013 2014 2015year (A.D.)

-0.3

-0.2

-0.1

0.0

CO

2 Flu

x (P

gC/y

r)

– Retrieved from “synthetic data”

(s04 v3.8 sites +assumend FINNMAID data)

Travemunde↔ Helsinki

What do the atmospheric stations “see”?Testing existing and potential CO2 observations (RINGO)

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Conclusions W Europe

1990 1995 2000 2005 2010-1.2

-0.9

-0.6

-0.3

0.0

CO

2 Flu

x (P

gC/y

ear)

Atmospheric CO2 data & inversion:• Constraint on land variability• Southern Ocean trends

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Conclusions W Europe

1990 1995 2000 2005 2010-1.2

-0.9

-0.6

-0.3

0.0

CO

2 Flu

x (P

gC/y

ear)

Atmospheric CO2 data & inversion:• Constraint on land variability• Southern Ocean trends

Surface-ocean pCO2 data & mapping:Well-constrained ocean seasonality •

Ocean IAV constrained e.g. in Eq. Pac. •

Yearly CO2 flux (PgC/yr)

1990 1995 2000 2005 20100.0

0.2

0.4

0.6

0.8

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Conclusions W Europe

1990 1995 2000 2005 2010-1.2

-0.9

-0.6

-0.3

0.0

CO

2 Flu

x (P

gC/y

ear)

Atmospheric CO2 data & inversion:• Constraint on land variability• Southern Ocean trends

Surface-ocean pCO2 data & mapping:Well-constrained ocean seasonality •

Ocean IAV constrained e.g. in Eq. Pac. •

Yearly CO2 flux (PgC/yr)

1990 1995 2000 2005 20100.0

0.2

0.4

0.6

0.8

Ship-based atmospheric CO2 meas.:• Testing impact of additional data• Potential for regional flux estimates

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Conclusions W Europe

1990 1995 2000 2005 2010-1.2

-0.9

-0.6

-0.3

0.0

CO

2 Flu

x (P

gC/y

ear)

Atmospheric CO2 data & inversion:• Constraint on land variability• Southern Ocean trends

Surface-ocean pCO2 data & mapping:Well-constrained ocean seasonality •

Ocean IAV constrained e.g. in Eq. Pac. •

Yearly CO2 flux (PgC/yr)

1990 1995 2000 2005 20100.0

0.2

0.4

0.6

0.8

Ship-based atmospheric CO2 meas.:• Testing impact of additional data• Potential for regional flux estimates

Products available for download:Atmospheric CO2 inversion •

pCO2-based mixed-layer scheme •Combined products, sensitivity cases, atm. fields •

www.BGC-Jena.mpg.de/CarboScope/

JenaCarboScope

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BACK-UP SLIDES

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Statistical

Interpolation

Linear

Regression

Non-linear

Regression

Model-based

Regr./Tuning

Role of driver data

Modelassump-

tions

Direct data signals

Bridging data gaps

−→ Interesting complementarity−→ Extracting robust features

SOCOM: Collating 14 mapping methods

Mapping methods

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Statistical

Interpolation

Linear

Regression

Non-linear

Regression

Model-based

Regr./Tuning

Role of driver data

Modelassump-

tions

Direct data signals

Bridging data gaps

−→ Interesting complementarity−→ Extracting robust features

SOCOM: Collating 14 mapping methods

Jena-MLS �

[Rodenbeck et al.]

� ETH-SOMFFN[Landschutzer

et al.]

Mapping methods

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(18.%) Jena oc_v1.4S

(28.%) ETH-SOMFFN2016

Yearly CO2 flux (PgC/yr)

1985 1990 1995 2000 2005 2010 20150.1

0.2

0.3

0.4

0.5

Yearly pCO2 mismatch (uatm)

1985 1990 1995 2000 2005 2010 2015-50

-30

-10

10

30

50

Cross Validation

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(18.%) Jena oc_v1.4S

(28.%) ETH-SOMFFN2016

Yearly CO2 flux (PgC/yr)

1985 1990 1995 2000 2005 2010 20150.1

0.2

0.3

0.4

0.5

Yearly pCO2 mismatch (uatm)

1985 1990 1995 2000 2005 2010 2015-50

-30

-10

10

30

50

(18.%) Jena oc_v1.4S

Yearly pCO2 (uatm)

