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LUDWIG-MAXIMILIANS-UNIVERSITÄTMÜNCHEN
Agenda
● Overview● Carbon- electronics and hybridization● Raman characterisation● 0-d Buckyball● 1-d Carbon Nanotubes● 2-d Graphene● 3-d Systems (Applications)
Page 1 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Carbon Based Nanostructures
LUDWIG-MAXIMILIANS-UNIVERSITÄTMÜNCHEN
Page 2 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Carbon Based Nanostructures
Overview
Carbon (C): just 0.09% of the geosphere, but:
CH2, CH4, C2H4, ...
CO, CO2, CS2, CF4, …
H2CO3, C6H12O6, C2H6O, …
allotropes of carbon:
diamond, graphite, amorphous carbon
also: Buckyballs, CNTs, Graphene – known since the 1970s
Page 3 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Carbon electronics
● electron configuration: 1s² 2s² 2p²● sorts of hybridization: sp, sp², sp³
Page 4 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
sp³ sp²
Hybridization
Page 5 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
sp³ (diamond) sp² (graphite)
Hybridization - Properties
http://en.wikipedia.org/wiki/Carbon
Page 6 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Raman Spectroscopy
Monochromatic light on object → scattering (mostly Rayleigh)
Excitation in the ~const. Regime → excactly defined ΔE (specific for each material)
Page 7 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Raman Spectroscopy
Example: Comparison of three pure Elements
Lower frequencies – less energy in atom-vibrations (phonons)
Joe Hodkiewicz: “Characterizing Carbon Materials with Raman Spectroscopy“Joe Hodkiewicz: “Characterizing Carbon Materials with Raman Spectroscopy“
Page 8 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Diamond-band: ~1335cm ¹⁻Graphite-band: ~1582cm ¹⁻
Raman Spectrum of Carbon
Joe Hodkiewicz: “Characterizing Carbon Materials with Raman Spectroscopy“Joe Hodkiewicz: “Characterizing Carbon Materials with Raman Spectroscopy“
Page 9 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
● Natural ● Production via electric arc (inert atmosphere)● Most stable C60, C70, C76, C80, C82, C84, C86, C90, C94, ...
0-d – Fullerenes (Buckyballs)
Page 10 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Raman Spectrum of Buckyballs
Diamond-band: ~1335cm ¹⁻Graphit-band: ~1582cm ¹⁻
0-d – Fullerenes (Buckyballs)
G-band D-band
Joe Hodkiewicz: “Characterizing Carbon Materials with Raman Spectroscopy“Joe Hodkiewicz: “Characterizing Carbon Materials with Raman Spectroscopy“
Page 11 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
● Properties● Applications● Endohedral fullerenes
0-d - Fullerenes (Buckyballs)
Page 12 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
● Structure – wrapped graphite layer● SW and MW tubes
1-d – Carbon Nanotubes (CNTs)
Page 13 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Growth via chemical vapor deposition (CVD)
1-d – Carbon Nanotubes (CNTs)
Page 14 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Raman Spectrum of CNTs Diamond-band: ~1335cm ¹⁻Graphit-band: ~1582cm ¹⁻
1-d – Carbon Nanotubes (CNTs)
Joe Hodkiewicz: “Characterizing Carbon Materials with Raman Spectroscopy“Joe Hodkiewicz: “Characterizing Carbon Materials with Raman Spectroscopy“
Page 15 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Different species
1-d – Carbon Nanotubes (CNTs)
Andrew G. Rinzler†, Richard E. Smalley† & Cees Dekker*: “Electronic structure of Andrew G. Rinzler†, Richard E. Smalley† & Cees Dekker*: “Electronic structure of atomically resolved carbon nanotubesatomically resolved carbon nanotubes
Page 16 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Electrical properties
for m=n → armchair → metallic
otherwise: if n-m=3*l (with l=1,2,3,...) → also metallic
if n-m≠3*l → semiconducting, band gap E 0.5eV≃
1-d – Carbon Nanotubes (CNTs)
http://en.wikipedia.org/wiki/File:Carbon_nanotube_bands.gif
Page 17 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
● Structure● Single layer, dual layer
2-d – Graphene
Page 18 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Raman Spectrum of Graphene Diamond-band: ~1335cm ¹⁻Graphit-band: ~1582cm ¹⁻
2-d – Graphene
Joe Hodkiewicz: “Characterizing Carbon Materials with Raman Spectroscopy“Joe Hodkiewicz: “Characterizing Carbon Materials with Raman Spectroscopy“
Page 19 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Electrical properties
linear disp. relation → zero effective mass!!
2-d – Graphene
Page 20 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Klein Paradox (better: Klein effect / Klein tunneling)
2-d – Graphene
Katsnelson, Novoselov and Geim: “Chiral tunneling and the Klein paradox in graphene”
???
Page 21 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Klein tunneling
2-d – Graphene
Katsnelson, Novoselov and Geim: “Chiral tunneling and the Klein paradox in graphene”
Page 22 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Klein Paradox – experiments
2-d – Graphene
N. Stander, B. Huard, D. Goldhaber-Gordon: “Evidence for Klein Tunneling in Graphene p-n Junctions”, Physical Review Letters 2009
result: saturation of resistance for growing potential barrier (consistent with description)
Page 23 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
● abnormal quantum hall effect● other extraordinary properties
2-d – Graphene
Page 24 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Applications – mechanical (CNTs)
specific strength up to 300 times stronger than best steel
● mix with plastics (similar to carbon fibers)
● Paraffin wax + CNTs → twine
3-d Structures
https://theconversation.com/power-to-you-carbon-nanotube-muscles-are-going-strong-10747
Page 25 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Applications - electrical
● displays● Solar cells● nanoelectronics● CNT transistors● Hydrogen storage● ...
3-d Structures
Dimitrakakis, Froudakis, Tylianakis: “Designing novel carbon nanostructures for hydrogen storage”
LUDWIG-MAXIMILIANS-UNIVERSITÄTMÜNCHEN
Page 26 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Carbon Based Nanostructures
The end
Thanks for the attention!
Page 27 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Pictures (1)Pictures (1)
http://spie.org/x33929.xmlhttp://spie.org/x33929.xml
http://www.nanowerk.com/nanotechnology/ten_things_you_should_know_4.phphttp://www.nanowerk.com/nanotechnology/ten_things_you_should_know_4.php
http://en.wikipedia.org/wiki/Carbon_nanotubehttp://en.wikipedia.org/wiki/Carbon_nanotube
http://www.intechopen.com/books/carbon-nanotubes/interconnect-challenges-and-carbon-nanotube-as-interconnect-in-nano-vlsi-circuitshttp://www.intechopen.com/books/carbon-nanotubes/interconnect-challenges-and-carbon-nanotube-as-interconnect-in-nano-vlsi-circuits
http://www.essentialchemicalindustry.org/materials-and-applications/nanomaterials.htmlhttp://www.essentialchemicalindustry.org/materials-and-applications/nanomaterials.html
http://sekidiamond.com/images/hf/applications/raman.gifhttp://sekidiamond.com/images/hf/applications/raman.gif
http://en.wikipedia.org/wiki/Carbonhttp://en.wikipedia.org/wiki/Carbon
http://www.mdpi.com/1996-1944/3/11/4871http://www.mdpi.com/1996-1944/3/11/4871
http://upload.wikimedia.org/wikipedia/commons/thumb/a/ae/Fullerene_4.png/250px-Fullerene_4.pnghttp://upload.wikimedia.org/wikipedia/commons/thumb/a/ae/Fullerene_4.png/250px-Fullerene_4.png
http://upload.wikimedia.org/wikipedia/commons/thumb/e/e1/Endohedral_fullerene.png/220px-Endohedral_fullerene.pnghttp://upload.wikimedia.org/wikipedia/commons/thumb/e/e1/Endohedral_fullerene.png/220px-Endohedral_fullerene.png
https://theconversation.com/power-to-you-carbon-nanotube-muscles-are-going-strong-10747https://theconversation.com/power-to-you-carbon-nanotube-muscles-are-going-strong-10747