1985 1990 1995 2000 2005 2010 2015360

380

400

420

440

460

Cross Validation

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(18.%) Jena oc_v1.4S

(28.%) ETH-SOMFFN2016

Yearly CO2 flux (PgC/yr)

1985 1990 1995 2000 2005 2010 20150.1

0.2

0.3

0.4

0.5

Yearly pCO2 mismatch (uatm)

1985 1990 1995 2000 2005 2010 2015-50

-30

-10

10

30

50

(18.%) Jena oc_v1.4S

(100.%) Jena oc_v1.4S Benchmark

Yearly pCO2 (uatm)

1985 1990 1995 2000 2005 2010 2015360

380

400

420

440

460

“Benchmark”:Keep seasonality+trend, but no IAV→ Mismatch ≈ signal size→ “100% error”

Cross Validation

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(18.%) Jena oc_v1.4S

(28.%) ETH-SOMFFN2016

Yearly CO2 flux (PgC/yr)

1985 1990 1995 2000 2005 2010 20150.1

0.2

0.3

0.4

0.5

Yearly pCO2 mismatch (uatm)

1985 1990 1995 2000 2005 2010 2015-50

-30

-10

10

30

50

Interpolation: Regression:Time-dep. DoF’s Constant DoF’s→ Any IAV possible → IAV from drivers

Cross Validation

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(18.%) Jena oc_v1.4S

Yearly CO2 flux (PgC/yr)

1985 1990 1995 2000 2005 2010 20150.1

0.2

0.3

0.4

0.5

Yearly pCO2 mismatch (uatm)

1985 1990 1995 2000 2005 2010 2015-50

-30

-10

10

30

50

Cross Validation

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(18.%) Jena oc_v1.4S(121.%) Jena oc_v1.4S (CrossVal5yr0)

Yearly CO2 flux (PgC/yr)

1985 1990 1995 2000 2005 2010 20150.1

0.2

0.3

0.4

0.5

Yearly pCO2 mismatch (uatm)

1985 1990 1995 2000 2005 2010 2015-50

-30

-10

10

30

50

No dataData

No dataData

No dataData

→ Data-only interpolationcannot bridge multi-year gaps

Cross Validation

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(28.%) ETH-SOMFFN2016

(48.%) ETH-SOMFFN2016 (CrossVal5yr0)

Yearly CO2 flux (PgC/yr)

1985 1990 1995 2000 2005 2010 20150.1

0.2

0.3

0.4

0.5

Yearly pCO2 mismatch (uatm)

1985 1990 1995 2000 2005 2010 2015-50

-30

-10

10

30

50

No dataData

No dataData

No dataData

→ Regression against drivers(SST, SSS, Chl-a, atm. CO2)offers some bridging capacity

Cross Validation

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(28.%) ETH-SOMFFN2016

(48.%) ETH-SOMFFN2016 (CrossVal5yr0)

Yearly CO2 flux (PgC/yr)

1985 1990 1995 2000 2005 2010 20150.1

0.2

0.3

0.4

0.5

Yearly pCO2 mismatch (uatm)

1985 1990 1995 2000 2005 2010 2015-50

-30

-10

10

30

50

No dataData

No dataData

No dataData

Yearly pCO2 mismatch (uatm)

1985 1990 1995 2000 2005 2010 2015-50

-30

-10

10

30

50

DataNo data

DataNo data

DataNo data

Cross Validation

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(28.%) ETH-SOMFFN2016

(62.%) ETH-SOMFFN2016 (Unconstrained periods)

Yearly CO2 flux (PgC/yr)

1985 1990 1995 2000 2005 2010 20150.1

0.2

0.3

0.4

0.5

Yearly pCO2 mismatch (uatm)

1985 1990 1995 2000 2005 2010 2015-50

-30

-10

10

30

50

→ Regression against drivers

(SST, SSS, Chl-a, atm. CO2)offers some bridging capacity

Cross Validation

just-to-prevent-the-PDF-page-to-be-flipped

(28.%) ETH-SOMFFN2016

(35.%) ETH-SOMFFN2016, regr. SST & SSS

Yearly CO2 flux (PgC/yr)

1985 1990 1995 2000 2005 2010 20150.1

0.2

0.3

0.4

0.5

Yearly pCO2 mismatch (uatm)

1985 1990 1995 2000 2005 2010 2015-50

-30

-10

10

30

50

Chl-a data only available since 1998

– do SST and SSS suffice?