http://static.newworldencyclopedia.org/0/00/NanoBud.JPGhttp://static.newworldencyclopedia.org/0/00/NanoBud.JPG
Sources
Page 28 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
Pictures (2)Pictures (2)
http://afrodita.rcub.bg.ac.rs/~rzoran/Allotropes%20of%20carbon_files/image002.gifhttp://afrodita.rcub.bg.ac.rs/~rzoran/Allotropes%20of%20carbon_files/image002.gif
http://yfzhang.sjtu.edu.cn/en/research.asp?id=7http://yfzhang.sjtu.edu.cn/en/research.asp?id=7
http://www.eie.gr/nhrf/institutes/tpci/researchteams/mspc/mspc-cnanotubes-en.htmlhttp://www.eie.gr/nhrf/institutes/tpci/researchteams/mspc/mspc-cnanotubes-en.html
http://en.wikipedia.org/wiki/File:Carbon_nanotube_bands.gifhttp://en.wikipedia.org/wiki/File:Carbon_nanotube_bands.gif
http://ncem.lbl.gov/images/G2.jpghttp://ncem.lbl.gov/images/G2.jpg
http://en.wikipedia.org/wiki/Raman_scatteringhttp://en.wikipedia.org/wiki/Raman_scattering
http://upload.wikimedia.org/wikipedia/commons/0/04/Diatomic_phonons.pnghttp://upload.wikimedia.org/wikipedia/commons/0/04/Diatomic_phonons.png
Sources
Page 29 17.12.2013 Advanced Physics of Nanosystems Christian Straubinger
PapersPapers
M.S. Dresselhaus: „Carbon-Based Nanostructures“M.S. Dresselhaus: „Carbon-Based Nanostructures“
D.W. Brenner, O.A. Shenderova, D.A. Areshkin, J.D. Schall1 and S.-J. V. Frankland: “Atomic Modeling of D.W. Brenner, O.A. Shenderova, D.A. Areshkin, J.D. Schall1 and S.-J. V. Frankland: “Atomic Modeling of Carbon-Based Nanostructures as a Tool for Developing New Materials and Technologies“Carbon-Based Nanostructures as a Tool for Developing New Materials and Technologies“
K. S. Novoselov, V. I. Falko, L. Colombo, P. R. Gellert, M. G. Schwab & K. Kim: “A roadmap for graphene“K. S. Novoselov, V. I. Falko, L. Colombo, P. R. Gellert, M. G. Schwab & K. Kim: “A roadmap for graphene“
Joe Hodkiewicz: “Characterizing Carbon Materials with Raman Spectroscopy“, Thermo Fisher Scientific, 2010Joe Hodkiewicz: “Characterizing Carbon Materials with Raman Spectroscopy“, Thermo Fisher Scientific, 2010
Dimitrakakis, Froudakis, Tylianakis: “Designing novel carbon nanostructures for hydrogen storage”Dimitrakakis, Froudakis, Tylianakis: “Designing novel carbon nanostructures for hydrogen storage”
Katsnelson, Novoselov and Geim: “Chiral tunneling and the Klein paradox in graphene”Katsnelson, Novoselov and Geim: “Chiral tunneling and the Klein paradox in graphene”
N. Stander, B. Huard, D. Goldhaber-Gordon: “Evidence for Klein Tunneling in Graphene p-n Junctions”, N. Stander, B. Huard, D. Goldhaber-Gordon: “Evidence for Klein Tunneling in Graphene p-n Junctions”, Physical Review Letters 2009Physical Review Letters 2009
Mikhail I. Katsnelson: “Graphene: carbon in two dimensions“Mikhail I. Katsnelson: “Graphene: carbon in two dimensions“
Jeroen W. G. Wildo¨ er*, Liesbeth C. Venema*,Jeroen W. G. Wildo¨ er*, Liesbeth C. Venema*,
Andrew G. Rinzler†, Richard E. Smalley† & Cees Dekker*: “Electronic structure of atomically resolved carbon Andrew G. Rinzler†, Richard E. Smalley† & Cees Dekker*: “Electronic structure of atomically resolved carbon nanotubes“nanotubes“
Sources
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