→ Less fitting capacity(but main modes similar)

Cross Validation

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(28.%) ETH-SOMFFN2016(62.%) ETH-SOMFFN2016 (Unconstrained periods)(35.%) ETH-SOMFFN2016, regr. SST & SSS(77.%) ETH-SOMFFN2016, regr. SST & SSS (Unconstr.)

Yearly CO2 flux (PgC/yr)

1985 1990 1995 2000 2005 2010 20150.1

0.2

0.3

0.4

0.5

Yearly pCO2 mismatch (uatm)

1985 1990 1995 2000 2005 2010 2015-50

-30

-10

10

30

50

Chl-a data only available since 1998

– do SST and SSS suffice?

→ Less fitting capacity(but main modes similar)

→ Less bridging capacity

Cross Validation

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(18.%) Jena oc_v1.4S(16.%) Jena oc_v1.4S, regr. SST & SSS(131.%) Jena oc_v1.4S, regr. SST & SSS (Unconstr.)

Yearly CO2 flux (PgC/yr)

1985 1990 1995 2000 2005 2010 20150.1

0.2

0.3

0.4

0.5

Yearly pCO2 mismatch (uatm)

1985 1990 1995 2000 2005 2010 2015-50

-30

-10

10

30

50

Cross Validation

just-to-prevent-the-PDF-page-to-be-flipped

(47.%) ETH-SOMFFN2016

Yearly CO2 flux (PgC/yr)

1985 1990 1995 2000 2005 2010 2015-0.4-0.3

-0.2

-0.1

0.0

0.10.2

Yearly pCO2 mismatch (uatm)

1985 1990 1995 2000 2005 2010 2015-50

-30

-10

10

30

50

Southern Ocean – sparse data

Cross Validation

just-to-prevent-the-PDF-page-to-be-flipped

(47.%) ETH-SOMFFN2016

(106.%) ETH-SOMFFN2016 (Unconstrained periods)

Yearly CO2 flux (PgC/yr)

1985 1990 1995 2000 2005 2010 2015-0.4-0.3

-0.2

-0.1

0.0

0.10.2

Yearly pCO2 mismatch (uatm)

1985 1990 1995 2000 2005 2010 2015-50

-30

-10

10

30

50

Southern Ocean – sparse data

→ Bridging difficult &difficult to test

Cross Validation

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(47.%) ETH-SOMFFN2016(106.%) ETH-SOMFFN2016 (Unconstrained periods)(53.%) ETH-SOMFFN2016, regr. SST & SSS

Yearly CO2 flux (PgC/yr)

1985 1990 1995 2000 2005 2010 2015-0.4-0.3

-0.2

-0.1

0.0

0.10.2

Yearly pCO2 mismatch (uatm)

1985 1990 1995 2000 2005 2010 2015-50

-30

-10

10

30

50

Southern Ocean – sparse data

→ Bridging difficult &difficult to test

→ again main modes similar w/o Chl-a

Cross Validation

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(37.%) Jena oc_v1.4S

(47.%) ETH-SOMFFN2016

Yearly CO2 flux (PgC/yr)

1985 1990 1995 2000 2005 2010 2015-0.4-0.3

-0.2

-0.1

0.0

0.10.2

Yearly pCO2 mismatch (uatm)

1985 1990 1995 2000 2005 2010 2015-50

-30

-10

10

30

50

Southern Ocean – sparse data

→ Bridging difficult &difficult to test

→ again main modes similar w/o Chl-a

→ Decadal trends also from data directly

Cross Validation

just-to-prevent-the-PDF-page-to-be-flipped

(25.%) ETH-SOMFFN2016

(18.%) Jena-MLS14SSS

Yearly CO2 flux (PgC/yr)

1985 1990 1995 2000 2005 2010 2015-2.50-2.25-2.00-1.75-1.50-1.25-1.00-0.75

Yearly pCO2 mismatch (uatm)

1985 1990 1995 2000 2005 2010 2015-50

-30

-10

10

30

50

Global Ocean flux– affected by data-sparse regions

→ Complementary mapping methods(interpolation, regression)help to assess robustness

Cross Validation

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